Quaternary Nitrogen-containing Monomer, E.g., Tetramethyl Ammonium, Etc. Patents (Class 524/815)
  • Patent number: 8680038
    Abstract: The present invention provides a new copolymer comprising zwitterionic units and other units, a new composition comprising the copolymer, and the use of the copolymer or the compositions for treating or modifying surfaces.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: March 25, 2014
    Assignee: Rhodia Operations
    Inventors: Marc Balastre, Regan Crooks, Chi-Thanh Vuong
  • Patent number: 8299183
    Abstract: The invention relates to a process for preparing an aqueous polymer dispersion comprising reacting, in the presence of a polymeric cationic co-stabilizer (A), one or more monomers (m), and a polymer (B) of a monomer mixture comprising at least one monomer (x) having a primary, secondary or tertiary amine or amide group and at least one olefinic unsaturation, and, at least one cationic monomer (y) having at least one olefinic unsaturation. The invention also relates to a polymer dispersion, a process for preparing a polymeric stabilizer (C), a polymeric stabilizer (C) and a process for producing paper.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: October 30, 2012
    Assignees: Akzo Nobel N.V., Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung E.V.
    Inventors: Mathias Hahn, Werner Jaeger, André Laschewsky, Bernd Paulke, Christian Przybyla, Achim Sieger
  • Patent number: 8258235
    Abstract: Polymers comprising a polyethylenimine, a biodegradable group, and a relatively hydrophobic group are useful for the delivery of bioactive agents to cells.
    Type: Grant
    Filed: February 18, 2010
    Date of Patent: September 4, 2012
    Assignee: Nitto Denko Corporation
    Inventors: Gang Zhao, Xiaoli Fu, Lei Yu
  • Patent number: 8232236
    Abstract: The claims encompass hard surface cleaner and hard surface treatment compositions containing particular ampholytic polymers which impart not only good residual cleaning properties but in particular give fast drying properties to the cleaning compositions. The polymers are for example terpolymers formed from diallydialkyammonium chloride, anionic monomers and N,N di-C1-C8 alkyl(meth)acrylamides.
    Type: Grant
    Filed: March 18, 2010
    Date of Patent: July 31, 2012
    Assignee: BASF SE
    Inventors: Bingham S. Jaynes, Ashish Taneja, Xian-Zhi Zhou, Joseph A. Lupia
  • Patent number: 7973095
    Abstract: The invention relates to a process for the production of water-soluble or water-swellable polymers having a low content of residual monomers, particularly on the basis of acrylic acid and/or acrylamide and at least one additional water-soluble comonomer, in which process a monomer solution in a polymerizing state is treated with electromagnetic radiation at the earliest after reaching the maximum temperature of polymerization, and the gel obtained is subsequently crushed and dried, and it also relates to the water-soluble or water-swellable polymers as such, which can be obtained according to said process, to their use in the hygiene industry, packaging industry, in the agrarian technology or in agriculture and horticulture, in the cable industry and information technology, in the food industry, papermaking industry, and to their use as flocculation aids and as drilling fluid in petroleum production.
    Type: Grant
    Filed: January 16, 2006
    Date of Patent: July 5, 2011
    Assignee: Evonik Stockhausen GmbH
    Inventors: Gregor Herth, Manfred Dannehl, Norbert Steiner
  • Patent number: 7935757
    Abstract: A process is described for making an aqueous coating composition comprising a cationic vinyl oligomer comprising the following steps: I. preparation of a cationic vinyl oligomer by solution or bulk polymerization of components: i) 2 to 50 wt % of vinyl monomers bearing amine functional groups selected from the group consisting of non-ionic amine functional groups (a), permanent quaternary ammonium functional groups (b), neutralized amine functional groups (c) and mixtures thereof; and ii) 20 to 98 wt % of Ci to Ci8 alkyl (meth)acrylates; and II. dispersion of the cationic vinyl oligomer in an aqueous medium and neutralization of non-ionic amine functional groups.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: May 3, 2011
    Assignee: DSM IP Assets B.V.
