Halogen Patents (Class 524/373)
  • Patent number: 10968338
    Abstract: The present disclosure provides a composition. The composition includes a silanol functionalized polyolefin; an anhydride-free brominated flame retardant; antimony trioxide; and the composition has an antimony (Sb) to bromine (Br) molar ratio (Sb:Br molar ratio) from 0.37 to 1.05. The present disclosure also provides a coated conductor. The coated conductor includes a conductor and a coating on the conductor, the coating including a composition. The composition includes a silanol functionalized polyolefin; an anhydride-free brominated flame retardant; antimony trioxide; and the composition has an antimony (Sb) to bromine (Br) molar ratio (Sb:Br molar ratio) from 0.37 to 1.05.
    Type: Grant
    Filed: September 8, 2017
    Date of Patent: April 6, 2021
    Assignee: Dow Global Technologies LLC
    Inventors: Manish Mundra, Bharat I. Chaudhary, Abhijit Ghosh-Dastidar, Peter C. Dreux
  • Patent number: 9587084
    Abstract: Silane-grafted polyolefin composition comprising a brominated, flame retardant additive is prepared by a process comprising the step of contacting within a reaction-extrusion zone operated at grafting conditions: A. A polyolefin, B. A hydrolysable unsaturated silane, C. A free radical generator, and D. Halogenated polyaryl alkane, e.g., decabromodiphenyl ethane, such that at least a portion of the hydrolysable unsaturated silane is grafted to the polyolefin. The silane-grafted polyolefin is crosslinked after extrusion from the zone, typically as a wire and cable coating, upon exposure to moisture.
    Type: Grant
    Filed: June 8, 2015
    Date of Patent: March 7, 2017
    Assignee: Union Carbide Chemicals & Plastics Technology LLC
    Inventor: Michael B. Biscoglio
  • Patent number: 8952083
    Abstract: To provide a composition comprising a fluorocopolymer such as an ethylene/tetrafluoroethylene copolymer which can be produced at a relatively low temperature, and its production process. A fluorocopolymer composition which comprises a fluorocopolymer such as an ethylene/tetrafluoroethylene copolymer and a fluorinated aromatic compound having a melting point of at most 230° C. and having a fluorine content in the compound of from 5 to 75 mass %, and is in a solution state at a temperature of at most the melting point of the fluorocopolymer, and a process for producing the fluorocopolymer composition, which comprises a step of dissolving the fluorocopolymer in a solvent containing the fluorinated aromatic compound at a temperature of at most the melting point of the fluorocopolymer.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: February 10, 2015
    Assignee: Asahi Glass Company, Limited
    Inventors: Takashi Nakano, Tomoyuki Fujita, Yoshitomi Morizawa
  • Publication number: 20140031474
    Abstract: To provide an electric cable that can satisfy flame retardancy and battery fluid resistance in the CHFUS region provided in ISO 6722 and also satisfy low-temperature resistance, wear resistance, and peelability by using a halogen-containing flame retardant. An electric cable in which a coat layer is formed of a non-crosslinked resin composition that includes (A) 40 to 84 parts by mass of a polypropylene homopolymer, (B) 1 to 10 parts by mass of a polypropylene-based modified resin, (C) 10 to 30 parts by mass of a polyolefin-based copolymer, and (D) 5 to 20 parts by mass of an olefin-based elastomer and further includes 1 to 45 parts by mass of a metal hydroxide and 10 to 80 parts by mass of a halogen-containing flame retardant based on 100 parts by mass of the resins (A), (B), (C), and (D) in total.
    Type: Application
    Filed: February 24, 2012
    Publication date: January 30, 2014
    Inventor: Kousuke Kogo
  • Patent number: 8513339
    Abstract: Disclosed are sulfur-containing polymers containing copolymerizable adhesion promoters and compositions including sealant compositions useful in aerospace applications comprising sulfur-containing polymers containing copolymerizable adhesion promoters. In particular, polythioethers and polysulfides incorporating copolymerizable adhesion promoters are disclosed.
    Type: Grant
    Filed: June 21, 2012
    Date of Patent: August 20, 2013
    Assignee: PRC-DeSoto International, Inc.
