Solid Polymer Derived From Ethylenic Reactants Only At Least One Of Which Contains A Carboxylic Acid Or Derivative Patents (Class 524/69)
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Patent number: 7625963Abstract: A polyurethane hot melt adhesive composition comprising an isocyanate, one or more polyols, one or more bituminous materials and optionally one or more thermoplastic materials. Another embodiment is directed to a method for bonding materials together which comprises applying the reactive hot melt adhesive composition in a liquid form to a first substrate, bringing a second substrate in contact with the composition applied to the first substrate, and subjecting the applied composition to conditions which will allow the composition to cool and cure to an irreversible solid form, said conditions comprising moisture. Still another aspect is directed to an article of manufacture comprising the adhesive.Type: GrantFiled: January 25, 2007Date of Patent: December 1, 2009Assignee: Henkel AG & Co. KGaAInventors: Yongxia Wang, Louis A. Moore, Gary Raykovitz
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Patent number: 7608650Abstract: Asphalt and elastomeric polymer compositions crosslinked with mixed polythiomorpholines or at least one alkyl polysulfide can give polymer modified asphalts (PMAs) with improved properties and/or reduced H2S evolution. When at least one alkyl polysulfide is used to completely or partially replace conventional crosslinkers such as S or MBT, mercaptobenzimidazole (MBI) may be optionally used as a co-crosslinker. The use of mixed polythiomorpholines as crosslinkers provide PMAs with better low temperature profiles (BBR m-values). The use of at least one alkyl polysulfide crosslinker gives PMAs with improved PAV-aged DSR results, and reduced H2S evolution. The use of at least one alkyl polysulfide crosslinker together with MBI may give PMAs with improved PAV DSR Fail Temperatures.Type: GrantFiled: February 6, 2009Date of Patent: October 27, 2009Assignee: Fina Technology, Inc.Inventors: Paul Buras, William Lee, James Butler, Wendy Stanley
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Publication number: 20090215931Abstract: Bituminous paving mixtures containing lubricating agents or additives may be prepared at hot mix temperatures and cooled, paved and compacted at temperatures 10-55 Celsius degrees lower than the hot mix temperatures. The increased temperature range between the hot mix temperatures and the paving and compacting temperatures is facilitated by the improved compacting properties of the paving mixture when it includes the lubricating agents or additives.Type: ApplicationFiled: February 20, 2009Publication date: August 27, 2009Applicant: ALM Holding Co.Inventors: Gerald H. REINKE, Gaylon L. BAUMGARDNER, Steven L. ENGBER
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Patent number: 7569627Abstract: The binder is produced based on natural bitumen, or bitumen from the oil industry, and comprises a first additive which is constituted by a hydrocarbon wax whose melting point is greater than 85° C. This binder further comprises a fatty acid ester wax which is of synthetic, vegetable or fossil vegetable origin and which has a melting point of less than 85° C. Use in the production of sealing coatings for buildings or civil engineering works, coatings for traffic routes or urban amenities.Type: GrantFiled: May 28, 2004Date of Patent: August 4, 2009Assignee: COLASInventor: Jean-Pierre Dean
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Publication number: 20090163625Abstract: High performance bituminous mixtures that are useful for the road paving and roofing industries comprise mineral aggregates coated with a thermoplastic polymer composition. Because of their high performance properties, the absence of any aggressive and toxic adhesion promoters and the possibility of using recovered or recycled thermoplastic polymers to form the coating or “membrane,” the bituminous mixtures described herein provide an excellent environmentally friendly solution for pavement construction and roofing industries.Type: ApplicationFiled: December 19, 2008Publication date: June 25, 2009Inventors: JIRI LANG, Stephen L. Cluff
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Patent number: 7544239Abstract: Methods of modifying crude fractions are described herein. The methods generally include blending a crude fraction with an emissions reducing additive to form a modified crude fraction, wherein the modified crude fraction exhibits reduced sulfur emissions. The emissions reducing additive generally includes a dispersion of a metal oxide.Type: GrantFiled: October 14, 2005Date of Patent: June 9, 2009Assignee: Fina Technology, Inc.Inventors: Paul J. Buras, William D. Lee, James R. Butler
