Abstract: Two-part polyurea-urethane adhesive compositions comprising a Part A prepolymer component having an isocyanate component comprising polymeric isocyanate and an oligomer content greater than 15 weight percent, polyol having a molecular weight of about 5,000 to about 12,000 and about 20 weight percent to about 44 percent weight percent filler; and a Part B curative component comprising polyol having molecular weight of about 5,000 to about 12,000, aromatic amine, about 20 weight percent to about 44 percent weight percent filler and catalyst wherein the adhesive has an 85° C. storage modulus greater than about 20 MPa. The two-part polyurea-urethane adhesive composition can be applied to bond various substrates including composite materials and metal, including making parts for the transportation and assembly markets.

Abstract: A liquid isocyanate composition is provided. The composition comprises at least one isocyanate component; at least one polyol and/or the adduct of said at least one isocyanate component and at least one polyol; clay nanoparticles. The polyol is an EO-tipped polyol, the NCO/OH ratio being in the range of 1500 to 1.5.

Abstract: A process for preparing aqueous dispersions of composite particles using monomers containing silane groups.

Abstract: A clay-aerogel composite including a plurality of clay flakes having a layered structure and an aerogel on a surface of the clay flakes, wherein the plurality of clay flakes are connected to each other to provide a three-dimensional network structure, and the aerogel includes a copolymer of a first compound selected from an aryl alcohol, an amino-substituted triazine, or a combination thereof, and a second compound, which is an aldehyde.

Abstract: A process for preparing aqueous dispersions of composite particles using nonpolymerizable silane compounds.

Abstract: Disclosed is a coating formed from a composition containing a film-forming resin and a plurality of particles dispersed in the resin. The average particle size of the particles is 0.1 to 50 microns, and the particles have a hardness sufficient to impart greater mar and/or scratch resistance to the coating as compared to a coating where no particles are present. Also, the difference between the refractive ranges from 1 to 1.5. A method for preparing a powder coating including the particles also is provided.

Abstract: The invention relates to a one-component, storage-stable formulation for marking road surfaces. The invention in particular relates to a formulation for roadway marking comprising encapsulated radical initiators which do not influence the storage stability of the roadway marking and are simple to break open upon application in order to release the initiator.

Abstract: Polycarbonate nanocomposites comprising a polycarbonate matrix having non-oxidized metal nanoparticles dispersed therein are disclosed. The polycarbonate nanocomposite is produced by a process comprising forming a reaction mixture comprising a dihydroxy compound, an activated carbonate, a metal precursor, and a solvent; and in-situ polymerizing the reaction mixture to form a nanocomposite comprising a polycarbonate matrix and metal nanoparticles dispersed therein. The metal precursor comprises a metal selected from a specified group. The nanocomposites have improved mechanical, optical, electrical and/or magnetic properties. Also disclosed are articles formed from such polycarbonate nanocomposites.

Abstract: A curable composition having a low viscosity and good workability which can give a mechanically strong cured product is provided. A curable composition comprising a curable resin component containing a polymer (A) having a polyoxyalkylene chain, a reactive silicon group and a urethane bond in the molecule and at least one silicate mineral (X) selected from the group consisting of a silicate mineral (B) represented by Al2O3.2SiO2.nH2O (wherein n is from 0 to 4) and a calcined silicate mineral (C) obtained by calcining the silicate mineral at 350 to 1,200° C.

Abstract: Disclosed are a polyamic acid solution, a polyimide resin prepared by imidization of the polyamic acid solution, a flexible metal clad laminate using the polyimide resin, and a printed circuit board including the flexible metal clad laminate, wherein the polyamic acid solution includes (a) 3,3?,4,4?-biphenyltetracarboxylic acid dianhydride (BPDA), and pyromellitic dianhydride (PMDA) as aromatic tetracarboxylic acid dianhydride; (b) at least one aromatic diamine; (c) an organic solvent; and (d) an inorganic filler.