    Inventors: Raquel Keledjian, Renhe Lin, Bruce Vimelson
  • Patent number: 8063141
    Abstract: An adhesive composition is provided for adhering together roofing materials such as EPDM rubber and thermoplastic polyolefin (TPO). The adhesive composition includes a rubbery polymer comprising a blend of a thermoplastic block copolymer selected from the group consisting styrene-butadiene-styrene, styrene-isoprene-styrene, styrene-ethylene-butylene-styrene, styrene-ethylene-propylene-styrene, styrene-ethylene-propylene, ethylene-propylene, and combinations thereof, and a paraffinic hydrocarbon polymer. Roofing articles incorporating the adhesive composition are also provided. The composition is a pressure sensitive adhesive that allows roofing articles to be applied in a peel and stick manner.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: November 22, 2011
    Assignee: ADCO Products, Inc.
    Inventor: Dennis K. Fisher
  • Patent number: 6924331
    Abstract: A flame retarded polyolefin resin composition comprises polyolefin resin, 1 to 40 parts by weight per 100 parts of the polyolefin resin of a brominated bisphenol ether derivative of the formula: wherein R is hydrogen or methyl, and A is —C(CH3)2—, —SO2—, —S—, or —CH2—; and 1 to 30 parts by weight per 100 parts of the polyolefin resin of 2,4,6-tris(mono-, di- or tribromophenoxy)triazine.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: August 2, 2005
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Makoto Teramoto, Hideaki Onishi
  • Patent number: 6919391
    Abstract: A flame retarded polyolefin resin composition comprises polyolefin resin, 1 to 40 parts by weight per 100 parts of the polyolefin resin of a brominated bisphenol ether derivative of the formula 1: wherein R is hydrogen or methyl, and A is —C(CH3)2—, —SO2—, —S—, or —CH2—; and 1 to 30 parts by weight per 100 parts of the polyolefin resin of a compound of the formula 2. wherein B is mono-, di- or tribromophenyl group, n is an integer from 1 to 20, and A is as defined above.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: July 19, 2005
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Makoto Teramoto, Hideaki Onishi
  • Patent number: 6780348
    Abstract: Thermally stable flame retardant additive compositions comprise a mixture of (1) a polybromodiphenylalkane and/or a polybromodiphenyl oxide, (2) a tetrabromobisphenol-A-bis(bromoalkyl ether), and preferably (3) a synthetic zeolite and/or hydrotalcite in specified proportions. Such additives are useful in thermoplastic polymers, such as homopolymers and copolymers of vinylaromatic monomers, and polyolefin polymers, especially impact or rubber-modified polystyrenes, and most especially HIPS.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: August 24, 2004
    Assignee: Albemarle Corporation
    Inventors: Manon Loos, Susan D. Landry, Dominique Fasbinder
  • Publication number: 20030139507
    Abstract: A flame retarded polyolefin resin composition comprises polyolefin resin, 1 to 40 parts by weight per 100 parts of the polyolefin resin of a brominated bisphenol ether derivative of the formula: 1
    Type: Application
    Filed: November 18, 2002
    Publication date: July 24, 2003
    Inventors: Makoto Teramoto, Hideaki Onishi
  • Publication number: 20030139508
    Abstract: A flame retarded polyolefin resin composition comprises polyolefin resin, 1 to 40 parts by weight per 100 parts of the polyolefin resin of a brominated bisphenol ether derivative of the formula 1: 1
    Type: Application
    Filed: November 18, 2002
    Publication date: July 24, 2003
    Inventors: Makoto Teramoto, Hideaki Onishi
  • Patent number: 6596798
    Abstract: The present invention provides a method of forming a functionalized polymer. The method includes the steps of providing a living lithium polymer and terminating the polymer with an oxazoline compound selected from an organic halide oxazoline and a branched or unbranched vinyl oxazoline compound. The present invention also provides a compounded rubber article wherein carbon black is compounded with a terminated rubber that is the reaction product of a living lithium polymer and such oxazoline compounds.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: July 22, 2003
