Si-containing Reactant Forming A Solid Polymer Or Sicp In The Presence Of A Nonreactant Material Patents (Class 524/858)
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Patent number: 5332779Abstract: This invention provides polymerizable silica sols in which at least one monomer containing double bond is used as its dispersion medium, especially a silica sol in which the monomer containing double bond is a monomer containing double bond and OH group or is a monomer having an adamantane structure. This invention also provides compositions which comprise these silica sols as composing elements, cured resins that are obtained by polymerizing these silica sols alone or together with other copolymerizable components, and new adamantane derivatives for use in these silica sols.Type: GrantFiled: May 31, 1991Date of Patent: July 26, 1994Assignee: Kawasaki Steel CorporationInventors: Taizo Mohri, Katsuhiko Takagi, Yoshihiro Naruse, Yukio Asami
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Patent number: 5326557Abstract: Moisturizing compositions for a human skin which contain oxyethylene function organosilanes. When used in skin care applications, these compounds exhibit humectant properties. The oxyethylene functional organosilane is a compound having the formula RSiR'.sub.3 in which R is the radical --O(CH.sub.2 CH.sub.2 O).sub.x R"; R' is an R group or an alkyl radical having one to six carbon atoms; R" is a radical such as hydrogen; an alkyl group of one to six carbon atoms; and an aryl group; and x is an integer having a value of six to thirty.Type: GrantFiled: April 6, 1993Date of Patent: July 5, 1994Assignee: Dow Corning CorporationInventors: David A. Glover, Gary E. LeGrow, Linda M. Madore, Regina M. Malczweski
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Patent number: 5322888Abstract: A coating composition that can be applied to optical plastic moldings having a high refractive index, to protect them from deterioration by light without any adverse effect on their optical functions. The coating composition contains the following essential constituents.(A) 1 part of a hydrolyzate of a silane compound;(B) 0.2-5 parts of titanium oxide-based composite fine particles having a particle diameter of 1-100 nm in which titanium oxide integrally combines with iron oxide, with the ratio of iron oxide to titanium oxide being 0.005-0.15 by weight;(C) 0.02-0.5 part of an unsaturated or saturated polycarboxylic acid or an anhydride thereof; and(D) 0.01-0.2 part of a heat-curing catalyst.Type: GrantFiled: June 22, 1992Date of Patent: June 21, 1994Assignee: Itoh Optical Industrial Co., Ltd.Inventors: Hirohisa Kato, Sachio Murai, Mutsuyo Honda
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Patent number: 5300561Abstract: A solution of amphiphilic molecules and water is atomized to form a mist of droplets which are deposited on a substrate surface to completely cover same with a coating of the solution. The amphiphilic molecules in the coating self-assemble on the surface into a continuous thin film that is less than 500 nanometers thick. The water is evaporated from the coating to leave only the film chemically bonded to the surface.Type: GrantFiled: August 5, 1992Date of Patent: April 5, 1994Assignee: NanoFilm CorporationInventors: Brij P. Singh, Raj Subramaniam, Scott E. Rickert
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Patent number: 5292798Abstract: Cyclopentadienyl and/or cyclopentadienylene and/or dicyclopentadienylene-substituted polyorganosiloxanes that are crosslinkable into elastomeric state on exposure to atmospheric oxygen and/or to moisture are well suited, e.g., for adhesive applications in the construction industry and for diverse insulating/coating applications.Type: GrantFiled: April 30, 1992Date of Patent: March 8, 1994Assignee: Rhone-Poulenc ChimieInventors: Jean-Marc Frances, Frederic Leising
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Patent number: 5283279Abstract: A coating composition comprising (A) a polyorganosiloxane graft copolymer emulsion, (B) a reaction product between an amino functional silane and/or a hydrolyzate thereof and an acid anhydride, (C) colloidal silica, (D) a curing catalyst, and (E) an inorganic filler is useful in coating exterior and interior building materials. The composition is applicable to a substrate to form a coating at room temperature having sufficient extensibility to follow cracks in the underlying substrate as well as low-to-high temperature sensitive performance, moisture permeability, flame retardance, and decorative effect.Type: GrantFiled: May 17, 1991Date of Patent: February 1, 1994Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yasuaki Hara, Morizo Nakazato, Yasunori Takaichi, Tsuyoshi Urashima, Tsuyoshi Aoyama, Seiichi Nishimura
