At Least One Polyol Containing Only Two -c-oh Groups Reactant Patents (Class 524/604)
-
Patent number: 5985988Abstract: A process for coloration of a substrate comprising printing an ink onto the substrate using a thermal ink jet printer, characterised in that the ink comprises water and a water-dissipatable polyester dyed using a disperse dye or solvent soluble dye. An ink comprising a water-dissipatable polyester dyed using a disperse dye or solvent dye and an aqueous medium.Type: GrantFiled: February 10, 1998Date of Patent: November 16, 1999Assignee: Zeneca LimitedInventor: David John Hodge
-
Patent number: 5973032Abstract: Dispersible additive systems for polymeric materials include dispersant-coated pigments in a liquid nonaqueous polymeric carrier. The additive systems are most preferably in the form of a particulate nonaqueous paste which can be added in metered amounts (dosed) to a melt flow of the polymeric host material prior to being shaped (for example, prior to being spun into synthetic filaments). By providing a number of additive systems having a number of different additive attributes, and controllably dosing one or more into the melt flow of polymeric material, shaped objects of the polymeric material (e.g., melt-spun filaments) having different additive attributes may be produced on a continuous basis without shutting down the shaping operation.Type: GrantFiled: October 14, 1997Date of Patent: October 26, 1999Assignee: BASF CorporationInventors: Donald Caswell, Frank R. Jones, Stanley A. McIntosh, Gary W. Shore, G. Daniel Gasperson
-
Patent number: 5969020Abstract: Highly uniform microporous foam suitable for medical applications and methods for preparing these foams. The highly uniform microporous foams are of controlled pore size that may be utilized in a variety of applications. In preparing the foams, an organic crystalline polymer is melted and combined with a selected solid crystalline fugitive compound to produce a substantially isotropic solution. The solution is cooled under controlled conditions, which foster solid-solid phase separation by the simultaneous crystallization of the fugitive compound and the polymer, to produce a foam precursor containing the solidified fugitive compound dispersed through a matrix of the organic polymer. Crystals of fugitive compound are then removed by solvent extraction and/or sublimation, or like process to produce microcellular foams having a continuous, open-cell structure.Type: GrantFiled: February 6, 1998Date of Patent: October 19, 1999Assignee: Poly-Med, Inc.Inventors: Shalaby W. Shalaby, Susan L. Roweton
-
Patent number: 5945477Abstract: The present invention provides processes for preparing polyesters. The processes include (a) providing a polymerization medium comprising carbon dioxide, (b) contacting a monomer capable of forming a polyester polymer with the polymerization medium, and (c) polymerizing the monomer in the polymerization medium. The processes of the present invention include preparing polyesters by direct esterification polymerization, transesterification polymerization, melt acidolysis polymerization and acid halide polymerization. As a further aspect, the present invention provides a method of separating the polyester produced from the polymerization medium. Polyester polymers prepared according to the methods of the present invention are also provided.Type: GrantFiled: September 26, 1996Date of Patent: August 31, 1999Assignee: The University of North Carolina at Chapel HillInventors: Joseph M. DeSimone, Gerhard Maier
-
Patent number: 5914374Abstract: A urethanized polyester is claimed which is suitable as an additive for aqueous coating systems, which is obtainable by, in a first reaction stage (A), subjecting(a) from 10 to 45 mol-% of one or more diols,(b) from 5 to 50 mol-% of one or more polyols having at least 3 OH groups, and(c) from 35 to 47 mol-% of one or more aromatic, aliphatic or cycloaliphatic polycarboxylic acids and/or reactive derivatives thereof to a polycondensation reaction in a manner known per se until the reaction mixture has an acid number of from 1 to 10, and, in a reaction stage (B), reacting the resulting reaction product in a manner known per se with an organic polyisocyanate. The urethanized polyester is outstandingly suitable as an additive for aqueous coating materials in order to improve the rheological stabilization of coating materials.Type: GrantFiled: February 20, 1997Date of Patent: June 22, 1999Assignee: BASF Coatings AGInventors: Vera Block, Harald Borgholte, Uwe Meisenburg, Heinz-Peter Rink, Ludwig Moorkamp
-
