Coating Or Adhesive Composition For Application To A Wet Or Contaminated Surface (e.g., Underwater Or Oil-contaminated, Etc.) Or Process Of Preparing Patents (Class 523/177)
  • Patent number: 11702363
    Abstract: A preparation method for a concrete additive for a maritime work environment includes: S1, compounding a volcanic ash material containing aluminum oxide and lime in proportion, loading a mixture into a sugar coating machine, and spraying a proper amount of alcohol, to prepare spherical particles; S2, adding the spherical particles in S1 and cement into the sugar coating machine, uniformly spraying deionized water in a rotating process, and coating surface layers of the spherical particles with a layer of cement for maintenance; and S3, placing the maintained particles in S2 into a hydrophobic emulsion, and coating the surface layers of the particles with a layer of hydrophobic emulsion, to obtain a concrete additive.
    Type: Grant
    Filed: October 18, 2022
    Date of Patent: July 18, 2023
    Assignee: JIANGSU UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Qiwei Zhan, Zhihong Pan, Anhui Wang, Juanlan Zhou, Changhao Fu, Wanying Dong, Haitao Hu, Xinyu Wang, Xinxuan Sun, Yiming Ge
  • Patent number: 11312038
    Abstract: The present invention provides wood preservative composition containing a dispersed and/or emulsified phase comprising a wood preservative component; and a stabilizer. The stabilizer is a cationic polymer, an enzyme, organic polymer, quaternary ammonium compound and/or a mixture thereof. Also provided is a method of preserving wood or other cellulosic material which comprises applying to the wood or other cellulosic material.
    Type: Grant
    Filed: April 30, 2015
    Date of Patent: April 26, 2022
    Assignee: ARCH WOOD PROTECTION, INC.
    Inventors: Kimberlee Thompson, Susan Thomason, Alex Valcke, David Cantrell
  • Patent number: 10913861
    Abstract: A process and composition for coating a pipe and a pipe support includes mixing a cellulose acetate, a plasticizer, and an oil together so as to form a solid mixture, heating the solid mixture so as to form a liquid state, covering an area of the joinder of the pipe and the pipe support with the liquid state, and drying the liquid state on the area of the joinder. An ethylene-based polymer stabilizer is added to the mixture of the cellulose acetate, the plasticizer and the oil. The oil migrates by gravity from the liquid state from the covered pipe into an area of contact between the pipe and the pipe support. The liquid state is applied around the outer diameter of the pipe and over the outer surface of the pipe support underlying the outer diameter of the pipe.
    Type: Grant
    Filed: June 14, 2018
    Date of Patent: February 9, 2021
    Assignee: STOPAQ B.V.
    Inventor: Edward Hall
  • Patent number: 10844279
    Abstract: Proppants coated with a cured reactive resin composition containing 92-99.5 wt. % of a reactive resin and 0.5 to 8 wt. % of a silicone resin containing at least 5 wt. % of alkoxy groups and at least 20 mol percent of T and/or Q units, in liquid form, exhibit high freedom from fines generation, and are free flowing.
    Type: Grant
    Filed: June 29, 2017
    Date of Patent: November 24, 2020
    Assignee: WACKER CHEMIE AG
    Inventors: Sebastian Knoer, Daniel Calimente, Arndt Schlosser
  • Patent number: 10131798
    Abstract: A composition containing 4,5-dichloro-2-n-octylisothiazolin-3-one, an activated carbon having a surface area of at least 700 m2/g and a cured isocyanate.
    Type: Grant
    Filed: December 8, 2015
    Date of Patent: November 20, 2018
    Assignees: DOW GLOBAL TECHNOLGOIES LLC, ROHM AND HAAS COMPANY
    Inventors: Bolatito Ajayi, David M. Laganella
  • Patent number: 9540520
    Abstract: A composition containing unique particles of copper pyrithione wherein greater than 20 wt % to 90 wt % of the particles have a particle size of greater than 10 microns, as determined by laser light scattering using a particle size distribution analyzer, and wherein the particles are flat acicular needle-shaped is described herein. Also described herein is an antifouling paint containing the copper pyrithione and a method of making the composition and antifouling paint.
    Type: Grant
    Filed: August 17, 2012
    Date of Patent: January 10, 2017
    Assignee: Arch Chemicals, Inc.