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Publication number: 20090064904Abstract: The present invention relates to a black pigment/auxiliary combination having an improved relative colour strength of greater than or equal to 110%, the preparation thereof and the use thereof.Type: ApplicationFiled: January 22, 2007Publication date: March 12, 2009Applicant: LANXESS DEUTSCHLAND GMBHInventors: Holger Friedrich, Jurgen Kischkewitz, Gerald Buchner
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Publication number: 20080283273Abstract: The present invention relates to a semiconductive composition and a power cable using the same. The semiconductive composition according to the present invention constituting a semi-conductive layer of a power cable includes 100 parts by weight of a base resin composed of an ethylene-based copolymer resin; 45 to 70 parts by weight of a carbon black; and 0.2 to 5.0 parts by weight of a nonionic surfactant. The semiconductive composition according to the present invention has an improved interfacial smoothness in the semiconductive layer and the insulation layer of the power cable and an increased dielectric breakdown strength of the insulation layer. Also, the semiconductive composition according to the present invention may be useful to ensure an easy cleaning property of a mold upon extruding/molding a power cable.Type: ApplicationFiled: February 6, 2006Publication date: November 20, 2008Inventors: Jin-Ho Nam, Dae-Hee Cho
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Patent number: 7402619Abstract: The present invention relates to a bituminous composition comprising a bituminous component, an elastomeric polymer component, and a specific cross-linking composition component comprising elemental sulfur, a sulfur-containing derivative, a sulfur activator, a fatty acid or fatty acid derivative and a polymeric carrier. Compositions according to the invention are particularly useful in preparing polymer-modified asphalt (“PMA”) for road applications.Type: GrantFiled: March 31, 2005Date of Patent: July 22, 2008Assignee: Kraton Polymers U.S. LLCInventor: Keith E. Stephens
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Publication number: 20080119591Abstract: The present invention is directed to an air-blown roofing asphalt modified with polyphosphoric acid and roofing products made with the polyphosphoric acid-modified, air-blown asphalt.Type: ApplicationFiled: November 22, 2006Publication date: May 22, 2008Applicant: ICL PERFORMANCE PRODUCTS LPInventors: Michael Falkiewicz, Rene Maldonado
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Patent number: 7323503Abstract: A process for producing an ethylene-vinyl alcohol copolymer resin, including feeding EVOH into an extruder, keeping the temperature of the melting resin in the extruder at 70 to 170° C., adjusting the amount of water in the extruder so that the water content right after being discharged from the extruder is 5 to 40 weight %, and extruding out the EVOH resin. The extruded EVOH resin is cut into EVOH pellets. Thereby, it is possible to obtain resin pellets in which no spherocrystals are observed in the center of the cross section of the resin when the cross section is observed by the use of a polarization microscope, or no lubricant is contained in the resin pellets, and the angle of repose is 23° or less when the resin pellets are laminated.Type: GrantFiled: December 8, 2003Date of Patent: January 29, 2008Assignee: Kuraray Co., Ltd.Inventors: Takaharu Kawahara, Hiroshi Kawai, Toshio Tuboi, Yukihiro Ohara, Masao Hikasa
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Patent number: 7241818Abstract: The present invention is a fly ash filler or filler blend having a particle size distribution with at least three modes that can be combined with a polymer or bitumen at higher filler loadings to produce a filled polymer or bitumen for composites that, in many cases, can produce improved mechanical properties for the composites over composites using conventional fillers. As a result, superior composites (e.g. those used in carpet backing) can be produced at a lower cost than conventional composites. The present invention also includes a method for producing a composite, comprising the steps of combining a polymer or bitumen with a fly ash filler or a filler blend having a particle size distribution with at least three modes to produce a filled polymer or bitumen and producing a composite with the resulting filled polymer or bitumen. The present invention further includes a method of determining what fly ashes can be used as fillers for composites.Type: GrantFiled: February 28, 2005Date of Patent: July 10, 2007Assignee: Boral Material Technologies, Inc.Inventors: Raymond T. Hemmings, Russell L. Hill, Bruce J. Cornelius
