From Fluorine-containing Monomer Patents (Class 524/544)
  • Patent number: 8820541
    Abstract: A method for producing a curable composition for imprints includes the step of passing a curable composition containing a polymerizable monomer (A) and a polymerization initiator (B) through a filter having an effective filter area of 200 cm2 or more at least one time. The method suppresses pattern-peeling when peeling the mold employed in forming a pattern using the curable composition for imprints, and thus provides excellent patternability.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: September 2, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Yuichiro Enomoto, Kunihiko Kodama, Shinji Tarutani
  • Patent number: 8822588
    Abstract: A fluorine-containing polymer has a repeating unit of the general formula (2) and is produced by homopolymerization or copolymerization with another polymerizable double bond-containing monomer. In general formula (2), W represents a linking group; R1 each independently represents a perfluoroalkyl group; Q represents a unit structure formed by cleavage of a double bond of a polymerizable double bond-containing group; and M+ represents a hydrogen cation, a metal ion or a quaternary ammonium ion.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: September 2, 2014
    Assignee: Central Glass Company, Limited
    Inventors: Yoshiharu Terui, Haruhiko Komoriya, Susumu Inoue, Takashi Kume
  • Publication number: 20140234630
    Abstract: Disclosed is a copolymer film that includes a first comonomer including a chlorofluoro olefin and a second comonomer that is selected from the group consisting of itaconic acid, 2,3-dihydropyran, D-glucal, glycerine carbonate vinyl ether, 2-hydroxypropyl acrylate, maleic anhydride, vinylidene chloride, and mixtures thereof.
    Type: Application
    Filed: February 11, 2014
    Publication date: August 21, 2014
    Inventors: Alagappan Thenappan, Bruno Ameduri, Gerald Lopez, Eric Rainal, Noureddine Ajellal, Gary Martin
  • Patent number: 8802238
    Abstract: An optical compensation film composition is disclosed herein having a polymer film and a substrate, wherein the polymer film has a positive birefringence greater than 0.005 throughout the wavelength range of 400 nm<?<800 nm, the film having been cast from a polymer solution comprising a solvent and a polymer having a moiety of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is hydrogen or a substituent on the styrenic ring.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: August 12, 2014
    Assignee: Akron Polymer Systems, Inc.
    Inventors: Xiaoliang Zheng, Dong Zhang, Jiaokai Jing, Frank Harris, Brian King, Ted Germroth, Thauming Kuo
  • Publication number: 20140221533
    Abstract: A carbon nanotube composite material having carbon nanotubes and carbon fibers dispersed in a matrix is provided wherein a carbon nanotube group formed from a plurality of the carbon nanotubes is present between the carbon fibers, an average diameter of the carbon fibers is 1 ?m or more and 50 ?m or less, an average diameter of the carbon nanotubes is 0.7 nm or more and 50 nm or less, the carbon nanotubes are included in a range of 0.01 wt % or more and 30 wt % or less and the carbon fibers are included in a range of 10 wt % or more and 60 wt % or less with respect to 100 wt % of the carbon nanotube composite material, thermal conductivity of the matrix is less than 10 W/mK, and the carbon nanotube composite material includes thermal conductivity in a direction of 10 W/mK or more.
    Type: Application
    Filed: April 7, 2014
    Publication date: August 7, 2014
    Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Kenji HATA, Seisuke ATA
  • Patent number: 8796368
    Abstract: A water- and oil-repellent comprising an aqueous dispersion of a fluorine-containing copolymer including as a copolymerization unit (a) a perfluoroalkylalkyl (meth)acrylate represented by the general formula CnF2n+1CmH2mOCOCR?CH2 (wherein R represents hydrogen atom or methyl group; n represents 4, 5, or 6; and m represents 1, 2, 3, or 4), (b) benzyl (meth)acrylate, (c) a fluorine-free polymerizable monomer other than benzyl (meth)acrylate, and (d) a cross-linkable group-containing polymerizable monomer; and a blocked isocyanate added to the aqueous dispersion in a weight ratio of 0.05 to 3.0 to the weight of the solid content of the aqueous dispersion.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: August 5, 2014
    Assignee: Unimatec Co., Ltd.
