Phosphorus Bonded To Only Two Chalcogen Atoms And Having At Least One P-c Linkage Patents (Class 524/133)
  • Publication number: 20100240814
    Abstract: Disclosed herein is a flame retardant polyester resin composition that can have excellent heat resistance comprising (A) about 100 parts by weight of a polyester resin; (B) about 1 to about 50 parts by weight of a metal salt of an organic phosphinic acid; (C) about 0.01 to about 20 parts by weight of an ionomer resin; and (D) about 1 to about 100 parts by weight of a filler. The resin composition of the present invention composition can have excellent heat resistance while maintaining mechanical properties, and also does not produce toxic halide gases.
    Type: Application
    Filed: June 2, 2010
    Publication date: September 23, 2010
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Seong Ho KONG, Kyung Hoon SHIN, Jin Seong LEE
  • Publication number: 20100240813
    Abstract: There are provided a thermoplastic resin composition excellent in a balance between fluidity and low outgassing, and a molded product and a sheet including the thermoplastic resin composition. The thermoplastic resin composition may include from 70 to 99% by mass of (A) a polyphenylene ether, from 1 to 30% by mass of (B) a copolymer including an aromatic vinyl compound and an unsaturated dicarboximide derivative as constituent monomers, and from 0 to 20% by mass of (C) a copolymer including an aromatic vinyl compound and a cyanided vinyl compound as constituent monomers, based on 100% by mass of the total of the (A) component, the (B) component and the (C) component, wherein the (B) component has a weight-average molecular weight of from 70,000 to 250,000.
    Type: Application
    Filed: November 6, 2008
    Publication date: September 23, 2010
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventor: Kazunori Terada
  • Publication number: 20100233474
    Abstract: A laser-weldable flame-retardant resin composition (for a member located in a transmitting side) comprises (A) a polyester-series resin and (B) at least one phosphinic acid compound selected from the group consisting of a salt of a phosphinic acid, a salt of a diphosphinic acid, and a polymer thereof (preferably, a metal salt). The resin composition may have a laser light transmittance of not less than 15% for a molded product comprising the resin composition and having a thickness of 2 mm. The resin composition may further contain a fluorine-containing resin, a nitrogen-containing flame retardant (e.g., a salt of a triazine compound with cyanuric acid and/or isocyanuric acid), and/or a filler (e.g., a glass fiber), and others. Such a resin composition realizes both of laser-weldability (laser transmissivity) and flame retardancy at high levels.
    Type: Application
    Filed: December 25, 2006
    Publication date: September 16, 2010
    Applicant: WINTECH POLYMER LTD.
    Inventors: Jun Haruhara, Takakazu Hirakawa, Kazuhito Hanabusa
  • Publication number: 20100227957
    Abstract: A flame-retardant glass fiber-reinforced polyamide resin composition, containing: 100 parts by mass of a flame-retardant resin composition consisting of (A) 60 to 90 percent by mass of a polyamide resin, and (B) 40 to 10 percent by mass of a flame retardant containing no halogen atom, (A)+(B) being 100 percent by mass; and 60 to 210 parts by mass of a flattened glass fiber (C) having a flat section of 1.5-10 in a ratio of major axis/minor axis, wherein the polyamide resin (A) contains a crystalline polyamide resin (a1) and an amorphous polyamide resin (a2), the flame retardant containing no halogen atom (B) contains a phosphinate (b1) and/or a diphosphinate (b2), and a blending ratio of the amorphous polyamide resin (a2) in the polyamide resin (A) is 0.1?(a2)/(A)?0.5.
    Type: Application
    Filed: September 2, 2008
    Publication date: September 9, 2010
    Inventor: Shigeta Fujii
  • Patent number: 7790790
    Abstract: Flame retardant thermoplastic elastomer composition comprising a thermoplastic vulcanizate composition and non-halogenated flame retardant.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: September 7, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Eleni Karayianni, Jean-Michel Philippoz
  • Publication number: 20100222476
    Abstract: A thermoplastic polymer blend is disclosed comprising a polyester, a polycarbonate, and a minor amount of a flow enhancer selected from non-sulfonated phosphonium salts. Optionally, impact modifiers and other conventional additives are included.