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Patent number: 7241821Abstract: A method is provided for improving high temperature performance grade properties of polymer-modified, vulcanized asphalt by treating an asphalt cement under mild oxidizing conditions sufficient to provide a change in viscosity per hour as measured at 140° C. of less than about 500 poises per hour, of said asphalt cement, adding 1 wt. % to 10 wt. % of a polymer based on weight of said asphalt cement, and vulcanizing the polymer-containing asphalt cement. The invention further relates to asphalt compositions thus made and paving compositions containing these asphalt compositions.Type: GrantFiled: August 10, 2004Date of Patent: July 10, 2007Assignee: Marathon Ashland Petroleum LLCInventors: Roger E. Hayner, Patricia K. Doolin, Robert H. Wombles
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Publication number: 20070142507Abstract: A solvent-based coating composition, used in automotive original and automotive refinish coating, comprising 10-90% by weight of at least one hydroxyl-functional (meth)acrylic copolymer A) having an OH value from 80 to 200 KOH/g and a weight average molecular weight Mw from 2,500 to 30,000 and 90-10 weight.-% of at least one cross-linking agent B), which is capable of entering into a cross-linking reaction with the OH-groups of components A), wherein the % by weight of component A) and B) add up to 100 weight.Type: ApplicationFiled: December 20, 2005Publication date: June 21, 2007Inventors: Josef Huybrechts, Carmen Flosbach, Ann Vaes, Eline de Rouck
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Patent number: 7160935Abstract: Polymeric modified asphalt for road paving applications wherein the polymer modifier is a tubular reactor produced ethylene/alkyl acrylate copolymer (e.g., EMA) optionally blended with an epoxy functionalized ethylene copolymer (e.g., EnBAGMA) and added to the asphalt with or without the use of an acid adjuvant (e.g., PSA).Type: GrantFiled: March 23, 2004Date of Patent: January 9, 2007Assignee: E. I. du Pont de Nemours and CompanyInventor: George Wyatt Prejean
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Patent number: 7157508Abstract: Disclosed are a thermoplastic polymer-linked-asphalt composition and a process for making a thermoplastic polymer-linked-asphalt. More particularly, the present invention relates to the reaction and resultant linking of a combination of epoxide-containing polymers and anhydride-containing polymers to asphalt to form a polymer-linked-asphalt composition having higher softening points. The improved polymer-linked-asphalt product is particularly useful in roofing applications.Type: GrantFiled: April 14, 2004Date of Patent: January 2, 2007Assignee: E. I. du Pont de Nemours and CompanyInventor: David M. Dean
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Patent number: 7097759Abstract: A method for dispersing asphaltenes in a petroleum product by adding to the petroleum product 0.001% to 20% of at least one compound having formula (V) wherein R14 is C15–C21 alkyl. In addition to dispersing asphaltenes, the method of the present invention typically also increases demulsibility, reduces viscosity, reduces sediment formation, reduces surface fouling and reduces corrosion.Type: GrantFiled: May 23, 2003Date of Patent: August 29, 2006Assignee: Rohm and Haas CompanyInventor: Ravindranath Mukkamala
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Patent number: 7091282Abstract: A composition suitable for forming a sidewall for a tire includes a rubber composition which includes at least one rubber, an ethylene/propylene/diene terpolymer, and a polyalkylene copolymer. The rubber may include one or more natural or synthetic rubbers, such as butadiene rubbers and isoprene rubbers. The ethylene/propylene/diene terpolymer preferably has an ethylene content of at least 60%. The polyalkylene copolymer may be a copolymer of a polyalkylene and an ?-olefin, which is formed in a polymerization reaction involving a single site catalyst. The polyalkylene copolymer preferably has a high degree of crystallinity, being preferably at least about 90% by weight ethylene, with a melting point in the range of 80° C.–120° C. The presence of such a copolymer in the rubber composition markedly increases the resistance to crack growth and formation of cracks in the tire sidewall.Type: GrantFiled: May 15, 2003Date of Patent: August 15, 2006Assignee: Bridgestone CorporationInventors: Zhong-Ren Chen, Christine M. Rademacher