    Inventors: Ji-Shan Jin, Sumiko Mouri, Katsuyuki Sato
  • Patent number: 8784961
    Abstract: Perfluoropolymer composites are provided which are obtained by dispersing layered-silicates having properties of swelling or cleaving in dispersion media in perfluoropolymers and having the ratio of the viscosity, V0.1, at 0.1 rad/sec by a parallel plate mode of a dynamic rheometer to the viscosity, V1, measured at 1 rad/sec is 1.5 or greater, viscosity being measured at 340° C. A method for making the perfluoropolymer composites is provided, and molded articles therefrom. And additionally, perfluoropolymer composites, where layered-silicates having properties of swelling or cleaving in dispersion media are dispersed in perfluoropolymers, with the storage elasticity of 2 times or higher than that of fluoropolymers, at temperatures greater than the glass transition temperature of perfluoropolymers.
    Type: Grant
    Filed: June 11, 2009
    Date of Patent: July 22, 2014
    Inventors: Pham Hoai Nam, Jeong Chang Lee, Kenji Oki, Hajime Sato
  • Patent number: 8785556
    Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Durable, weatherable and scratch-resistant coatings are provided by compositions comprising a fluorinated component and an adhesion promoter compound. The adhesion promoter compound can include an alkoxy group, a furfuryl-containing ring structure, and a reactive group.
    Type: Grant
    Filed: April 30, 2012
    Date of Patent: July 22, 2014
    Assignee: Cytonix, LLC
    Inventor: James F. Brown
  • Patent number: 8779065
    Abstract: The present invention provides a fluorine-containing curable resin that can impart high stain resistant properties to the surface of a cured coating film and can exhibit high stain resistant properties even when curing is performed in an air atmosphere (in the presence of oxygen). It is also an object to provide an active-energy-ray-curable composition that uses the fluorine-containing curable resin and can exhibit high stain resistant properties even when curing is performed in an air atmosphere and a cured product of the active-energy-ray-curable composition. To achieve the object, there is provided a fluorine-containing curable resin including a poly(perfluoroalkylene ether) chain, a maleimide group, and a mercapto group in a structure of a urethane polymer or a polymer composed of a monomer having a polymerizable unsaturated group.
    Type: Grant
    Filed: June 11, 2012
    Date of Patent: July 15, 2014
    Assignee: DIC Corporation
    Inventors: Yusuke Ozaki, Hideya Suzuki
  • Patent number: 8760728
    Abstract: Provided is a transparent plate for a platen which is used in a document scanning apparatus, including a transparent supporting member, and a transparent protective layer that has a self-repairability and has a surface coefficient of kinetic friction with respect to copy paper of 0.7 or less on the transparent supporting member.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: June 24, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Tomoko Miyahara, Hisae Yoshizawa, Hiroshi Saegusa, Kazunori Anazawa, Kaoru Torikoshi
  • Publication number: 20140171584
    Abstract: A fluorine-containing compound represented by the formula 1, where R1 is a methyl group or trifluoromethyl group, each of R2 and R3 is independently a hydrogen atom or a group containing (a) a hydrocarbon group having a straight-chain, branched or ring form and having a carbon atom number of 1-25 or (b) an aromatic hydrocarbon group, the group optionally containing at least one of a fluorine atom, an oxygen atom and a carbonyl bond, l is an integer of from 0 to 2, each of m and n is independently an integer of 1-5 to satisfy an expression of m+n?6, and when at least one of R1, R2 and R3 is in a plural number, the at least one of R1, R2 and R3 may be identical with or different from each other.
    Type: Application
    Filed: February 24, 2014
    Publication date: June 19, 2014
    Applicant: Central Glass Company, Limited
    Inventors: Shinichi SUMIDA, Haruhiko KOMORIYA, Kazuhiko MAEDA
  • Patent number: 8754167
    Abstract: Disclosed is an active energy ray-curing composition containing an active energy ray-curing prepolymer (A) obtainable by a reaction of an acrylic-based prepolymer having a hydroxyl group and an acrylic monomer (a4) having an isocyanate group, an active energy ray-curing compound (B) having a benzotriazole group, another active energy ray-curing compound (C) differing from the (A) component and the (B) component, and inorganic oxide particles (D). The acrylic-based prepolymer having the hydroxyl group is a copolymer that includes an acrylic monomer (a1) having a piperidinyl group, an acrylic monomer (a2) having a hydroxyl group, etc., as monomer units.