    Assignee: Bridgestone Corporation
    Inventors: Christine M. Rademacher, William L. Hergenrother, Daniel F. Graves, James D. Ulmer
  • Patent number: 6518344
    Abstract: The present invention provides a new and improved flame retarded polyolefin composition that displays good retained physical properties upon aging. The composition also exhibits excellent moldability and it may be easily colored. In a preferred embodiment the composition includes a polyolefin, a halogen-containing flame retardant additive, from at least about 1.00% by weight to about 2.5% by weight of a stabilizer package, and from about 0% to about 1.0% by weight of an acid/halogen scavenger. The stabilizer package includes by weight from about 20% to about 80% of a hindered phenolic antioxidant, from about 20% to about 80% of a phosphite containing antioxidant, and from about 0% to about 40% of a thio-ester antioxidant. In addition to displaying excellent color and physical property development and retention characteristics, the composition of the present invention displays an improved UL94 vertical burn rating.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: February 11, 2003
    Assignee: Ferro Corporation
    Inventors: Deenadayalu Chundury, Ann Mendel, Howard E. Munro, Roy C. Sanford
  • Patent number: 6344509
    Abstract: The present invention relates to a thermoplastic resin composition characterized by comprising (A) a thermoplastic resin, (B) an inorganic filler and/or organic filler, and (C) a polyhydroxy alcohol ester of condensed hydroxyfatty acid and/or (C′) a condensed hydroxyfatty acid having a degree of condensation exceeding 3.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: February 5, 2002
    Assignee: Taiyo Kagaku Co., Ltd.
    Inventor: Yoshinobu Mizutani
  • Patent number: 6197864
    Abstract: Improved flame retardant compositions suitable for insulating wire and cable products comprised of ethylene-alkoxy silane copolymer, halogenated organic compound, antimony trioxide, silane condensation catalyst and magnesium hydroxide are provided. Additionally, antioxidant(s), other mineral fillers and other conventional compounding ingredients may be included in the formulations. The compositions have good processability and are capable of being cured under ambient conditions to provide products which meet all of the specifications of SAE J-1128 for thin wall crosslinked polyolefin low tension primary cable insulation. Wire and cable products comprising a metal conductor coated with from 2 to 100 mils of the flame retardant insulation are also disclosed.
    Type: Grant
    Filed: January 25, 1996
    Date of Patent: March 6, 2001
    Assignee: Equistar Chemicals, LP
    Inventors: Jeffrey S. Borke, Koksal Tonyali
  • Patent number: 5883168
    Abstract: A profiled element for use as a wiping strip in a motor vehicle screen wiper is made of rubber or an elastomer, and has a coating formed by applying a solution to the profiled element. The solution comprises a powder of graphite for example, which is dispersed in a resin, and the solution includes a proofing agent for making the coating impermeable.
    Type: Grant
    Filed: June 13, 1997
    Date of Patent: March 16, 1999
    Assignee: Valeo Systemes D'Essuyage
    Inventor: Michel Oulie
  • Patent number: 5837799
    Abstract: A fire-retardant compound including bromine indicated by general formula (1), wherein the end group X and Y are comprised by A or B shown in formula (2), and the said fire-retardant compound is a mixture of the composition including 15 to 30% of X=Y=A, the composition including 40 to 60% of X=A and Y=B and the composition including 20 to 35% of X=Y=B, and degree of polymerization n is indicated by an integral number from 0 to 30, and a flame-retarded thermoplastic resin including said fire-retardant compound.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: November 17, 1998
    Assignee: Tohto Kasei Co., Inc.
