With Water Nrm Patents (Class 524/276)
  • Patent number: 10233348
    Abstract: A new coating composition comprising, by dry weight based on the total dry weight of the coating composition, i) from 12% to 80% of polymer particles comprising, as polymerized units, by dry weight based on the total dry weight of the polymer particles, from 25% to 90%, of a vinyl acetate; and from 5% to 75%, of a vinyl ester of versatic acid and/or a vinyl ester of 2-ethyl hexanoic acid; and ii) from 0.1% to 6% of a wax; and iii) from 14% to 55% of a pigment.
    Type: Grant
    Filed: October 10, 2013
    Date of Patent: March 19, 2019
    Assignee: Rohm and Haas Company
    Inventors: Qiaoqiao Cai, Xiangting Dong, Juan Li, Tao Wang, Tingke Zhang
  • Patent number: 9920204
    Abstract: Methods for making emulsified hydrophobizing compositions and uses thereof are provided. In at least one specific embodiment, a method for making an emulsified hydrophobizing composition, can include mixing a hydrophobizing agent, a liquid medium, and a lignosulfonic acid or salt thereof to provide a hydrophobizing composition and emulsifying the hydrophobizing composition using hydrodynamic cavitation to provide an emulsified hydrophobizing composition. The emulsified hydrophobizing composition can have an average particle size of about 0.3 microns to about 160 microns. The method can also include maintaining the emulsified hydrophobizing composition at a temperature of greater than a melting point of the hydrophobizing agent for at least 10 minutes.
    Type: Grant
    Filed: July 8, 2014
    Date of Patent: March 20, 2018
    Assignee: Georgia-Pacific Wood Products LLC
    Inventor: Brian D Earnshaw
  • Patent number: 9493627
    Abstract: The present invention relates to moldable sand compositions, methods for making the moldable sand compositions, and methods for using the moldable sand compositions. In a particular embodiment, the moldable sand composition comprises between about 70% to about 95% sand, between about 5% to about 30% water, a polar polymeric resin, a crosslinking agent, and a humectant. In an exemplary embodiment, the composition contains no oils, waxes, glycols, or rubbers. The composition is capable of becoming hardened over time in order to maintain the achieved shape, and can be re-wetted and molded again after becoming hardened.
    Type: Grant
    Filed: April 22, 2015
    Date of Patent: November 15, 2016
    Assignee: Crayola LLC
    Inventors: Michael Moskal, Jie Li, Leena Vadaketh, Michael Spera
  • Patent number: 8859053
    Abstract: A waterborne base coat having a light metallic color and containing 0.5 to 2 wt.-% of poly(meth)acrylic acid thickener and 2 to 7 wt.-% of non-ionically emulsified EVA copolymer wax with a drop point of the wax portion of 80 to 110° C., the wt.-% in each case calculated as solids and relative to the solids content of the waterborne base coat.
    Type: Grant
    Filed: July 25, 2011
    Date of Patent: October 14, 2014
    Assignee: Axalta Coating Systems IP Co., LLC
    Inventors: Frank Tessari, Ralf Wilhelms
  • Publication number: 20140121311
    Abstract: The present invention relates to composition and use of a binder for the production of paints and inks. Said binder comprises the following elements: waxes, emulsifying agents, curing agents, drying oils, resins, metal ions and water. Furthermore, the present invention discloses a process for the preparation of binder compositions and paints containing them.
    Type: Application
    Filed: May 9, 2012
    Publication date: May 1, 2014
    Inventors: Jorge Cuní Bravo, Pedro Cuní Bravo, Montserrat Cuní Bravo
  • Patent number: 8604109
    Abstract: An aqueous binder for an inorganic fiber heat-insulating sound-absorbing member is cured by heating at low temperatures and is capable of providing a strong binder cured product. The inorganic fiber heat-insulating sound-absorbing member is produced by applying an aqueous binder to inorganic fibers and heating the resulting inorganic fibers at 180-220° C. The aqueous binder contains 5.5-10 parts by mass of an ammonium salt of an inorganic acid per 100 parts by mass of the total of an acrylic resin that has an acid value of 350-850 mgKOH/g and a crosslinking agent that contains at least one alkanol amine. The ratio of the total mole number of hydroxy groups, amino groups and imino groups in the crosslinking agent relative to the mole number of carboxyl groups in the acrylic resin is 0.8-1.5. The pH of the aqueous binder is adjusted to 5.0-8.0 by a basic compound.