Abstract: The present invention relates to a process for preparing super absorbent polymers, and more specifically to a process for preparing super absorbent polymers comprising the steps of: forming a monomer composition comprising water-soluble, ethylenic unsaturated monomers and non-reactive fine particles having a diameter of 20 nm to 1 mm; and subjecting the monomer composition to a thermal polymerization or a UV-induced polymerization. In the present invention, introducing fine particles into the monomer composition can provide paths for effectively discharging moisture or heat from the super absorbent polymers during or after a polymerization, thereby making it possible to obtain high quality super absorbent polymers showing a low water content and a low temperature and thus having excellent properties and enabling one to expect an energy-saving effect in a drying process.

Abstract: A surface-treating article includes an organic matrix substantially engulfed by a binder that includes a reaction product of a blocked polyurethane prepolymer and a mixture of aromatic amines. The aromatic amines include polymethylene polyaniline having a functionality equal to or greater than 4.

Abstract: An embodiment of the invention is luminescent silicon nanoparticle polymer composite that can serve as a wavelength converter or a UV absorber. The composite includes a polymer or an organosilicon compound; and within the polymer or organosilicon compound, a dispersion of luminescent silicon nanoparticles. In a preferred composite, the silicon nanoparticles have multiple Si—H termination sites, the silicon nanoparticles being linked to a C site to produce a silicon carbide bond (Si—C). In a preferred embodiment, the polymer comprises polyurethane. A composite of the invention can perform wavelength conversion. In a wavelength converted film of the invention, the silicon nanoparticles are incorporated into the polymer or organosilicon compound in a quantity sufficient for wavelength conversion but small enough to have no or an insubstantial effect on the properties of the polymer or the organosilicon compound. A white LED of the invention includes a light emitting diode having a narrow band wavelength output.

Abstract: An adhesive composition for use in adhering insulation panels to roofing substrates and roofing membranes to the insulation panels include two components that are mixed prior to application on the roofing substrate. The first component may include a renewable polyol and catalyst. The renewable polyol is selected from any non-petroleum based polyol that is derived from a renewable source. The second component includes isocyanate, and may also include a polyol and a catalyst. The isocyanate and the polyol may each be any non-petroleum based isocyanate or polyol that is derived from a renewable source.

Abstract: A hydrogel having a floatability where from 40% to 90% of a solution and/or suspension to be thickened are thickened starting from the surface of the liquid and the rest of the solution and/or suspension to be thickened is thickened starting from the bottom of the container, a process for preparing the hydrogel and also its use for absorbing blood and/or body fluids, especially in hygiene articles, or for thickening aqueous solutions and/or suspensions, especially for thickening medical wastes.

Abstract: A syrup composition of the present invention comprises a mixture of monomers (A), each having a molecular mass of 130 to 300 and one (meth)acryloyl group; a resin (C) which is soluble in the monomers (A) and has a glass transition temperature of 20 to 155° C.; a wax (D); and a tertiary amine (E), wherein the monomers (A) contain a heterocyclic ring-containing (meth)acrylate (a1), an oligoethylene glycol monoalkyl ether (meth)acrylate (a2), and a hydroxyalkyl (meth)acrylate (a3) having a hydroxyalkyl group with 2 or 3 carbon atoms. The syrup composition does not substantially contain a polyvalent metal soap.

Abstract: A sol to form an inorganic-organic hybrid coating having a thick highly transparent hard coating is described. The hybrid coating is formed from a combined aqueous sol with least one hydrolyzable silane and at least one hydrolyzable metal oxide precursor where the only organic solvents present are those liberated upon hydrolysis of the silanes and metal oxide precursors. In one embodiment an inorganic-organic hybrid coating is formed by combination of a sol, prepared by the hydrolysis of tetraethoxysilane and ?-glycidoxypropyltrimethoxysilane with an excess of water, and a sol, prepared by the hydrolysis of titanium tetrabutoxide and ?-glycidoxypropyltrimethoxysilane with a deficiency of water. A plastic substrate can be coated with the combined sol and the combined sol gelled to a thickness of at least 5 ?m with heating to less than 150° C.