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Patent number: 5281657Abstract: A process for preparing organopolysiloxane hydrosols by mixing an organosilicon compound with water, which comprises mixing a silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)where a is 0, 1, 2 or 3, R can be the same or different and is a hydrogen atom or a monovalent organic radical, R.sup.1 can be the same or different and is a monovalent organic radical, and/or a partial hydrolysis product thereof and, optionally, an organodisiloxane of the formulaR.sup.2.sub.3 Si-O-SiR.sup.2.sub.3 (II)where R.sup.2 can be the same or different and is the same as R, with water in the presence of an emulsifier at a temperature below 15.degree. C.Type: GrantFiled: August 16, 1993Date of Patent: January 25, 1994Assignee: Wacker-Chemie GmbHInventors: Konrad Mautner, Bernward Deubzer, Helmut Oswaldbauer, Hilmar Sinner
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Patent number: 5272204Abstract: Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer in situ in a polyol in the presence of inner-olefin containing at least 5 carbon atoms, are of lower viscosity and can provide polyurethanes having improved properties. Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer, in situ in a polyol in the presence of an azo compound and a peroxide having a 10 hours half-life period temperature which is lower by at least 10.degree. C. than that of the azo compound, have improved stability even at higher styrene content.Type: GrantFiled: May 31, 1991Date of Patent: December 21, 1993Assignee: Sanyo Chemical Industries, Ltd.Inventors: Keiichi Akimoto, Takeshi Sumita, Masahiro Matsuoka
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Patent number: 5269844Abstract: A colored paste composed of a silicone ladder polymer, a solvent, and an organic pigment insoluble in said solvent, said silicone ladder polymer being a polymer having an average molecular weight of 1.0.times.10.sup.3 to 3.5.times.10.sup.5. The colored paste has good storage stability and readily forms a uniform film by spin coating.Type: GrantFiled: December 10, 1992Date of Patent: December 14, 1993Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Shigeyuki Yamamoto, Hiroshi Adachi
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Patent number: 5260377Abstract: Crosslinkable carbosilane polymer formulations are prepared from saturated or unsaturated carbosilane polymers containing reactive silicon hydride radicals in the polymer chain combined with polycyclic polyene crosslinkers having two or more double bonds that are reactive in the hydrosilation crosslinking reaction.Type: GrantFiled: November 5, 1992Date of Patent: November 9, 1993Assignees: University of Southern California, Hercules IncorporatedInventors: William P. Weber, Raymond T. Leibfried, Xiugao Liao
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Patent number: 5219922Abstract: The present invention relates to silicone elastomers based on platinum-catalyzed, hot-curing organopolysiloxane compositions which are characterized by particularly low compression set after crosslinking and to a process for the production of these elastomers.Type: GrantFiled: April 24, 1991Date of Patent: June 15, 1993Assignee: Bayer AktiengesellschaftInventors: Helmut Steinberger, Klaus-Dieter Pesch, Thomas Naumann
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Patent number: 5205860Abstract: A surface treating composition for excluding water penetration which is a solution obtained by combining water; an alkyltrialkoxysilane selected from the group consisting of C.sub.1 to C.sub.6 alkyl groups on silicon and blends of alkyltrialkoxysilanes with C.sub.1 to C.sub.6 alkyl groups on silicon; a silane coupling agent; and an aqueous silicone emulsion of an anionically stabilized hydroxyl endblocked polydiorganosiloxane, amorphous silica and an organic tin salt.Type: GrantFiled: January 23, 1992Date of Patent: April 27, 1993Assignee: Dow Corning CorporationInventors: Dipak Narula, Lori A. Stark
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Patent number: 5180771Abstract: A room temperature curable organopolysiloxane composition comprising a diorganopolysiloxane having a hydroxyl group or alkoxy groups, a filler, a particular alkoxysilane, an organosilicon compound having a particular guanidinyl group, and an organic tin compound, and further comprising an organosilicon compound having at least one group represented by the general formula: ##STR1## where R.sup.4 is a substituted or unsubstituted monovalent hydrocarbon group, or a substituted or unsubstituted phenyl group, R.sup.5 and R.sup.6 are each a hydrogen atom, methyl or ethyl group, and n is an integer of 0, 1 or 2. By virtue of the last component, the composition exhibits markedly good storage stability.Type: GrantFiled: April 13, 1990Date of Patent: January 19, 1993Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masatoshi Arai, Yoshifumi Inoue, Yoshio Inoue