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Patent number: 7060743Abstract: The present invention provides a bitumen composition including: —(i) from 0.1 to 25% wt of an elastomer, (ii) from 0.1 to 40% wt of a solvent, (iii) from 30 to 99% wt of a bitumen, (iv) from 0.1 to 30% wt of a lithium salt of a C10–C40 fatty acid or hydroxy fatty acid, and optionally (v) from 0 to 70% wt of a filler, all weights based on total bitumen composition, wherein the solvent is of general formula (I), wherein R1 represents a hydrogen atom or a hydrocarbyl group having from 1 to 6 carbon atoms, R2 represents a hydrocarbyl group having from 1 to 6 carbon atoms, and the sum of the carbon atoms in R1 and R2 is from 5 to 7; a process of preparing said bitumen composition and the use of the composition as a cold-applicable adhesive.Type: GrantFiled: October 10, 2003Date of Patent: June 13, 2006Assignee: Shell Oil CompanyInventors: François Julien Raoul Deygout, Alain Marcel Bernard Seive
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Patent number: 7045570Abstract: The present invention relates to compositions and methods for providing an improved means of modifying asphalt with a polymer. More particularly, this invention provides a solvent system that permits addition of the polymer as a liquid that is preferred over solids addition and handling. The solvent system includes a polymerizable monomer solvent and a rubber or elastomeric polymer.Type: GrantFiled: August 4, 2003Date of Patent: May 16, 2006Assignee: General Electric Co.Inventors: Paul R. Hart, Alan E. Goliaszewski
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Patent number: 7041717Abstract: A composition and a method for protection of constructions and structures from chemical action and destructive environmental effects. The main components of the composition are a polymerizing monomer, inert mineral filler, and chemical additives for improvement of chemical and physical properties. The method includes preliminary energetic activation of 5% by weight of the whole composition mass, adding the activated part of the composition to its main mass, and application of the composition to the surface of material chosen from the group including concrete, asphalt concrete, metal, and wood to obtain the required surface protection.Type: GrantFiled: August 12, 2003Date of Patent: May 9, 2006Inventor: Yuri Margulis
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Patent number: 6949593Abstract: Disclosed is a bituminous composition that comprises a bituminous component (A), an elastomer component (B), preferably a block copolymer of a conjugated diene and a monovinylaromatic hydrocarbon, and an additive (C), wherein the additive is a compound of the general formula Ar—R—Ar??(I) wherein each “Ar” independently is a benzene ring or fused aromatic ring system of 6 to 20 carbon atoms, substituted by at least one hydroxyl group, and “R” is an optionally substituted divalent radical comprising 6 to 20 atoms in the backbone and at least one amide and/or ester group in the backbone. These compositions are disclosed to be particularly useful in the preparing and repair of roofing.Type: GrantFiled: September 5, 2003Date of Patent: September 27, 2005Assignee: Kraton Polymers U.S. LLCInventors: Gerardus Wilhelmus Jozef Heimerikx, Erik Adrianus Theunis Trommelen
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Patent number: 6927245Abstract: The present invention provides a dispersing agent that facilitates the delivery of a cross-linking agent to polymer modified asphalt. The present invention further includes a composition comprising a liquid hydrocarbon, the dispersant and cross-linking agent, and methods of preparing the composition and of preparing cross-linked polymer modified asphalt composition.Type: GrantFiled: June 4, 2003Date of Patent: August 9, 2005Assignee: Fina Technology, Inc.Inventors: Paul Buras, James R. Butler
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Patent number: 6872763Abstract: Provided is a vulcanizing agent for vulcanizing bitumen, which vulcanizing agent comprises a sulphur agent and a binder, wherein the vulcanizing agent is in the form of pellets. Further provided is a process for producing a surfacing composition, which process comprises contacting bitumen with an elastomer and the vulcanizing agent of the present invention.Type: GrantFiled: October 24, 2001Date of Patent: March 29, 2005Assignee: ATOFINA Research, S.A.Inventor: Patrizio Andriolo
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Publication number: 20040229980Abstract: A method for improving the anti-stripping properties of an asphalt composition. The method comprises adding to the composition 0.05% to 10% of an amine-substituted polymer having an amine nitrogen content of at least 0.1% and a weight-average molecular weight of at least 5,000.Type: ApplicationFiled: May 16, 2003Publication date: November 18, 2004Inventors: Lawrence James Guilbault, Warren Harvey Machleder