Patent number: 5859152Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: September 12, 1997Date of Patent: January 12, 1999Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Mark A. Montgomery
-
Patent number: 5859121Abstract: Disclosed herein is a stable aqueous dispersant solution containing a high concentration of an EO/PO nonionic block copolymer incapable of liquid phase continuity at ambient temperatures, and a formulation and processing approach providing an effective combination of an anionic dispersant with a water miscible solvent in an aqueous system that allows the feasible production of a dispersant solution containing a high concentration of EO/PO nonionic block copolymer.Type: GrantFiled: July 17, 1997Date of Patent: January 12, 1999Assignee: Bayer CorporationInventor: John W. Brandriff
-
Patent number: 5859073Abstract: A PES/PC blend having enhanced properties as virgin material and as recyclate comprises:A) at least one metal oxide or metal salt of a fatty acid; andB) at least one phosphite and at least one sterically hindered phenol orat least one difunctional epoxy resin ora combination of both.Type: GrantFiled: November 25, 1996Date of Patent: January 12, 1999Assignee: Ciba Specialty Chemicals CorportationInventors: Rudolf Pfaendner, Kurt Hoffmann, Heinz Herbst
-
Patent number: 5834547Abstract: A molding compound composition of the present invention comprises a resin composition, for example, unsaturated polyester, a succinic acid derivative, and a thickening agent such as magnesium oxide, and the moisture content thereof is adjusted in a range of from 0.1 to 0.45 percent by weight. A molding compound comprises the molding compound composition and reinforced fibers such as glass fibers, and the moisture content thereof is adjusted to be in a range of from 0.1 percent to 0.4 percent by weight. As shown in FIG. 1, the molding compound composition has excellent viscosity characteristics since the initial thickening action due to the thickering agent is restrained. Although the viscosity after thickened is lower than that of a conventional composition, the stickiness of the surface of the molding compound composition is reduced.Type: GrantFiled: June 17, 1997Date of Patent: November 10, 1998Assignee: Nippon Shokubai Co., Ltd.Inventors: Kouji Takabatake, Katsura Hayashi, Yoshinori Utikoshi
-
Patent number: 5804634Abstract: Disclosed herein is a liquid crystalline resin compound which includes about 100 pbw of liquid crystalline resin and about 5-200 pbw of inorganic filler, the liquid crystalline resin being composed of about 99.5-50 wt % of partially aromatic liquid crystalline polyester resin and about 0.5-50 wt % of wholly aromatic liquid crystalline polyester resin, and the inorganic filler having an average aspect ratio in the range of 3 to 25. Also disclosed is a molded article of liquid crystalline resin obtained by molding from the liquid crystalline resin compound. The resin compound is superior in flowability and the molded article has good mechanical properties, especially balanced rigidity and toughness.Type: GrantFiled: December 10, 1996Date of Patent: September 8, 1998Assignee: Toray Industries, Inc.Inventors: Hideyuki Umetsu, Kiyokazu Nakamura, Toshihide Inoue, Miki Sakai, Toshio Kurematsu
-
Patent number: 5798432Abstract: Liquid crystalline polymers that are made from 4-hydroxybenzoic acid, 2,6-naphthalenedicarboxylic acid, terephthalic acid, hydroquinone, and N-acetyl-4-aminophenol by heating the monomers in the presence of acetic anhydride are more easily synthesized in high molecular weight if isophthalic acid is also included as a monomer at a level of about 0.5 mole % to about 10 mole %.Type: GrantFiled: March 22, 1996Date of Patent: August 25, 1998Assignee: Hoechst Celanese Corp.Inventors: Cherylyn Lee, Vincent J. Provino, H. Clay Linstid, III
-
Patent number: 5726277Abstract: An adhesive or coating composition comprises a reaction product of terephthalate polymer and mixture of glycols in the presence of a glycolysis catalyst. The reaction product is further reacted with a difunctional organic acid. The recycled polymer which is formulated as adhesive or binder can be used in many fields.Type: GrantFiled: February 2, 1994Date of Patent: March 10, 1998Assignee: Seydel Companies, Inc.Inventor: Robert Keith Salsman
-
