Si-h Containing Reactant Patents (Class 524/861)
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Patent number: 11292280Abstract: The present invention is directed to a composition and method of providing a silicone release coating material for a thermally-responsive record material while maintaining strong printability with UV inks and water based inks, as well as scuff resistance. The thermally-responsive record material includes a substrate with first and second surfaces. The first surface includes a heat sensitive coating having a colorless dye precursor and an acidic developer material in contiguous relationship. The release coating is provided with an aqueous mixture of a water soluble or water dispersible polymeric material, a silicone release agent, an excess of platinum catalyst, and a hydrophilic silica. The platinum catalyst is preferably provided in excess of 150 ppm. The hydrophilic silica is preferably fumed silica. The release coating is cured at a temperature of 160° C. or less, or even from 70° C. to 120° C.Type: GrantFiled: December 27, 2017Date of Patent: April 5, 2022Assignee: APPVION OPERATIONS, INC.Inventors: Mark Fisher, Yves Defrenne, Lei Xu
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Patent number: 10040907Abstract: A method for producing a siloxane resin, by hydrolyzing and condensing a silane compound containing a hydrolyzable silyl group represented by RnSiX4-n using a neutral salt as a catalyst. In the formula RnSiX4-n, R represents an organic group having a carbon atom directly bonded to Si, X represents a hydroxyl group or a hydrolyzable group, and n represents an integer of 0 to 3, provided that when n is 2 or greater each R may be the same as or different from each other, and when (4-n) is 2 or greater, each X may be the same as or different from each other.Type: GrantFiled: March 30, 2017Date of Patent: August 7, 2018Assignee: Kaneka CorporationInventors: Hiroki Fukaumi, Shinji Kagitani
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Patent number: 9487677Abstract: There is described a release composition including a polyorganosiloxane polymer and a release modifier. The release modifier includes comprising an alkenyl silsesquioxane an organo functional siloxane of the formula MDxM, wherein M represents R3SiO1/2, D represents R2SiO2/2, wherein R is alkyl or alkenyl of 1 to 40 carbon atoms, or hydrogen wherein the organo functional siloxane has a viscosity of from about 5 centipoises to about 80 centipoises and x is from about 5 to about 80, and an optionally a reactive diluent. The release composition includes at least one siloxane cross-linking agent, an inhibitor; and a hydrosilation catalyst.Type: GrantFiled: May 27, 2014Date of Patent: November 8, 2016Assignee: Momentive Performance Materials, Inc.Inventors: Roy Melvin Griswold, Melania Lapinski
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Publication number: 20140309370Abstract: Crosslinkable compositions based on organosilicon compounds, more particularly RTV-1 sealants, contain (A) at least one organosilicon compound having at least two condensable radicals, (B) at least one finely divided silicon dioxide having a BET surface area of 30 to 120 m2/g and a relative thickening effect ?rel of 1.4 to 10, and (C) at least one hydrocarbon component which has an initial boiling point above 150° C., a final boiling point below 350° C., each at a pressure of 1013 hPa, a kinematic viscosity of 1.5 to 6.0 mm2/s as measured at 40° C., a viscosity-density constant (VDC) of less than or equal to 0.820, a pour point of less than ?5° C., and an aromatic carbon atom (CA) content of less than 0.1% CA.Type: ApplicationFiled: March 26, 2014Publication date: October 16, 2014Applicant: Wacker Chemie AGInventors: Detlev Ostendorf, Uwe Scheim, Peter Schoeley
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Patent number: 8841404Abstract: Polycarbonate compositions having flame retardant properties and improved impact resistance are disclosed, together with methods for preparing the same.Type: GrantFiled: May 18, 2011Date of Patent: September 23, 2014Assignee: SABIC Global Technologies B.V.Inventors: Haseena Aripuram Parakkal, Sriram Krishnamurthy, Wim Steendam, Gautam Chatterjee
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Patent number: 8835555Abstract: The present invention has an objective to easily obtain an emulsion exhibiting superior storage stability, and in particular, an emulsion of a polyorganosiloxane. The present invention provides a method for producing an emulsion characterized by obtaining an emulsion by emulsifying a mixture of an oil and a surfactant, obtained by synthesizing the surfactant in the oil. In particular, the method is suitably used for the preparation of an emulsion of an organopolysiloxane (A) which is usually difficult to be stably emulsified. A silicone-based surfactant (B), and in particular, a silicone-based surfactant having a small degree of polymerization of a siloxane chain such as a trisiloxane is synthesized in an oil. Thereby, an emulsion exhibiting superior storage stability can be produced.Type: GrantFiled: December 21, 2009Date of Patent: September 16, 2014Assignee: Dow Corning Toray Co. Ltd.Inventors: Kazuhiko Kojima, Tsutomu Naganawa, Asao Harashima
