Si-containing Reactant Forming A Solid Polymer Or Sicp In The Presence Of A Nonreactant Material Patents (Class 524/858)
  • Patent number: 5332779
    Abstract: This invention provides polymerizable silica sols in which at least one monomer containing double bond is used as its dispersion medium, especially a silica sol in which the monomer containing double bond is a monomer containing double bond and OH group or is a monomer having an adamantane structure. This invention also provides compositions which comprise these silica sols as composing elements, cured resins that are obtained by polymerizing these silica sols alone or together with other copolymerizable components, and new adamantane derivatives for use in these silica sols.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: July 26, 1994
    Assignee: Kawasaki Steel Corporation
    Inventors: Taizo Mohri, Katsuhiko Takagi, Yoshihiro Naruse, Yukio Asami
  • Patent number: 5326557
    Abstract: Moisturizing compositions for a human skin which contain oxyethylene function organosilanes. When used in skin care applications, these compounds exhibit humectant properties. The oxyethylene functional organosilane is a compound having the formula RSiR'.sub.3 in which R is the radical --O(CH.sub.2 CH.sub.2 O).sub.x R"; R' is an R group or an alkyl radical having one to six carbon atoms; R" is a radical such as hydrogen; an alkyl group of one to six carbon atoms; and an aryl group; and x is an integer having a value of six to thirty.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: July 5, 1994
    Assignee: Dow Corning Corporation
    Inventors: David A. Glover, Gary E. LeGrow, Linda M. Madore, Regina M. Malczweski
  • Patent number: 5322888
    Abstract: A coating composition that can be applied to optical plastic moldings having a high refractive index, to protect them from deterioration by light without any adverse effect on their optical functions. The coating composition contains the following essential constituents.(A) 1 part of a hydrolyzate of a silane compound;(B) 0.2-5 parts of titanium oxide-based composite fine particles having a particle diameter of 1-100 nm in which titanium oxide integrally combines with iron oxide, with the ratio of iron oxide to titanium oxide being 0.005-0.15 by weight;(C) 0.02-0.5 part of an unsaturated or saturated polycarboxylic acid or an anhydride thereof; and(D) 0.01-0.2 part of a heat-curing catalyst.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: June 21, 1994
    Assignee: Itoh Optical Industrial Co., Ltd.
    Inventors: Hirohisa Kato, Sachio Murai, Mutsuyo Honda
  • Patent number: 5300561
    Abstract: A solution of amphiphilic molecules and water is atomized to form a mist of droplets which are deposited on a substrate surface to completely cover same with a coating of the solution. The amphiphilic molecules in the coating self-assemble on the surface into a continuous thin film that is less than 500 nanometers thick. The water is evaporated from the coating to leave only the film chemically bonded to the surface.
    Type: Grant
    Filed: August 5, 1992
    Date of Patent: April 5, 1994
    Assignee: NanoFilm Corporation
    Inventors: Brij P. Singh, Raj Subramaniam, Scott E. Rickert
  • Patent number: 5292798
    Abstract: Cyclopentadienyl and/or cyclopentadienylene and/or dicyclopentadienylene-substituted polyorganosiloxanes that are crosslinkable into elastomeric state on exposure to atmospheric oxygen and/or to moisture are well suited, e.g., for adhesive applications in the construction industry and for diverse insulating/coating applications.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: March 8, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Marc Frances, Frederic Leising
  • Patent number: 5283279
    Abstract: A coating composition comprising (A) a polyorganosiloxane graft copolymer emulsion, (B) a reaction product between an amino functional silane and/or a hydrolyzate thereof and an acid anhydride, (C) colloidal silica, (D) a curing catalyst, and (E) an inorganic filler is useful in coating exterior and interior building materials. The composition is applicable to a substrate to form a coating at room temperature having sufficient extensibility to follow cracks in the underlying substrate as well as low-to-high temperature sensitive performance, moisture permeability, flame retardance, and decorative effect.
    Type: Grant
    Filed: May 17, 1991
    Date of Patent: February 1, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yasuaki Hara, Morizo Nakazato, Yasunori Takaichi, Tsuyoshi Urashima, Tsuyoshi Aoyama, Seiichi Nishimura
  • Patent number: 5281657
    Abstract: A process for preparing organopolysiloxane hydrosols by mixing an organosilicon compound with water, which comprises mixing a silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)where a is 0, 1, 2 or 3, R can be the same or different and is a hydrogen atom or a monovalent organic radical, R.sup.1 can be the same or different and is a monovalent organic radical, and/or a partial hydrolysis product thereof and, optionally, an organodisiloxane of the formulaR.sup.2.sub.3 Si-O-SiR.sup.2.sub.3 (II)where R.sup.2 can be the same or different and is the same as R, with water in the presence of an emulsifier at a temperature below 15.degree. C.
