Phosphorus Bonded To Only Two Chalcogen Atoms And Having At Least One P-c Linkage Patents (Class 524/133)
  • Publication number: 20120224818
    Abstract: Halogen-free flame retardant compositions comprising thermoplastic elastomers, which exhibit flame retardance and low-smoke emission. The flame retardant compositions comprise a) one or more thermoplastic elastomers, and b) from at or about 18 to at or about 50 weight percent, the weight percentage being based on the total weight of the flame retardant composition, of a flame retardant mixture comprising: b1) at least one flame retardant comprising a phosphinate, diphosphinate and/or polymers thereof, b2) a phosphorous-containing amino composition; and b3) a zeolite.
    Type: Application
    Filed: February 29, 2012
    Publication date: September 6, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Eleni Karayianni
  • Publication number: 20120211256
    Abstract: Halogen-free flame retardant compositions exhibiting flame retardance and retention of mechanical properties, especially elongation at break, upon long-term high temperature exposure and comprising a) at least one copolyester thermoplastic elastomer, and b) from at or about 1 to at or about 30 weight percent, based on the total weight of the composition, of at least one flame retardant comprising a phosphinate, diphosphinate and/or polymers of these; c) from at or about 0.25 to at or about 15 weight percent, based on the total weight of the flame retardant composition, of one or more polyhydroxy polymers having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene vinyl alcohol copolymers and poly(vinyl alcohol)s.
    Type: Application
    Filed: August 17, 2011
    Publication date: August 23, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Eleni Karayianni, David J. Wrigley
  • Publication number: 20120214914
    Abstract: A dimethyl terephthalate residual composition comprising a. dimethyl terephthalate derived from a terephthalic-containing polyester homopolymer, terephthalic-containing polyester copolymer, or a combination thereof and b. from more than 0 to less than 3.6 wt. % of a residual component selected from dimethyl isophthalate, cyclohexane dimethanol, diethylene glycol, triethylene glycol, and combinations thereof.
    Type: Application
    Filed: February 22, 2011
    Publication date: August 23, 2012
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Philip Wesley BELL, Dhaval SHAH
  • Patent number: 8236881
    Abstract: The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.
    Type: Grant
    Filed: December 20, 2011
    Date of Patent: August 7, 2012
    Assignee: BASF SE
    Inventor: Michael Roth
  • Patent number: 8222329
    Abstract: Disclosed herein is a symmetric cyclic phosphonate compound represented by the following Formula 1, a method of preparing the same and a flame retardant styrenic resin composition including the same: wherein R1 and R2 are each independently hydrogen, C1-C6 alkyl or C6-C20 aryl. The styrene resin composition employing the symmetric cyclic phosphonate compound exhibits good flame retardancy and impact strength, does not release halide gas during preparation or combustion of the resin composition, and thus is environmentally friendly.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: July 17, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Beom Jun Joo, Sang Hyen Hong, Min Soo Lee, Byun Kun Lee
  • Publication number: 20120165443
    Abstract: Disclosed is a copolyether ester elastomer resin including a polybutylene terephthalate (PBT) repeat unit, and a titanium catalyst deactivating compound.
    Type: Application
    Filed: February 27, 2012
    Publication date: June 28, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Judith Alison Peacock, David J. Wrigley
  • Patent number: 8206832
    Abstract: There is provided a photosensitive thermosetting resin composition of an alkali development type from which it is possible to form a coating film that is halogen-free yet has high-level flame retardancy, has a superior low warpage property after it is cured, is excellent in plasticity, resolution, soldering heat resistance, chemical resistance, and the like, and a flexible printed circuit board using the same.
    Type: Grant
    Filed: November 29, 2007
    Date of Patent: June 26, 2012
    Assignee: Kyocera Chemical Corporation
    Inventors: Tetsuya Ezaki, Masakazu Fujiwara, Masanobu Yanahara
  • Publication number: 20120149816
    Abstract: A flame retardant thermoplastic resin composition includes (A) about 20 to about 99.49 wt % of an aromatic polyamide resin; (B) 0 to about 50 wt % of a polyphenylene sulfide resin; (C) about 0.5 to about 30 wt % of a phosphinic acid metal salt flame retardant; (D) about 0.01 to about 10 wt % of a zinc compound; and (E) 0 to about 70 wt % of a filler comprising an organic filler, an inorganic filler, or a combination thereof. The flame retardant thermoplastic resin composition can have excellent heat resistance, mechanical strength and processability, a low moisture absorption rate and can inhibit corrosion of a metal surface of an extruder or a mold. The flame retardant thermoplastic resin composition can be used for various electrical electronic parts or auto parts as an environmentally friendly flame retardant thermoplastic resin composition.