    Inventors: Toshihiko Chen, Yoshiaki Nakamura, Tetsunori Sato, Yoshiyuki Morikawa
  • Patent number: 5777007
    Abstract: Brominated p-cumylphenol represented by the formula (1) described hereinafter and derivative thereof represented by the formula (2) described hereinabove, process for the preparation of the same, and flame-retardant resin compositions containing the same, are disclosed. Those compounds are useful flame retardant, and can be blended with various thermosetting resins or thermoplastic resins to obtain flame retardant resin compositions.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: July 7, 1998
    Assignee: Tosoh Corporation
    Inventors: Takumi Kagawa, Norihisa Kondo, Noriyuki Kasai, Hideo Sakka
  • Patent number: 5712336
    Abstract: Flameproofed thermoplastic molding materials containA) a thermoplastic polyester,B) decabromodiphenylethane,C) a metal oxide or metal sulfide or metal borate or a mixture thereof,D) an ester of at least one alcohol having at least 3 OH groups and one or more aliphatic mono- or dichaboxylic acids of 5 to 34 carbon atoms and optionally,E) by weight of conventional additives and processing assistants.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: January 27, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Brigitte Gareiss, Manfred Knoll, Christoph Plachetta
  • Patent number: 5681875
    Abstract: A process is provided for making a flame composition. The process involves (a) mechanically dry blending (i) a tetrafluoroethylene polymer, preferably in powder form, and (ii) a first thermoplastic resin, preferably a vinyl aromatic resin to form a preblend composition and (b) admixing the preblend composition with a thermoplastic resin and a flame retardant to form the thermoplastic resin. The process provides enhanced levels of falling dart impact strength in articles molded from the thermoplastic composition.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: October 28, 1997
    Assignee: General Electric Company
    Inventors: Jianing Huang, Fuh-Sheng Fred Chen, Jacobus Johannes Maria Brasser
  • Patent number: 5681879
    Abstract: The disclosure describes a flame-retardant polyester resin composition comprising: (1) 100 parts by weight of a polyester resin which may contain a halogen atom;(2) 0.01 to 5 parts by weight of a polyhydric alcohol having not less than 3 hydroxyl groups in the molecule with a hydroxyl group concentration of 1.0.times.10.sup.-2 to 3.5.times.10.sup.-2 eq/g;(3) 0 to 20 parts by weight of an inorganic flame retarding synergist; and(4) 0 to 50 parts by weight of a halogen-based flame retardant,the halogen content in the composition being 0.1 to 20% by weight.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: October 28, 1997
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masanori Yamamoto, Michio Kawai
  • Patent number: 5674972
    Abstract: This invention relates to polyamide-based formulations flame retarded with synergized brominated flame retardants and having good thermal stability.
    Type: Grant
    Filed: July 27, 1995
    Date of Patent: October 7, 1997
    Assignee: Albemarle Corporation
    Inventors: Luc Van Wabeeke, Daniel De Schryver
  • Patent number: 5569681
    Abstract: Flame-retardant foamed particles of a polyolefin resin, which contain a bis(alkyl ether)tetrabromobisphenol A flame retardant and/or a bis(alkyl ether)tetrabromobisphenol S flame retardant, and a synergist of the flame retardant, are disclosed. The flame retardant has a bromine content of at least 50 wt. %. The alkyl group in the alkyl ether moiety of the flame retardant is any one of ethyl, propyl, bromoethyl and bromopropyl. The synergist of the flame retardant is selected from the group consisting of antimony oxides, metal oxides, boric acid salts and metal hydroxides. An expansion-molded article is obtained by filling the flame-retardant foamed particles into a mold and molding the foamed particles.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: October 29, 1996
    Assignee: JSP Corporation
    Inventors: Hisao Tokoro, Kazuo Tsurugai, Satoru Shioya, Masaharu Oikawa
  • Patent number: 5559172
    Abstract: A flame retardant thermoplastic composition is provided containing a vinyl aromatic resin and a flame retardant. The flame retardant is an oligomeric condensation product of a halogenated aromatic diol and an alkylene dihalide composition which is preferably an admixture of an alkyl monohalide and an alkylene dihalide. The compositions are useful for making molded articles for automotive parts and for business machine housings. The composition exhibit no bloom, good thermal color stability, and good resistance to ultraviolet light.