    Type: Grant
    Filed: August 16, 1993
    Date of Patent: January 25, 1994
    Assignee: Wacker-Chemie GmbH
    Inventors: Konrad Mautner, Bernward Deubzer, Helmut Oswaldbauer, Hilmar Sinner
  • Patent number: 5272204
    Abstract: Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer in situ in a polyol in the presence of inner-olefin containing at least 5 carbon atoms, are of lower viscosity and can provide polyurethanes having improved properties. Polymer/polyol compositions, obtained by polymerizing an ethylenically unsaturated monomer, in situ in a polyol in the presence of an azo compound and a peroxide having a 10 hours half-life period temperature which is lower by at least 10.degree. C. than that of the azo compound, have improved stability even at higher styrene content.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: December 21, 1993
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Keiichi Akimoto, Takeshi Sumita, Masahiro Matsuoka
  • Patent number: 5269844
    Abstract: A colored paste composed of a silicone ladder polymer, a solvent, and an organic pigment insoluble in said solvent, said silicone ladder polymer being a polymer having an average molecular weight of 1.0.times.10.sup.3 to 3.5.times.10.sup.5. The colored paste has good storage stability and readily forms a uniform film by spin coating.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: December 14, 1993
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Shigeyuki Yamamoto, Hiroshi Adachi
  • Patent number: 5260377
    Abstract: Crosslinkable carbosilane polymer formulations are prepared from saturated or unsaturated carbosilane polymers containing reactive silicon hydride radicals in the polymer chain combined with polycyclic polyene crosslinkers having two or more double bonds that are reactive in the hydrosilation crosslinking reaction.
    Type: Grant
    Filed: November 5, 1992
    Date of Patent: November 9, 1993
    Assignees: University of Southern California, Hercules Incorporated
    Inventors: William P. Weber, Raymond T. Leibfried, Xiugao Liao
  • Patent number: 5219922
    Abstract: The present invention relates to silicone elastomers based on platinum-catalyzed, hot-curing organopolysiloxane compositions which are characterized by particularly low compression set after crosslinking and to a process for the production of these elastomers.
    Type: Grant
    Filed: April 24, 1991
    Date of Patent: June 15, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Steinberger, Klaus-Dieter Pesch, Thomas Naumann
  • Patent number: 5205860
    Abstract: A surface treating composition for excluding water penetration which is a solution obtained by combining water; an alkyltrialkoxysilane selected from the group consisting of C.sub.1 to C.sub.6 alkyl groups on silicon and blends of alkyltrialkoxysilanes with C.sub.1 to C.sub.6 alkyl groups on silicon; a silane coupling agent; and an aqueous silicone emulsion of an anionically stabilized hydroxyl endblocked polydiorganosiloxane, amorphous silica and an organic tin salt.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: April 27, 1993
    Assignee: Dow Corning Corporation
    Inventors: Dipak Narula, Lori A. Stark
  • Patent number: 5180771
    Abstract: A room temperature curable organopolysiloxane composition comprising a diorganopolysiloxane having a hydroxyl group or alkoxy groups, a filler, a particular alkoxysilane, an organosilicon compound having a particular guanidinyl group, and an organic tin compound, and further comprising an organosilicon compound having at least one group represented by the general formula: ##STR1## where R.sup.4 is a substituted or unsubstituted monovalent hydrocarbon group, or a substituted or unsubstituted phenyl group, R.sup.5 and R.sup.6 are each a hydrogen atom, methyl or ethyl group, and n is an integer of 0, 1 or 2. By virtue of the last component, the composition exhibits markedly good storage stability.
    Type: Grant
    Filed: April 13, 1990
    Date of Patent: January 19, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Yoshifumi Inoue, Yoshio Inoue
  • Patent number: 5164501
    Abstract: A method of preparing pure 3-butenyl triorgano oxysilanes, the intermediate products 3,4-dichlorobutyl triorgano oxysilanes and the use of the final products in rubber mixtures reinforced with silicic acid and vulcanizable with peroxides. 3,4-dichlorobutene-1 and trichlorosilane are used as initial products.