    Type: Application
    Filed: September 30, 2011
    Publication date: June 14, 2012
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Eun Joo LEE, In Sik SIM, Jong Cheol LIM
  • Publication number: 20120141723
    Abstract: The present invention provides a polymer fiber containing a flame retardant. In particular, the invention provides a fiber containing poly(trimethylene terephthalate) and a flame retardant that melts at a temperature of equal to or below 280° C. The present invention also provides a process for producing such a fiber, and a material incorporating such fibers.
    Type: Application
    Filed: November 13, 2007
    Publication date: June 7, 2012
    Inventors: Hoe Hin Chuah, Kailash Dangayach, Venkataratnam Ramachandran
  • Patent number: 8193263
    Abstract: A flame-retardant glass fiber-reinforced polyamide resin composition, containing: 100 parts by mass of a flame-retardant resin composition consisting of (A) 60 to 90 percent by mass of a polyamide resin, and (B) 40 to 10 percent by mass of a flame retardant containing no halogen atom, (A)+(B) being 100 percent by mass; and 60 to 210 parts by mass of a flattened glass fiber (C) having a flat section of 1.5-10 in a ratio of major axis/minor axis, wherein the polyamide resin (A) contains a crystalline polyamide resin (a1) and an amorphous polyamide resin (a2), the flame retardant containing no halogen atom (B) contains a phosphinate (b1) and/or a diphosphinate (b2), and a blending ratio of the amorphous polyamide resin (a2) in the polyamide resin (A) is 0.1?(a2)/(A)?0.5.
    Type: Grant
    Filed: September 2, 2008
    Date of Patent: June 5, 2012
    Assignee: Unitika Ltd.
    Inventor: Shigeta Fujii
  • Patent number: 8188172
    Abstract: A composition is described, comprising: (a) from 20 to 80 wt % of a polyester; (b) from 5 to 35 wt % of a flame retardant phosphinate of the formula (I) [(R1)(R2)(PO)—O]?mMm+??(I), a flame retardant diphosphinate of the formula (II) [(O—POR1)(R3)(POR2—O)]2?nMxm+??(II), and/or a flame retardant polymer derived from the flame retardant phosphinate of the formula (I) or the flame retardant diphosphinate of the formula (II), wherein R1 and R2 are identical or different and are H, C1-C6-alkyl, linear or branched, or C6-C10-aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is an alkaline earth metal, alkali metal, Al, Ti, Zn, Fe, or boron; m is 1, 2, 3 or 4; n is 1, 2, or 3; and x is 1 or 2; (c) from 1 to 25 wt % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; (d) from more than 0 to 25 wt % of a polyetherimide; and (e) optionally, an additive.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: May 29, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Somasundaram Elango, Rama Konduri, Subodh Kumar Pal, Reema Sinha, Veeraraghavan Srinivasan, Chris van der Weele, Gerrit de Wit
  • Publication number: 20120108713
    Abstract: The present invention relates to a mixture comprising at least one plastic K and from 0.1 to 50% by weight, based on the entire mixture, of at least one compound A selected from the group consisting of borophosphates, borate phosphates, metalloborophosphates, and mixtures thereof, to a process for the production of said mixture, and to the use of said mixture as flame retardant.
    Type: Application
    Filed: July 1, 2010
    Publication date: May 3, 2012
    Applicant: BASF SE
    Inventors: Bastian Ewald, Harlmut Hibst
  • Patent number: 8168707
    Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % of a polyester, 10-49 wt % of an ABS impact modifier; 0 to 20 wt % of a multifunctional epoxy compound; 0-40 wt % of a filler; 0-2 wt % of a fibrillated fluoropolymer; and from more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 40-100 Joules at ?30° C.; a ductility of more than 90%, a permeability of more than 0 to less than or equal to 1.5 g/m2-day, measured after exposure Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break after exposure to Fuel E85 for 28 days at 70° C.
