Abstract: This invention relates to a composition and method for improving the storage stability of acid treated polymer modified asphalts. More specifically, the storage stability of an asphalt which contains greater than 1.0 wt. % polymer can be improved by adding a branched, rather than a non-branched, polymer to an asphalt which has previously been reacted with an inorganic acid. The storage stable acid treated branched polymer modified asphalt thus produced is particularly well suited for use as a binder in paving materials and as a coating or saturant for roofing shingles.

Abstract: A thermoformable acoustical mat composition having reduced quantities of ethylene vinyl acetate and elastomers and increased filler concentrations. The composition includes an intimate blend of 5% to 30% of an asphalt constituent; 4% to 15% of an elastomer binder constituent; 50% to 80% of a filler constituent and 1% to 8% of an ethylene co-polymer constituent. A method of melt mixing and extrusion forming thermoformable acoustical mat compositions is also provided.

Abstract: A method of dispersing asphalt/asphaltene comprising an admixture of polymer A and polymer B ranging from 90 to 10 weight percent A to from 10 to 90 weight percent B. Wherein polymer A is an alkyl substituted phenolformaldehyde liquid resin having a weight average molecular weight ranging from about 1000 to about 20,000 and an alkyl substituent containing from 4 to 24 carbon atoms, with alkyl substituent may be linear or branched alkyl group. Polymer B is a hydrophilic-lipophilic vinylic polymer.

Abstract: The invention concerns a solvent-free, polymerizing hotmelt substance free of, or low in monomers, for corrosion- and/or abrasion proofing and/or forming a protective film with barrier properties on a real substrates and molded bodies made of metal, plastic, cellulose materials and/or inorganic materials, in particular for wrapping purposes, and consisting of(a) one or more polymerizing polymers containing hydroxyls with an average molecular weight (M.sub.w) between 1,000 and 500,000 and with a glass transition temperature (T.sub.g).gtoreq.20.degree. C., and/or(b) one or more polymerizing, linear, unbranched and/or unbranched polyesters and/or their copolymers with an average molecular weight (M.sub.w) between 900 and 50,000 and with a glass transition temperature (T.sub.g).gtoreq.-50.degree. C.

Abstract: This invention relates to a composition and method for improving the storage stability of polymer modified asphalts. More specifically, the storage stability of an asphalt which contains greater than 1.0 wt. % polymer can be improved by adding the polymer to an asphalt which has previously been reacted with an inorganic acid. The storage stable acid treated polymer modified asphalt thus produced is particularly well suited for use as a binder in paving materials and as a coating or saturant for roofing shingles.

Abstract: Modified asphalt compositions are described which comprise(A) asphalt, and(B) a minor effective amount, sufficient to improve the durability of the asphalt in service, of at least one hydrocarbon-soluble acrylate polymer of the formula ##STR1## wherein R.sup.1 is a lower alkyl group containing from 1 to about 4 carbon atoms, R.sup.2 is a mixture of alkyl groups containing from about 4 to about 20 carbon atoms, and x is an integer providing a weight average molecular weight (Mw) to the acrylate polymer of about 5000 to about 1,000,000.Generally, the modified asphalt compositions will contain from about 0.01 to about 10% by weight, based on the weight of the asphalt, of the acrylate polymer as defined. The modified asphalt compositions of the present invention are useful in roofing and in preparing aggregate-containing asphalt concretes which can be employed as paving compositions.

Abstract: An cationic emulsifier obtained from the reaction products of an alkyl phenol, polyamine, and formaldehyde or of an alkyl phenol, fatty acid/polyamine condensate, and formaldehyde and the uses of the emulsifier in cationic bituminous emulsions and paving slurry seal mixtures are disclosed.

Abstract: Process for the production of a binder modified with synthetic material for building materials, especially street-building material, in which for the formation of the binder, molten bitumen together with a thermoplast or a thermoplast mixture, preferably an olefin polymer, is subjected to a homogenization treatment. To the mixture containing the bitumen and a thermoplast or a thermoplast mixture, there is supplied in the form of kinetic energy an amount of energy corresponding to the difference between the treatment temperature and the disintegration temperature of the thermoplast or thermoplast mixture to form readily reacting molecular fragments of the thermoplast or thermoplast mixture. Preferably, the mixture containing bitumen and the thermoplast or a thermoplast mixture is driven through a narrow gap between two mixing tools standing opposite to one another and rotating relatively to one another.

