Aryl-oh Group Patents (Class 524/222)
  • Patent number: 5597856
    Abstract: Phase change inks capable of passing light therethrough are suitable for color overhead transparencies, as well as plain paper printing. A composition for the ink carrier comprises an unsaturated bis-amide as a transparency enhancer, a low viscosity monoamide as a thinner material, and a polyamide resin as a base and binder.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: January 28, 1997
    Assignee: Dataproducts Corporation
    Inventors: Kelvin W. Yu, Susan Schnitzel
  • Patent number: 5589566
    Abstract: This invention relates to aliphatic copolyesters prepared from succinic acid (or derivatives thereof) and a process for the preparation thereof. The aliphatic copolyesters contain a second component, 1,4-butanediol, and a third component which is either a diacid or a diol (or derivatives thereof).
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: December 31, 1996
    Assignee: Eastman Chemical Company
    Inventors: Alan W. White, Barry G. Pearcy, Allan S. Jones, Charles M. Buchanan, Robert M. Gardner
  • Patent number: 5562984
    Abstract: A polyester film contains a polyester having an intrinsic viscosity (IV) in the range from 0.65 to 0.8 and an antioxidant. The polyester has an endothermic high temperature peak at a temperature of (A).degree.C. and an endothermic low temperature peak at a temperature of (B).degree.C., both peaks being measured by differential scanning calorimetry (DSC), and the value of (A-B) is in the range from 25.degree. C. to 50.degree. C. The polyester film is suitable for use an insulation film, exhibiting improved ageing properties.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: October 8, 1996
    Assignee: Imperial Chemical Industries PLC
    Inventors: Simon V. Mortlock, Barry J. Lewis
  • Patent number: 5480962
    Abstract: This invention relates to aliphatic copolyesters prepared from succinic acid (or derivatives thereof) and a process for the preparation thereof. The aliphatic copolyesters contain a second component, 1,4-butanediol, and a third component which is either a diacid or a diol (or derivatives thereof).
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: January 2, 1996
    Assignee: Eastman Chemical Company
    Inventors: Alan W. White, Barry G. Pearcy, Allan S. Jones, Charles M. Buchanan, Robert M. Gardner
  • Patent number: 5449711
    Abstract: Blooming on the surface of products molded from an olefinic thermoplastic elastomer composition containing an olefinic thermoplastic elastomer and one or more additives which promotes such blooming is prevented by compounding into the elastomer one or more compounds selected from the group consisting of esters of polyhydric alcohols, alkylalkanolamines, alkylalkanolamides, fatty acid amides, higher alcohols, aliphatic amines, fatty acids and adducts of alkylene oxides to these compounds. The composition thus can be advantageously used as interior materials of automobiles and materials for electronic instruments.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: September 12, 1995
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Nobuo Saito, Yoshihiro Shigemori, Mitsuo Noda, Jun-ichi Itou
  • Patent number: 5424349
    Abstract: Tertiary amides have been developed which have low volatility and good thermal stability and which are effective in stabilizing organic materials that are normally susceptible to oxidative deterioration. The novel antioxidants are tertiary amides corresponding to the formula: ##STR1## wherein R is a mono-, di-, or trivalent aromatic or saturated aliphatic hydrocarbon group containing 1-20 carbons; n is an integer of 1-3 which is equal to the valence of R; R' is phenyl, benzyl, or C.sub.1 -C.sub.6 alkyl; m is an integer of 1-3; R" is a C.sub.1 -C.sub.4 alkylene group; Z and Z' are independently selected from hydrogen and alkyl; and Q is carbonyl or sulfonyl.
    Type: Grant
    Filed: August 9, 1993
    Date of Patent: June 13, 1995
    Assignee: Albemarle Corporation
    Inventor: Vincent J. Gatto
  • Patent number: 5403880
    Abstract: A corrosion-resistant polyurethane coating for application directly to a face as a self-priming topcoat comprising major amount of a polyurethane binder and minor amount of a combination of pigments consisting essentially of an aluminum phosphate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 30 parts by weight of a titanium dioxide pigment, up to about 2.0 parts by weight of an oil soluble surface active agent and up to about 50 parts by weight of at least one organic solvent.
