From Fluorine-containing Monomer Patents (Class 524/544)
  • Patent number: 9073788
    Abstract: Disclosed is a ceramic paint, including a mixture of a silica sol-gel, 20 to 60 parts by weight of filler, and 1 to 50 parts by weight of a fluorine-containing polymer, wherein the silica sol-gel is formed by reacting 100 parts by weight of silica sol, 50 to 100 parts by weight of organic silane, and 0.3 to 1 parts by weight of a catalyst.
    Type: Grant
    Filed: February 23, 2012
    Date of Patent: July 7, 2015
    Assignee: GRAND TEK ADVANCE MATERIAL SCIENCE CO., LTD.
    Inventors: Hsueh-Tso Lin, Kuan-Ching Chen, Dick Zhong
  • Patent number: 9068053
    Abstract: A fluoro rubber composition which is able to make both a high tensile strength and a high elongation at break after vulcanization compatible with each other and from which favorable mechanical characteristics are obtained even in a high-temperature environment; and a bladder for tire fabrication, which is manufactured using the same are provided. The fluoro rubber composition includes a rubber component containing a fluoro rubber and carbon black, wherein in a dynamic viscoelasticity test of an unvulcanized rubber by a rubber process analyzer (RPA) (measurement temperature: 100° C., measurement frequency: 1 Hz), a difference ?GA? (G?(1%)?G?(100%)) between a shear modulus G? (1%) at the time of a dynamic strain of 1% and a shear modulus G? (100%) at the time of a dynamic strain of 100% is 120 kPa or more and not more than 3,000 kPa.
    Type: Grant
    Filed: August 25, 2010
    Date of Patent: June 30, 2015
    Assignees: BRIDGESTONE CORPORATION, E.I. DU PONT DE NEMOURS AND COMPANY, DAIKIN INDUSTRIES, LTD.
    Inventors: Masashi Yano, Daisuke Ota, Shuichi Okutsu
  • Publication number: 20150147579
    Abstract: A composition comprising at least one first divalent unit represented by formula: and at least one of a second divalent unit comprising a pendant Z group or a monovalent unit comprising a thioether linkage and a terminal Z group, wherein each Z group is independently selected from the group consisting of —P(O)(OY)2 and —O—P(O)(OY)2. R? and R?? are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Y is selected from the group consisting of hydrogen, alkyl, trialkylsilyl, and a counter cation. Methods of treating a surface using these compositions and articles with a surface in contact with these compositions are provided. Methods of making these compositions are also provided.
    Type: Application
    Filed: January 30, 2015
    Publication date: May 28, 2015
    Inventors: Chetan P. Jariwala, Gregory D. Clark, Jason T. Petrin, Rudolf J. Dams, Steven J. Martin, Mark J. Pellerite
  • Patent number: 9040625
    Abstract: To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20° C., monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.
    Type: Grant
    Filed: October 24, 2013
    Date of Patent: May 26, 2015
    Assignee: ASAHI GLASS COMPANY, LIMITED
    Inventors: Kyouichi Kaneko, Kazunori Sugiyama, Reika Fukuda, Takao Hirono
  • Publication number: 20150140222
    Abstract: The present invention relates to a method of producing a water repelling surface or imparting hydrophobicity onto a surface comprises applying a polymer-based coating composition. The water repelling surface or the hydrophobic surface imparted by the present method has at least 90° of water contact angle. The water repelling surface or the hydrophobic surface imparted by the present method is preferably on a concrete surface. The present method imparts hydrophobicity onto surfaces that are durable without an additional primer layer between the surfaces and the coating composition.
    Type: Application
    Filed: June 4, 2014
    Publication date: May 21, 2015
    Applicant: Nano and Advanced Materials Institute Limited
    Inventors: Kai Tai WAN, Su Ping BAO, Hong Gang ZHU, Ran Yuan WANG, Bin Meng CHEN
  • Publication number: 20150136712
    Abstract: Provided herein are copolymers and copolymer compositions that are both hydrophilic and oleophobic. The copolymers include structural units derived from a fluoroalkyl monomer and a zwitterionic monomer. It further relates to membranes formed by coating a porous substrate with the copolymeric compositions. The copolymeric coating imparts hydrophilicity and oleophobicity/oil-tolerance to the membranes. The uses of such membranes as microfiltration membrane or ultrafiltration membrane are also provided.