    Type: Grant
    Filed: January 26, 2011
    Date of Patent: June 17, 2014
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Tetsuya Mitsuoka, Naoharu Ueda, Naohiro Hamada, Toru Oya, Satoshi Maeda, Toshifumi Midorikawa, Takenobu Nakano
  • Publication number: 20140163159
    Abstract: The present invention aims to provide a fluorine-containing polymer powder that is environmentally less harmful and forms a sufficiently smooth film without impairing the properties of the fluorine-containing polymers. The present invention relates to a fluorine-containing polymer powder including a fluorine-containing polymer prepared by suspension polymerization, which contains less than 0.1 ppm of a fluorine-containing surfactant and has an average particle size of not less than 1 ?m and less than 100 ?m and a bulk density of 0.90 to 1.50 g/cm3.
    Type: Application
    Filed: August 29, 2012
    Publication date: June 12, 2014
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Yasukazu Nakatani, Toshio Miyatani, Fumiko Shigenai, Toshiyuki Kinoshita
  • Publication number: 20140163158
    Abstract: A diaphragm including a cross-linked fluororubber layer obtained by cross-linking a fluororubber composition containing a fluororubber (A) and a carbon black (B), the cross-linked fluororubber layer having a loss modulus E? of 400 kPa or higher and 6,000 kPa or lower determined by a dynamic viscoelasticity test under conditions of measurement temperature: 160° C., tensile strain: 1%, static tension under a constant static load condition for measuring strain distribution: 157 cN, and frequency: 10 Hz.
    Type: Application
    Filed: August 16, 2012
    Publication date: June 12, 2014
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Junpei Terada, Daisuke Ota, Masanori Kitaichi, Shoji Fukuoka
  • Patent number: 8748530
    Abstract: The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (Tg), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (Tg), and to a process for making such arborescent polymers.
    Type: Grant
    Filed: July 11, 2013
    Date of Patent: June 10, 2014
    Assignees: The University of Akron, Lanxess, Inc.
    Inventors: Gabor Kaszas, Judit E. Puskas, Kevin Kulbaba
  • Publication number: 20140154420
    Abstract: This invention is directed to a copolymer comprising fluorinated (met)acrylates, alkyl methacrylates, ethoxylates (meth)acrylates, and alkyl amino (meth)acrylates. These copolymers are capable of providing improved oil and water repellency to hard substrates while also maintaining its stability in a mixture of organic solvents.
    Type: Application
    Filed: November 5, 2013
    Publication date: June 5, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: JOHN CHRISTOPHER SWOREN
  • Publication number: 20140154519
    Abstract: A solvent-based non-aqueous fluorinated methacrylate polymer comprising repeating units in any sequence from (1) at least one fluorinated methacrylate, and (2) at least one non-fluorinated alkyl acrylate and (3) at least one non-fluorinated hydroxyalkyl methacrylate, provided that a) the repeating unit of fluorinated methacrylate is present in a range of about 40%-80% by weight of total monomers added, b) the repeating unit of non-fluorinated alkyl acrylate is present in a range of about 10%-35% by weight of total monomers added, and c) the repeating unit of non-fluorinated hydroxyalkyl methacrylate is present in a range of about 5%-25% by weight of total monomers added, and d) the total of all repeating units is 100% by weight.
    Type: Application
    Filed: November 5, 2013
    Publication date: June 5, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Michael Henry Ober, John Christopher Sworen, Ernest Byron Wysong, Kathleen L. Kanetsky
  • Publication number: 20140155522
    Abstract: A superhydrophobic coating including a plurality of particles and a resin. The particles covalently bond to the resin and the resin does not fill the pores of the superhydrophobic particles such that the three dimensional surface topology of the superhydrophobic particles is preserved.
    Type: Application
    Filed: March 11, 2013
    Publication date: June 5, 2014
    Applicant: UT-BATTELLE, LLC
    Inventors: John T. SIMPSON, Georgios POLYZOS, Daniel A. SCHAEFFER
  • Patent number: 8742011
    Abstract: Disclosed is a vehicle member that includes a molded body and a protective film disposed on a surface of the molded body and formed by curing of an active energy ray-curing composition. The active energy ray-curing composition contains an active energy ray-curing prepolymer (A) obtainable by a reaction of an acrylic-based prepolymer having a hydroxyl group and an acrylic monomer (a4) having an isocyanate group, an active energy ray-curing compound (B) having a benzotriazole group, another active energy ray-curing compound (C) differing from the (A) component and the (B) component, and inorganic oxide particles (D). The acrylic-based prepolymer having the hydroxyl group is a copolymer that includes an acrylic monomer (a1) having a piperidinyl group, an acrylic monomer (a2) having a hydroxyl group, etc., as monomer units.