Patent number: 5723537Abstract: Pigment pastes are produced by pasting or blending one or several pigments and/or fillers in a paste resin based on a polyester oligomer polyacrylate which is obtainable by radical polymerisation ofA) 80-50 wt % ofa) one or several hydroxyfunctional acrylic acid esters and/or methacrylic acid esters andb) one or several monofunctional ethylenically unsaturated acids, as well as, optionally,c) one or several alpha,beta-ethylenically unsaturated monomers without functional groups inB) 20-50 wt % of one or several hydroxyfunctional polyester oligomers with a calculated molecular weight of 200-1000, a hydroxy number of 280-600 and an acid number of 0-1.5, obtainable by polycondensation of one or several diols, polyols and dicarboxylic acids and derivatives thereof,whereby the monomers a), b) and c) are used in such quantities as to ensure that the polyester oligomer polyacrylate obtained has a hydroxyl number of 150-390 and an acid number of 16-40.Type: GrantFiled: June 5, 1995Date of Patent: March 3, 1998Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Gerda Bajorat, Claudia Hamel, Hartmut Kern
-
Patent number: 5709940Abstract: This invention relates to linear, water-dispersible sulfopolyesters prepared using high molecular weight polyethylene glycol blocks and low molecular weight polyethylene glycol. The high molecular weight polyethylene glycol has the formula H--(OCH.sub.2 CH.sub.2).sub.n --OH where n is 20 to 500, and the low molecular weight polyethylene glycol has the structure H--(OCH.sub.2 CH.sub.2).sub.n' --OH where n' is 2 to 6. The sulfopolyesters are useful as textile fiber sizes that possess improved adhesion, flexibility, and abrasion resistance.Type: GrantFiled: May 21, 1996Date of Patent: January 20, 1998Assignee: Eastman Chemical CompanyInventors: Scott E. George, Bobby J. Sublett
-
Patent number: 5700882Abstract: Polymeric vehicles with liquid crystalline-like properties, solvent dispersible polymeric vehicles, formulated coating compositions with liquid crystalline-like properties and a method for imparting liquid crystalline properties to a coating binder are described. The materials with liquid crystalline-like properties lack structural segments previously regarded as mesogenic.Type: GrantFiled: June 5, 1995Date of Patent: December 23, 1997Assignee: North Dakota State UniversityInventors: Frank N. Jones, Cong Du, Ganghui Teng, Adel F. Dimian, Daozhang Wang
-
Patent number: 5686510Abstract: A biaxially oriented polyester film made of a polyester composition,(A) which polyester composition comprises (a) an aromatic copolyester having a melting point of 210-245.degree. C., (b) first inert fine solid particles having an average particle diameter of 0.05 to 0.6 .mu.m, and (c) second inert fine solid particles having an average particle diameter of 0.3 to 2.5 .mu.m, the ratio of the average particle diameter of the second inert fine solid particles to the average particle diameter of the first inert fine solid particles being at least 2.5, and the amounts of the components (b) and (c) being 0.01 to 3% by weight and 0.001 to 0.2% by weight, respectively, based on the total weight of the components (a), (b) and (c);(B) which polyester film has a plane orientation coefficient of 0.08 to 0.16; and,(C) which polyester film shows excellent moldability when laminated onto a metal sheet and subjected to deep drawing.A can for drinks, foods, etc.Type: GrantFiled: November 10, 1994Date of Patent: November 11, 1997Assignee: Teijin LimitedInventors: Takeo Asai, Kinji Hasegawa, Mitsumasa Ono
-
Patent number: 5684072Abstract: A waterborne coating composition having improved smoothness is provided which contains a polymeric film-forming resin in aqueous medium and from about 0.1 percent to about 10 percent by weight based on total weight of resin solids of at least one material having the following structure: ##STR1## where n is an integer that is at least 1, R.sup.1 is hydrogen or lower alkyl having 1 to 10 carbon atoms, R.sup.2 is a divalent organic radical, and R.sup.3 is an alkyl, aryl, or alkylaryl group having 1 to 20 carbon atoms.Type: GrantFiled: March 22, 1995Date of Patent: November 4, 1997Assignee: PPG Industries, Inc.Inventors: Daniel E. Rardon, Roxalana L. Martin, Dennis L. Faler, James E. Poole
-
Patent number: 5670571Abstract: An aqueous dispersion of small particles of a phenol/formaldehyde novolac resin, referred to as a dispersed novolac resin, useful for example as a binder in preparing glass fiber insulation. The dispersed novolac resin is produced by preparing a molten novolac resin, cooling, adding water and optionally a surfactant and then adding a protective colloid. Additional water is added to provide the desired dispersion.Type: GrantFiled: November 3, 1995Date of Patent: September 23, 1997Assignee: Georgia-Pacific Resins, Inc.Inventors: Kurt D. Gabrielson, Rodney R. Conner
-
Patent number: 5665151Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.Type: GrantFiled: November 18, 1996Date of Patent: September 9, 1997Assignee: Eastman Chemical CompanyInventors: Nelson Zamora Escano, James John Krutak, Sr.