    Type: Application
    Filed: May 31, 2007
    Publication date: September 2, 2010
    Applicant: POLYONE CORPORATION
    Inventors: Roger W. Avakian, John Papadopulos
  • Patent number: 7786195
    Abstract: A spectacle lens made of a polycarbonate resin composition which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of (A) at least one ultraviolet light absorber selected from the group consisting of 2-(2?-hydroxy-5?-methylphenyl)benzotriazole and 2-(2?-hydroxy-5?-tert-octylphenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of (B) at least one ultraviolet light absorber selected from the group consisting of 2-(3-tert-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2,2?-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotraizole)-2-ylphenol] and 2-[2-hydroxy-3,5-bis(?,?-dimethylbenzyl)phenyl]-2H-benzotriazole, and (4) 0.01 to 0.5 part by weight of (C) a full ester of a tetravalent to octavalent aliphatic polyhydric alcohol having 5 to 30 carbon atoms and an aliphatic carboxylic acid having 10 to 22 carbon atoms, having an acid value of 4 to 20.
    Type: Grant
    Filed: October 28, 2005
    Date of Patent: August 31, 2010
    Assignee: Teijin Chemicals Ltd.
    Inventors: Jiro Ariki, Seiichi Tanabe
  • Publication number: 20100216918
    Abstract: Flame-proofed thermoplastic compositions include organophosphorus compounds as flame retardants; thermoplastic articles shaped therefrom do not experience deterioration of the appearance of the surfaces thereof by corrosion or deposition.
    Type: Application
    Filed: June 17, 2008
    Publication date: August 26, 2010
    Inventors: Silvia Angeli, Xavier Couillens, Michelangelo Amorese
  • Publication number: 20100190901
    Abstract: The invention relates to alkylphosphonous acids, salts and esters of formula (I) A-P(?O)(OX)—H (I) wherein A is C2-C20alkyl, C2-C20alkylene, and C8-C20 alkaryl are optionally substituted, and X is H, alkyl, aryl, alkylaryl, alkenyl, substituted alkyl, aryl, alkaryl, alkenyl, ammonium, primary, secondary, tertiary, quaternary alkyl and/or aryl ammonium, an alkali metal, an alkaline earth metal, a metal of the third and fourth main group and the second, fourth and eight sub-group or a metal of the lanthanoid group. The invention also relates to methods for producing same and to the uses of said compounds.
    Type: Application
    Filed: July 2, 2008
    Publication date: July 29, 2010
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Hill, Harald Bauer, Werner Krause
  • Publication number: 20100168289
    Abstract: A composition comprises, based on the total weight of the composition: from 20 to 90 wt. % of a polyester component comprising a poly(butylene terephthalate); from 5 to 35 wt. % of a flame retardant phosphinate of the formula (I) [(R1)(R2)(PO)—O]?mMm+??(I) a flame retardant diphosphinate of the formula (II) [(O—POR1)(R3)(POR2—O)]2?nMm+x??(II), and/or a flame retardant polymer derived from the flame retardant phosphinate of the formula (I) or the flame retardant diphosphinate of the formula (II); from 1 to 25 wt. % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; from greater than zero to 50 wt. % of a glass fiber having a non-circular cross-section; and from 0 to 5 wt. % of an additive selected from the group consisting of a mold release agent, an antioxidant, a thermal stabilizer, an antioxidant, and a UV stabilizer; wherein the components have a combined total weight of 100 wt. %.
    Type: Application
    Filed: December 30, 2008
    Publication date: July 1, 2010
    Inventors: Tianhua DING, Sung Dug Kim
  • Publication number: 20100139944
    Abstract: A poly(arylene ether) composition includes a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, a flame retardant, and a poly(arylene ether)-polysiloxane block copolymer reaction product that itself includes a poly(arylene ether)-polysiloxane block copolymer. The composition is useful for forming extruded articles, including insulation for wire and cable. The poly(arylene ether)-polysiloxane block copolymer contributes improved flame retardancy and, in many cases, improved physical properties to the composition.
    Type: Application
    Filed: December 10, 2008
    Publication date: June 10, 2010
    Inventors: Hua Guo, Jian Guo, Kazunari Kosaka, Xiucuo Li
  • Publication number: 20100137483
    Abstract: The mixture of the invention comprises at least one cycloaliphatic polyisocyanate and at least one solvent comprising an ester function and an ether function. An aqueous emulsion can be obtained from this mixture which also comprises a compound bearing a function with a mobile hydrogen, selected from primary or secondary hydroxyl functions, phenol functions, primary and/or secondary amino functions, carboxylic functions and a thiol function or a compound containing precursor functions capable of freeing hydroxyl functions. The emulsion can be used for the manufacture of coatings on a substrate of cement, of wood or especially of leather, and also for the manufacture of adhesives.