    Type: Grant
    Filed: August 7, 2008
    Date of Patent: May 1, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Donald Howard Ellington, Robert Russell Gallucci, Josephus Gerardus M. van Gisbergen, Vishvajit Chandrakant Juikar, Ihab Odeh, Sathish Kumar Ranganathan, Kenneth Frederick Miller, Veeraraghavan Srinivasan
  • Publication number: 20120100371
    Abstract: The present invention provides a resin composition that simultaneously (1) supports high productivities, (2) is resistant to bleed out by the flame retardant present in the composition, (3) is resistant to migration of its components to another resin, (4) exhibits a high flame retardancy, and (5) exhibits high flexibility. The resin composition includes components (A) a polyphenylene ether, (B) a hydrogenated copolymer, (C) a styrene resin and/or olefin resin, and (D) a metal phosphinate, wherein the component (B) includes (B1) a polymer block principally comprising an aromatic vinyl monomer unit, and (B2) a hydrogenated copolymer block principally comprising an aromatic vinyl monomer unit and a conjugated diene monomer unit, and a content of the aromatic vinyl monomer unit in the (B2) is 20 to 95% by weight, and a content of the aromatic vinyl monomer unit in the (B) is 35 to 80% by weight.
    Type: Application
    Filed: September 23, 2011
    Publication date: April 26, 2012
    Inventors: Yoshifumi Araki, Takashi Sato, Takahiro Hisasue
  • Patent number: 8163841
    Abstract: Polyethylene naphthalate fibers that are characterized in that the fibers have a crystal volume of from 550 to 1,200 nm3 obtained by wide angle X-ray diffraction of the fiber and a degree of crystallization of from 30 to 60%. It is preferred that the fibers have a maximum peak diffraction angle of wide angle X-ray diffraction of from 25.5 to 27.0° and a melting point of from 285 to 315° C. The production method thereof is characterized in that a particular phosphorus compound is added to the polymer in a molten state, the spinning draft ratio after discharging from the spinneret is from 100 to 5,000, and the molten polymer immediately after discharging from the spinneret is allowed to pass through a heat-retaining spinning chimney at a temperature within ±50° C. of a temperature of the molten polymer, and is drawn.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: April 24, 2012
    Assignee: Teijin Fibers Limited
    Inventors: Shintaro Shimada, Fuyuki Terasaka
  • Publication number: 20120095129
    Abstract: Disclosed is a resin composition comprising (A) a polyester resin or a polycarbonate resin, (B) a polyethylene resin, (C) an aromatic compound other than the polyester resin and the polycarbonate resin, the aromatic compound having a residual carbon rate of not less than 20% by mass, and (D) a flame retardant, wherein the polyethylene resin is dispersed as crystal particles in the resin composition, and the content of the polyethylene resin crystal particles having a major axis diameter of 0.1 to 10 ?m and an aspect ratio of 1 to 10 is not less than 60% by number based on the total polyethylene resin crystal particle number.
    Type: Application
    Filed: October 7, 2011
    Publication date: April 19, 2012
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Masashi MAMINO, Yasuo KURACHI, Ryuji KITANI, Yasuharu SAITA
  • Patent number: 8158718
    Abstract: Polyethylene naphthalate fibers that are characterized in that the fibers have a crystal volume of from 100 to 200 nm3 obtained by wide angle X-ray diffraction of the fiber and a degree of crystallization of from 30 to 60%. It is preferred that the fibers have a maximum peak diffraction angle of wide angle X-ray diffraction of from 23.0 to 25.0°. The production method thereof is characterized in that a particular phosphorus compound is added to the polymer in a molten state, the spinning speed is from 4,000 to 8,000 m/min, and the molten polymer immediately after discharging from the spinneret is allowed to pass through a heated spinning chimney at a high temperature exceeding a temperature of the molten polymer by 50° C. or more, and is drawn.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: April 17, 2012
    Assignee: Teijin Fibers Limited
    Inventors: Shintaro Shimada, Fuyuki Terasaka
  • Patent number: 8153705
    Abstract: A hydrolysable paint composition comprising organosilyl esters. The organosilyl esters are used in paint formulations which require hydrolysis of one or more of the components of the paint in use. The organosilylesters of the invention may also independently be film forming. The organosilyl ester may be the ester of a carboxylic, sulphonic or phosphoric acid. The binder systems of the invention can be used in paint compositions, such as self-polishing antifouling paints.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: April 10, 2012
    Assignee: SigmaKalon B.V.
