Polymer Derived From Ethylenic Reactants Only Derived From Reactant Containing An Alcohol Or Ether Group (includes Phenols) Patents (Class 525/118)
  • Patent number: 5585221
    Abstract: An active energy ray-curing resin composition comprises a graft copolymerized polymer and at least one of a monomer having an ethylenically unsaturated bond and a partially esterified epoxy resin.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: December 17, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5565525
    Abstract: A resin composition curable through a Michael reaction between (a) a component having a plurality of .alpha., .beta.-unsaturated carbonyl groups and (b) a component having a plurality of activated methylene, activated methyne or hydroxyl groups is disclosed. The curing reaction is catalyzed with a quaternary ammonium, quaternary phosphonium or tertiary sulfonium salt in the presence of an epoxy compound independently added to the composition or covalently attacted to either component (a) or component (b).
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: October 15, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hideo Morimoto, Kei Aoki, Takashi Irie, Hiroto Yoneda
  • Patent number: 5552486
    Abstract: Propoxylated allyl alcohol homopolymers and copolymers of allyl alcohol and propoxylated allyl alcohol are disclosed. The polymers are soluble in many organic solvents, making them useful in a variety of applications, including polyesters, polyurethanes, alkyds, uralkyds, polyamines, acrylates, crosslinked polymeric resins, and polymer blends.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: September 3, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Shao-Hua Guo, Robert G. Gastinger
  • Patent number: 5543266
    Abstract: An active energy ray-curing resin composition comprises (i) a graft copolymerized polymer, (iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule and (iv) a polymerization initiator capable of generating a Lewis acid by irradiation of an active energy ray.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: August 6, 1996
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5543483
    Abstract: Hydroxy-functional allyl terpolymers are disclosed. The terpolymers comprise recurring units of an allyl ester, an allylic alcohols or propoxylated allylic alcohol, and a vinyl monomer. The high hydroxyl group content and favorable solubility characteristics make the terpolymers easy to formulate into many polymer products, including polyurethanes, polyesters, melamines, alkyds, uralkyds, and other thermoset polymers.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: August 6, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Shao-Hua Guo
  • Patent number: 5539064
    Abstract: A resist ink composition developable with a diluted, alkaline solution, which exhibits high dispersion stability itself, can form a pattern with excellent resolution, even in the case of a low exposure amount, and can produce a cured resist film excellent in solvent resistance for high-performance printed circuits and which comprises an ultraviolet-curable resin obtained by copolymerizing (a) from 5 to 50% by weight of an ethylenically unsaturated monomer of a general formula: ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group; R.sub.2 represents a hydrogen atom or an alkyl group; n represent an integer of from 1 to 4, and/or glycerol mono(meth)acrylate, (b) from 10 to 90% by weight or glycidyl (meth)acrylate and (c) from 0 to 80% by weight of other ethylenically unsaturated monomers capable of copolymerizing with these (a) and (b), followed by reacting the resulting copolymer with from 0.7 to 1.
    Type: Grant
    Filed: September 12, 1995
    Date of Patent: July 23, 1996
    Assignee: Goo Chemical Industries Co., Ltd.
    Inventors: Soichi Hashimoto, Satoshi Miyayama, Toshiaki Nishimura, Toshikazu Oda
  • Patent number: 5525673
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: June 11, 1996
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5476752
    Abstract: An active energy ray-curing resin composition comprises:(i) a linear polymer having a glass transition temperature of 50.degree. C. or higher and a weight average molecular weight of about 3.0.times.10.sup.4 or higher;(ii) a monomer having an ethylenically unsaturated bond;(iii) an epoxy resin comprising at least one compound having one or more epoxy groups in the molecule; and(iv) a polymerization initiator capable of generating a Lewis acid by irradiation with an active energy ray.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: December 19, 1995
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5464885
    Abstract: An aqueous dispersed acrylic grafted epoxy-ester polymer useful as a polymeric binder for protective coatings is produced by first forming a carboxyl functional epoxy-ester by esterifying a low molecular weight epoxy resin with a low molecular weight, unsaturated, carboxyl terminated polyester, followed by in-situ copolymerizing ethylenic monomers in the presence of water-dispersed epoxy-ester.