    Inventors: Paul S. Kappock, Robert J. Martin
  • Patent number: 9266292
    Abstract: Resins and thermoset composites comprising them, these materials being able to be hot-fashioned. These compositions resulting from placing at least one thermosetting resin precursor, this thermosetting resin precursor comprising hydroxyl functions and/or epoxy groups, and optionally ester functions, in contact with at least one hardener chosen from carboxylic acids, in the presence of at least one transesterification catalyst whose total molar amount is between 5% and 25% of the total molar amount of hydroxyl and epoxy contained in the thermosetting resin precursor. Process for manufacturing these materials, process for transforming and process for recycling these materials. New solid forms of resins and of thermoset composites that may be used in the implementation of these processes.
    Type: Grant
    Filed: May 30, 2011
    Date of Patent: February 23, 2016
    Assignees: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, ARKEMA FRANCE
    Inventors: Ludwik Leibler, Damien Montarnal, François-Genes Tournilhac, Mathieu Capelot
  • Patent number: 9017473
    Abstract: The invention relates to a method of neutralizing paints, that includes adding at least one associative neutralizing agent to a formulation such as a pigment concentrate, a white paint base or paint. The associative neutralizing agent includes at least one neutralizing group N and at least one nitrogenous associative group A bonded together by at least one “spacer” group Sp. The invention also relates to pigment concentrates and to paints containing at least one such associative neutralizing agent.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: April 28, 2015
    Assignee: Arkema France
    Inventors: Bruno Van Hemelryck, Manuel Hidalgo
  • Patent number: 8946319
    Abstract: The invention relates to the use of butyl ionomers or partially halogenated butyl ionomers in reducing a population of and/or preventing accumulation of organisms. The organisms may be bacteria, algae, fungi, mollusca or arthropoda. The invention also relates to coatings for shaped articles comprising the butyl ionomers.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: February 3, 2015
    Assignee: LAXNESS International S.A.
    Inventors: Dana Adkinson, Lorenzo P. Ferrari, J. Scott Parent, Ralph A. Whitney, Rui Resendes
  • Publication number: 20140311673
    Abstract: The disclosure is directed to an adhesive material which can be applied underwater comprising hydrophilic adhesive molecules. In other embodiments, the adhesive material may also include hydrophilic polymers and/or an oxidizing agent.
    Type: Application
    Filed: November 28, 2012
    Publication date: October 23, 2014
    Inventors: Boxin ZHAO, Fut (Kuo) Yang
  • Patent number: 8657943
    Abstract: 1-OH-2-acyl-sn-glycero-3-phosphocholine compounds and its analogs, pure or mixed, having formula WCH2CHXCH2PO3YCH2CH2Z, where W is preferably a hydroxyl group or an O-acyl group containing from 2 to 22 carbon atoms, and where X is preferably an O-acyl group containing from 2 to 22 carbon atoms or a hydroxyl (OH) and where Y may be an (O?) or OH and where Z is preferably a trimethyl-ammonium group [N+(CH3)3] can be protonated dimethyl ammonium [N+H(CH3)2] group. In the O-acyl groups containing 18 carbon atoms can be observed from 0 to 3 instaurations, useful as biocidal agents; processes for their preparation; and antifouling compositions, preferably paints useful in susceptible fouling surfaces, such as hulls of vessels. Methods to turn a surface into an antifouling surface, to a method to prevent fouling and to the antifouling surfaces comprising a coating of the said antifouling composition.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: February 25, 2014
    Assignee: UFRJ, IEAPM, UFF
    Inventors: William Romao Batista, Ricardo Coutinho, Maria Campos Beta Neves, Claudio Cerqueira Lopes, Rosangela Sabbatini Lopes, Vanessa de Almeida Martins, Renato Crespo Pereira
  • Patent number: 8575232
    Abstract: Provided are coating composition containing an organic polymer particle (A) composed of an organic polymer having a hydroxyl group and a cationic group in a molecule, the weight average particle size of which being 10 to 35 ?m, and a base resin (B), wherein the content of the organic polymer particle (A) is 0.5 to 5.0% by weight in the solid content of the coating composition, and a method of producing the same, and a coating film and underwater structure using the coating composition.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: November 5, 2013
    Assignees: Nippon Paint Co., Ltd., Nippon Paint Marine Coatings Co., Ltd.
