Abstract: It is an object of the present invention, which has been made in view of the above-mentioned state of the art, to provide a cement admixture capable of improving the water-reducing ability of cement compositions and the like and enhancing the strength and durability of hardened products produced therefrom and further capable of adjusting the viscosity of such compositions so as to facilitate the works at the sites of handling the same, as well as a method of producing such cement additive. A cement admixture comprising a polycarboxylic acid polymer and a nitrogen atom-containing compound having non-amide bond, wherein the mass ratio (A/B) between the mass (A) of said polycarboxylic acid polymer and the mass (B) of said nitrogen atom-containing compound having non-amide bond satisfies the relation 200>(A/B)>1.

Abstract: A sliding member formed of a resinous material is in sliding contact with a steel member in an automotive internal combustion engine. The resinous material includes a thermoplastic resin composition which includes a fluororesin in an amount ranging from 5 to 40 parts by weight, and a thermoplastic resin other than the fluororesin, in an amount ranging from 95 to 60 parts by weight. The fluororesin contains crosslink formed between at least a part of carbon atoms forming part of a molecule chain of the fluororesin and at least a part of carbon atoms forming part another molecular chain of the fluororesin, and active end group formed at least a part of the molecule chain of the fluororesin.

Abstract: Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 99 weight percent phenolphthalein, based on the total weight of the phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is purified by a combination of techniques to produce a solid comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine with sufficient purity to be used as a monomer in the synthesis of clear polymers.

Abstract: The present invention provides a thermoplastic composition which may be unvulcanized or vulcanized. The thermoplastic composition can be a blend of a thermoplastic engineering resin, a halogenated terpolymer of a C4 to C7 isomonoolefin, a para-alkylstyrene, and a multiolefin. The engineering resin can be a polyamide, such as nylon 6/66 copolymers for example. The isomonoolefin can be an isobutylene for example. The multiolefin can be a C4 to C14 diene, such as isoprene for example.

Abstract: A controlled molecular weight polymer of styrene is provided having bromine substituted thereon. Control of molecular weight is achieved by the use of alph?-methyl styrene dimer as a chain transfer agent. The brominated polymer of styrene is useful as a flame retardant, particularly for polyamides giving improved properties including color retention after molding.

Abstract: A seal ring (10) of the present invention seals operating oil hermetically and is attached to an annular seal ring groove (16) provided on an outer circumference of a shaft member (12). The seal ring (10) includes fluororesin, modified fluororesin formed by being irradiated with an ionizing radiation in a range from 1 kGy to 10 MGy inclusive in a state of being heated up to a melting point thereof or higher under an inert gas atmosphere with an oxygen partial pressure of 1.33 kPa or less, and synthetic resin having a surface energy ranging from +0 N/cm to 20˜10?5 N/cm inclusive of that of the operating oil.

Abstract: A thermoplastic elastomer composition comprising a dynamically vulcanized blend of (A) a partially cured halogenated isobutylene elastomer and (B) a polyamide, wherein a tensile modulus at 100% elongation of the halogenated isobutylene elastomer dispersed in the polyamide matrix is less than 0.60 MPa.

Abstract: A resin comprises a resin containing a vulcanization-activating agent, or crosslinkable group-containing resin (e.g., a resin having an unsaturated bond). Moreover, a composite dispersion may be formed by a combination of a specific resin and rubber [e.g., (a) a combination of a resin, and an unvulcanized rubber containing a vulcanizing agent and a vulcanization-activating agent at a specific ratio; (b) a combination of a polyamide-series resin, and an unvulcanized rubber containing a vulcanizing agent and a polyalkenylene at a specific ratio; (c) a combination of a resin and a silicone-series unvulcanized rubber; and (d) a combination of a polyphenylene ether-series resin containing a polyalkenylene, and an unvulcanized rubber containing a sulfur or sulfur-containing organic compound as a vulcanizing agent].

Abstract: Multilayered pellets are provided that contain an ethylene-vinyl alcohol copolymer (EVOH) and a polyamide resin and that have excellent thermal stability during pelletizing and melt molding. The multilayered pellets each are composed of at least two resin layers and include a resin layer A whose main component is EVOH and a resin layer B whose main component is a polyamide resin. In the multilayered pellets, at least 70 mol % of all the terminals of the polyamide resin are blocked by units each containing an imide structure.

Abstract: A thermoplastic elastomer composition having improved mechanical properties and fatigue resistance comprising (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an amine component selected from tertiary amines and secondary diamines, wherein the elastomers are dispersed as a domain in a continuous phase of the polyamide.

Abstract: A hot melt adhesive composition that includes thermoplastic polyamide, adhesion promoter that includes at least one acid group, and wax having a melting point greater than 82° C.

Abstract: The present invention provides an abrasion resistant composition comprising fluoropolymer and an effective amount of micropulp to increase the abrasion resistance of an article such as a film formed from the composition by at least 25% as compared to film formed from the fluoropolymer by itself. In an especially preferred embodiment, the composition also contains an effective amount of pigment to further increase the abrasion resistance of film formed from the composition as compared to film formed from the fluoropolymer by itself. The invention is especially useful for films formed on a fuser roll.