    Inventors: Michel Gillard, Marcel Vos
  • Publication number: 20120083553
    Abstract: A molded article for an electric vehicle part is provided using a thermoplastic polyester resin composition imparting excellent hydrolysis resistance, electric insulation, flame retardance, and tracking resistance. The molded article for an electric vehicle part is formed by molding the thermoplastic polyester resin composition including a thermoplastic polyester resin, which has a terminal carboxyl group amount that is no more than 30 meq/kg, and a flame retardant, in which the tracking resistance measured according to IEC 112, the third edition, after pressurized heat treatment with the 120° C. saturated steam for 200 hours is no less than 500 V, and in which the volume resistivity value measured after the pressurized heating treatment with the 120° C. saturated steam for 200 hours is no less than 1×1015 ?·m.
    Type: Application
    Filed: June 2, 2010
    Publication date: April 5, 2012
    Applicant: Win-Tech Polymer Ltd.
    Inventors: Sei Wakatsuka, Nobuyuki Sueyasu
  • Publication number: 20120083558
    Abstract: The invention relates to a flame-retardant polyamide molding composition based on semicrystalline polyamides. This polyamide molding composition is based on (A) from 30 to 92% by weight of at least one aliphatic or semiaromatic, semicrystalline polyamide with melting point (Tm) in the range from 240° C. to 340° C.; (B) from 0 to 50% by weight of at least one filler and reinforcing agent; (C) from 8 to 18% by weight of at least one halogen-free flame retardant; (D) from 0 to 2.0% by weight of at least one barium carboxylate; (E) from 0 to 5% by weight of at least one additive; wherein the percentages by weight of components (A) to (E) give a total of 100%, and with the proviso that if the proportion of component (D) is in the range from 0 to 0.1% by weight the halogen-free flame retardant of component (C) is based on a barium phosphinate.
    Type: Application
    Filed: June 5, 2009
    Publication date: April 5, 2012
    Applicant: EMS-PATENT AG
    Inventors: Andreas Bayer, Nikolai Lamberts
  • Patent number: 8148446
    Abstract: A method of boosting alkaline hydrolysis or erodability of a hydrolysable paint formulation, the method comprising the step of adding an organosilyl ester to a binder system of a hydrolysable paint formulation. The booster is used in paint formulations which require hydrolysis of one or more of the components of the paint in use. The organosilylesters of the invention may also independently be film forming. The organosilyl ester may be the ester of a carboxylic, sulphonic or phosphoric acid. The binder systems of the invention can be used in paint compositions, such as self-polishing antifouling paints.
    Type: Grant
    Filed: June 3, 2010
    Date of Patent: April 3, 2012
    Assignee: SigmaKalon B.V.
    Inventors: Michel Gillard, Marcel Vos
  • Patent number: 8119716
    Abstract: The invention discloses a method of incorporating deagglomerated barium sulphate having an average primary particle size of less than 0.5 ?m and coated with a dispersant into plastics or precursors of plastics, for example into polyols. The deagglomerated barium sulphate is dispersed in an organic solvent, the dispersion is incorporated into the plastic or the precursor of the plastic, and the solvent is evaporated off.
    Type: Grant
    Filed: June 2, 2006
    Date of Patent: February 21, 2012
    Assignee: Solvay Infra Bad Hoenningen GmbH
    Inventors: Ferdinand Hardinghaus, David-Christopher Glende, Jai-Won Park, Karl Kohler
  • Patent number: 8119710
    Abstract: The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
    Type: Grant
    Filed: September 12, 2006
    Date of Patent: February 21, 2012
    Assignee: BASF SE
    Inventors: Michèle Gerster, Gerrit Knobloch, Pierre Rota-Graziosi, Francesco Fuso
  • Publication number: 20120040115
    Abstract: The invention relates to a composition comprising, relative to the total weight of the composition: between 25% and 52% by weight of at least one semi-crystalline or amorphous polyamide, having an amine chain-end content of less than 0.040 meq/g, between 24% and 40% by weight of at least one reinforcer, and between 24% and 35% by weight of at least one metal salt, optionally contained in a polymer, chosen from a metal salt of phosphinic acid, a metal salt of diphosphinic acid, and a mixture thereof. The invention also relates to the process for preparing this composition and its use.