    Inventors: Naoki Yamamori, Hiroshi Tominaga, Mamoru Shimada
  • Patent number: 8546471
    Abstract: A Waterborne adhesive comprising 1 to 50 weight-% of a (meth)acrylate copolymer manufactured by polymerization of at least one ester of methacrylic acid, acrylic acid, crotonic acid and/or itaconic acid with aliphatic alcohols, substituted aliphatic alcohols, aromatic alcohols, polyether glycols, and other copolymerizable monomers, having an acid number from 0 to 150 mgKOH/g, 0 to 40 wt-% of natural polymers 0.5 to 30 wt-% of urea, 0.1 to 20 wt-% of additives, characterized in that the adhesive contains 0.05 to 20 weight-% of a super absorbent polymer.
    Type: Grant
    Filed: February 6, 2012
    Date of Patent: October 1, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Nicolas De Calmes, Victor Dario Buj Vilalata, Ralf Gossen, Hermann-Josef Plum, Ethel Abrahams-Meyer
  • Patent number: 8507580
    Abstract: To provide a process for efficiently producing a fluorine type antifouling composition employing a short chain Rf group, which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has a good soil release property (SR property). A process for producing an antifouling composition, which comprises a step of subjecting monomer components (Z) comprising from 30 to 80 mass % of a monomer (a) having a polyfluoroalkyl group in which the number of carbon atoms to which fluorine atoms are bonded is from 4 to 6, and from 20 to 70 mass % of a monomer (b) having no polyfluoroalkyl group and having a hydrophilic group, to solution polymerization in a volatile organic solvent having a boiling point of at most 100° C.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: August 13, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroyuki Hara, Shuichiro Sugimoto, Takao Hirono
  • Patent number: 8367752
    Abstract: New gel coat composition, in particular new marine gel coat compositions, a process for their manufacture as well as their use to coat surfaces of articles exposed to light, water and solvents. The gel coats incorporate a precipitated silica having A BET surface of from 150 to 250 m2/g A SiO2 content of more than or equal to 98.5% by weight A Na2O content of less than or equal to 0.5% by weight.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: February 5, 2013
    Assignee: Evonik Degussa Corporation
    Inventors: James Toth, Matt Romaine
  • Patent number: 8309625
    Abstract: A method for preventing accumulation of organisms on a surface exposed to a marine environment. Nano-particles are provided in a water soluble polymer. The nano-particles have a thickness of about 2 nanometers and a major surface area of about 3 microns and are treated by a quaternary ammonium salt. The treated nano-particles are mixed into the water soluble polymer material. This mixture can be applied to the exposed surface. Biofouling is prevented by the sharpness of the nano-particles, sloughing of the water soluble material, and biocidal action caused by the quaternary ammonium salt.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: November 13, 2012
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Thomas S. Ramotowski
  • Publication number: 20120208920
    Abstract: A Waterborne adhesive comprising 1 to 50 weight-% of a (meth)acrylate copolymer manufactured by polymerization of at least one ester of methacrylic acid, acrylic acid, crotonic acid and/or itaconic acid with aliphatic alcohols, substituted aliphatic alcohols, aromatic alcohols, polyether glycols, and other copolymerizable monomers, having an acid number from 0 to 150 mgKOH/g, 0 to 40 wt-% of natural polymers 0.5 to 30 wt-% of urea, 0.1 to 20 wt-% of additives, characterized in that the adhesive contains 0.05 to 20 weight-% of a super absorbent polymer.
    Type: Application
    Filed: February 6, 2012
    Publication date: August 16, 2012
    Applicant: Henkel AG & Co. KGaA
    Inventors: Nicolas DE CALMES, Victor Dario BUJ VILALATA, Ralf GOSSEN, Hermann-Josef PLUM, Ethel ABRAHAMS-MEYER
  • Patent number: 8177896
    Abstract: A novel chemical genus of furan-2-one antifouling compound as non-toxic, environment friendly antifouling agent, a coating material for objects submerged under the water based on the furan-2-one compounds. The substituted furan-2-one antifouling compounds have a furan-2-one ring and an alkyl side chain thereto and are of the formula: where n=6-14, representing the number of carbon atoms in said side chain.
    Type: Grant
    Filed: April 16, 2009
    Date of Patent: May 15, 2012
    Assignee: The Hong Kong University of Science and Technology
    Inventors: Peiyuan Qian, Ying Xu, Xiaojian Zhou, Hongping He, Nobuhiro Fusetani, Wei-Min Dai
  • Publication number: 20110263751
    Abstract: The invention relates to a suspension comprising: fine-particulate particles in an amount of 0.01-50 wt %, wherein the particles have a fractal mass dimension Dm of less than or equal to 2.8, —fluid-elastic adhesive in an amount of 101-1000 parts by weight based on 100 parts of particles.
