At Least One Polyol Containing Only Two -c-oh Groups Reactant Patents (Class 524/604)
  • Publication number: 20130313468
    Abstract: The thermoplastic resin in accordance with the present invention includes a unit (A) by 25 mol % to 60 mol %, the unit (A) having a biphenyl group, a linear unit (e.g., a linear aliphatic hydrocarbon chain) (B) by 25 mol % to 60 mol %, and a unit (C) by 1 mol % to 25 mol %, the unit (C) having a substituent selected from the group consisting of non-fused aromatic groups, fused aromatic groups, heterocyclic groups, alicyclic groups, and alicyclic heterocyclic groups, each of which has an effect of folding a main chain.
    Type: Application
    Filed: February 7, 2012
    Publication date: November 28, 2013
    Applicant: KANEKA CORPORATION
    Inventors: Mitsuru Nakamura, Shusuke Yoshihara
  • Publication number: 20130302628
    Abstract: A protective coating including a crosslinked polyester that is removable with a basic composition, as well as coated articles, methods of preparing a protective coating, and methods of using a protective coating.
    Type: Application
    Filed: April 19, 2013
    Publication date: November 14, 2013
    Applicant: NDSU Research Foundation
    Inventors: Tara J. Shedlosky, Gordon P. Bierwagen, Dean C. Webster, Andrew M. Huovinen
  • Publication number: 20130296488
    Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.
    Type: Application
    Filed: July 8, 2013
    Publication date: November 7, 2013
    Inventors: Stacey James Marsh, Angela Hartley Honeycutt
  • Publication number: 20130289154
    Abstract: Radiation-curable formulations leading to flexible coatings with enhanced corrosion control on metal substrates. The invention relates to radiation-curable formulations which in the cured state offer a particular degree of corrosion control for metallic substrates and at the same time are sufficiently flexible for deformation.
    Type: Application
    Filed: June 28, 2013
    Publication date: October 31, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Emmanouil SPYROU, Thorsten Brand
  • Publication number: 20130280453
    Abstract: A coating composition comprising a polyester resin binder and a phosphatized polyester. The compositions are useful for coating containers such as food and beverage containers. The compositions have excellent hydrolytic stability upon storage at high temperature. The compositions are formulated to be substantially free of bisphenol A (BPA) and bisphenol A diglycidyl ether (BADGE).
    Type: Application
    Filed: June 21, 2013
    Publication date: October 24, 2013
    Inventors: Carl Seneker, Jessica Williamson, Claudia Knotts, Youssef Moussa
  • Publication number: 20130281619
    Abstract: Provided is a polyester polymer including a repeating unit derived from a dicarboxylic acid compound containing a partial structure represented by the following Formula (C) and a repeating unit derived from a diol compound containing a cyclic structure, in which the partial structure represented by Formula (C) constitutes a portion of the main chain: wherein in Formula (C), RA and RB each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; n and in each independently represent an integer from 0 to 2; Cy represents an unsaturated 6-membered or 7-membered ring which may contain a heteroatom; and * and ** each represent a bonding hand, while * may be a bonding hand extending from RA.
    Type: Application
    Filed: June 19, 2013
    Publication date: October 24, 2013
    Inventors: Shigeki UEHIRA, Toshimitsu SAKUMA, Toshihide YOSHITANI, Kozo SATO
  • Publication number: 20130214441
    Abstract: The present invention provides aqueous stable suspensions of biodegradable diblock copolyesters and a method for their production. The diblock copolyesters comprise one block of an aliphatic polyester and one block of a polyethylene oxide. Suspensions according to the present invention are suitable to be used as biodegradable viscosity modifiers, compatibilizers in blends, as glues, varnishes, paper additives, flame retardants, impact modifiers and hazers of transparent plastics, and for the production of biodegradable sheets, films, fibers, plates, vessels, tubes and capillaries for transport or packaging purposes. Furthermore, the suspensions according to the present invention are suitable to be used for the production of nano- and microfibers and nano- and microfiber nonwovens with non-oriented or oriented fibers by means of electrospinning.
    Type: Application
    Filed: August 12, 2011
    Publication date: August 22, 2013
    Applicant: PHILLIPS-UNIVERSITÄT MARBURG
    Inventors: Andreas Greiner, Seema Agarwal, Kathrin Bubel
  • Patent number: 8513343
    Abstract: The present invention relates to unsaturated polyester resin composition comprising an unsaturated polyester resin, a manganese compound, a 1,3-dioxo compound and a base; the molar ratio between the dioxo compound and the basic functionality of the base is from 170:1 to 1:30 and the resin composition being curable with a peroxide. The present invention further relates to a process for radically curing such a resin composition wherein a peroxide is added to the resin composition and the curing is effected in the absence of cobalt.