    Inventors: Jurgen Scheerder, Emilio Martin, Gerardus Cornelis Overbeek
  • Patent number: 7915318
    Abstract: A water soluble ROMP catalyst, which has high catalytic efficiency for ring opening metathesis is use in the preparation of polymeric blends for use in monolithic columns. In one embodiments a method for making a polymeric blend is discolosed comprising reaction of a water-soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor, and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support. In another embodiment a monolithic bed is disclosed comprising the water-soluble ROMP catalyst immobilized on a surface of a solid support. Also disclosed is a monolithic bed comprising: a polymer blend, the polymer blend produced from contacting a water soluble ROMP catalyst with a norbornene-substituted cycloolefin polymer or a polynorbornene polymer precursor; and wherein the contacting occurs in an aqueous or polar solvent in the presence of a solid support.
    Type: Grant
    Filed: September 9, 2008
    Date of Patent: March 29, 2011
    Assignee: General Electric Company
    Inventors: Su Lu, Liangliang Qiang, Yanrong Zhu, Zhida Pan
  • Patent number: 7834085
    Abstract: A self-reversible invert latex having a crosslinked cationic polyelectrolyte, formed by the copolymerization of at least one cationic monomer with at least one neutral monomer and at least one nonionic surfactant monomer.
    Type: Grant
    Filed: March 2, 2010
    Date of Patent: November 16, 2010
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC
    Inventors: Olivier Braun, Paul Mallo, Herve Rolland
  • Patent number: 7618540
    Abstract: A flocculant for separating and flocculating oily components and water components is provided so that no sludge is produced when the oily components and the water components contained in the emulsion having a high COD value; and the throughput of the active sludge is not decreased in the secondary treatment of the active sludge. A flocculant for separating and flocculing oily components and water components contained in oil-in-water type or water-in-oil type emulsion, comprises a unit (i), and at least one of units (ii) and (iii) represented by the following formulas: (i) —(C(R1R2)C(R3X))—, (ii) —(C(R4R5)C(R6Y))—, (iii) —(C(R7R8)C(R9Z))—; wherein X is a group having —SO3M, M is hydrogen or a metal element, Y is a group having a quaternary nitrogen atom, Z is an electrophilic group, each R1 to R9 is hydrogen or an alkyl group, and a ratio per molecule of these units (i):(ii):(iii) is (1 to 100):(1 to 100):(1 to 100).
    Type: Grant
    Filed: December 15, 2008
    Date of Patent: November 17, 2009
    Assignee: Japan ALSI Co., Ltd
    Inventor: Kiyoharu Fujino
  • Patent number: 7591890
    Abstract: A photocurable pigment type inkjet ink composition including 5 to 95 wt % of water; 0.5 to 20 wt % of a pigment; 1 to 70 wt % of a photocurable component; and 0.0001 to 30 wt % of a reactive surfactant. The reactive surfactant can serve as a pigment dispersant for dispersing pigment particles or as an emulsifier for emulsifying the photocurable component.
    Type: Grant
    Filed: September 21, 2006
    Date of Patent: September 22, 2009
    Assignee: Industrial Technology Research Institute
    Inventors: Chi-Jung Chang, Shu-chen Tsou, Feng-Mei Wu, Shinn-Jen Chang
  • Patent number: 7528291
    Abstract: A color-stable superabsorbent polymer having long-term color stability, and methods of manufacturing the polymer, are disclosed. The color-stable superabsorbent polymer is prepared in the essential absence of a persulfate, and is subjected to a low dose of ultraviolet radiation. The resulting superabsorbent polymer resists color degradation during periods of extended storage, even at an elevated temperature and humidity.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: May 5, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Herfert, Michael M. Azad, Peter W. Carrico
  • Patent number: 7504551
    Abstract: A color-stable superabsorbent polymer having long-term color stability, and methods of manufacturing the polymer, are disclosed. The superabsorbent polymer is prepared using a sulfinic acid derivative, like 2-hydroxy-2-sulfinatoacetic acid, a salt thereof, or a mixture thereof, as the reducing agent in a polymerization initiator system for the preparation of a superabsorbent polymer from monomers. The resulting superabsorbent polymer resists color degradation during periods of extended storage, even at an elevated temperature and humidity.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: March 17, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Herfert, Michael M. Azad, Peter W. Carrico, Guy Thomas Woodrum, Michael A. Mitchell, Ma-Ikay Kikama Miatudila