    Type: Application
    Filed: December 1, 2009
    Publication date: October 27, 2011
    Applicant: Wacker Chemie AG
    Inventors: Erwin-Peter Mayer, Herbert Barthel, Arnulf Schindelar
  • Patent number: 8022115
    Abstract: It has now been surprisingly and unexpectedly discovered that a combination of polychlorophenoxyphenol, a silver-containing biocide, and an organopolysiloxane, when added to UHMWPE, renders the UHMWPE resistant to both soft and hard fouling. The polychlorophenoxy phenol is preferably 2.4.4?-trichloro-2?-hydroxy-diphenylether and the metal-containing biocide is preferably a silver zeolite.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: September 20, 2011
    Assignee: Quadrant EPP AG
    Inventors: Joseph V. Gregg, Brian Yarcich
  • Patent number: 7989521
    Abstract: An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that is unlikely to cause a hairline crack and like coating film defects even when immersed in seawater for a long time, and that prevents or inhibits attachment of slime.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: August 2, 2011
    Assignee: Nitto Kasei Co., Ltd.
    Inventors: Kiyomi Mori, Hidenori Waku, Takayoshi Fujimoto, Satoshi Minamino
  • Publication number: 20110184088
    Abstract: The present invention relates to a coating material in the form of an aqueous composition comprising: 25% to 55% by weight of composite particles having an average particle size of 50 to 350 nm, in the form of an aqueous dispersion, which are constructed of 20% to 60% by weight, based on the composite particle, of inorganic solid having an average particle size of 5 to 100 nm, 40% to 80% by weight, based on the composite particle, of a polymer matrix having a T9 in the range from ?60 to +40° C. and obtainable by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer, and 20% to 50% by weight of fillers, with 5% to 40% by weight, based on the total solids content, being selected from aluminum silicates, borosilicate glasses, polymethyl methacrylate particles, and polystyrene particles, 1% to 30% by weight of pigments, and 0% to 5% by weight of one or more thickeners 0.
    Type: Application
    Filed: January 24, 2011
    Publication date: July 28, 2011
    Applicant: BASF SE
    Inventors: Bas LOHMEIJER, Oliver Wagner, Ekkehard Jahns
  • Patent number: 7977407
    Abstract: An object of the present invention is to provide a composition for forming an environment friendly antifouling coating film that can effectively exhibit an antifouling effect in seawater for a long period of time and furthermore exhibits a small temperature dependency of the coating film dissolving amount.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: July 12, 2011
    Assignee: Nitto Kasei Co., Ltd.
    Inventors: Kiyomi Mori, Hidenori Waku, Nobuyuki Hamaura, Takayoshi Fujimoto, Satoshi Minamino
  • Publication number: 20110123750
    Abstract: New gel coat composition, in particular new marine gel coat compositions, a process for their manufacture as well as their use to coat surfaces of articles exposed to light, water and solvents. The gel coats incorporate a precipitated silica having A BET surface of from 150 to 250 m2/g A SiO2 content of more than or equal to 98.5% by weight A Na2O content of less than or equal to 0.5% by weight.
    Type: Application
    Filed: February 4, 2011
    Publication date: May 26, 2011
    Applicant: Degussa Corporation
    Inventors: James TOTH, Matt ROMAINE
  • Publication number: 20110124772
    Abstract: Polymers with non-leaching antimicrobial activity and their use as surface coatings or bulk resins for medical devices. The antimicrobial polymers are prepared with antimicrobial moieties covalently bonded to a polymer chain end or to a polymer backbone at a side chain end. The antimicrobial moiety-containing endgroups include surface active (or surface assembling) moieties which promote enrichment of antimicrobial endgroups at the polymer surface and thus formation of an antimicrobially active surface. Polymers with built-in antimicrobial endgroups can be used as bulk resins, as antimicrobial additives, or as infection preventative coatings in the manufacture of medical devices (e.g., catheters, vascular access devices, peripheral lines, IV sites, drains, gastric feeding and tubes, and other implantable devices).
    Type: Application
    Filed: May 26, 2009
    Publication date: May 26, 2011
    Applicant: DSM IP Assets B.V.
    Inventors: Shanger Wang, Robert S. Ward, Yuan Tian, Li Li, Keith Mccrea, James Parakka, Robert L. Jones, JR.