Abstract: Chain-extended nanonylon is made from the reaction of in-situ polymerized nanonylon and chain-extending agents. Knowing the viscosity/shear rate curve for a thermoplastic polymer to be replaced, such as nylon, the method of the present invention allows via adjustment of organoclay concentration and chain extension of the nylon polymer and other reaction factors to achieve a chain-extended, in-situ polymerized nanonylon to have a viscosity/shear rate curve that essentially matches the viscosity/shear rate curve for that neat nylon within a commercially operable shear rate.

Abstract: A method for producing a thermoplastic polymeric matrix includes adding a suspension containing a silicate compound and/or barium sulfate either before or during the polymerization of the polymerizable polymeric matrix; various articles are obtained by forming this polymeric matrix, such as yarns, fibers, filaments, films and molded articles.

Abstract: The invention concerns an aqueous specific silica-based nanocomposite polymer dispersion, a method for preparing same, a coating composition, in particular protective, containing said dispersion, for applications requiring high anti-corrosive, anti-abrasive and chemical resistance performances. It concerns an aqueous nanocomposite polymer dispersion obtainable by an emulsion polymerization process of at least one monomer composition in the presence of at least one aqueous silica nanoparticle dispersion, said monomer composition being added at least in one step into the reactor already containing the aqueous silica nanoparticle dispersion, said aqueous silica nanoparticle dispersion having an anionic character and being stable in a pH range between 2 to 10, and said emulsion polymerization being performed in the presence of at least one organic initiator free of any ionic group and in the absence of any monomer or cationic dispersant.

Abstract: A (thio)phenoxyphenyl phenyl silane composition is disclosed. A method of making the (thio)phenoxyphenyl phenyl silane composition is also disclosed, the method further including a step of purification. A high purity (thio)phenoxyphenyl phenyl silane composition suitable for use in the preparation of encapsulants for high brightness light emitting devices is further disclosed.

Abstract: Solution blending of masterbatch of cationically functionalized polyvinyl acetate copolymer/silicate nanocomposite where the silicate is substantially exfoliated, and ethylene-vinyl acetate copolymer (EVA), produces product of increased tensile strength and Young's Modulus compared to neat EVA and reduced flammability compared to neat EVA. The product can be injection molded or compression molded or extruded without loss of these advantages.

Abstract: An object of the present invention is to improve abrasion-resistance and spin performance of a golf ball having a polyurethane cover. The golf ball of the present invention is a golf ball having a core and a cover covering the core. The cover contains a layered silicate and a polyurethane resin having a secondary or a tertiary amine structure in a molecular chain thereof. In the present invention, the polyurethane resin used as a resin component constituting the cover has a secondary or tertiary amine structure in a molecular chain. Thus, it has a strong interaction with the layered silicate, and a reinforcing effect of the filler becomes even higher. As a result, abrasion-resistance and spin performance of the resultant cover are improved.

Abstract: In one embodiment, the present invention provides a method of making a polymer-organoclay composite composition comprising (a) contacting under condensation polymerization conditions a first monomer, a second monomer, a solvent, and an organoclay composition, said organoclay composition comprising alternating inorganic silicate layers and organic layers, to provide a first polymerization reaction mixture, wherein one of said first monomer and second monomers is a diamine and the other is an dianhydride; (b) carrying out a stoichiometry verification step on the first polymerization reaction mixture; (c) optionally adding additional reactant (monomer 1, monomer 2, or chainstopper) to the first polymerization reaction mixture to provide a second polymerization reaction mixture; and (d) removing solvent from the first polymerization reaction mixture or the second polymerization reaction mixture to provide a first polymer-organoclay composite composition comprising a polymer component and an organoclay component w

Abstract: The present invention relates to an organopolysiloxane composition that can be vulcanized at room temperature into an elastomer that is crosslinked by polycondensation and that does not contain alkyltin-based catalysts and also to novel organopolysiloxane polycondensation catalysts.