    Type: Grant
    Filed: April 4, 1994
    Date of Patent: November 7, 1995
    Assignee: The Glidden Company
    Inventor: Gary P. Craun
  • Patent number: 5453323
    Abstract: Super-absorbent polymers having superior dryness properties when incorporated into absorbent articles are made from acrylic acid and crosslinking agent polymerized under controlled conditions.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: September 26, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Douglas R. Chambers, Hubert H. Fowler, Jr., Yoji Fujiura, Fusayoshi Masuda
  • Patent number: 5412002
    Abstract: An epoxy resin composition contains an epoxy resin represented by the formula (I) and a curing accelerator: ##STR1## wherein R.sup.1 stands for ##STR2## where G stands for a glycidyl group, R.sup.2 stands for an alkyl group having 1 to 4 carbon atoms, R.sup.3 and R.sup.4 stand for the same or different groups and each denote a hydrogen atom or a glycidyl group, m and x each denote an integer of 0 to 10, n denotes an integer of 0 to 2, provided that m.gtoreq.x and, if m=0, then x=0, in which case at least one of R.sup.3 and R.sup.4 denotes a glycidyl group on the condition that when m.gtoreq.1 and m>x, R.sup.1 may each stand for different groups.
    Type: Grant
    Filed: December 9, 1992
    Date of Patent: May 2, 1995
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Masami Enomoto, Susumu Kubota, Hitoshi Yuasa, Fumiaki Oshimi, Yutaka Otsuki
  • Patent number: 5408001
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: April 18, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5389727
    Abstract: A resin composition comprising a high molecular weight compound containing an average of 2 or more hydroxyl groups and an average of 1 or more functional groups selected from the class consisting of alkoxysilane, silanol and acyloxysilane groups per molecule and having a number average molecular weight of 3,000 to 200,000; a low molecular weight compound containing an average of 2 or more epoxy groups per molecule and having a number average molecular weight of 240 to 5,000; and, as a curing catalyst, a metal chelate compound, is curable at a relatively low temperature to yield a film having excellent resistance to weathering.
    Type: Grant
    Filed: August 27, 1993
    Date of Patent: February 14, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Noboru Nakai, Osamu Isozaki, Naozumi Iwasawa
  • Patent number: 5369144
    Abstract: An adhesive composition for adhering an artificial nail to the nail comprising 2-methoxyisopropyl .alpha.-cyanoacrylate, and a copolymer of a specified alkyl acrylate or alkyl methacrylate and a specified fluorinated alkyl acrylate or fluorinated alkyl methacrylate. The composition is very low in exothermic temperature and has satisfactory properties to permit the artificial nail to be peeled off easily within a short period of time.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: November 29, 1994
    Assignee: Ohara Paragium Chemical Co., Ltd.
    Inventors: Hiroshi Uemura, Ethuo Yosida, Shin Iwaki
  • Patent number: 5344881
    Abstract: A rubber composition which is vulcanizable with organic peroxides and provides vulcanized rubber excellent in oil resistance, heat resistance, low-temperature resistance and compression set.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: September 6, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Keisaku Yamamoto, Yoshio Tanimoto, Masahiro Fukuyama, Noriyasu Yasuda
  • Patent number: 5342887
    Abstract: The invention relates to a thermoplastic elastomer composition comprising a) a polyolefin and b) a crosslinked ethylene copolymer, the crosslinks between the main chains of the molecules of which have been formed of the hetero groups of at least two comonomer units being in different main chains and at least two hetero groups of the crosslinking-agent molecule being chemically attached to each other. The problem of such a mixture is that the lipophilic thermoplastic polyolefin and the ethylene copolymer to be crosslinked with its polar hetero groups are not compatible. Now, the problem has been solved by forming the crosslinks between the main chains so that either the hetero group of the comonomer unit in the main chain or then the hetero group of the crosslinking agent molecule always is a hydroxyl group, the hydroxyl group always forming a permanent oxygen crosslink bond with the other hetero group attached to it.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: August 30, 1994
