Halogen Patents (Class 524/373)
  • Patent number: 4707510
    Abstract: A resin composition comprises 100 parts by weight of a thermoplastic resin and 9 to 55 parts by weight of an additive mixture comprising (A) 3 to 35 parts by weight of a tetrahalogenated bisphenol A carbonate oligomer, (B) 3 to 35 parts by weight of bis(tribromo-phenoxy)ethane and (C) 0.5 to 15 parts by weight of antimony trioxide. It is advantageous in respect to flame retardancy, impact resistance and light durability.
    Type: Grant
    Filed: March 20, 1987
    Date of Patent: November 17, 1987
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Tatsuhiko Imai, Masuo Kawasawa
  • Patent number: 4567218
    Abstract: There is disclosed a flame-retarded acrylonitrile-butadiene-styrene composition containing from about 5 to about 35 percent (by weight) bis(2,4,6-tribromophenoxyethyl) tetrabromobisphenol A ether and a method for forming such a composition.
    Type: Grant
    Filed: February 27, 1985
    Date of Patent: January 28, 1986
    Assignee: Great Lakes Chemical Corporation
    Inventor: Thomas J. Petiet
  • Patent number: 4567242
    Abstract: Compounds useful as flame retarders for organic high molecular compounds are obtained by reacting a polycondensate of a halogenated phenol, e.g. a tribromophenol polycondensate, with a metal compound or organic compound having at least two functional groups capable of reacting with the terminal hydroxyl group of the polycondensate, e.g. an alkaline earth metal halide, an alkyl dihalide or an acyl dihalide.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: January 28, 1986
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Setsuo Nishibori, Hirohito Komori, Syuji Saeki, Hiromitsu Kinoshita
  • Patent number: 4562216
    Abstract: Flame retardant reinforced with thermoplastic polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-40 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant components (I) to (II) is in the range of 0<(I)/(II).ltoreq.5, and that the total amount of flame retardants (I) plus (II) is in the range of 3-40 parts by weight. From 2 to 3 parts by weight of antimony trioxide is present and 5 to 60% by weight of glass fiber is also present, these two percentages being expressed on the basis of the weight of the total resin composition. The resin compositions exhibit outstanding mechanical, thermal, forming and machining properties in addition to being fire retardant.
    Type: Grant
    Filed: January 5, 1984
    Date of Patent: December 31, 1985
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori
  • Patent number: 4551493
    Abstract: Transparent flame-retardant poly(arylether-arylsulfone) molding materials preferably contain not less than 50% by weight of units of the formula ##STR1## and, as a flameproofing agent, from 0.1 to 10% by weight, based on the weight of poly(arylether-arylsulfone), of a poly(2,6-dibromophenylene 1,4-oxide) having a molecular weight of from 1000 to 20000, and, if required, a heat stabilizer.The molding materials are useful for the production of shaped articles, films and fibers.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: November 5, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Blinne, Volker Muench
  • Patent number: 4532287
    Abstract: Compositions for flameproofing polymeric material comprising:(a) a halogenated alkylaryl ether, the aryl group of which may be substituted by halogen;(b) an organo-tin compound; and(c) a sterically hindered phenol or a bisphenol containing a sterically hindered --OH group on each phenyl.In this specification by the term "bisphenol" is meant a compound containing two phenol groups linked by a bridging group that is not attached to any other bisphenol groups and by the term "phenol" is meant compounds containing only a single phenol group.
    Type: Grant
    Filed: May 11, 1984
    Date of Patent: July 30, 1985
    Assignee: Sandoz Ltd.
    Inventors: Rudolf Bill, Rainer Wolf
  • Patent number: 4456720
    Abstract: There is provided a novel flame retardant system or additive which when incorporated in a polymer, such as polyphenylene ether resin compositons, produces novel flame resistant non-discolored polyphenylene ether resin compositions. The flame retardant system comprises a composition of stable halogenated organic compounds and boron containing salts or esters which are stable at 250.degree.-300.degree. C.
    Type: Grant
    Filed: August 29, 1983
    Date of Patent: June 26, 1984
    Assignee: General Electric Company
    Inventors: Visvaldis Abolins, Fred F. Holub
  • Patent number: 4419473
    Abstract: A polyolefin plastic composition is provided having improved transparency, which comprises:(a) a major portion of a linear, low density polyethylene polymer;(b) a di-acetal of sorbitol and an aromatic aldehyde in an amount sufficient to improve transparency characteristics; and(c) a di-acetal decomposition inhibitor in an amount sufficient to inhibit decomposition of said di-acetal.