    Type: Grant
    Filed: July 5, 2007
    Date of Patent: August 20, 2013
    Assignee: DSM IP Assets B.V.
    Inventors: Johan Franz Gradus Antonius Jansen, Ronald Ivo Kraeger
  • Publication number: 20130211002
    Abstract: The invention relates to heat-curable powder coating composition comprising: i) at least one crystalline polyester resin present in an amount of at least 7.5 wt %; and ii) at least one amorphous polyester resin present in an amount of at most 92.5 wt %; and iii) at least one peroxide present in an amount of at least 0.
    Type: Application
    Filed: May 6, 2011
    Publication date: August 15, 2013
    Applicant: DSM IP Assets B.V.
    Inventors: Tosko Misev, Leendert Jan Molhoek, Johan Franz Gradus Jansen, Matthias Johannes Cornelis Bos, Gerrit Johannes De Lange, Gerbert Dijkstra
  • Publication number: 20130203938
    Abstract: The invention relates to a heat-curable powder coating composition comprising i) at least one crystalline polyester resin present in an amount of at most 90 wt %; and ii) at least one amorphous polyester resin; and iii) at least one crosslinking agent; and iv) at least one thermal radical initiator, wherein, the at least one crystalline polyester resin and/or the at least one amorphous polyester resin has di-acid ethylenic unsaturations; wherein the at least one crosslinking agent is either crystalline or amorphous; wherein the at least one crosslinking agent has reactive unsaturations that are reactable with the ethylenic unsaturations of the di-acid ethylenic unsaturations of the at least one crystalline polyester resin and/or the at least one amorphous polyester resin to be crosslinked, said unsaturations of the crosslinking agent are different from the unsaturations of the at least one crystalline polyester resin and the unsaturations of the at least amorphous polyester resin; wherein the wt % is based on
    Type: Application
    Filed: May 6, 2011
    Publication date: August 8, 2013
    Applicant: DMS IP ASSETS B.V.
    Inventors: Tosko Alexandar Misev, Leendert Jan Molhoek, Johan Franz Gradus Antonius Jansen, Nicole Van Der Werf, Sven Johan Wilbert Reijmer, Jan Pieter Drijfhout, Peter Wellenberg
  • Patent number: 8501851
    Abstract: The present invention relates to a pre-accelerated resin composition comprising an unsaturated polyester resin and/or a vinyl ester resin, wherein the composition further comprises a. a copper salt, and b. a compound according to formula (1) in which R can be selected from H, optionally substituted C1-C20 alkyl, optionally substituted C6-C20 aryl, and wherein the copper is present in an amount of more than 0.1 mmol/kg resin.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: August 6, 2013
    Assignee: DSM IP Assets B.V.
    Inventors: Johan Franz Gradus Antonius Jansen, Ronald Ivo Kraeger
  • Patent number: 8487040
    Abstract: HVAC and building and construction components are molded from novel compositions that meet the flame spread and smoke index, as well as the molding, safety, strength, and aesthetic requirements for this use. These compounds are based on a polyester resin and more specifically can be an polypropylene glycol dicyclopentadiene copolymerized with maleic anhydride, a low profile additive and hydroxy ethyl methacrylate monomer with additional additives including an appropriate catalyst package, a mold release agent, a thickening agent, a loading of aluminum hydroxide which is from about 40 to 65% by weight, and having a loading of glass fibers of from about 10 to about 25%.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: July 16, 2013
    Assignee: Premix Inc.
    Inventors: Thomas J. Cebasek, Michael Gruskiewicz, Steven Ted Searl
  • Patent number: 8487041
    Abstract: The present invention relates to a resin composition comprising (a) an unsaturated polyester resin having a molecular weight Mn of at least 750 Dalton and at most 5000 Dalton and (b) a reactive diluent, wherein the unsaturated polyester resin comprises C5-C10 unsaturated diacid building blocks and isosorbide building blocks. Preferably, at least part of the isosorbide is derived from a non-fossil source. Preferably, itaconic acid or anhydride is used as the C5 unsaturated dicarboxylic acid.
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: July 16, 2013
    Assignee: DSM IP Assets B.V.