    Type: Grant
    Filed: January 26, 2011
    Date of Patent: June 3, 2014
    Assignee: Kabushiki Kaisha Toyota Jidoshokki
    Inventors: Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Tetsuya Mitsuoka, Naoharu Ueda, Naohiro Hamada, Toru Oya, Satoshi Maeda, Toshifumi Midorikawa, Takenobu Nakano
  • Publication number: 20140148547
    Abstract: A forming material having a layer on at least one of surfaces of a support substrate material, wherein the layer contains a fluorine-containing compound, and has a 60-degree specular gloss level prescribed in JIS Z8741 (1997 edition) greater than or equal to 60%, and the layer has a surface property with a number of peaks exceeding a root-mean-square roughness (Rq) observed under an atomic force microscope (AFM) greater than or equal to 500 and less than or equal to 1500 per 25 ?m2.
    Type: Application
    Filed: June 29, 2012
    Publication date: May 29, 2014
    Inventors: Yasuyuki Ishida, Tadahiko Iwaya, Takashi Mimura, Yasushi Takada
  • Patent number: 8735492
    Abstract: An object of the present invention is to provide a method for producing a fluoropolymer which produces a large number of particles with a small particle size using a specific non-fluorous compound having surfactant ability. The method for producing a fluoropolymer includes aqueous dispersion polymerization of a monomer including at least one fluoroolefin in the presence of a compound (1) represented by the formula: CH2?CR1—R2—O-(AO)p—X (in the formula, R1 is hydrogen or an alkyl group; R2 is an alkylene group having two or more carbon atoms; AO is a linear or branched oxyalkylene group having 2 to 4 carbon atoms; p is a positive integer; X is H or SO3Y wherein Y is NH4 or an alkaline metal; and AO may be the same or different and may form two or more blocks if there is more than one AO.
    Type: Grant
    Filed: August 25, 2010
    Date of Patent: May 27, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Katsuhiko Imoto, Shumi Nishii, Yoshinari Fukuhara
  • Publication number: 20140142239
    Abstract: A compound of formula CF2?CFCF2OSF5 and polymers comprising recurring units deriving from CF2?CFCF2OSF5 are disclosed as well as processes for their preparation.
    Type: Application
    Filed: June 15, 2012
    Publication date: May 22, 2014
    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Cristiano Monzani, Vito Tortelli
  • Patent number: 8729175
    Abstract: Fluoroelastomeric gel having the following properties: appearance: transparent gelatinous solid; water content between 10% and 90% by weight; density between 1.1 and 2.1 g/cm3; said gel satisfies the following test: dried in a stove at 90° C. until a constant weight gives curable fluoroelastomers.
    Type: Grant
    Filed: July 9, 2013
    Date of Patent: May 20, 2014
    Assignee: Solvay Solexis S.p.A.
    Inventors: Marco Apostolo, Stefano Arrigoni, Margherita Albano
  • Patent number: 8722780
    Abstract: The present invention provides a perfluoroelastomer composition comprising: a perfluoroelastomer having a nitrogen-containing curing site; and a catalyst mixture comprising: a tertiary amine; and an organic dicarboxylic acid represented by general formula (1) or (2) in an amount of 0.4 to 2 mol per mol of the tertiary amine: HOOC—COOH??(1) HOOC-A-COOH??(2) wherein A in formula (2) is an alkyl group having 1 to 10 carbon atoms or a phenyl group, which may be partially or fully fluorinated. Also disclosed is a perfluoroelastomer molded article obtained from the composition.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: May 13, 2014
    Assignee: Nichias Corporation
    Inventors: Tomoya Shimizu, Naoya Kuzawa, Takeshi Kuboyama, Hideyuki Shishitani
  • Publication number: 20140127434
    Abstract: The invention pertains to a composition (C1) comprising: at least one (meth)acrylic modified VDF polymer [polymer (A)] comprising recurring units derived from comprising recurring units derived from vinylidene fluoride (VDF) monomer and at least one hydrophilic (meth)acrylic monomer (MA) of formula (I), wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group; at least one inorganic UV blocker compound in an amount not exceeding 5% wt, with respect to the weight of polymer (A), to multilayer assemblies comprising one layer made from said composition (C1), to a method for manufacturing said multilayer assemblies and to the use of the same in different field of use, including protection of PV modules.