  • Patent number: 7868056
    Abstract: Silicone compositions particularly useful for the production of anti-fouling varnishes for application to support substrates, these providing an anti-fouling varnish for textiles covered with silicone elastomers which is economical, adhesive, non-slip and glossy; the subject varnishes comprise a crosslinkable silicone composition containing, per 100 parts by weight: 1, at least 80 parts by weight of: (1.1), 2., 0.1 to 10 parts of weight of: (1.2), 3., 0 to 10 parts by weight of at least one polydimethylisiloxane (PDMS) acrylate or epoxide, 4., 0 to 10 parts by weight of at least one silylated compound which includes at least one ultrafine filler, 7., 0 to 10 parts by weight of at least one thickener, and 8., 0 to 10 parts by weigh of at least one additional functional additive.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: January 11, 2011
    Assignee: Bluestar Silicones France
    Inventors: Francis Lafaysse, Pierre Luciani, Didier Dhaler, Laurent Dumont, Jean-Marc Frances
  • Publication number: 20100267506
    Abstract: The invention provides a sliding material for use in a wet-type continuously variable transmission, the sliding material including a resin as a matrix and mesophase pitch carbon fibers, the mesophase pitch carbon fibers being included in the sliding material at a content ratio of from 1% by volume to 60% by volume.
    Type: Application
    Filed: November 26, 2008
    Publication date: October 21, 2010
    Inventors: Hiroyuki Murase, Atsushi Suzuki, Masaru Okuyama, Mamoru Tohyama, Toshihide Ohmori
  • Patent number: 7807734
    Abstract: Provided is a low friction type anti-fouling paint. The anti-fouling paint includes prepolymer fluid formed of 10% to 30% NCO mythylene diisocyanate of 100 wt %; and resin fluid formed of polyoxylpropylenediamine of about 42 wt % to 48 wt % for adjusting an elongation and a tensile strength of a paint film, polyethertriamine of about 8 wt % to 10 wt % having a molecular weight of 5,000 for adjusting a curing time, polydiphenyltriamine of about 15 wt % to 20 wt % for adjusting a curing physical property and increasing the elongation, a modified silicone fluid of about 8 wt % to 12 wt % for increasing a slip and an anti fouling property, a filler of about 5 wt % to 9 wt % for increasing an abrasion resistance, an adhesion promoter of about 1 wt % to 2 wt %, and a pigment of about 1 wt % to 2 wt %.
    Type: Grant
    Filed: December 18, 2006
    Date of Patent: October 5, 2010
    Inventor: Dong Kyu Kim
  • Patent number: 7790785
    Abstract: Silicone compositions particularly useful for the production of anti-fouling varnishes for application to support substrates, these providing an anti-fouling varnish for textiles covered with silicone elastomers which is economical, adhesive, non-slip and glossy; the subject varnishes comprise a crosslinkable silicone composition containing, per 100 parts by weight: 1, at least 80 parts by weight of: (1.1), 2., 0.1 to 10 parts of weight of: (1.2), 3., 0 to 10 parts by weight of at least one polydimethylisiloxane (PDMS) acrylate or epoxide, 4., 0 to 10 parts by weight of at least one silylated compound which includes at least one ultrafine filler, 7., 0 to 10 parts by weight of at least one thickener, and 8., 0 to 10 parts by weigh of at least one additional functional additive.
    Type: Grant
    Filed: June 27, 2005
    Date of Patent: September 7, 2010
    Assignee: Rhodia Chimie
    Inventors: Francis Lafaysse, Pierre Luciani, Didier Dhaler, Laurent Dumont, Jean-Marc Frances
  • Patent number: 7754787
    Abstract: Curable film-forming compositions comprising a film-forming resin and an organic sol of particles are provided. The sol of particles may be prepared by providing a suspension of particles in an aqueous medium; adding a first organic liquid compatible with the aqueous medium to form an admixture; reacting the particles with a first and a second modifying compound; adding a second organic liquid compatible with the liquid portion of the admixture wherein the second organic liquid is different from the first organic liquid; and maintaining the admixture at a temperature and pressure and for a time sufficient to substantially remove the water and the first organic liquid. The film-forming resin comprises an active hydrogen-functional polymer having low functionality; i.e., a functional group equivalent weight greater than 380 g/equivalent, and a crosslinking agent, yet surprisingly offers outstanding mar and scratch resistance.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: July 13, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Steven V. Barancyk
  • Publication number: 20100113643
    Abstract: The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.