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Patent number: 6818687Abstract: A polymer modified asphalt is characterized by the addition of a carrier material such as mineral oil. The carrier material is mixed with an activator material and then added to a hot mixture of polymer and asphalt. The activator assists the polymer material in linking with the asphalt while the carrier prevents the formation of gel or lumps within the asphalt. The modified asphalt retains its rheological and solubility characteristics.Type: GrantFiled: March 18, 2003Date of Patent: November 16, 2004Inventor: G. Mohammed Memon
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Publication number: 20040198874Abstract: Polymeric modified asphalt for road paving applications wherein the polymer modifier is a tubular reactor produced ethylene/alkyl acrylate copolymer (e.g., EMA) optionally blended with an epoxy functionalized ethylene copolymer (e.g., EnBAGMA) and added to the asphalt with or without the use of an acid adjuvant (e.g., PSA).Type: ApplicationFiled: March 23, 2004Publication date: October 7, 2004Inventor: George Wyatt Prejean
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Patent number: 6759453Abstract: The invention comprises polymers which have been functionalized so as to be able to chemically react with polyamines to form adducts containing at least one or more groups consisting of amino, amido, imino, imido, or imidazloyl. Furthermore, the invention teaches processes to prepare these adducts by solution, melt or in-situ methods. A further embodiment of the invention pertains to the use of polyolefin plastomers or elastomers, elastomeric polyethylene-polypropylene, compositions or interpolymers of styrene-&agr; olefins, which have been chemically modified so that they react with polyamines to confer to asphalt significantly improved desired chemical and physical properties.Type: GrantFiled: October 3, 2001Date of Patent: July 6, 2004Inventors: Murray Jelling, Richard F. Stockel, James Henderson Collins, Mohamed Emam Labib
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Patent number: 6743838Abstract: The present invention relates to polyepoxy-polymer-linked-asphalt having enhanced properties made by reacting a glycidyl-functionalized ethylene copolymer with reactive asphalt, wherein the glycidyl-functionalized ethylene copolymer has a glycidyl-containing comonomer content of 5 weight percent or less and relatively high number average molecular weight characterized by a melt index of 4 grams/10 minutes or less measured in accord with ASTM D1238-65T, Condition E.Type: GrantFiled: July 1, 2002Date of Patent: June 1, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert Joseph Statz, Elizabeth R. Griffin
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Patent number: 6743891Abstract: The present invention provides a method for producing an ethylene-vinyl alcohol copolymer resin composition, said method comprising: a) introducing into an extruder an ethylene-vinyl alcohol copolymer resin having a water content of at least 0.5 weight % and an additional component; b) kneading the resin and the additional component whereby to form an ethylene-vinyl alcohol copolymer resin composition; and c) discharging said resin composition from the extruder; wherein said method further comprises feeding water in a liquid state to the extruder and/or removing water in a liquid state from the extruder. Thereby, strand-breakage or cutting errors are suppressed and thus, molded products such as pellets can be provided with a stable shape.Type: GrantFiled: January 22, 2002Date of Patent: June 1, 2004Assignee: Kuraray Co., Ltd.Inventors: Hiroshi Kawai, Masao Hikasa, Takaharu Kawahara, Toshio Tuboi
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Publication number: 20030075834Abstract: In order to obtain curable molding compositions and shaped plastics articles produced therefrom which have an improved hot-pot resistance, it is proposed that a curable molding composition for the production of shaped plastics articles contains, in addition to a liquid monomeric acrylate component and a particulate inorganic material, the latter in a concentration ranging from 45 to 85 wt % and preferably from 55 to 75 wt %, based on the molding composition, an additional portion comprising a particulate hydrophobic and/or oleophobic plastics material in a concentration of 0.5 wt % or more.Type: ApplicationFiled: April 11, 2002Publication date: April 24, 2003Inventors: Andreas Hajek, Stefan Harke, Josef Geier, Klaus Hock