    Type: Application
    Filed: July 10, 2012
    Publication date: May 8, 2014
    Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    Inventors: Stefano Mortara, Julio A. Abusleme
  • Patent number: 8716385
    Abstract: Disclosed is a polymerizable fluoromonomer represented by the following general formula (1). In the formula, R1 represents a hydrogen atom, methyl group, fluorine atom, or trifluoromethyl group. n is an integer of 0 or 1, and m is that of from 1 to (3+n). R2 and R3 each independently represents a hydrogen atom or a protective group. A resist containing a fluoropolymer obtained by polymerizing or copolymerizing the monomer is suitable for use in microfabrication by immersion exposure or by a double patterning process based on immersion exposure.
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: May 6, 2014
    Assignee: Central Glass Company, Limited
    Inventors: Haruhiko Komoriya, Shinichi Sumida, Kenjin Inomiya, Takashi Mori, Takamasa Kitamoto, Yusuke Kanto
  • Patent number: 8710142
    Abstract: The present invention provides a low-staining room temperature curable coating composition having an excellent low-staining property and recoatability, and comprising (A) a hydroxyl-containing resin, (B) an isocyanate based curing agent, (C) an organosilicate based hydrophilizing agent, (D) a recoatability modifier and (E) an organic solvent, in which the recoatability modifier (D) comprises at least (D1) an amide-containing polymer and (D2) a silane coupling agent.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: April 29, 2014
    Assignee: Daikin Industries, Ltd.
    Inventors: Akira Chida, Shinya Murakami, Susumu Wada
  • Publication number: 20140113517
    Abstract: An aqueous emulsion composition comprising: i) partially fluorinated copolymer; ii) one or more co-solvents; iii) one or more surfactants; and optionally iv) one or more defoamers; wherein the co-solvent comprises fatty acids, esters of fatty acids, glycerides, glycols, or mixture thereof, and is useful for providing water and oil repellency to fibrous substrates without excessive pad roller build-up during application.
    Type: Application
    Filed: September 23, 2013
    Publication date: April 24, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: GERALD ORONDE BROWN, JOHN CHRISTOPHER SWOREN
  • Patent number: 8691344
    Abstract: Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (?m), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processible fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (?m).
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: April 8, 2014
    Assignee: Whitford Corporation
    Inventors: Leonard W. Harvey, Michael Coates, Julie K. Wright
  • Publication number: 20140093826
    Abstract: A composition for forming a liquid immersion upper layer film includes a polymer component including a polymer having a structural unit represented by a formula (1); and a solvent. R1 represents a carboxy group or a group represented by a formula (2); X represents a single bond, a divalent hydrocarbon group having 1 to 20 carbon atoms or a divalent fluorinated hydrocarbon group having 1 to 20 carbon atoms; R2 represents a hydrocarbon group having 1 to 20 carbon atoms and a valency of (n+1), a fluorinated hydrocarbon group having 1 to 20 carbon atoms and a valency of (n+1), or one of these groups each including between adjacent two carbon atoms thereof —CO—, —COO—, —O—, —NR?—, —CS—, —S—, —SO—, —SO2— or a combination thereof; and R3 represents a hydrogen atom or a monovalent organic group having 1 to 20 carbon atoms.
    Type: Application
    Filed: September 20, 2013
    Publication date: April 3, 2014
    Applicant: JSR CORPORATION
    Inventors: Shinya MINEGISHI, Kiyoshi TANAKA, Kazunori KUSABIRAKI
  • Publication number: 20140094557
    Abstract: A true tetrafluoroethylene (TFE) copolymer of the fine powder type is provided, wherein the copolymer contains polymerized comonomer units of at least one comonomer other than TFE in concentrations of at least or exceeding 1.0 weight percent, and which can exceed 5.0 weight percent, wherein the copolymer is expandable, that is, the copolymer may be expanded to produce strong, useful, expanded TFE copolymeric articles having a microstructure of nodes interconnected by fibrils. Articles made from the expandable copolymer may include tapes, membranes, films, fibers, and are suitable in a variety of end applications, including medical devices.
    Type: Application
    Filed: December 4, 2013
    Publication date: April 3, 2014
    Applicant: W. L. Gore & Associates, Inc.