    Type: Grant
    Filed: March 7, 1994
    Date of Patent: April 4, 1995
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
  • Patent number: 5338606
    Abstract: Disclosed are polyester adhesive compositions which exhibit increased melt viscosity and improved adhesion comprised of residues of terephthalic acid, ethylene glycol and diethylene glycol and having reacted therewith or copolymerized therein the residue of a phosphite ester compound and optionally containing a phenolic antioxidant. Also disclosed are articles coated with the polyester compositions and bonded laminate articles based on the compositions.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: August 16, 1994
    Assignee: Eastman Chemical Company
    Inventors: Alan W. White, Barry G. Pearcy, Marc A. Strand, Joey C. Carico
  • Patent number: 5229442
    Abstract: Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: July 20, 1993
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Fabio Broussard, Carlo Busetto
  • Patent number: 5229445
    Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.
    Type: Grant
    Filed: February 19, 1992
    Date of Patent: July 20, 1993
    Assignee: Shell Oil Company
    Inventors: Johannes L. M. Syrier, Hendrik Van De Weg
  • Patent number: 5216054
    Abstract: A polymer composition comprising resin components comprising (a) 5-95 weight % of a polyamide resin, and (b) 5-95 weight % of polyolefin + unsaturated carboxylic acid-modified polyolefin, and (c) additives comprising the following compounds in amounts per 100 parts by weight of the total composition: (1) 0.1-2 parts by weight of a substituted hydrazine: (2) 0.05-2 parts by weight of a hindered phenol compound; (3) 0.05-0.5 parts by weight of a phosphite or phosphonite; and (4) 0.15-1 parts by weight of a thiodipropionate.
    Type: Grant
    Filed: February 27, 1992
    Date of Patent: June 1, 1993
    Assignee: Tonen Sekiyukagaku Kabushiki Kaisha
    Inventors: Kunio Iwanami, Kissho Kitano, Yukihiko Yagi, Takashi Mikami
  • Patent number: 5191003
    Abstract: A rubber composition comprising a rubber, a filler and a diamide compound represented by the formula: ##STR1## wherein X is hydrogen, alkyl of 1 to 18 carbon atoms, alkoxy of 1 to 18 carbon atoms, alkanoyl of 2 to 19 total carbon atoms, amino, nitro, cyano, hydroxy, carboxy or halogen, and n is an integer of 2 to 12. This rubber composition is increased in its loss factor and is useful for tires and rubber vibration isolators. For example, the resulting tires prepared from the rubber composition are improved in their gripping performance.
    Type: Grant
    Filed: August 7, 1991
    Date of Patent: March 2, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Naoki Inui, Chinehito Ebina, Miyuki Oikawa, Hideo Nagasaki, Shinichi Yachigo, Manji Sasaki
  • Patent number: 5189088
    Abstract: Disclosed is a class of bis(phenolic-amine)quinone compounds which are useful as stablizers for polyolefins. The bis(phenolic-amine)quinone compounds inhibit oxidative degradation of polyolefins which is attributable to heat and/or ultraviolet light and is promoted or accelerated by metals, e.g., copper, in contact with the polyolefin. The compounds also exhibit excellent thermal stability.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: February 23, 1993
    Assignee: Eastman Kodak Company
    Inventors: Richard H. S. Wang, Ping P. Shang, Daniel A. Jervis
  • Patent number: 5179152
    Abstract: A fiber-reinforced resin composition having surface smoothness, which comprises(1) 100 parts by weight of a thermoplastic resin composition comprising an aromatic polycarbonate resin and a thermoplastic polyester resin in a weight ratio of from 10/90 to 90/10,(2) from 50 to 100 parts by weight of glass fiber sheet chips having an almost rectangular shape, each side having a length of from 1 to 30 mm, the glass fiber sheet chips being obtained by forming E-glass fibers having an average fiber diameter of 2 .mu.m or less which have been surface-treated with a silane coupling agent, into a sheet by a paper making process and then cutting the resulting sheet, and(3) from 0 to 40 parts by weight of a thermoplastic elastomeric polymer,and an exterior automotive part showing excellent image clarity, obtained by shaping the fiber-reinforced resin composition.