    Type: Application
    Filed: November 15, 2013
    Publication date: May 21, 2015
    Applicant: General Electric Company
    Inventors: Louisa Ruth Carr, James Manio Silva, Paul Michael Smigelski, JR., Jason Nichols
  • Patent number: 9029452
    Abstract: This invention relates to a composition comprising a solvent-based fluoropolymer and its use as a coating additive, and a coating composition comprising the fluoropolymer. The coating composition comprising the solvent-based fluoropolymer provides desirable properties including uniform spreading, and cleanability and increased contact angle to a coated substrate. There is further provided a method of treating a substrate using the coating composition.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: May 12, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Gerald Oronde Brown, Xianjun Meng
  • Patent number: 9029471
    Abstract: Various fluoropolymers have been proposed for imparting oil and water repellency to leather. Commonly, these fluoropolymers are amphiphilic; i.e., they are made from at least one monomer which is hydrophobic and at least one monomer which is hydrophilic. The present invention identifies and remedies disadvantages associated with the ability of amphiphilic fluoropolymers to impart oil and water repellency to leather. Contrary to conventional thinking, it has now been discovered that the incorporation of hydrophilic groups in a fluoropolymer undesirably reduces its ability to impart water resistance to leather. Correspondingly, it has also been discovered that a fluoropolymer incorporating fewer or no hydrophilic groups imparts superior oil and water repellency to leather when compared to fluoropolymers incorporating more hydrophilic groups. Therefore, this invention provides fluoropolymers which incorporate reduced levels of hydrophilic groups.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: May 12, 2015
    Assignee: E I du Pont du Nemours and Company
    Inventors: Romain Severac, Agnes Ibos, Lamia Heuze, Renaud Laloux-Walther
  • Publication number: 20150113704
    Abstract: Methods for preparing copolymeric emulsions from at least one water soluble monomer and at least one water insoluble monomer are disclosed herein. In some embodiments, one or more surfactants and stabilizers may be used. In some embodiments, the monomers used in the process include, by total monomer weight, at least 50% water soluble monomers and at least 10% water insoluble monomers. Copolymer emulsions formed from the reaction product of at least one water soluble monomer and at least one water insoluble monomer are also disclosed along with articles coated with such emulsions and coating formulations made from such emulsions as well as methods for the manufacture and coating of such articles.
    Type: Application
    Filed: October 29, 2014
    Publication date: April 30, 2015
    Applicant: ALLEGIANCE CORPORATION
    Inventors: Wei Cheong WONG, SHIPING WANG, Chii Yih LOW, Chuang Sim CHONG, Xiaochuan HU, Dennis KOPP, Andre MAYER, Michael MEYERS, Daniel L. Holguin, Sou Phong LEE
  • Patent number: 9012562
    Abstract: The present invention relates to acrylic adhesive composition comprising a mixture of at least one polyol tri(meth)acrylate monomer and at least one polyalkylene glycol mono(meth)acrylate monomer for assembling elements made of plastic materials, like PMMA or SAN, or inorganic material, like glass or metals, employed for manufacturing of devices for the distribution or containment of biological substances, like proteins, enzymes, antibodies, antigens, DNA, and the like. The present invention also relates to devices for the distribution or containment of biological substances assembled with the above mentioned acrylic adhesive composition, and particularly thermal or piezoelectric ejecting devices, and biochip microarray, as well as to a method for assembling thereof.
    Type: Grant
    Filed: December 30, 2008
    Date of Patent: April 21, 2015
    Assignee: SICPA Holding SA
    Inventors: Davide Ciampini, Lucia Giovanola, Cristina Panciatichi, Oriana Rossotto, Duccio Spartaco Sassano
  • Patent number: 9006565
    Abstract: A fluoropolymer composition having a total luminous transmittance (TT) of less than 15%, when measured according to ASTM D1003 on a sample having a thickness of about 50 ?m, said composition comprising: at least one hydrogen-containing fluoropolymer [polymer (A)]; from 5 to 80% by weight of (A) of at least one inorganic pigment [pigment (I)]; and from 1 to 99% by weight of (I) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad×sec?1 of less than 100 Pa×sec at a temperature of 280° C. [polymer (B)]. By adding polymer (B) to the composition based on polymer (A) it is advantageously possible to obtain an even dispersion of the pigment (I) so that a composition possessing outstanding opacity and still being processable under the form of films, so as to provide adequate mechanical properties, can be manufactured therefrom.
    Type: Grant
    Filed: October 15, 2009
    Date of Patent: April 14, 2015
    Assignee: Solvay Specialty Polymers Italy S.p.A.
    Inventors: Julio A. Abusleme, Mattia Bassi, Régis Faig, Paolo Toniolo
  • Patent number: 8993679
    Abstract: There is provided a method for producing an aqueous dispersion of fluorine-containing seed polymer (B) particles, comprising a step for preparing an aqueous dispersion of fluorine-containing polymer (A) particles by polymerizing monomer comprising at least one fluoroolefin in an aqueous dispersion in the presence of a compound (1) represented by the formula: CH2?CHCH2—O—R, wherein R is a hydrocarbon group which may have an oxygen atom, a nitrogen atom and/or a polar group, and (II) a step for seed-polymerizing ethylenically unsaturated monomer with the fluorine-containing polymer (A) particles in the aqueous dispersion of the fluorine-containing polymer (A) particles.
