Aryl-oh Group Patents (Class 524/222)
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Patent number: 5597856Abstract: Phase change inks capable of passing light therethrough are suitable for color overhead transparencies, as well as plain paper printing. A composition for the ink carrier comprises an unsaturated bis-amide as a transparency enhancer, a low viscosity monoamide as a thinner material, and a polyamide resin as a base and binder.Type: GrantFiled: September 24, 1993Date of Patent: January 28, 1997Assignee: Dataproducts CorporationInventors: Kelvin W. Yu, Susan Schnitzel
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Patent number: 5589566Abstract: This invention relates to aliphatic copolyesters prepared from succinic acid (or derivatives thereof) and a process for the preparation thereof. The aliphatic copolyesters contain a second component, 1,4-butanediol, and a third component which is either a diacid or a diol (or derivatives thereof).Type: GrantFiled: March 1, 1996Date of Patent: December 31, 1996Assignee: Eastman Chemical CompanyInventors: Alan W. White, Barry G. Pearcy, Allan S. Jones, Charles M. Buchanan, Robert M. Gardner
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Patent number: 5562984Abstract: A polyester film contains a polyester having an intrinsic viscosity (IV) in the range from 0.65 to 0.8 and an antioxidant. The polyester has an endothermic high temperature peak at a temperature of (A).degree.C. and an endothermic low temperature peak at a temperature of (B).degree.C., both peaks being measured by differential scanning calorimetry (DSC), and the value of (A-B) is in the range from 25.degree. C. to 50.degree. C. The polyester film is suitable for use an insulation film, exhibiting improved ageing properties.Type: GrantFiled: March 30, 1994Date of Patent: October 8, 1996Assignee: Imperial Chemical Industries PLCInventors: Simon V. Mortlock, Barry J. Lewis
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Patent number: 5480962Abstract: This invention relates to aliphatic copolyesters prepared from succinic acid (or derivatives thereof) and a process for the preparation thereof. The aliphatic copolyesters contain a second component, 1,4-butanediol, and a third component which is either a diacid or a diol (or derivatives thereof).Type: GrantFiled: March 7, 1994Date of Patent: January 2, 1996Assignee: Eastman Chemical CompanyInventors: Alan W. White, Barry G. Pearcy, Allan S. Jones, Charles M. Buchanan, Robert M. Gardner
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Patent number: 5449711Abstract: Blooming on the surface of products molded from an olefinic thermoplastic elastomer composition containing an olefinic thermoplastic elastomer and one or more additives which promotes such blooming is prevented by compounding into the elastomer one or more compounds selected from the group consisting of esters of polyhydric alcohols, alkylalkanolamines, alkylalkanolamides, fatty acid amides, higher alcohols, aliphatic amines, fatty acids and adducts of alkylene oxides to these compounds. The composition thus can be advantageously used as interior materials of automobiles and materials for electronic instruments.Type: GrantFiled: April 7, 1993Date of Patent: September 12, 1995Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Nobuo Saito, Yoshihiro Shigemori, Mitsuo Noda, Jun-ichi Itou
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Patent number: 5424349Abstract: Tertiary amides have been developed which have low volatility and good thermal stability and which are effective in stabilizing organic materials that are normally susceptible to oxidative deterioration. The novel antioxidants are tertiary amides corresponding to the formula: ##STR1## wherein R is a mono-, di-, or trivalent aromatic or saturated aliphatic hydrocarbon group containing 1-20 carbons; n is an integer of 1-3 which is equal to the valence of R; R' is phenyl, benzyl, or C.sub.1 -C.sub.6 alkyl; m is an integer of 1-3; R" is a C.sub.1 -C.sub.4 alkylene group; Z and Z' are independently selected from hydrogen and alkyl; and Q is carbonyl or sulfonyl.Type: GrantFiled: August 9, 1993Date of Patent: June 13, 1995Assignee: Albemarle CorporationInventor: Vincent J. Gatto