    Type: Grant
    Filed: May 20, 1982
    Date of Patent: December 6, 1983
    Assignee: Milliken Research Corporation
    Inventor: Robert L. Mahaffey, Jr.
  • Patent number: 4417003
    Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis(allyl ether) of tetrabromobisphenol A and a minor amount of dibromoethyldibromocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.
    Type: Grant
    Filed: April 8, 1983
    Date of Patent: November 22, 1983
    Assignee: Cosden Technology, Inc.
    Inventor: Richard A. Schwarz
  • Patent number: 4389495
    Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis(allyl ether) of tetrabromobisphenol A and a minor amount of pentabromomonochlorocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: June 21, 1983
    Assignee: Cosden Technology, Inc.
    Inventor: Richard A. Schwarz
  • Patent number: 4388418
    Abstract: An expandable polymeric styrene particle is provided from which molded foamed articles can be produced exhibiting reduced flammability characteristics. The expandable polymeric styrene particle contains a blowing agent, a minor amount of bis (allyl ether) of tetrabromobisphenol A and a minor amount of dibromoethyldibromocyclohexane. The additives can be incorporated during impregnation with the blowing agent or by blending with the expandable particles after impregnation.
    Type: Grant
    Filed: September 24, 1982
    Date of Patent: June 14, 1983
    Assignee: Cosden Technology, Inc.
    Inventor: Richard A. Schwarz
  • Patent number: 4381364
    Abstract: Thermoplastic compositions are disclosed which comprise blends of about 50 to about 85 percent by weight of a thermoplastic polyurethane and the balance of the blend comprising (a) a polyvinyl halide resin and (b) a diene-nitrile copolymer rubber, the weight ratio of (a) to (b) being within the range of from about 1:4 to about 1.5:1.The novel blends do not melt or spread flaming drip when combusted but rather form chars. The blends are optionally fire retarded by the addition of flame retardants.The fire retarded blends find utility in, inter alia, electric wire and cable jacketing where a high degree of fire retardance is required. The blends without fire retardants provide a good thermoplastic polyurethane at lower cost than the polyurethanes alone and find utility in those applications normally associated with polyurethanes such as films, footwear, wire jacketing, and particularly those applications calling for a higher degree of oil resistance than polyurethanes alone.
    Type: Grant
    Filed: June 14, 1982
    Date of Patent: April 26, 1983
    Assignee: The Upjohn Company
    Inventors: Costas N. Georgacopoulos, Curtis P. Smith
  • Patent number: 4366279
    Abstract: A flame retardant polycarbonate resin composition comprising a polycarbonate resin, a nuclear substituted benzoic acid containing at least one substituent selected from the group consisting of thiosalicylic acid and dihydroxy benzoic acid, and tetrabromobisphenol A or ##STR1## .
    Type: Grant
    Filed: August 19, 1981
    Date of Patent: December 28, 1982
    Assignee: Idemitsu Kosan Company Limited
    Inventors: Tatsuya Tomioka, Norio Ogata
  • Patent number: 4346052
    Abstract: Process and composition relating to novel, fine denier, homogeneous, curly synthetic fibers are set out. The process comprises orientation of a fiber-forming, slowly crystallizing, synthetic polymer composition in fiber form, generally after melt spinning, such orientation resulting from application of a longitudinal tensile force to said fiber above the crystallization temperature range and maintaining it at least through such range during a controlled, substantially axially symmetric cooling of the fiber. The novel fibers have a substantially axially symmetric, residual tensile force differential between their outer sheaths and inner portions, are generally of helical configuration and can exhibit more than about fifteen turns per linear centimeter.
    Type: Grant
    Filed: July 31, 1980
    Date of Patent: August 24, 1982
    Assignee: Standard Oil Company (Indiana)
    Inventor: Jack R. Knox
  • Patent number: 4329272
    Abstract: Styrene/maleic anhydride polymers can be made more resistant to combustion by incorporation therein of minor amounts of polyvinyl chloride. The compositions can also comprise MBS, ABS and other flame retardant additives.
    Type: Grant
    Filed: March 17, 1981
    Date of Patent: May 11, 1982
    Assignee: Monsanto Company
    Inventor: Daniel L. Dufour