    Inventors: Marian Henryk Szkudlarek, Johan Franz Gradus Antonius Jansen, Stefanus Jacobus Duyvestijn
  • Patent number: 8481641
    Abstract: HVAC and building and construction components are molded from novel compositions that meet the flame spread and smoke index, and the molding, safety, strength, and aesthetic requirements for this use. In a further embodiment, these compounds also promote better indoor air quality by inhibiting the growth of microbial contaminants within and on the surface of products molded therefrom. These compounds are based on thermoset resin, e.g. a polyester resin which preferably can comprise a polypropylene glycol dicyclopentadiene copolymerized with maleic anhydride, a low profile additive and hydroxy ethyl methacrylate monomer with additional additives including an appropriate catalyst package, a mold release agent, a thickening agent, a loading of aluminum hydroxide which is from about 40 to 65% by weight, having a loading of glass fibers of from about 10 to about 25% and preferably containing a silver ion containing antimicrobial agent, such as soluble glass containing silver ions.
    Type: Grant
    Filed: April 8, 2011
    Date of Patent: July 9, 2013
    Assignee: Premix Inc.
    Inventors: Thomas J. Cebasek, Michael Gruskiewicz, Steven T. Searl
  • Publication number: 20130158168
    Abstract: Provided are aliphatic-aromatic copolyetheresters that can exhibit biodegradation with improved physical properties. The copolyetheresters can be blended with other polymeric materials, and are useful for making a variety of shaped articles. The aliphatic-aromatic copolyetheresters can include combinations of terephthalic acid or ester with linear aliphatic, or a non-linear dicarboxylic acid or ester, that is condensed with a linear glycol and a polyalkylene ether glycol.
    Type: Application
    Filed: December 12, 2012
    Publication date: June 20, 2013
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventor: E I DU PONT DE NEMOURS AND COMPANY
  • Patent number: 8445107
    Abstract: Process for production of multicomponent moldings, which comprises producing a molding of which at least one layer is composed of a thermoplastic molding composition composed of A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, and C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
    Type: Grant
    Filed: June 13, 2006
    Date of Patent: May 21, 2013
    Assignee: BASF SE
    Inventors: Andreas Eipper, Bernd Bruchmann, Carsten Weiss, Mark Voelkel, Bernhard Rosenau, Christophe Ginss, Kurt Hofli
  • Publication number: 20130102687
    Abstract: The present invention relates to a micelle composition comprising a hydrophobic compound and an amphiphilic block copolymer, wherein the amphiphilic block copolymer consists of a hydrophobic block A and a hydrophilic block B, the hydrophobic block A comprises at least one hydrophobic polymeric unit X and the hydrophilic block B comprises at least one hydrophilic polymeric unit Y whereby the X and Y blocks alternate. The present invention further relates to a process for the preparation of the micelle composition wherein the process comprises the steps of: a) dissolving the hydrophobic compound and the amphiphilic block copolymer in an organic solvent to form a solution, b) adding said organic solution into an aqueous medium, c) optionally repeating aforementioned steps.
    Type: Application
    Filed: March 14, 2011
    Publication date: April 25, 2013
    Inventors: Jerome George Jozeph Loui Lebouille, Tessa Kockelkoren, Leopold Franciscus Wijnand Vleugels, Remco Tuinier
  • Publication number: 20130095270
    Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 1,4-cyclohexanedimethanol. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.
    Type: Application
    Filed: October 10, 2012
    Publication date: April 18, 2013
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventor: EASTMAN CHEMICAL COMPANY
  • Publication number: 20130095272
    Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues, 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and ethylene glycol. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.
    Type: Application
    Filed: October 10, 2012
    Publication date: April 18, 2013
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventor: EASTMAN CHEMICAL COMPANY
  • Publication number: 20130095263
    Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising 2,5-furandicarboxylic acid residues; optionally, aromatic dicarboxylic acid residues and/or modifying aliphatic dicarboxylic acid residues and 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues. The polyesters may be manufactured into articles such as fibers, films, bottles, coatings, or sheets.
    Type: Application
    Filed: October 10, 2012
    Publication date: April 18, 2013
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventor: Eastman Chemical Company
  • Publication number: 20130072628
    Abstract: This invention is related to coating compositions comprising a polyester which further comprises 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, 1,4-cyclohexanedimethanol residues, and residues of a modifying glycol other than ethylene glycol, chosen from at least one of diethylene glycol, triethylene glycol, propylene glycol, neopentyl glycol, and 1,6-hexanediol; and 50 to 100 mole % of residues of at least one of phthalic anhydride, isophthalic acid, and terephthalic acid.
