Abstract: A method for producing a nitrile group-containing copolymer rubber including copolymerizing a monomer mixture containing an ?,?-ethylenically unsaturated nitrile monomer and a conjugated diene monomer, in which the copolymer has a Mooney viscosity (ML1+4, 100° C.) in a range of 30 to 60 at a time point when a polymerization conversion rate is 60%, the copolymerization is carried out until the polymerization conversion rate reaches 85% or more, and the obtained nitrile group-containing copolymer rubber has a Mooney viscosity (ML1+4, 100° C.) of 85 to 150.

Abstract: The invention relates to aqueous polymer dispersions, comprising a water insoluble polymer P in the form of dispersed polymer particles, which is obtainable by free radical aqueous emulsion polymerization of ethylenically unsaturated monomers M, which comprise a) at least one monomer M1 which exhibits two ethylenically unsaturated moieties which are connected by a linker which comprises a disulfide moiety, and b) at least one monoethylenically unsaturated monomer M2, which has a low water solubility. The invention also relates to processes for preparing such an aqueous polymer dispersion, to solid polymer compositions in powder form, obtainable by drying such polymer dispersions, to the use of such polymer dispersions in a coating material, adhesive or sealant and to a methods of coating a surface of a substrate which comprises applying an aqueous coating composition, which contains such an polymer dispersion.

Abstract: Provided is a water repellent composition which does not use a fluorine-containing monomer, especially a fluoroalkyl group-containing monomer. A water repellent composition which contains (1) (a) a polymer which has a repeating unit derived from an amide group-containing monomer that is represented by formula: (wherein R1 represents an organic residue having an ethylenically unsaturated polymerizable group; R2 represents a hydrocarbon group having 7-30 carbon atoms; and R3 represents a hydrocarbon group having 1-5 carbon atoms) in an amount of 2-100% by weight relative to the polymer, and (2) a liquid medium.

Abstract: The present invention provides an aqueous emulsion excellent in heat resistance, water resistance (particularly, hot water resistance and boiling resistance), and viscosity stability. The present invention also provides an adhesive containing the aqueous emulsion, forming an adhesive layer resistant to staining, and ensuring a high level of safety. The present invention relates to an aqueous emulsion containing an ethylenically unsaturated monomer unit-containing polymer (A) as a dispersoid and vinyl alcohol polymer (B) as a dispersant, wherein, the ethylenically unsaturated monomer unit-containing polymer (A) includes a structural unit derived from a radical-polymerizable ethylenically unsaturated monomer (a) having a functional group represented by the following general formula (W), and the degree of saponification of the vinyl alcohol polymer (B) is 80 mol % or more: wherein, X is an oxygen atom or sulfur atom, and * represents a bond.

Abstract: Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C 1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a)+(b)+(c)+(d)+(e)+(f) being 100% by weight, in a first emulsion po

Abstract: A hydrophobic binder/adhesive, for treating a substrate, may include about 60% to 98.9% by weight bulk polymer selected from one or more monomers associated with styrene, vinyl acetate, acrylic acid ester, methacrylic acid esters, ethylene, or butadiene; about 0.1% to about 10.0%, by weight of one or more hydrophobic monomers selected from stearyl methacrylate or laurel acrylate; and about 1% to about 30%, by weight of one or more protective colloids associated with a hard resin polymer. The hydrophobic binder/adhesive may increase resistance to wetting of the substrate when expose to moisture, and increases durability of the substrate.

Abstract: The current invention utilizes an extrusion coating method as a key step in a series of multilayer construction processes to make a laminate for graphic application. The extrusion coated layer performs as a strengthening layer to provide mechanical properties for the construction, while an ink receptive coating layer delivers high quality printability performance. High gloss can be achieved through the use of a PET carrier.

Abstract: The present invention is a process for preparing a multistage polymer by contacting under emulsion polymerization conditions an acrylic monomer, a sulfur acid monomer, and a phosphorous acid monomer as described herein. The present invention is also a composition comprising a nonionic surfactant and a stable aqueous dispersion of polymer particles comprising structural units of butyl acrylate, methyl methacrylate, a sodium vinylbenzenesulfonate, and phosphoethyl methacrylate; wherein the polymer particles have a Tg of less than 10° C. The composition of the present invention is useful as a binder for coatings compositions.

Abstract: Stable, coating compositions are disclosed. The compositions comprise an aqueous solution of cationic polymer, starch, and a stabilizing agent. Method of using the coating composition to improve the dry strength of paper is also disclosed.

Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion by free-radical emulsion polymerization of a monomer mixture which comprises N,N-diethylaminoethyl methacrylate, to the polymer dispersion obtainable by this process, and to the use thereof.