    Type: Grant
    Filed: December 7, 2012
    Date of Patent: December 10, 2013
    Assignee: Asahi Fiber Glass Company, Limited
    Inventors: Atsushi Matsuo, Takuya Sakoda
  • Patent number: 8519021
    Abstract: An ink set for ink jet recording containing an ink composition containing a pigment, polymer particles, a water-soluble organic solvent, a lubricant, and water and a reaction liquid that forms an aggregate by contacting with the ink composition and an ink jet recording method using the same are provided.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: August 27, 2013
    Assignee: FUJIFILM Corporation
    Inventor: Tomoyuki Ohzeki
  • Publication number: 20130115379
    Abstract: A waterborne base coat having a special-effect color and which contains aqueous microgel as binder, 0.5 to 2 wt.-% of poly(meth)acrylic acid thickener and 2 to 7 wt.-% of non-ionically emulsified EVA copolymer wax with a drop point of the wax portion of 80 to 110° C., the wt.-% in each case calculated as solids and relative to the solids content of the waterborne base coat.
    Type: Application
    Filed: July 25, 2011
    Publication date: May 9, 2013
    Inventors: Frank Tessari, Ralf Wilhelms
  • Publication number: 20130084403
    Abstract: A waterborne base coat having a light metallic color and containing 0.5 to 2 wt.-% of poly(meth)acrylic acid thickener and 2 to 7 wt.-% of non-ionically emulsified EVA copolymer wax with a drop point of the wax portion of 80 to 110° C., the wt.-% in each case calculated as solids and relative to the solids content of the waterborne base coat.
    Type: Application
    Filed: July 25, 2011
    Publication date: April 4, 2013
    Applicant: E.I DUPONT DE NEMOURS AND COMPANY
    Inventors: Frank Tessari, Ralf Wilhelms
  • Publication number: 20130035430
    Abstract: The present invention relates to a coating composition, especially, relates to an aqueous coating composition with improved liquid stain repellency, it has a fraction of critical pigment volume concentration of from 35% to 110%, and comprises (i) pigment composition, including 15 wt. %-100 wt. %, in percentage by weight based on the dry weight of the pigment composition, polymer-encapsulated pigment; and 0-85 wt. %, in percentage by weight based on the dry weight of the pigment composition, un-encapsulated pigment; and (ii) 0.01 wt. %-5 wt. %, in percentage by dry weight based on the wet weight of the aqueous coating composition, at least one paraffin wax emulsion.
    Type: Application
    Filed: August 2, 2012
    Publication date: February 7, 2013
    Inventors: Juan LI, Tao WANG, Tao WANG, David G. SPECECE, JR.
  • Patent number: 8343634
    Abstract: Composite panels may be prepared using a moisture resistance additive having a formulation that includes a triglyceride having a saponification value of at least 150 and an iodine value of at least 35. The additive may be used in the form of a water emulsion. The water emulsion may be prepared by dispersing the components of the additive formulation under conditions sufficient to at least partially saponify the triglyceride. The moisture resistance additive can impart resistance to moisture absorption and thickness swelling to composite panels prepared therewith.
    Type: Grant
    Filed: January 14, 2010
    Date of Patent: January 1, 2013
    Assignee: Momentive Specialty Chemicals Inc.