    Type: Grant
    Filed: June 20, 1991
    Date of Patent: January 12, 1993
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Goro Shimaoka, Makoto Mizutani, Isamu Mio, Kunitoshi Mimura
  • Patent number: 5162405
    Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: November 10, 1992
    Assignee: ELF Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
  • Patent number: 5147935
    Abstract: Stabilized compositions based on polyamides containing(a) a symmetrical triaryl phosphite,(b) an amide derived from an alkylhydroxyphenylalkanoic acid, and(c) an alkylhydroxyphenylalkanoylhydrazine.These compositions, which are highly resistant to thermooxidative degradation, are suitable for the manufacture of all kinds of shaped objects.
    Type: Grant
    Filed: February 20, 1991
    Date of Patent: September 15, 1992
    Assignee: Solvay S.A.
    Inventors: Sophie Volmer, Dominique Debecker
  • Patent number: 5120792
    Abstract: Organic materials which are normally susceptible to oxidative deterioration are stabilized with tertiary amide antioxidants corresponding to the formula:(p--HO--C.sub.6 R.sub.n H.sub.4-n --R").sub.2 N--C(O)--R'wherein R and R' are independently selected from alkyl, aryl, and benzyl groups, R" is an alkylene group containing 1-5 carbons, and n is an integer of 1-3.
    Type: Grant
    Filed: March 15, 1991
    Date of Patent: June 9, 1992
    Assignee: Ethyl Corporation
    Inventor: Vincent J. Gatto
  • Patent number: 5114997
    Abstract: Talc filled thermoplastic polyester compositions which have been modified by the addition of a butadiene-based impact modifier are stabilized against degradation by the addition thereto of a specific diamide compound.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: May 19, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Michael D. Golder, David K. Walker
  • Patent number: 5110849
    Abstract: The present invention concerns a thermoplastic polyester resin composition comprising a thermoplastic polyester and a metal alcoholate salt of an aromatic alcohol containing a hydroxy group directly attached to the aromatic ring as the essential ingredient, having a high crystallization rate, excellent moldability upon molding at low temperature, less molecular weight reduction during production and molding of the resin composition, and satisfactory melt degradation stability and hydrolysis resistance.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: May 5, 1992
    Assignee: Toray Industries, Inc.
    Inventors: Hiroo Karasawa, Kiichi Kometani, Kiyokazu Nakamura
  • Patent number: 5106891
    Abstract: Coating compositions which, in addition to a 2-hydroxyphenylbenzotriazole UV absorber, also contain a UV absorber belonging to the group of the 2-hydroxyphenyltriazines, 2-hydroxybenzophenones and/or, in addition to a 2-hydroxyphenyltriazine, also contain a 2-hydroxybenzophenone and/or oxanilide are described.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: April 21, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Andreas Valet
  • Patent number: 5059644
    Abstract: Polyacetal compositions containing 0.05 to 5 weight percent of an oxo-piperazinyl-triazine hindered amine light stabilizer wherein the hindered N.sup.4 atom in the piperazinone ring of the stabilizer is alkylated with a metyl, ethyl, or propyl group, said compositions being relatively stable upon exposure to UV light. A polyacetal composition containing a specific oxo-piperazinyl-triazine hindered amine light stabilizer wherein the hindered N.sup.4 atom is not alkylated is shown to be relatively stable upon exposure to UV light. Both compositions possess stability during melt processing and do not significantly lose physical properties upon exposure to heat and light.