    Type: Grant
    Filed: May 11, 1995
    Date of Patent: September 24, 1996
    Assignee: General Electric Company
    Inventors: Donald M. Kulich, Thomas B. Cleveland, Enrico J. Termine, Arthur G. Mack
  • Patent number: 5541242
    Abstract: The present invention provides an antistatic and flame retardant thermoplastic resin composition which comprises [A] 100 weight parts of a thermoplastic resin, [B] 2.0 to 40 weight parts of a bromine-containing organic flame retardant, and [C] 1.0 to 30 weight parts of a (meth)acrylamide-based copolymer and/or a (meth)acrylate ester-based copolymer each comprising 65 to 99 mole percent of an olefin-derived structural unit (I), 0 to 15 mole percent of a (meth)acrylate-derived structural unit (II) and 1 to 35 mole percent of a (meth)acrylamide-derived or (meth)acrylate ester-derived structural unit (III), as arranged linearly, with a weight average molecular weight of 1,000 to 50,000.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: July 30, 1996
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Yutaka Nakayama, Hideyuki Sumi, Hiroshi Hotta
  • Patent number: 5539036
    Abstract: A flame retardant thermoplastic composition is provided containing a vinyl aromatic polymer, a brominated flame retardant, and a very low level of tetrafluoroethylene polymer which had been preblended with a lubricant which is either a metal salt or ester of a fatty acid. The composition is useful for making mold parts such as business machine housings.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: July 23, 1996
    Assignee: General Electric Company
    Inventors: Yoke K. Fong, James E. Lamp, Ralph S. Bickle
  • Patent number: 5420183
    Abstract: The invention provides a substantially uniformly blended, flame retardant polypropylene composition and an extruded polypropylene sheet which comprises a polypropylene polymer, the bis(2,3-dibromopropylether) of tetrabromobisphenol A, antimony trioxide, titanium dioxide, calcium sulfate and distearyl pentaerythritol diphosphite. The invention further provides a method for producing such a polypropylene sheet material by forming a substantially uniform physical blend of the above components; drying the blend; heating the blend at a temperature above its melting point to form a melt of the blend components while mixing the melt; and extruding the blend through a sheet forming die and highly polished rollers.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: May 30, 1995
    Assignee: HPG International, Inc.
    Inventors: Arthur A. Arena, Parvin Sawhney
  • Patent number: 5395874
    Abstract: A flame retardant resin composition which includes 100 weight parts of a rubber-reinforced styrene-based resin, 2.about.35 weight parts of an epoxy-oligomer of tetrabromobisphenol-A (A1), 2.about.35 weight parts of bis-(tribromophenoxy)ethane (A2), 1.about.15 weight parts of antimony trioxide (B), and 0.1.about.10 weight parts of chlorinated polyethylene (C), wherein the total of the above (A1), (A2), (B) and (C) are 8.about.50 weight parts and the weight ratio of (A1)/(A2) is 10/90.about.75/25. The composition of the present invention has well-balanced flame retardance and impact resistance.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: March 7, 1995
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Ikuhiro Mishima, Rika Munakata, Mamoru Ishida
  • Patent number: 5382614
    Abstract: Difunctional perfluoropolyetheral compounds having polar or non-polar hydrogenated end groups, suitable for being used as inner lubricants in the chemical formulation of the active layer of magnetic recording media, characterized by a solubility in methylethylketone at 20.degree. C. ranging from 0.05% to 2% by weight.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: January 17, 1995
    Assignee: Ausimont S.p.A.
    Inventors: Mario A. Scarati, Gerardo Caporiccio
  • Patent number: 5306758
    Abstract: Curable, crosslinkable compositions and coatings prepared therefrom that can be used to form low-surface energy liners that can be used with aggressive pressure-sensitive adhesives, such as adhesives formed from silicone resins. The release characteristics of these coatings do not diminish upon aging and do not adversely affect the readhesion properties of adhesives that have-come in contact with the coatings. The invention further provides substrates bearing a layer of the composition of the invention. These coated substrates are particularly suitable for release liners, especially differential release liners and low-adhesion backsizes for pressure-sensitive adhesive tapes and sheet materials, especially for pressure-sensitive adhesives derived from silicone resins.
    Type: Grant
    Filed: May 26, 1993
    Date of Patent: April 26, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Mark J. Pellerite
  • Patent number: 5284889
    Abstract: An electrically insulating film having a total halogen content of about 1% to about 8%, comprising a resin component containing:a) from 0 to about 40 parts of a rubber selected from EP or EPDM rubber,b) correspondingly, from about 60 to about 100 parts of an ethylene vinyl acetate polymer,c) from about 20% to about 40% based on said resin component, of a flame retardant system comprisingi) from about 5 to about 25% of a bromine containing flame retardant,ii) from about 1.5% to about 10% of an antimony containing flame retardant, andiii) from 1% to about 20% of a flame retardant selected from granular metal oxide hydrates, wherein said flame retardant system has a ratio of metal oxide hydrate to bromine of no more than about 3;said film being free of vinyl chloride wherein a nonoriented film self-extinguishes in less than about 5 seconds, has an elongation at break of at least about 500%, a dielectric strength of at least about 1200 V/Mil, and a stress-strain curve having a wholly positive slope.