    Type: Grant
    Filed: March 11, 2010
    Date of Patent: March 31, 2015
    Assignee: Daikin Industries, Ltd.
    Inventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
  • Patent number: 8985818
    Abstract: The LED mounting substrate of the present invention includes a thermally conductive layer (thermally conductive sheet (10)) made of a composition containing boron nitride powder and a fluororesin, and the fluororesin contains polytetrafluoroethylene. The thermally conductive layer has a thermal conductivity of 2 W/(m·K) or more. The thermally conductive layer has a reflectance of 0.80 or more at wavelengths of 380 nm, 470 nm, and 650 nm.
    Type: Grant
    Filed: November 26, 2010
    Date of Patent: March 24, 2015
    Assignee: Nitto Denko Corporation
    Inventors: Daisuke Kitagawa, Yoshinari Takayama, Ichiro Suehiro, Hideyuki Usui, Takashi Oda
  • Publication number: 20150080524
    Abstract: Provided is a polymer, a composition and film comprising the polymer, and a preparation method of the polymer. The polymer includes a compound having a hydrophobic property at its terminal, and thus a film capable of having a hydrophobic surface can be provided at the same time when the film is formed without a separate surface treatment. Further, an effect capable of permanently hydrophobically modifying a film surface is obtained at a low cost and a composition that does not occur a phase separation phenomenon in a polymer solution state is provided. For example, the film is used as a water repellent coating film, an anti-contamination film, or the like.
    Type: Application
    Filed: November 26, 2014
    Publication date: March 19, 2015
    Applicant: LG CHEM, LTD.
    Inventors: Jeong Ae Yoon, No Ma Kim, Su Jeong Kim, In Ho Hwang
  • Publication number: 20150072128
    Abstract: There is provided a novel fluorine-containing highly branched polymer which imparts water repellency and oil repellency to the polycarbonate resin, further is excellent in miscibility and dispersibility in the resin, and can maintain luxurious feeling of the resin, such as transparency and gloss feeling. A fluorine-containing highly branched polymer obtained by polymerizing a monomer A having in a molecule a bisphenol A structure and two or more radical-polymerizable double bonds, and a monomer B having in a molecule a fluoroalkyl group and at least one radical-polymerizable double bond, in the presence of a polymerization initiator C in an amount of 5 to 200 mol %, based on the number of moles of the monomer A; a resin composition comprising the fluorine-containing highly branched polymer and a polycarbonate resin; and a surface-modified film obtained from the resin composition.
    Type: Application
    Filed: April 12, 2013
    Publication date: March 12, 2015
    Inventors: Motonobu Matsuyama, Masayuki Haraguchi, Masaaki Ozawa
  • Patent number: 8975348
    Abstract: A solvent-based non-aqueous fluorinated methacrylate polymer comprising repeating units in any sequence from (1) at least one fluorinated methacrylate, and (2) at least one non-fluorinated alkyl acrylate and (3) at least one non-fluorinated hydroxyalkyl methacrylate, provided that a) the repeating unit of fluorinated methacrylate is present in a range of about 40%-80% by weight of total monomers added, b) the repeating unit of non-fluorinated alkyl acrylate is present in a range of about 10%-35% by weight of total monomers added, and c) the repeating unit of non-fluorinated hydroxyalkyl methacrylate is present in a range of about 5%-25% by weight of total monomers added, and d) the total of all repeating units is 100% by weight.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: March 10, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Michael Henry Ober, Ernest Byron Wysong, Timothy Edward Hopkins, Andrew Hen Liu
  • Patent number: 8971707
    Abstract: Use in LAN cable applications, as materials for the coating of the primary cable and for the external jacket, of TFE thermoprocessable perfluoropolymers comprising perfluoroalkylvinylethers in the following amounts, expressed as percent by weight on the total of the monomers: a) 0-5.5% of perfluoromethylvinylether (PMVE); b) 0.4-4.5% of perfluoroethylvinylether (PEVE) and/or perfluoropropylvinylether (PPVE); when a) is present, then a)+b) ranges from 1.5% to 5.5% by weight on the total of the monomers; optionally c) 0-6% of hexafluoropropene (HFP); the TFE amount being the complement to 100% by weight.
    Type: Grant
    Filed: February 20, 2007
    Date of Patent: March 3, 2015
    Assignee: Solvay Solexis S.p.A.