Abstract: A novel process for producing a polyamidoamine-epihalohydrin resin composition comprises (a) reacting a polyamidoamine with epihalohydrin to obtain a reaction mixture comprising a polyamidoamine-epihalohydrin resin; (b) adding a first acid to the reaction mixture obtained in step (a) to obtain an acid treatment composition; (c) adding a base to the acid treatment composition in step (b) to obtain a base treatment composition; and (d) adding a second acid to the base treatment composition in step (c) to obtain a polyamidoamine-epihalohydrin resin composition; wherein the polyamidoamine-epihalohydrin resin composition obtained in step (d) has less than about 700 ppm of dihalopropanol (DHP) and 3-halopropanediol (HPD).

Abstract: Stable, coating compositions useful for enhancing the dry strength of paper are disclosed. The compositions comprise an aqueous solution of nearly neutral polymer, cationic polymer and starch. Method of using the coating composition to improve the dry strength of paper is also disclosed.

Abstract: A process for the preparation of monodisperse polymer particles which are formed by contacting monomers with aqueous dispersions comprising monodisperse swellable seed polymers/oligomers, and initiating polymerization in the presence of a steric stabilizer. The resulting swollen seed particles are characterized by the particle mode diameter.

Abstract: A copolymer defines interconnected pores and comprises polymerized monomers. The monomers comprise a first monomer more hydrophilic than 2-hydroxyethyl methacrylate (HEMA), and a second monomer as hydrophilic as, or less hydrophilic than, HEMA. In a method of forming a polymer, a bicontinuous microemulsion comprising water, a surfactant, and a combination of monomers copolymerizable for forming a porous copolymer is provided. The combination of monomers comprises the first and second monomers. The monomers in the bicontinuous microemulsion are polymerized to form the porous copolymer. The first monomer may comprise N-vinylpyrrolidone (NVP) or methacrylic acid (MAA). The second monomer may comprise HEMA or methyl methacrylate (MMA).

Abstract: Acid-labile poly(N-vinyl formamide) (“PNVF”) nanocapsules were synthesized by free radical polymerization of N-vinyl formamide with optional active ingredients on the surface of silica nanoparticles. Polymerization in the presence of a novel cross-linker that contains an acid-labile ketal facilitated stable etching of silica nanoparticle templates using sodium hydroxide and recovery of PNVF nanocapsules. The formamido side group of PNVF was then hydrolyzed by extended exposure to sodium hydroxide to produce polyvinylamine (“PVAm”) nanocapsules. PNVF and PVAm nanoparticles are also synthesized that form nanogels with optional active ingredients.

Abstract: The present invention relates to a process for the preparation of hydrothermal hybrid material, in particular coal-like hybrid material from biomass. The process involves the heating of a reaction mixture comprising water, biomass and a copolymerizable compound, wherein the copolymerizable compound is added when preparing the reaction mixture, in a variant of the process, the biomass is converted to activated biomass in a first step, and the copolymerization of the activated biomass and a copolymerizable compound to give the hydrothermal, preferably coal-like, hybrid material is started by adding a polymerization initiator. The invention also relates to the hydrothermal hybrid materials obtainable by the processes as such, e.g. to aqueous dispersions thereof. By incorporating copolymerizable compounds, e.g. petrochemical compounds in the structure of the hydrothermal hybrid materials, the physical properties of the materials and the preparation process thereof can be controlled.

Abstract: The present invention is directed to a fatty amide (meth)acrylate monomer, methods of making the monomer, and latex polymers comprising the fatty amide (meth)acrylate monomer. The monomers are derived by reacting unsaturated vegetable oils with ethanolamine or substituted ethanolamine. The vegetable oil derivative is then reacted with either (meth)acryloyl chloride or (meth)acrylic acid to form a fatty amide (meth)acrylate monomer or the product of the reaction of hydroxyethyl (meth)acrylate reacted with isophorone diisocyanate to form a urethane fatty amide (meth)acrylate monomer. The increased hydrophilicity of the fatty amide (meth)acrylate monomer facilitates the diffusion through the aqueous phase. The monomer synthesis is designed to be glycerol ester-free to increase long term stability for monomers and polymers.

Abstract: The present invention provides a process for producing an N-vinylamide polymer in an efficient manner by an aqueous solution polymerization method in which a gel-like polymer having an excellent handling property can be produced, and a polymerization time can be shortened. The process for producing an N-vinylamide polymer by subjecting a monomer component comprising N-vinylamide to aqueous solution polymerization according to the present invention comprises the step of polymerizing the monomer component comprising N-vinylamide in the presence of an inorganic salt, which inorganic salt is present in an amount of not less than 7% by mass based on water in a uniform aqueous solution comprising the monomer component at a concentration not more than a saturated solution concentration thereof as measured at a polymerization initiation temperature.