    Inventor: Lawrence A. Ford
  • Patent number: 8686078
    Abstract: Provided is a rubber composition, which is excellent in fuel permeation resistance, and is capable of achieving improvements in low-temperature embrittlement property and solvent crack property. The rubber composition includes: a fluororubber having a fluorine concentration content of 70 to 71 wt % as a main component; a crosslink-type agent; and the following components (A) and (B), in which: the total content [(A)+(B)] of the above-mentioned components (A) and (B) falls within the range of 17 to 25 parts by weight with respect to 100 parts by weight of the above-mentioned fluororubber; and a weight ratio (A)/(B) of the content of the above-mentioned component (A) to the content of the above-mentioned component (B) falls within the range of 2.0/1 to 3.0/1: (A) barium sulfate; and (B) a neutral silica.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: April 1, 2014
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Masashi Noda, Eiji Matsunaga
  • Patent number: 8679578
    Abstract: A method of manufacturing an anti-reflection film, the method forming a multi-layer structure with different refractive indices from a coating composition in which the following (A) to (F) components are mixed. (A) Fluorine-containing polymer including a fluorine-containing hydrocarbon structure and a constituent unit derived from a compound having at least one group selected from a polyalkylene oxide group and a basic functional group, (B) Low refractive index inorganic fine particles which are not surface-modified or low refractive index inorganic fine particles which are surface-treated with a silane coupling agent having the molecular weight of 600 or less, (C) A curable binder containing no fluorine atoms in the molecule, (D) A solvent, (E) A polyfunctional fluorine-containing curable compound, and (F) High refractive index inorganic fine particles treated with a specific surface modifying agent.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: March 25, 2014
    Assignee: Fujifilm Corporation
    Inventors: Nobuyuki Akutagawa, Hiroyuki Yoneyama, Daiki Wakizaka
  • Patent number: 8669319
    Abstract: A polymer is provided comprising a first pendant group selected from at least one of a perfluorinated ether group or a perfluoroalkanesulfonamido group, a second pendant group comprising an ammonium group, wherein the second pendant group is free of silicon, and a third pendant group comprising an ammonium group and a reactive silicon-containing group. A composition comprising the polymer is provided. The polymer and composition are useful for protecting a substrate, for example, to render the substrate oil repellent, water repellent, or both, or to provide stain repellency to the substrate.
    Type: Grant
    Filed: December 10, 2012
    Date of Patent: March 11, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Rudolf J. Dams, Suresh S. Iyer, Chetan P. Jariwala, Thomas P. Klun, Inge Nuyts
  • Patent number: 8668992
    Abstract: The present invention provides new polyimide materials suitable for use in optically transparent fiber composites, ribbon composites, and optical communications applications. The polyimide compounds include monomeric repeat units comprising a fluorinated moiety and a fluorene cardo structure. The polyimides exhibit good optical transparency and have a low absolute thermo-optic coefficient (|dn/dT|).
    Type: Grant
    Filed: June 1, 2011
    Date of Patent: March 11, 2014
    Assignee: Brewer Science Inc.
    Inventors: Wenbin Hong, Tantiboro Ouattara, Kang Le Wang
  • Publication number: 20140051797
    Abstract: To provide a water/oil repellent composition which can impart sufficient post-air-drying water/oil repellency to the surface of an article, and which presents a low environmental impact, and an article having its surface treated with the water/oil repellent composition. A water/oil repellent composition comprising a copolymer (A) having structural units based on a monomer (a), structural units based on a monomer (b), structural units based on a monomer (c) and/or structural units based on a monomer (d); and an aqueous medium (B) containing water, and a film-forming assistant (x) and/or a film-forming assistant (y). Monomer (a): a monomer having a C1-6 polyfluoroalkyl group, monomer (b): vinylidene chloride, monomer (c): a monomer, the homopolymer of which has a glass transition temperature of at least 20° C., monomer (d): a monomer having a crosslinkable functional group, film-forming assistant (x): a specific amide solvent, and film-forming assistant (y): a specific glycol solvent.