    Type: Grant
    Filed: November 20, 1992
    Date of Patent: February 8, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Eumi Pyun, Pamela S. Tucker
  • Patent number: 5281639
    Abstract: A flame-retardant thermoplastic resin composition is disclosed, comprising (A) a thermoplastic resin, (B) a halogenated bisphenol type epoxy resin flame-retardant, and (C) an organic phosphite compound. The composition exhibits improved thermal stability to provide molded articles having improved mechanical strength and appearance.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: January 25, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yuji Satoh, Katsuji Takahashi
  • Patent number: 5278215
    Abstract: A flame-retardant synthetic resin composition containing (A) a synthetic resin and (B) a compound having a 3-halogeno-2-hydroxypropyl group, which shows excellent thermal stability during molding and having good light resistance, is disclosed. A flame retardant comprising a compound having a 3-halogeno-2-hydroxypropyl group is also disclosed.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: January 11, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Katsuji Takahashi, Yuji Satoh
  • Patent number: 5258434
    Abstract: A flame-retardant polybutylene terephthalate resin composition, suitable for use as a support structure for an electrical contact includes (A) 100 parts by weight of a polybutylene terephthalate base resin having an intrinsic viscosity of 0.75 to 1.5 dl/g; (B) between 1 to 50 parts by weight of a halogenated phenoxy compound; (C) between 0.1 to 30 parts by weight of an antimony compound containing antimony pentaoxide and an alkali metal oxide; (D) between 0.01 to 10 parts by weight of a fatty acid ester of a polyhydric alcohol, and optionally (E) an inorganic filler.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: November 2, 1993
    Assignee: Polyplastics Co., Ltd.
    Inventor: Kazuhito Hanabusa
  • Patent number: 5250590
    Abstract: A flame retardant resin composition comprising (A) 70 to 10% by weight of a rubber-reinforced styrene base resin, (B) 20 to 85% by weight of a polycarbonate resin, (C) 5 to 35% by weight of a high molecular weight halogen-containing compound of the formula: ##STR1## wherein n is an average polymerization degree and an integer of 4 to 30, R and R' are independently a hydrogen atom, a methyl group, an epoxypropyl group, a phenyl group, a halogenated phenyl group or a group of the formula: wherein m is an integer of 0 to 3, which compound has a bromine content of at least 45% by weight and an epoxy equivalent of at least 10,000 g/mol, and (D) 0 to 10% by weight of an antimony compound, which resin composition is excellent not only in heat stability but also in heat resistance, impact resistance, processability and light resistance.
    Type: Grant
    Filed: November 5, 1991
    Date of Patent: October 5, 1993
    Assignee: Sumitomo Naugatuck Co., Ltd.
    Inventors: Fumio Nakai, Hidetaka Matsuzaki, Koji Matsumoto, Ichiro Kondou
  • Patent number: 5187212
    Abstract: This invention relates to flame retardant thermoplastic molding compositions, comprising:(a) a polyester resin derived from a cyclohexanedimethanol and a carbocyclic dicarboxylic acid or ester;(b) a tetra brominated bisphenol-A epoxy oligomer endcapped with epichlorohydrin flame retardant; and(c) a reinforcing agent.The compositions of the present invention have excellent thermal stability and other mechanical properties.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: February 16, 1993
    Assignee: General Electric Company
    Inventor: Keith N. Gray
  • Patent number: 5187208
    Abstract: A thermoplastic polycarbonate molding composition resistant to gamma-radiation is disclosed. The composition incorporates about 0.05 to 5.0 percent by weight of and end-capped poly(alkyl oxide) conforming to ##STR1## where hal denotes bromine or chlorine, n is about 10 to 40 and x is 1 to 5.The composition was found to be resistant to the yellowing which characterized polycarbonate compositions upon exposure to gamma radiation. The composition of the invention not only has low initial color change upon exposure but also a small change in yellowness after long term storing.