    Assignee: Neste Oy
    Inventors: Christer Bergstrom, Gunilla Krook
  • Patent number: 5317067
    Abstract: The present invention provides an epoxy resin composition which is obtained by melt-mixing 100 parts by weight of an epoxy resin with 3 to 33 parts by weight of a thermoplastic resin alone or in combination with other components and additives than a hardener in the first mixing step and then with a hardener alone or in combination with other components and additives in the second mixing step, said epoxy resin having a number-average molecular weight of at least 200 and lower than 5000 and said thermoplastic resin having a number-average molecular weight of at least 5000; an adhesive epoxy resin molded article which is obtained by molding said epoxy resin composition; a process for producing an adhesive epoxy resin molded article which comprises molding said epoxy resin composition into a 0.01 to 10 mm thick film or sheet in a substantially uncured state and subsequently punching the film or sheet at temperatures higher than 15.degree. C. and lower than 70.degree. C.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: May 31, 1994
    Assignee: Tokyo Tire & Rubber Company Limited
    Inventors: Koji Yagi, Seiichi Fukunaga
  • Patent number: 5300573
    Abstract: Thermoplastic elastomer compositions comprise a blend of polyester resin and a covalently-crosslinked acrylate rubber. Such compositions can be prepared by dynamic vulcanization of the rubber in admixture with the polyester and can exhibit high temperature dimensional stability and low oil swell.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: April 5, 1994
    Assignee: Advanced Elastomer Systems, L.P.
    Inventor: Raman Patel
  • Patent number: 5288770
    Abstract: A resin composition for a cationically electrodepositable paint comprising(A) a resin having hydroxyl groups and cationic groups,(B) an epoxy resin having at least 2 epoxy functional groups each of which comprises an epoxy group directly bound to an alicyclic ring and/or bridged alicyclic ring on average per molecule, and(C) a finely divided gelled polymer as principal components, wherein said finely divided gelled polymer is obtained by emulsion polymerizing(C-1) a polymerizable monomer containing at least two radically polymerizable unsaturated groups in the molecule, and(C-2) a radically polymerizable unsaturated monomer other than the one mentioned in (C-1), abovein the presence of a reactive emulsifier containing an allyl group in the molecule.
    Type: Grant
    Filed: January 22, 1991
    Date of Patent: February 22, 1994
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Teiji Katayama, Eisaku Nakatani, Haruo Nagaoka, Kenji Yamamoto, Reiziro Nishida
  • Patent number: 5280068
    Abstract: Curable epoxy resins are toughened with statistical monofunctional carboxyl, amine or epoxy terminated reactive polymers and have low viscosities before cure thereby making them useful in a wide range of applications. The cured epoxy resin systems which are modified by the statistical monofunctional reactive polymers have physical properties, such as adhesion and elongation, generally equal to or better than those of cured epoxy resin systems modified with statistical difunctional reactive polymers. A process of preparation for the modified epoxy resin systems of the present invention includes admixing an epoxy resin with a statistical monofunctional carboxyl, amine, or epoxy-terminated reactive polymer in the presence of a curing agent and reaction therewith to form the toughened, cured epoxy resin system.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: January 18, 1994
    Assignee: The B.F. Goodrich Company
    Inventors: Alan R. Siebert, Robert J. Bertsch
  • Patent number: 5268428
    Abstract: The present invention relates to binder compositions containingA) 10 to 99 parts by weight of a copolymer component containing at least one copolymer prepared from olefinically unsaturated compositions having a weight average molecular weight of 1,500 to 75,000 and having in chemically bound form both(i) 1 to 30% by weight of cyclic carboxylic anhydride groups (calculated as C.sub.4 H.sub.2 O.sub.3) and(ii) 1 to 29% by weight of epoxide groups (calculated as C.sub.2 H.sub.3 O) andB) 1 to 90 parts by weight of a hydroxyl component containing at least one organic polyol having at least two hydroxyl groups per molecule,provided that for every anhydride group of component A) there are 0.1 to 10 hydroxyl groups of component B).