  • Patent number: 7442723
    Abstract: This invention pertains to an inkjet ink comprising a polyazetidinium groups-containing component, various ink sets comprising this ink, including one ink set with at least one co-reactive ink, and a method of printing with the ink and ink sets. When the inks are printed onto a substrate, the polyazetidinium groups can chemically react to enhance the durability of the printed image.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: October 28, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Richard Douglas Bauer
  • Patent number: 7442746
    Abstract: The present invention is directed to a process for synthesizing an epoxidized polymer that includes the steps of: (1) preparing a cationically stabilized polymer latex containing at least one conjugated diolefin monomer in a first stage, (2) treating the polymer latex from step (1) with formic or acetic acid and hydrogen peroxide, and (3) allowing the mixture to react for a predetermined time and predetermined temperature to attain the desired level of epoxidation.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: October 28, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Dane Kenton Parker
  • Patent number: 7408004
    Abstract: The present invention relates to a water-soluble polymer dispersion comprising: a dispersed polymer made up of at least one water-soluble monomer A and at least one water-soluble cationic monomer B, at least one stabiliser C, and at least one cationic polyelectrolyte as co-stabiliser D. It also relates to a method of producing a polymer dispersion and to a paper-making process.
    Type: Grant
    Filed: May 15, 2003
    Date of Patent: August 5, 2008
    Assignee: Akzo Nobel N.V.
    Inventors: Oliver Struck, Christian Przybyla, Werner Jaeger, Mathias Hahn, Dirk Ruppelt
  • Patent number: 7396874
    Abstract: A papermaking method and a composition which utilize, as a drainage aid, a water-soluble cationic or amphoteric copolymer prepared via a water-in-oil polymerization technique that, absent a cross-linking agent, is characterized by a Huggins' constant (k?) determined in 0.01M NaCl greater than 0.3 and a storage modulus (G?) at 6.3 Hz greater than 50 Pa.
    Type: Grant
    Filed: December 4, 2003
    Date of Patent: July 8, 2008
    Assignee: Hercules Incorporated
    Inventors: Martha Hollomon, Brian L. Walchuk, Frank J. Sutman
  • Patent number: 7220339
    Abstract: The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen or C1-C2 alkyl, R3 is hydrogen, C1-C4 alkyl, phenyl, or benzyl, n=1 to 4, and x=1 to 50, and then, polymerising one or more water-soluble monomers (m) in an aqueous solution of a salt in the presence of the obtained dispersant polymer. The invention also relates to an aqueous polymer dispersion, use of the dispersion and a process for the production of paper.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: May 22, 2007
    Assignee: Akzo Nobel N.V.
    Inventors: Oliver Struck, Christian Przybyla, Achim Sieger, Mathias Hahn, Dirk Ruppelt, Werner Jaeger
  • Patent number: 7173085
    Abstract: This invention relates to aqueous emulsions comprising a water-dispersible copolymer which is non-dispersible in aqueous solutions containing 0.5% or more of an inorganic salt, comprising acidic ethylenically unsaturated monomers and ethylenically unsaturated monomers. The acidic ethylenically unsaturated monomers and the ethylenically unsaturated monomers are defined herein. The present invention also pertains to emulsion polymerization methods for making the aqueous emulsions with or without a surfactant.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: February 6, 2007
    Assignee: Celanese International Corporation
    Inventor: Michael W. Eknoian
  • Patent number: 7084205
    Abstract: Compositions comprising of blends of polymeric materials, including a cationic polymer having an intrinsic viscosity of from 8 to 17 dl/g and a cationic content of from 20 to 100% which may be used in the dewatering of thermophilic sludges.