    Inventors: Steven J. Wantling, Harden Christopher Wren, Jason L. Holder
  • Patent number: 8329785
    Abstract: A wall repair compound useful for filling and repairing cracks, holes, and other imperfections in a wall surface includes a conventional filler material, a conventional binder material, and a dust reducing additive which reduces the quantity of airborne dust particles generated when sanding the hardened joint compound. Airborne dust reducing additives include oils, surfactants, solvents, waxes, and other petroleum derivatives. The additive can be added to conventional ready-mixed joint compounds and to setting type joint compounds. A method of reducing the quantity of airborne dust generated when sanding a fully hardened joint compound includes mixing a sufficient quantity of the dust reducing additive with the joint compound prior to when the joint compound has been applied to the wall.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: December 11, 2012
    Assignee: 3M Innovative Properties Company
    Inventor: Nathaniel P. Langford
  • Patent number: 8309647
    Abstract: Spherical particles having a mean diameter in the range from 1 to 20 ?m, comprising (a) from 85 to 99% by weight of a crosslinked random copolymer having a glass transition temperature Tg in the range from ?75 to ?40° C. (b) and from 1 to 15% by weight of at least one organic substance selected from waxes, protective colloids and plasticizers.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: November 13, 2012
    Assignee: BASF SE
    Inventors: Cedric du Fresne von Hohenesche, Stefan Adams, Klaus Dieter Hörner, Dominik Winter
  • Publication number: 20120212536
    Abstract: An ink composition is disclosed which includes carbon black; at least one selected from the group consisting of a cyan pigment and a magenta pigment; at least one selected from the group consisting of polyvinyl pyrrolidone, polyvinyl alcohol, and polyethylene glycol, at a ratio of 0.01% by mass or higher but lower than 1.00% by mass, relative to the total amount of the composition; water-insoluble or substantially water-insoluble resin particles, water-insoluble or substantially water-insoluble wax particles or any mixture thereof; and water. An ink set and an image forming method are also disclosed.
    Type: Application
    Filed: January 27, 2012
    Publication date: August 23, 2012
    Applicant: FUJIFILM CORPORATION
    Inventors: Ryo SAITO, Yasufumi OOISHI
  • Patent number: 8173733
    Abstract: A polyolefin wax-containing aqueous resin composition that can provide excellent properties without the use of a surfactant is provided. The aqueous resin composition is obtained by heating and dissolving 100 parts by mass of a carboxyl group-containing polyolefin wax in the presence of 15 to 67 parts by mass of a compound that satisfies formula (1) shown below, and 90 to 380 parts by mass of water, and then dispersing this with a basic compound that has been added at a ratio of 1 to 4 chemical equivalents per carboxyl group of the carboxyl group-containing polyolefin wax. CmH2m+1—(OCH2CH2)n—OH Formula (1) m: an integer from 4 to 6, n: an integer from 1 to 4.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: May 8, 2012
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventor: Kenji Kashihara
  • Patent number: 8138250
    Abstract: Waxes prepared from hydrogenated plant oils, such as castor and soybean, are formulated into aqueous ink and paper coating compositions. Ink compositions comprising these waxes and evaluated for their resistance to mar and abrasion achieved rub resistance and slip performance comparable to compositions utilizing conventional wax additives, which are generally derived from petroleum. The waxes in the inventive compositions have a low iodine value (ranging from approximately 2 to approximately 5), and a melting point between approximately 120 degrees to approximately 190 degrees F. (Mettler Drop Point). These naturally derived waxes are used as an alternative to petroleum and synthetically derived waxes in the manufacture of inks and coatings for paper and cellulosic products.
    Type: Grant
    Filed: October 26, 2004
    Date of Patent: March 20, 2012
    Assignee: H R D Corporation
    Inventors: Aziz Hassan, Gregory Borsinger
  • Patent number: 8076006
    Abstract: Composite panels may be prepared using a moisture resistance additive having a formulation that includes a triglyceride having a saponification value of at least 150 and an iodine value of at least 35. The additive may be used in the form of a water emulsion. The water emulsion may be prepared by dispersing the components of the additive formulation under conditions sufficient to at least partially saponify the triglyceride. The moisture resistance additive can impart resistance to moisture absorption and thickness swelling to composite panels prepared therewith.
    Type: Grant
    Filed: January 27, 2009
    Date of Patent: December 13, 2011
    Assignee: Momentive Specialty Chemicals Inc.