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Publication number: 20130287959Abstract: A silicon based coating composition for a wide range of surfaces, which composition is formed from a mixture of constituents comprising appropriate portions of silazane, siloxane, and silane, and optionally organic solvent and additives, and the composition results in a coating having a thickness between 0.1 and 1.5 mil, a hardness of 2-9H and a standard coefficient of friction between about 0.03 to about 0.04.Type: ApplicationFiled: April 29, 2013Publication date: October 31, 2013Inventors: Chris Fish, Jerry Kilby
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Patent number: 8530617Abstract: A process for producing silicon-containing particles having an extremely small particle diameter by a simple process without using surface-active agents or the like. The process is characterized by forming silicon-containing particles as a result of phase separation from an organic polymer, wherein the phase separation is achieved by an addition reaction, condensation reaction, ring-opening reaction, or a radical reaction of a curable silicon-containing compound or a curable composition that contains said compound, and the silicon-containing compound or the composition is maintained in a uniform liquid, fused, or dissolved phase with the organic polymer that is free of silicon and does not participate in the curing reaction of the silicon-containing compound or the composition.Type: GrantFiled: January 23, 2009Date of Patent: September 10, 2013Assignee: Dow Corning Toray Company, Ltd.Inventor: Yukinari Harimoto
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Patent number: 8466210Abstract: The present invention relates to a curable dental composition comprising a surfactant and an F-containing compound. The dental composition can be used e.g. as impression material and/or for the production of crown and bridges.Type: GrantFiled: December 17, 2008Date of Patent: June 18, 2013Assignee: 3M Innovative Properties CompanyInventors: Joachim W. Zech, Peter U. Osswald, Henning Hoffmann, Andreas R. Maurer, Peter Bissinger, Klaus Hintzer
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Publication number: 20130142949Abstract: An environmentally acceptable catalyst, coating system, and methods for thermal cure silicone release coatings that utilize bismuth (“Bi”) catalyst to retain properties of tin (“Sn”)-catalyzed systems but do not have the toxicity and environmental hazards associated therewith. The coating systems and methods also provide a laminate that shows reduced orange peel distortion over time compared with tin (“Sn”)-catalyzed systems and methods.Type: ApplicationFiled: November 30, 2012Publication date: June 6, 2013Applicant: CPFILMS INC.Inventor: CPFILMS INC.
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Patent number: 8450442Abstract: A borosiloxane composition comprising a borosiloxane having an average of at least two alkenyl groups per molecule, an organosilicon compound having an average of at least two silicon-bonded hydrogen atoms per molecule, and a hydrosilylation catalyst; a borosiloxane adhesive comprising a cured product of at least one borosiloxane; and a coated substrate and a laminated substrate, each comprising the borosiloxane adhesive.Type: GrantFiled: February 23, 2009Date of Patent: May 28, 2013Assignee: Dow Corning CorporationInventor: Bizhong Zhu
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Patent number: 8343632Abstract: The present invention relates to curable alkenyl based silicone release coating compositions having improved adhesion to paper and polymeric substrates. Furthermore the present invention relates to the process for making a silicone release coating with improved adhesion to paper and polymeric substrates.Type: GrantFiled: October 19, 2010Date of Patent: January 1, 2013Assignee: Momentive Performance Materials Inc.Inventors: Roy Melvin Griswold, Richard Paul Eckberg, Slawomir Rubinsztajn, Stanislaw Slomkowski, Anna Kowalewska, Stanislaw Sosnowski
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Patent number: 8299197Abstract: A polymer for gap-filling in a semiconductor device, the polymer being prepared by polycondensation of hydrolysates of the compound represented by Formula 1, the compound represented by Formula 2, and one or more compounds represented by Formulae 3 and 4: [RO]3Si—[CH2]n—Si[OR]3??(1) wherein n is from 0 to 2 and each R is independently a C1-C6 alkyl group; [RO]3Si—[CH2]nX??(2) wherein X is a C6-C12 aryl group, n is from 0 to 2, and R is a C1-C6 alkyl group; [RO]3Si—R???(3) wherein R and R? are independently a C1-C6 alkyl group; and [RO]3Si—H??(4) wherein R is a C1-C6 alkyl group.Type: GrantFiled: March 8, 2010Date of Patent: October 30, 2012Assignee: Cheil Industries, Inc.Inventors: Chang Soo Woo, Hyun Hoo Sung, Jin Hee Bae, Dong Seon Uh, Jong Seob Kim