    Type: Grant
    Filed: March 19, 1990
    Date of Patent: October 22, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Leonard E. R. Kosinski
  • Patent number: 5023283
    Abstract: Esters of N,N-bis(hydroxyethyl)hydroxylamines corresponding to the formula ##STR1## wherein R are various aliphatic and aromatic groups, and X is hydroxy or substituted carboxyethyl are effective in stabilizing various organic materials against oxidative, thermal and actinic degradation.
    Type: Grant
    Filed: April 25, 1989
    Date of Patent: June 11, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Raymond Seltzer
  • Patent number: 5008459
    Abstract: Novel compositions are described which comprise an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: April 16, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans R. Meier, Samuel Evans, Paul Dubs
  • Patent number: 4992499
    Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of a stabilizing amount of a combination of a phenolic compound and an aromatic amine.
    Type: Grant
    Filed: November 30, 1989
    Date of Patent: February 12, 1991
    Assignee: Shell Oil Company
    Inventors: Johannes L. M. Syrier, Hendrik Van De Weg, Robert Q. Kluttz
  • Patent number: 4985481
    Abstract: A solid stabilizer composition for synthetic polymers is formed by a solid, continuous phase and by a solid dispersed phase in said continuous phase, wherein the continuous phase is constituted by amorphous 2,2'-oxamido-bis[ethyl-3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionate] and the dispersed phase is constituted by an amorphous, or crystalline, or partially amorphous and partially crystalline organic phosphite, with the weight ratio of said continuous phase to said dispersed phase being comprised within the range of from 9:1 to 1:9.The process for preparing said solid composition and its use in the stabilization of synthetic polymers are disclosed.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: January 15, 1991
    Assignee: Enichem Synthesis, S.p.A.
    Inventors: Carlo Neri, Nereo Nodari, Giovanni Sandre
  • Patent number: 4966960
    Abstract: A process and nylon release sheet for manufacturing printed circuit boards from epoxy prepregs is disclosed. In such process layers of the prepregs are separated from one another by a release sheet. The release sheet comprises an aliphatic or aromatic nylon or nylon copolymer which is a condensation product of a dicarboxylic acid and a diamine. The nylon film contains a heat stabilizer and an inorganic particulate antiblock additive, e.g. diatomaceous earth, glass beads, amorphous silica, talc, mica and molybdenum disulphide. The nylon may be toughened by the addition of a phosphorus-containing catalyst or an epoxide.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: October 30, 1990
    Assignee: Du Pont Canada Inc.
    Inventors: Peter A. Sipos, Erica M. Besso
  • Patent number: 4960808
    Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.
    Type: Grant
    Filed: March 30, 1988
    Date of Patent: October 2, 1990
    Assignee: Shell Oil Company
    Inventor: Andre Schmitter
  • Patent number: 4857572
    Abstract: Novel compositions are described which contain an elastomer or a tackifying resin and at least one compound of formula I ##STR1## The symbols R.sub.1 is alkyl or cycloalkyl, R.sub.2 is alkyl, hydroxyalkyl, phenyl or benzyl, and R.sub.3 is hydrogen or methyl with the proviso that, when R.sub.1 is other than methyl, R.sub.3 is methyl.
    Type: Grant
    Filed: February 10, 1988
    Date of Patent: August 15, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans-Rudolf Meier, Gerrit Knobloch
  • Patent number: 4780492
    Abstract: A liquid concentrate comprising an oxamide and a 2,2,6,6-tetraalkylpiperidine compound dissolved in an organic solvent is useful for the UV-stabilization of hardenable liquid finishes, particularly automotive finishes.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: October 25, 1988
    Assignee: Sandoz Ltd.
    Inventor: Lajos Avar
  • Patent number: 4775710
    Abstract: Disclosed are stabilized linear low-density polyethylene (LLDPE) compositions containing a stabilizing amount of a ring-substituted N-acyl-para-aminophenol. In a preferred embodiment, the latter compound is N-stearoyl-2,6-di-t-butyl-4-aminophenol.