    Inventor: Steven J. Wantling
  • Patent number: 8044129
    Abstract: Provided is an aqueous binder for inorganic fibers, which is formaldehyde-free, has excellent strength, and is suitable for use under conditions of weakly acidic to weakly basic, and by which a cured product composed of the binder having excellent strength is obtained, and an thermal and/or acoustical insulation material made of inorganic fiber using the same. The thermal and/or acoustical insulation material is molded by using an aqueous binder for inorganic fibers including: an acrylic resin with an acid value of 350 to 850 mgKOH/g; a crosslinking agent containing at least one dialkanolamine; and a curing accelerator, in which a molar ratio of the total number of the hydroxyl groups and imino groups in the crosslinking agent to the total number of carboxyl groups in the acrylic resin is 0.8:1 to 1.5:1, and in which pH of the binder is adjusted to 6.0 to 8.0 with a volatile basic compound.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: October 25, 2011
    Assignee: Asahi Fiber Glass Company, Limited
    Inventors: Akira Inoue, Yuka Akiyama
  • Patent number: 7875665
    Abstract: Polymer particles of ultrahigh molecular weight poly(alpha-olefins) may be made stable toward agglomeration by suspension within a co-suspension of self-dispersing waxes. This combination prevents polymer agglomeration over time while maintaining good flowability properties. Such materials, ultimately used as pipeline additives to reduce the fluid drag and increase the volumetric throughput, may be shipped and stored for extended periods of time without irreversible loss of the suspension stability.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: January 25, 2011
    Assignee: Baker Hughes Incorporated
    Inventors: Thomas J. Martin, William P. Cottom
  • Publication number: 20090194450
    Abstract: Novel coated substrates are disclosed wherein a substrate is coated with a coating composition that forms good hermetic seals at very low temperatures and exhibits good blocking and slip characteristics. Such coating composition is comprised of an aqueous dispersion of a substantially non-polar copolymer of ethylene and an alpha-olefin having less than 20 carbon atoms, and an additive selected from the group consisting of an anti-blocking and slip agent, a coalescent and wetting agent, and mixtures thereof.
    Type: Application
    Filed: February 1, 2008
    Publication date: August 6, 2009
    Inventors: Thierry Jean-Luc Dabadie, Bruno R. Gringoire, Pang-Chia Lu, Jean-Pierre Frognet, Brad M. Moncla, Matthew J. Kalinowski
  • Patent number: 7407996
    Abstract: A wall repair compound useful for filling and repairing cracks, holes, and other imperfections in a wall surface includes a conventional filler material, a conventional binder material, and a dust reducing additive which reduces the quantity of airborne dust particles generated when sanding the hardened joint compound. Airborne dust reducing additives include oils, surfactants, solvents, waxes, and other petroleum derivatives. The additive can be added to conventional ready-mixed joint compounds and to setting type joint compounds. A method of reducing the quantity of airborne dust generated when sanding a fully hardened joint compound includes mixing a sufficient quantity of the dust reducing additive with the joint compound prior to when the joint compound has been applied to the wall.
    Type: Grant
    Filed: February 17, 2006
    Date of Patent: August 5, 2008
    Assignee: 3M Innovative Properties Company
    Inventor: Nathaniel P. Langford
  • Patent number: 7388046
    Abstract: Polymer particles of ultrahigh molecular weight poly(alpha-olefins) may be made stable toward agglomeration by suspension within a co-suspension of self-dispersing waxes. This combination prevents polymer agglomeration over time while maintaining good flowability properties. Such materials, ultimately used as pipeline additives to reduce the fluid drag and increase the volumetric throughput, may be shipped and stored for extended periods of time without irreversible loss of the suspension stability.
    Type: Grant
    Filed: April 19, 2006
    Date of Patent: June 17, 2008
    Assignee: Baker Hughes Incorporated
    Inventors: Thomas J. Martin, William P. Cottom
  • Patent number: 7282273
    Abstract: A method of improving grease and/or water resistance of a material is disclosed that comprises treating the material with wax and poly(vinyl alcohol) and optionally with a polyamine. Compositions for practicing the method and materials that have been treated by the method are also disclosed.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: October 16, 2007
    Assignee: Polymer Ventures, Inc.
    Inventors: Christopher B. Murphy, Jon O. Fabri
  • Patent number: 7256224
    Abstract: A method for producing a stabilized polymer drag reducing agent slurry comprising combining a fatty acid wax and a liquid carrier to form a dispersion; pre-treating the dispersion by heating to partially dissolve the fatty acid wax in the liquid carrier; and adding the polymer drag reducing agent thereto, to form a stabilized polymer drag reducing agent slurry. The resulting slurry is relatively stable against settling, separation and agglomeration.