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Patent number: 5164501Abstract: A method of preparing pure 3-butenyl triorgano oxysilanes, the intermediate products 3,4-dichlorobutyl triorgano oxysilanes and the use of the final products in rubber mixtures reinforced with silicic acid and vulcanizable with peroxides. 3,4-dichlorobutene-1 and trichlorosilane are used as initial products.Type: GrantFiled: February 19, 1992Date of Patent: November 17, 1992Assignee: Degussa AGInventors: Ulrich Deschler, Peter Kleinschmit, Siegfried Wolff, Ewe-Hong Tan
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Patent number: 5079286Abstract: Disclosed is a casting resin based on acrylic acid esters having a high content of finely dispersed fillers and containing a mixture of organosilicon compounds having functional groups and metallic acid esters of metals of Groups IVB and VB of the Periodic Table of the Elements. The functional group of the organosilicon compound is ethylenically unsaturated and bound to the silicon atom either directly or through alkylene groups. The addition of this mixture to the casing resins produces a desirable reduction of the viscosity of these resins, which are used, for example, for the manufacture of sanitary articles.The filler content is at least 20% and can be as high as 95% with the proviso that when the filler content is in excess of 80 wt. -%, the filler contains 10 to 30 wt. -%, based on the total weight of filler, of fines having a particle size less than 0.1 mm and the remainder of the filler being coarse up to 4 mm.Type: GrantFiled: April 5, 1988Date of Patent: January 7, 1992Assignee: Huels Troisdorf AGInventors: Horst Hanisch, Theo Lenz, Guenther Bernhardt
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Patent number: 5079312Abstract: The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.Type: GrantFiled: May 11, 1990Date of Patent: January 7, 1992Assignee: Kansai Paint Company, LimitedInventors: Osamu Isozaki, Noboru Nakai, Koichiro Murata
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Patent number: 5036135Abstract: Reaction resin mixtures which can be economically processed provide inflammable molded materials with excellent mechanical properties and high dimensional stability under heat when they contain the following constituents: (A) a phosphorus-free polyfunctional epoxide; (B) an epoxy-group-containing phosphorus compound; (C) a polyfunctional isocyanate; (D) a curing catalyst; and, if required, (E) filler material.Type: GrantFiled: July 19, 1990Date of Patent: July 30, 1991Assignee: Siemens AktiengesellschaftInventors: Wolfgang von Gentzkow, Jurgen Huber, Wolfgang Rogler, Dieter Wilhelm
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Patent number: 5019340Abstract: An alcohol-based composition inhibited against high temperature aluminum cavitation erosion corrosion characterized by the presence of a polysilyl compound of the formula: ##STR1## wherein R is a substituted or unsubstituted organic radical; R.sup.1 is selected from the group consisting of hydrogen, monovalent hydrocarbon radicals and substituted monovalent hydrocarbon radicals; R.sup.2 is a monovalent moiety hydrolyzable to a hydroxyl group, each R.sup.2 being the same or different; a is an integer from 2 to 4, inclusive; b is an integer having a value of 0 or 1; n is an integer from 1 to 36, inclusive; and c is an integer having a value of 0 or 1; each ##STR2## group being the same or different, with the provision that the compound have at least one ##STR3## group.Type: GrantFiled: April 23, 1990Date of Patent: May 28, 1991Assignee: First Brands CorporationInventors: Paul H. Mohr, Enrico J. Pepe
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Patent number: 4978702Abstract: A coating composition is disclosed which includes(A) 15 to 65% by weight (calculated as SiO.sub.2) of colloidal silica,a partially hydrolyzed and partially co-condensed product of the following component (B) and component (C):(B) 10 to 80% by weight (calculated as R.sup.1 Si(OH).sub.3) of a trialkoxysilane of the formula: R.sup.1 Si(OR.sup.2).sub.3 wherein the group R.sup.1 is methyl or vinyl and the group R.sup.2 is alkyl having 1 to 4 carbon atoms,(C) 1 to 50% by weight (calculated as R.sup.3.sub.n Si(OH).sub.4-n) of an acetoxysilane of the formula: R.sup.3.sub.n Si(OCOCH.sub.3).sub.4-n wherein the group R.sup.3 is alkyl having 1 to 3 carbon atoms, vinyl, phenyl, or mercaptoalkyl having 1 to 3 carbon atoms, and n is an integer of 0 to 2, provided that the total amount of the component (B) wherein the group R.sup.1 is methyl and the component (C) wherein the group R.sup.Type: GrantFiled: August 26, 1988Date of Patent: December 18, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Masahiro Yuyama, Masahiko Moritani, Mikio Futagami