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Patent number: 8044121Abstract: A cement mold-making silicone rubber composition is provided comprising (A) 100 parts by weight of a polyorganosiloxane having at least two silicon-bonded monovalent aliphatic unsaturated hydrocarbon groups in a molecule, (B) a polyorganohydrogensiloxane having at least three silicon-bonded hydrogen atoms in a molecule, in such an amount as to provide 0.1-5 silicon-bonded hydrogen atoms per monovalent aliphatic unsaturated hydrocarbon group in component (A), (C) a platinum base compound in such an amount as to provide 1-100 ppm of platinum atoms based on the weight of component (A), (D) 5-60 parts by weight of finely divided silica having a specific surface area of at least 50 m2/g, and (E) 0.1-100 parts by weight of coal ash and/or pozzolan powder.Type: GrantFiled: June 25, 2008Date of Patent: October 25, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroshi Mogi, Susumu Sekiguchi, Thomas Tupa
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Publication number: 20110124812Abstract: A fixing material includes a silane compound polymer as the main component, the silane compound polymer being produced by condensing a silane compound mixture that includes at least one silane compound (1) shown by the following formula (1): R1Si(OR2)p(X1)3-p (wherein R1 represents a group including an ester structure or a cyanoalkyl group, R2 represents an alkyl group having 1 to 6 carbon atoms or the like, X1 represents a halogen atom, and p is an integer from 0 to 3), and at least one silane compound (2) shown by the following formula (2): Si(OR3)q(X2)4-q (wherein R3 represents an alkyl group having 1 to 6 carbon atoms, X2 represents a halogen atom, and q is an integer from 0 to 4). A sealed optical device includes an optical device that is sealed with a cured product of the fixing material. The fixing material produces a cured product that exhibits high hardness, excellent transparency and heat resistance, and rarely undergoes coloration even when subjected to high-energy light or heat for a long time.Type: ApplicationFiled: March 25, 2009Publication date: May 26, 2011Applicant: LINTEC CORPORATIONInventors: Takashi Tamada, Mikihiro Kashio
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Patent number: 7846550Abstract: The present invention relates to new curable siloxane compositions, and their use for the manufacture of cured products thereof having modified release properties. The modified release forces are achieved by incorporating a selected pressure sensitive adhesive additive.Type: GrantFiled: December 22, 2004Date of Patent: December 7, 2010Assignee: Momentive Performance Materials GmbHInventors: Marco Ooms, Jos Delis, Pierre Leveque
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Patent number: 7803868Abstract: Addition-crosslinkable silicone compositions contain (A) 100 parts by weight of polydiorganosiloxane(s) which has alkenyl groups and whose viscosity is from 5000 to 50,000,000 mPas at 25° C., having at least 2 alkenyl groups per molecule, and at least 0.15 mol % of alkenylsiloxane units, based on all siloxane units, (B) from 1 to 50 parts by weight of polydiorganosiloxane(s) whose viscosity is at least 5,000,000 mPas at 25° C., and having no alkenyl groups, (C) SiH-functional crosslinking agent(s), (D) hydrosilylation catalyst(s), and (E) from 3 to 90 parts by weight of filler(s) whose BET specific surface area is at least 50 m2/g. Vulcanizates of the addition-crosslinkable silicone compositions have low coefficients of friction.Type: GrantFiled: February 6, 2008Date of Patent: September 28, 2010Assignee: Wacker Chemie AGInventors: Christof Woerner, Willi Primas
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Patent number: 7727635Abstract: A coating composition that is capable of forming a coating film that combines abrasion resistance and crack resistance. The composition comprises: (A) a silicone resin obtained by hydrolysis and condensation of an alkoxysilane that includes an alkoxysilane represented by a general formula (1): (R1)mSi(OR2)4-m??(1) (wherein, R1 represents a hydrogen atom, or a substituted or unsubstituted monovalent hydrocarbon group, R2 represents an alkyl group of 1 to 3 carbon atoms, and m represents either 0 or 1), (B) hydrophobic silica microparticles, (C) a curing catalyst, and (D) a solvent.Type: GrantFiled: May 27, 2008Date of Patent: June 1, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masahiro Furuya, Muneo Kudo
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Patent number: 7718748Abstract: A two-component addition-crosslinking silicone comprises (a) 0.1-70% by weight polyorganosiloxanes containing at least two unsaturated groups in the molecule; (b) 0.1-15% by weight polyorganohydrogensiloxanes containing at least two SiH groups in the molecule; (c) 0.01-2.0% by weight noble metal catalyst; and (d) 0.1-5% by weight of a non-toxic antimicrobial additive or a combination of at least two non-toxic antimicrobial additives.Type: GrantFiled: October 16, 2006Date of Patent: May 18, 2010Assignee: Dreve-Otoplastik GmbHInventors: Thomas Veit, Martin Klare, Michael Kutschinski, Reiner Altmann