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Patent number: 6469075Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents comprise zinc 2-mercaptobenzothiole and elemental sulfur in a ratio of zinc 2-mercaptobenzothiazole to sulfur of 2.0/1.0. Useful concentrates are possible using this method while avoiding gel formation.Type: GrantFiled: November 14, 2000Date of Patent: October 22, 2002Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly, Karen Scheel
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Patent number: 6429241Abstract: Polymer modified bituminous compositions which are stable against phase separation are provided at greater levels of incorporation of elastomeric polymer having a conjugated diene structure, such as styrene-butadiene rubbers, and/or cross-linking agent, specifically sulfur, by incremental addition of elastomeric polymer and/or cross-linking agent into the bitumen at elevated temperatures of about 150° to about 220° C.Type: GrantFiled: December 2, 1999Date of Patent: August 6, 2002Assignee: Polyphalt LLCInventor: Zhi-Zhong Liang
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Patent number: 6414056Abstract: The present invention relates to novel polymer modified asphalt polyphosphoric and superphosphoric acid treated binder compositions having enhanced high service temperature performance properties and the method of making them and to road paving asphalts containing them.Type: GrantFiled: May 8, 1998Date of Patent: July 2, 2002Assignee: ExxonMobil Research and Engineering CompanyInventors: Olga Puzic, Kenneth Edward Williamson
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Patent number: 6407152Abstract: A process for the preparation of an asphalt and polymer composition in which a minor amount of polymer component is subjected to a crosslinking. An asphalt base material is heated in a mixing chamber at a temperature sufficient to melt the asphalt and allow stirring of the asphalt within the chamber. A thermoplastic elastomer is added to the chamber in an amount not greater than 12 wt. %. While the asphalt elastomer formulation is stirred, a crosslinking agent is added in an amount effective to crosslink the thermoplastic elastomer. The crosslinking agent formulation comprises at least two components. One component is a thiopolymer incorporating organic sulfur prepared by the reaction of 6-tertiary butyl cresol and sulfur dichloride which reacts to produce a reaction product comprising 4,4-thiobis(6-tertiary butyl-m-cresol) and the thiopolymer, followed by subsequent separation of the 4,4-thiobis(6-tertiary-butyl-m-cresol) from the thiopolymer product.Type: GrantFiled: November 28, 2000Date of Patent: June 18, 2002Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly
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Patent number: 6399680Abstract: An acid-reacted polymer-modified asphalt composition comprising (1) at least about 80 weight percent, based upon the composition, of an asphalt; (ii) about 0.2 to about 15 weight percent, based upon the composition, of a polymer containing available epoxy groups; and (iii) an amount of an acid effective for promoting chemical bonding between the asphalt and the polymer, wherein the composition exhibits substantially improved Dynamic Shear Rheometer stiffness values without an appreciable loss in the G″ viscous component of complex modulus, and low temperature creep stiffness and “m” values.Type: GrantFiled: August 22, 2000Date of Patent: June 4, 2002Assignee: Mathy Construction CompanyInventors: Steven L. Engber, Gerald H. Reinke
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Patent number: 6384112Abstract: A bitumen emulsion comprising bituminous binder, emulsifier, and water. The bituminous binder comprises bitumen and an oxidised wax, and optionally one or more polymers. The incorporation of the oxidised wax into the bituminous binder provides modified bitumen with both a high softening point and a low enough viscosity to allow it to be emulsified. The emulsion may be used as a tack coat in applying a waterproofing layer to a roof base. The emulsion may be made using a static mixing emulsion process.Type: GrantFiled: May 8, 2000Date of Patent: May 7, 2002Assignee: ExxonMobil Research and Engineering CompanyInventor: Nadjib Boussad