    Type: Grant
    Filed: September 21, 2005
    Date of Patent: August 14, 2007
    Assignee: Baker Hughes Incorporated
    Inventors: Thomas J. Martin, Lu Chien Chou
  • Patent number: 7163972
    Abstract: The present invention provide methods for producing a low moisture organophyllosilicate composition using monomers, oligomers, or polymers to displace water associated with the organophyllosilicates in an aqueous organophyllosilicate slurry or filter cake. The invention additionally provides methods for producing organophyllosilicate nanocomposites from the concentrated organophyllosilicate compositions by dispersing the compositions in a polymer matrix.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: January 16, 2007
    Assignee: UChicago Argonne, LLC
    Inventors: David J. Chaiko, Suhas G. Niyogi
  • Patent number: 7148271
    Abstract: A water-borne resin composition which can be readily applied to treat fibrous substrates at ambient temperatures and which provides enhanced strength and rigidity for the substrate under both ambient as well as wet or humid conditions is provided. Preferably, paper substrates treated with the resin are capable of being repulped and recycled.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: December 12, 2006
    Assignee: Michelman, Inc.
    Inventors: Richard I. Michelman, Scot E. Duckworth
  • Patent number: 7094829
    Abstract: A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: August 22, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Frans A. Audenaert, Rudolf J. Dams, Richard S. Buckanin
  • Patent number: 7091268
    Abstract: The present invention provides the use of a mineral oil in a fluoroelastomer composition comprising a fluoroelastomer to improve the flow of said composition during processing to form an article therefrom and/or to improve the release from a mold of a vulcanized article produced from said fluoroelastomer composition. Further provide are a fluoroelastomer composition that includes a mineral oil, a method of making an article therewith and a method of preparing the fluoroelastomer composition.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: August 15, 2006
    Assignee: 3M Innovative Properties Company
    Inventor: Steven G. Corveleyn
  • Patent number: 6903151
    Abstract: A wet-stick pressure-sensitive adhesive is provided wherein the pressure-sensitive adhesive comprises: at least one copolymerized monoethylenically unsaturated (meth)acrylic acid ester monomer, wherein the (meth)acrylic acid ester monomer, when homopolymerized, has a Tg of less than about 10° C.; at least one copolymerized hydrophilic acidic comonomer; and at least one nonreactive copolymer comprising at least two copolymerized alkylene oxides, at least one of which is hydrophobic and at least one of which is hydrophilic.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: June 7, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: Donald H. Lucast, Dong-Wei Zhu
  • Patent number: 6890976
    Abstract: An aqueous emulsion for imparting water repellency characteristics to gypsum products comprising: a) a hydrocarbon wax: b) a polyolefin-maleic anhydride graft polymer; and c) a polyvinyl alcohol composition comprising partially and/or fully hydrolyzed polyvinyl acetate. The emulsion may also contain other known ancillary components such as emulsifiers and stabilizers.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: May 10, 2005
    Assignee: Walker Industries Holdings Limited
    Inventor: Laurence Anthony Sinnige
  • Patent number: 6818597
    Abstract: Liquid water soluble polymer suspensions in non-aqueous solvents are extremely stable over long periods of time with minimum separation of the solvent and no hard packing of the dispersed water soluble polymer. The suspensions enable a user to rapidly add the suspension to water, being mixed at low speeds, without the formation of lumps or fisheyes and without generating fugitive dust in the process. The suspensions are environmentally safe and biodegradable. Unlike many other liquid polymer suspensions, the suspensions exhibit minimal oil or grease upon dilution. They contain no surfactants that can add to the oil and grease determination. The suspensions and the fluids produced by diluting the fluids to a working concentration of the water soluble polymer exhibit low toxicity to marine organisms and to humans. The suspensions can be manufactured from ingredients suitable for use in personal care applications such as cosmetics, shampoos and the like.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: November 16, 2004
    Assignee: Benchmark Research & Technology, Inc.