    Type: Application
    Filed: April 9, 2008
    Publication date: May 6, 2010
    Applicant: DESIGNER MOLECULES, INC.
    Inventor: Stephen M. Dershem
  • Publication number: 20100069531
    Abstract: A process for producing a room temperature vulcanizable organopolysiloxane composition comprising: (A) 100 parts by weight of a diorganopolysiloxane having in one molecule at least two hydroxyl groups and/or hydrolyzable groups connecting to silicon atoms; (B) 0.2 to 10 parts by weight of an alkylene oxide compound having silicon atoms in a molecule; (C) 0.5 to 100 parts by weight of a silica; and (D) 0.5 to 30 parts by weight of a silane and/or condensate of partial hydrolyzate thereof, wherein said process comprises steps of hot-mixing component (A), component (B), and component (C) together, and subsequently mixing component (D) thereto.
    Type: Application
    Filed: September 11, 2009
    Publication date: March 18, 2010
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Takafumi Sakamoto, Tokuo Sato
  • Patent number: 7662222
    Abstract: This invention relates to the use of a combination of selected substances in paint to prevent the settlement and growth of different biofouling organisms with a reduced negative effect on the ecosystems compared to present methods.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: February 16, 2010
    Assignee: I-Tech AB
    Inventors: Magnus Nydén, Camilla Fant
  • Publication number: 20090274844
    Abstract: The present invention relates to a method for the establishment of a crack resistant epoxy paint coat and paint compositions suitable for said method. The method is developed for use in ballast tanks e.g. a ballast tank of a vessel. The method involves the steps: (i) applying a paint composition comprising an epoxy-based binder system onto the surface thereby forming a curable paint film on the surface, and (ii) allowing the curable paint film to cure thereby forming the epoxy paint coat. The paint composition has a viscosity of at the most 140 KU, when ready to be applied. The paint composition comprises 35-80% by solids volume of the paint of an epoxy-based binder system having a ratio between the hydrogen equivalents and the epoxy equivalents in the range of 20:100 to 120:100. The paint composition furthermore comprises 0.5-30% by solids volume of the paint of one or more fibres. The fibres have an average length, of at the most 250 ?m.
    Type: Application
    Filed: May 11, 2006
    Publication date: November 5, 2009
    Applicant: Hempel A/S
    Inventors: Kim Scheibel, Jorn Kahle, Michael Stanley Pedersen, Lars Thorslund Pedersen
  • Patent number: 7598299
    Abstract: The invention relates to the use of a polymer including salts of amine-functional groups and/or salts of phosphine-functional groups bound (pendant) to the backbone of the polymer, said salts including as counter-ion the anionic residue of an acid having an aliphatic, aromatic, or alkaryl hydrocarbon group comprising at least 5 carbon atoms in antifouling compositions. The invention further relates to antifouling compositions including such a polymer.
    Type: Grant
    Filed: January 11, 2005
    Date of Patent: October 6, 2009
    Assignee: Akzo Nobel Coatings International B.V.
    Inventor: Clayton Price
  • Publication number: 20090215925
    Abstract: The invention relates to a dispersion or solution of a polymer in water, organic solvents or mixtures thereof. The invention is characterised in that the polymer contains at least 0.001 mols of 3,4 dihydroxyphenyl groups (calculated at 109 g/mol) for 100 g polymer.
    Type: Application
    Filed: January 18, 2005
    Publication date: August 27, 2009
    Applicant: BASF Aktiengesellschaft
    Inventors: Dieter Urban, Reinhold Schwalm, Stefan Kirsch, Kai Michael Exner, Alexander Centner
  • Patent number: 7553481
    Abstract: An underwater antifouling coating composition which contains a metal pyrithione compound and cuprous oxide as an active ingredient, and a compound represented by the general formula (II): (wherein M2 is H, Na, ½Zn or ½Cu) as a stabilizer has high storage stability over long.