-
Patent number: 5645892Abstract: A method of treating natural or synthetic pile or brushed fabrics to reduce marking caused by rubbing or handling the fabrics, while leaving the fabrics with a soft feel and a full, thick hand. The method consists of the application to the fabrics of liquid compositions comprising a) about 80-100% of a water-dispersible, hydrophilic polyester or polyurethane dispersed in an aqueous medium; b) about 0-20% of a carrier of the type used to enhance the penetration of dyes and other materials into the polymer structure of polyester fibers; and c) about 0-10% of a non-rewetting wetting agent.Type: GrantFiled: October 31, 1995Date of Patent: July 8, 1997Assignee: IVAX Industries, Inc.Inventors: David Anderson Whitley, Carl Lewis Wolhar
-
Patent number: 5637356Abstract: Polyesters are formed from diols and dibasic carboxylic acids at an OH/COOH ratio to provide --OH termination, and then end-capped with tribasic carboxylic acids. A major portion of the dibasic carboxylic acids used to form the polyesters have the formula: ##STR1## where x=8-32, y=0-8, x+y=8-32. The polyesters are used as support resins for forming acrylic resin emulsions. The polyester/acrylic acid emulsions are useful, for example, as textile size.Type: GrantFiled: March 5, 1996Date of Patent: June 10, 1997Assignee: Morton International, Inc.Inventors: Ronald J. Kerr, John P. Petrovich, Stephen J. Walker, J. Alvin Binkley
-
Patent number: 5635555Abstract: PVC-free coil coated steel having excellent cut-side corrosive resistance can be prepared by using on one or both sides a primer composition essentially consisting of a linear polyester of Mn=3,000-15,000, of acid number 0-10, and hydroxyl index 10-25; a blocked polyisocyanate, melamine or an urea-formaldehyde adduct, in an equivalent ratio of 0.8-4.0 to polyester; a catalyst; anti-corrosive pigments of the chromate type, being at least 50 weight percent of all pigments; and solvents.Type: GrantFiled: April 29, 1996Date of Patent: June 3, 1997Assignee: Fina Research, S.A.Inventors: Paul Vranken, Philippe Pigeolet
-
Patent number: 5626959Abstract: A polymeric film comprising from 0.0005% to 2% by weight, based upon the weight of the polymer in the film, of filler particles having a volume distributed median particle diameter of from 0.1 to 12.5 .mu.m, the filler particles being obtainable by calcining precursor silicone resin particles prior to incorporation into the film polymer.Type: GrantFiled: July 7, 1994Date of Patent: May 6, 1997Assignee: Imperial Chemical Industries PLCInventors: Paul D. A. Mills, Junaid A. Siddiqui, Karl Rakos
-
Patent number: 5614008Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.Type: GrantFiled: October 23, 1995Date of Patent: March 25, 1997Inventors: Nelson Z. Escano, James J. Krutak, Sr.
-
Patent number: 5610222Abstract: A polymeric film comprising from 0.0005% to 2% by weight, based upon the weight of the polymer in the film, of filler particles having a volume distributed median particle diameter of from 0.1 to 12.5 .mu.m, the filler particles being obtainable by calcining precursor silicone resin particles prior to incorporation into the film polymer.Type: GrantFiled: September 27, 1994Date of Patent: March 11, 1997Assignee: Imperial Chemical Industries PLCInventors: Paul D. A. Mills, Junaid A. Siddiqui, Karl Rakos
-
Patent number: 5599875Abstract: Coating compositions and processes for coating wood and wood materials are described. The compositions comprise a first component comprising at least one reactive thinner and at least one unsaturated polyester, and a second component comprising a curing catalyst. The unsaturated polyester of the first component is the reaction product of: (a) a mixture of at least one saturated aliphatic dicarboxylic acid with 6 to 10 carbon atoms and at least one ethylenically unsaturated aliphatic dicarboxylic acid selected from maleic acid, fumaric acid, itaconic acid, citraconic acid, and mixtures thereof; (b) a diol component consisting of at least one of 1,4-dimethylolcyclohexane and substituted dimethylolcyclohexanes, with up to 50 mol % monomeric or oligomeric glycol, based on total moles of the diol component; and (c) up to 10 mol % of a polyol, based on total moles of polyester reactants. The compositions and processes of the invention result in coatings with improved hardness and aged cold crack resistance.Type: GrantFiled: August 28, 1995Date of Patent: February 4, 1997Assignee: BASF Lacke + Farben, AGInventors: Karl-Dieter Depping, Horst Hintze-Bruning
-
Patent number: 5597861Abstract: A waterborne paint is provided by dissolving or dispersing a polyester resin and a crosslinker in an aqueous medium containing a base. The polyester resin contains a hydroxy-terminated polyalkadienediol having an average degree of polymerization from 5 to 50, a hydrogenated product thereof or a mixture thereof in a proportion from 1 to 30% by weight of the entire polyester-forming reactants, and has an acid number from 5 to 150, a hydroxyl number from 30 to 250. The paint is useful for forming a multilayer coating film on automobile bodies by applying the paint between an electrodeposition coating layer and a top coating layer.Type: GrantFiled: March 15, 1995Date of Patent: January 28, 1997Assignee: Nippon Paint Company, Ltd.Inventors: Yasuhiko Nakae, Shigeru Ishida, Shoichi Mure, Yasuhiro Shibata