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Patent number: 6380284Abstract: The invention concerns the continuous production of asphalts modified by the addition of polymers and reacted with sulfur. The binders produced by said methods can contain very high amounts of polymers, also combined with secondary materials such as: rubber, various plastics, and waste lubricants. This type of binder, which cannot be obtained by discontinuous batch technology, is produced by the continuous mixing of several asphalt components through a static mixer. Said binders provide very high-performance asphalts and agents for regenerating old asphalts contained in waste road materials, in the process of hot recycling of coated materials. They are also used for producing novel emulsions of highly modified binders, with multiple applications and in particular for cold recycling. This novel method, by regenerating old asphalt contained in waste coated materials, represents a means for waste conversion and for limiting the use of asphalt and road-surfacing aggregates.Type: GrantFiled: May 15, 2000Date of Patent: April 30, 2002Inventor: Emile Lopez
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Publication number: 20010053804Abstract: A multipurpose cement dispersing, shrinkage compensating and anticorrosive polymer and an admixture comprising said polymer, which improve the workability and the early strength development of fresh concrete, are described.Type: ApplicationFiled: March 22, 2001Publication date: December 20, 2001Inventors: Jurg Widmer, Ueli Sulser, Ulf Velten, Irene Schober, Theodor A. Burge
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Patent number: 6310122Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion or aqueous emulsion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.Type: GrantFiled: September 3, 1999Date of Patent: October 30, 2001Assignee: Fina Technology, Inc.Inventors: James R. Butler, Kevin P. Kelly
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Patent number: 6180697Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.Type: GrantFiled: September 4, 1999Date of Patent: January 30, 2001Assignee: Fina Technology, Inc.Inventors: Kevin P. Kelly, James R. Butler
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Patent number: 6136898Abstract: A method is provided for improving high temperature performance grade properties of unblown asphalt by i) heating an asphalt cement to 200.degree. F. to 500.degree. F. (93.degree. C. to 260.degree. C.), ii) adding 0.1 wt. % to 10 wt. % ethylene-vinyl acetate copolymer based on weight of said asphalt cement to the heated asphalt cement, iii) adding 0.05 wt. % to 1.0 wt. % phosphorus-containing acid, e.g., polyphosphoric acid, based on weight of said asphalt cement and iv) mixing the resulting blend, thereby providing an unblown asphalt composition of greater useful temperature index (UTI). The invention further relates to asphalt compositions thus made and paving compositions containing these asphalt compositions.Type: GrantFiled: June 15, 1999Date of Patent: October 24, 2000Assignees: Marathon Ashland Petroleum LLC, Ashland Inc.Inventors: Roman Loza, Laurence G. Dammann, Roger E. Hayner, Patricia K. Doolin
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Patent number: 6130276Abstract: In a method of melting asphalt in a vessel, the molten asphalt normally emitting fumes, 0.2 weight percent to 6 weight percent of a polymer is added to the asphalt to reduce the visual opacity of the fumes by at least 25% over the same asphalt without the polymer. In another embodiment, the total emissions of benzene soluble suspended particulates is reduced by at least 15% over the same asphalt without the polymer. Preferably, the added polymer has a melt flow index of from 15 grams/10 minutes to 95 grams/10 minutes, and the added polymer reduces the visual opacity of the fumes by forming a skim on the upper surface of the molten asphalt.Type: GrantFiled: March 12, 1999Date of Patent: October 10, 2000Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Donn Roy Vermilion, Michael Richard Franzen, Richard T. Janicki, David Charles Trumbore, Jay W. Keating, Jorge Alberto Marzari
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Patent number: 6121375Abstract: The present invention, which addresses the needs of the prior art, provides irreversible, hydrophilic gels which can be incorporated into dressing compositions, dermatologically compatible compositions, wound packings, wound dressings, burn dressings, drug delivery dressings, dry films, cosmetic masks and cosmetic wrap dressings. The gels of the invention include a blend of a hydrophilic poly(aldehyde) and a polymer selected from the group consisting of a poly(amide), a poly(amine) and a poly(alcohol).Type: GrantFiled: February 11, 1999Date of Patent: September 19, 2000Assignee: Hydromer, Inc.Inventor: Michael Eknoian