    Type: Application
    Filed: January 27, 2010
    Publication date: February 16, 2012
    Applicant: Arkema France
    Inventors: Philippe Blondel, Eric Gamache, Benjamin Saillard, Barbara Ramfel
  • Publication number: 20120037396
    Abstract: A flame-retardant thermoplastic elastomer compound is disclosed having polyphenylene ether, a hydrogenated styrene block copolymer, at least one solid non-halogenated phosphorus containing flame retardant, and a nucleated olefinic polymer. The compound has a before-aging tensile elongation of >200% and an after-aging tensile elongation residual of at least 75%, according to the UL 62 test, which makes it useful as an insulation layer, a jacketing layer, or both for protected electrical lines such as alternating current wire and cable products, accessory cables, and variety of injection molded electrical or electronic parts.
    Type: Application
    Filed: April 27, 2010
    Publication date: February 16, 2012
    Applicant: POLYONE CORPORATION
    Inventor: Jiren Gu
  • Publication number: 20120035303
    Abstract: This invention relates to a flame retardant thermoplastic composition comprising a thermoplastic polymer composition; a flame retardant containing a phosphorus containing anion; a borate; and an acid scavenger.
    Type: Application
    Filed: February 3, 2010
    Publication date: February 9, 2012
    Applicant: DSM IP Assets B.V.
    Inventors: Angelika Schmidt, Luc E.F. Leemans, Atze J. Nijenhuis
  • Publication number: 20120029122
    Abstract: Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of a thermoplastic polymer, B) from 0.5 to 40% by weight of a flame retardant compound comprising phosphorus, C) from 0.5 to 35% by weight of iron sulfide, D) from 0 to 70% by weight of further additives, where the total of the percentages by weight of components A) to D) is 100%.
    Type: Application
    Filed: July 29, 2011
    Publication date: February 2, 2012
    Applicant: BASF SE
    Inventors: Siqi Xue, Sabine Fuchs
  • Publication number: 20120029124
    Abstract: A polymer composition comprising (i) at least one semi-aromatic polyamide having a melting point of at least 270° C., (ii) at least one organophosphorous compound selected from phosphinates, diphosphinates and condensation products thereof, and (iii) at least 0.01 wt. %, based on the total weight of the composition, of calcium oxide.
    Type: Application
    Filed: April 8, 2010
    Publication date: February 2, 2012
    Applicant: SOLVAY ADVANCED POLYMERS, L.L.C.
    Inventors: Linda M. Norfolk, Glenn W. Cupta, Charles T. Roney
  • Publication number: 20120022194
    Abstract: An unreinforced, halogen-free polyamide moulding composition which is provided with flame retardants and from which it is possible to produce electric and/or electronic components which can be reliably soldered, i.e. in particular without blisters being formed in the soldering process, in particular at 260° C. and possibly higher temperatures after water absorption and in the case of critical designs of the components, and which have an elongation at break of at least 5% and reliably achieve the UL94 classification V0. These polyamide moulding compositions have the following composition: (A) 62-87% by weight of a partially aromatic, partially crystalline copolyamide having a melting point of 270° C. to 320° C.
    Type: Application
    Filed: July 8, 2011
    Publication date: January 26, 2012
    Applicant: EMS-PATENT AG
    Inventors: Andreas BAYER, Manfred HEWEL
  • Patent number: 8101678
    Abstract: The present invention relates to flame retardant polymer compositions which comprise mixtures of phosphinic acid salts and dihydro-oxa-phospho-phenantrene derivatives. The compositions are especially useful for the manufacture of flame retardant compounds based on polycondensates like polyesters, polyamides and polycarbonates.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: January 24, 2012
    Assignee: BASF SE
    Inventor: Michael Roth
  • Publication number: 20110315423
    Abstract: The present invention relates to flame retardant thermoplastic vulcanizate compositions having improved abrasion resistance and strip force. In addition, the invention relates to wire and cable coated with these compositions. The flame retardant thermoplastic vulcanizate compositions comprise a thermoplastic vulcanizate composition, at least one halogen-free flame retardant and an ultra-high molecular weight polysiloxane.