-
Patent number: 5591255Abstract: The present invention comprises a series of discoveries related to the problems associated with formulations that destroy the color change properties of thermochromic encapsulated dyes. One aspect of the present invention is the discovery of a method of correcting these formulations to allow the addition of thermochromic dyes. Certain solvents destroy the dye, therefore any aldehydes, ketones, and diols, and most aromatic compounds should be removed from the formulation and if needed they should be replaced with solvents preferably having a large molecular weight (i.e. greater than 100 and low reactivity). Secondly, the formulation should be adjusted to be neutral (i.e. 6.5-7.5 pH) or have a low acid value. These two adjustments will allow the thermochromic dyes to added to the formulation without a loss of its color change properties.Type: GrantFiled: September 30, 1994Date of Patent: January 7, 1997Assignee: Chromatic Technologies, Inc.Inventors: Lyle D. Small, Gerald Highberger
-
Patent number: 5563200Abstract: A coating powder composition for providing a smooth, heat-resistant coating contains A) between about 60 and about 95 parts by weight or a polyester resin which has either hydroxyl functionality of 2 or greater or carboxylic acid functionality of 2 or greater, B) between about 5 and about 40 parts by weight of a curative for the polyester resin A), A) and B), in total, being 100 parts resin, C) between about 50 and about 150 parts per hundred resin by weight (phr) silicone resin, D) between about 20 and about 100 phr of a filler selected from calcium silicate, silica, magnesium aluminum silicate, calcium carbonate, barium sulfate, and mixtures thereof, E) between about 1 and about 10 phr silicone rubber, and F), up to about 50 phr mica.Type: GrantFiled: September 21, 1995Date of Patent: October 8, 1996Assignee: Morton International, Inc.Inventors: Andrew T. Daly, Leo T. Grundowski
-
Patent number: 5554675Abstract: A composition useful in printing inks exemplified as comprising:(1) from about 4 to about 80% by weight of one or more polyester materials having an acid component of from about 75 to about 84 mole % isophthalic acid and conversely from about 25 to about 16 mole % 5-sodiosulfoisophthalic acid, and having a glycol component of from about 45 to about 60 mole % diethylene glycol and conversely from about 55 to about 40 mole % 1,4-cyclohexanedimethanol or ethylene glycol or mixtures thereof;(2) from about 1.0 to about 60% by weight of pigment material;(3) from about 0.05 to about 30% by weight of a nonionic, polyether type property modifier; and(4) from substantially none to about 90% by weight of water.Type: GrantFiled: May 9, 1994Date of Patent: September 10, 1996Inventors: Gary T. Clark, John N. Rasar, Rebecca R. Stockl
-
Patent number: 5552475Abstract: Substituted polycarboxylic acids or substituted anhydrides as acidifying agents stabilize a waterborne polyester from saponification, provided: (a) the acidification is carried out to an extent sufficient to provide an acid number of at least 40 milligrams KOH per gram of polyester resin; and (b) the substitution on the polycarboxylic acid or anhydride is either an alkenyl group having at least four carbon atoms or a cyclic group in which the ring is not aromatic. The relatively high acid number renders the polyester dispersible in water without the need to rely on surfactants.Type: GrantFiled: October 4, 1993Date of Patent: September 3, 1996Assignee: PPG Industries, Inc.Inventors: Padmanabhan Sundararaman, Ronald R. Ambrose, Douglas R. Camp, Truman F. Wilt
-
Patent number: 5530059Abstract: Disclosed is a water-dissipatable alkyd resin containing a sulfonate group. The alkyd resin is prepared by reacting at least one monoglyceride, a polycarboxylic acid, and a polyol sulfomonomer adduct containing at least one sulfonate group. The alkyd resin is useful to prepare cross-linked coatings such as obtained with oil based paints.Type: GrantFiled: November 25, 1994Date of Patent: June 25, 1996Inventors: William W. Blount, Jr., Thauming Kuo
-
Patent number: 5525700Abstract: This invention relates to liquid crystalline polymers (LCPs) derived from (I) hydroquinone and/or 4,4'-biphenol and/or bis(4-hydroxylphenyl) ether, (II) terephthalic acid, (lII) 2,6-naphthalene dicarboxylic acid and/or 4,4'-bibenzoic acid, (IV) 4-hydroxybenzoic acid, (V) 6-hydroxy-2-naphthoic acid, and optionally (VI) an aliphatic diol in specified ratios. In addition to forming exceptionally tough films, the LCPs are useful as molding resins or for blending with other thermoplastic polymers.Type: GrantFiled: April 17, 1995Date of Patent: June 11, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Michael R. Samuels, Marion G. Waggoner