    Inventor: William Franklin Harris
  • Patent number: 6770687
    Abstract: A water-based security printing ink is provided with two means of security. The use of a variable light absorbing and/or transmitting pigment or dye is a first security and a water repelling agent is provided as a second security. Visible images can be generated from the printed ink upon exposure to UV or infrared light. The water repelling agent renders the image waterproof and differentiates the printed image from the substrate, which allows the image to be detected upon exposure to water or other aqueous mixture. Suitable inks can be used in conventional printing methods, such as jet printing, lithography, offset printing and impact printing. Also provided are substrates imaged with these security printing inks.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: August 3, 2004
    Assignee: NCR Corporation
    Inventors: Yaoping Tan, Maurice W. Lewis
  • Patent number: 6743844
    Abstract: An aqueous dispersed polymeric composition for preparing the spill resistant carpet backing is provided. The aqueous dispersed polymeric composition of the present invention comprises an aqueous dispersed polymeric material, an inorganic filler, and a hydrophobic compound selected from the group consisting of a hydrophobic acid, a salt of a hydrophobic acid, and mixtures thereof. Alternatively, the inorganic filler is pretreated with the hydrophobic compound. Also, a kit and a method for preparing a spill resistant carpet backing from the aqueous dispersed polymeric composition is provided.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: June 1, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Rick L. Tabor, Rhonda R. Suarez, Randall C. Jenkines
  • Patent number: 6734228
    Abstract: A thermosetting water-based resin composition comprising an oil-soluble initiator of which a temperature for one-minute half-life is from 90° to 270 ° C. and a polycondensation resin comprising an unsaturated dicarboxylic acid having a radical-polymerizable unsaturated bond or an acid anhydride thereof as at least one constituent monomer, wherein the polycondensation resin has an acid value of from 3 to 100 mg KOH/g, and wherein said oil-soluble initiator is present in said polycondensation resin; a process for preparing the thermosetting water-based resin composition; a molding compound composition comprising the water-based resin composition; and a molding product prepared by molding the molding compound composition.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: May 11, 2004
    Assignee: Kao Corporation
    Inventors: Tadashi Sakuma, Kuniyasu Kawabe
  • Patent number: 6683131
    Abstract: A water-based liquid treatment composition for metal surfaces comprises water, (A) dissolved, dispersed, or both dissolved and dispersed urethane resin, acrylic resin; or both urethane and acrylic resins; (B) dissolved, dispersed, or both dissolved and dispersed curing agent molecules; (C) dispersed silica powder; (D) dispersed oxidized polyethylene wax with an average particle size of 0.01 to 0.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: January 27, 2004
    Inventors: Yasuhiro Kinoshita, Keiichi Ueno, Takashi Koyama
  • Patent number: 6617421
    Abstract: The present invention is a method of producing substantially dry water insoluble polymers from poly alkyl esters of vinylic monomers for use in a method for the clarification of red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite ore. The polymers can be either homopolymers, copolymers or terpolymers. Preferably, the dried emulsion polymers are high molecular weight polymers of poly(methyl acrylate), poly(methyl acrylate/acrylic acid), poly(vinyl acetate/acrylic acid/methyl acrylate), poly(t-butyl methacrylate/acrylic acid/methyl acrylate) and poly(t-butyl acrylate/acrylic acid/methyl acrylate).
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: September 9, 2003
    Assignee: Ondeo Nalco Company
    Inventors: Everett C. Phillips, Ronald J. Allain
  • Patent number: 6586510
    Abstract: Improved, removable PSA compositions and constructions contain an emulsion acrylic PSA copolymer of a plurality of acrylic monomers and at least one multifunctional crosslinking monomer, compounded with a wax and a plasticizer. Peel forces required to remove the constructions from a variety of substrates are notably smaller than those required to remove comparable compositions containing no crosslinking monomer.
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: July 1, 2003
    Assignee: Avery Dennison Corporation
    Inventors: Ian Brown, Graham Yeadon
  • Patent number: 6518334
    Abstract: This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: February 11, 2003
    Assignee: JohnsonDiversey, Inc.