    Inventors: Pasqua Colaianna, Giulio Brinati, Aldo Sanguineti
  • Patent number: 8957138
    Abstract: The present teachings disclose a composite. The composite includes a cellulose material dispersed in a fluoropolymer. The cellulose material is present in an amount of from about 1 weight percent to about to about 30 weight percent of the composition. A method of manufacturing a composite article and coating is described.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: February 17, 2015
    Assignee: Xerox Corporation
    Inventors: Carolyn P. Moorlag, Yu Qi, Brynn M. Dooley, Qi Zhang
  • Publication number: 20150045498
    Abstract: A method for producing a surface-functionalised object involves: (i) providing negative mould (2) with a surface topography complementary to that desired on the object; (ii) applying a functional entity (20) to the mould surface, in an exciting medium; (iii) forming the object (21) in or on the mould (2), the object being in direct contact, as it forms, with the functional entity (20); and (iv) releasing the object (21) from the mould, wherein during steps (iii) and/or (iv), at least some (22) of the functional entity (20) is transferred from the mould to the object, whilst a proportion remains on the mould (2) surface. The method can be used to functionalise the surface of an object as it is cast, and the mould can be re-used to form multiple replicate objects. The invention also provides an object produced using the method, and a surface-functionalised negative mould for use in the method.
    Type: Application
    Filed: July 18, 2012
    Publication date: February 12, 2015
    Inventors: Jas Pal S. Badyal, Hayley G. Andrews
  • Patent number: 8937112
    Abstract: An aqueous fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of about 10 to about 400 nm. The dispersion has a solids content of at least about 35 to about 70 wt % and comprises about 0.03 wt % to about 10 wt % anionic polyelectrolyte dispersing agent based on the weight of fluoropolymer solids. The dispersion has a Gel Time of at least about 100 seconds.
    Type: Grant
    Filed: August 20, 2013
    Date of Patent: January 20, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventors: Robert John Cavanaugh, Clay Woodward Jones
  • Patent number: 8927623
    Abstract: To provide a recording ink which contains at least a water-dispersible colorant, a water-dispersible resin, a wetting agent, a surfactant and water, wherein the content of the wetting agent in the recording ink is in the range of from 20% by mass to 35% by mass, the total solid content of the water-dispersible colorant and the water-dispersible resin in the recording ink is in the range of from 12% by mass to 40% by mass, the water-dispersible resin contains fluorine resin particulates, and the ratio A:B, where A is the solid content of the water-dispersible resin in the recording ink and B is the solid content of a pigment contained in the water-dispersible colorant in the recording ink, is in the range of 0.5 to 8.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: January 6, 2015
    Assignee: Ricoh Company, Ltd.
    Inventor: Hiroshi Goto
  • Publication number: 20150000557
    Abstract: The present disclosure relates to compositions and methods for making stable aqueous fluorinated silane dispersions.
    Type: Application
    Filed: January 9, 2013
    Publication date: January 1, 2015
    Inventor: Chetan P. Jariwala
  • Publication number: 20150002592
    Abstract: A marking system surface material includes a fluoroelastomer including grafted fluorinated polymers. The fluoroelastomer is a perfluoropolyether-grafted fluoroelastomer formed using an alkoxy-terminated fluorosilicone component, and exhibiting high contact angle and low sliding angle.
    Type: Application
    Filed: June 30, 2013
    Publication date: January 1, 2015
    Applicant: XEROX CORPORATION
    Inventors: Mandakini KANUNGO, Chakkaravarthy CHIDAMBARESWARAPATTAR, David J. GERVASI, Santokh S. BADESHA, Matthew M. KELLY, Akshat SHARMA
  • Publication number: 20150004379
    Abstract: This invention relates to the preparation and purification of high-X (“chi”) diblock copolymers. Such copolymers contain two segments (“blocks”) of polymers with significantly different interaction parameters and can be used in directed self-assembly applications.
    Type: Application
    Filed: February 11, 2013
    Publication date: January 1, 2015
    Inventors: William Brown Farnham, Michael Thomas Sheehan, Hoang Vi Tran
  • Publication number: 20140377707
    Abstract: A composition for forming a liquid immersion upper layer film includes a polymer component including a polymer having a structural unit represented by a formula (1); and a solvent. R1 represents a carboxy group or a group represented by a formula (2); X represents a single bond, a divalent hydrocarbon group having 1 to 20 carbon atoms or a divalent fluorinated hydrocarbon group having 1 to 20 carbon atoms; R2 represents a hydrocarbon group having 1 to 20 carbon atoms and a valency of (n+1), a fluorinated hydrocarbon group having 1 to 20 carbon atoms and a valency of (n+1), or one of these groups each including between adjacent two carbon atoms thereof —CO—, —COO—, —O—, —NR?—, —CS—, —S—, —SO—, —SO2— or a combination thereof; and R3 represents a hydrogen atom or a monovalent organic group having 1 to 20 carbon atoms.