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Patent number: 5403880Abstract: A corrosion-resistant polyurethane coating for application directly to a face as a self-priming topcoat comprising major amount of a polyurethane binder and minor amount of a combination of pigments consisting essentially of an aluminum phosphate, zinc salts of benzoic acids, and an alkaline earth metal phosphate such as zinc-barium phosphate. In addition, the coating contains up to about 30 parts by weight of a titanium dioxide pigment, up to about 2.0 parts by weight of an oil soluble surface active agent and up to about 50 parts by weight of at least one organic solvent.Type: GrantFiled: March 7, 1994Date of Patent: April 4, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng
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Patent number: 5338606Abstract: Disclosed are polyester adhesive compositions which exhibit increased melt viscosity and improved adhesion comprised of residues of terephthalic acid, ethylene glycol and diethylene glycol and having reacted therewith or copolymerized therein the residue of a phosphite ester compound and optionally containing a phenolic antioxidant. Also disclosed are articles coated with the polyester compositions and bonded laminate articles based on the compositions.Type: GrantFiled: July 12, 1993Date of Patent: August 16, 1994Assignee: Eastman Chemical CompanyInventors: Alan W. White, Barry G. Pearcy, Marc A. Strand, Joey C. Carico
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Patent number: 5229442Abstract: Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.Type: GrantFiled: March 6, 1992Date of Patent: July 20, 1993Assignee: Enichem Synthesis S.p.A.Inventors: Fabio Broussard, Carlo Busetto
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Patent number: 5229445Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.Type: GrantFiled: February 19, 1992Date of Patent: July 20, 1993Assignee: Shell Oil CompanyInventors: Johannes L. M. Syrier, Hendrik Van De Weg
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Patent number: 5216054Abstract: A polymer composition comprising resin components comprising (a) 5-95 weight % of a polyamide resin, and (b) 5-95 weight % of polyolefin + unsaturated carboxylic acid-modified polyolefin, and (c) additives comprising the following compounds in amounts per 100 parts by weight of the total composition: (1) 0.1-2 parts by weight of a substituted hydrazine: (2) 0.05-2 parts by weight of a hindered phenol compound; (3) 0.05-0.5 parts by weight of a phosphite or phosphonite; and (4) 0.15-1 parts by weight of a thiodipropionate.Type: GrantFiled: February 27, 1992Date of Patent: June 1, 1993Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Kunio Iwanami, Kissho Kitano, Yukihiko Yagi, Takashi Mikami
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Patent number: 5191003Abstract: A rubber composition comprising a rubber, a filler and a diamide compound represented by the formula: ##STR1## wherein X is hydrogen, alkyl of 1 to 18 carbon atoms, alkoxy of 1 to 18 carbon atoms, alkanoyl of 2 to 19 total carbon atoms, amino, nitro, cyano, hydroxy, carboxy or halogen, and n is an integer of 2 to 12. This rubber composition is increased in its loss factor and is useful for tires and rubber vibration isolators. For example, the resulting tires prepared from the rubber composition are improved in their gripping performance.Type: GrantFiled: August 7, 1991Date of Patent: March 2, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Naoki Inui, Chinehito Ebina, Miyuki Oikawa, Hideo Nagasaki, Shinichi Yachigo, Manji Sasaki
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Patent number: 5189088Abstract: Disclosed is a class of bis(phenolic-amine)quinone compounds which are useful as stablizers for polyolefins. The bis(phenolic-amine)quinone compounds inhibit oxidative degradation of polyolefins which is attributable to heat and/or ultraviolet light and is promoted or accelerated by metals, e.g., copper, in contact with the polyolefin. The compounds also exhibit excellent thermal stability.Type: GrantFiled: March 30, 1992Date of Patent: February 23, 1993Assignee: Eastman Kodak CompanyInventors: Richard H. S. Wang, Ping P. Shang, Daniel A. Jervis
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Patent number: 5179152Abstract: A fiber-reinforced resin composition having surface smoothness, which comprises(1) 100 parts by weight of a thermoplastic resin composition comprising an aromatic polycarbonate resin and a thermoplastic polyester resin in a weight ratio of from 10/90 to 90/10,(2) from 50 to 100 parts by weight of glass fiber sheet chips having an almost rectangular shape, each side having a length of from 1 to 30 mm, the glass fiber sheet chips being obtained by forming E-glass fibers having an average fiber diameter of 2 .mu.m or less which have been surface-treated with a silane coupling agent, into a sheet by a paper making process and then cutting the resulting sheet, and(3) from 0 to 40 parts by weight of a thermoplastic elastomeric polymer,and an exterior automotive part showing excellent image clarity, obtained by shaping the fiber-reinforced resin composition.Type: GrantFiled: June 20, 1991Date of Patent: January 12, 1993Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Goro Shimaoka, Makoto Mizutani, Isamu Mio, Kunitoshi Mimura