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Patent number: 4973623Abstract: A room temperature curing composition which cures fast and has good reversion resistance and good package stability is a mixture of 66.75 to 89.4 weight percent of a hydroxyl endblocked polydiorganosiloxane; 5.5 to 10 weight percent of a tetrafunctional ethoxy-ketoximo silane mixture having 6 to 27 weight perent tetraketoximosilane, 9 to 39 weight percent of monoethoxytriketoximosilane, 38 to 60 weight percent of diethoxydiketoximosilane, and 5.5 to 25 weight percent triethoxymonoketoximosilane; 0.1 to 0.25 weight percent of a tin catalyst, 0 to 3 weight percent of an adhesion promoter, and 5 to 20 weight percent of reinforcing silica. These compositions cure to elastomeric materials useful as caulking materials, adhesives, coatings and encapsulating materials for construction and automotive industries.Type: GrantFiled: May 26, 1989Date of Patent: November 27, 1990Assignee: Dow Corning CorporationInventors: Michael H. Haugsby, Loren D. Lower
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Patent number: 4940844Abstract: A stable polyol-alkali metal silicate emulsion is produced by mixing and emulsifying an aqueous alkali metal solution, a polyol and an organic compound that will cause the aqueous alkali metal silicate solution to solidify. The polyol-alkali metal silicate emulsion may be used to react with compounds containing at least two isocyanate radicals to produce polyurethane silicate solid or foamed products which may be used for thermal and sound insulation, coating agents, adhesives, caulking agents and molded objects.Type: GrantFiled: April 4, 1988Date of Patent: July 10, 1990Inventor: David H. Blunt
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Patent number: 4933415Abstract: There are provided polyethers end-blocked with hydrolyzable silyl groups which have molecular weight from 500 to 50,000 and are represented by the formula: ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 individually represent a divalent hydrocarbon group, R.sup.5 represents a monovalent hydrocarbon group, R.sup.6 represents an alkyl group with 1 to 6 carbon atoms, A represents a substituted or non-substituted divalent aromatic group, a represents a number of 1 to 3, m represents a number of 10 to 500 and n represents a number of 1 or greater. The polyether is produced by reacting an epoxy end-blocked polyoxyalkylene, a mono-epoxy substituted hydrolyzable silane, and an aromatic diamine.Type: GrantFiled: August 26, 1988Date of Patent: June 12, 1990Assignee: Toshiba Silicone Co., Ltd.Inventors: Chiyuki Shimizu, Tamio Yoshida
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Patent number: 4933413Abstract: Organosilicon compounds containing at least one acylamino-substituted hydrocarbon radical are prepared by reacting an organohydroxysilicon compound containing at least one silicon-bonded hydroxy radical with a base to yield a silanolate. The silanolate is reacted with a cyclic aminosilane compound to form a siloxyalkylamide that is then reacted with an acyl chloride to give the desired product. All reactions can be carried out in a single reaction vessel using a nonaqueous solvent.Type: GrantFiled: April 10, 1989Date of Patent: June 12, 1990Assignee: Dow Corning CorporationInventor: Sudarsanan Varaprath
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Patent number: 4923927Abstract: A curable composition comprises 100 parts by weight of an oxyalkylene polymer having at least one silicon-containing group which has a hydroxyl or hydrolyzable group attached to silicon atom and which is crosslinkable by forming a siloxane linkage and from 0.1 to less than 10 parts by weight of a liquid diene polymer.Type: GrantFiled: December 1, 1988Date of Patent: May 8, 1990Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Toshifumi Hirose, Katsuhiko Isayama
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Patent number: 4914143Abstract: An improved silica-containing curable coating composition is described herein. The composition has an alkaline pH and contains a dialkyldialkoxysilane/alkyltrialkoxysilane mixture and a dispersion of ammonium-stabilized colloidal silica having an average particle size no greater than about 5-10 millimicrons. Methods for preparing such compositions are also disclosed, as are thermoplastic articles which include the cured protective coatings.Type: GrantFiled: April 25, 1988Date of Patent: April 3, 1990Assignee: General Electric CompanyInventor: Gautam A. Patel