Abstract: Bitumen-polyolefin compositions, e.g. for use as binders in paving compositions, are stabilized by an emulsifier system comprising a polyethylene wax terminally functionalized with acidic groups and having a polymeric main chain structure which is compatible with the polyolefin of the dispersed phase of the binder. In a preferred embodiment, the emulsifier system also includes an inorganic metal compound which will react chemically with the terminal functional groups of the polyethylene wax. Especially preferred is maleated polyethylene wax (as the polyethylene wax) and ferric oxide (as the inorganic metal compound). The emulsifier system forms a sheath of inorganic material around the dispersed polyolefin droplets, to stabilize them and to hinder their floatation to the surface of the binder composition.

Abstract: A composition useful as a pavement material comprising a mixture of asphalt and a polymer of an .alpha.-olefin, or an interpolymer of an .alpha.-olefin, and at least one copolymer selected from the group consisting of an .alpha.,.beta.-unsaturated carboxylic acid, a monomer of an .alpha.,.beta.-unsaturated carboxylic acid, a vinyl ester of alkanoic acid, and carbon monoxide.

Abstract: A sealant composition is provided to seal wood products against moisture absorption and the swelling caused thereby. The sealant composition is especially adapted to be applied to the cut ends of dimensioned lumber and particularly to the edges of wood products such as plywood, waferboard, oriented strand board and particle board. The composition includes a water-based polymeric binder, a wax hydrophobic filler and a water-soluble alkali metal siliconate salt. The polymeric binder preferably has two components. The first is a soft, stretchy polymer with a low glass transition temperature which allows the binder to stretch when the wood swells due to moisture absorption. The second is a polymer with a high glass transition temperature which enhances binding properties.

Abstract: A wet filter cake of coal fines or other inorganic particulate material is converted to a crumbly mass by blending with water absorbent polymer particles.

Abstract: Paving binders, especially hot mix paving structures, may be modified to have both storage stability and increased creep resistance by the addition of copolymers of ethylene with vinyl acetate or lower alkyl esters of acrylic acid and methacrylic acid to the asphalt used in said binder, provided the asphalt has an asphaltene content of about 7 wt. % or less.

Abstract: A composition useful as a pavement material comprising a mixture of asphalt, aggregate and an interpolymer of an .alpha.-olefin monomer selected from the group consisting of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid or an ionomer of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid.

Abstract: Modified asphalt compositions are described which comprise(A) asphalt, and(B) a minor effective amount, sufficient to improve the durability of the asphalt in service, of at least one hydrocarbon-soluble acrylate polymer of the formula ##STR1## wherein R.sup.1 is a lower alkyl group containing from 1 to about 4 carbon atoms, R.sup.2 is a mixture of alkyl groups containing from about 4 to about 20 carbons atoms, and x is an integer providing a weight average molecular weight (Mw) to the acrylate polymer of about 5000 to about 1,000,000. Generally, the modified asphalt compositions will contain from about 0.01 to about 10% by weight, based on the weight of the asphalt, of the acrylate polymer as defined. The modified asphalt compositions of the present invention are useful in roofing and in preparing aggregate-containing asphalt concretes which can be employed as paving compositions.

Abstract: (1) Polymeric compositions, suitable for use as bitumen modifiers, comprising, by weight:(a) 20-50% of an ethylene/propylene elastomeric copolymer containing from 60 to 75% by weight of ethylene, and having a value of Mooney viscosity (ML 1+4) at 100.degree. C. higher than 5;(b) 0-25% of polypropylene prevailingly constituted by isotactic macromolecules having an M.I. value higher than 1;(c) 0-70% of substantially amorphous polypropylene, possibly in mixture with amorphous copolymers of ethylene with propylene, such component (c) having a total combined ethylene content lower than 60% by weight, and intrinsic viscosity (in tetralin at 135.degree. C.) lower than 2 dl/g;(d) 0-25% of polyethylene having density comprised between 0.98 and 0.96 g/cm.sup.3, and having a value of M.I. higher than 5;(e) 0-25% of an ethylene/vinyl acetate (EVA) copolymer containing from 60 to 95% by weight of ethylene, having a value of M.I. higher than 0.

Abstract: An asphalt composition containing an asphalt, a copolymer of an olefin with an anhydride or a nitrile, and an unsaturated elastomer having at least two terminal groups each with an active hydrogen, a halogen, an epoxy oxygen or a cyanocarbon. The composition may be prepared by copolymerizing an olefin with an anhydride or a nitrile in the presence of a free radical initiator, and thereafter mixing the copolymer with the asphalt and elastomer. The copolymer may be mixed first with a petroleum oil, then with the elastomer and lastly with the asphalt. The copolymer may be a polyanhydride from maleic anhydride and 1-octadecene and the elastomer may be a hydroxy-terminated polybutadiene.