    Type: Grant
    Filed: August 14, 2001
    Date of Patent: August 1, 2006
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Peter Ian Norman, Helen Elizabeth Read, Nils Berggren
  • Patent number: 7071260
    Abstract: The invention relates to rapid-curing aqueous coating agents, containing at least one binding agent and at least one water-soluble, quaternary poly(allylamine). Said agents have rapid curing properties and do not discolor during the curing process. Poly(diallyl dialkyl ammonium chlorides) are particularly suitable for use as the water-soluble quaternary poly(allylamine). The inventive coating agents are suitable for use as dyes, rendering agents, primers and wood paints for external applications.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: July 4, 2006
    Assignee: Clariant GmbH
    Inventors: Rolf Kuropka, Thomas Fichtner
  • Patent number: 7060201
    Abstract: Optical brighteners (PAB) of formula wherein each n independently signifies 1 or 2, the group SO3M shown with the floating bond is linked to the position 4 or 5, each M independently signifies an equivalent of a non-chromophoric cation, each M? independently signifies hydrogen or M, at least a part of the cations M of (PAB) are cationic groups of a polycationic polyol/epichlorohydrin/amine polymer (PA), which contains quaternary ammonium groups in salt form as heteroatomic ring members or chain members, any others being cations selected from alkali metal cations, unsubstituted ammonium and ammonium substituted with C1-3-alkyl or/and C2-3-hydroxyalkyl, the polycationic polymer (PA) is a polymer which is at least in part crosslinked over one or more of its quaternary ammonium groups, any other counterions to the cationic groups of (PA) being non-chromophoric anions of low molecular acids, and the ratio of the total anionic groups in the anionic optical brightener portion of (PAB) to the total of cationi
    Type: Grant
    Filed: October 18, 2002
    Date of Patent: June 13, 2006
    Assignee: Clariant Finance (BVI) Limited
    Inventor: John Martin Farrar
  • Patent number: 7015279
    Abstract: A composition and method for a linear or crosslinked cationic polyelectrolyte, involving copolymerization of at least one cationic monomer with at least one neutral monomer and at least one nonionic surfactant monomer.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: March 21, 2006
    Assignee: Société d'Exploitation de Produits pour les Industries Chimiques (SEPPIC)
    Inventors: Olivier Braun, Paul Mallo, Hervé Rolland
  • Patent number: 6900262
    Abstract: The present invention generally provides a method for producing an exfoliated nanocomposite. The method involves charging to water, as the continuous phase, monomers, polymerizable surfactant, and water-soluble initiator. The monomers are allowed to polymerize under agitation to form an emulsion of polymers, and the polymerizable surfactant is bound to the polymers so formed, with an ionic end of the polymerizable surfactant extending from the polymers to provide surface charges. Thereafter, a suspension of nanofillers in water is charged to the emulsion. The nanofillers are oppositely charged from the ionic end of the polymerizable surfactant such that they electrostatically bind to the polymers within the emulsion. The water is subsequently decanted to produce a nanocomposite with an exfoliated structure.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: May 31, 2005
    Assignee: The University of Akron
    Inventors: William J. Brittain, Xinyu Huang
  • Patent number: 6864314
    Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: March 8, 2005
    Inventors: Dominic Wai-Kwing Yeung, Vance Bergeron, Jean-Francois Bodet, Mark Robert Sivik, Bernard William Kluesener, William Michael Scheper
  • Patent number: 6841588
    Abstract: A radiation curable resin composition comprising a water soluble amine salt prepolymer formed between an oligomer or compound having at least one amine group and an unsaturated carboxylic acid and use of this composition as a surface coating or ink.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: January 11, 2005
    Inventors: Robert John Bolton, Kevin George Jarrett
  • Patent number: 6743514
    Abstract: This invention pertains to radiation-curable aqueous compositions comprising a mixture of water-reducible oligomer, monomer, and water-insoluble cationically-modified latex. More particularly, the invention pertains to radiation-curable aqueous compositions that are suitable for use as ink jet printing receptive coatings and in the production of ink jet printable products.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: June 1, 2004
    Assignee: MeadWestvaco Corporation
    Inventor: Gamini S. Samaranayake
  • Patent number: 6702946
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: March 9, 2004
    Assignee: Cytec Technology Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 6683129