    Type: Application
    Filed: September 20, 2013
    Publication date: December 25, 2014
    Applicant: JSR CORPORATION
    Inventors: Shinya MINEGISHI, Kiyoshi TANAKA, Kazunori KUSABIRAKI
  • Patent number: 8916643
    Abstract: A water- and oil-repellent includes, as an active ingredient, a fluorine-containing copolymer including as a copolymer unit (A) at least one of perfluoroalkylalkyl acrylates and corresponding methacrylates, (B) benzyl acrylate or benzyl methacrylate represented by the general formula: CnF2n+1CmH2mOCOCR?CH2 (wherein R represents a hydrogen atom or a methyl group; n represents 4, 5, or 6; and m represents 1, 2, 3, or 4), (C) a fluorine-free polymerizable monomer other than benzyl acrylate and benzyl methacrylate, and (D) a cross-linkable group-containing polymerizable monomer.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: December 23, 2014
    Assignee: Unimatec Co., Ltd.
    Inventors: Ji-Shan Jin, Satoshi Kurihara, Sumiko Mouri, Katsuyuki Sato
  • Patent number: 8916631
    Abstract: Provided is a film or sheet composed of a resin composition that includes a poly lactic acid (A), an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000, a tetrafluoroethylene polymer (C), and an aromatic-condensed phosphoric acid ester-containing flame retardant (D) including a compound of General Formula (I) and in which the aromatic-condensed phosphoric acid ester-containing flame retardant (D) is included in an amount of 10 to 80 parts by weight based on 100 parts by weight of the poly lactic acid (A), and a method for manufacturing the film or sheet by melt film formation. Each sign in Formula is as described in the specification.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: December 23, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Shigeki Ishiguro, Hiroki Senda
  • Patent number: 8912243
    Abstract: The disclosure provides a composition or set of compositions and method for producing cellular, foamed, or blown fluoropolymers such as perfluoropolymers and other thermoplastics to create a lower cost communications cable, conductor separator, conductor support-separator, jacketing, tape, wire insulation and in some cases a conduit tube as individual components or combined configurations that exhibit improved electrical, flammability and optical properties. Specifically, the foamable or blown perfluoropolymer cellular insulation composition comprises; talc and the selected fluoropolymers such as perfluoropolymers. Compounded pellets including inorganic and organic fillers resulting in products in cellular or foamable form with and without solid skin surfaces has also been realized by providing melt combinations within the pellets primarily comprising talc and a perfluoropolymer, and additives as needed to provide desired property differentiation.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: December 16, 2014
    Assignee: Cable Components Group, LLC
    Inventor: Charles A. Glew
  • Publication number: 20140364028
    Abstract: Disclosed is a fluorine-containing composition which contains a fluorine-containing polymer that has repeating units respectively derived from (A) a fluorine-containing monomer that is an alpha-chloroacrylate having a fluoroalkyl group, (B) a monomer that has a linear or branched hydrocarbon group but does not have a fluoroalkyl group, and (C) a monomer that has a cyclic hydrocarbon group but does not have a fluoroalkyl group. This fluorine-containing composition is capable of providing a base such as a fiber product with excellent water repellency, especially strong water repellency.
    Type: Application
    Filed: December 12, 2012
    Publication date: December 11, 2014
    Inventors: Shinichi Minami, Masaki Fukumori, Tetsuya Uehara, Hisako Nakamura, Ikuo Yamamoto
  • Patent number: 8889796
    Abstract: There is provided a perfluoroelastomer composition having a low glass transition temperature and excellent cold resistance and heat resistance and comprising a perfluoroelastomer comprising a tetrafluoroethylene unit (a), a perfluoro vinyl ether unit (b) and a cure site unit (c) having nitrile group, carboxyl group and/or alkoxycarbonyl group as a cure site, wherein the perfluoro vinyl ether unit (b) is contained in an amount of 8 to 23% by mole in the perfluoroelastomer.