    Type: Application
    Filed: April 29, 2008
    Publication date: June 3, 2010
    Applicant: PERSTORP FRANCE
    Inventors: Philippe Barbeau, Philippe Olier, Johannes Schwarz
  • Patent number: 7723411
    Abstract: The invention relates to flameproof polyamide molding compositions, comprising 30-80% by weight of a semi-aromatic, partially crystalline polyamide and 1-30% by weight of a flame retardant containing a phosphinic acid salt and/or a diphosphinic acid salt.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: May 25, 2010
    Assignee: EMS-Chemie AG
    Inventor: Ewald Schneider
  • Publication number: 20100113656
    Abstract: There is provided high temperature flame retarded polyamides which provide superior properties in molded articles while maintaining high flow in the molding process. The resin compositions include, in addition to the polyamide and flame retardant, talc and at least one inorganic reinforcing agent and/or filler other than talc. Processes for their preparation and articles made from these compositions are also disclosed.
    Type: Application
    Filed: October 21, 2009
    Publication date: May 6, 2010
    Applicant: E.I. DU PONT DE NEMOURS AND COMPNAY
    Inventor: Yuji Saga
  • Publication number: 20100113655
    Abstract: There is provided high temperature flame retarded semiaromatic polyamides which provide superior properties in molded articles while maintaining high flow in the molding process. The resin compositions include, in addition to the polyamide and flame retardant, aromatic organic acid and at least one inorganic reinforcing agent and/or filler. Processes for their preparation and articles made from these compositions are also disclosed.
    Type: Application
    Filed: October 21, 2009
    Publication date: May 6, 2010
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Yuji Saga
  • Publication number: 20100113657
    Abstract: Disclosed is a flame-retardant polyamide composition which is excellent in mechanical properties such as toughness, and heat resistance, flame retardancy and flow ability during a reflow soldering process. In addition, this polyamide composition exhibits high thermal stability during molding. Specifically disclosed is a flame-retardant polyamide composition containing (A) 20-80% by weight of a specific polyamide resin, (B) 10-20% by weight of a metal phosphinate, (C) 0.05-1% by weight of a lithium salt, a calcium salt, a barium salt, a zinc salt or an aluminum salt of montanic acid, behenic acid or stearic acid. It is preferable that this flame-retardant polyamide composition contains no halogen flame retardant.
    Type: Application
    Filed: March 28, 2008
    Publication date: May 6, 2010
    Applicant: Mitsui Chemicals, Inc
    Inventor: Masashi Seki
  • Publication number: 20100113637
    Abstract: The present subject matter relates generally to polymer compositions, and more particularly to irradiated polymer compositions comprising at least one non-phenolic stabilizer. The present polymer compositions comprise an unexpected balance of properties after being subjected to irradiation treatments, including an unexpected combination of a lower melt flow rate ratio (MFRr) and high melt tension after being irradiated, while minimizing negative yellowing effects.
    Type: Application
    Filed: June 27, 2008
    Publication date: May 6, 2010
    Applicant: Basell Poliolefine Italia s.r.l,
    Inventors: Jeffrey D. Abata, Ronald F. Becker, Vu A. Dang, Anthony J. De Nicola, JR., Theodore Dziemianowicz
  • Publication number: 20100087079
    Abstract: A composition includes in relative proportion: 60 to 94 parts by weight of mineral oil; 1 to 30 parts by weight of at least one thermoplastic elastomer; and 5 to 30 parts by weight of non-halogenated metal phosphinate, wherein the non-halogenated metal phosphinate has a decomposition temperature of at least 240° C., and wherein the composition is a gel. A method of making the composition and its use as an encapsulant are also disclosed.
    Type: Application
    Filed: October 5, 2009
    Publication date: April 8, 2010
    Inventors: Eumi Pyun, Lisa S. Lim, Haohao Lin, William V. Dower, Sidney J. Berglund
  • Patent number: 7691927
    Abstract: A process for stabilising a natural or synthetic organic polymer or copolymer obtained from a water based latex or emulsion of the polymer or copolymer comprising adding to the later or emulsion prior to coagulation of the polymer or copolymer a substantially water-free self-emulsifying liquid stabiliser mixture comprising (a) a phosphite or phosphonite stabiliser; (b) a phenolic antioxidant and (c) an emulsifying agent. The preferred stabiliser package is a blend of 2 parts by weight liquid phosphite stabiliser to 1 part by weight liquid phenolic antioxidant which has dissolved in it a fatty acid ester emulsifier.