    Abstract: This invention relates to aqueous emulsions comprising a water-dispersible copolymer which is non-dispersible in aqueous solutions containing 0.5% or more of an inorganic salt, comprising acidic ethylenically unsaturated monomers and ethylenically unsaturated monomers. The acidic ethylenically unsaturated monomers and the ethylenically unsaturated monomers are defined herein. The present invention also pertains to emulsion polymerization methods for making the aqueous emulsions with or without a surfactant.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: January 27, 2004
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Michael W. Eknoian
  • Patent number: 6670508
    Abstract: A compound of formula (I) is prepared alone or in combination with at least one monomer of formula (II): the quaternizing agents benzyl chloride is introduced into a solution, in a solvent selected from compounds of the formulae (I) and (II) and mixtures of these, of the compound of formula (III) at a temperature of from 35 to 60° C., and then water is added and the reaction is allowed to proceed to complete or substantially complete conversion of the compound (III), an aqueous solution of desired compound (I) is isolated where appropriate with at least one compound (II), if this or these have/has been used as solvent, and the water is removed where appropriate.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: December 30, 2003
    Assignee: Atofina
    Inventor: Alain Riondel
  • Publication number: 20030171489
    Abstract: The invention concerns a saline aqueous dispersion of a water soluble (co)polymer obtained from a composition of water soluble monomers, comprising for 100 mole parts, 2 to 100 mole parts of at least a compound of formula (I) wherein: R1=H or —CH3: R2=—CH3; —C2H5; —C3H7 or —C4H9; and compound (I) is optionally quaternized on one of the nitrogen atoms, which is symbolised by the fact that the associated R3 and X− and + are within square brackets; when compound (I) is quaternized on a single nitrogen, R3 and X− represent the following: (I) R3=CH2C6H5; and X=Cl− or CH3OSO−; or (2) R3=—(CH2)pCH; with p an integer from 3 to 11; and X− represents Br− or I−; when compound (I) is quaternized on both nitrogen atoms, both X− can he identical or different and the both R3's can he identical or different, in which case (3) R3=—CH2—C6H5; and X−=Cl−; or (4) R3&equa
    Type: Application
    Filed: November 20, 2002
    Publication date: September 11, 2003
    Inventors: Alain Riondel, Denis Tembou N'Zudie, Didier Vanhoye
  • Publication number: 20030153675
    Abstract: The invention concerns a salt-free aqueous dispersion of a water soluble dispersion obtained from a composition of monomers comprising, for 100 mole parts, 0.5 to 99.
    Type: Application
    Filed: November 20, 2002
    Publication date: August 14, 2003
    Inventors: Alain Riondel, Denis Tembou N'Zudie
  • Patent number: 6531561
    Abstract: Linear, branched or crosslinked polymer, capable of being obtained by polymerization of N-alkylacrylamide, in which the alkyl radical is linear or branched and comprises from 1 to 6 carbon atoms, with one or more monomers chosen from cationic monomers, monomers comprising at least one partially salified or completely salified strong acid functional group or monomers comprising at least one partially salified or completely salified weak acid functional group. A method of preparing the polymer is also disclosed.
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: March 11, 2003
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques Seppic
    Inventors: Francoise Candau, Joseph Selb, Paul Mallo, Olivier Braun
  • Publication number: 20030022987
    Abstract: Novel water soluble polymers in solution or water-in-oil emulsion form are disclosed containing quaternary ammonium monomers; and optionally (meth)acrylic acid or 2-(meth)acrylamido-2-methylpropane sulfonic acid; methylene bis-acryamide and the like; and a C1-C3 alkyl (meth)acrylate acrylamide or methacrylamide and the use thereof in hair, skin and nail conditioning; papermaking; and subterranean well drilling and well cementing operations.
    Type: Application
    Filed: September 13, 2002
    Publication date: January 30, 2003
    Inventors: Gary F. Matz, Randy J. Loeffler, Shih-Ruey T. Chen, Allan L. Melby, Nicholas F. Vozza
  • Patent number: 6489395
    Abstract: Emulsions are claimed which comprise oligoesters as emulsifiers. These oligoesters have hitherto only been used as soil release polymers.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: December 3, 2002
    Assignee: Clariant GmbH
    Inventor: Matthias Löffler
  • Publication number: 20020161108
    Abstract: Disclosed is an improved method of making polymers. The method utilizes at least one ethylenically unsaturated monomer and at least one polymerizable surface active agent. The polymerizable surface active agent is capable of co-polymerization with traditional monomers and/or polymerization with itself (i.e. homopolymerization) and is preferably substantially completely consumed during the course of the polymerization. Polymers produced by the method of the present invention are well suited for use in coatings, adhesives, sealants, elastomers and the like, as they form stable films, possess excellent adhesion properties and have improved hydrolytic stability characteristics. The present invention also encompasses homopolymeric surface active agents and their use in polymerization reactions.