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Patent number: 7699337Abstract: Provided is a liquid silicone rubber coating agent composition, including: (A) an organopolysiloxane containing at least one alkenyl group bonded to a silicon atom within each molecule, (B) a straight-chain organohydrogenpolysiloxane containing a single silicon atom-bonded hydrogen atom only at each molecular chain terminal, with a viscosity at 25° C. within a range from 0.001 to 1.0 Pa·s, (C) an organohydrogenpolysiloxane containing at least three silicon atom-bonded hydrogen atoms within each molecule, with a viscosity at 25° C. within a range from 0.001 to 10 Pa·s, (D) an addition reaction catalyst, (E) a finely powdered silica with a BET specific surface area of at least 50 m2/g, and (F) an adhesion imparting agent. Also provided is a curtain air bag with a rubber coating layer formed by curing this composition.Type: GrantFiled: February 3, 2006Date of Patent: April 20, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masayuki Ikeno, Hidenori Mizushima
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Patent number: 7687563Abstract: A silicone rubber emulsion composition comprising (A) 100 parts diorganopolysiloxane having at least two silicon-bonded alkenyl groups, (E) 0 to 60 parts reinforcing silica filler, (B) 10 to 250 parts water containing a smectite clay, (C) 0.1 to 15 parts emulsifier, and (D) a cross-linking agent (e.g., an organohydrogenpolysiloxane) in an amount sufficient for cross-linking component (A) and a catalyst (e.g., a platinum-type catalyst). A method for preparing the aforementioned emulsion composition comprising mixing components (A) and (E) with other components in a high-speed stirrer-equipped mixer. A method of manufacturing a silicone rubber comprising either heating and dehydrating the aforementioned emulsion composition.Type: GrantFiled: May 21, 2004Date of Patent: March 30, 2010Assignee: Dow Corning Toray Company, Ltd.Inventors: Shinya Shirasaki, Tadanori Fukamachi, Mitsuo Hamada
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Patent number: 7683125Abstract: A method of manufacturing a silicone rubber comprises a first stage and a second stage. The first stage comprises (1-1) the step of preparing an aqueous dispersion composed of water that contains a water-soluble polymer (E), a finely powdered silica filler (B), a conductive filler (C), and a non-conductive inorganic filler (D) and (1-2) the step of preparing an aqueous emulsion by stirring and mixing the obtained aqueous dispersion with the following components: an organopolysiloxane (A) that contains silicon-bonded alkenyl groups, an emulsification agent (F), and a curing agent (G). The second stage obtains the silicon rubber either (2-1) by curing the aqueous emulsion prepared in the aforementioned first stage, forming a wet silicone-rubber like cured body, and then removing water from the aforementioned wet silicone-rubber like cured body; or (2-2) by dehydrating and curing the aqueous emulsion prepared in the aforementioned first stage.Type: GrantFiled: February 24, 2004Date of Patent: March 23, 2010Assignee: Dow Corning Toray Company, Ltd.Inventors: Shinya Shirasaki, Tadanori Fukamachi, Mitsuo Hamada
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Patent number: 7641980Abstract: A liquid silicone rubber coating composition comprising (A) an organopolysiloxane containing silicon-bonded alkenyl radicals, (B) an organohydrogenpolysiloxane containing SiH radicals, (C) an addition reaction catalyst, (D) finely divided silica, (E) an organosilicon compound containing epoxy and alkoxy radicals, (F) an organic titanium, zirconium or aluminum compound, and (G) a silanol-containing silane or siloxane compound is coated on a surface of an airbag base fabric and cured to form a rubber coating layer thereon. The composition is suited for curtain airbags.Type: GrantFiled: June 5, 2008Date of Patent: January 5, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masayuki Ikeno, Tsutomu Nakamura, Hidenori Mizushima, Shigeru Ubukata, Daichi Todoroki, Takashi Tanaka
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Patent number: 7619043Abstract: Defoaming compositions employing organopolysiloxanes bearing aryl radicals exhibit surprising efficiency relative to their alkyl counterparts.Type: GrantFiled: August 4, 2005Date of Patent: November 17, 2009Assignee: Wacker Chemie AGInventors: Holger Rautschek, Richard Becker, Willibald Burger