    Type: Grant
    Filed: July 26, 2005
    Date of Patent: April 6, 2010
    Assignee: Chemtura Europe GmbH
    Inventors: Corrado Callierotti, Jonathan Simon Hill
  • Patent number: 7691926
    Abstract: 4,4?-Biphenol polysulfone composition comprising: as main ingredient, at least one polysulfone comprising more than 50 mol. % of recurring units formed by reacting 4,4?-biphenol with at least one sulfone monomer SM1 (Bo1 PSU), more than 0.01% by weight, based on the total weight of the composition, of at least one phosphorus-containing compound chosen from organic phosphites and organic phosphonites, and at least one polysulfone comprising more than 50 mol. % of recurring units formed by reacting bisphenol A with at least one sulfone monomer SM2(Bo1 A PSU). 4,4?-Biphenol polysulfone composition containing at least 60% by weight, based on the total weight of the 4,4?-biphenol polysulfone composition, of at least one Bo1 PSU, said composition having a melt viscosity ratio at 410° C. and at a shear rate of 50 s?1 (VR40) of below 1.20. Process which is especially well-suited to prepare the above compositions. Articles made from the above compositions or prepared by the above process.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: April 6, 2010
    Assignee: Solvay Advanced Polymers, L.L.C.
    Inventor: Mohammad Jamal El-Hibri
  • Publication number: 20100076132
    Abstract: A flame retarded thermoplastic polymer composition comprising a thermoplastic polymer and a mixture of metal salts of dialkylphosphinic and monoalkylphosphinic acid providing improved flame retardant performance and better processability compared to a similar composition containing only a salt of dialkylphosphinic acid.
    Type: Application
    Filed: November 29, 2006
    Publication date: March 25, 2010
    Inventors: Sergei Levchik, Qiang Yao, Gerald R. Alessio
  • Publication number: 20100069539
    Abstract: To provide a flame-retardant polyamide resin composition generally excellent in flame resistance, mechanical characteristics and electrical characteristics, and suitable for electrics/electronics components and vehicles. Used is a flame-retardant polyamide resin composition comprising, a polyamide resin (A), a phosphorus-containing flame retarder (B), and glass fiber having a non-circular cross-section (C), wherein the contents in the composition are 15 to 78% by weight for the polyamide resin (A), 2 to 20% by weight for the phosphorus-containing flame retarder (B), and 20 to 65% by weight for the glass fiber having a non-circular cross-section (C).
    Type: Application
    Filed: December 4, 2007
    Publication date: March 18, 2010
    Applicant: Mitsubishi Engineering-Plastics Corporation
    Inventors: Kei Morimoto, Yasushi Yamanaka
  • Publication number: 20100025643
    Abstract: The invention relates to flame retardant mixtures for thermoplastic polymers, comprising a phosphinic salt of the formula (I) where M=Al (component A) and a fusible phosphinic salt of the formula (I) where M=Zn (component B), in which R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; and n is from 1 to 3; where the amount of component A present is from 5 to 95% by weight and the amount of component B present is from 5 to 95% by weight, and also flame-retardant polymers. The polymers are polyamides which contain, as aromatic dicarboxylic acids, terephthalic acid or isophthalic acid.
    Type: Application
    Filed: July 31, 2008
    Publication date: February 4, 2010
    Inventors: Sebastian Hoerold, Wolfgang Wanzke
  • Patent number: 7655715
    Abstract: The invention relates to phosphorus-containing mixtures containing compounds of the formula RO—PO(A)-CH2—CH2—CO2H and??(I) HO—PO(A)-CH2—CH2—CO2R??(II) in which A is C1-C18-alkyl, C6-C18-alkylaryl, C6-C18-aralkyl or aryl, R is (D,E)C?C(B, R5), H B, D, E are identical or different and are each H or C1-C18-alkyl R5 is C1-C20-alkylene, a process for their preparation and their use.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: February 2, 2010
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Harald Bauer, Mathias Dietz, Ottmar Schacker
  • Patent number: 7649038
    Abstract: Phosphate derivatives of a 1,3,5-triazine compound, preferably melamine polyphosphate, which are heat-resistant at the processing temperature, are selected which have an average condensation coefficient n (number average)>20, a pH-value of a 10% slurry of the polyphosphate derivative in water at 25° C. of 5 or higher, a molar ratio of 1,3,5-triazine compound to phosphorus (M/P)<1.1 and a decomposition temperature>320° C. They can be produced by heat treatment of an orthophosphate or condensed phosphate with an average condensation coefficient n (number average) below 20 in an ammonia atmosphere at a temperature in the range of 300 to 400° C. until the average condensation coefficient is above 20 and the molar ratio of 1,3,5-triazine compound to phosphorus (M/P) is below 1.1. The polyphosphates of the invention can be represented in simplified form by the following general formula: wherein M denotes a 1,3,5-triazine compound and n denotes the average condensation coefficient.