    Type: Grant
    Filed: February 19, 1992
    Date of Patent: November 17, 1992
    Assignee: Degussa AG
    Inventors: Ulrich Deschler, Peter Kleinschmit, Siegfried Wolff, Ewe-Hong Tan
  • Patent number: 5079286
    Abstract: Disclosed is a casting resin based on acrylic acid esters having a high content of finely dispersed fillers and containing a mixture of organosilicon compounds having functional groups and metallic acid esters of metals of Groups IVB and VB of the Periodic Table of the Elements. The functional group of the organosilicon compound is ethylenically unsaturated and bound to the silicon atom either directly or through alkylene groups. The addition of this mixture to the casing resins produces a desirable reduction of the viscosity of these resins, which are used, for example, for the manufacture of sanitary articles.The filler content is at least 20% and can be as high as 95% with the proviso that when the filler content is in excess of 80 wt. -%, the filler contains 10 to 30 wt. -%, based on the total weight of filler, of fines having a particle size less than 0.1 mm and the remainder of the filler being coarse up to 4 mm.
    Type: Grant
    Filed: April 5, 1988
    Date of Patent: January 7, 1992
    Assignee: Huels Troisdorf AG
    Inventors: Horst Hanisch, Theo Lenz, Guenther Bernhardt
  • Patent number: 5079312
    Abstract: The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: January 7, 1992
    Assignee: Kansai Paint Company, Limited
    Inventors: Osamu Isozaki, Noboru Nakai, Koichiro Murata
  • Patent number: 5036135
    Abstract: Reaction resin mixtures which can be economically processed provide inflammable molded materials with excellent mechanical properties and high dimensional stability under heat when they contain the following constituents: (A) a phosphorus-free polyfunctional epoxide; (B) an epoxy-group-containing phosphorus compound; (C) a polyfunctional isocyanate; (D) a curing catalyst; and, if required, (E) filler material.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: July 30, 1991
    Assignee: Siemens Aktiengesellschaft
    Inventors: Wolfgang von Gentzkow, Jurgen Huber, Wolfgang Rogler, Dieter Wilhelm
  • Patent number: 5019340
    Abstract: An alcohol-based composition inhibited against high temperature aluminum cavitation erosion corrosion characterized by the presence of a polysilyl compound of the formula: ##STR1## wherein R is a substituted or unsubstituted organic radical; R.sup.1 is selected from the group consisting of hydrogen, monovalent hydrocarbon radicals and substituted monovalent hydrocarbon radicals; R.sup.2 is a monovalent moiety hydrolyzable to a hydroxyl group, each R.sup.2 being the same or different; a is an integer from 2 to 4, inclusive; b is an integer having a value of 0 or 1; n is an integer from 1 to 36, inclusive; and c is an integer having a value of 0 or 1; each ##STR2## group being the same or different, with the provision that the compound have at least one ##STR3## group.
    Type: Grant
    Filed: April 23, 1990
    Date of Patent: May 28, 1991
    Assignee: First Brands Corporation
    Inventors: Paul H. Mohr, Enrico J. Pepe
  • Patent number: 4978702
    Abstract: A coating composition is disclosed which includes(A) 15 to 65% by weight (calculated as SiO.sub.2) of colloidal silica,a partially hydrolyzed and partially co-condensed product of the following component (B) and component (C):(B) 10 to 80% by weight (calculated as R.sup.1 Si(OH).sub.3) of a trialkoxysilane of the formula: R.sup.1 Si(OR.sup.2).sub.3 wherein the group R.sup.1 is methyl or vinyl and the group R.sup.2 is alkyl having 1 to 4 carbon atoms,(C) 1 to 50% by weight (calculated as R.sup.3.sub.n Si(OH).sub.4-n) of an acetoxysilane of the formula: R.sup.3.sub.n Si(OCOCH.sub.3).sub.4-n wherein the group R.sup.3 is alkyl having 1 to 3 carbon atoms, vinyl, phenyl, or mercaptoalkyl having 1 to 3 carbon atoms, and n is an integer of 0 to 2, provided that the total amount of the component (B) wherein the group R.sup.1 is methyl and the component (C) wherein the group R.sup.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: December 18, 1990
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masahiro Yuyama, Masahiko Moritani, Mikio Futagami
  • Patent number: 4973623