    Type: Grant
    Filed: August 21, 1991
    Date of Patent: December 7, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Harald Blum, Josef Pedain
  • Patent number: 5260376
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: November 9, 1993
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5227243
    Abstract: Coating compositions which comprise: (i) a hydroxy-functional compound containing in the molecule an average of at least two hydroxyl groups; (ii) an anhydride-functional compound containing in the molecule an average of at least two cyclic carboxylic acid anhydride groups; and (iii) an epoxy-functional compound containing in the molecule an average of at least two cycloaliphatic epoxy groups, provide low temperature cure response and excellent durability.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: July 13, 1993
    Assignee: The Sherwin-Williams Company
    Inventors: Mohamad D. Shalati, James A. Marquart, John R. Babjak, Rodney M. Harris
  • Patent number: 5219939
    Abstract: The present invention relates to powder coating compositions which are solid below 3O.degree. C. and contain a mixture ofA) a copolymer component which is solid below 3O.degree. C. and contains at least one copolymer containing both cyclic carboxylic anhydride groups and hydroxyl groups,B) a polyepoxide component which contains at least one polyepoxide containing at least two epoxide groups per molecule.
    Type: Grant
    Filed: August 21, 1991
    Date of Patent: June 15, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Hans-Joachim Kreuder
  • Patent number: 5218018
    Abstract: A thermosetting coating composition comprising as essential components:(a) a hydroxyl group-containing base resin,(b) an alicyclic polyepoxide crosslinking agent, and(c) a catalyst selected from the group consisting of a quaternary ammonium hydroxide and a metal chelate.
    Type: Grant
    Filed: December 31, 1990
    Date of Patent: June 8, 1993
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Akira Tominaga, Reiziro Nishida, Hiroshi Inoue, Motoshi Yabuta, Yoshio Sasaki, Akira Kasari, Hiroshi Igarashi, Tohru Ozaki
  • Patent number: 5218045
    Abstract: Coating compositions comprising liquid crystalline binders are provided by a combination of mesogenic groups and amorphous resins. The mesogenic groups are either covalently bonded or cross-linked to the amorphous resins to provide coatings of exceptional hardness and toughness. Also provided is an economical process suitable for commercial manufacture of mesogenic compounds and more particularly for the production of liquid-crystalline oligoester polyols.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: June 8, 1993
    Assignee: North Dakota State University
    Inventors: Frank N. Jones, Der-Shyang Chen, Adel F. Dimian, Daozhang Wang
  • Patent number: 5216094
    Abstract: The present invention provides a curable resin coating composition consisting essentially of:(i) a resin (A) containing .alpha.,.beta.-unsaturated carbonyl group and primary and/or secondary hydroxyl group, or(ii) a mixture of a resin (B) containing .alpha.,.beta.-unsaturated carbonyl group and a resin (C) containing primary and/or secondary hydroxyl group, and(iii) at least one curing catalyst selected from the group consisting of alkali metal alkoxides, metal hydroxides, organic acid salts of metals, quaternary ammonium hydroxides, quaternary phosphonium hydroxides, tertiary sulfonium hydroxides and organic acid salts of these onium hydroxides.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: June 1, 1993
    Assignee: Kansai Paint Company, Limited
    Inventors: Osamu Isozaki, Naozumi Iwasawa
  • Patent number: 5212261
    Abstract: Latent, heat-curable epoxy resin compositions containing metal carboxylate curing systems provide exceptional latency, particularly at elevated temperature, as well as facile curing, high T.sub.g and adhesive strength, and other attractive properties. The metal carboxylates comprise alkali metals and alkaline earth metals, aromatic and aliphatic metal carboxylates. The preferred curing systems comprise synergistic combinations of the metal carboxylates with cure modifiers.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: May 18, 1993
    Assignee: Henkel Research Corporation
    Inventor: Thomas J. Stierman
  • Patent number: 5194493
    Abstract: A polymer polyol composition comprising a continuous phase, a disperse phase within the continuous phase, and a dispersant to enhance the stability of the polymer polyol is disclosed. The dispersant is a grafted polyol-polyacrylate dispersant comprised of a isocyanate vinyl monomer/ethylenically unsaturated monomer random copolymer and a polyoxyalkylene polyether, wherein the random copolymer and the polyoxyalkylene polyether are connected through at least one urethane graft site.Methods of preparing the polymer polyol composition and the grafted polyol-polyacrylate dispersant are provided. The polymer polyol compositions have low viscosities as well as high stability and may be prepared with high levels of dispersed vinyl polymer and high styrene:acrylonitrile ratios in the dispersed vinyl polymer. The polymer polyol compositions are useful for the preparation of polyurethanes, particularly polyurethane foams.