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: January 19, 2010
    Assignee: Chemische Fabrik Budenheim KG
    Inventors: Hans Dieter-Naegerl, Thomas Futterer, Vincens Mans Fibla, David Garcia Martinez, Eduardo Tortosa Gimeno
  • Publication number: 20100008711
    Abstract: A dry-erase ink is disclosed for writing or marking on glossy and non-porous surfaces, in particular whiteboards or dry-erase boards, which ink is wipeable or erasable after drying without leaving visible colored residues. The ink contains a solvent, one or more dye(s) soluble in the solvent, a film forming resin such as polyvinylpyrrolidone or a derivative thereof, a strongly-alkaline substance such as a diamine and/or a quaternary organic ammonium hydroxide, an organic acid or a salt thereof and, if desired, a nonvolatile, liquid component serving as a release agent.
    Type: Application
    Filed: July 10, 2007
    Publication date: January 14, 2010
    Applicant: EDDING AG
    Inventor: Rainer Kaufmann
  • Patent number: 7645851
    Abstract: A method of making polycarbonate includes the steps of forming polycarbonate by a melt transesterification method using an activated diaryl carbonate, and compounding the polycarbonate with a phosphorus-containing compound that has an abstractable proton or hydrolyzable group. The phosphorus-containing compound is compounded with the polycarbonate in an amount sufficient to result in an improvement in the color properties of the polycarbonate as compared to pellets formed from the same polycarbonate without addition of the phosphorus-containing compound.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: January 12, 2010
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Sjef Berndsen, Hans Peter Brack, Bernd Jansen, Edward Kung, Daniel Lowery, Patrick Joseph McCloskey, Dennis Karlik, Gerardo Hidalgo Llinas
  • Publication number: 20100001430
    Abstract: Disclosed are polyamide compositions containing non-halogenated flame retardant and zinc stannate that have reduced corrosion effects on melt processing equipment.
    Type: Application
    Filed: July 1, 2008
    Publication date: January 7, 2010
    Inventor: Yige Yin
  • Publication number: 20090312468
    Abstract: A flame retardant polyamide resin composition having excellent extrudability and moldability, being free of generating a highly corrosive hydrogen halide gas upon combustion, exhibiting very high flame retardancy, having excellent mechanical properties and electrical properties and being suited for use in electrical and electronic parts and parts for automobile electrical equipments, and a molded article thereof are provided. A polyamide resin composition comprising 100 parts by weight of an aliphatic polyamide resin (A) having a viscosity number of 70 to 200 ml/g, 0.1 to 30 parts by weight of a polyphenylene ether-based resin (B), and 5 to 100 parts by weight of flame retardant agent (C) comprising at least the following components (a), (b) and (c); (a) a reaction product of a melamine and a phosphoric acid, (b) a phosphinic acid salt and/or a diphosphinic acid salt, and (c) a metal salt of boric acid, wherein a compounding weight ratio (a):(b):(c) of the flame retardant agent components is 1:(0.5 to 2.
    Type: Application
    Filed: March 12, 2007
    Publication date: December 17, 2009
    Inventors: Morio Tsunoda, Yasushi Yamanaka
  • Publication number: 20090298978
    Abstract: The present invention discloses a stabilized composition comprising a) an synthetic polymer subject to oxidative, thermal or light-induced degradation, b) a filler, c) a monomeric or polymeric dispersing or solvating agent free of nitrogen atoms having amphiphilic properties, d) a monomeric or polymeric dispersing or solvating agent having amphiphilic properties containing an amido group or an ethoxylated amino group, and e) a stabilizer. The mixture of components (c), (d) and (e) show a surprising synergistic effect in stabilizing a synthetic polymer which contains a filler.