    Type: Application
    Filed: October 23, 2012
    Publication date: March 21, 2013
    Applicant: EASTMAN CHEMICAL COMPANY
    Inventor: Eastman Chemical Company
  • Publication number: 20130071785
    Abstract: It is an object of the present invention to provide a new alcohol compound, a polyester resin, an unsaturated polyester resin, a resin particle and an electrophotographic toner using the compound capable of using the renewable resources as a part of a raw material. An alcohol compound according to the present invention is characterized by representing the chemical formula [Chemical 1]. Furthermore, the polyester resin or the unsaturated polyester resin according to the present invention, is characterized in that the compound (wherein X is an aliphatic or an aromatic residue, Y is a refined rosin residue, a disproportionated rosin residue or a hydrogenated rosin residue, and n=0 to 1 in the formula.) is an essential component of an alcohol component. Further, the resin particle of the present invention is characterized by comprising the polyester resin.
    Type: Application
    Filed: March 2, 2011
    Publication date: March 21, 2013
    Applicant: Japan U-Pica Company, Ltd.
    Inventors: Tetsuji Moroiwa, Nobutaka Yoshida, Hiroshi Aihara, Akira Yamane, Kei Yamasaki, Keiko Taniuchi
  • Patent number: 8357742
    Abstract: A resin composition for a vibration damping material, comprising a polyester resin mainly formed of a dicarboxylic acid constitutional unit and a diol constitutional unit; and a filler, in which the polyester resin contains: a dicarboxylic acid constitutional unit (A) mainly derived from an aromatic dicarboxylic acid, in particular, isophthalic acid; a diol constitutional unit (B) mainly derived from ethylene glycol; and a constitutional unit (C) formed of an aliphatic dicarboxylic acid, an aliphatic diol, and/or an aliphatic hydroxycarboxylic acid each having 5 or more carbon atoms, and the resin composition contains, as the filler, a flake-like or plate-like filler (D) and a filler (E) made of a particulate metal oxide.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: January 22, 2013
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takuya Minezaki, Takeo Hayashi, Satoshi Yoshinaka, Kazuaki Mukasa
  • Publication number: 20130005901
    Abstract: A thermoplastic elastomer compound is disclosed having copolyester elastomer, epoxidized soybean oil, and vulcanized vegetable oil. The compound has a biorenewable content of at least about 50 weight percent of the compound. The compound can be used to make a plastic article needing a Shore A hardness of from about 40 to about 70. The compound is a sustainable solution for extruded or molded articles.
    Type: Application
    Filed: March 16, 2011
    Publication date: January 3, 2013
    Applicant: PolyOne Corporation
    Inventors: Guoqiang Qian, Krishna Venkataswamy
  • Publication number: 20120316272
    Abstract: Thermoplastic articles may be manufactured having a high degree of visual appeal to consumers. Clarifying agents may be employed as additives in such thermoplastic articles to produce high clarity articles. A coloring agent may be mixed with clarifying agents to form a first blend, and then such a first blend may be applied in very low loadings to form a clarified polymeric article. It is possible to achieve an observable visual benefit while using very low loadings of coloring agent in a polyolefin, such as polypropylene. Carbon black is a pigment that may provide such observable benefits in polypropylene.
    Type: Application
    Filed: June 26, 2012
    Publication date: December 13, 2012
    Inventors: Todd D. Danielson, Jennifer Rockwood, Nathan A. Mehl
  • Publication number: 20120301717
    Abstract: The present invention has an object to provide a solvent-free polyester-based adhesive composition having good coatability and capable of forming an adhesive that shows good adhesion performance. The present invention provides a polyester-based adhesive composition containing a polyester having Mw of from 1×103 to 20×103 as a main component and a trifunctional or more polyepoxy compound as a crosslinking agent, and containing substantially no organic solvent. The molar number, mOH, of hydroxyl group contained in a polyalcohol component constituting the polyester is from 0.5 to 0.98 times of the molar number, mCOOH, of carboxyl group contained in a polycarboxylic acid component. The composition has a viscosity at 23° C. of at most 80 Pa·s.
    Type: Application
    Filed: December 27, 2010
    Publication date: November 29, 2012
    Applicant: NITTO DENKO CORPORATION
    Inventors: Hitoshi Takahira, Satomi Yoshie, Miki Tanimura
  • Publication number: 20120258393
    Abstract: A process for making a latex emulsion suitable for use in a toner composition includes co-emulsifying a bio-based resin with an insoluble component, such as a pigment or wax, whereby the resin encapsulates the insoluble component. The resulting latex, including the insoluble component encapsulated in the resin, may then be utilized to form a toner. The insoluble component may thus be included in toner particles, which might otherwise be difficult to achieve, using emulsion aggregation processes.