    Type: Grant
    Filed: November 7, 1991
    Date of Patent: March 16, 1993
    Inventors: John E. Hayes, Robert G. Gastinger
  • Patent number: 5189119
    Abstract: An article coated with a cationically electrodepositable paint composition comprises (A) a resin having hydroxyl and cationic groups, (B) an epoxy resin having at least 2 epoxy groups, each directly bound to an alicyclic ring, and (C) lead hydroxide and/or lead maleate as curing catalyst(s).
    Type: Grant
    Filed: October 21, 1991
    Date of Patent: February 23, 1993
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Reiziro Nishida, Akira Tominaga
  • Patent number: 5179183
    Abstract: Curable compositions based on (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylate polymers. When cured the compositions are, for example, high-quality industrial finishes, sealants or encapsulants.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: January 12, 1993
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Joseph V. Koleske, Donald F. Smith, Jr., Robert J. Weber, Jr.
  • Patent number: 5171765
    Abstract: This application describes a water dispersible polymeric vehicle comprising epoxy polymers having about 5 to 50 weight percent mesogens or a cross-linkable blend of an amine salt of a mesogenic carboxylic acid, cross-linker resin and an epoxy polymer, the mesogenic acid providing about 5 to 50 weight percent mesogenic groups to the blend.
    Type: Grant
    Filed: May 8, 1991
    Date of Patent: December 15, 1992
    Assignee: North Dakota State University
    Inventors: Frank N. Jones, Daozhang Wang, Steven L. Kangas, Der-Shyang Chen, Adel F. Dimian
  • Patent number: 5166265
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: March 1, 1990
    Date of Patent: November 24, 1992
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5162438
    Abstract: In an adhesive for printed circuit boards, whose main components are an epoxy resin and a polymer rubber, the improvement wherein the polymer rubber is a hydrogenated conjugated diene polymer rubber having not more than 100 ppm of metal content, not more than 100 ppm of ion content as determined by ion chromatography, and an iodine value of not more than 120, the ratio by weight of the hydrogenated conjugated diene polymer rubber to the epoxy resin in the adhesive being 35-75 weight % to 65-25 weight %.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: November 10, 1992
    Assignee: Nippon Zeon Co., Ltd.
    Inventor: Suguru Tsuji
  • Patent number: 5162439
    Abstract: In an adhesive for printed circuit boards, whose main components are an epoxy resin and a polymer rubber, the improvement wherein the polymer rubber is a hydrogenated conjugated diene polymer rubber having not more than 100 ppm of metal content, not more than 100 ppm of ion content as determined by ion chromatography, and an iodine value of not more than 120.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: November 10, 1992
    Assignee: Nippon Zeon Co., Ltd.