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Patent number: 4902736Abstract: A one-part curing composition comprising a compound (a) having two or more structural groups, per molecule, expressed by the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are groups selected from an alkyl group having 1 to 6 carbon atoms, a phenyl group, and a chloromethyl group, and a polymer (b) having two or more isocyanate groups per molecule, has a good stability in storage under conditions which exclude moisture and humidity, and which further cures in the presence of humidity. This composition does not foam under high temperatures and humidities and has a good heat resistance.Type: GrantFiled: August 10, 1988Date of Patent: February 20, 1990Assignee: Toray Thiokol Company LimitedInventors: Toshiaki Nonaka, Masashi Nakajima, Tatsuro Matsui, Noriaki Dokoshi
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Patent number: 4880861Abstract: A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use of automotive refinishing paints and industrial coatings.Type: GrantFiled: March 8, 1989Date of Patent: November 14, 1989Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Shoichi Matsumura, Toshiro Nanbu, Hisao Furukawa
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Patent number: 4873272Abstract: A polyether having molecular weight from 1,000 to 50,000, end-blocked with hydrolyzable silyl groups and represented by the general formula (P): ##STR1## where R.sup.1, R.sup.2, R.sup.6 and R.sup.7 individually represent a divalent hydrocarbon group, R.sup.4 represents a monovalent hydrocarbon group, R.sup.8 represents an alkyl group with 1 to 6 carbon atoms, a represents a number from 1 to 3, m represents a number from 10 to 500, n represents a number of 1 or greater and --N.dbd.X.dbd.N-- represents a residue group of a diimino heterocyclic compound, from which nitrogen-bonded hydrogen atoms are eliminated, said diimino heterocyclic compound having no ##STR2## bond in a molecule is produced and utilized in room temperature curing compositions containing inorganic filler and curing catalyst. There is also disclosed a method for producing the above polyether by reacting polyoxyalkylene end-blocked with epoxy groups, diimino heterocyclic compound and organo silicon compound.Type: GrantFiled: November 9, 1987Date of Patent: October 10, 1989Assignee: Toshiba Silicone Co., Ltd.Inventors: Chiyuki Shimizu, Tamio Yoshida
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Patent number: 4857582Abstract: Colloidal suspensions of organopolysiloxanes are prepared by mixing an organosilicon compound selected from the group consisting of mixtures of alkoxysilanes and/or partial hydrolysates thereof and an organo(poly)siloxane which is optionally free of alkoxy groups and contains a maximum of 8 siloxane units, which is mixed with at least one alkoxysilane and/or a partial hydrolysate thereof, with water in the presence of an emulsifier, at a maximum rate of 5 moles of organosilicon compound per hour per liter of water, in which the organosilicon compound and the water is fed continuously, but separately from one another, into a reactor, in which at least one of the two substances contains an emulsifier, while the alkanol is being continuously removed by distillation from the aqueous suspension continuously emerging from the reactor. The aqueous suspension from which the alkanol has been removed by distillation is, if desired, recycled back into the reactor.Type: GrantFiled: May 18, 1988Date of Patent: August 15, 1989Assignee: Wacker-Chemie GmbHInventors: Matthias Wolfgruber, Bernward Deubzer, Volker Frey
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Patent number: 4826904Abstract: A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use as automotive refinishing paints and industrial coatings.Type: GrantFiled: November 23, 1987Date of Patent: May 2, 1989Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Shoichi Matsumura, Toshiro Nanbu, Hisao Furukawa
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Patent number: 4772494Abstract: Method of spinning fibers and coating from an organopolysilazane composition that can be crosslinked by an energy input. The organopolysilazane composition comprises an organopolysilazane and a free radical generator in an amount effective to crosslink the organopolysilazane. The energy input capable of generated the radical may be provided in the form of heat, ultraviolet radiation, an electron beam, and the like.The crosslinked organopolysilazane compositions exhibit good thermal behavior and, in particular, can be used, after pyrolysis, as precursors of ceramic products.Type: GrantFiled: October 1, 1987Date of Patent: September 20, 1988Assignee: Rhone-Poulenc Specialites ChimiquesInventors: Hugues Porte, Jean-Jacques Lebrun