    Type: Grant
    Filed: November 6, 1991
    Date of Patent: February 16, 1993
    Assignee: Miles Inc.
    Inventor: Randall A. Rodenhouse
  • Patent number: 5153252
    Abstract: The present invention relates to a thermosetting powder coating composition comprising a thermosetting polymer, a crosslinking agent, and a bisphenoxy-propanol as a melt viscosity modifier. Preferably, the composition additionally comprises a flow control agent different from the bisphenoxy-propanol.
    Type: Grant
    Filed: November 29, 1991
    Date of Patent: October 6, 1992
    Assignee: Estron Chemical, Inc.
    Inventor: Stanislaw B. Skora
  • Patent number: 5115010
    Abstract: A composition comprising (I) a thermally stable polyamide such as an aromatic polyamide, (II) a halogenated polystyrene or a halogenated polyphenylene oxide, and (III) sodium antimonate has excellent fire retardancy and excellent thermal stability during molding. The thermal stability of the composition is further enhanced by including (IV) a hydrotalcite-type complex hydroxide or (V) magnesium oxide and/or zinc oxide.
    Type: Grant
    Filed: April 15, 1991
    Date of Patent: May 19, 1992
    Assignee: Mitsui Petrochemical Industries, Inc.
    Inventors: Hideki Sakai, Kazuo Ishiwatari, Fumitoshi Ikejiri
  • Patent number: 5064885
    Abstract: This invention relates to aliphatic polycarbonates including sequential copolymers based on cyclic aliphatic carbonates and esters and block copolymers of blocks of polymerised cyclic aliphatic carbonates and blocks of polymerised vinyl compounds stabilized against thermal degradation containing 0.01 to 3.0% by weight, based on polymer, of a compound of trivalent phosphorus.
    Type: Grant
    Filed: February 11, 1991
    Date of Patent: November 12, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Friedemann Muller, Edgar Leitz, Herbert Eichenauer, Karl-Heinz Ott, Hans-Josef Buysch
  • Patent number: 5043375
    Abstract: The present invention relates to a coating composition which contains a one- or two-component binder and, in addition,a) 0.1 to 15.0% by weight, based on the weight of the binder, of at least one coupling agent based on a chemically modified, amorphous polyolefin having an average molecular weight of 10,000 to 100,000, a non-uniformity of 1.0 to 6.5, a chlorine content of 2.5 to 50% by weight and a total content of nitrogen, oxygen, sulfur and silicon, in the form of chemically incorporated functional groups, of about 2.5 to 15% by weight, andb) 2.5 to 50% by weight, based on the weight of the amorphous polyolefin, of a bisphenol derivative corresponding to the formula ##STR1## The present invention also relates to a process for coating plastic substrates with this coating composition and to the coated plastics obtained therefrom.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: August 27, 1991
    Assignees: Bayer Aktiengesellschaft, Mobay Corporation
    Inventors: Wolfgang Henning, Kirkor Sirinyan, Bruce Benda
  • Patent number: 5028651
    Abstract: The present invention provides a novel resin composition possessing excellent heat resistance and flame retardance without the flame dripping during combustion. The claimed resin composition comprises a matrix resin composed of two types of resin components with improved heat resistance; an organic flame retardant; antimony trioxide; and a thermoplastic phenoxy resin.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: July 2, 1991
    Assignee: Lucky, Ltd.
    Inventors: Bong H. Park, Bong G. Yi, Jin N. Yoo
  • Patent number: 4954542
    Abstract: Tetrahalophthalate esters are disclosed herein as flame retardant processing aids for polybutylene terephthalate (PBT) resins.
    Type: Grant
    Filed: March 25, 1988
    Date of Patent: September 4, 1990
    Assignee: Pennwalt Corporation
    Inventors: Joseph M. Bohen, Ronald F. Lovenguth
  • Patent number: 4885318
    Abstract: Flame retardant compositions comprise linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon and a minor quantity, relative to the polymer, of certain flame retardants containing an organo halide.