    Inventors: Glenn C. Calhoun, Michael T. Sarkis
  • Patent number: 6518343
    Abstract: A wet-stick pressure-sensitive adhesive is provided wherein the pressure-sensitive adhesive comprises: at least one copolymerized monoethylenically unsaturated (meth)acrylic acid ester monomer, wherein the (meth)acrylic acid ester monomer, when homopolymerized, has a Tg of less than about 10° C.; at least one copolymerized hydrophilic acidic comonomer; and at least one nonreactive copolymer comprising at least two copolymerized alkylene oxides, at least one of which is hydrophobic and at least one of which is hydrophilic.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: February 11, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Donald H. Lucast, Dong-Wei Zhu
  • Patent number: 6461549
    Abstract: A method of producing a biodegradable product. which is intended, for instance, for only temporarily containing foodstuffs, or of producing objects such as a container for snacks, a beaker for hot or cold,drinks, etc., which product is. manufactured under pressure and heat in a mold from a basic material. The method is characterized in that the composition of the basic material consists of a moist granulate consisting of 50-250 parts by weight amylose-comprising flour derived from an edible crop plant, 10-85 parts by weight wood flour, 2-30 parts by weight natural wax and 50-250 parts by weight water and optionally a natural colorant as an additive.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: October 8, 2002
    Assignee: Potatopak Limited
    Inventor: Marinus Comelis Meeuwsen
  • Patent number: 6433116
    Abstract: A novel polymer having the moiety: wherein R is an alkyl group containing 1-5 carbon atoms or an aryl, substituted aryl, substituted or unsubstituted heteroaryl, alkyl-aryl, alkylether-aryl or O; R1 and R2 are hydrogen or a methyl group; X is O, NH, NR′ wherein R′ is an alkyl group containing 1-5 carbon atoms, or O—R″ or NR″ wherein O—R″ is O-alkyl-O or O-alkyl, NR″ is O-alkyl-ONH, wherein each instance alkyl contains 1-5 carbon atoms and n is 0 or 1. The compound of this invention is useful as a monomer which can be polymerized and/or copolymerized by catonic polymerization. Polymers and copolymers produced in this invention can be crosslinked and are useful in coatings, inks, overprint varnishes, and surface treatment applications.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: August 13, 2002
    Assignee: S. C. Johnson Commercial Markets, Inc.
    Inventors: Bill M. Culbertson, David L. Trumbo
  • Patent number: 6407160
    Abstract: The present invention relates to a polymer particle having a wax phase and a second phase. The wax phase includes a wax having a melting point of greater than 30° C. and comprising greater than 80% by weight of the wax phase. The second phase, free of ionic charge groups, includes a mono-alpha, beta-ethylenically unsaturated monomer free of ionic charge groups capable of addition polymerization to form a water soluble homopolymer including from 1 to 40% by weight of the second phase and a mono-alpha, beta-ethylenically unsaturated monomer capable of addition polymerization to form a water insoluble homopolymer.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: June 18, 2002
    Assignee: Eastman Kodak Company
    Inventors: Yongcai Wang, James L. Bello, Janglin Chen, Dwight W. Schwark
  • Patent number: 6384120
    Abstract: A synthetic resin film for agriculture suited as a covering material for greenhouses or the like, which shows good anti-clouding and anti-fogging properties immediately after being spread and for longer period than 2 years. The synthetic resin film for agriculture is obtained by using (a) an ester of sorbitan with a higher fatty acid mainly containing 24 to 34 carbon atoms (montanic acid wax), an ester of glycerin with montanic acid wax and/or alkylene oxide adducts thereto and/or an ester of polyoxyalkylene with montanic acid wax as an anti-clouding agent, and (b) a fluorine-containing surfactant as an anti-fogging agent, kneading them with a film-forming resin such as vinyl chloride resin, polyethylene, ethylene/vinyl acetate copolymer, and forming it into a film.