Abstract: The invention relates to a process for producing a water-absorbing resin by polymerization of a reaction mixture comprising at least one hydrophilic monomer and, if appropriate, at least one crosslinker in a reactor, which comprises admixing the reaction mixture with at least one first portion of a particulate additive before the reaction mixture has reached a residence time of 40% of the overall residence time in the reactor and with at least one second portion of a particulate additive when the reaction mixture has reached a residence time of 45% or more of the overall residence time in the reactor, the additive being selected from water-absorbing resin powders, fillers and mixtures thereof, the total solids content of monomer and additive being in the range from 30% to 60% by weight, the amount of additive being in the range from 5% to 50% by weight, based on the monomers, and the weight ratio of the first portion to the second portion of the additive being in the range from 10:1 to 1:5.

Abstract: The invention includes embodiments that relate to a method of improving the abrasion resistance of a plastic article. The method comprises: (a) providing a composition comprising at least one e-beam active nanoparticle compound and at least one thermoplastic polymeric material; (b) forming an article from the composition of step (a); and (c) exposing the article formed in step (b) to an electron beam source. The invention also includes embodiments that relate to an article comprising an abrasion resistant surface.

Abstract: A process of repairing a plasma etched low-k dielectric material having surface-bound silanol groups includes exposing at least one surface of the dielectric material to (a) a catalyst so as to form hydrogen bonds between the catalyst and the surface-bound silanol groups obtaining a catalytic intermediary that reacts with the silane capping agent so as to form surface-bound silane compounds, or (b) a solution comprising a supercritical solvent, a catalyst, and a silane capping agent so as to form hydrogen bonds between a catalyst and the surface-bound silanol groups obtaining a catalytic intermediary that reacts with the silane capping agent so as to form surface-bound silane compounds. Horizontal networks can be formed between adjacent surface-bound silane compounds.

Abstract: A binder formulation is provided that is capable of forming a heat and erosion resistant coating on the surface of a substrate, particularly a substrate comprising titanium or aluminum. The binder formulation comprises a metal alkoxide compound, such as a titanium alkoxide and an organosilane, such as 3-glycidoxypropyltrimethoxysilane (GTMS). The binder material may be capable of strongly bonding the binder to the substrate. The binder coating may also include one or more additives that may help improve the heat resistance and impact absorbance of the coating. The binder may also include one or more pigments so that the resulting sol-gel coating has a desired appearance and properties. The sol-gel coating can be cured under ambient conditions and does not require additional heat curing.

Abstract: The present invention relates to a polyamide-based composition stabilized with respect to light and/or heat comprising at least one stabilizer exhibiting at least one hindered amine functional group. The invention also relates to yarns, fibres, filaments and/or articles obtained from this composition.

Abstract: A process is provided for preparing polyester composite materials, comprising polymerizing at least one polyester precursor in the presence of filler microparticles and/or nanoparticles and organosilane having nucleophilic functionality. The organosilane is added as a distinct ingredient. The polyester composites so prepared have low acid end group content, thus improved hydrolytic and melt stability and improved elongation at break.

Abstract: A binder formulation is provided that is capable of forming a heat and erosion resistant coating on the surface of a substrate, particularly a substrate comprising titanium or aluminum. The binder formulation comprises a metal alkoxide compound, such as a titanium alkoxide and an organosilane, such as 3-glycidoxypropyltrimethoxysilane (GTMS). The binder material may be capable of strongly bonding the binder to the substrate. The binder coating may also include one or more additives that may help improve the heat resistance and impact absorbance of the coating. The binder may also include one or more pigments so that the resulting sol-gel coating has a desired appearance and properties. The sol-gel coating can be cured under ambient conditions and does not require additional heat curing.

Abstract: The present invention relates to an aqueous composition comprising anionic organic polymeric particles and colloidal anionic silica-based particles. The anionic organic polymeric particles are obtainable by polymerizing one or more ethylenically unsaturated monomers together with one or more polyfunctional branching agents and/or polyfunctional crosslinking agents. The anionic organic polymeric particles and the colloidal anionic silica-based particles in the aqueous composition are present in an amount of at least 0.01% by weight based on the total weight of the aqueous composition. The present invention further relates to a method for the preparation of the aqueous composition, uses of the aqueous composition and a process for the production or paper, in which the aqueous composition is added to a cellulosic suspension.