    Inventor: Suguru Tsuji
  • Patent number: 5140068
    Abstract: Curable epoxy resins are toughened with statistical monofunctional carboxyl, amine or epoxy terminated reactive polymers and have low viscosities before cure thereby making them useful in a wide range of applications. The cured epoxy resin systems which are modified by the statistical monofunctional reactive polymers have physical properties, such as adhesion and elongation, generally equal to or better than those of cured epoxy resin systems modified with statistical difunctional reactive polymers. A process of preparation for the modified epoxy resin systems of the present invention includes admixing an epoxy resin with a statistical monofunctional carboxyl, amine, or epoxy-terminated reactive polymer in the presence of a curing agent and reaction therewith to form the toughened, cured epoxy resin system.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: August 18, 1992
    Assignee: The B. F. Goodrich Company
    Inventors: Alan R. Siebert, Robert J. Bertsch
  • Patent number: 5120795
    Abstract: A) 100 parts by weight of at least one finely divided plastic which consists ofa) from 30 to 100% by weight of methyl methacrylate (monomer I),b) from 0 to 70% by weight of an acrylate of a C.sub.1 -C.sub.8 alkanol or of a methacrylate of a C.sub.2 -C.sub.8 -alkanol or of a mixture of these monomers (monomers II),c) from 0 to 15% by weight of an .alpha.,.beta.-monoethylenically unsaturated mono- and/or dicarboxylic acid of 3 to 5 carbon atoms (monomers III),d) from 0 to 20% by weight of copolymerizable monomers which contain at least one nitrogen base group and/or one hyroxyl group (monomers IV) ande) from 0 to 5% by weight of other copolymerizable monomers (monomers V), in polymerized form,B) from 30 to 300 parts by weight of at least one polymer which consists ofa) from 5 to 100% by weight of glycidyl acrylate and/or methacrylate (monomers VI),b) from 0 to 95% by weight of an acrylate or methacrylate of a C.sub.1 -C.sub.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: June 9, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Filges, Oral Aydin, Hermann Anders
  • Patent number: 5115025
    Abstract: This invention is directed to polymers (including oligomers) that contain (N-substituted carbamoyloxy)alkanoyloxyalkyl acrylates, to a process for their preparation by reacting the carbamoyloxy alkanoyloxyalkyl acrylates with themselves, with lactone acrylates, and/or with other ethylenically unsaturated monomers, and to coating, ink, adhesive, and sealant compositions (including the cured coatings, inks, adhesives, and sealants) that are obtained by curing the above compositions by various means. The cured compositions, which are, for example, high-quality industrial finishes, sealants or encapsulants, are preferably made by incorporation of various conventional crosslinking agents and other normally-used formulating ingredients with the polymeric compositons of the invention.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: May 19, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Joseph V. Koleske, Donald F. Smith, Jr., Robert J. Weber, Jr.
  • Patent number: 5096984
    Abstract: A cationically electrodepositable paint composition comprises (A) a resin having hydroxyl groups and cationic groups, (B) an epoxy resin having at least two epoxy groups, each directly bound to a (bridged) alicyclic ring, and (C) lead hydroxide and/or lead maleate as curing catalyst(s).
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: March 17, 1992
    Assignee: Kansai Paint Company, Limited
    Inventors: Reiziro Nishida, Akira Tominaga
  • Patent number: 5093391
    Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 5-50% by weight, based on the weight of the binder of an acid functional monomeric, oligomeric or polymeric compound which may or may not contain hydroxyl functionality; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.
    Type: Grant
    Filed: June 15, 1990
    Date of Patent: March 3, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Robert J. Barsotti, Lee R. Harper
  • Patent number: 5091498
    Abstract: The present invention describes the use of 1,3-dialkylimidazole-2-thiones as a catalyst for epoxy/anhydride reactions (and other reactions) and a method of making these catalysts. Epoxy/anhydride coatings containing these improved catalysts offer the following advantages: improved appearance (especially since even weeks after application the coatings still have a "wet" look); better pot-life; improved resistance to alkaline substances which will improve durability; improved solubility; and coatings which have a reduced volatile organic content (VOC).
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: February 25, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Anthony J. Arduengo, III, Robert J. Barsotti, Patrick H. Corcoran
  • Patent number: 5081183
    Abstract: The present invention provides a poly(alpha-ketoester) compound represented by the formula (1); ##STR1## wherein G is a residue of an active hydrogen-containing compound G--(X--H).sub.n, or an alkyl, aryl, aralkyl, alkenyl, alkynyl group having 3 to 20 carbon atoms which may contain oxygen or nitrogen atoms, or a polymeric compound residue, X is an oxygen atom or --CH.sub.2, n is an integer of 3 to 1,000, R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group or an aryl group, and a production thereof.
    Type: Grant
    Filed: January 12, 1990
    Date of Patent: January 14, 1992
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Aoki Kei, Takagawa Ryozo, Tomita Nobuaki, Mori Hirohiko
  • Patent number: 5075378
    Abstract: A multifunctional coating composition comprising a fluorocarbon polymer, an epoxy resin and a fluorinated curing agent resulting in a fluorinated epoxy resin network with improved properties of corrosion resistance and hydrophobicity.