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Patent number: 4752633Abstract: Ethoxylated siloxane surfactants, and mixtures of such surfactants with curable silicone prepolymers. The mixtures are hydrophilic after cure, have semipermanent hydrophilicity, and are especially useful as dental impressions.Type: GrantFiled: June 5, 1987Date of Patent: June 21, 1988Assignee: Minnesota Mining and Manufacturing Co.Inventors: Steven M. Aasen, Thomas T. Bryan
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Patent number: 4746693Abstract: A composition suitable for forming polyalkylsilsesquioxane coatings is prepared by emulsion hydrolysis of one or more silanes in the presence of a nonvolatile, nonionic catalyst, a nonionic fluorochemical surfactant and sufficient water to only partially hydrolyze the silanes. The resulting stable composition will form the final resin upon exposure to atmospheric moisture. A novel resin, polymethyl/isobutylsilsesquioxane, is particularly suitable for such coatings.Type: GrantFiled: December 12, 1986Date of Patent: May 24, 1988Assignee: RCA CorporationInventor: Martin G. Meder
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Patent number: 4722988Abstract: An organopolysilazane composition that can be crosslinked by an energy input. The organopolysilazane composition comprises an organopolysilazane and a free radical generator in an amount effective to crosslink the organopolysilazane. The energy input capable of generating the radical may be provided in the form of heat, ultraviolet radiation, an electron beam, and the like.The crosslinked organopolysilazane compositions exhibit good thermal behavior and, in particular, can be used, after pyrolysis, as precursors of ceramic products.Type: GrantFiled: May 6, 1986Date of Patent: February 2, 1988Assignee: Rhone-Poulenc Specialites ChimiquesInventors: Hugues Porte, Jean-Jacques Lebrun
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Patent number: 4694040Abstract: The invention provides a novel means for providing a highly heat-resistant and corrosion-resistant coating film on the surface of a substrate such as a semiconductor silicon wafer or glass plate by coating the surface with a liquid coating composition which is a solution of an oligomeric organopolysiloxane as a partial dehydration-condensation product of a monohydrocarbylsilane triol RSi(OH).sub.3, optionally, with admixture of a dihydrocarbylsilane diol R.sub.2 Si(OH).sub.2, R being a monovalent hydrocarbon group, e.g. methyl or phenyl, in an organic solvent followed by baking of the coated substrate to convert the coating layer into a cured resin film.Type: GrantFiled: August 25, 1986Date of Patent: September 15, 1987Assignee: Tokyo Denshi Kagaku Kabushiki KaishaInventors: Akira Hashimoto, Toshihiro Nishimura, Muneo Nakayama, Hisashi Nakane, Shozo Toda
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Patent number: 4689252Abstract: A crosslinkable composition comprising at least one polysilazane containing at least 2, preferably at least 3, .tbd.SiH groups per molecule and at least 2 SiR.sub.2 groups per molecule, R.sub.2 being an unsaturated hydrocarbon radical and a catalytically effective quantity of a metal element or of a metal compound to catalyze the hydrosilylation reaction SiH/SiR.sub.2.The compositions according to the invention can crosslink under the effect of heat and can be used for coating or impregnating substrates with ceramic material after pyrolysis. The mechanical properties of the crosslinked compositions are assessed by evaluating the relative rigidity RR measured by the fiber torsion pendulum method (FIG. 1).Type: GrantFiled: March 28, 1986Date of Patent: August 25, 1987Assignee: Rhone-Poulenc Specialites ChimiquesInventors: Jean-Jacques Lebrun, Huques Porte
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Patent number: 4657959Abstract: Curable silicon prepolymers are made hydrophilic after cure by mixing the prepolymer with ethoxylated nonionic surface active agent or cationic or amphoteric fluorochemical surface active agent. The cured silicones have semipermanent hydrophilicity and are especially useful as dental impressions.Type: GrantFiled: November 15, 1985Date of Patent: April 14, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas T. Bryan, Harvey L. Anderson
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Patent number: 4652497Abstract: This invention relates to organosiloxane compositions which have application as protective coatings for soft substrates. The compositions of the invention include a substituent selected from each of the following classes of compositions: organo-alkoxysilanes; polyoxymethylenes; monocarboxylic organic acids; and optionally inorganic hydroxyacids. The coatings formed form these compositions have properties as adhesion promoters and are abrasion resistant.Type: GrantFiled: December 17, 1984Date of Patent: March 24, 1987Assignee: AGIP S.p.A.Inventors: Paolo Ascarelli, Gianfranco Boccalon, Mario De Antoniis