    Type: Application
    Filed: December 7, 2005
    Publication date: December 3, 2009
    Inventor: Bruno Rotzinger
  • Patent number: 7622522
    Abstract: A flame retardant poly(arylene ether) composition is described. In addition to the poly(arylene ether), the composition includes a polyolefin component, and a flame retardant composition that includes a metal dialkyl phosphinate, a nitrogen-containing flame retardant, and a liquid triaryl phosphate. The polyolefin component can be a polyolefin polymer and/or the polyolefin block of a poly(alkenyl aromatic)-polyolefin block copolymer. The composition is particularly suitable as a replacement for poly(vinyl chloride) in insulation for wire and cable.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: November 24, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Weili Qiu, Jian Guo, Xiucuo Li, Hua Guo
  • Patent number: 7622517
    Abstract: The invention relates to a phosphorus-containing flame retardant formulation for cellulose-containing moldings, comprising from 0.1 to 99.9% by weight of a resin of an organic nitrogen compound and from 0.1 to 99.9% by weight of a phosphorus-containing flame retardant.
    Type: Grant
    Filed: April 18, 2008
    Date of Patent: November 24, 2009
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Harald Bauer, Werner Krause, Martin Sicken, Volker Thewes
  • Patent number: 7619021
    Abstract: The invention comprises an adhesion promoter for a printing ink and a printing ink comprising the adhesion promoter. The adhesion promoter comprises the product of (a) mixing together a solution of a polymer or synthetic resin with an organophosphorus compound, and then (b) mixing the mixture formed in (a) with a titanium compound selected from a titanium halide, alkoxide, halo-alkoxide or a condensed titanium alkoxide or a mixture of more than one of these titanium compounds.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: November 17, 2009
    Assignee: Sun Chemical Corporation
    Inventor: Robert Hume Duncan
  • Publication number: 20090281216
    Abstract: The present invention relates to polycarbonate compositions comprising: A) an aromatic polycarbonate and/or aromatic polyester carbonate; B) a graft polymer obtainable by co-precipitation of a mixture of at least two graft polymer dispersions B.1 and B.2, wherein the production of the graft polymer component B.1 takes place using at least one redox system as initiator and wherein the production of the graft polymer component B.2 takes place using at least one persulfate compound as initiator; C) optionally a vinyl (co)polymer and/or polyalkylene terephthalate; D) optionally a phosphorus-containing flame retardant; E) at least one phenolic antioxidant; F) optionally a neutral phosphorus- or sulfur-containing co-stabilisers (synergists); and G) optionally additives. Compositions of the present invention are distinguished by an optimum combination of good hydrolysis resistance and a light natural colour.
    Type: Application
    Filed: April 22, 2009
    Publication date: November 12, 2009
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Evgueni AVTOMONOV, Andreas SEIDEL, Thomas ECKEL, Eckhard WENZ
  • Publication number: 20090275683
    Abstract: Disclosed is a flame retardant thermoplastic resin composition that includes about 100 parts by weight of a mixed resin (A) including about 10 to about 90 wt % of an aromatic polyamide resin (A-1) and about 10 to about 90 wt % of a polyphenylene sulfide resin (A-2), about 0.5 to about 30 parts by weight of a phosphinic acid metal salt flame retardant (B), and about 10 to about 100 parts by weight of a filler (C).
    Type: Application
    Filed: April 29, 2009
    Publication date: November 5, 2009
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Eun-Joo LEE, Chang-Min HONG
  • Publication number: 20090275682
    Abstract: The present invention relates to a resin composition containing (A) a polyamide having a viscosity number (as measured in the 96% sulfuric acid according to ISO 307 (1997)) of from 50 ml/g to 250 ml/g; (B) a polyphenylene ether; and (C) a phosphinate represented by a particular formula. The resin composition according to the present invention is excellent in flame retardancy, impact resistance and thin-wall moldability and can significantly suppress gas generation during the molding process and substantially inhibit the generation of deposits on a mold during injection molding. As a result, a molded product thereof excellent in surface appearance can be provided.
    Type: Application
    Filed: November 2, 2006
    Publication date: November 5, 2009
    Applicant: Asahi Kasei Chemicals Corporation
    Inventors: Hiroaki Furukawa, Takaaki Miyoshi, Yasukazu Shikano, Makoto Doki
  • Patent number: 7612131
    Abstract: A flame-retardant resin composition comprises 25 to 150 parts by weight of (B) a thermoplastic polyester1 elastomer, 5 to 40 parts by weight of (C) a phosphinic acid compound comprising a salt of at least one member selected from the group consisting of a phosphinic acid, a diphosphinic acid, and a polymerized product thereof, and 0.5 to 20 parts by weight of (D) an epoxy compound, relative to 100 parts by weight of (A) a polybutylene terephthalate-series resin. Such a flame-retardant resin composition is useful for various molded products and for covering the surface of an electric wire, or the like. The present invention provides a halogen-free flame-retardant resin composition which has a high heat resistance and a high flame retardancy and is excellent in hydrolysis resistance, abrasion resistance, and moldability (e.g., extrusion properties).