    Type: Application
    Filed: April 8, 2011
    Publication date: October 11, 2012
    Applicant: XEROX CORPORATION
    Inventors: Ke Zhou, Kimberly D. Nosella, Guerino G. Sacripante, Sonja Hadzidedic
  • Publication number: 20120225977
    Abstract: Reactive compositions are formed into melt processable reactive pellets. The reactive compositions include at least one filler such as talc, clay, pulp, etc. and a reactive mixture comprising at least one polyhydric alcohol and a reactant selected from the group consisting of at least one organic polyacid; at least one organic anhydride; and combinations thereof. Alternatively, the reactive compositions comprise at least one filler and a prepolymer formed from the reactive mixture.
    Type: Application
    Filed: May 10, 2012
    Publication date: September 6, 2012
    Inventors: Isao Noda, William Maxwell Allen, JR., James Terry Knapmeyer, Michael Matthew Satkowski
  • Publication number: 20120214940
    Abstract: A thermosetting unsaturated polyester resin (UPR) composition comprising an unsaturated polyester polymer having at least two strained cycloolefinic double bonds and optional unstrained cycloolefinic double bonds, which can be cross-linked through a ring-opening metathesis polymerization (ROMP) or combination of ROMP and cationic or free radical polymerization is provided. No styrene is used in the resin composition. The thermosetting unsaturated polyester resin composition also comprises a catalyst system for the ring-opening metathesis polymerization, and in embodiments, can further comprise one or more optional unsubstituted or substituted cycloolefin monomer containing unsaturation, an optional co-catalyst selected from a cationic initiator or free radical initiator, and optional additives. The cured resin properties can be controlled through adjusting the structure and properties of the unsaturated polyester resin.
    Type: Application
    Filed: February 15, 2012
    Publication date: August 23, 2012
    Inventors: Chih-Pin Hsu, Ming Yang Zhao, Steven L. Voeks
  • Publication number: 20120207956
    Abstract: Provided is a polymer compound having a furan ring having a degree of polymerization of 185 or more and 600 or less. This polymer compound has excellent mechanical strength (flexural strength).
    Type: Application
    Filed: February 22, 2012
    Publication date: August 16, 2012
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Katsuhiro Matsuda, Hirohide Matsuhisa, Hitoshi Horie, Takeshi Komuro
  • Publication number: 20120208955
    Abstract: A double sided pressure-sensitive adhesive sheet includes a pressure-sensitive adhesive layer made from a polyester-based pressure-sensitive adhesive composition containing a polyester including at least a lactic acid unit, a dibasic acid unit, and a glycol unit, a tackifier resin, and a crosslinking agent. The dibasic acid unit includes a dimer acid, the polyester has a weight average molecular weight of 20,000 to 200,000 and a glass transition temperature of ?70 to ?20° C. as measured using a differential scanning calorimeter at a temperature rise rate of 20° C./minute, the polyester has a hydroxyl value of 1 to 60 mgKOH/g, the adhesive composition contains 10 to 70 parts by weight of the tackifier resin based on 100 parts by weight of the polyester, and the pressure-sensitive adhesive layer has a gel fraction of 50 to 90% by weight.
    Type: Application
    Filed: October 20, 2010
    Publication date: August 16, 2012
    Applicant: NITTO DENKO CORPORATION
    Inventors: Satomi Yoshie, Hitoshi Takahira
  • Publication number: 20120196968
    Abstract: The invention relates to a biaxially oriented film containing at least one black pigment. The film is predominantly formed from a polyester whose diol component includes at least 80 mol-% of 1,4-cyclohexanedimethanol (CHDM), and whose the dicarboxylic acid component includes at least 80 mol-% of one or more benzenedicarboxylic acid(s) and/or one or more naphthalene dicarboxylic acid(s). The dicarboxylic acid component includes a main dicarboxylic acid component forming an at least 55 mol-% portion, chosen from either 2,6-naphthalene dicarboxylic acid or terephthalic acid. The dicarboxylic acid component further includes a secondary dicarboxylic acid component, present in an amount of at least 18 mol-%, with the secondary dicarboxylic acid component differing from the main dicarboxylic acid component. The invention further relates to a method for producing the film and its use.