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Patent number: 6117926Abstract: An acid-reacted polymer-modified asphalt composition including (i) 80 weight percent asphalt, (ii) 0.2 to 15 weight percent polymer containing available epoxy groups, and (iii) an acid effective for promoting chemical bonding between the asphalt and the polymer, wherein the composition exhibits substantially improved Dynamic Shear Rheometer stiffness values, without an appreciable loss in the G" viscous component of the complex modulus, low temperature creep stiffness and "m" values of the composition.Type: GrantFiled: May 23, 1997Date of Patent: September 12, 2000Assignee: Mathy Construction CompanyInventors: Steven L. Engber, Gerald H. Reinke
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Patent number: 6114418Abstract: The present invention provides an oil-in-water asphalt emulsion having excellent stability in a stationary state. That is, the present invention provides a method for emulsifying an asphalt in water, which comprises the step of mixing the asphalt and water with an emulsifier comprising a nonionic compound (1) having the formula (1):R--O--(C.sub.2 H.sub.4 O).sub.x --(CH(CH.sub.3)--CH.sub.2 --O).sub.y --(C.sub.2 H.sub.4 O).sub.z --H (1)in which R is an alkyl or an alkenyl, having 8 to 22 carbon atoms, being either straight or branched; x is a number of 0 to 40; y is a number of 1 to 10; and z is a number of 1 to 80.Type: GrantFiled: October 16, 1998Date of Patent: September 5, 2000Assignee: Kao CorporationInventors: Kazuo Isobe, Ryoichi Tamaki
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Patent number: 6107373Abstract: A consumable container is molded from a composition comprising 40 to 90 weight % of an asphalt and 10 to 60 weight % of a polymer material, which advantageously can include a first polymer such as PP that imparts heat resistance and a second polymer such as EVA that imparts toughness and impact resistance. This molded asphalt/polymer material preferably has an unnotched Izod impact strength of at least 2 joules. The container is consumable--it can be melted along with roofing asphalt held in the container without adversely affecting the properties of the asphalt and without requiring undue mixing. The composition also can be used to reduce fumes normally emitted from a kettle of molten asphalt, e.g., as measured by a reduction of the visual opacity of the fumes by at least 25%, a reduction of the hydrocarbon emissions of the fumes by at least 20%, or a reduction of the total suspended particulates emissions of the fumes by at least 15%. The container may be used, e.g.Type: GrantFiled: September 30, 1997Date of Patent: August 22, 2000Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Richard T. Janicki, Donn R. Vermilion, Kevin P. Gallagher, Frederick H. Ponn, Michael R. Franzen, Jorge A. Marzari, Jay W. Keating, David C. Trumbore, Steven G. Harris, Edward Mirra, Jr.
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Patent number: 6100317Abstract: Two or more different polymeric materials are stably incorporated into bitumen by effecting steric stabilization of a polyolefin, such as polyethylene, and by dispersing the other polymer, such as a styrene-butadiene-styrene copolymer, an ethylene-vinyl acetate copolymer or an EPDM copolymer in the stabilized polyethylene-bitumen composition. The ability to incorporate different polymeric materials in bitumen permits desirable modifications to the properties of the composition to be effected. In addition, different properties can be attained by modifying processing parameters.Type: GrantFiled: August 13, 1996Date of Patent: August 8, 2000Assignee: Polyphalt L.L.C.Inventors: Zhi-zhong Liang, Raymond T. Woodhams, James W. Smith
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Patent number: 6069194Abstract: A method and apparatus for packaging a low-fuming meltable asphalt composition which includes the introduction of pellets comprising one or more polymeric materials into molten asphalt flowed into a conventional container or carton.Type: GrantFiled: December 12, 1997Date of Patent: May 30, 2000Assignee: Owens Corning Fiberglass Technology, Inc.Inventors: Michael R. Franzen, Donn R. Vermilion, David C. Trumbore, Richard T. Janicki, Jeffrey W. Smith, Jay W. Keating, Jorge A. Marzari, Thomas C. Bitsky, Ron S. Bliss
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Patent number: 6060542Abstract: The invention provides a process for preparing a bitumen composition comprising blowing a mixture with an oxygen-containing gas which mixture comprises a bitumen having a penetration of less than 300 dmm (as measured by ASTM D 5 at 25.degree. C.), a thermoplastic rubber which is present in an amount of less than 10% w, and a bitumen blowing catalyst which is present in an amount of more than 0.5% w and up to 3% w, both based on total mixture; and bitumen compositions obtainable by such process.Type: GrantFiled: May 5, 1998Date of Patent: May 9, 2000Assignee: Shell Oil CompanyInventors: Gerrit Van Gooswilligen, Michael Christopher Phillips, Koen Steernberg