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Publication number: 20090208660Abstract: The invention concerns the general field of high speed silicone coating on various flexible cylinders, such as paper or synthetic polymer (polyolefin, polyester), or textile sheets. The invention concerns an efficient method for controlling the onset of fog when coating flexible supports with a liquid silicone composition precursor of crosslinked coatings, said coating being performed using a cylinder-type coating device operating at a high speed.Type: ApplicationFiled: December 8, 2006Publication date: August 20, 2009Applicant: Bluestar Silicones FranceInventors: Nathalie Guennouni, Tania Ireland, Lucile Gambut-Garel, Etienne Fleury, Didier Dhaler
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Publication number: 20090131585Abstract: Organosilicon compounds having units of the formula RdXeSiY(4-d-e)/2??(I), where X is OH or a hydrolyzable radical and Y is a divalent hydrolyzable radical are useful in crosslinkable compositions, in particular in compositions crosslinkable via a condensation reaction, preferably as sealing compounds.Type: ApplicationFiled: December 17, 2007Publication date: May 21, 2009Applicant: WACKER CHEMIE AGInventor: Marko Prasse
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Patent number: 7528209Abstract: A curable silicone composition which comprises (A) a diorganopolysiloxane which has a viscosity of about 50 to 500 mPa·s at 25° C. and has silicon-bonded alkenyl groups only at the molecular chain ends, (B) a diorganopolysiloxane which has a viscosity of about 50,000 to 500,000 mPa·s at 25° C. and has silicon-bonded alkenyl groups only at the molecular chain ends, (C) an organohydrogenpolysiloxane which has at least eight silicon-bonded hydrogen atoms per molecule and has a viscosity of about 3 to 15 mPa·s at 25° C., and (D) a catalytic amount of a platinum-group metal catalyst as essential components, wherein said composition has a viscosity of about 100 to 1,000 mPa·s at 25° C.; and a sheet having a releasability comprising a cured coating film of the composition.Type: GrantFiled: October 27, 2005Date of Patent: May 5, 2009Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Hideyuki Ito
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Patent number: 7479522Abstract: High tear strength, low hardness silicone elastomer-forming composition is provided using a unique combination(s) of polyorganosiloxanes and organohydrogenpolysiloxanes, where the polyorganosiloxanes and the organohydrogenpolysiloxanes contain both straight-chain and resinous polyorganosiloxanes.Type: GrantFiled: November 9, 2005Date of Patent: January 20, 2009Assignee: Momentive Performance Materials Inc.Inventor: Aijun Zhu
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Publication number: 20080287603Abstract: Provided is an addition curing silicone composition for CIPG, including: (A) 100 parts by mass of an organopolysiloxane containing at least two alkenyl groups bonded to silicon atoms within each molecule, (B) an organohydrogenpolysiloxane, in sufficient quantity to provide from 0.4 to 10.0 mols of hydrogen atoms bonded to silicon atoms within this component (B) for every 1 mol of alkenyl groups bonded to silicon atoms within the entire composition, (C) an effective quantity of a platinum group metal-based catalyst, (D) a curing retarder, and (E) an acid-receiving agent which is inorganic. The composition yields a cured product with particularly superior compression set, and exhibits excellent storage stability, curing stability (curability following storage), and adhesion.Type: ApplicationFiled: July 25, 2008Publication date: November 20, 2008Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Hiroyasu HARA
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Patent number: 7307122Abstract: A silicone rubber coating composition which cures into a silicone rubber having a tear strength of 25-50 kN/m and a peeling bond strength of 30-60 N/cm is suited for coating of hollow weave type air bags. A hollow weave type air bag coated with the coating composition can be instantaneously inflated while the bag prevents the silicone rubber film from being peeled from the base fabric, eliminates inflating gas leakage, and retains an acceptable inflation time.Type: GrantFiled: June 27, 2005Date of Patent: December 11, 2007Assignee: Shin-Estu Chemical Co., Ltd.Inventors: Masayuki Ikeno, Atsushi Yaginuma, Syuichi Azechi, Takeshi Miyao
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Publication number: 20070208132Abstract: The invention relates to crosslinkable compositions (V) containing (A) linear organopolysiloxanes (A) having alkenyl groups, (B) linear organopolysiloxanes (B) which have diorganosilyloxy units and Si—H groups and are obtainable by a cohydrolysis process in which diorganodichlorosilanes and monochlorosilanes and optionally dichlorosilanes, at least the monochlorosilanes or dichlorosilanes containing Si—H groups, are hydrolyzed with water, and (C) catalysts (C) promoting the addition of Si—H groups at an aliphatic carbon-carbon double bond.Type: ApplicationFiled: February 22, 2007Publication date: September 6, 2007Applicant: WACKER CHEMIE AGInventors: Gilbert Geisberger, Hans Lautenschlager