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: November 3, 2009
    Assignee: Wintech Polymer Ltd.
    Inventor: Shinya Yamada
  • Patent number: 7608651
    Abstract: An article comprises a compatibilized poly(arylene ether)/polyamide blend, an optional electrically conductive filler, a phosphinate, and flame retardant augment selected from the group consisting of melamine polyphosphate, zinc borate, low melting glass, talc, and combinations of two or more of the foregoing flame retardant augments.
    Type: Grant
    Filed: April 10, 2006
    Date of Patent: October 27, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Pravin Borade, Manatesh Chakraborty, Anantharaman Dhanabalan, Roshan Kumar Jha, Jaykisor Pal
  • Publication number: 20090253836
    Abstract: The present invention relates to flame-retarded flexible thermoplastic compositions of high thermomechanical strength, containing no halogen compound, comprising a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the radicals of an unsaturated monomer (X) having a function capable of reacting with an amine-terminal polyamide, the radicals of the unsaturated monomer (X) being fixed to the backbone by grafting or copolymerization from its double bond, wherein said composition comprises, in a mixture: 50% to 70% by weight of the graft copolymer containing polyamide blocks, 25% to 35% by weight of a flame retardant selected from ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, approximately 2% by weight of molecular sieve, such as a zeolite, or of hydrotalcite(s).
    Type: Application
    Filed: June 1, 2007
    Publication date: October 8, 2009
    Applicant: Arkema France
    Inventors: Jean-Jacques Flat, Philippe Blondel, David Meslet
  • Publication number: 20090242844
    Abstract: Disclosed herein is a flame resistant composition comprising a compatibilized blend of a polyphthalamide and a poly(arylene ether); and a phosphinate, wherein the composition is substantially free of linear aliphatic polyamides.
    Type: Application
    Filed: November 4, 2008
    Publication date: October 1, 2009
    Applicant: SABIC Innovative Plastics, IP B.V.
    Inventor: Mark Elkovitch
  • Patent number: 7592382
    Abstract: A flame retardant poly(arylene ether)/polyamide composition includes a poly(arylene ether), a polyamide, about 5 to about 15 weight percent glass fiber, and a flame retardant consisting of a metal dialkyl phosphinate. Methods of preparing the composition are described, as are articles that include it.
    Type: Grant
    Filed: June 19, 2007
    Date of Patent: September 22, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Pravin Kamlakar Borade, Mark Elkovich, Jaykisor Pal
  • Publication number: 20090234051
    Abstract: The present invention relates to halogen-free flame-retardants for thermoplastic polyesters with UL 94 V-0 classification and with particularly good mechanical properties and high tracking resistance.
    Type: Application
    Filed: October 12, 2006
    Publication date: September 17, 2009
    Inventors: Jochen Endtner, Matthias Bienmüller, Martin Wanders
  • Publication number: 20090179035
    Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % polyester, 10-49 wt % ABS impact modifier; 0-20 wt % omultifunctional epoxy compound; 0-40 wt % filler; 0-2 wt % fibrillated fluoropolymer; and more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 30-100 Joules at ?30° C. and a ductility of more than 90%; a permeability of more than 0 and less than or equal to 1.5g/m2-day to ASTM D 471-98 Fuel C, measured after exposure to ASTM D 471-98 Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min., measured at 265° C.; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break, after exposure to Fuel E85 for 28 days at 70° C.
    Type: Application
    Filed: August 7, 2008
    Publication date: July 16, 2009
    Inventors: Parminder AGARWAL, Donald Howard ELLINGTON, Robert Russell GALLUCCI, Josephus Gerardus van GISBERGEN, Vishvajit Chandrakant JUIKAR, Ihab ODEH, Sathish Kumar RANGANATHAN, Kenneth Frederick MILLER, Veeraraghavan SRINIVASAN
  • Publication number: 20090181199
    Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % of a polyester, 10-49 wt % of an ABS impact modifier; 0 to 20 wt % of a multifunctional epoxy compound; 0-40 wt % of a filler; 0-2 wt % of a fibrillated fluoropolymer; and from more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 40-100 Joules at ?30° C.; a ductility of more than 90%, a permeability of more than 0 to less than or equal to 1.5g/m2-day, measured after exposure Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break after exposure to Fuel E85 for 28 days at 70° C.