    Type: Application
    Filed: June 23, 2011
    Publication date: December 29, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: ELENI KARAYIANNI
  • Patent number: 8084518
    Abstract: The invention relates to an ethylenebis(hydroxyalkylphosphinic acid) and salts thereof. The acid has the general formula: A-P(O)(OX)—CR1R2—CR3R4—P(O)(OX)-A. Variable A is CR5R6—OH. Variables R1, R2, R3, R4, R5, and R6 are the same or different, and denote independently from each other H, C1-C20 alkyl, C6-C20 aryl, or C6-C20 aralkyl, so long as at least one of R1 and R2 is H and at least one of R3 and R4 is H. Variable X denotes H, an alkali metal, an element of main or transition group 2, an element of main or transition group 3, an element of main or transition group 4, an element of main or transition group 5, an element of transition group 6, an element of transition group 7, an element of transition group 8 and/or a nitrogen base. Also disclosed are a method for producing same and the use thereof.
    Type: Grant
    Filed: October 6, 2007
    Date of Patent: December 27, 2011
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Harald Bauer, Werner Krause, Peter Staniek
  • Publication number: 20110311759
    Abstract: Poly(trimethylene terephthalate) compositions, and articles made therefrom, having improved flame retardancy are provided. The compositions can be used to make carpets that are suitable for installation where flame retardancy is desired.
    Type: Application
    Filed: May 16, 2011
    Publication date: December 22, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Benjamin Weaver Messmore, Paul Ellis Rollin, JR., Kalika Ranjan Samant, Jing-Chung Chang
  • Patent number: 8080599
    Abstract: A thermoplastic polyester composition comprises, based on the total weight of the composition, from 20 to 95 wt. % of a polyester comprising a poly(alkylene terephthalate); from 1 to 35 wt. % of a phosphorous flame retardant consisting of a phosphinate of the formula (I) [(R1)(R2(PO)—O]?mMm+??(I), a diphosphinate of the formula (II) [(O—POR1)(R3)(POR2—O)]2?nMm+x??(II), and/or a polymer derived from the phosphinate of formula (I) or the diphosphinate of the formula (II); from 0.1 to less than 20 wt. % of a copolyetherester; from 0.1 to 5 wt. % of an anti-dripping agent; from 0 to 4.5 wt. % of a reinforcing fiber; and from 0 to 5 wt. % of an additive selected from the group consisting of a mold release agent, an antioxidant, a thermal stabilizer, and a UV stabilizer.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: December 20, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Tianhua Ding, Rodney Fonseca, Sung Dug Kim, Chris Van Der Weele
  • Publication number: 20110306710
    Abstract: Disclosed is a method for increasing the solid state polymerization (SSP) rates of metal catalyzed polyesters. The method comprises in a first step, reacting a dicarboxylic acid or a C1-C4 dicarboxylic diester with a diol at a suitable temperature and pressure to effect esterification or transesterification to prepare a precondensate and in a second step, reacting the precondensate to effect polycondensation at a suitable temperature and pressure to prepare a high molecular weight polyester and in a third step, further increasing the molecular weight and viscosity of the polyester under SSP conditions of a suitable temperature and pressure, where a metal catalyst is added in the first step or in the second step as a reaction catalyst, and where a certain phosphinic acid compound is added in the first step, in the second step or just prior to the third step. The polyester product exhibits low aldehyde formation during melt processing steps as well as excellent color.
    Type: Application
    Filed: August 22, 2011
    Publication date: December 15, 2011
    Inventors: Paul Odorisio, Stephen M. Andrews, Thomas F. Thompson, Si Wu, Paragkumar Thanki, Deepak M. Rane, Delina Joseph, Jianzhao Wang
  • Publication number: 20110294931
    Abstract: A composition that includes at least one silane-functional polymer P and 20 to 60% by weight of aluminum hydroxide or magnesium hydroxide or mixture thereof, is disclosed. The composition has a viscosity of 500 to 20,000 mPa·s measured according to DIN 53018 at a temperature of 20° C. The composition is suitable as a liquid membrane and has very good flammability properties, i.e., it is difficult to ignite and is self-extinguishing.
    Type: Application
    Filed: June 20, 2011
    Publication date: December 1, 2011
    Applicant: Sika Technology AG
    Inventors: Thomas PUSEL, Raphael Teysseire, Willi Tenisch, Susanne Strauss, Barbara Jucker, Carsten Zilg
  • Patent number: 8063124
    Abstract: The use of oxidizable phosphorus or phosphorous stabilizers, such as the phosphites, to reduce the color formation of the ionomeric polyester compositions is disclosed.