    Type: Grant
    Filed: January 21, 1987
    Date of Patent: October 4, 1988
    Assignee: Mallinckrodt, Inc.
    Inventors: Neil Dunski, Henry J. Buehler
  • Patent number: 4758614
    Abstract: Substituted amino carbamate derivatives corresponding to the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.
    Type: Grant
    Filed: April 25, 1986
    Date of Patent: July 19, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Edward T. Hessell, Ramanathan Ravichandran
  • Patent number: 4722956
    Abstract: Disclosed are stabilized A-B-A type block copolymer compositions containing at least two monoalkenyl arene polymer end blocks and at least one polydiene internal block and a stabilizing amount of a ring-substituted N-acyl-para-aminophenol. In two preferred embodiments, the latter compound is N-stearoyl-2,6-di-t-butyl-4-aminophenol, while the block copolymers are polystyrene-polybutadiene-polystyrene and polystyrene-polyisoprene-polystyrene, respectively.
    Type: Grant
    Filed: December 8, 1986
    Date of Patent: February 2, 1988
    Assignee: Mallinckrodt, Inc.
    Inventor: Neil Dunski
  • Patent number: 4720517
    Abstract: N-hydroxyiminodiacetic and dipropionic acids and esters thereof corresponding to the formula ##STR1## are effective in stabilizing various organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in synthetic polymers containing phenolic antioxidants and/or metal salts of fatty acids and as stabilizers in lubricants.
    Type: Grant
    Filed: November 24, 1986
    Date of Patent: January 19, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Thomas E. Snead
  • Patent number: 4699942
    Abstract: Compositions suitable for molding are produced by examining a (1) polyethylene terephthalate polyester, (2) a low molecular weight polyethylene mold release agent (3) talc as nucleating agent, (4) carbon black, (5) a hindered phenolic antioxidant and (6) other optional ingredients such as reinforcing glass fibers.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: October 13, 1987
    Assignee: Eastman Kodak Co.
    Inventors: James C. Weaver, Wayne P. Pruett
  • Patent number: 4581413
    Abstract: Vinyl dispersion resins containing a major proportion of vinyl chloride that provide fluid suspensions thereof with thixotropic properties are obtained by isolating and drying the vinyl chloride polymer resin from an emulsion (latex) thereof containing a small amount of a cross-linked, water-swellable polymer of an unsaturated carboxylic acid.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: April 8, 1986
    Assignee: The B. F. Goodrich Company
    Inventor: Jong S. Kim
  • Patent number: 4555542
    Abstract: A polyester-polyether copolymer composition which comprises a polyester-polyether copolymer composed mainly of an aromatic dicarboxylic acid, 1,4-butanediol, and a polyalkylene glycol of average molecular weight from about 400 to 6,000, an effective amount of organotin compound, and an amide-containing phenolic antioxidant having the following general moiety: ##STR1## (where R is a secondary or tertiary alkyl group, R' is a hydrogen atom or a secondary or tertiary alkyl group, and n is from 0 to 6).
    Type: Grant
    Filed: December 21, 1983
    Date of Patent: November 26, 1985
    Assignee: Toray Industries, Inc.
    Inventors: Hideo Komatsu, Hiroyuki Harada, Tomiji Matsuki
  • Patent number: 4552926
    Abstract: The title compounds correspond to the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are alkyl, A is alkylene, X is --NH-- or --S--, m is 1 and n is 0 or 1, and are useful as stabilizers for organic polymers and lubricating oils to counteract the degradative effects of heat, light and air.