    Type: Application
    Filed: August 7, 2008
    Publication date: July 16, 2009
    Inventors: Parminder Agarwal, Donald Howard ELLINGTON, Robert Russell GALLUCCI, Josephus Gerardus van GISBERGEN, Vishvajit Chandrakant JUIKAR, Ihab Odeh, Sathish Kumar RANGANATHAN, Kenneth Frederick MILLER, Veeraraghavan SRINIVASAN
  • Publication number: 20090182078
    Abstract: The present invention describes a process for preventing the formation of aldehydic contaminants in polyether polyols, polyester polyols or polyurethanes which comprises incorporating into said polyether polyols, polyester polyols or polyurethanes an effective amount of a) a phenolic antioxidant, b) one or more compounds selected from (i) aminic antioxidants, (ii) benzofuran-2-ones, and (iii) phosphites or phosphonites, or (iv) mixtures thereof.
    Type: Application
    Filed: April 11, 2006
    Publication date: July 16, 2009
    Inventors: Chin Siong Goh, Kerstin Schrinner, Pascal Xanthopoulos
  • Publication number: 20090176091
    Abstract: Flame retardant thermoplastic elastomer composition comprising a thermoplastic vulcanizate composition and non-halogenated flame retardant.
    Type: Application
    Filed: November 2, 2007
    Publication date: July 9, 2009
    Inventors: Eleni Karayianni, Jean-Michel Philippoz
  • Publication number: 20090166576
    Abstract: Provided is an insulating material satisfying IEC60695-12 Standard for the molded parts composed of a flame retardant PBT resin composition, specifically for a thin-walled molded article, even without applying secondary working. For details, to (A) 100 parts by weight of a polybutylene terephthalate resin, there are added (B) 5 to 50 parts by weight of a halogen-based flame retardant, (C) 5 to 40 parts by weight of an flame retardant assistant, (D) 5 to 100 parts by weight of a liquid crystalline polymer, and (E) 0 to 200 parts by weight of an inorganic filler.
    Type: Application
    Filed: June 19, 2007
    Publication date: July 2, 2009
    Applicant: WinTech Polymer Ltd.
    Inventor: Yasumitsu Miyamoto
  • Publication number: 20090163629
    Abstract: The present invention relates to impact-modified polycarbonate compositions comprising A) 50 to 99.4 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C) of aromatic polycarbonate and/or aromatic polyester carbonate, B) 0.5 to 20 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C) of graft polymer containing a silicone rubber or silicone/acrylate rubber, C) 0.1 to 30 parts by wt. (in each case based on the sum of the parts by weight of components A+B+C) of a salt of a phosphinic acid. which are distinguished by an optimum combination of good flameproofing, high heat distortion temperature, good mechanical properties and good resistance to chemicals, the use of the polycarbonate compositions for the production of shaped articles and the shaped articles themselves.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 25, 2009
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Thomas ECKEL, Vera BUCHHOLZ, Dieter WITTMANN, Eckhard WENZ
  • Patent number: 7541420
    Abstract: A method for preparing a molded article includes the steps of (a) obtaining a polycarbonate resin and (b) molding the polycarbonate resin. The polycarbonate resin is made by a transesterification reaction using an activated diaryl carbonate such that the polycarbonate is susceptible to the formation of internal ester linkages (IEL). The method occurs with the proviso that the polycarbonate resin, the molding conditions or both are selected to control the amount of IEL formed during the molding process to a level of less than 0.4 mol %.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: June 2, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Sjef Berndsen, Hans Peter Brack, Bernd Jansen, Jan Henk Kamps, Edward Kung, Daniel Lowery, Patrick Joseph McCloskey, Paul Michael Smigelski, Jr., Dennis Willemse
  • Publication number: 20090137707
    Abstract: The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate?)x(carboxylic acid anionz?1/z)y] where n=from 1 to 4 x=from 0.01 to n?0.01 y=n?x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.
    Type: Application
    Filed: November 21, 2008
    Publication date: May 28, 2009
    Inventors: Harald Bauer, Werner Krause, Wolfgang Wanzke