Abstract: A process for the preparation of monodisperse polymer particles which are formed by contacting monomers with aqueous dispersions comprising monodisperse swellable seed polymers/oligomers, and initiating polymerization in the presence of a steric stabilizer. The resulting swollen seed particles are characterized by the particle mode diameter.

Abstract: The invention relates to a process for preparing an aqueous polymer dispersion comprising reacting, in the presence of a polymeric cationic co-stabilizer (A), one or more monomers (m), and a polymer (B) of a monomer mixture comprising at least one monomer (x) having a primary, secondary or tertiary amine or amide group and at least one olefinic unsaturation, and, at least one cationic monomer (y) having at least one olefinic unsaturation. The invention also relates to a polymer dispersion, a process for preparing a polymeric stabilizer (C), a polymeric stabilizer (C) and a process for producing paper.

Abstract: An ink composition includes: (Component a) a polymerizable compound having an ethylenically unsaturated double bond; (Component b) a polymerization initiator; (Component c) water; and (Component d) a polyhydric alcohol having an alkyleneoxy chain, wherein the (Component a) polymerizable compound includes a monofunctional polymerizable monomer having a (meth)acrylamide structure, and a content of the monofunctional polymerizable monomer is 5% by mass or more with respect to a total content of the (Component a) polymerizable compound.

Abstract: “The invention provides an ink composition including a polymerizable compound represented by following Formula (1), a polymerization initiator and water: X?A)n ??Formula (1) wherein, in Formula (1), X represents a divalent or trivalent nitrogen-containing linking group represented by any one of following Formulae (X1) to (X3), A represents a polymerizable functional group having an amide group, and n represents 2 or 3: wherein, in Formulae (X1) to (X3), Z represents an alkylene group having 2 or 3 carbon atoms, or a divalent linking group including an alkylene group having 2 or 3 carbon atoms and an oxygen atom; and R1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.

Abstract: Acid-labile poly(N-vinyl formamide) (“PNVF”) nanocapsules were synthesized by free radical polymerization of N-vinyl formamide with optional active ingredients on the surface of silica nanoparticles. Polymerization in the presence of a novel cross-linker that contains an acid-labile ketal facilitated stable etching of silica nanoparticle templates using sodium hydroxide and recovery of PNVF nanocapsules. The formamido side group of PNVF was then hydrolyzed by extended exposure to sodium hydroxide to produce polyvinylamine (“PVAm”) nanocapsules. PNVF and PVAm nanoparticles are also synthesized that form nanogels with optional active ingredients.

Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.

Abstract: The present invention relates to a process for the preparation of hydrothermal hybrid material, in particular coal-like hybrid material from biomass. The process involves the heating of a reaction mixture comprising water, biomass and a copolymerizable compound, wherein the copolymerizable compound is added when preparing the reaction mixture, in a variant of the process, the biomass is converted to activated biomass in a first step, and the copolymerization of the activated biomass and a copolymerizable compound to give the hydrothermal, preferably coal-like, hybrid material is started by adding a polymerization initiator. The invention also relates to the hydrothermal hybrid materials obtainable by the processes as such, e.g. to aqueous dispersions thereof. By incorporating copolymerizable compounds, e.g. petrochemical compounds in the structure of the hydrothermal hybrid materials, the physical properties of the materials and the preparation process thereof can be controlled.

Abstract: The present invention is a thickener consisting of a microgel obtained by radical polymerization of water soluble ethylene-type unsaturated monomers dissolved in the dispersion phase in a composition having an organic solvent or an oil component as the dispersion medium and water as the dispersion phase, as well as a cosmetic containing said thickener.

Abstract: A water soluble ROMP catalyst, which has high catalytic efficiency for ring opening metathesis is use in the preparation of polymeric blends for use in monolithic columns. In one embodiments a method for making a polymeric blend is discolosed comprising reaction of a water-soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor, and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support. In another embodiment a monolithic bed is disclosed comprising the water-soluble ROMP catalyst immobilized on a surface of a solid support. Also disclosed is a monolithic bed comprising: a polymer blend, the polymer blend produced from contacting a water soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor; and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support.

Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.