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: November 12, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: John D. Spivack, Stephen D. Pastor
  • Patent number: 4540727
    Abstract: The high temperature aging of polyamides is substantially improved by incorporating therein an antioxidant and an oxide of a metal of Group II or III of the Periodic Table, preferably a crystalline aluminosilicate such as a synthetic zeolite. The amount of antioxidant is preferably 1 to 5% and the amount of metal oxide is preferably 0.5 to 5%. Polyamides which can be stabilized in this way include Nylon-6, Nylon-11 and Nylon-12.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: September 10, 1985
    Assignee: Raychem Corporation
    Inventor: Christine E. Vogdes
  • Patent number: 4525504
    Abstract: Disclosed are stabilized polyester compositions having significantly improved weatherability, said polyesters consisting of homopolyesters derived from a dicarboxylic acid component wherein at least a major portion of which is 1,4-cyclohexanedicarboxylic acid (or ester) having a trans isomer content of at least 65% and a glycol component wherein at least a major portion of which is 2,2,4,4-tetramethyl-1,3-cyclobutanediol and copolyesters thereof with modifying aliphatic glycols and/or aliphatic dicarboxylic acids, said polyesters being stabilized with the combination of at least one ultraviolet light stabilizing compound compatible with said polyester and at least one hindered amine light stabilizer having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: June 25, 1985
    Assignee: Eastman Kodak Company
    Inventors: John C. Morris, Joseph S. Zannucci
  • Patent number: 4524165
    Abstract: Disclosed are stabilized polyester compositions having significantly improved weatherability. These polyesters consist of copolyesterethers derived from a dicarboxylic acid component comprising about 80-100 mole % 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70% and about 0-20 mole % of a second dicarboxylic acid and a glycol component comprising about 70-95 mole % 1,4-cyclohexanedimethanol and about 5-30 mole % of a polyalkylene ether glycol having a molecular weight of about 600 to about 3000. The copolyesterether compositions further comprise a stabilizing effective amount of the combination of (1) at least one hindered phenolic antioxidant, (2) at least one ultraviolet light stabilizing compound compatible with said copolyesterether and (3) at least one hindered amine light stabilizing compound having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: June 18, 1985
    Assignee: Eastman Kodak Company
    Inventors: Harry R. Musser, Thomas H. Strickland, Joseph S. Zannucci
  • Patent number: 4485034
    Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;and R.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: November 27, 1984
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
  • Patent number: 4464496
    Abstract: A non-yellowing antioxidant-UV stabilizer combination especially useful in AES polymers comprising(A) at least one antioxidant selected from the group consisting of:(i) a thiodialkylene bis-(3,5-dialkyl-4-hydroxy) hydrocinnamate antioxidant;(ii) An N,N'-alkylene bis-(3,5-dialkyl-4-hydroxy) hydrocinnamamide antioxidant;(iii) an O,O-dialkyl-3,5-dialkyl-4-hydroxybenzyl phosphonate antioxidant;(iv) an oxamidobis alkyl (3,5)-dialkyl-4-hydroxyphenyl) propionate antioxidant; and(v) a [3-(3,5-dialkyl-4-hydroxyphenyl)propionamido]alkyl stearate antioxidant; and(B) a UV stabilizer package comprising:(vi) at least one UV stabilizer of the hindered amine type, with or without(vii) at least one UV absorber.
    Type: Grant
    Filed: March 26, 1982
    Date of Patent: August 7, 1984
    Assignee: Uniroyal, Inc.
    Inventors: Thomas L. Nemzek, Brendan J. Geelan
  • Patent number: 4452933
    Abstract: Ester-carbonate interchange in blends of aromatic polycarbonates and poly(alkylene dicarboxylates) is inhibited by adding thereto a hydroxy- or amino-substituted carboxylic acid derivative such as methyl salicylate, malic acid, glycine or dibutyl tartrate.