    Type: Grant
    Filed: November 11, 2010
    Date of Patent: November 22, 2011
    Assignee: M&G USA Corporation
    Inventor: Paul L. Heater
  • Patent number: 8063123
    Abstract: The invention relates to phosphorus-containing mixtures containing compounds of the formula RO—PO(A)-CH2—CH2—CO2H and??(I) HO—PO(A)-CH2—CH2—CO2R??(II) in which A is C1-C18-alkyl, C6-C18-alkylaryl, C6-C18-aralkyl or aryl, R is (D,E)C?C(B, R5) or H B, D, E are identical or different and are each H or C1-C18-alkyl R5 is —CO-alkoxy, a process for their preparation and their use.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: November 22, 2011
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Harald Bauer, Mathias Dietz, Ottmar Schacker
  • Publication number: 20110281983
    Abstract: The invention relates to a method for producing monohydroxy-functionalized dialkylphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, b) the, obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with alkylene oxides of formula (V) in the presence of a catalyst B to obtain a monofunctionalized dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R5, R6, R7, R8 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, and X represents H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogenous base, catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transiti
    Type: Application
    Filed: October 6, 2009
    Publication date: November 17, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Publication number: 20110275743
    Abstract: A flame-retardant thermoplastic resin composition that has a largely decreased corrosiveness to metals while maintaining a high degree of flame retardancy is provided, which is produced by adding a phosphinic acid salt and a compound having a specific structure to a thermoplastic resin, and molded articles with largely decreased corrosiveness to metals are also provided, so that useful molded articles can be provided as materials for mechanical machine parts, electric/electronic components, and automotive parts. The flame-retardant thermoplastic resin composition includes 65 to 99 wt % of (A) a thermoplastic resin, 1 to 35 wt % of (B) at least one phosphinic acid salt selected from the group of phosphinic acid salt, diphosphinic acid salt, polymer of phosphinic acid salts, and polymer of diphosphinic acid salts, and 0.001 to 0.70 wt % of (C) a compound having a specific, and molded articles produced therefrom.
    Type: Application
    Filed: July 5, 2010
    Publication date: November 10, 2011
    Applicant: TORAY INDUSTRIES, INC.
    Inventors: Hiromitsu Ishii, Kentaro Togawa, Sadanori Kumazawa
  • Publication number: 20110275744
    Abstract: The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ether.
    Type: Application
    Filed: October 6, 2009
    Publication date: November 10, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Mathias Dietz, Werner Krause, Martin Sicken
  • Patent number: 8053500
    Abstract: To provide a flame-retardant polyamide resin composition generally excellent in flame resistance, mechanical characteristics and electrical characteristics, and suitable for electrics/electronics components and vehicles. Used is a flame-retardant polyamide resin composition comprising, a polyamide resin (A), a phosphorus-containing flame retarder (B), and glass fiber having a non-circular cross-section (C), wherein the contents in the composition are 15 to 78% by weight for the polyamide resin (A), 2 to 20% by weight for the phosphorus-containing flame retarder (B), and 20 to 65% by weight for the glass fiber having a non-circular cross-section (C).
    Type: Grant
    Filed: December 4, 2007
    Date of Patent: November 8, 2011
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Kei Morimoto, Yasushi Yamanaka
  • Patent number: 8051947
    Abstract: The present invention relates to a method for vibration damping and noise reduction by using thermoplastic vulcanizate compositions and to multilayer structures for use in vibration damping and noise reduction applications comprising at least one polymeric layer made of a thermoplastic vulcanizate composition.
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: November 8, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Eleni Karayianni
  • Publication number: 20110266024
    Abstract: A flame retardant poly(arylene ether) composition is described. In addition to the poly(arylene ether), the composition includes a polyolefin component, and a flame retardant composition that includes a metal dialkyl phosphinate. The polyolefin component can be a polyolefin polymer and/or the polyolefin block of a poly(alkenyl aromatic)-polyolefin block copolymer. The composition is particularly suitable as a replacement for poly(vinyl chloride) in insulation for wire and cable.
    Type: Application
    Filed: September 5, 2008
    Publication date: November 3, 2011
    Inventors: Weili Qiu, Jian Guo, Xiucuo Li, Hua Guo
  • Publication number: 20110257313
    Abstract: A halogen-free flame-retardant polyamide composition which generates no halogen compound during combustion. The composition has excellent thermal stability during high-temperature molding and is capable of showing high flame retardancy when burned. The composition is effective in inhibiting steel materials, such as the screw or cylinder of an extruder or molding machine, from corroding or wearing. The flame-retardant polyamide composition in a preferred embodiment comprises 20-60 mass % polyamide resin (A), 5-40 mass % thermoplastic resin (B) other than (A), 3-15 mass % flame retardant (C) having no halogen radicals in the molecule, and 0-50 mass % reinforcement (D), wherein the thermoplastic resin (B) satisfies the UL94V-0 standards, the flame retardant (C) is a phosphinic acid salt compound, and the sum of the thermoplastic resin (B) and the flame retardant (C) is 16-45 mass %.