Abstract: An aqueous asphaltic emulsion wherein the asphaltic component is either a chemically-modified asphalt or an asphalt-elastomer blend, and the aqueous component contains water, a surfactant, and a high molecular weight, non-ionic, homopolymer of acrylamide. The emulsions find use as crack fillers for concrete or asphaltic roads and the like, or as coating compositions which can be sprayed on a building wall or the like as a waterproofing coating. The incorporation of the acrylamide ingredient into the composition ensures rapid and complete curing of other types of emulsions, and the emulsions possess physical properties and low-temperature flex properties which closely approximate those of the original asphaltic component.

Abstract: A slurry of coal particles in water includes as a dispersing agent a copolymer of acrylonitrile or methacrylonitrile with an acrylate or methacrylate compound wherein the copolymer has a molecular weight below 80,000 and comprises:(a) from 10 to 80% by weight of acrylonitrile or methacrylonitrile, and(b) 20 to 90% by weight of acrylic acid or methacrylic acid or an alkali metal, ammonium or amine salt thereof.

Abstract: Disclosed is a new and improved sealant and cement asphalt composition that is asbestos-free. The asbestos-free asphalt composition comprises about 40 to about 70 weight percent asphalt, about 5 to about 40 weight percent mineral filler, about 2 to about 10 weight percent cellulose fibers and about 2 to about 20 weight percent of a water-containing material such as an acrylic latex emulsion, asphalt emulsion or aqueous surfactant solution.

Abstract: Thermal insulating articles are disclosed of the type which comprises a laminate of thermal insulation and a flexible jacket material with the jacket and thermal insulation being directly adhesively adhered to each other by means of a hot-melt adhesive. The hot-melt adhesive employed consists essentially of an asphalt, an ethylene-vinyl acetate copolymer and a wax. Also provided is a hot-melt adhesive which consists essentially of an asphalt, an ethylene-vinyl acetate copolymer and a compatible wax, which is especially useful in adhering paper used as package wrap.

Abstract: A membrane for waterproofing a building component, e.g., a roof or a basement wall. The membrane includes a first layer of asphalt-elastomer blend which preferably is self-adherent to the building component and an overlying layer of plastic film which bears at least one adhesive strip adhered to the plastic film. The membrane is in the form of elongated strips which are overlapped to cover the building component, and the adhesive of each strip ensures a waterproof joint between the laminae of the overlapped strips.

Abstract: Ethylene-vinyl acetate copolymers having a melt index of 700-10,000 and a vinyl acetate content of from 1-40% by weight (based on the copolymer) are used as components of bitumenous binder compositions for the surface dressing of roads to improve the temperature range of their operability, the particular EVA's are also found to have good compatibility with the types of bitumen used.

Abstract: The present invention relates to bituminous polymer emulsions and more particularly to a novel method for producing such emulsions to produce a coating which yields superior flexiblity and water resistance.The method of producing the bituminous polymer consists in passing heated asphalt and a heated polymer emulsion through a colloid meal. The resultant emulsion may have up to 75% solids.

Abstract: Compositions comprising 15 to 20% amorphous olefin copolymer, 3 to 5% ethene-propene-ethylidine norbornene terpolymer of the sequence type with 25 to 30% propene content, 6 to 8% double bonds, and raw strength 10 MPa, 60 to 82% distilled bitumen, 0 to 3% isotactic polypropylene, 0 to 15% filler and 0 to 1% antioxidizing agent, when heat-sealed to a layer of oxidized bitumen, form a stable bond therewith and thus can be used to form a waterproofing surface coat on fibrous roofing sheets.

Abstract: Modified asphalt compositions are described which comprise(A) asphalt, and(B) a minor amount, sufficient to reduce or retard degradation of the asphalt in service, of at least one carboxy ester-containing interpolymer derived from(B-1) at least one olefin monomer, and(B-2) at least one alpha, beta-unsaturated carboxylic acid or derivative thereof, said interpolymer having (1) pendant carboxylic acid ester groups derived from the esterification of the carboxy groups of the interpolymer with at least one alcohol containing at least about 4 carbon atoms.Generally, the modified asphalt composition will contain from about 0.01 to about 10% by weight, based on the weight of the asphalt, of the ester of a carboxy interpolymer as defined. The modified asphalt compositions of the present invention are useful in roofing applications and in preparing aggregate-containing asphalt concretes which can be employed as paving compositions.