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Patent number: 5162405Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.Type: GrantFiled: March 22, 1991Date of Patent: November 10, 1992Assignee: ELF Atochem North America, Inc.Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
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Patent number: 5147935Abstract: Stabilized compositions based on polyamides containing(a) a symmetrical triaryl phosphite,(b) an amide derived from an alkylhydroxyphenylalkanoic acid, and(c) an alkylhydroxyphenylalkanoylhydrazine.These compositions, which are highly resistant to thermooxidative degradation, are suitable for the manufacture of all kinds of shaped objects.Type: GrantFiled: February 20, 1991Date of Patent: September 15, 1992Assignee: Solvay S.A.Inventors: Sophie Volmer, Dominique Debecker
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Patent number: 5120792Abstract: Organic materials which are normally susceptible to oxidative deterioration are stabilized with tertiary amide antioxidants corresponding to the formula:(p--HO--C.sub.6 R.sub.n H.sub.4-n --R").sub.2 N--C(O)--R'wherein R and R' are independently selected from alkyl, aryl, and benzyl groups, R" is an alkylene group containing 1-5 carbons, and n is an integer of 1-3.Type: GrantFiled: March 15, 1991Date of Patent: June 9, 1992Assignee: Ethyl CorporationInventor: Vincent J. Gatto
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Patent number: 5114997Abstract: Talc filled thermoplastic polyester compositions which have been modified by the addition of a butadiene-based impact modifier are stabilized against degradation by the addition thereto of a specific diamide compound.Type: GrantFiled: December 6, 1990Date of Patent: May 19, 1992Assignee: Hoechst Celanese Corp.Inventors: Michael D. Golder, David K. Walker
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Patent number: 5110849Abstract: The present invention concerns a thermoplastic polyester resin composition comprising a thermoplastic polyester and a metal alcoholate salt of an aromatic alcohol containing a hydroxy group directly attached to the aromatic ring as the essential ingredient, having a high crystallization rate, excellent moldability upon molding at low temperature, less molecular weight reduction during production and molding of the resin composition, and satisfactory melt degradation stability and hydrolysis resistance.Type: GrantFiled: August 10, 1990Date of Patent: May 5, 1992Assignee: Toray Industries, Inc.Inventors: Hiroo Karasawa, Kiichi Kometani, Kiyokazu Nakamura
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Patent number: 5106891Abstract: Coating compositions which, in addition to a 2-hydroxyphenylbenzotriazole UV absorber, also contain a UV absorber belonging to the group of the 2-hydroxyphenyltriazines, 2-hydroxybenzophenones and/or, in addition to a 2-hydroxyphenyltriazine, also contain a 2-hydroxybenzophenone and/or oxanilide are described.Type: GrantFiled: March 22, 1991Date of Patent: April 21, 1992Assignee: Ciba-Geigy CorporationInventor: Andreas Valet
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Patent number: 5059644Abstract: Polyacetal compositions containing 0.05 to 5 weight percent of an oxo-piperazinyl-triazine hindered amine light stabilizer wherein the hindered N.sup.4 atom in the piperazinone ring of the stabilizer is alkylated with a metyl, ethyl, or propyl group, said compositions being relatively stable upon exposure to UV light. A polyacetal composition containing a specific oxo-piperazinyl-triazine hindered amine light stabilizer wherein the hindered N.sup.4 atom is not alkylated is shown to be relatively stable upon exposure to UV light. Both compositions possess stability during melt processing and do not significantly lose physical properties upon exposure to heat and light.Type: GrantFiled: March 19, 1990Date of Patent: October 22, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Leonard E. R. Kosinski
