Abstract: A medium for electrophoresis in the form of an aqueous gel comprising an acrylamide copolymer having at least one specifically selected repeating unit; and a compound containing at least one carbamoyl group such as urea or formamide which serves as modifier.
Abstract: Formaldehyde-containing cationic electrodepositable compositions to which are added a formaldehyde scavenger are disclosed. Also disclosed are the use of these compositions in a method of cationic electrodeposition. Free formaldehyde in cationic compositions can lower the pH of the compositions making them more corrosive to the metal parts such as ferrous metal tanks and attending piping and pumps in contact with such compositions. The presence of the formaldehyde scavenger in such compositions stabilizes the pH.
Type:
Grant
Filed:
July 3, 1984
Date of Patent:
December 24, 1985
Assignee:
PPG Industries, Inc.
Inventors:
Roger M. Christenson, Joseph T. Valko, Joseph E. Plasynski, Roger L. Scriven
Abstract: Flexible, resilient, polyurethane foam having improved flame retardancy and intumescent properties is prepared from the reaction of polyether polyol with organic isocyanate and an additive combination comprising: (i) a polyester polyol, (ii) an halogenated flame retardant, and (iii) water or alcohol soluble urea-formaldehyde resin.
Abstract: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additives uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
Abstract: What are disclosed are aqueous dispersions of a self-crosslinking synthetic resin, said dispersions consisting of an aqueous phase containing from 0.2 to 5 weight percent of urea and, dispersed therein, resin particles formed of a vinyl polymer comprising (a) from 52.1 to 97.9 weight percent of acrylate or methacrylate esters, vinyl esters, or styrene; (b) from 0.1 to 10 weight percent of N-methylol acrylamide or methacrylamide; (c) from 2 to 10 weight percent of an hydroxyalkyl ester of an unsaturated carboxylic acid; and (d) 0 to 27.9 weight percent of other monomers, which dispersions, on drying and condensation to form films, liberate much less formaldehyde than comparable dispersions without urea while retaining good solvent resistance.
Type:
Grant
Filed:
November 15, 1982
Date of Patent:
September 25, 1984
Assignee:
Rohm GmbH
Inventors:
Herbert Fink, Norbert Suetterlin, Klaus Huebner, Werner Siol
Abstract: An improved process for substantially increasing the shelf-life of aqueous solutions of melamine-formaldehyde resins wherein the molar ratio of melamine to formaldehyde is from 1:1.7 to 1:3.5 by the addition of a stabilizing amount of urea after condensation, which process includes the steps of adjusting pH of the resin solution before and after the dissolution of the urea within certain narrow but easily controllable pH ranges. The properties of the resin solution can be further improved and the stabilizing effect of the addition of urea increased by adding a monohydric C.sub.1 -C.sub.4 alkanol during condensation of the resin.
Abstract: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
Abstract: This invention relates to unique and novel blend compounds of an amine neutralized sulfonated elastomeric polymer and an unsulfonated elastomeric or thermoplastic polymer. These compounds can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
Type:
Grant
Filed:
September 29, 1982
Date of Patent:
April 10, 1984
Assignee:
Exxon Research and Engineering Co.
Inventors:
Robert D. Lundberg, Warren A. Thaler, Pawan K. Agarwal
Abstract: An aqueous adhesive, resistant to humidity and water, which debonds in the presence of strong base, comprises finely divided aluminum, a natural product bonding agent and water.
Abstract: Organic fibers are impregnated with an aqueous emulsion comprising (1) an organopolysiloxane containing diorganosiloxane units in which both organic radicals are monovalent hydrocarbon radicals, and further contains at least two monovalent SiC-bonded organic radicals with a basic nitrogen atom per molecule in which the SiC-bonded organic radicals with a basic nitrogen are present in monoorganosiloxane units, (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule, (3) a catalyst for the condensation of Si-bonded condensable groups (4) emulsifiers, and (5) a diorganopolysiloxane containing an Si-bonded hydroxyl group in each of its terminal units and whose radicals are free of the basic nitrogen atom. If it is desired to impart hydrophobic properties to the impregnated organic fibers, then it is essential that (6) a trimethylsiloxy end-blocked diorganopolysiloxane be added to the aqueous emulsion.
Abstract: Absorbent articles are rendered more blood absorptive by incorporating water soluble amido compounds having the formulaH.sub.2 N--X--NH.sub.2where X is --CO--, --CS--, --SO-- or --SO.sub.2 --, and nonionic surfactants into the articles.
Abstract: In a polysiloxane molding composition which can be cured to give flame-repellent products, comprising(a) a diorganopolysiloxane of the formula ##EQU1## in which n is 1.9 to 2.05, andR.sup.1 is an alkyl, alkenyl and/or or aryl radical with 1-8 C-atoms,(b) finely divided TiO.sub.2 with a surface area, measured by the BET method, greater than 20 m.sup.2 /g and a particle size less than 0.5 .mu.m,(d) platinum and/or one of its sulphur-free compounds, and(e) a curing agent,the improvement which comprises about 0.05 to 10% by weight of (a) to (e) of nitrogen compound of the formula ##STR1## in which R is H, phenyl, alkyl with 1-6 C-atoms, tolyl, nitrile, --NHR.sup.2, --CH.sub.2 OR.sup.2, --CH.sub.2 COOR.sup.2, --C(.dbd.NH)NHR.sup.2, --CO--NH--R.sup.2 or (R.sup.1).sub.2 C--,R.sub.2.sup.1 is H, alkyl with 1-6 C-atoms, Si(CH.sub.3).sub.3 -- or R,R.sup.2 is H or --CO--R, andZ is NH, O or NR,or a salt thereof. Articles molded therefrom and then cured are of enhanced flame-repellency.