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Patent number: 7241835Abstract: Methods for making homogenized cosmetic formulations comprising a silicone gel.Type: GrantFiled: May 16, 2003Date of Patent: July 10, 2007Assignee: General Electric CompanyInventors: Michael Joseph O'Brien, Suresh K. Rajaraman
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Patent number: 7223802Abstract: It is an object of the present invention to provide a high order silane composition that contains a polysilane having a higher molecular weight than conventionally, this being from the viewpoints of wettability when applying onto a substrate, boiling point and safety, and hence in particular enables a high-quality silicon film to be formed easily, and also a method of forming an excellent silicon film using the composition. The present invention attains this object by providing a high order silane composition containing a polysilane obtained through photopolymerization by irradiating a solution of a photopolymerizable silane or a photopolymerizable like-liquid silane with ultraviolet light. Moreover, the present invention provides a method of forming a silicon film comprising the step of applying such a high order silane composition onto a substrate.Type: GrantFiled: April 22, 2003Date of Patent: May 29, 2007Assignees: Seiko Epson Corporation, JSR CorporationInventors: Takashi Aoki, Masahiro Furusawa, Yasuo Matsuki, Haruo Iwasawa, Yasumasa Kateuchi
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Patent number: 7132170Abstract: An adhesive coating composition for fabric substrates, such as automotive airbags. The coating is formed from a blend including a silicone polymer and a second polymer which is thermodynamically compatible with silicone. In particular, the second polymer has a cohesion parameter (?/MPa1/2) that is similar to that of silicone so that any thermodynamic barrier to the second polymer dissolving in silicone is removed.Type: GrantFiled: July 29, 2003Date of Patent: November 7, 2006Assignee: Milliken & CompanyInventor: Richard Henry Parker
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Patent number: 7101643Abstract: New polymer electrolytes were prepared by in situ cross-linking of allyl functional polymers based on hydrosilation reaction using a multifunctional silane cross-linker and an organoplatinum catalyst. The new cross-linked electrolytes are insoluble in organic solvent and show much better mechanical strength. In addition, the processability of the polymer electrolyte is maintained since the casting is finished well before the gel formation.Type: GrantFiled: May 31, 2002Date of Patent: September 5, 2006Assignee: The Regents of the University of CaliforniaInventors: John Borland Kerr, Shanger Wang, Jun Hou, Steven Edward Sloop, Yong Bong Han, Gao Liu
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Patent number: 7090923Abstract: The present invention relates to curable alkenyl based silicone release coating compositions having improved adhesion to paper and polymeric substrates. Furthermore the present invention relates to the process for making a silicone release coating with improved adhesion to paper and polymeric substrates.Type: GrantFiled: February 12, 2003Date of Patent: August 15, 2006Assignee: General Electric CorporationInventors: Roy Melvin Griswold, Richard Paul Eckberg, Slawomir Rubinsztajn, Stanislaw Slomkowski, Anna Kowalewska, Stanislaw Sosnowski
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Patent number: 7059627Abstract: A silicone rubber coating composition which cures into a silicone rubber having a tear strength of 25–50 kN/m and a peeling bond strength of 30–60 N/cm is suited for coating of hollow weave type air bags. A hollow weave type air bag coated with the coating composition can be instantaneously inflated while the bag prevents the silicone rubber film from being peeled from the base fabric, eliminates inflating gas leakage, and retains an acceptable inflation time.Type: GrantFiled: May 7, 2003Date of Patent: June 13, 2006Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masayuki Ikeno, Atsushi Yaginuma, Syuichi Azechi, Takeshi Miyao
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Patent number: 7005475Abstract: The present invention relates to curable silicone coating compositions having improved adhesion to polymeric substrates. The present invention also relates to additives that improve adhesion of silicone pressure sensitive adhesive coating compositions to polymeric substrates. Furthermore the present invention relates to the process for making a silicone pressure sensitive adhesive coating with improved adhesion to polymeric substrates.Type: GrantFiled: June 10, 2003Date of Patent: February 28, 2006Assignee: General Electric CompanyInventor: Roy Melvin Griswold