    Type: Grant
    Filed: October 2, 2009
    Date of Patent: November 18, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Junpei Terada, Tatsuya Morikawa, Daisuke Ota, Meiten Koh
  • Patent number: 8883942
    Abstract: A process for preparing a macromonomer by cationic ring-opening polymerization of at least one hydroxyoxetane with a terminally ethylenically unsaturated starter molecule free of allyl groups in a molar ratio (hydroxyoxetane(s):starter molecule) of (100:1) to (1:1) in the presence of at least one suitable catalyst; macromononomers obtainable therefrom and use thereof.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: November 11, 2014
    Assignee: BYK-Chemie GmbH
    Inventors: Albert Frank, Wojciech Jaunky, Jörg Issberner
  • Patent number: 8877823
    Abstract: The present invention relates generally to a method for manufacturing a foamed article, which comprises providing a composition comprising a melt-processable perfluoropolymer and talc, said perfluoropolymer comprising at least 50 percent by weight of said composition and said talc comprising about 2 percent to 3 percent by weight of said composition; wherein said melt-processable perfluoropolymer is selected from the group consisting of tetrafluoroethylent/perfluoromethylvinyl ether copolymer (MFA), hexafluoropropylene/tetrafluoroethylene copolymer (FEP), and perfluroralkoxy (PFA) and any blend thereof. The composition is heated to a processing temperature of at least 600° F. at which talc functions as a foaming agent, thereby causing the foaming of said composition at a foaming rate in a range from 20% to 50% so as to form a foamed article. The talc is the only foaming agent in said composition and the foaming is achieved without gas injection.
    Type: Grant
    Filed: October 1, 2012
    Date of Patent: November 4, 2014
    Assignee: Cable Components Group, LLC
    Inventors: Charles A. Glew, Kenneth R. Boyle, Bradley Lane Kent, Jeffrey A. Hrivnak
  • Publication number: 20140322525
    Abstract: A plasma chamber (11?) for coating a substrate with a polymer layer, the plasma chamber comprises a first electrode set (14?) and a second electrode set (14?), the first and second electrode sets are arranged either side of a sample chamber for receiving a substrate, wherein the first and second electrode sets comprise plural electrode layers (141?, 142?) and wherein each electrode set comprises plural radiofrequency electrode layers or plural ground electrode layers for coating polymer to each surface of a substrate.
    Type: Application
    Filed: September 7, 2012
    Publication date: October 30, 2014
    Applicant: EUROPLASMA NV
    Inventors: Filip Legein, Frank Ferdinandi
  • Patent number: 8871882
    Abstract: A method for the preparation of a fluoropolymer by means of emulsion polymerization of a reaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; b) an emulsion stabilizer combination comprising: i) an anionic surfactant; and, ii) a cationic surfactant or a non-ionic surfactant; and, c) a free-radical initiator.
    Type: Grant
    Filed: February 14, 2012
    Date of Patent: October 28, 2014
    Assignee: Akron Polymer Systems, Inc.
    Inventors: Xiaoliang Zheng, Dong Zhang, Jiaokai Jing, Ted Calvin Germroth, Frank W. Harris, Thauming Kuo, Bin Wang, Douglas Stephens McWilliams
  • Patent number: 8871332
    Abstract: Disclosed is a fluorine-containing polymer obtained by polymerizing a 1,6-diene-type ether compound represented by formula [1] and, for example, a (meth)acrylic acid compound represented by formula [2]. The fluorine-containing polymer shows high transparency, has a high glass transition point, and is soluble in a solvent and therefore has moldability. In the case where a (meth)acrylic unit has a reactive substituent, by utilizing the crosslinking reaction thereof, a thin film having high solvent resistance can be produced. In formulae [1] and [2], R1 and R2 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, which may be substituted, R3 represents a hydrogen atom, a fluorine atom, or a methyl group, and R4 represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, which may be substituted, or an aromatic group having 5 to 10 ring members, which may be substituted.
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: October 28, 2014
    Assignees: Ibaraki University, Nissan Chemical Industries, Ltd.
    Inventors: Toshio Kubota, Takehiro Nagasawa, Makoto Hirooka, Eiko Hirooka
  • Publication number: 20140308503
    Abstract: A material for a surface modifying agent with which the problems of insufficient durability as abrasion and chemical resistances of surface modification effect in polyurethane surface modification by the prior surface modifying agent are resolved, and is immobilized in a matrix resin firmly and improved in durability. A reactive fluorine-containing highly branched polymer obtained by: polymerizing monomer A having in a molecule two or more radically polymerizable double bonds, monomer B having in a molecule a fluoroalkyl group and at least one radically polymerizable double bond, and monomer C having in a molecule an alcoholic hydroxy group and minimum, one radically polymerizable double bond, in presence of a polymerization initiator D in an amount of 5% to 200% by mole with respect to the number of moles of the monomer A; a curable composition containing the reactive fluorine-containing highly branched polymer; and a cured film obtained from the composition.