    Type: Grant
    Filed: March 31, 1989
    Date of Patent: December 5, 1989
    Assignee: Shell Oil Company
    Inventors: Richard L. Danforth, Darlene G. Smith
  • Patent number: 4880862
    Abstract: Flame retardant ABS compositions incorporate an effective amount of halogenated unsymmetrical higher alkyl bisphenoxy alkane and an enhancing agent.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: November 14, 1989
    Assignee: Great Lakes Chemical Corporation
    Inventors: Enrico J. Termine, Nicolai A. Faystritsky, Dennis M. Borden
  • Patent number: 4780496
    Abstract: Normally combustible thermoplastic polyolefins such as polystyrene and polypropylene may be flame retarded without discoloration utilizing a flame retardant additive mixture comprising hexabromocyclododecane and one or more bis-(polybromophenoxy)ethane.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: October 25, 1988
    Assignee: Great Lakes Chemical Corporation
    Inventors: Enrico J. Termine, Harry A. Hodgen
  • Patent number: 4753970
    Abstract: Disclosed herein is a novel fire-retardant polyolefin composition comprising a polyolefin, an organohalogenous fire retardant and a carbonic acid ester represented by the formula (I): ##STR1## wherein R and R' respectively represent an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, an aralkyl group or an aryl group, Z represents a residual group of an aliphatic diol, an alicyclic diol, an aromatic diol, a diphenyl ketone diol, or a diphenylsulfone diol and n is 0 or 1.
    Type: Grant
    Filed: August 19, 1986
    Date of Patent: June 28, 1988
    Assignee: Nippon Kasei Chemical Co., Ltd.
    Inventors: Hiroyasu Saito, Shun Suzuki, Fumio Tanimoto, Hisao Kitano
  • Patent number: 4716196
    Abstract: Polytetrafluoroethylene resin within a specific particle size range, preferably about 70 to about 700 microns, in polymeric thermoplastic styrenic compositions containing conventional flame retardant additives permits reducing the amount of such additives in the composition to levels low enough to avoid adverse effect on performance properties of such compositions which would otherwise occur at higher levels of such additives necessary to achieve UL-94 flame retardant performance.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: December 29, 1987
    Assignee: Monsanto Company
    Inventors: Glenn B. Hilton, Wayne W. Robertson
  • Patent number: 4714729
    Abstract: The novel compositions of this invention are ignition resistant thermoplastic compositions comprising in admixture a thermoplastic resin and an ignition resistant additive selected from the group consisting of: at least one unsymmetrical carbonic acid ester of the general formula ##STR1## at least one unsymmetrical ether of the general formulaR.sup.2 --O--R.sup.3 ; anda mixture of at least one unsymmetrical carbonic acid ester and at least one unsymmetrical ether;wherein R, R.sup.1, R.sup.2 and R.sup.3 are selected from the group consisting of a halogenated aryl group, a halogenated alkyl group, a halogenated ether group, and mixtures thereof, containing a halogen selected from the group consisting of Br, Cl, I, Fl, and mixtures thereof, wherein R and R.sup.1 are dissimilar and R.sup.2 and R.sup.3 are dissimilar.
    Type: Grant
    Filed: January 27, 1986
    Date of Patent: December 22, 1987
    Assignee: The Dow Chemical Company
    Inventors: Mark R. Christy, Ernest L. Ecker
  • Patent number: 4710531
    Abstract: Self-extinguishing polycarbonates are disclosed, which consist of mixtures of polycarbonates with at least one salt of metals of the I and/or the II A and B Groups of the Periodic Table, and/or ammonium salts of organic carboxylic compounds having the general formula (I) ##STR1## and, as an adjuvant, at least one compound which is a member selected from the group consisting of the following classes of compounds:(i) a halogenated phenyl ether;(ii) a phthalimide or naphthalimide;(iii) an organic sulphone or a derivative thereof;(iv) an inorganic compound selected from the group consisting of halides of alkali metals or of alkaline earth metals, oxides of metals of the Groups IB,VIB,VIIB,IIIA,IVA and VIII of the Periodic Table, of the lanthanide group, carbon black and the residues of the pyrolysis of the organic acid salts of formula (I).
    Type: Grant
    Filed: August 19, 1983
    Date of Patent: December 1, 1987
    Assignee: Anic, S.p.A.
    Inventors: Giovanni Dozzi, Giorgio Della Fortuna, Salvatore Cucinella