    Type: Application
    Filed: January 23, 2012
    Publication date: August 2, 2012
    Inventors: Holger Kliesch, Oliver Klein, Gottfried Hilkert, Rainer Kurz
  • Publication number: 20120196978
    Abstract: A polyester heat storage material and a preparation method thereof are disclosed. The repeating unit of the polyester's main chain comprises a diacid fragment and a polyalkylene glycol fragment. The method for preparing the polyester heat storage material includes melting diacid anhydride and polyalkylene glycol and conducting the polycondensation reaction.
    Type: Application
    Filed: June 21, 2011
    Publication date: August 2, 2012
    Applicant: TAIWAN TEXTILE RESEARCH INSTITUTE
    Inventors: Yin-Hsi Lin, Chi-Shu Wei, Cheng-Chu Lin, Ming-Chih Kuo, Sheng-Shan Chang
  • Publication number: 20120196111
    Abstract: The invention relates to a white biaxially oriented film predominantly formed from a polyester whose diol component includes at least 80 mol-% of 1,4-cyclohexanedimethanol (CHDM), and whose dicarboxylic acid component includes at least 80 mol-% of one or more benzenedicarboxylic acid(s) and/or one or more naphthalene dicarboxylic acid(s). The dicarboxylic acid component includes a main dicarboxylic acid component forming an at least 55 mol-% portion, chosen from either 2,6-naphthalene dicarboxylic acid or terephthalic acid. The dicarboxylic acid component further includes a secondary dicarboxylic acid component, present in an amount of at least 18 mol-%, with the secondary dicarboxylic acid component differing from the main dicarboxylic acid component. The invention further relates to a method for producing the film and its use.
    Type: Application
    Filed: January 23, 2012
    Publication date: August 2, 2012
    Inventors: Holger KLIESCH, Oliver Klein, Matthias Konrad, Bodo Kuhmann
  • Publication number: 20120196112
    Abstract: The invention relates to electrical insulation films incorporating biaxially oriented film predominantly formed from polyester. The polyester has a diol component that includes at least 80 mol-% of 1,4-cyclohexanedimethanol (CHDM) and a dicarboxylic acid component containing at least 80 mol-% of one or more benzenedicarboxylic acid(s) and/or one or more naphthalene dicarboxylic acid(s). The dicarboxylic acid component includes a main dicarboxylic acid component forming an at least 55 mol-% portion, chosen from either 2,6-naphthalene dicarboxylic acid or terephthalic acid. The dicarboxylic acid component further includes a secondary dicarboxylic acid component, present in an amount of at least 5 mol-%, with the secondary dicarboxylic acid component differing from the main dicarboxylic acid component. The invention further relates to a method for producing the film and its use.
    Type: Application
    Filed: January 23, 2012
    Publication date: August 2, 2012
    Inventors: Holger KLIESCH, Oliver Klein, Dagmar Klein, Ingo Fischer, Andreas Bork
  • Patent number: 8222347
    Abstract: A composition of matter comprising a thermoplastic resin composition derived from (i) a polyester derived from a cycloaliphatic diol, and an aromatic diacid; (ii) a polycarbonate derived from at least from 20 mole percent to 100 mole percent of an aromatic diol derived from structure II wherein R3 and R4 are independently selected from the group consisting of C1-C30 aliphatic, C2-C30 cycloaliphatic and C2-C30 aromatic groups, X is CH2 and m is an integer from 3 to 7, n is an integer from 1 to 4, p is an integer from 1 to 4, and from 0 mole percent to 80 mole percent of a second aromatic dihydroxy compound; and wherein the resin composition is transparent is disclosed. Also disclosed is a process to prepare this composition and articles therefrom.
    Type: Grant
    Filed: July 25, 2007
    Date of Patent: July 17, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Shreyas Chakravarti, Songping Liao, Dake Shen, Huiping Zhang
  • Publication number: 20120178866
    Abstract: The resin composition of the present invention is characterized by comprising (A) biodegradable resin, (B) at least one inorganic filler selected from a fibrous inorganic filler, a plate-like inorganic filler, a rod-like inorganic filler and a granular inorganic filler, or an organic filler having water repellency, and (C) a di- or higher functional compound or resin having an isocyanate group. The resin composition of the present invention comprises a biodegradable resin as a main resin component, but can provide molded articles excellent in hydrolysis resistance, mechanical characteristics, and dimensional stability.
    Type: Application
    Filed: March 31, 2010
    Publication date: July 12, 2012
    Applicants: SHOWA DENKO K.K., SONY CORPORATION
    Inventors: Shun Kayama, Minoru Tomita, Yukiko Shimizu, Terumitsu Kotani, Kei Takahashi
  • Publication number: 20120172520
    Abstract: Disclosed are polyester resins and solvent borne thermosetting coating compositions that include these resins in combination with at least one crosslinker. The polyester resins contain 2,2,4,4-tetramethyl-1,3-cyclobutanediol and exhibit a combination of good solubility in organic solvents and high hardness with good flexibility in a coating composition.