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Patent number: 5023283Abstract: Esters of N,N-bis(hydroxyethyl)hydroxylamines corresponding to the formula ##STR1## wherein R are various aliphatic and aromatic groups, and X is hydroxy or substituted carboxyethyl are effective in stabilizing various organic materials against oxidative, thermal and actinic degradation.Type: GrantFiled: April 25, 1989Date of Patent: June 11, 1991Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Raymond Seltzer
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Patent number: 5008459Abstract: Novel compositions are described which comprise an elastomer or a lubricant and at least one compound of the formulae I or II ##STR1## The symbols R.sub.1, R.sub.2, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.The compounds of the formula II and some of the compounds of the formula I are novel, and they are used especially as antioxidants.Type: GrantFiled: December 22, 1987Date of Patent: April 16, 1991Assignee: Ciba-Geigy CorporationInventors: Hans R. Meier, Samuel Evans, Paul Dubs
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Patent number: 4992499Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of a stabilizing amount of a combination of a phenolic compound and an aromatic amine.Type: GrantFiled: November 30, 1989Date of Patent: February 12, 1991Assignee: Shell Oil CompanyInventors: Johannes L. M. Syrier, Hendrik Van De Weg, Robert Q. Kluttz
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Patent number: 4985481Abstract: A solid stabilizer composition for synthetic polymers is formed by a solid, continuous phase and by a solid dispersed phase in said continuous phase, wherein the continuous phase is constituted by amorphous 2,2'-oxamido-bis[ethyl-3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionate] and the dispersed phase is constituted by an amorphous, or crystalline, or partially amorphous and partially crystalline organic phosphite, with the weight ratio of said continuous phase to said dispersed phase being comprised within the range of from 9:1 to 1:9.The process for preparing said solid composition and its use in the stabilization of synthetic polymers are disclosed.Type: GrantFiled: September 19, 1989Date of Patent: January 15, 1991Assignee: Enichem Synthesis, S.p.A.Inventors: Carlo Neri, Nereo Nodari, Giovanni Sandre
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Patent number: 4966960Abstract: A process and nylon release sheet for manufacturing printed circuit boards from epoxy prepregs is disclosed. In such process layers of the prepregs are separated from one another by a release sheet. The release sheet comprises an aliphatic or aromatic nylon or nylon copolymer which is a condensation product of a dicarboxylic acid and a diamine. The nylon film contains a heat stabilizer and an inorganic particulate antiblock additive, e.g. diatomaceous earth, glass beads, amorphous silica, talc, mica and molybdenum disulphide. The nylon may be toughened by the addition of a phosphorus-containing catalyst or an epoxide.Type: GrantFiled: November 2, 1988Date of Patent: October 30, 1990Assignee: Du Pont Canada Inc.Inventors: Peter A. Sipos, Erica M. Besso
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Patent number: 4960808Abstract: Linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against thermal degradation by the inclusion therein of certain phenolic compounds.Type: GrantFiled: March 30, 1988Date of Patent: October 2, 1990Assignee: Shell Oil CompanyInventor: Andre Schmitter
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Patent number: 4857572Abstract: Novel compositions are described which contain an elastomer or a tackifying resin and at least one compound of formula I ##STR1## The symbols R.sub.1 is alkyl or cycloalkyl, R.sub.2 is alkyl, hydroxyalkyl, phenyl or benzyl, and R.sub.3 is hydrogen or methyl with the proviso that, when R.sub.1 is other than methyl, R.sub.3 is methyl.Type: GrantFiled: February 10, 1988Date of Patent: August 15, 1989Assignee: Ciba-Geigy CorporationInventors: Hans-Rudolf Meier, Gerrit Knobloch
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Patent number: 4780492Abstract: A liquid concentrate comprising an oxamide and a 2,2,6,6-tetraalkylpiperidine compound dissolved in an organic solvent is useful for the UV-stabilization of hardenable liquid finishes, particularly automotive finishes.Type: GrantFiled: December 22, 1986Date of Patent: October 25, 1988Assignee: Sandoz Ltd.Inventor: Lajos Avar
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Patent number: 4775710Abstract: Disclosed are stabilized linear low-density polyethylene (LLDPE) compositions containing a stabilizing amount of a ring-substituted N-acyl-para-aminophenol. In a preferred embodiment, the latter compound is N-stearoyl-2,6-di-t-butyl-4-aminophenol.Type: GrantFiled: January 21, 1987Date of Patent: October 4, 1988Assignee: Mallinckrodt, Inc.Inventors: Neil Dunski, Henry J. Buehler