    Type: Application
    Filed: November 26, 2012
    Publication date: October 16, 2014
    Inventors: Hiroyasu Tamura, Masayuki Haraguchi, Masaaki Ozawa
  • Patent number: 8859645
    Abstract: The invention pertain to a process for purifying a fluoropolymer dispersion, said process comprising: (i) providing an aqueous dispersion (D) of at least one fluoropolymer [polymer (F)]comprising at least one fluorinated surfactant [surfactant (FS)], having a solids content (SC) of 15% by weight or more; (ii) adding to said aqueous dispersion (D) at least one non-ionic non-fluorinated surfactant [surfactant (NS)]; (iii) adjusting said solid content (SC) to less than 10% by weight, to obtain a diluted aqueous dispersion (dD); (iv) contacting said diluted aqueous dispersion (dD) with at least one adsorbing material, so as to obtain an aqueous dispersion of polymer (F) having a content of the fluorinated surfactant (FS) of less than 1 ppm based on the total weight of solids. Still an object of the invention is an aqueous fluoropolymer dispersion comprising less than 1 ppm of fluorinated surfactant.
    Type: Grant
    Filed: April 6, 2007
    Date of Patent: October 14, 2014
    Assignee: Solvay Solexis S.p.A.
    Inventors: Tiziana Poggio, Fabrizio Spada, Valeri Kapeliouchko
  • Publication number: 20140303312
    Abstract: A fluorinated silane-modified polyacrylic resin comprising: (a) 1% to 50% by weight of at least one acrylic ester monomer; (b) 1 to 50% by weight of an ethylenically unsaturated monomer; (c) 1% to 50% by weight of an organofunctional silane monomer; and (d) 0.1% to 50% by weight of a fluorine-containing monomer.
    Type: Application
    Filed: March 15, 2013
    Publication date: October 9, 2014
    Applicant: THE SHERWIN-WILLIAMS COMPANY
    Inventor: THE SHERWIN-WILLIAMS COMPANY
  • Publication number: 20140303281
    Abstract: The present invention relates to coating compositions formed by combining two latex resins: a base latex resin and a stratifying latex resin. The stratifying latex resin comprises hybrid metal oxide latex particles wherein the hybrid particles are the polymerization reaction product of at least one or more copolymerizable monoethylenically unsaturated monomers, wherein the monoethylenically unsaturated monomers comprise at least one low surface energy driver monomer selected from the group consisting of (i) a fluorine containing monomer; and (ii) a silane-containing monomer; and wherein the polymerization reaction is in the presence of a metal oxide nanoparticle; and wherein the metal oxide nanoparticle is embedded within the hybrid particles.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 9, 2014
    Applicant: THE SHERWIN-WILLIAMS COMPANY
    Inventor: The Sherwin-Williams Company
  • Patent number: 8852693
    Abstract: The present disclosure provides an electronic device and related method, wherein the device has a polymeric coating with low toxicity. The polymeric coating formed by exposing the electronic device to continuous plasma comprising a compound of CH2?C(R1)—COO—R2, where R1 includes —H or —CH3; and where R2 includes —(CH2)2—(CF2)m—CF3 and m is 3 or 5.
    Type: Grant
    Filed: May 19, 2011
    Date of Patent: October 7, 2014
    Assignee: Liquipel IP LLC
    Inventors: Filip Legein, Anthony Vanlandeghem, Peter Martens
  • Publication number: 20140295149
    Abstract: A cured film is formed by using a curable composition comprising a liquid repellent polymer having units (u1) based on a liquid repellent compound represented by the following formula (m1): wherein Cf is a C1-20 fluoroalkyl group or a C1-20 fluoroalkyl group having an etheric oxygen atom between carbon atoms, each of R1 and R2 which are independent of each other, is a hydrogen atom, a C1-6 alkyl group or a phenyl group, X is an oxygen atom, a sulfur atom, a nitrogen atom or NH, n in an integer of from 0 to 4, m is 1 when X is an oxygen atom, a sulfur atom or NH, or 2 when X is a nitrogen atom, Z is R4R5C?CR3—CO—, and each of R3, R4 and R5 which are independent of one another, is a hydrogen atom or a methyl group.
    Type: Application
    Filed: June 16, 2014
    Publication date: October 2, 2014
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Masahiro ITO, Kaori TSURUOKA
  • Publication number: 20140288232
    Abstract: Diaminospirobisindane diols, curable compositions, curative compositions, cured articles, and methods of curing are described.
    Type: Application
    Filed: November 7, 2012
    Publication date: September 25, 2014
    Inventors: Werner M.A. Grootaert, Michael S. Wendland, George W. Griesgraber
  • Publication number: 20140288230
    Abstract: The present invention provides methylene beta-ketoester monomers, methods for producing the same, and compositions and products formed therefrom. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester is reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to further processing, which may be vaporization by contact with an energy transfer means in order to isolate the beta-ketoester monomer. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).