    Type: Application
    Filed: March 13, 2012
    Publication date: July 5, 2012
    Applicant: Eastman Chemical Company
    Inventors: Stacey James Marsh, Angela Hartley Honeycutt
  • Publication number: 20120157618
    Abstract: The present invention relates to a resin composition comprising an unsaturated polyester resin comprising 1,3-propane diol building blocks and C5-C10 unsaturated dicarboxylic acid building blocks and further comprising a reactive diluent. Preferably, at least part of the 1,3-propane diol is derived from a non-fossil source. Preferably, itaconic acid or anhydride is used as the C5 unsaturated dicarboxylic acid.
    Type: Application
    Filed: March 24, 2010
    Publication date: June 21, 2012
    Inventors: Marian Henryk Szkudlarek, Johan Franz Gradus Antonius Jansen
  • Publication number: 20120141812
    Abstract: The use of a composition which is liquid under standard conditions (20° C., 1 bar) as a coating material, wherein the composition comprises a) an unsaturated polyester resin composed of ?-olefinically unsaturated polycarboxylic acids, polyols, and optionally further compounds, b) compounds with vinyl ether groups (vinyl ethers for short), and c) optionally ?-olefinically unsaturated polycarboxylic acids or their monoesters or diesters, where the sum of the double bonds of the ?-olefinically unsaturated polycarboxylic acids from a) and optionally of the compounds c) to the double bonds of the vinyl ethers b) is in a molar ratio of 1.3:1 to 0.8:1.
    Type: Application
    Filed: August 16, 2010
    Publication date: June 7, 2012
    Applicant: BASF SE
    Inventors: Matthias Fies, Ulrich Poth, Oliver Seewald, Wolfgang Bremser
  • Publication number: 20120136117
    Abstract: The present invention relates to a resin composition comprising (a) an unsaturated polyester resin having a molecular weight Mn of at least 750 Dalton and at most 5000 Dalton and (b) a reactive diluent, wherein the unsaturated polyester resin comprises C5-C10 unsaturated diacid building blocks and isosorbide building blocks. Preferably, at least part of the isosorbide is derived from a non-fossil source. Preferably, itaconic acid or anhydride is used as the C5 unsaturated dicarboxylic acid.
    Type: Application
    Filed: March 24, 2010
    Publication date: May 31, 2012
    Inventors: Marian Henryk Szkudlarek, Hohan Franz Gradus Antonius Jamsen, Stefanus Jacobus Duyvestijn
  • Publication number: 20120136116
    Abstract: A series of resins were synthesized using a range of bio-based materials to control the molecular architecture, and therefore the properties, of the inventive resins. The utility of these resins was demonstrated in the formulation of powder coatings, such as ?-hydroxy amide crosslinked and hybrid types. Generally, the bio-based resins flowed out on heating faster than conventional petrochemically-based resins, allowing the use of lower temperatures in the curing oven than is typically possible and a more active catalyst system, especially in the carboxylic acid-epoxy crosslinked hybrid coating formulations.
    Type: Application
    Filed: January 26, 2012
    Publication date: May 31, 2012
    Inventors: Bhima R. Vijayendran, Jerry L. King, II, Katherine P. Mitchell, Michael C. Clingerman, Jeffrey T. Cafmeyer
  • Publication number: 20120121839
    Abstract: The present invention relates to a process for preparing an unsaturated polyester resin comprising itaconate ester units as reactive unsaturations by reacting at least itaconic acid and/or itaconic anhydride and at least one diol, wherein the process is effected in the presence of an inhibitor having a gelation activity factor less than or equal to (0.5) and having an efficiency factor of from (0.55) up to 1.
    Type: Application
    Filed: March 24, 2010
    Publication date: May 17, 2012
    Inventors: Marian Henryk Szkudlarek, Johan Franz Gradus Anton Jansen, Stefanus Jacobus Duyvestijn, di Silvana Rensina Antonnietta Silvestre
  • Publication number: 20120121841
    Abstract: The present invention relates to an unsaturated polyester resin comprising itaconate esters as reactive unsaturations, wherein the acid value of the resin is in the range of from 25 to 125 and the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 0.33 to 3. In one embodiment, the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 0.33 to 0.9. In another embodiment, the molar ratio of hydroxyl end groups and carboxylic acid end groups is in the range of from 1.1 to 3.