Type:
Grant
Filed:
October 20, 1981
Date of Patent:
December 6, 1983
Assignee:
Bayer Aktiengesellschaft
Inventors:
Jurgen Ackermann, Hans-Heinrich Moretto, Wilfried Kniege, Werner Rauer
Abstract: Methylated methylol melamine resin condensate compositions, represented by the empirical formula:MF.sub.3-4 Me.sub.0.5-3wherein M represents a melamine moiety, F represents a formaldehyde moiety, and Me represents a methyl group moiety, are combined with from about 5 percent to about 30 percent by weight of urea, based on the resin condensate solids content, to provide modified methylated methylol melamine resin condensate compositions which exhibit a reduced tendency to release formaldehyde into the atmosphere during curing of the textile materials treated therewith or during storage of the treated textile materials during storage at elevated temperatures.
Abstract: An injection molding or extrusion polypropylene composition having improved impact strength and improved weld line properties, wherein the polypropylene composition comprises a blend composition of an isotactic polypropylene homopolymer having a number average molecular weight as measured by GPC of at least 15,000, about 5 to about 15 parts by weight of a zinc neutralized sulfonated EPDM terpolymer per 100 parts by weight of the isotactic polypropylene homopolymer, and about 5 to about 15 parts by weight of a high molecular weight polypropylene.
Abstract: Aminoplastic resin dispersions which are stable to sedimentation are obtained by condensation of aldehydes with aminoplastic resin formers in an aqueous medium, in the presence of water-soluble compounds of the formulaR--X--(A--O).sub.m --B--NHCONH--Y].sub.nhaving the substituent meanings mentioned in the description. The condensation is preferably carried out in the presence of dyestuffs or optical brighteners which have groups capable of condensation. The dispersions obtained thereby are particularly suitable for whitening the coating compositions used in the paper industry, and for coating paper, wood, films and textile materials.
Type:
Grant
Filed:
March 8, 1982
Date of Patent:
September 20, 1983
Assignee:
Bayer Aktiengesellschaft
Inventors:
Hanns P. Muller, Kuno Wagner, Peter Mummenhoff, Gottfried Wallpott, Karlheinz Scheuss
Abstract: The properties of polymeric compositions can be improved by the presence of a polysiloxane unit of formula ##STR1## where Q is a substituted or unsubstituted aromatic group,Z is ##STR2## D is unsubstituted or substituted hydrocarbylene R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each, independently, is unsubstituted or substituted hydrocarbyl.x, y and z each independently has a value from 0 to 100.Polyimides containing these units display improved solubility and adhesion; they are useful, among other things as protective coatings.
Abstract: An aqueous sizing composition having a cationic lubricant, amide compound, and cationic silicone polymer aqueous emulsion which is used to produce wet chopped sized glass fiber strands or which also has a film former to produce continuous glass fiber strands. The moisture content of the wet chopped glass fiber strands is controlled to within about 9 to about 20 weight percent. The sized wet chopped glass fiber strands have good flowability and when used to produce non-woven glass fiber strand mat, produces mat with good flexibility and tensile strength.
Abstract: This invention relates to hot melt adhesive compositions which include an elastomeric co- or terpolymer, about 5 to about 100 parts by weight of a neutralized sulfonated co- or terpolymer per 100 parts by weight of the highly unsaturated hydrocarbon rubber, wherein the neutralized sulfonated elastomeric polymer has about 0.2 to about 5 weight percent of chemically combined sulfur and about 25 to about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono and diolefins, cyclic olefins of 5 to 6 carbon atoms and hydrogenated poly cyclics per 100 parts by weight of the neutralized sulfonated co- or terpolymer rubber.
Type:
Grant
Filed:
September 28, 1981
Date of Patent:
June 7, 1983
Assignee:
Exxon Research and Engineering Co.
Inventors:
Robert D. Lundberg, Pawan K. Agarwal, Robert A. Weiss
Abstract: This invention relates to hot melt adhesive compositions which include a neutralized sulfonated 1,2-syndiotactic polybutadiene resin which has about 5 to about 25 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated 1,2-syndiotactic polybutadiene, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to about 6 carbon atoms the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated 1,2-syndiotactic polybutadiene polymer.
Abstract: This invention relates to hot melt adhesive compositions which include a highly unsaturated hydrocarbon rubber, about 5 to about 100 parts by weight of a neutralized sulfonated elastomeric polymer per 100 parts by weight of the highly unsaturated hydrocarbon rubber, wherein the neutralized sulfonated elastomeric polymer has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric polymer, and about 25 to about 200 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, aliphatic dienes and mono- and di-olefins, cyclic olefins of 5 or 6 carbon atoms and hydrogenated polycyclics per 100 parts by weight of the highly unsaturated hydrocarbon rubber.
Abstract: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and a tertiary amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.
Abstract: This invention relates to hot melt adhesive compositions which include a neutralized EPDM terpolymer which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated elastomeric EPDM terpolymer, a neutralized sulfonated 1,2-syndiotactic polybutadiene resin which has about 5 to about 50 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated polybutadiene, and about 25 to about 250 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate having about 5 to about 6 carbon atoms the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated EPDM terpolymer.