    Type: Application
    Filed: October 24, 2013
    Publication date: February 20, 2014
    Applicant: Asahi Glass Company, Limited
    Inventors: Kyouichi KANEKO, Kazunori Sugiyama, Reika Fukuda, Takao Hirono
  • Patent number: 8653213
    Abstract: Hydrophobic coating compositions are provided as are processes to coat articles with the compositions. Extremely hydrophobic coatings are provided by the compositions. Compositions that include perfluorohexyl(meth)acrylate and a branched or high Tg monomer are provided as are articles coated with the polymerization product of the composition. Methods are also provided for forming hydrophobic coatings on articles.
    Type: Grant
    Filed: August 16, 2011
    Date of Patent: February 18, 2014
    Assignee: Cytonix, LLC
    Inventor: James F Brown
  • Patent number: 8642177
    Abstract: A method to provide acid etch resistance to contacting a calcareous substrate with a copolymer prepared from fluorinated methacrylate, short chain branched (meth)acrylate, and (meth)acrylic acid salt and a treated substrate.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: February 4, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Brad M Rosen, Siddhartha R. Shenoy, Anilkumar Raghavanpillai, Ernest Bryon Wysong, Joel M Pollino, James J Hughes, John Russell Crompton, Jr.
  • Publication number: 20140030592
    Abstract: An electrode binder composition is used to produce an electrode used for an electrical storage device, and includes (A) a polymer, (B) a compound represented by the following general formula (1), and (C) a liquid medium, the polymer (A) being fluorine-containing polymer particles or diene polymer particles, and a concentration of the compound (B) in the electrode binder composition being 5 to 500 ppm. wherein R1 and R2 independently represent a hydrogen atom, a halogen atom, or a monovalent alkyl group, and n is an integer from 0 to 5.
    Type: Application
    Filed: September 27, 2013
    Publication date: January 30, 2014
    Applicant: JSR CORPORATION
    Inventors: Maki MAEGAWA, Tatsuaki HONDA, Tatsuya ABE, Hiroyuki MIYAUCHI
  • Patent number: 8632856
    Abstract: Highly water repellent coated articles may be made by applying to a substrate a coating having dispersed therein or sprinkled thereon partially or fully fluorinated polymer microparticles. The coating includes a partially fluorinated hexafluoropropylene copolymer binder in a nonfluorinated solvent that dissolves the binder and does not dissolve the microparticles. The coating is heated sufficiently to bond the microparticles to the binder but not so much as to cause the receding water contact angle for the coating to fall below 80°.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: January 21, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Naiyong Jing, Lisa P. Chen
  • Publication number: 20140018492
    Abstract: Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH2?CH—O—(CH2)n—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R1R2C?CR3—(CH2)m—COOH wherein R1, R2, and R3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.
    Type: Application
    Filed: March 30, 2012
    Publication date: January 16, 2014
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Yuji Imahori, Hirotoshi Yoshida, Mayumi Iida, Kengo Ito, Yoshito Tanaka, Katsuhiko Imoto, Takuma Kawabe, Akiko Ohya
  • Publication number: 20140011023
    Abstract: Provided herein are the polymers shown below. The value n is a positive integer. R1 is an organic group, and each R2 is H or a chemisorbed group, with at least one R2 being a chemisorbed group. The polymer may be a nanostructured film. Also provided herein is a method of: converting a di-p-xylylene paracyclophane dimer to a reactive vapor of monomers; depositing the reactive vapor onto a substrate held at an angle relative to the vapor flux to form nanostructured poly(p-xylylene) film; reacting the film with an agent to form hydrogen atoms that are reactive with a precursor of a chemisorbed group, if the film does not contain the hydrogen atoms; and reacting the hydrogen atoms with the precursor. Also provided herein is a device having a nanostructured polyp-xylylene) film on a pivotable substrate. The film has directional hydrophobic or oleophobic properties and directional adhesive properties.
    Type: Application
    Filed: September 5, 2013
    Publication date: January 9, 2014
    Applicant: The Government of the United States of America, as represented by the Secretary of the Navy
    Inventors: Walter J. Dressick, Melik C. Demirel, Alok Singh
  • Patent number: 8617765
    Abstract: Ionomeric polymers that are chemically stabilized and contain inorganic fillers are prepared, and show reduced degradation. The ionomers care useful in membranes and electrochemical cells.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: December 31, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventor: Mark Gerrit Roelofs
  • Patent number: 8618203
    Abstract: The present invention relates to a heat-meltable fluoropolymer composite composition having excellent thermal conductivity, gas and chemical liquid barrier properties and dynamic properties such as storage modulus which comprises a heat-meltable fluoropolymer fine powder and a layered-compound organized by treatment with tetraphenyl phosphonium ions. The present invention also relates to a heat-meltable fluoropolymer composite composition having similar properties to those mentioned above which is obtained by a process (I) in which a heat-meltable fluoropolymer composite composition is obtained by grinding and mixing a heat-meltable fluoropolymer fine powder and a layered-compound and a process (II) in which such heat-meltable fluoropolymer composite composition thus obtained is melted and mixed under shear stress by means of a melt-mixing extruder.