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Patent number: 6962752Abstract: A curable composition comprising: (A) a branched polyfluorodialkenyl compound represented by a general formula (1): CH2?CH—(X)a-Rf1-(X?)a—CH?CH2??(1) wherein, X and X? are bivalent groups such as —CH2— and —CH2O—, a represents, independently, either 0 or 1, and Rf1 is a specific bivalent fluorine-containing group, (B) a branched polyfluoromonoalkenyl compound represented by a general formula (2): Rf2-(X?)a—CH?CH2??(2) wherein, X? and a are as defined above, and Rf2 is a specific fluorine-containing group, (C) an organohydrogensiloxane compound with at least two hydrogen atoms bonded to silicon atoms, and (D) a platinum group metal catalyst; as well as a low bleeding gel type cured product obtained by curing such a composition, and an electrical or electronic component sealed or encapsulated using such a cured product. The gel type cured product displays very little bleeding of free oil constituents from the gel as a result of stress such as pressure fluctuation or heat history.Type: GrantFiled: January 9, 2003Date of Patent: November 8, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kenichi Fukuda, Mikio Shiono
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Patent number: 6884660Abstract: The present invention relates to a thermoconducting silicone composition having a viscosity at 25° C. before curing of 10-1,000 Pa·s, a method of installing the composition, and a heat dissipating structure comprising the silicone composition.Type: GrantFiled: December 11, 2002Date of Patent: April 26, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroaki Tetsuka, Kunihiro Yamada, Kunihiko Mita
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Patent number: 6881416Abstract: Organopolysiloxane gel products having a variety of physical forms and which produce a silky feel when applied to the skin are prepared by reacting an unsaturated organopolysiloxane resin, an Si—H functional organosiloxane crosslinker bearing pendant hydrido functionality, a C4 or higher unsaturated hydrocarbon, and optionally, an unsaturated hydrophile component. Products ranging from viscous liquids, creamy gels, pastes, and soft powders may be obtained. The products are highly useful in formulating cosmetic and pharmaceutical products.Type: GrantFiled: April 8, 2002Date of Patent: April 19, 2005Assignee: Wacker Chemical CorporationInventor: Bryan E. Fry
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Patent number: 6878773Abstract: In a process for the preparation of an emulsion of a silicone organic block copolymer in water, a polydiorganosiloxane having terminal reactive groups (A), an organic material having terminal groups (B) which are reactive with the groups (A) and a catalyst are emulsified in water with a surfactant and the resulting emulsion is subjected to conditions under which the reaction between groups (A) and (B) proceeds in the presence of the catalyst, thereby forming a copolymer chain containing polysiloxane blocks and blocks of organic material. Preferred emulsions comprise a copolymer comprising polydiorganosiloxane blocks and organic blocks, having a viscosity in the range 10 to 1000000 Pa.s and a mean particle size of 0.3 to 1000 micrometers.Type: GrantFiled: January 30, 2001Date of Patent: April 12, 2005Assignee: Dow Corning S.A.Inventors: Leon Andre Marteaux, Anne-Lise Girboux
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Patent number: 6838499Abstract: A curable composition comprising a liquid base polymer, a silicone elastomer powder, and a crosslinking agent is in putty form prior to curing, tack-free to the hand, easy to work, and adherent.Type: GrantFiled: February 19, 2003Date of Patent: January 4, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Tsuneo Kimura
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Publication number: 20040266945Abstract: A cross-linkable and cross-linked organosilicon polymer which is prepared from a mixture of a reactive polysiloxane resin having both reactive carbon-carbon double bonds and silicone-hydrogen groups, characterized by alternating structures of polycyclic polyene residue and cyclic (or tetrahedral) polysiloxane residue, and either vinyl terminated fluorine-containing polysiloxane or vinyl terminated phenyl-substituted siloxane. In an alternative embodiment, the polymer comprises a mixture of vinyl terminated phenyl-substituted polysiloxane and vinyl functional fluorosilicone elastomer with the cross-linkable and cross linked organosilicon polymer.Type: ApplicationFiled: July 29, 2004Publication date: December 30, 2004Inventors: Elizabeth M. Walker, Jiazhong Luo, Rose Ann Schultz, Katharine Louise Pearce