    Type: Grant
    Filed: June 9, 1983
    Date of Patent: June 5, 1984
    Assignee: General Electric Company
    Inventor: Russell J. McCready
  • Patent number: 4431762
    Abstract: A resin composition containing at least one compound (A) selected from compounds of formulas ##STR1## wherein R.sub.1 and R.sub.2 each denote a hydrogen atom, halogen atom, or alkyl or alkoxy group having 1 to 10 carbon atoms, ##STR2## R.sub.3 denotes a hydrogen atom, alkyl group containing 1 to 10 carbon atoms, naphthyl group or substituent of formula ##STR3## wherein R.sub.4 to R.sub.8, which may be the same or different, each denote a hydrogen atom, halogen atom, nitro group and alkyl or alkoxy group having 1 to 10 carbon atoms.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: February 14, 1984
    Assignee: Dainippon Ink & Chemicals Inc.
    Inventors: Shingo Araki, Keizo Asai, Seibei Ono
  • Patent number: 4412024
    Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;andR.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.
    Type: Grant
    Filed: September 14, 1981
    Date of Patent: October 25, 1983
    Assignee: Sandoz Ltd.
    Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
  • Patent number: 4396698
    Abstract: A loaded polymer latex composition is disclosed. The composition comprises an aqueous polymer latex whose dispersed phase is made up of a specified cross-linked quaternary salt polymer loaded with a specified hydrophobic substance. The latex composition can be advantageously employed as a mordant polymer in a photographic element for a color diffusion transfer process. Use of the latex improves light resistance without lowering the maximum densities of the film images.
    Type: Grant
    Filed: June 8, 1982
    Date of Patent: August 2, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Karino, Masakazu Morigaki, Shinji Sakaguchi
  • Patent number: 4385147
    Abstract: Chlorine-containing thermoplastics which contain, as a stabilizer, a compound of the formula I ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are as defined in the description.
    Type: Grant
    Filed: September 8, 1981
    Date of Patent: May 24, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Jurgen Bussing, Hans-Helmut Friedrich
  • Patent number: 4383064
    Abstract: Disclosed is a flame retardant polyamide composition having desirable mechanical, electrical and processing properties, and therefore, being useful for producing parts of electric and electronic devices and appliances. The composition comprises a polyamide resin matrix and 1 to 40%, based on the weight of the polyamide matrix, of a flame-retarding agent in the form of fine particles dispersed in the matrix. The composition is characterized in that the flame-retarding agent consists of at least one member selected from:(A) crystals of addition salts of cyanuric acid or isocyanuric acid with melamine, and;(B) mixed crystals of addition salts of cyanuric acid or isocyanuric acid with a mixture of melamine and acetoguanamine in an amount by mole not larger than that of the melamine.
    Type: Grant
    Filed: February 22, 1978
    Date of Patent: May 10, 1983
    Assignee: Toray Industries, Inc.
    Inventor: Hiroshi Iida
  • Patent number: 4373042
    Abstract: New N,N'-di-(hydroxy-phenyl) derivatives of piperazine are disclosed. These new compounds are useful for stabilizing thermoplastic polymers, in particular polyolefins, against sunlight, heat and oxidation.A process for producing the new compounds is also disclosed, as well as the polymeric compositions stabilized with said new compounds.
    Type: Grant
    Filed: May 9, 1980
    Date of Patent: February 8, 1983
    Assignee: Montedison S.p.A.
    Inventors: Francesco Gratani, Giuseppe Nelli, Piero Di Battista, Osvaldo Cicchetti
  • Patent number: 4341879
    Abstract: A polyphenylene ether resin composition having improved heat stability, said composition comprising a polymer matrix composed of a polyphenylene ether resin and a vinyl aromatic resin, and dispersed in the polymer matrix, at least one compound selected from the group consisting of(1). 2-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyanilino)-4,6-di-C.sub.5 -C.sub.15 -alkylthio-1,3,5-triazines,(2). .omega.,.omega.'-thiodi(C.sub.2 -C.sub.6 polymethylene)-bis[3-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)-carboxylates],(3). N,N'-C.sub.2 -C.sub.10 polymethylene-bis[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxamides], and(4). tetrakis-{methylene-[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxylate]}methanes.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: July 27, 1982
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Masatugu Matunaga, Kozo Ishiyama