Abstract: The present invention relates to a spray-polyurethane system which comprises a polyol component (A) and an isocyanate component (B), where the polyol component (A) comprises a1) at least one compound reactive with isocyanate, a2) at least one reactive chain extender having at least two groups reactive toward isocyanates, where at least one group reactive toward isocyanates is a free, primary NH2 group, and also a3) at least one metal catalyst, and a4) if appropriate, further additives, where the spray-polyurethane system comprises no amine catalyst. The present invention moreover relates to a process for production of a backing layer composed of polyurethane for moldings and to the use of this backing layer for production of automobile parts. Inventive backing layers have good mechanical properties, and low emissions, and their demolding time is small when compared with the open assembly time.

Abstract: The invention concerns an aqueous specific silica-based nanocomposite polymer dispersion, a method for preparing same, a coating composition, in particular protective, containing said dispersion, for applications requiring high anti-corrosive, anti-abrasive and chemical resistance performances. It concerns an aqueous nanocomposite polymer dispersion obtainable by an emulsion polymerization process of at least one monomer composition in the presence of at least one aqueous silica nanoparticle dispersion, said monomer composition being added at least in one step into the reactor already containing the aqueous silica nanoparticle dispersion, said aqueous silica nanoparticle dispersion having an anionic character and being stable in a pH range between 2 to 10, and said emulsion polymerization being performed in the presence of at least one organic initiator free of any ionic group and in the absence of any monomer or cationic dispersant.

Abstract: A photo-curable adhesive composition includes oligourethane acrylate in a range of about 11 to about 23% by weight, reactive monomer-diluent in a range of about 11 to about 24% by weight, silicate filler in a range of about 50 to about 65% by weight, photoinitiator in a range of about 2.5 to about 5.0% by weight, organic peroxide in a range of about 0.1 to about 0.5% by weight, thixotropic agent in a range of about 0.5 to about 3.5% by weight, antioxidant in a range of about 0.005 to about 0.02% by weight, silane finishing agent in a range of about 0.1 to about 2.5% by weight, and oxalic acid in a range of about 0.5 to about 1.5% by weight, based on the total weight of the composition.

Abstract: A method for processing a crosslinkable elastomeric composition including at least one silica reinforcing filler and at least one sulfur-containing organosilane compound by using at least one processing apparatus having an internal metal surface, includes the following steps: (a) pretreating at least one portion of the internal metal surface of the at least one processing apparatus with at least one sulfur-free organosilane compound having at least one hydrolizable group; (b) feeding the crosslinkable elastomeric composition including silica to the at least one processing apparatus; and (c) processing the crosslinkable elastomeric composition.

Abstract: The invention relates to a method for production of polyester resins containing nanodisperse nanoscale additives as binder for powder paints, whereby firstly at least one precursor compound for nanoscale solid particles to be formed is added to the reaction starting materials during the resin synthesis and distributed in the reaction starting materials. The precursor compound(s) which may be reacted at a temperature between 30? and 260° C., preferably between 80° and 250° C., are reacted to give the desired nanoscale solid particles under the effect of a reaction temperature in the range between 30? and 260° C., preferably between 80? and 250° C., the nanoscale solid particles thus formed being nanodispersedly distributed in the polyester resin.

Abstract: Compounds containing a lanthanide rare earth element or yttrium are effective catalysts for the polymerization of macrocyclic polyester oligomers. The catalysts are stable at elevated temperatures, and the polymerization is rapid, resulting in high monomer conversion, high molecular weight, and a mechanically sound material.

Abstract: N-heterocyclic carbenes are effective catalysts for the ring opening polymerization of cyclic amides. The catalysts provide rapid polymerization, high monomer conversion, high molecular weight, and a mechanically sound material.

Abstract: Mixtures or adducts of N-heterocyclic carbenes with metal amides or metal alkoxides are effective catalysts for the polymerization of macrocyclic polyester oligomers. The catalysts are stable at polymerization temperatures, and the polymerization is rapid, resulting in high monomer conversion, high molecular weight, and a mechanically sound material.