    Type: Grant
    Filed: September 14, 1999
    Date of Patent: May 7, 2002
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Takuya Hoga, Hiroshi Ohsawa, Masaki Nakamura
  • Patent number: 6372882
    Abstract: The present invention is a method of producing substantially dry water insoluble polymers from poly alkyl esters of vinylic monomers for use in a method for the clarification of red mud-containing liquors generated in the Bayer process for the recovery of alumina from bauxite ore. The polymers can be either homopolymers, copolymers or terpolymers. Preferably, the dried emulsion polymers are high molecular weight polymers of poly(methyl acrylate), poly(methyl acrylate/acrylic acid), poly(vinyl acetate/acrylic acid/methyl acrylate), poly(t-butyl methacrylate/acrylic acid/methyl acrylate) and poly(t-butyl acrylate/acrylic acid/methyl acrylate).
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: April 16, 2002
    Assignee: Nalco Chemical Company
    Inventors: Everett C. Phillips, Ronald J. Allain
  • Patent number: 6323268
    Abstract: A composition for rendering surfaces water repellent is formed by combining water or a solvent; a methylhydrogensiloxane polymer or copolymer; an alkoxysilane having the formula RaSi(OR′)4-a in which R represents an alkyl group containing 1-10 carbon atoms, an alkenyl group containing 2-8 carbon atoms, an aryl group, or an haloalkyl group, a has a value of 1 or 2, and R′ represents an alkyl group containing 1-6 carbon atoms; and a silicone resin. The composition can also contain other components such as a volatile methyl siloxane, a cationic oil-in-water emulsion of an aminofunctional polydimethylsiloxane, a surfactant, a catalyst, a beading agent, an organic wax, a preservative, an antifoam, a mildewcide, an UV absorber/UV light stabilizer, or a freeze-thaw additive.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: November 27, 2001
    Assignee: Dow Corning Corporation
    Inventors: Paul David Fisher, Feifei Lin, Lori Ann Stark-Kasley
  • Patent number: 6300398
    Abstract: The subject invention is directed to polymer compositions which comprise a homogeneous ethylene/&agr;-olefin interpolymer, a wax and a nucleating agent, wherein the nucleating agent is provided in an effective amount such that the percent elongation at break of the polymer composition is at least about fifty percent greater than the percent elongation at break of a comparative composition which lacks the nucleating agent. The polymer compositions of the invention will find utility in applications r equiring high elongation at break, while maintaining a high onset of crystallization temperature, such as in the high-speed coating of fabrics, carpet backing, floor tile and sheeting, and adhesives.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: October 9, 2001
    Assignee: The Dow Chemical Company
    Inventors: Gary Lee Jialanella, Thomas J. McKeand, Jr., Kalyan Sehanobish
  • Patent number: 6275816
    Abstract: A aqueous ink for a ball-point pen which is stable over time and has high pigment dispersion stability, includes a pigment, a water-soluble organic solvent, water, xanthane gum of about 0.01 to about 0.2 wt. % and a sodium alginate of about 0.2 to about 0.6 wt. % of a total amount of the ink.
    Type: Grant
    Filed: August 26, 1999
    Date of Patent: August 14, 2001
    Assignee: Kotobuki & Co., LTD
    Inventors: Katsuya Hattori, Akio Nakamura, Mikio Morishita
  • Patent number: 6228926
    Abstract: A coating composition comprising a colloid of a thermoplastic, elastomeric polyurethane and a wax dispersible in water is applied to the surface of a substrate, drying rapidly to form a tough, durable, protective film bonded firmly to the surface.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: May 8, 2001
    Inventor: Harvey J. Golumbic
  • Patent number: 6132503
    Abstract: Process for the production of sheets or molded bodies from lignocellulosic materials utilizing an organic polyisocyanate binder material and a release agent which is an aqueous emulsion of a polyolefin wax.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: October 17, 2000
    Inventors: Bart Singule, James Anthony Yavorsky
  • Patent number: 6028133
    Abstract: A phenolic resin modified with an alkali salt of sulfite or bisulfite in order to provide compatibility with a wax emulsion sizing agent, an adhesive prepared from the phenolic resin and wax emulsion, and the use of the adhesive in making bonded composites such as wood products, including, parallel strand lumber, oriented strand board (OSB), laminated veneer lumber (LVL), medium density fiberboard, wafer board and particle board, and textile products.
    Type: Grant
    Filed: March 20, 1998
    Date of Patent: February 22, 2000
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Brian M. Peek, Barry W. Sewell