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Patent number: 4758614Abstract: Substituted amino carbamate derivatives corresponding to the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.Type: GrantFiled: April 25, 1986Date of Patent: July 19, 1988Assignee: Ciba-Geigy CorporationInventors: Stephen D. Pastor, Edward T. Hessell, Ramanathan Ravichandran
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Patent number: 4722956Abstract: Disclosed are stabilized A-B-A type block copolymer compositions containing at least two monoalkenyl arene polymer end blocks and at least one polydiene internal block and a stabilizing amount of a ring-substituted N-acyl-para-aminophenol. In two preferred embodiments, the latter compound is N-stearoyl-2,6-di-t-butyl-4-aminophenol, while the block copolymers are polystyrene-polybutadiene-polystyrene and polystyrene-polyisoprene-polystyrene, respectively.Type: GrantFiled: December 8, 1986Date of Patent: February 2, 1988Assignee: Mallinckrodt, Inc.Inventor: Neil Dunski
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Patent number: 4720517Abstract: N-hydroxyiminodiacetic and dipropionic acids and esters thereof corresponding to the formula ##STR1## are effective in stabilizing various organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in synthetic polymers containing phenolic antioxidants and/or metal salts of fatty acids and as stabilizers in lubricants.Type: GrantFiled: November 24, 1986Date of Patent: January 19, 1988Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Thomas E. Snead
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Patent number: 4699942Abstract: Compositions suitable for molding are produced by examining a (1) polyethylene terephthalate polyester, (2) a low molecular weight polyethylene mold release agent (3) talc as nucleating agent, (4) carbon black, (5) a hindered phenolic antioxidant and (6) other optional ingredients such as reinforcing glass fibers.Type: GrantFiled: August 30, 1985Date of Patent: October 13, 1987Assignee: Eastman Kodak Co.Inventors: James C. Weaver, Wayne P. Pruett
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Patent number: 4581413Abstract: Vinyl dispersion resins containing a major proportion of vinyl chloride that provide fluid suspensions thereof with thixotropic properties are obtained by isolating and drying the vinyl chloride polymer resin from an emulsion (latex) thereof containing a small amount of a cross-linked, water-swellable polymer of an unsaturated carboxylic acid.Type: GrantFiled: December 24, 1984Date of Patent: April 8, 1986Assignee: The B. F. Goodrich CompanyInventor: Jong S. Kim
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Patent number: 4555542Abstract: A polyester-polyether copolymer composition which comprises a polyester-polyether copolymer composed mainly of an aromatic dicarboxylic acid, 1,4-butanediol, and a polyalkylene glycol of average molecular weight from about 400 to 6,000, an effective amount of organotin compound, and an amide-containing phenolic antioxidant having the following general moiety: ##STR1## (where R is a secondary or tertiary alkyl group, R' is a hydrogen atom or a secondary or tertiary alkyl group, and n is from 0 to 6).Type: GrantFiled: December 21, 1983Date of Patent: November 26, 1985Assignee: Toray Industries, Inc.Inventors: Hideo Komatsu, Hiroyuki Harada, Tomiji Matsuki
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Patent number: 4552926Abstract: The title compounds correspond to the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are alkyl, A is alkylene, X is --NH-- or --S--, m is 1 and n is 0 or 1, and are useful as stabilizers for organic polymers and lubricating oils to counteract the degradative effects of heat, light and air.Type: GrantFiled: September 26, 1983Date of Patent: November 12, 1985Assignee: Ciba-Geigy CorporationInventors: John D. Spivack, Stephen D. Pastor
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Patent number: 4540727Abstract: The high temperature aging of polyamides is substantially improved by incorporating therein an antioxidant and an oxide of a metal of Group II or III of the Periodic Table, preferably a crystalline aluminosilicate such as a synthetic zeolite. The amount of antioxidant is preferably 1 to 5% and the amount of metal oxide is preferably 0.5 to 5%. Polyamides which can be stabilized in this way include Nylon-6, Nylon-11 and Nylon-12.Type: GrantFiled: October 29, 1982Date of Patent: September 10, 1985Assignee: Raychem CorporationInventor: Christine E. Vogdes