    Type: Application
    Filed: April 8, 2002
    Publication date: October 31, 2002
    Applicant: STEPAN COMPANY, A corporation of the State of Delaware
    Inventors: Alfred K. Schultz, Adnan Siddiqui
  • Publication number: 20020132919
    Abstract: A cationic polymer latex comprises at least one ethylenically unsaturated monomer, an ethylenically unsaturated cationic monomer, and a component which is incorporated into the cationic polymer latex to provide steric stabilization to the cationic polymer latex.
    Type: Application
    Filed: March 18, 2002
    Publication date: September 19, 2002
    Inventor: Venkataram Krishnan
  • Patent number: 6444723
    Abstract: A crosslinked micellar gel composition is comprised of a polymer formed by a reaction between (a) ionic surfactant units which include ionic surfactant molecules, each of which includes a counterion which has a first polymerizable functional group, (b) crosslinking agent molecules, each of which includes two second polymerizable functional groups, and (c) a reaction initiator selected from the group consisting of reaction initiator molecules and ultraviolet light radiation, wherein the reaction initiator initiates a reaction between a plurality of the ionic surfactant units with each other and a plurality of the ionic surfactant units with the second polymerizable functional groups. The polymer compositions formed from the reactions are crosslinked micellar gels which include a network structure of rodlike micelles forming a soft gel material which retains features and utility of rodlike micelles and benefits from the structural stability of a crosslinked polymer matrix.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: September 3, 2002
    Assignee: The United States of America as represented by the Secretary of Commerce
    Inventor: Steven R. Kline
  • Patent number: 6437019
    Abstract: The present invention provides a multiple part ionomeric cement system comprising an organic composition that is substantially free of added water, and an aqueous composition comprising water. The organic composition contains at least a hydrophilic component and an acid functional compound that is provided as greater than 1.0% weight of the organic composition. The liquid ingredients of the compositions are miscible, both as separate compositions and when mixed together.
    Type: Grant
    Filed: May 16, 2000
    Date of Patent: August 20, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Richard P. Rusin, Joel D. Oxman, Edward J. Winters
  • Patent number: 6433075
    Abstract: A composition, in particular a wellbore service fluid, comprising monomeric surfactants, preferably viscoelastic surfactants, in combination with a polymerization agent. Additionally, the fluid may contain a cross-linking agent to cross-link the polymerized surfactants.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: August 13, 2002
    Assignee: Schlumberger Technology Corporation
    Inventors: Stephen N. Davies, Timothy G. J. Jones, Gary J. Tustin
  • Patent number: 6426382
    Abstract: Aqueous solutions of polycationic polymers (PAB) containing quaternary ammonium groups in salt form as heteroatomic chain members or ring members of the polymer, wherein a part of the counter-ions to the quaternary cationic groups are anionic groups of anionic optical brighteners, containing at least one anionic group, are valuable multi-functional agents in papermaking.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: July 30, 2002
    Assignee: Clariant Finance (BVI) Limited
    Inventors: John Farrar, Mark Graham, Andrew Jackson
  • Patent number: 6407162
    Abstract: Disclosed is an improved method of making polymers. The method utilizes at least one ethylenically unsaturated monomer and at least one polymerizable surface active agent. The polymerizable surface active agent is capable of co-polymerization with traditional monomers and/or polymerization with itself (i.e. homopolymerization) and is preferably substantially completely consumed during the course of the polymerization. Polymers produced by the method of the present invention are well suited for use in coatings, adhesives, sealants, elastomers and the like, as they form stable films, possess excellent adhesion properties and have improved hydrolytic stability characteristics. The present invention also encompasses homopolymeric surface active agents and their use in polymerization reactions.