-
Patent number: 5512614Abstract: A binder mixture for stoving lacquers comprising A) at least one alkyd resin; and B) at least one poly-N-acyl alkyleneimine prepared by cationic polymerization of a monomer mixture ofa) from 10 to 90% by weight of at least one monomer corresponding to formula (I): ##STR1## in which Z is a direct bond or the group CR.sup.5 R.sup.6, R.sup.1 to R.sup.4 can be the same or different and represent H or a C.sub.1-8 alkyl group, R.sup.5 and R.sup.6 can be the same or different and represent H or a C.sub.1-2 alkyl group, R.sup.7 is a hydroxyl-containing alkyl or alkylene group of a hydroxycarboxylic acid containing 2 to 32 carbon atoms,b) from 90 to 10% by weight of at least one monomer corresponding to formula (II): ##STR2## in which Z and R.sup.1 to R.sup.6 are as defined above and R.sup.8 is the radical of an aromatic monocarboxylic acid, andc) from 0 to 80% by weight of at least one monomer corresponding formula (III): ##STR3## in which Z and R.sup.1 to R.sup.6 are as defined above, and R.sup.Type: GrantFiled: February 13, 1995Date of Patent: April 30, 1996Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Ulrich Eicken, Herbert Fischer, Wolfgang Gress, Ulrich Nagorny, Norbert Stork
-
Patent number: 5510417Abstract: An aqueous dispersion comprising (A) a polyester comprising an aromatic dicarboxylic acid, an addition product of bisphenol A with ethylene oxide and/or propylene oxide, and a dicarboxylic acid having a metal base of sulfonic acid and/or a polyol having a metal base of sulfonic acid, (B) a water-soluble organic compound having a boiling temperature of about 60.degree. C. to about 250.degree. C., (C) water and (D) a neutralizer; the amounts of the components A, B, C and D satisfying the following ratios of (1) to (3):(1) A/B/C being about 1% to about 70% by weight/about 0% to about 69% by weight/about 9% to about 99% by weight,(2) B/(B+C) being about 0 to about 0.7 (weight ratio), and(3) the equivalent ratio of D to A being about 0.1 to about 20.Type: GrantFiled: November 4, 1994Date of Patent: April 23, 1996Assignee: Toyo Boseki Kabushiki KaishaInventors: Hiroshi Tachika, Keiichiro Togawa, Hiroshi Fujimoto
-
Patent number: 5489448Abstract: A water-free, water-free reducible primer composition having a volatile organic content of less than 3 pounds per gallon yields a tough, flexible, and weatherable film when applied to metal or plastic substrates. The base resin is a polyester having an acid number of from about 50 to about 60 and a hydroxyl number of from about 160 to about 200. The polyester is the reaction product of from about 0.45 to about 0.5 mole % of adipic acid, from about 0.35 to about 0.4 mole % of neopentyl glycol, and from about 0.15 to about 0.2 mole % of trimethylolpropane.Type: GrantFiled: July 26, 1994Date of Patent: February 6, 1996Assignee: Bee Chemical CompanyInventors: Michael L. Jackson, Frank A. Stubbs, Joseph M. Mecozzi, Dean T. Smith
-
Patent number: 5489481Abstract: This development provides crystalline unsaturated polyesters having unreacted olefinically unsaturated monomer entrapped within its crystal lattice. The crystalline polyester can be used in high performance, structural SMC products or as a size or binder for glass fiber reinforcements or mats.Type: GrantFiled: December 27, 1994Date of Patent: February 6, 1996Assignee: Owens-Corning Fiberglas Technology, Inc.Inventors: William G. Hager, John D. Rinehart, James V. Gauchel, Edward L. Wilson
-
Patent number: 5484842Abstract: Aqueous dispersions having low VOCs are dispersions or solutions of polyesters. The polyesters useful are formed from A) between about 30 and about 60 mole percent polycarboxylic acids, of which at least about 80 mole percent comprises cyclohexanedicarboxylic acids, B) between about 35 and about 70 mole percent polyols of which at least about 95 mole percent comprises diols, and between about 40 and about 100 mole percent of the polyol content comprising cycloaliphatic diols, and C) between about 5 and about 25 mole percent of a monomer having dihydroxy, monocarboxylic acid functionality. The molar ratio of (B+C)/A is between about 1.01 and about 1.30, whereby the polyester is hydroxyl-terminated having hydroxyl numbers of between about 20 and about 150 and acid numbers between about 30 and about 100. The weight average molecular weight of the polyester is between about 1000 and about 20,000.Type: GrantFiled: May 23, 1994Date of Patent: January 16, 1996Assignee: Morton International, Inc.Inventors: Ronald J. Lewarchik, Marc L. Smith, Michael R. Sestrick
-