    Type: Grant
    Filed: October 16, 2009
    Date of Patent: December 31, 2013
    Assignees: Dupont-Mitsui Fluorochemicals Co., Ltd., E.I. Dupont de Nemours & Company
    Inventors: Jeong Chang Lee, Noriyuki Suzuki, Shousaku Kondo, Hajime Sato
  • Patent number: 8614275
    Abstract: A composition comprises a polymer having a first pendant group selected from at least one perfluorinated ether group or perfluoroalkanesulfonamido group, a second pendant group comprising an ammonium group, wherein the second pendant group is free of silicon, and a third pendant group comprising an ammonium group and a reactive silicon-containing group. The polymer and composition are useful for protecting a substrate, for example, to render the substrate oil repellent, water repellent, or both, or to provide stain repellency to the substrate.
    Type: Grant
    Filed: February 18, 2013
    Date of Patent: December 24, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Rudolf J. Dams, Thomas P. Klun, Inge Nuyts
  • Publication number: 20130337161
    Abstract: An organic-inorganic composite film containing an organic-inorganic composite including an inorganic compound particle and a polymer bonded to the inorganic compound particles. A percentage of voids in the film is 3 to 70 volume % with reference to a volume of the film.
    Type: Application
    Filed: February 20, 2012
    Publication date: December 19, 2013
    Applicant: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Mitsuyo Akimoto, Kenya Tanaka
  • Patent number: 8609756
    Abstract: Polymeric composition based on a PVDF homopolymer and a thermoplastic fluorocopolymer Polymeric composition based on a PVDF homopolymer and a thermoplastic fluoropolymer offering an improved toughness/processability compromise, possessing an apparent melt viscosity not exceeding 60 000 Pa·s at a shear rate of 1 s?1, a ductile-brittle transition temperature below +5° C. and a weight loss in air at 150° C. of 5% or less. Pipes and fashioned articles prepared from this composition.
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: December 17, 2013
    Assignee: Solvay (Societe Anonyme)
    Inventors: Thierry Baert, Bernard Goffaux, Vincent Bodart, Stephane Heuschling
  • Patent number: 8598267
    Abstract: The present invention provides a fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g/mol or contains the fluorinated surfactant having a molecular weight of less than 1000 g/mol in an amount of not more than 0.025% by weight based on the total weight of solids in the dispersion. The dispersion further comprises a non-ionic surfactant and an anionic surfactant selected from fluorinated anionic surfactants having a molecular weight of at least 1000 g/mol, non-fluorinated anionic surfactants and mixtures thereof.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: December 3, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Michael C. Dadalas, Rebekka Epsch, Friedrich Kloos, Leonard W. Harvey
  • Patent number: 8592508
    Abstract: Disclosed is a top coat composition for photoresist, which is characterized by containing a fluorinated polymer having a repeating unit represented by general formula (5). In the formula, R1 represents a hydrogen atom, a methyl group, a fluorine atom, or a trifluoromethyl group; n represents 0 or 1; m represents an integer of 1 to (3+n); and R2 or R3 represents a hydrogen atom or a protecting group. The top coat composition has a proper degree of solubility in a developing solution.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: November 26, 2013
    Assignee: Central Glass Company, Limited
    Inventors: Haruhiko Komoriya, Shinichi Sumida, Kenjin Inomiya, Takashi Mori, Takamasa Kitamoto, Yusuke Kanto
  • Patent number: 8586184
    Abstract: Disclosed is a fluorine-containing polymer having (A) repeating units derived from a fluorine-containing acrylate monomer, and (B) repeating units derived from an amino group-containing monomer, wherein the fluorine-containing polymer is water-soluble. The fluorine-containing polymer has sufficiently high solubility, and can impart high water repellency, high oil repellency and high soil resistance to a porous substrate.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: November 19, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Teruyuki Fukuda, Akihiko Ueda, Shigeru Maruyama