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Patent number: 4525504Abstract: Disclosed are stabilized polyester compositions having significantly improved weatherability, said polyesters consisting of homopolyesters derived from a dicarboxylic acid component wherein at least a major portion of which is 1,4-cyclohexanedicarboxylic acid (or ester) having a trans isomer content of at least 65% and a glycol component wherein at least a major portion of which is 2,2,4,4-tetramethyl-1,3-cyclobutanediol and copolyesters thereof with modifying aliphatic glycols and/or aliphatic dicarboxylic acids, said polyesters being stabilized with the combination of at least one ultraviolet light stabilizing compound compatible with said polyester and at least one hindered amine light stabilizer having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.Type: GrantFiled: October 24, 1983Date of Patent: June 25, 1985Assignee: Eastman Kodak CompanyInventors: John C. Morris, Joseph S. Zannucci
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Patent number: 4524165Abstract: Disclosed are stabilized polyester compositions having significantly improved weatherability. These polyesters consist of copolyesterethers derived from a dicarboxylic acid component comprising about 80-100 mole % 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70% and about 0-20 mole % of a second dicarboxylic acid and a glycol component comprising about 70-95 mole % 1,4-cyclohexanedimethanol and about 5-30 mole % of a polyalkylene ether glycol having a molecular weight of about 600 to about 3000. The copolyesterether compositions further comprise a stabilizing effective amount of the combination of (1) at least one hindered phenolic antioxidant, (2) at least one ultraviolet light stabilizing compound compatible with said copolyesterether and (3) at least one hindered amine light stabilizing compound having the formulae ##STR1## the groups shown as R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from various substituents.Type: GrantFiled: October 24, 1983Date of Patent: June 18, 1985Assignee: Eastman Kodak CompanyInventors: Harry R. Musser, Thomas H. Strickland, Joseph S. Zannucci
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Patent number: 4485034Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;and R.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.Type: GrantFiled: September 6, 1983Date of Patent: November 27, 1984Assignee: Sandoz Ltd.Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
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Patent number: 4464496Abstract: A non-yellowing antioxidant-UV stabilizer combination especially useful in AES polymers comprising(A) at least one antioxidant selected from the group consisting of:(i) a thiodialkylene bis-(3,5-dialkyl-4-hydroxy) hydrocinnamate antioxidant;(ii) An N,N'-alkylene bis-(3,5-dialkyl-4-hydroxy) hydrocinnamamide antioxidant;(iii) an O,O-dialkyl-3,5-dialkyl-4-hydroxybenzyl phosphonate antioxidant;(iv) an oxamidobis alkyl (3,5)-dialkyl-4-hydroxyphenyl) propionate antioxidant; and(v) a [3-(3,5-dialkyl-4-hydroxyphenyl)propionamido]alkyl stearate antioxidant; and(B) a UV stabilizer package comprising:(vi) at least one UV stabilizer of the hindered amine type, with or without(vii) at least one UV absorber.Type: GrantFiled: March 26, 1982Date of Patent: August 7, 1984Assignee: Uniroyal, Inc.Inventors: Thomas L. Nemzek, Brendan J. Geelan
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Patent number: 4452933Abstract: Ester-carbonate interchange in blends of aromatic polycarbonates and poly(alkylene dicarboxylates) is inhibited by adding thereto a hydroxy- or amino-substituted carboxylic acid derivative such as methyl salicylate, malic acid, glycine or dibutyl tartrate.Type: GrantFiled: June 9, 1983Date of Patent: June 5, 1984Assignee: General Electric CompanyInventor: Russell J. McCready
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Patent number: 4431762Abstract: A resin composition containing at least one compound (A) selected from compounds of formulas ##STR1## wherein R.sub.1 and R.sub.2 each denote a hydrogen atom, halogen atom, or alkyl or alkoxy group having 1 to 10 carbon atoms, ##STR2## R.sub.3 denotes a hydrogen atom, alkyl group containing 1 to 10 carbon atoms, naphthyl group or substituent of formula ##STR3## wherein R.sub.4 to R.sub.8, which may be the same or different, each denote a hydrogen atom, halogen atom, nitro group and alkyl or alkoxy group having 1 to 10 carbon atoms.Type: GrantFiled: July 21, 1982Date of Patent: February 14, 1984Assignee: Dainippon Ink & Chemicals Inc.Inventors: Shingo Araki, Keizo Asai, Seibei Ono