Patent number: 5473004Abstract: A biaxially oriented polyester film comprising a copolyester which contains a lubricant having an average particle diameter of no greater than 2.5 .mu.m and has a melting point of from 210.degree. to 245.degree. C., the film having a plane orientation coefficient of from 0.10 to 0.16, a thermal shrinkage at 150.degree. C. of no higher than 10%, and a density of lower than 1.385 g/cm.sup.3, and optionally a refractive index in a direction of thickness of from 1.495 to 1.530 as well as a film plane refractive index of from 1.61 to 1.66 in all directions.Type: GrantFiled: July 20, 1994Date of Patent: December 5, 1995Assignee: Teijin LimitedInventors: Tadashi Ono, Kinji Hasegawa, Takeo Asai, Yoji Murakami
-
Patent number: 5446082Abstract: A water-dispersible polyester composition for an image recording medium, comprising (1) a polyester having a glass transition temperature of not less than 40.degree.C., a specific gravity of not less than 1.25, a value of SP of 9.5-12.0, and at least one kind of hydrophilic polar group, and which is insoluble in methyl ethyl ketone, toluene, and a mixed solvent thereof, wherein 65% by mole or more of a glycol component constituting the polyester is ethylene glycol, in a proportion of 5-50% by weight, (2) an organic compound compatible with water in a proportion of 0-20% by weight, and (3) water in a proportion of 30-95% by weight all percentages by weight being based upon the total weight of said composition containing components (1), (2) and (3). When used for an image recording layer of an image recording medium, the composition of the invention is conducive to the durability of the recorded images excellent in heat resistance, resistance to plasticizer, resistance to fingerprint, and solvent resistance.Type: GrantFiled: May 4, 1993Date of Patent: August 29, 1995Assignee: Toyo Boseki Kabushiki KaishaInventors: Haruo Asai, Mitsuru Kuwahara, Nobukazu Kotera
-
Patent number: 5428100Abstract: There are provided a liquid crystal polyester resin composition comprising 100 parts by weight of a liquid crystal polyester, 45 to 80 parts by weight of graphite having an average particle size of 5 .mu.m or more and 0 to 140 parts by weight of talc having an average particle size of 5 .mu.m or more, the total amount of the graphite and the talc being 55 to 185 parts by weight. There are provided a molded article such as a carrier for electronic part, a heat-resistant tray for IC, or the like, which has high heat resistance in soldering, only slight anisotropy and warpage, a surface resistivity of 1.times.10.sup.4 to 1.times.10.sup.8 .OMEGA., and an initial voltage due to electrification and a half-life (a time required for the initial voltage due to electrification to be reduced to one-half) which are controlled to be further reduced; and a liquid crystal polyester resin composition excellent in moldability which gives said molded article.Type: GrantFiled: June 1, 1993Date of Patent: June 27, 1995Assignee: Sumitomo Chemical Company, LimitedInventors: Kuniaki Asai, Tadayasu Kobayashi, Mituo Maeda
-
Patent number: 5423432Abstract: Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.Type: GrantFiled: May 5, 1994Date of Patent: June 13, 1995Assignee: Eastman Chemical CompanyInventors: James J. Krutak, Michael R. Cushman, William W. Parham, Clarence A. Coates, Max A. Weaver, Gabor Patonay
-
Patent number: 5397828Abstract: A biaxially stretched polyester film is disclosed.The biaxially stretched polyester film comprises substantially spherical silica particles of colloidal state having average diameters ranging from approximately 20 nm to approximately 200 nm in amounts ranging from approximately 0.005% to approximately 1.0% by weight based on the total weight of the polyester; and alumina particles having average diameters ranging from approximately 50 nm to approximately 500 nm in amounts ranging from approximately 0.05% to approximately 5.0% by weight, the average diameter of the alumina particles being larger than that of the silica particles.The biaxially stretched film prepared according to the present invention has excellent surface properties such as slip property and abrasion resistance, so that the film may be used for manufacturing final products without scratches and white powders occurring thereon.Type: GrantFiled: June 24, 1994Date of Patent: March 14, 1995Assignee: Cheil Synthetics Inc.Inventors: Dae W. Ihm, Jeong L. Kim, Seung B. Jun
-
Patent number: 5389710Abstract: This invention relates to an improved polyester composition that has a wide temperature range of crystallization. The composition comprises a polyester and a chemically reacting crystallization modifier having the following formula:H.sub.2 N--R.sup.1 --O--(R.sup.2 --O).sub.x --R.sup.3 --NH.sub.2whereinR.sup.1 and R.sup.3 are independently selected from the group consisting of alkylene units having from about 2 to about 6 carbon atoms;R.sup.2 is a hydrocarbon radical of 2-6 carbon atoms; andx is from 1 to 100.Type: GrantFiled: November 23, 1992Date of Patent: February 14, 1995Inventors: Gerald J. Dege, Murali K. Akkapeddi, Harold W. Tuller, Nicholas Vanderkooi, Jr.