Abstract: This invention relates to dispersions and powders of micro gel particles, and more specifically, at least in some instances, dispersions of micro gel particles formed from crosslinked water-soluble or swellable polymers, and methods of preparing such micro gel particle dispersions. In one aspect, the invention provides a method of preparing synthetic micro gel particles, comprising forming a reaction mixture by dissolving or swelling a water-soluble or water-swellable unsaturated monomer, unsaturated crosslinking agent, and radical initiator in a common solvent that is substantially inert toward chain transfer reactions, wherein the monomer and the crosslinking agent polymerize to form crosslinked polymer micro gel particles that are insoluble or at most swellable in the common solvent.

Abstract: A weather resistant, easily removable paint composition for application over a surface or over another paint. The removable paint composition comprises from about 19 to about 34% by weight of a combination of two different acrylic polymers, from about 0.2 to 4% by weight of an aliphatic water-borne urethane polymer, from 0.06% to 0.6% by weight of an alkali, and water. The removable paint composition can be removed without damaging the underlying surface or paint.

Abstract: A process for the preparation of monodisperse polymer particles which are formed by contacting monomers with aqueous dispersions comprising monodisperse swellable seed polymers/oligomers, and initiating polymerization in the presence of a steric stabilizer. The resulting swollen seed particles are characterized by the particle mode diameter.

Abstract: The present invention pertains to a process for the preparation of aqueous dispersions which are stabilised with a water-insoluble stabilising colloid, characterised in that a) in a first step a water-insoluble stabilising colloid is prepared, with this being prepared, based on the amount of monomer used for the preparation of the stabilising colloid, by means of radical polymerization of a1) about 1 to 90 wt. % of at least one olefinically unsaturated monomer, containing at least one sulfate and/or sulfonate group, which optionally may be protonated, a2) about 5 to 99 wt. % of at least one olefinically unsaturated monomer with a water solubility at 20° C. of less than 50 g/l, and a3) up to 50 wt. % of at least one olefinically unsaturated monomer with a water solubility at 20° C.

Abstract: A precision fragmentation assemblage is disclosed, along with precision fragmentation assemblage catalysts derivable therefrom. A method for the preparation of a precision fragmentation assemblage is also disclosed, along with a method for preparing precision fragmentation assemblage catalysts from precision fragmentation assemblages. A method is further disclosed for using precision fragmentation catalysts in the polymerization of olefins to produce polyolefins.

Abstract: Polymer capsules from amphiphilic graft copolymers comprising reactive, hydrophobic polyolefin backbones, and hydrophilic poly(ethylene glycol) (PEG) grafts are produced by self-assembly of the polymers at the oil-water interface, and crosslinking the assembly with bis-cyclooctene PEG derivatives in conjunction with ring-open metathesis polymerization catalysts. The use of the graft copolymer architecture in capsule synthesis provides significant opportunities to tune both the surface properties, in terms of recognition, and the membrane properties, in terms of mechanical strength, encapsulation, and release.

Abstract: An aqueous copolymer composition containing copolymer particles containing polymerized units of (meth)acrylonitrile, (meth)acrylamide, or combinations thereof; and at least one unsaturated fatty acid ester is provided. A method is provided for preparing a coating from the aqueous copolymer composition. The aqueous copolymer composition is useful for preparing crosslinked coatings, suitable in coating applications such as architectural or maintenance paints.

Abstract: An energy curable aqueous composition is disclosed containing: water; an ethylenically unsaturated oligomer; and a resin not containing energy curable functional groups.

Abstract: An aqueous dispersion of a polymer, obtainable by emulsion polymerization of compounds (monomers) having unsaturated radicals in the presence of at least two different polymerization regulators A) and B), wherein A) is a compound selected from ?-methylstyrene dimer and hydrocarbons which form a pentadienyl or 1-phenylallyl radical on abstraction of a hydrogen atom and B) is a compound having a mercapto group, the amount of B) being more than 2 parts by weight per 100 parts by weight of monomers.

Abstract: A water-based ink for ink jetting and ink jet recording method, in which stable jetting, clearness of the recorded matter, high density recording, water resistance, and friction resistance are well-balanced, and being useful for ink for various types of ink jet recording. After 5% of the water soluble colored resin comprising 5,5?-dimethylhydantoinformaldehyde resin and color index number basic red 1:1 and 10% of polyethyleneglycol (average molecular weight 200) and 6% of triethyleneglycolmonometylether and 79% of pure water are fully stirred to be mixed, the mixture is filtered with a membrane filter of 0.8 ?m thickness to become ink. Experimental evaluation using the recording head regarding jetting stability, jetting response, quality of the recorded images, friction resistance against various recording materials, and water resistance against various recording materials is made, and good results are obtained.

Abstract: A process for the preparation of monodisperse polymer particles which are formed by contacting monomers with aqueous dispersions comprising monodisperse swellable seed polymers/oligomers, and initiating polymerization in the presence of a steric stabilizer. The resulting swollen seed particles are characterized by the particle mode diameter.