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Patent number: 4645691Abstract: A method for treating a solid material to give it hydrophilic and/or antistatic properties comprises applying a composition containing a silicone compound to the material which has one or more alkoxysilylalkyl groups and one or more polyoxyalkylene groups. In a preferred embodiment the method is used to treat fibers and fiber-containing materials. The composition can further contain a curing agent for the silicone. Emulsion compositions are particularly useful.Type: GrantFiled: December 20, 1985Date of Patent: February 24, 1987Assignee: Toray Silicone Co., Ltd.Inventors: Isao Ona, Masaru Ozaki
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Patent number: 4621029Abstract: This invention relates to a medical sealant comprising polyorganosiloxane gel for sealing a junction part between living skin and a medical instrument penetrating through the skin, said polyorganosiloxane gel having a partially cross-linked three dimentional structure expressed by the basis general formula ofR.sub.n SiO.sub.(4-n)/2(wherein R represents hydrogen or monovalent hydrocarbonyl group and n represents an integer of 1 to 3), characterized in that said gel self-supports its figure at room temperature and has a hardness expressed by a loading weight of 1 g to 250 g by which a disc of a diameter of 10 mm sinks to 1.0 mm on the gel.Type: GrantFiled: January 11, 1985Date of Patent: November 4, 1986Assignee: Fuji Systems CorporationInventor: Nobuhisa Kawaguchi
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Patent number: 4617344Abstract: The organopolysiloxane in the inventive latex is modified with phosphonate ester-containing groups such as those expressed by the formula --Si--CH.sub.2 CH.sub.2 --PO(OEt).sub.2 (Et: ethyl group) and --Si--CH.sub.2 CH.sub.2 CH.sub.2 --PO(ODd).sub.2 (Dd: dodecyl group) and exhibits excellent performance in the applications as a fabric treatment agent and the like. The inventive organopolysiloxane latex can be prepared by the polymerizing reaction of an organosilicon compound or, preferably, an organopolysiloxane and a phosphonate ester-modified alkoxysilane emulsified together in an aqueous medium containing a surface active agent of the class of the organic sulfonic acid type or a sulfate ester type ones which serves both as an emulsifier and as an acid catalyst.Type: GrantFiled: May 8, 1985Date of Patent: October 14, 1986Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masaki Tanaka, Hiroshi Ohashi
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Patent number: 4617327Abstract: A filler for a polymerizable composition comprising an inorganic core of particles with a particle size of 10 to 500 nm, a first shell of vinylsilane and a second shell of a (meth)acrylate polymer. The filler is then used to prepare dental moldings of acrylates in conventional manner. The moldings are very hard and abrasion resistant.Type: GrantFiled: October 10, 1985Date of Patent: October 14, 1986Assignee: Bayer AktiengesellschaftInventor: Wolfgang Podszun
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Patent number: 4578417Abstract: A moisture curable composition having an improved storage stability comprising a hydrolyzable silyl group-containing vinyl polymer and an orthoacetic acid ester as a stabilizer. The storage stability of the composition containing the hydrolyzable silyl group-containing vinyl polymer, which is curable in the presence of moisture at low temperatures, can be remarkably improved by the presence of the orthoacetic acid ester.Type: GrantFiled: October 2, 1984Date of Patent: March 25, 1986Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Hisao Furukawa, Keiko Okada, Joe Kawamura, Yasushi Kato
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Patent number: 4571365Abstract: There is disclosed transparent, abrasion resistant coating compositions comprising a colloidal dispersion of a water insoluble dispersant in a water-alcohol solution of the partial condensate of silanol wherein the dispersant comprises metals, alloys, salts, oxides and hydroxides thereof.Type: GrantFiled: April 1, 1982Date of Patent: February 18, 1986Assignee: Swedlow, Inc.Inventors: Lysander T. Ashlock, Harold Mukamal, William H. White