    Abstract: A room temperature curing composition which cures fast and has good reversion resistance and good package stability is a mixture of 66.75 to 89.4 weight percent of a hydroxyl endblocked polydiorganosiloxane; 5.5 to 10 weight percent of a tetrafunctional ethoxy-ketoximo silane mixture having 6 to 27 weight perent tetraketoximosilane, 9 to 39 weight percent of monoethoxytriketoximosilane, 38 to 60 weight percent of diethoxydiketoximosilane, and 5.5 to 25 weight percent triethoxymonoketoximosilane; 0.1 to 0.25 weight percent of a tin catalyst, 0 to 3 weight percent of an adhesion promoter, and 5 to 20 weight percent of reinforcing silica. These compositions cure to elastomeric materials useful as caulking materials, adhesives, coatings and encapsulating materials for construction and automotive industries.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: November 27, 1990
    Assignee: Dow Corning Corporation
    Inventors: Michael H. Haugsby, Loren D. Lower
  • Patent number: 4940844
    Abstract: A stable polyol-alkali metal silicate emulsion is produced by mixing and emulsifying an aqueous alkali metal solution, a polyol and an organic compound that will cause the aqueous alkali metal silicate solution to solidify. The polyol-alkali metal silicate emulsion may be used to react with compounds containing at least two isocyanate radicals to produce polyurethane silicate solid or foamed products which may be used for thermal and sound insulation, coating agents, adhesives, caulking agents and molded objects.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: July 10, 1990
    Inventor: David H. Blunt
  • Patent number: 4933415
    Abstract: There are provided polyethers end-blocked with hydrolyzable silyl groups which have molecular weight from 500 to 50,000 and are represented by the formula: ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 individually represent a divalent hydrocarbon group, R.sup.5 represents a monovalent hydrocarbon group, R.sup.6 represents an alkyl group with 1 to 6 carbon atoms, A represents a substituted or non-substituted divalent aromatic group, a represents a number of 1 to 3, m represents a number of 10 to 500 and n represents a number of 1 or greater. The polyether is produced by reacting an epoxy end-blocked polyoxyalkylene, a mono-epoxy substituted hydrolyzable silane, and an aromatic diamine.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: June 12, 1990
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Chiyuki Shimizu, Tamio Yoshida
  • Patent number: 4933413
    Abstract: Organosilicon compounds containing at least one acylamino-substituted hydrocarbon radical are prepared by reacting an organohydroxysilicon compound containing at least one silicon-bonded hydroxy radical with a base to yield a silanolate. The silanolate is reacted with a cyclic aminosilane compound to form a siloxyalkylamide that is then reacted with an acyl chloride to give the desired product. All reactions can be carried out in a single reaction vessel using a nonaqueous solvent.
    Type: Grant
    Filed: April 10, 1989
    Date of Patent: June 12, 1990
    Assignee: Dow Corning Corporation
    Inventor: Sudarsanan Varaprath
  • Patent number: 4923927
    Abstract: A curable composition comprises 100 parts by weight of an oxyalkylene polymer having at least one silicon-containing group which has a hydroxyl or hydrolyzable group attached to silicon atom and which is crosslinkable by forming a siloxane linkage and from 0.1 to less than 10 parts by weight of a liquid diene polymer.
    Type: Grant
    Filed: December 1, 1988
    Date of Patent: May 8, 1990
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Toshifumi Hirose, Katsuhiko Isayama
  • Patent number: 4914143
    Abstract: An improved silica-containing curable coating composition is described herein. The composition has an alkaline pH and contains a dialkyldialkoxysilane/alkyltrialkoxysilane mixture and a dispersion of ammonium-stabilized colloidal silica having an average particle size no greater than about 5-10 millimicrons. Methods for preparing such compositions are also disclosed, as are thermoplastic articles which include the cured protective coatings.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: April 3, 1990
    Assignee: General Electric Company
    Inventor: Gautam A. Patel
  • Patent number: 4902736
    Abstract: A one-part curing composition comprising a compound (a) having two or more structural groups, per molecule, expressed by the general formula: ##STR1## wherein R.sup.1, R.sup.2, and R.sup.3 are groups selected from an alkyl group having 1 to 6 carbon atoms, a phenyl group, and a chloromethyl group, and a polymer (b) having two or more isocyanate groups per molecule, has a good stability in storage under conditions which exclude moisture and humidity, and which further cures in the presence of humidity. This composition does not foam under high temperatures and humidities and has a good heat resistance.