    Type: Grant
    Filed: June 24, 1987
    Date of Patent: December 24, 1991
    Assignee: The Standard Oil Company
    Inventors: Richard C. Smierciak, Paul J. Giordano
  • Patent number: 5068153
    Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; and(c) 0.1-7% by weight, based on the weight of the binder, of a phosphonium catalyst or a blend of a phosphonium catalyst and a tertiary amine catalyst which may or may not contain hydroxyl groups.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: November 26, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Robert Barsotti, Lester S. Cohen
  • Patent number: 5057555
    Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;5-50% by weight, based on weight of the binder, of a polymeric component containing multiple hydroxy groups; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: October 15, 1991
    Inventors: Donald A. White, Robert J. Barsotti, Patrick H. Corcoran, Lili W. Altschuler
  • Patent number: 5043363
    Abstract: An active energy ray-curing resin composition comprises (i) a heat-crosslinkable linear copolymer comprising 5 to 30 mol % of a monomer represented by the general formula I shown below and 5 to 50 mol % of a monomer represented by the general formula II shown below as the copolymer constituents: ##STR1## (wherein R.sup.1 is hydrogen or alkyl or hydroxyalkyl group having 1 to 3 carbon atoms; R.sup.2 is hydrogen or alkyl or acyl group having 1 to 4 carbon atoms which may have a hydroxyl group; R.sup.3 is hydrogen or alkyl group having 1 to 3 carbon atoms; R.sup.4 is a divalent hydrocarbon group which may have internally an ether bond and may also be substituted with halogen atoms; and R.sup.5 is alkyl having 3 to 12 carbon atoms or phenylalkyl group or phenyl group), and (ii) a monomer having an ethylenically unsaturated bond.
    Type: Grant
    Filed: September 12, 1990
    Date of Patent: August 27, 1991
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiromichi Noguchi, Tadayoshi Inamoto, Megumi Munakata
  • Patent number: 5025067
    Abstract: An epoxy resin comprising an active hydrogen compound having at least three active hydrogen atoms capable of reacting with an epoxy group in its molecule or butadine or isoprene as a main monomer is modified with an oligomer having on average at least 1.5 equivalents of active hydrogen capable of reacting with an epoxy group in its molecule. An epoxy resin modified with a bisphenol and a compound having active hydrogen or acid anhydride groups capable of reacting with an epoxy group is also provided. A toner containing the epoxy resin as a binder is useful in electrostatography.
    Type: Grant
    Filed: November 16, 1988
    Date of Patent: June 18, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yohzoh Yamamoto, Goro Suzuki, Hideo Nakamura, Kiyomi Yasuda
  • Patent number: 4980416
    Abstract: A heat-resistant resin composition, comprising (A) 30 to 95% by weight of at least oen unsaturated ester compound selected from the group consisting of (I) unsaturated ester compounds represented by the formula I: ##STR1## wherein R.sup.1 s independently stand for one member selected from the class consisting of ##STR2## wherein R.sup.3 and R.sup.4 independently stand for a hydrogen atom or a methyl group, and a hydrogen atom, and at least one R.sup.1 stands for ##STR3## wherein R.sup.3 and R.sup.4 independently stand for a hydrogen atom or a methyl group, and R.sup.2 s independently stand for an atom or an organic group selected from the class consisting of a hydrogen atom, halogen atoms, a methoxy group, and alkyl groups of 1 to 5 carbon atoms, and m stands for 0 or an integer in the range of 1 to 10, and (II) unsaturated ester compounds represented by the formula II; ##STR4## wherein R.sup.5 s independently stand for one member selected from the class consisting of ##STR5## wherein R.sup.3 and R.sup.
    Type: Grant
    Filed: January 3, 1989
    Date of Patent: December 25, 1990
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Toshio Awaji, Takao Omi, Kenichi Ueda
  • Patent number: 4975474
    Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: December 4, 1990
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert J. Barsotti, Patrick H. Corcoran
  • Patent number: 4908397
    Abstract: A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about(a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000;(b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups;(c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; andthe composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.
    Type: Grant
    Filed: June 27, 1988
    Date of Patent: March 13, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Robert J. Barsotti, Patrick H. Corcoran