-
Patent number: 5380590Abstract: A water-dispersible aromatic polyester comprising a dicarboxylic acid component and a glycol component, wherein (A) at least 95 mol% of the dicarboxylic acid component is composed of an aromatic dicarboxylic acid component containing 30 to 99.5 mol% of a 2,6-naphthalenedicarboxylic acid component and at least 0.005 mol% to less than 5 mol% of an aromatic dicarboxylic acid component having a sulfonic acid salt group, and (B) at least 95 mol% of the glycol component is composed of an ethylene glycol component and a component from a propylene oxide adduce of bisphenol A, the molar ratio of the ethylene glycol component:the component of a propylene oxide adduct of bisphenol A being 40-99:60-1; and a fast-adhesion polyester film comprising a polyester film and a coating which contains the above water-dispersible aromatic polyester and is formed on at least one surface of the polyester film.Type: GrantFiled: March 4, 1994Date of Patent: January 10, 1995Assignee: Teijin LimitedInventors: Tomoki Nakamura, Tetsuo Ichihashi, Masayuki Fukuda
-
Patent number: 5380577Abstract: A biaxially oriented polyester film, (A) which is formed from polyethylene-2,6-naphthalenedicarboxylate containing 0.01 to 1% by weight of inert solid fine particles having an average particle size of 0.05 to 3 .mu.m, (B) which has a refractive index, in a film thickness direction, of at least 1.498, and (C) which has a Young's modulus, at least in one direction, of at least 700 kg/mm.sup.2 ; and a process for the production thereof. This film is useful as a magnetic recording medium, particularly as a base film excellent in abrasion resistance and tear resistance.Type: GrantFiled: June 10, 1994Date of Patent: January 10, 1995Assignee: Teijin LimitedInventors: Hisashi Hamano, Masahiro Hosoi, Ieyasu Kobayashi, Yasuhiro Saeki
-
Patent number: 5378757Abstract: Disclosed is a water-dissipatable alkyd resin containing a sulfonate group. The alkyd resin is prepared by reacting at least one monoglyceride, a polycarboxylic acid, and a polyol sulfomonomer adduct containing at least one sulfonate group. The alkyd resin is useful to prepare cross-linked coatings such as obtained with oil based paints.Type: GrantFiled: November 15, 1993Date of Patent: January 3, 1995Assignee: Eastman Chemical CompanyInventors: William W. Blount, Jr., Thauming Kuo
-
Patent number: 5371112Abstract: Coating compositions derived from the acidolysis of polyethylene terephthalate.Type: GrantFiled: January 23, 1992Date of Patent: December 6, 1994Assignee: The Sherwin-Williams CompanyInventors: Daniel R. Sayre, William B. Lesney, Madhukar Rao, Richard F. Tomko
-
Patent number: 5367011Abstract: Blends of low molecular weight PBT resin and high molecular weight polyester resin, such as high molecular weight PBT resin, are imparted with excellent melt viscosity stability by the addition of certain phosphorus-containing compounds.Type: GrantFiled: December 8, 1993Date of Patent: November 22, 1994Assignee: General Electric CompanyInventor: Eileen B. Walsh
-
Patent number: 5359025Abstract: Provided are novel phenolic-functional polyesters which are prepared by a direct polycondensation process. The polyesters formed therefrom are useful in enamel compositions and upon curing provide coatings which exhibit superior hardness, impact resistance and acid resistance heretofore unachievable with other polyester-based coatings.Type: GrantFiled: October 18, 1993Date of Patent: October 25, 1994Assignee: Eastman Chemical CompanyInventor: Thauming Kuo