    Type: Grant
    Filed: August 10, 1988
    Date of Patent: February 20, 1990
    Assignee: Toray Thiokol Company Limited
    Inventors: Toshiaki Nonaka, Masashi Nakajima, Tatsuro Matsui, Noriaki Dokoshi
  • Patent number: 4880861
    Abstract: A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use of automotive refinishing paints and industrial coatings.
    Type: Grant
    Filed: March 8, 1989
    Date of Patent: November 14, 1989
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shoichi Matsumura, Toshiro Nanbu, Hisao Furukawa
  • Patent number: 4873272
    Abstract: A polyether having molecular weight from 1,000 to 50,000, end-blocked with hydrolyzable silyl groups and represented by the general formula (P): ##STR1## where R.sup.1, R.sup.2, R.sup.6 and R.sup.7 individually represent a divalent hydrocarbon group, R.sup.4 represents a monovalent hydrocarbon group, R.sup.8 represents an alkyl group with 1 to 6 carbon atoms, a represents a number from 1 to 3, m represents a number from 10 to 500, n represents a number of 1 or greater and --N.dbd.X.dbd.N-- represents a residue group of a diimino heterocyclic compound, from which nitrogen-bonded hydrogen atoms are eliminated, said diimino heterocyclic compound having no ##STR2## bond in a molecule is produced and utilized in room temperature curing compositions containing inorganic filler and curing catalyst. There is also disclosed a method for producing the above polyether by reacting polyoxyalkylene end-blocked with epoxy groups, diimino heterocyclic compound and organo silicon compound.
    Type: Grant
    Filed: November 9, 1987
    Date of Patent: October 10, 1989
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Chiyuki Shimizu, Tamio Yoshida
  • Patent number: 4857582
    Abstract: Colloidal suspensions of organopolysiloxanes are prepared by mixing an organosilicon compound selected from the group consisting of mixtures of alkoxysilanes and/or partial hydrolysates thereof and an organo(poly)siloxane which is optionally free of alkoxy groups and contains a maximum of 8 siloxane units, which is mixed with at least one alkoxysilane and/or a partial hydrolysate thereof, with water in the presence of an emulsifier, at a maximum rate of 5 moles of organosilicon compound per hour per liter of water, in which the organosilicon compound and the water is fed continuously, but separately from one another, into a reactor, in which at least one of the two substances contains an emulsifier, while the alkanol is being continuously removed by distillation from the aqueous suspension continuously emerging from the reactor. The aqueous suspension from which the alkanol has been removed by distillation is, if desired, recycled back into the reactor.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: August 15, 1989
    Assignee: Wacker-Chemie GmbH
    Inventors: Matthias Wolfgruber, Bernward Deubzer, Volker Frey
  • Patent number: 4826904
    Abstract: A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use as automotive refinishing paints and industrial coatings.
    Type: Grant
    Filed: November 23, 1987
    Date of Patent: May 2, 1989
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Shoichi Matsumura, Toshiro Nanbu, Hisao Furukawa
  • Patent number: 4772494
    Abstract: Method of spinning fibers and coating from an organopolysilazane composition that can be crosslinked by an energy input. The organopolysilazane composition comprises an organopolysilazane and a free radical generator in an amount effective to crosslink the organopolysilazane. The energy input capable of generated the radical may be provided in the form of heat, ultraviolet radiation, an electron beam, and the like.The crosslinked organopolysilazane compositions exhibit good thermal behavior and, in particular, can be used, after pyrolysis, as precursors of ceramic products.
    Type: Grant
    Filed: October 1, 1987
    Date of Patent: September 20, 1988
    Assignee: Rhone-Poulenc Specialites Chimiques
    Inventors: Hugues Porte, Jean-Jacques Lebrun
  • Patent number: 4752633
    Abstract: Ethoxylated siloxane surfactants, and mixtures of such surfactants with curable silicone prepolymers. The mixtures are hydrophilic after cure, have semipermanent hydrophilicity, and are especially useful as dental impressions.
    Type: Grant
    Filed: June 5, 1987
    Date of Patent: June 21, 1988
    Assignee: Minnesota Mining and Manufacturing Co.