Abstract: A thermosetting resin composite material is manufactured by forming a polybenzoxazine resin by polycondensation reaction of a compound having a phenolic hydroxyl group, primary amines, and formaldehydes in the presence of a swelling clay mineral having been subjected to organizing treatment, or by adding the swelling clay mineral to the reaction system after termination of the polycondensation reaction. A friction material is provided with the thermosetting resin composite material obtained by the above method.

Abstract: Processes are disclosed relating to modifying clays with an olefinic functionalized surfactant containing a chain end polymerizable double bond, and to treating the thus modified organoclay with an olefin polymerization catalyst precursor, and polymerizing an olefin in the presence of the thus treated organoclay and an organoaluminum cocatalyst.

Abstract: Disclosed herein are high refractive index coating compositions containing a functionalized metal oxide nanoparticle and sulfur-containing polymerizable components. The composition can be prepared into optical articles via curing processes.

Abstract: The invention relates to a composition suitable for catalysis in a process for the manufacture of polyester containing as Component I a carrier substance on which catalytically effective metal compounds are adsorbed and as Component II a phosphonic acid compound.

Abstract: The invention provides intimate physical mixtures of macrocyclic polyester oligomer (MPO) and filler, as well as methods for their preparation and use. Improved dispersion of filler in a polymer matrix is achieved upon polymerization, and larger amounts of filler with high aspect ratio can be used. In one aspect, the invention provides mixtures of MPO with magnesium silicate. In another aspect, the invention provides a mixture of MPO, filler, and polymerization catalyst as a one-part, ready-to-polymerize material with a long shelf life. The one-part material can be used, for example, in the manufacture of parts without modification of existing processing equipment.

Abstract: A method for making a golf ball including the steps of providing a core; providing a nanoparticulate; providing a first monomer including an olefin; providing a second monomer including an ?,?-ethylenically unsaturated carboxylic acid; in-situ polymerizing the first monomer and the second monomer in the presence of the nanoparticulate to form a nanocomposite non-ionic polymer; and forming a cover layer about the core from the nanocomposite non-ionic polymer.

Abstract: A curable fluoropolyether composition comprising (A) a fluoropolyether compound containing alkenyl radicals and having a fluorine content of at least 40% by weight, (B) a curing agent in the form of a fluorinated organosilicon compound which is fully soluble in the fluoropolyether compound, and (C) a hydrosilylation catalyst, is curable at room temperature or under heat, has a low viscosity and transparency, and exhibits improved water repellence, oil repellence, solvent resistance, chemical resistance and weather resistance.

Abstract: A method for preparing exfoliated clay nanocomposites by in-situ polymerization comprising the steps of (a) providing a mixture of at least one type of monomer and at least one type of organophilic clay; and (b) initiating an in-situ polymerization reaction in the mixture so as to cause the at least one type of monomer to polymerize thereby forming the exfoliated clay nanocomposite. The exfoliated clay nanocomposite produces an x-ray diffraction pattern that is substantially devoid of an intercalation peak. The exfoliated clay nanocomposite may then be used as a masterbatch.

Abstract: The present invention provides a catalyst for polyester production capable of producing a polyester with high catalytic activity, a process for producing a polyester using the catalyst and a polyester produced thereby. The catalyst comprises a solid titanium compound obtained by dehydro-drying a hydrolyzate obtained by hydrolysis of a titanium halide and which has a molar ratio (OH/Ti) of a hydroxyl group (OH) to titanium (Ti) exceeding 0.09 and less than 4. In the process, the polyester is obtained by polycondensing an aromatic dicarboxylic acid, or an ester-forming derivative thereof, and an aliphatic diol, or ester-forming derivative thereof, in the presence of the catalyst. The resulting polyester has excellent transparency and tint, a titanium content of 1 to 100 ppm, a magnesium content of 1 to 200 ppm and a magnesium to titanium weight ratio of not less than 0.01.