    Type: Grant
    Filed: March 14, 2003
    Date of Patent: June 30, 2009
    Assignee: API Corporation
    Inventors: Yasuhiro Kozasa, Yuji Koga
  • Patent number: 7531581
    Abstract: The invention herein relates to the method and use in an antifouling paint that specifically and efficiently impede settlement of for example barnacles on aquatic structures, using imidazole containing compound, such as Medetomidine, bound to a sulfonated, acid sulphate ester, phosphonic acid, carboxylic acid or acid phosphate ester modified polymer backbone such as polystyrene or acrylate polymers. The aim is to employ the biocide-polymer complexes as additives in a self-polishing paint for controlled release purposes.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: May 12, 2009
    Assignee: I-Tech AB
    Inventors: Magnus Nydén, Camilla Fant, Krister Holmberg, Lars Swanson
  • Publication number: 20090114122
    Abstract: A composition for sealing leaks in an engine includes a water-soluble metal silicate, a body of organic fibers, and a body of inorganic fibers. The organic fibers may include synthetic polymeric fibers as well as natural fibers such as cellulose and animal-derived materials. The inorganic fibers may include refractory fibers such as glass, ceramic or mineral fibers. The composition may be prepared in the form of a dry material or as a solution. Also disclosed are methods for using the composition.
    Type: Application
    Filed: January 8, 2009
    Publication date: May 7, 2009
    Inventor: Douglas Erick
  • Publication number: 20080300341
    Abstract: A slurry rheology modifier comprises a first water-soluble low-molecular compound [referred to hereinafter as compound (A)] and a second water-soluble low-molecular compound [referred to hereinafter as compound (B)] being different from the compound (A), wherein the viscosity of an aqueous solution at 20° C. prepared by mixing an aqueous solution SA (with a viscosity at 20° C. of 100 mPa·s or less) of compound (A) with an aqueous solution SB (with a viscosity at 20° C. of 100 mPa·s or less) of compound (B) in the ratio of 50/50 by weight can be at least twice as high as the viscosity of either aqueous solution before mixed.
    Type: Application
    Filed: April 30, 2008
    Publication date: December 4, 2008
    Inventors: Hotaka Yamamuro, Koji Koyanagi, Daisuke Shiba
  • Patent number: 7442240
    Abstract: An alkoxylpropyl isothiazolinone of formula: C6H6Cl2NO2SR, in which R is CH3, CH2CH3, CH(CH3)2, CH2CH2CH2CH3, CH2CH2OCH3 or CH2CH2OC6H5Cl. A method for preparing the isothiazolinone by reacting sodium polysulphide with methyl acrylate to obtain dimethyl dithiodipropionate, followed by aminolysis with alkoxyl propylamine to obtain N,N?-dialkoxylpropyldithio-dipropionamide, which is then reacted with sulfuric chloride. The alkoxylpropyl-isothiazolinone of the invention can be used for preparing marine antifouling paint coating as antifoulant, and also used as bactericide.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: October 28, 2008
    Assignee: Ocean University of China
    Inventors: Liangmin Yu, Xiaohui Jiang, Zhiming Zhang, Huanzhi Xu, Changcheng Li
  • Patent number: 7390843
    Abstract: An antifouling coating which comprises a varnish comprised of a metal-containing acrylic resin having, in a side chain thereof, at least one group represented by the following formula (1): wherein X represents a group of the formula: n represents 0 or 1; Y represents a hydrocarbon group; M represents a metal; m represents an integer equal to [(the valence number of metal M)?1]; A represents an organic acid residue derived from a monobasic acid, said varnish having a nonvolatile fraction of not less than 40 weight % and a viscosity at 25° C. of not more than 18 poises and said antifouling coating having a volatile organic compound (VOC) content of not more than 400 g/L.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: June 24, 2008
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Kiyoaki Higo, Masayuki Matsuda, Satoshi Okamoto, Naoki Yamamori
  • Patent number: 7377968
    Abstract: The present invention relates to blends of encapsulated biocides with free biocides. In particular, the present invention relates to blends of encapsulated 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone (“DCOIT”) with free biocides. The invention also relates to marine antifouling coatings and paints incorporating free biocides and encapsulated DCOIT, and using the free biocides and encapsulated DCOIT in marine antifouling coatings and paints.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: May 27, 2008
    Assignee: Rohm and Haas Company
    Inventors: Sarah E. Reybuck, Curtis Schwartz
  • Patent number: 7335248
    Abstract: Disclosed are marine coating compositions that are useful to inhibit the fouling of a marine structure by a broad spectrum of organisms. Generally, the marine coating composition comprises an antifouling agent and an organic vehicle.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: February 26, 2008
    Assignee: Novus International, Inc.