    Inventors: Steven M. Aasen, Thomas T. Bryan
  • Patent number: 4746693
    Abstract: A composition suitable for forming polyalkylsilsesquioxane coatings is prepared by emulsion hydrolysis of one or more silanes in the presence of a nonvolatile, nonionic catalyst, a nonionic fluorochemical surfactant and sufficient water to only partially hydrolyze the silanes. The resulting stable composition will form the final resin upon exposure to atmospheric moisture. A novel resin, polymethyl/isobutylsilsesquioxane, is particularly suitable for such coatings.
    Type: Grant
    Filed: December 12, 1986
    Date of Patent: May 24, 1988
    Assignee: RCA Corporation
    Inventor: Martin G. Meder
  • Patent number: 4722988
    Abstract: An organopolysilazane composition that can be crosslinked by an energy input. The organopolysilazane composition comprises an organopolysilazane and a free radical generator in an amount effective to crosslink the organopolysilazane. The energy input capable of generating the radical may be provided in the form of heat, ultraviolet radiation, an electron beam, and the like.The crosslinked organopolysilazane compositions exhibit good thermal behavior and, in particular, can be used, after pyrolysis, as precursors of ceramic products.
    Type: Grant
    Filed: May 6, 1986
    Date of Patent: February 2, 1988
    Assignee: Rhone-Poulenc Specialites Chimiques
    Inventors: Hugues Porte, Jean-Jacques Lebrun
  • Patent number: 4694040
    Abstract: The invention provides a novel means for providing a highly heat-resistant and corrosion-resistant coating film on the surface of a substrate such as a semiconductor silicon wafer or glass plate by coating the surface with a liquid coating composition which is a solution of an oligomeric organopolysiloxane as a partial dehydration-condensation product of a monohydrocarbylsilane triol RSi(OH).sub.3, optionally, with admixture of a dihydrocarbylsilane diol R.sub.2 Si(OH).sub.2, R being a monovalent hydrocarbon group, e.g. methyl or phenyl, in an organic solvent followed by baking of the coated substrate to convert the coating layer into a cured resin film.
    Type: Grant
    Filed: August 25, 1986
    Date of Patent: September 15, 1987
    Assignee: Tokyo Denshi Kagaku Kabushiki Kaisha
    Inventors: Akira Hashimoto, Toshihiro Nishimura, Muneo Nakayama, Hisashi Nakane, Shozo Toda
  • Patent number: 4689252
    Abstract: A crosslinkable composition comprising at least one polysilazane containing at least 2, preferably at least 3, .tbd.SiH groups per molecule and at least 2 SiR.sub.2 groups per molecule, R.sub.2 being an unsaturated hydrocarbon radical and a catalytically effective quantity of a metal element or of a metal compound to catalyze the hydrosilylation reaction SiH/SiR.sub.2.The compositions according to the invention can crosslink under the effect of heat and can be used for coating or impregnating substrates with ceramic material after pyrolysis. The mechanical properties of the crosslinked compositions are assessed by evaluating the relative rigidity RR measured by the fiber torsion pendulum method (FIG. 1).
    Type: Grant
    Filed: March 28, 1986
    Date of Patent: August 25, 1987
    Assignee: Rhone-Poulenc Specialites Chimiques
    Inventors: Jean-Jacques Lebrun, Huques Porte
  • Patent number: 4657959
    Abstract: Curable silicon prepolymers are made hydrophilic after cure by mixing the prepolymer with ethoxylated nonionic surface active agent or cationic or amphoteric fluorochemical surface active agent. The cured silicones have semipermanent hydrophilicity and are especially useful as dental impressions.
    Type: Grant
    Filed: November 15, 1985
    Date of Patent: April 14, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Thomas T. Bryan, Harvey L. Anderson
  • Patent number: 4652497
    Abstract: This invention relates to organosiloxane compositions which have application as protective coatings for soft substrates. The compositions of the invention include a substituent selected from each of the following classes of compositions: organo-alkoxysilanes; polyoxymethylenes; monocarboxylic organic acids; and optionally inorganic hydroxyacids. The coatings formed form these compositions have properties as adhesion promoters and are abrasion resistant.
    Type: Grant
    Filed: December 17, 1984
    Date of Patent: March 24, 1987
    Assignee: AGIP S.p.A.