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Publication number: 20040236014Abstract: To provide a silicone rubber composition for wiper blades, which, due excellent moldability and ability to closely repeat the shape of the die during extrusion, is suitable for forming wiper blades of complicated shapes; to provide a method of manufacturing the aforementioned composition. A silicone rubber composition for a wiper blade comprising (A), a polydiorganosiloxane, (B) a finely divided, reinforcing silica filler, (C) orthoboric acid or inetaboric acid, (D) a powdered calcium carbonate, (E) an organic peroxide curing agent, and an additive for improving water-repellent properties of a wiper blade made from said composition, comprising one or both of (F) a polyorganosiloxane having a viscosity of 1 to 10000 mPa·s and containing in one molecule at least two silicon-bonded hydrogen atoms and (G) a polydiorganosiloxane having a viscosity of 1 to 10000 mPa·s; a method of manufacturing the aforementioned composition.Type: ApplicationFiled: November 26, 2003Publication date: November 25, 2004Inventors: Kenji Ota, Hiroshi Honma
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Publication number: 20040222618Abstract: Liquid silicone rubber coating compositions which include specific amounts of an organopolysiloxane bearing at least two alkenyl groups, an organohydrogenpolysiloxane bearing at least two silicon-bonded hydrogen atoms, a crosslinking reaction catalyst which is an organic peroxide, a finely divided silica and a tackifier have a good coatability even when not diluted with a solvent. In airbags obtained by coating such a composition onto a woven base fabric and curing the applied composition, the cured coat does not delaminate during airbag inflation, thus minimizing inflator gas leakage and resulting in excellent inflation time sustainability.Type: ApplicationFiled: May 6, 2004Publication date: November 11, 2004Inventors: Syuuichi Azechi, Hidenori Mizushima
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Publication number: 20040209998Abstract: The present invention relates to a biocompatible polymer composition, suitable for in vivo vessel repair, comprising a matrix pre-polymer, a filler and a curing agent, wherein said composition wherein said biocompatible polymer composition is curable in the presence of a curing catalyst at 37° C. to form a cured material with an elongation until rupture of at least 5% and an elastic modulus of at least 1 MPa.Type: ApplicationFiled: January 2, 2004Publication date: October 21, 2004Applicant: Vesalius N.V.Inventor: Alexander Cornelis de Vries
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Publication number: 20040198905Abstract: A solventless method for the preparation of organically modified organopolysiloxanes comprising a hydrosilylation reaction of (A) liquid organopolysiloxane that contains at least one silicon atom-bonded hydrogen atom in each molecule with (B) a non-silicone liquid organic compound that contains at least one aliphatic carbon-carbon double bond in each molecule in the presence of a (C) a hydrosilylation reaction catalyst, where the hydrosilylation reaction is carried out in a dispersion of component (B) in component (A) or of component (A) in component (B) having a microparticulate form of average particle size ≧100 &mgr;m induced by high-shear agitation of components (A) and (B).Type: ApplicationFiled: January 8, 2004Publication date: October 7, 2004Inventors: Hideyuki Mori, Toyohiko Yamadera, Mitsuo Hamada
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Patent number: 6791839Abstract: A composition that can be used to prepare a thermal interface material includes: A) a curable matrix having a curing temperature, B) a metal filler having a low melting point, optionally C) a spacer, and optionally D) a conductive filler. The temperature at which component B) commences softening is less than the curing temperature of component A). A thermal interface material is prepared by: 1) interposing the composition between an electronic component and a heat spreader to form a bondline, 2) heating the composition to a temperature higher than the temperature at which component B) commences softening but less than the curing temperature of component A) and optionally applying pressure to the composition, and 3) heating the composition to a temperature greater than or equal to the curing temperature of component A). The average particle size of component B) is greater than or equal to the bondline thickness.Type: GrantFiled: June 25, 2002Date of Patent: September 14, 2004Assignee: Dow Corning CorporationInventor: Dorab Edul Bhagwagar
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Patent number: 6780518Abstract: A silicone rubber adhesive composition comprising (A) a heat curable organopolysiloxane composition of the addition curing type or peroxide curing type, (B) reinforcing silica fines, and (C) an organic compound or organosilicon compound having an epoxy equivalent of 100-5,000 g/mol and containing at least one aromatic ring in a molecule is easily moldable within a short time by injection molding, suitable in primerless molding, and bondable with various thermoplastic resins. Integrally molded articles in which the silicone rubber adhesive composition is firmly bonded to the thermoplastic resin are obtainable without a need for modification of the resin.Type: GrantFiled: January 4, 2002Date of Patent: August 24, 2004Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Syuuichi Azechi, Naoki Yamakawa