    Type: Application
    Filed: December 21, 2009
    Publication date: October 20, 2011
    Applicant: Mitsui Cheicals, Inc.
    Inventor: Masashi Seki
  • Publication number: 20110251315
    Abstract: The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C?C, C?O, or C?N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compo
    Type: Application
    Filed: October 6, 2009
    Publication date: October 13, 2011
    Applicant: Clariant Finance (BVI) Limited
    Inventors: Michael Hill, Harald Bauer, Werner Krause, Martin Sicken
  • Publication number: 20110251313
    Abstract: The present invention provides phosphonate compounds represented by Chemical Formula 1. In addition, the invention provides flame retardant styrene resin compositions comprising (A) styrene resin, (B) polyphenylene ether resin, and (C) the phosphonate compound. The flame retardant styrene resin compositions according to the invention: can provide protection against fire, exhibit improved impact strength, and can be environment-friendly.
    Type: Application
    Filed: June 22, 2011
    Publication date: October 13, 2011
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Beom Jun JOO, Man Suk KIM, Woo Joong KIM, Seon Ae LEE, Byun Kun LEE, Myoung Jun KIM
  • Publication number: 20110251310
    Abstract: The invention relates to addition compounds of a) alkylphosphonous acid derivatives of the formula A-P(?O)(OX)—H (I) in which A represents C2-C18-alkyl, C2-C18-alkylene, C6-C18-arylalkyl, C6-C18-arylalkyl, optionally substituted, and X represents H, C1-C18-alkyl, C6-C18-aryl, C6-C18-arylalkyl, C6-C18-alkylaryl, optionally substituted C2-C18-alkylene, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H and/or a protonated nitrogenous base, and b) diester-forming olefins of formula (II) in which R2, R4 are identical or different from each other and represent CO2H, CO2R5, R6—CO2H, R6—CO2R5 and R1, R3 are identical or different from each other and represent H, R5; or R1, R4 are identical or different from each other and represent CO2H, CO2R5, R6—CO2H, R6—CO2R5 and R2, R3 are identical or different from each other and represent H, R5; or R2, R4 are identical or different from each other and represent —CO—O—CO—, —CO—S—CO—, —CO—NR1—CO—, —CO—PR1—CO— and R1, R3 are identical or different f
    Type: Application
    Filed: October 6, 2009
    Publication date: October 13, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Harald Bauer, Werner Krause, Martin Sicken
  • Publication number: 20110245386
    Abstract: The invention relates to a method for producing mixed-substituted dialkyiphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, b) the obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with an olefin (IV) in the presence of a catalyst B to obtain the mixed-substituted dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R11, R12, R13, R14 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, X represents H, C1-C18-alkyl, C8-C18-aryl, C6-C18-aralkyl, C8-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogenous base, catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transit
    Type: Application
    Filed: October 6, 2009
    Publication date: October 6, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Werner Krause, Martin Sicken
  • Publication number: 20110245385
    Abstract: The invention relates to a process for preparing mono-carboxy-functionalized dialkylphosphinic acids, dialkylphosphinic esters and dialkylphosphinic salts by means of alkylene oxides, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to form an alkylphosphonous acid, its salt or ester (II), b) the resultant alkylphosphonous acid, its salt or ester (II) is reacted with alkylene oxides of the formula (V) in the presence of a catalyst B, to give a mono-functionalized dialkylphosphinic acid derivative (VI), and c) the resultant mono-functionalized dialkylphosphinic acid derivative (VI) is reacted in the presence a catalyst C to give the mono-carboxy-functionalized dialkylphosphinic acid derivative (III), where R1,R2,R3,R4,R5, and R6 are identical or different and independently of one another are inter alia H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl or C6-C18-alkylaryl, and X and Y are identical or different and independently of one another are H,
    Type: Application
    Filed: October 6, 2009
    Publication date: October 6, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Mathias Dietz, Werner Krause, Martin Sicken