    Inventors: Paolo Ascarelli, Gianfranco Boccalon, Mario De Antoniis
  • Patent number: 4645691
    Abstract: A method for treating a solid material to give it hydrophilic and/or antistatic properties comprises applying a composition containing a silicone compound to the material which has one or more alkoxysilylalkyl groups and one or more polyoxyalkylene groups. In a preferred embodiment the method is used to treat fibers and fiber-containing materials. The composition can further contain a curing agent for the silicone. Emulsion compositions are particularly useful.
    Type: Grant
    Filed: December 20, 1985
    Date of Patent: February 24, 1987
    Assignee: Toray Silicone Co., Ltd.
    Inventors: Isao Ona, Masaru Ozaki
  • Patent number: 4621029
    Abstract: This invention relates to a medical sealant comprising polyorganosiloxane gel for sealing a junction part between living skin and a medical instrument penetrating through the skin, said polyorganosiloxane gel having a partially cross-linked three dimentional structure expressed by the basis general formula ofR.sub.n SiO.sub.(4-n)/2(wherein R represents hydrogen or monovalent hydrocarbonyl group and n represents an integer of 1 to 3), characterized in that said gel self-supports its figure at room temperature and has a hardness expressed by a loading weight of 1 g to 250 g by which a disc of a diameter of 10 mm sinks to 1.0 mm on the gel.
    Type: Grant
    Filed: January 11, 1985
    Date of Patent: November 4, 1986
    Assignee: Fuji Systems Corporation
    Inventor: Nobuhisa Kawaguchi
  • Patent number: 4617344
    Abstract: The organopolysiloxane in the inventive latex is modified with phosphonate ester-containing groups such as those expressed by the formula --Si--CH.sub.2 CH.sub.2 --PO(OEt).sub.2 (Et: ethyl group) and --Si--CH.sub.2 CH.sub.2 CH.sub.2 --PO(ODd).sub.2 (Dd: dodecyl group) and exhibits excellent performance in the applications as a fabric treatment agent and the like. The inventive organopolysiloxane latex can be prepared by the polymerizing reaction of an organosilicon compound or, preferably, an organopolysiloxane and a phosphonate ester-modified alkoxysilane emulsified together in an aqueous medium containing a surface active agent of the class of the organic sulfonic acid type or a sulfate ester type ones which serves both as an emulsifier and as an acid catalyst.
    Type: Grant
    Filed: May 8, 1985
    Date of Patent: October 14, 1986
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaki Tanaka, Hiroshi Ohashi
  • Patent number: 4617327
    Abstract: A filler for a polymerizable composition comprising an inorganic core of particles with a particle size of 10 to 500 nm, a first shell of vinylsilane and a second shell of a (meth)acrylate polymer. The filler is then used to prepare dental moldings of acrylates in conventional manner. The moldings are very hard and abrasion resistant.
    Type: Grant
    Filed: October 10, 1985
    Date of Patent: October 14, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventor: Wolfgang Podszun
  • Patent number: 4578417
    Abstract: A moisture curable composition having an improved storage stability comprising a hydrolyzable silyl group-containing vinyl polymer and an orthoacetic acid ester as a stabilizer. The storage stability of the composition containing the hydrolyzable silyl group-containing vinyl polymer, which is curable in the presence of moisture at low temperatures, can be remarkably improved by the presence of the orthoacetic acid ester.
    Type: Grant
    Filed: October 2, 1984
    Date of Patent: March 25, 1986
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hisao Furukawa, Keiko Okada, Joe Kawamura, Yasushi Kato
  • Patent number: 4571365
    Abstract: There is disclosed transparent, abrasion resistant coating compositions comprising a colloidal dispersion of a water insoluble dispersant in a water-alcohol solution of the partial condensate of silanol wherein the dispersant comprises metals, alloys, salts, oxides and hydroxides thereof.
    Type: Grant
    Filed: April 1, 1982
    Date of Patent: February 18, 1986
    Assignee: Swedlow, Inc.
    Inventors: Lysander T. Ashlock, Harold Mukamal, William H. White
  • Patent number: 4555545
    Abstract: A composition for coating, which comprises:(1) 100 parts by weight of film forming components comprising:(A) 10 to 90% by weight of an organosilane triol of the following formula and/or its partial condensate:R.sup.1 Si(OH).sub.3wherein R.sup.1 represents a monovalent group selected from the group consisting of alkyl groups having 1 to 3 carbon atoms and aryl groups, and(B) 90 to 10% by weight of colloidal silica; and(2) 5 to 40 parts by weight of a copolymer of:(C) a compound represented by the formula: ##STR1## wherein Q represents >C.dbd.O or the following formula: ##STR2## wherein each X may be either the same or different and each represents hydrogen atom or hydroxyl group, of which at least one is hydroxyl group, and R.sup.2 represents an alkyl group having 1 to 18 carbon atoms, and(D) an epoxy group-containing trialkoxysilane.