    Inventor: Ibrahim Abou-Nemeh
  • Patent number: 7311766
    Abstract: This invention relates to the use of a combination of selected substances in paint to prevent the settlement and growth of different biofouling organisms with a reduced negative effect on the ecosystems compared to present methods.
    Type: Grant
    Filed: March 10, 2006
    Date of Patent: December 25, 2007
    Assignee: I-Tech AB
    Inventors: Magnus Nydén, Camilla Fant
  • Patent number: 7297727
    Abstract: Polymers containing triarylsilyl(meth)acryloyl units are erodible in seawater and can be used to formulate antifouling marine paints. The polymers are characterized by low levels of triarylsilyl(meth) acrylate units and an erosion rate in seawater of 2 to about 15 microns per month.
    Type: Grant
    Filed: November 10, 2003
    Date of Patent: November 20, 2007
    Assignee: Arkema Inc.
    Inventors: Mark Anthony Aubart, Michael Benjamin Abrams, Gary Stephen Silverman, Jerome Obiols, Kenneth Kuo-Shu Tseng, David A. Mountz
  • Patent number: 7201790
    Abstract: The present invention provides a coating composition comprising zinc particles and a binder wherein the zinc particles contain at least 80% by weight of zinc flake and wherein the zinc particle to binder weight ratio is between 2:1 to 9:1. The coating composition may be an anti-corrosive composition or an antifouling composition. The coating composition may also inhibit or galvanize rust formation. The coating composition is of particular use in the marine industry.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: April 10, 2007
    Inventor: Ronald R. Savin
  • Patent number: 7169846
    Abstract: Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) at least one hydrophobic alkyl acrylate or alkyl methacrylate ester of an alcohol, (ii) at least about 1 wt. % of at least one hydrophilic monomer, (iii) at least about 5 wt. % of at least one partially hydrophilic alkyl acrylate or alkyl methacrylate ester of an alcohol, and (iv) a water-soluble or water-dispersible polymerizable surfactant selected from compounds having a terminal allyl amine moiety, substituted phenyl compounds having at least one alkenyl substituent, polyoxyalkylene-1-(allyloxymethyl) alkyl ether sulfate salts, or mixtures thereof, and the average particle size of the polymer is less than or equal to 200 nm. Also disclosed are processes for preparing same.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: January 30, 2007
    Assignee: Cytec Surface Specialties, Inc.
    Inventors: Augustin T. Chen, Jong-Shing Guo, Tibor Pernecker
  • Patent number: 7108741
    Abstract: A novel antifouling paint composition is disclosed. The antifouling paint composition comprises a resin of 5 to 20 wt %, a solvent of 3 to 30 wt %; a polyhexamethyleneguanidine salt of the following chemical formula 1 of 0.05 to 20 wt %, a pigment of 1 to 50 wt %; and cuprous oxide of 22 to 75 wt % and/or zinc pyrithione of the following chemical formula 2 of 0.05 to 20 wt %; wherein in chemical formula 1, X can be the same or different, and at least one of X is an inorganic acid salt or an organic acid salt; R1 can be the same or different, and is a linear or branched alkyl group containing from 1 to 20 carbon atoms, a phenyl group, a chlorophenyl group, a bromophenyl group, an iodophenyl group, a benzyl group, a chlorobenzyl group, a bromobenzyl group, a iodobenzyl group, a phenethyl group, a naphthyl group or a hydrogen; and n is an integer of 1 or more.
    Type: Grant
    Filed: October 23, 2003
    Date of Patent: September 19, 2006
    Assignee: SK Chemicals Co., Ltd.
    Inventors: Kyung-Wook Yang, Nam-Sik Park, Ki-Seung Choi, Soon-Jong Hahn, Jin-Man Kim, Wan-Pyo Hong
  • Patent number: 7045560
    Abstract: An antifouling coating which comprises a varnish comprised of a metal-containing acrylic resin having, in a side chain thereof, at least one group represented by the following formula (1): wherein X represents a group of the formula: n represents 0 or 1; Y represents a hydrocarbon group; M represents a metal; m represents an integer equal to [(the valence number of metal M)-1]; A represents an organic acid residue derived from a monobasic acid, said varnish having a nonvolatile fraction of not less than 40 weight % and a viscosity at 25° C. of not more than 18 poises and said antifouling coating having a volatile organic compound (VOC) content of not more than 400 g/L.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: May 16, 2006
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Naoki Yamamori, Satoshi Okamoto, Kiyoaki Higo, Masayuki Matsuda