    Type: Application
    Filed: March 24, 2010
    Publication date: May 17, 2012
    Applicant: DSM IP Assets B.V.
    Inventors: Marian Henryk Szkudlarek, Johan Franz Gradus Antonius Jansen, Silvana Rensina Antonnietta Di Silvestre, Stefanus Jacobus Duyvestijn
  • Patent number: 8178630
    Abstract: The present invention relates to a preparation comprising at least one specific oligomeric siloxane component and at least one polymer component, to processes for producing it and to its use in formulations, more particularly metal coating formulations.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: May 15, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Rene Koschabek, Martin Bartmann, Thorsten Brand, Burkhard Standke, Roland Edelmann, Christian Wassmer
  • Patent number: 8163841
    Abstract: Polyethylene naphthalate fibers that are characterized in that the fibers have a crystal volume of from 550 to 1,200 nm3 obtained by wide angle X-ray diffraction of the fiber and a degree of crystallization of from 30 to 60%. It is preferred that the fibers have a maximum peak diffraction angle of wide angle X-ray diffraction of from 25.5 to 27.0° and a melting point of from 285 to 315° C. The production method thereof is characterized in that a particular phosphorus compound is added to the polymer in a molten state, the spinning draft ratio after discharging from the spinneret is from 100 to 5,000, and the molten polymer immediately after discharging from the spinneret is allowed to pass through a heat-retaining spinning chimney at a temperature within ±50° C. of a temperature of the molten polymer, and is drawn.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: April 24, 2012
    Assignee: Teijin Fibers Limited
    Inventors: Shintaro Shimada, Fuyuki Terasaka
  • Publication number: 20120095160
    Abstract: The present invention relates to an unsaturated polyester resin comprising itaconate ester units as reactive unsaturation, wherein the resin comprises itaconate, citraconate and mesaconate ester units. Preferably, the resin comprises itaconate, citraconate and mesaconate ester units in an amount of from 40 to 90 mol % itaconate, from 2 to 30 mol % citraconate and from 5 to 40 mol % mesaconate in which 100 mol % is the total amount of itaconate, citraconate and mesaconate esters units.
    Type: Application
    Filed: March 24, 2010
    Publication date: April 19, 2012
    Inventors: Marian Henryk Szkudlarek, Johan Franz Gradus Antonnius Jansen, Stefanus Jacobus Duyvestijn, Silvana Rensina Antonnietta Di Silvestre
  • Patent number: 8158718
    Abstract: Polyethylene naphthalate fibers that are characterized in that the fibers have a crystal volume of from 100 to 200 nm3 obtained by wide angle X-ray diffraction of the fiber and a degree of crystallization of from 30 to 60%. It is preferred that the fibers have a maximum peak diffraction angle of wide angle X-ray diffraction of from 23.0 to 25.0°. The production method thereof is characterized in that a particular phosphorus compound is added to the polymer in a molten state, the spinning speed is from 4,000 to 8,000 m/min, and the molten polymer immediately after discharging from the spinneret is allowed to pass through a heated spinning chimney at a high temperature exceeding a temperature of the molten polymer by 50° C. or more, and is drawn.
    Type: Grant
    Filed: March 4, 2009
    Date of Patent: April 17, 2012
    Assignee: Teijin Fibers Limited
    Inventors: Shintaro Shimada, Fuyuki Terasaka
  • Publication number: 20120086761
    Abstract: This disclosure is generally directed to curable phase change inks, such as radiation-curable phase change inks, and their use in forming images, such as through inkjet printing. More specifically, this disclosure is directed to radiation-curable phase change inks, such as ultraviolet-light-curable phase change inks, that an ink vehicle and at least one crystalline polyester resin.
    Type: Application
    Filed: October 8, 2010
    Publication date: April 12, 2012
    Applicant: XEROX CORPORATION
    Inventors: Michelle N. CHRÍTIEN, Bryan J. ROOF, Barkev KEOSHKERIAN, Naveen CHOPRA, Peter G. ODELL
  • Publication number: 20120082785
    Abstract: A back sheet for a solar cell, consisting of a polyester comprising at least one repeating unit of trimethylene naphthalate and trimethylene terephthalate in an amount of 85% by weight or more, has improved hydrolysis-resistance and is useful in the field requiring weatherability.
    Type: Application
    Filed: June 9, 2010
    Publication date: April 5, 2012
    Applicant: SKC CO., LTD.
    Inventors: Nam Ill Kim, Soo Hee Kim, Sung Jun Yoon