    Type: Grant
    Filed: March 9, 2000
    Date of Patent: June 18, 2002
    Assignee: Stepan Company
    Inventors: Alfred K. Schultz, Adnan Siddiqui
  • Patent number: 6365667
    Abstract: Synthetic polymers having hydrogen bonding capability and one or more aliphatic hydrocarbon moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: April 2, 2002
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Thomas Gerard Shannon, Daniel Arthur Clarahan, Mike Thomas Goulet, Wen Zyo Schroeder
  • Publication number: 20020035198
    Abstract: A water-soluble cationic (co)polymer is obtained from a monomer composition comprising, per 100 parts by moles, from 0 to 95 parts of at least one water-soluble monomer of formula (I); 0.20 to 100 parts of at least one cationic water-soluble monomer of formulae (II) or (III); 0 to 60 parts of at least one water-soluble monomer which is potentially anionic by varying the pH; 0 to 90 parts of at least one cationic water-soluble monomer containing only one quaternary amino, of formula (IV); 0 to 10 parts of at least one hydrophobic monomer; 0 to 30 parts by moles of at least one other water-soluble monomer formulae I-IV are defined herein.
    Type: Application
    Filed: August 7, 2001
    Publication date: March 21, 2002
    Applicant: ATOFINA
    Inventors: Denis Tembou N'Zudie, Yvon Legrand
  • Publication number: 20010047054
    Abstract: The present invention provides a liquid water-swellable coating compound, which is substantially devoid of volatile non-reactives. The water-swellable coating compound can be applied, to an article and cross-linked in place on the article to create a water-swellable, super absorbent polymer coating. The super absorbent polymer coating of the present invention is a flexible water-absorbent coating and comprises a cross-linked polymer prepared by polymerizing a reactive mixture, which comprises: substantially between thirty-five weight percent (35%) and ninety-nine and nine-tenths weight percent (99.9%) of one or more amine neutralized monomer; substantially between one tenth of one weight percent (0.1%) and fifteen weight percent (15%) cross-linking monomer; substantially between zero weight percent (0%) and fifty weight percent (50%) water soluble, substantially monofunctional oligomer; and substantially between one-half of one weight percent (0.
    Type: Application
    Filed: June 20, 2001
    Publication date: November 29, 2001
    Inventors: Richard F. Zopf, Brian D. Thiffault
  • Patent number: 6274667
    Abstract: Synthetic polymers having hydrogen bonding capability and one or more aliphatic hydrocarbon moieties are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: August 14, 2001
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Thomas Gerard Shannon, Daniel Arthur Clarahan, Mike Thomas Goulet, Wen Zyo Schroeder
  • Patent number: 6262141
    Abstract: Methods of preparing an acrylic polymer according to the present invention comprise the steps of: forming a gelled polymer by polymerizing a mixture containing an acrylic monomer and a photoinitiator; comminuting the gelled polymer to produce gel particles; and irradiating the gel particles with light to decompose the photoinitiator, simultaneously with, or after, the step of comminuting. The gel particles may be irradiated with UV light while they are being dried in a fluid-bed dryer.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: July 17, 2001
    Assignee: Cytec Technology Corporation
    Inventors: Douglas A. Cywar, Roderick G. Ryles, Melvyn Holdsworth
  • Patent number: 6235205
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: November 2, 1998
    Date of Patent: May 22, 2001
    Assignee: Cytec Technology Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 6225395
    Abstract: Water-in-water dispersions based on water-soluble polymers can be prepared using a polymer dispersant containing hydrophobic units. The dispersions of the invention are stable on storage and are of low viscosity.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: May 1, 2001
    Assignee: Elf Atochem, S.A.
    Inventors: Denis Tembou Nzudie, Christian Collette
  • Patent number: 6221957
    Abstract: The invention relates to aqueous saline dispersions containing a water-soluble polymer and a dispersant based on a polymer, preferably a cationic polymer, containing hydrophobic units.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: April 24, 2001
    Assignee: Elf Atochem S.A.
    Inventors: Denis Tembou Nzudie, Christian Collette
  • Patent number: RE39993
    Abstract: Emulsions are claimed which comprise oligoesters as emulsifiers. These oligoesters have hitherto only been used as soil release polymers.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: January 1, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventor: Matthias Loeffler