Abstract: Reactive polymeric surfactants are disclosed, and their use in processes for preparation of microcapsules, and in stabilising emulsions. The surfactants are random graft polymers or block copolymers which contain both hydrophobic and hydrophilic units and in which the hydrophobic unit includes a hydrophilic cross-linking unit which reacts with (a) a wall forming ingredient in a microencapsulation process, or (b) an ingredient in the disperse phase of an emulsion.

Abstract: This invention relates to aqueous emulsions comprising a water-dispersible copolymer which is non-dispersible in aqueous solutions containing 0.5% or more of an inorganic salt, comprising acidic ethylenically unsaturated monomers and ethylenically unsaturated monomers. The acidic ethylenically unsaturated monomers and the ethylenically unsaturated monomers are defined herein. The present invention also pertains to emulsion polymerization methods for making the aqueous emulsions with or without a surfactant.

Abstract: A coating mix for the production of coated paper and board is described in form of an aqueous dispersion with a solids content of 50 to 80% consisting of pigments, binders, and additives. The coating mix exhibits thixotropic flow characteristics and is characterized by the usage of special amine-group or amide-group containing polymers, which act as protective colloids for the pigment particles. The coating mix contains preferably between 0.1 to 1 weight percent of a grafted gelatin.

Abstract: A process for treating a composition containing a polyamine-epihalohydrin resin that has a low level of CPD-producing species and good gelation stability is disclosed. A polyamine-epihalohydrin resin is prepared with a ratio of epihalohydrin:amine of less than about 1.1:1.0; The resin is then subjected to a base treatment followed by an acid treatment resulting in a resin that has good gelation storage stability and produces low levels of CPD.

Abstract: To provide an aqueous emulsion composition which has high adhesion strength for a wide variety of materials including molded products and affords sufficient wettability even for the object to be adhesive bonded of low surface polarity so that it can develop sufficient adhesiveness and whose emulsion is stable so satisfactorily as to provide good mechanical stability and storage stability, and to provide an adherent composition comprising the aqueous emulsion composition, at least ethylene-vinyl acetate copolymer or modified resin thereof, photo polymerization initiator, and unsaturated ethylenic monomer are mixed and dissolved or dispersed, to prepare oil drop component, followed by emulsifying the oil drop component in water by using a surface-active agent, whereby an aqueous emulsion composition, in which micelles each encapsulating at least the ethylene-vinyl acetate copolymer or modified resin thereof, the photo polymerization initiator and unsaturated ethylenic monomer are dispersed in water, is prepared

Abstract: The present invention provides a compound having anionic functional groups that is useful as a pigment dispersant in waterborne coating compositions, particularly in anodic electrocoat compositions. The compound comprises an acrylic backbone having a stabilizing substituent and a plurality of anionic groups. The anionic groups result from the incorporation of a plurality of acid groups into the acrylic backbone followed by reaction with organic amine.

Abstract: The present invention relates to a novel process for the production of a water soluble polymer dispersion from vinylamide monomers, and, more particularly, polymers formed from N-vinylformamide monomers.

Abstract: A cationically stabilizable amino-functional polymer having a number-average molecular weight of >3000, exists in the presence of water as a solution or stable emulsion only when the pH is ?8. Upon drying the polymer contains ethenically unsaturated moieties selected from the group consisting of acrylic, methacrylic, and enamine. The polymer is useful to promote adhesion of curable inks and other coatings for plastic film. The invention further relates to a plastic film comprising such polymer.

Abstract: This invention relates to a process for making polymer-dye particles comprising, in order: I) forming a colorant mixture comprising a water insoluble dye and an organic medium containing at least one ethylenically-unsaturated monomer; II) combining the colorant mixture with an aqueous mixture comprising a surfactant and a co-stabilizer to form a colorant mixture/aqueous mixture; III) causing the colorant mixture/aqueous mixture to form a stable aqueous droplet mixture via strong agitation; and IV) initiating polymerization to form composite polymer-dye particles comprising a colorant phase and a polymer phase; wherein an addition polymerization initiator is added prior to initiating polymerization. It further relates to composite polymer dye particles prepared by the above process and to composite polymer dye particles comprising a colorant phase containing a water insoluble dye, and a polymer phase, said particles being associated with a co-stabilizer.

Abstract: The present invention provides a process for preparing aqueous copolymer solutions by polymerizing ethylenically unsaturated compounds in the presence of foam inhibitors.

Abstract: The invention relates to a method for preparing butadiene-based aqueous dispersions in the presence of at least one azocarboxylic acid ester.