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Patent number: 4412024Abstract: Oxalanilides of formula I ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxyR.sub.1 and R.sub.2 are independently, hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio; provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio;andR.sub.3 is hydrogen or C.sub.1-8 alkylcertain of which are novel, are useful as UV-stabilizers in organic polymers and organic polymer-containing coatings, particularly automotive finishes. The compounds have low volatility and excellent solubility in organic solvents such as are used in liquid finishes.Type: GrantFiled: September 14, 1981Date of Patent: October 25, 1983Assignee: Sandoz Ltd.Inventors: Lajos Avar, Evelyne Kalt, Hellmuth Reinshagen
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Patent number: 4396698Abstract: A loaded polymer latex composition is disclosed. The composition comprises an aqueous polymer latex whose dispersed phase is made up of a specified cross-linked quaternary salt polymer loaded with a specified hydrophobic substance. The latex composition can be advantageously employed as a mordant polymer in a photographic element for a color diffusion transfer process. Use of the latex improves light resistance without lowering the maximum densities of the film images.Type: GrantFiled: June 8, 1982Date of Patent: August 2, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Yukio Karino, Masakazu Morigaki, Shinji Sakaguchi
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Patent number: 4385147Abstract: Chlorine-containing thermoplastics which contain, as a stabilizer, a compound of the formula I ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are as defined in the description.Type: GrantFiled: September 8, 1981Date of Patent: May 24, 1983Assignee: Ciba-Geigy CorporationInventors: Hermann O. Wirth, Jurgen Bussing, Hans-Helmut Friedrich
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Patent number: 4383064Abstract: Disclosed is a flame retardant polyamide composition having desirable mechanical, electrical and processing properties, and therefore, being useful for producing parts of electric and electronic devices and appliances. The composition comprises a polyamide resin matrix and 1 to 40%, based on the weight of the polyamide matrix, of a flame-retarding agent in the form of fine particles dispersed in the matrix. The composition is characterized in that the flame-retarding agent consists of at least one member selected from:(A) crystals of addition salts of cyanuric acid or isocyanuric acid with melamine, and;(B) mixed crystals of addition salts of cyanuric acid or isocyanuric acid with a mixture of melamine and acetoguanamine in an amount by mole not larger than that of the melamine.Type: GrantFiled: February 22, 1978Date of Patent: May 10, 1983Assignee: Toray Industries, Inc.Inventor: Hiroshi Iida
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Patent number: 4373042Abstract: New N,N'-di-(hydroxy-phenyl) derivatives of piperazine are disclosed. These new compounds are useful for stabilizing thermoplastic polymers, in particular polyolefins, against sunlight, heat and oxidation.A process for producing the new compounds is also disclosed, as well as the polymeric compositions stabilized with said new compounds.Type: GrantFiled: May 9, 1980Date of Patent: February 8, 1983Assignee: Montedison S.p.A.Inventors: Francesco Gratani, Giuseppe Nelli, Piero Di Battista, Osvaldo Cicchetti
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Patent number: 4341879Abstract: A polyphenylene ether resin composition having improved heat stability, said composition comprising a polymer matrix composed of a polyphenylene ether resin and a vinyl aromatic resin, and dispersed in the polymer matrix, at least one compound selected from the group consisting of(1). 2-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyanilino)-4,6-di-C.sub.5 -C.sub.15 -alkylthio-1,3,5-triazines,(2). .omega.,.omega.'-thiodi(C.sub.2 -C.sub.6 polymethylene)-bis[3-(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)-carboxylates],(3). N,N'-C.sub.2 -C.sub.10 polymethylene-bis[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxamides], and(4). tetrakis-{methylene-[(3,5-di-C.sub.1 -C.sub.10 alkyl-4-hydroxyphenyl)-polymethylene(C.sub.1 -C.sub.4)carboxylate]}methanes.Type: GrantFiled: March 11, 1981Date of Patent: July 27, 1982Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Akitoshi Sugio, Masanobu Masu, Masao Okabe, Masatugu Matunaga, Kozo Ishiyama