    Type: Application
    Filed: October 18, 2012
    Publication date: September 25, 2014
    Inventors: Bernard M. Malofsky, Adam G. Malofsky, Tanmoy Dey
  • Publication number: 20140288231
    Abstract: Disclosed is a fluorine-containing copolymer comprising a copolymer of a polyfluoroalkyl alcohol (meth)acrylic acid derivative represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR?CH2 wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3, and styrene or a derivative thereof; and also disclosed is a surface modifier comprising the fluorine-containing copolymer as an active ingredient. When the fluorine-containing copolymer is used as an active ingredient of a surface modifier, the heat resistance of the surface modifier can be further improved.
    Type: Application
    Filed: October 11, 2012
    Publication date: September 25, 2014
    Inventors: Yuko Fujita, Yoshiyama Kaneumi
  • Publication number: 20140275400
    Abstract: The present invention provides methylene beta-diketone monomers, methods for producing the same, and compositions and products formed therefrom. In the method for producing the methylene beta-diketones of the invention, a beta-diketone is reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to further processing, which may be vaporization by contact with an energy transfer means in order to isolate the beta-diketone monomer. The present invention further compositions and products formed from methylene beta-diketone monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).
    Type: Application
    Filed: October 18, 2012
    Publication date: September 18, 2014
    Inventors: Yangbin Chen, Adam G. Malofsky, Jeffrey M. Sullivan, Stanley C. Wojciak, Tanmoy Dey, Bernard M. Malofsky
  • Publication number: 20140272523
    Abstract: An electrical storage device includes a cathode, an anode, a protective film that is provided between the cathode and the anode, and an electrolyte solution, the protective film including a polymer that includes a repeating unit derived from a fluorine-containing monomer, and a repeating unit derived from an unsaturated carboxylic acid.
    Type: Application
    Filed: October 4, 2012
    Publication date: September 18, 2014
    Applicant: JSR CORPORATION
    Inventors: Yoshiharu Otsuka, Hironori Kitaguchi, Nobuyuki Fujihara
  • Publication number: 20140275399
    Abstract: Novel fluorinated compounds, their method of preparation and use are disclosed, as well as the incorporation of new and old fluorinated compounds in controlled radical polymerization processes to efficiently produce polymer compositions with unique and enhanced properties. Various cure mechanisms and types of end-uses are disclosed.
    Type: Application
    Filed: April 4, 2014
    Publication date: September 18, 2014
    Inventors: Tianzhi Zhang, Matthew P. Burdzy, Dingsong Feng, Yonghui Zhang
  • Patent number: 8835551
    Abstract: Iodine containing amorphous fluoropolymers having at least one fluoropolymer with a cure site, where the fluoropolymer has a Mooney viscosity of 2 or less (ML 1+10) at 100° C. according to ASTM D1646, and a peel strength to a roll mill of 10 dN/cm or less and methods for making such iodine containing amorphous fluoropolymers are described. Articles derived from the cured product of such iodine containing amorphous fluoropolymers are also described. Solutions, dispersions and coatings derived from such iodine containing amorphous fluoropolymers are also described.
    Type: Grant
    Filed: September 11, 2008
    Date of Patent: September 16, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Tatsuo Fukushi, Peter J. Scott, Cynthia N. Ferguson, Werner M. A. Grootaert, Denis Duchesne, Yeng Moua, Larry A. Last, Terri A. Shefelbine, Luke M. B. Rodgers
  • Patent number: 8829087
    Abstract: Embodiments in accordance with the present invention provide polymers for forming layers/films useful in the manufacture of a variety of types of optoelectronic displays. Such embodiments also provide compositions of such polymers for forming such layers/films where the formed layers/films have high transparency over the visible light spectrum.
    Type: Grant
    Filed: December 9, 2011
    Date of Patent: September 9, 2014
    Assignees: Promerus, LLC, Sumitomo Bakelite Co., Ltd.
    Inventors: Osamu Onishi, Larry F. Rhodes, Nobuo Tagashira
  • Publication number: 20140248563
    Abstract: A composition includes a polymer component including a first polymer having a first structural unit represented by a following formula (1), and a solvent. In the formula (1), R1 represents a hydrogen atom or a monovalent organic group having 1 to 20 carbon atoms. R2 represents a single bond or a divalent organic group having 1 to 20 carbon atoms. R3 represents a hydrogen atom or a monovalent organic group having 1 to 20 carbon atoms. RQ represents a perfluoroalkyl group having 1 to 5 carbon atoms. RX represents a hydrogen atom or a monovalent base-labile group.
    Type: Application
    Filed: May 9, 2014
    Publication date: September 4, 2014
    Applicant: JSR CORPORATION
    Inventors: Kiyoshi TANAKA, Shinya MINEGISHI, Kazunori KUSABIRAKI, Takahiro HAYAMA