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Patent number: 4555545Abstract: A composition for coating, which comprises:(1) 100 parts by weight of film forming components comprising:(A) 10 to 90% by weight of an organosilane triol of the following formula and/or its partial condensate:R.sup.1 Si(OH).sub.3wherein R.sup.1 represents a monovalent group selected from the group consisting of alkyl groups having 1 to 3 carbon atoms and aryl groups, and(B) 90 to 10% by weight of colloidal silica; and(2) 5 to 40 parts by weight of a copolymer of:(C) a compound represented by the formula: ##STR1## wherein Q represents >C.dbd.O or the following formula: ##STR2## wherein each X may be either the same or different and each represents hydrogen atom or hydroxyl group, of which at least one is hydroxyl group, and R.sup.2 represents an alkyl group having 1 to 18 carbon atoms, and(D) an epoxy group-containing trialkoxysilane.Type: GrantFiled: February 1, 1985Date of Patent: November 26, 1985Assignee: Toshiba Silicone Co., Ltd.Inventors: Hiroshi Kimura, Ikurou Mori, Bunjirou Murai
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Patent number: 4547397Abstract: A tintable coating is applied to a transparent substrate such as a polycarbonate lens. The coating is made from a coating solution of (1) a further curable organopolysiloxane preferably made by hydrolyzing ethyl ortho silicate with methacryloxytrimethoxy silane and/or vinyltriethoxy silane with phenylphosphonic acid, and an (2) organic solvent for the organopolysiloxane. The coating is cured, an azo dye applied to the cured coating to provide a highly tinted coating without sacrificing scratch resistance. The cured coating can be tinted with an improved tinting speed and the resultant cured tinted coating has improved abrasion resistance.Type: GrantFiled: March 25, 1985Date of Patent: October 15, 1985Assignee: Owens-Illinois, Inc.Inventors: Alfred J. Burzynski, James J. Tillman
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Patent number: 4539232Abstract: A method for producing solventless liquid organopolysiloxanes is disclosed. The method involves hydrolyzing an organo silicon composition comprising at least one compound having the general formulaY.sub.(4-n) Si(OR).sub.nwhere Y is phenyl or a primary or secondary alkyl group having from one to four carbon atoms, R is an alkyl group having from one to three carbon atoms, and n is an integer from one to four, and wherein the ratio of OR groups to silicon atoms in the composition is from 2.3:1 to 3.1:1. The products of hydrolysis are then heated to cause substantial siloxane formation by condensation and to distill water and alcohol by-products. Heating is continued until the water content of the resulting siloxane composition is less than 1 percent. The purity of the organo silicon composition, the amount of water used for hydrolysis, the amount of acid present during hydrolysis, and the heating of the organopolysiloxane are so controlled that the solventless organopolysiloxane has a viscosity at 25.degree. C.Type: GrantFiled: August 29, 1983Date of Patent: September 3, 1985Assignee: Owens-Illinois, Inc.Inventors: Alfred J. Burzynski, Edward J. Stengle
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Patent number: 4518716Abstract: Polyorganosiloxane foams exhibiting a desirable combination of low density, an average cell size between 0.2 and 4 mm and a cell concentration of at least 4 per linear centimeter are obtained by dispensing and curing moisture curable organosiloxane compositions containing a dispersed liquid or gaseous blowing agent and, as a foam stabilizer, a resinous organosiloxane copolymer comprising trimethylsiloxy units, SiO.sub.4/2 units and fluorine-containing organosiloxane units. The polymer portion of the organosiloxane compositions can be a polydimethylsiloxane or a graft copolymer comprising at least 20 mole percent of dimethylsiloxane units in combination with organic units.Type: GrantFiled: October 26, 1984Date of Patent: May 21, 1985Assignee: Dow Corning CorporationInventors: Chi-Long Lee, James A. Rabe
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Patent number: 4518727Abstract: Water-based silicone resin emulsions are provided comprising an organopolysiloxane resin or mixture of resins which may include a solvent carrier, and a combination of emulsifying agents including cellulosic-type and anionic surfactant-type emulsifiers as well as an amount of water sufficient for providing a water-based emulsion having a desired viscosity and silicone resin solids content by weight.Type: GrantFiled: April 30, 1984Date of Patent: May 21, 1985Assignee: General Electric CompanyInventor: Frank J. Traver
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Patent number: 4500669Abstract: There is disclosed transparent, abrasion resistant coating compositions comprising a colloidal dispersion of a water insoluble dispersant in a water-alcohol solution of the partial condensate of silanol wherein the dispersant comprises metals, alloys and salts thereof.Type: GrantFiled: April 3, 1980Date of Patent: February 19, 1985Assignee: Swedlow, Inc.Inventors: L. T. Ashlock, Harold Mukamal, William H. White