Abstract: An asphaltic coating composition in the form of an emulsion of chemically modified asphalt and a normal, non-modified asphalt in an aqueous emulsification medium. The emulsion can be used as a primer or damp-proof coating and has good adherence to concrete, wooden or asphaltic substrates to yield a coating of excellent physical properties. The chemically modified asphalt and the normal asphalt can be blended prior to emulsification, can be separately emulsified and mixed to form a blended emulsion, or can be individually emulsified in the same emulsification medium.

Abstract: The present invention provides a bitumen-polymer composition comprising 95 to 99% by weight of a bitumen and 1 to 5% by weight of a terpolymer having a melt index between 5 and 50 dg/min. The terpolymer comprises 88 to 98.7 mol % of units derived from ethylene; 1 to 10 mol % of units derived from at least one ester selected from the group consisting of alkyl acrylates and methacrylates, the alkyl group having from 1 to 6 carbon atoms; and 0.3 to 3 mol % of units derived from maleic anhydride. The bitumen-polymer composition is used in the preparation of road surface binders.

Abstract: A binder composition which is pigmentable comprising from 30 to 99 wt % of a mineral lubricating oil extract and from 70 to 1 wt % of a petroleum resin and/or coumarone-indene resin, characterized in that the petroleum resin and/or coumarone-indene resin contains moieties derived from carboxylic acid, carboxylic acid anhydride or hydroxyl groups.

Abstract: A waterproof membrane useful as a coating or flashing for roofs or as a liner for containing liquids which comprises a composition containing a neutralized sulfonated EPDM polymer and asphalt, the former component comprising at least 30% by weight of the total weight of the polymer and asphalt. The composition has outstanding physical properties and an unexpectedly high tensile strength.

Abstract: Ethylene-vinyl acetate copolymers having a melt index of 2,000 to 7,500 and containing from 10 to 22% vinyl acetate are useful in hot melt road marking compositions containing from 1 to 30% of the EVA copolymer; from 0 to 29% by weight of a binder resin; and from 0 to 5% by weight of a plasticizer, the balance of the composition typically comprising from 70 to 80% by weight of aggregates, made up of particulate materials such as sand and/or fillers and/or pigments such as calcium carbonate and titanium dioxide.

Abstract: The present invention is directed to a foamed product having a substantially closed cellular configuration. The foamed product is formed from a blend of asphalt with a polyvalent metal salt of anionic group containing polymers. The resultant foam product exhibits low bulk densities and pore volumes of about 85 percent or greater.

Abstract: Pressure sensitive bitumen-based adhesive compositions are provided which comprise bitumen, oil, an ionomeric elastomer, and gilsonite. The adhesives are particularly useful as self adherent waterproofing layers in roofing. The presence of gilsonite can result in substantial increases in the shear strength of these adhesives at the relatively high temperatures encountered in roofing applications.Also provided are waterproofing membranes comprising the inventive adhesive compositions.

Abstract: Bitumen-based pressure sensitive adhesive compositions are provided which comprise bitumen, oil, and an ionomeric elastomer. The adhesive compositions are useful as self adherent waterproofing layers, particularly in roofing applications. The use of the ionomeric elastomer permits formulation of the adhesive to have improved tack at the lower temperatures encountered in such application while maintaining desired flexibility, shear strength, and flow resistance.Also provided are waterproofing membranes comprising the inventive adhesive compositions.

Abstract: Thermal insulating articles are disclosed of the type which comprises a laminate of thermal insulation and a flexible jacket material with the jacket and thermal insulation being directly adhesively adhered to each other by means of a hot-melt adhesive. The hot-melt adhesive employed consists essentially of an asphaltene enriched asphalt, an ethylene-vinyl acetate copolymer and a wax.

Abstract: Ionomeric polymer compositions are provided which comprise an ionomeric polymer and about 5 to about 125 parts by weight of gilsonite, per 100 parts by weight of the ionomeric polymer. The inventive compositions can be formulated as processable materials which can be fabricated into articles such as sheets, tubes, and films having improved tear propagation resistance and fire retardance and decreased levels of water absorption.

Abstract: A process and composition are provided that provide for thermal transfer of ink compositions and eliminate the need to prepare articles such as sign faces, particularly flexible sign faces, by painting with ink compositions that contain solvents. The present process and composition permit thermal transfer from a carrier to a receptor at low temperatures with the use of vacuum pressure. The transferred ink adheres tenaciously to the receptor and is flexible.

Abstract: The viscosity of an asphalt emulsion may be controlled by incorporating up to about 1 percent by weight of a modified starch containing not more than 27 percent amylose and the balance substantially amylopectin.