    Type: Grant
    Filed: February 1, 1985
    Date of Patent: November 26, 1985
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Hiroshi Kimura, Ikurou Mori, Bunjirou Murai
  • Patent number: 4547397
    Abstract: A tintable coating is applied to a transparent substrate such as a polycarbonate lens. The coating is made from a coating solution of (1) a further curable organopolysiloxane preferably made by hydrolyzing ethyl ortho silicate with methacryloxytrimethoxy silane and/or vinyltriethoxy silane with phenylphosphonic acid, and an (2) organic solvent for the organopolysiloxane. The coating is cured, an azo dye applied to the cured coating to provide a highly tinted coating without sacrificing scratch resistance. The cured coating can be tinted with an improved tinting speed and the resultant cured tinted coating has improved abrasion resistance.
    Type: Grant
    Filed: March 25, 1985
    Date of Patent: October 15, 1985
    Assignee: Owens-Illinois, Inc.
    Inventors: Alfred J. Burzynski, James J. Tillman
  • Patent number: 4539232
    Abstract: A method for producing solventless liquid organopolysiloxanes is disclosed. The method involves hydrolyzing an organo silicon composition comprising at least one compound having the general formulaY.sub.(4-n) Si(OR).sub.nwhere Y is phenyl or a primary or secondary alkyl group having from one to four carbon atoms, R is an alkyl group having from one to three carbon atoms, and n is an integer from one to four, and wherein the ratio of OR groups to silicon atoms in the composition is from 2.3:1 to 3.1:1. The products of hydrolysis are then heated to cause substantial siloxane formation by condensation and to distill water and alcohol by-products. Heating is continued until the water content of the resulting siloxane composition is less than 1 percent. The purity of the organo silicon composition, the amount of water used for hydrolysis, the amount of acid present during hydrolysis, and the heating of the organopolysiloxane are so controlled that the solventless organopolysiloxane has a viscosity at 25.degree. C.
    Type: Grant
    Filed: August 29, 1983
    Date of Patent: September 3, 1985
    Assignee: Owens-Illinois, Inc.
    Inventors: Alfred J. Burzynski, Edward J. Stengle
  • Patent number: 4518716
    Abstract: Polyorganosiloxane foams exhibiting a desirable combination of low density, an average cell size between 0.2 and 4 mm and a cell concentration of at least 4 per linear centimeter are obtained by dispensing and curing moisture curable organosiloxane compositions containing a dispersed liquid or gaseous blowing agent and, as a foam stabilizer, a resinous organosiloxane copolymer comprising trimethylsiloxy units, SiO.sub.4/2 units and fluorine-containing organosiloxane units. The polymer portion of the organosiloxane compositions can be a polydimethylsiloxane or a graft copolymer comprising at least 20 mole percent of dimethylsiloxane units in combination with organic units.
    Type: Grant
    Filed: October 26, 1984
    Date of Patent: May 21, 1985
    Assignee: Dow Corning Corporation
    Inventors: Chi-Long Lee, James A. Rabe
  • Patent number: 4518727
    Abstract: Water-based silicone resin emulsions are provided comprising an organopolysiloxane resin or mixture of resins which may include a solvent carrier, and a combination of emulsifying agents including cellulosic-type and anionic surfactant-type emulsifiers as well as an amount of water sufficient for providing a water-based emulsion having a desired viscosity and silicone resin solids content by weight.
    Type: Grant
    Filed: April 30, 1984
    Date of Patent: May 21, 1985
    Assignee: General Electric Company
    Inventor: Frank J. Traver
  • Patent number: 4500669
    Abstract: There is disclosed transparent, abrasion resistant coating compositions comprising a colloidal dispersion of a water insoluble dispersant in a water-alcohol solution of the partial condensate of silanol wherein the dispersant comprises metals, alloys and salts thereof.
    Type: Grant
    Filed: April 3, 1980
    Date of Patent: February 19, 1985
    Assignee: Swedlow, Inc.
    Inventors: L. T. Ashlock, Harold Mukamal, William H. White