Abstract: A process and composition are provided that provide for thermal transfer of ink compositions and eliminate the need to prepare articles such as sign faces, particularly flexible sign faces, by painting with ink compositions that contain solvents. The present process and composition permit thermal transfer from a carrier to a receptor at low temperatures with the use of vacuum pressure. The transferred ink adheres tenaciously to the receptor and is flexible.

Abstract: This invention relates to a blend of an olefin/alkyl acrylate copolymer and hardened extract which has a saturated hydrocarbon content of not more than 10% by weight and articles made therefrom, e.g. linings for reservoirs and for water proofing roofs. The new products are easier to manufacture since they resist gelation, do not suffer from problems of shrinkage and are appreciably cheaper.

Abstract: Method and composition for protecting, maintaining and repairing paved surfaces utilizing a workable fiber-containing asphalt and/or latex emulsion in combination with an active amount of a water-soluble polymer material differing in ionic characteristics from the emulsion or emulsifier component thereof.

Abstract: An asphalt blend in which a butadiene-styrene elastomeric block polymer can easily be dispersed at between about 325.degree. F. and about 400.degree. F. and, after cooling, forms a stable material useful as a roofing composition and having a flash point of greater than about 450.degree. F., said blend being composed of a propane extracted asphalt and from about 5 weight % to about 45 weight % of a fluid bed catalytic petroleum cracker bottoms oil comprising a major proportion of oils boiling above 700.degree. F. and, optionally, a minor proportion of oils between about 350.degree. F. and 700.degree. F.

Abstract: A method for producing air-blown industrial asphalt using asphalt, ethylene/vinyl-acetate copolymer and an air-blowing catalyst is disclosed. The EVA copolymer is present in a weight percent of from 1 weight percent to 10 weight percent. Also disclosed is the asphalt composition resulting from the air-blowing method.

Abstract: A composition for sealing products comprising from 35 to 95 weight percent of at least one distillation product selected from the group consisting of bitumens and soft pitches, and from 5 to 65 weight pecent of a terpolymer having a melt index between 1 and 10 dg/minute and comprising: (i) from 88 to 98.7 mole percent of units derived from ethylene (ii) from 1 to 10 mole percent of units derived from an ester selected from alkyl acrylates and methacrylates, wherein said alkyl group has from 1 to 6 carbon atoms, and (iii) from 0.3 to 3 mole percent of units derived from maleic anhydride.

Abstract: Plastisols useful for automobile undercoatings, anti-noise compositions, adhesives, sealing compositions and coatings for untreated, pretreated, phosphated, primed and prelacquered metal bases are improved by the addition of coke dust and coal dust fillers. The carbon dust fillers have a particle size of about 0.5 to 1000 microns and they are used in a concentration of about 9 to 90% by weight based on the total weight of plastisol and carbon dust. The carbon dust filled plastisols have a specific gravity of about 1.1 to 1.3.

Abstract: An aqueous asphaltic emulsion is provided in which the dispersed asphaltic material is the prereacted reaction product of asphalt having a viscosity of less than about 120,000 cps (at 140.degree. F.), an acrylamide, a vinyl aromatic monomer and an elastomer.

Abstract: Asphaltic compositions having improved elastic properties and improved adhesion to aggregate particles as well as a high degree of resistance to stripping action are provided which comprise a major amount of asphalt and a minor amount of terpolymer of ethylene, vinyl acetate or vinyl chloride and an organic acid alkoxylated with about 1 to about 10 weight percent of an alkylene oxide. Optionally, the composition may contain a minor amount of a synthetic terpenic resin.

Abstract: An asphalt composition for air-blowing is disclosed comprising asphalt flux, ethylene/vinyl-acetate copolymer, and an air-blowing catalyst. The EVA copolymer is present in a weight percent of from 1 weight percent to 10 weight percent and is comprised of from 35 to 45 vinyl acetate.

Abstract: Chemically modified asphalts having utility for road construction, repair and maintenance as well as coating for various substrates, including cementitious substrates, glass and metal are provided. These asphalts are the product produced by reacting an acrylamide, asphalt having a viscosity of less than about 120,000 cps (at 140.degree. F.), a vinyl aromatic monomer and a rubbery polymer.

Abstract: A rubberized asphalt composition which comprises a moisture-curing diene series liquid rubber, asphalt and aggregates, and a process for producing same. Liquid rubber having a molecular weight of from 500 to 50,000 and having an isocyanate group or an isocyanate group blocked by phenol or acetoxime as a functional group at the terminals of the molecule is preferably utilized. The liquid rubber comprises from 4 to 10% by weight of the total of liquid rubber and asphalt.