Abstract: Two-phase or single-phase admixtures of a plastic and an elastomer, two or more thermoplastics, or two or more elastomers are irradiated (preferably with electron beam radiation) to cross-link the thermoplastic and, in the case of elastomer and thermoplastic admixtures, generate bi-modal molecules having moieties derived from both the elastomer and the thermoplastic.

Abstract: Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 95 weight percent phenolphthalein, based on the total weight of phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is then triturated with a trituration solvent and washed to obtain a second solid, wherein the second solid comprises greater than or equal to 97 weight percent 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, based on the total weight of the second solid. The second solid may be polymerized to form a polycarbonate.

Abstract: Embodiments of the present invention may provide a method of preparing biodegradable polyester polymer materials both in a filament type and a sheet type using a compressed gas. The method of the present invention comprises the following steps: 1) preparing biodegradable polyester polymers through a solution-state polymerization process of a cyclic monomer using a compressed gas as a reaction solvent in the presence of a catalyst; 2) performing a flash-spinning process of the biodegradable polyester polymers prepared above to form a polymer material in a filament type; and 3) performing a calendering process of the polymer material in a filament type prepared above to form a polymer material in a point-bonded sheet type.

Abstract: The invention relates to thermoplastic compositions comprising a polymer matrix and an additive which modifies the rheological behavior of the matrix in the molten state. The purpose of the invention is to provide a preferably non-reactive additive which can be dispersed in the matrix and which can be used to obtain a good compromise in terms of rheological properties/mechanical properties. According to the invention, the additive is a hyperbranched polymer which is functionalized by R<2> radicals, R<2> being a radical of the following type: substituted or non-substituted hydrocarbon, of the silicon type, linear or branched alkyl, aromatic, arylalkyl, alkylaryl or cycloaliphatic, which can comprise one or more unsaturations and/or one or more heteroatoms.

Abstract: The present invention provides: a novel water-absorbing agent, which exhibits an excellent absorption capacity under a load (AAP), gel layer liquid permeation rate under a load (FRUP), saline flow conductivity (SFC), and shape-maintaining property and ball burst strength (BBS) of a swollen water-absorbing agent aggregate, and excellent persistency of these effects for a long time. The water-absorbing agent, which comprises a polymer obtained by a process including the steps of polymerizing and then crosslinking a monomer including acrylic acid and/or a salt thereof, with the water-absorbing agent being characterized by: (1) exhibiting a free swelling capacity of not less than 23 g/g (GV), a gel deformation of not more than 12.5 cm under a short-time load (0.5 hrPT), and a gel deformation deterioration of not more than 3.

Abstract: They are mixtures of (a) from 1 to 99.9% by weight of a water-soluble epihalohydrin-crosslinked polyamidoamine and (b) from 0.1 to 20% by weight of at least one other cationic polymer.

Abstract: The invention relates to a process for compounding polycondensates selected from the group consisting of polyamide, polyester and polycarbonate, in the presence of an epoxy-containing styrene and/or (meth)acrylic monomer, of a bisphenol A epoxide or of an epoxy-containing natural oil or fatty acid ester, which comprises carrying out the compounding at temperatures less than/equal to 220° C. and in the presence of an activator selected from the group consisting of: zinc, titanium compound and C1-C12-alkyltriphenylphosphonium halide.

Abstract: A thermoplastic elastomer composition possessing superior air impermeability, excellent durability and flexibility. In particular, the composition includes (A) at least one halogenated isobutylene-containing elastomer; and (B) at least one nylon resin having a melting point of about 170° C. to about 260° C.; and (C) a low molecular weight polymeric nylon plasticizer; wherein: (1) the at least one elastomer is present as a dispersed phase of small vulcanized particles in a continuous nylon phase; and (2) the elastomer particles are formed by dynamic vulcanization. Use of a low molecular weight nylon plasticizer provides for improved mixing and rubber dispersion while retaining the high levels of impermeability achievable by the use of nylon resin and halogenated isobutylene-containing elastomer in a dynamically vulcanized composition. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers as well as hoses.

Abstract: A thermoplastic elastomer composition having excellent durability and flexibility while possessing superior air impermeability. In particular, a process for producing a thermoplastic elastomer composition having high rubber content by multistage addition of at least one vulcanizable rubber component, in which the time required to substantially cure the at least one rubber component preferably is less the mixer residence time. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.

Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.

Abstract: The invention relates to the use of a thermoplastic composition in a nanostructured form, said composition essentially comprising a grafted copolymer with polyamide blocks, consisting of a polyolefin trunk selected from the maleic ethylene anhydride and maleic alkyl anhydride ethylene (meth)acrylate copolymers, and at least one polyamide graft, for the thermal protection of a substrate, at a temperature higher than 150° C. The invention is characterised in that at least one layer of said composition is deposited on the substrate. According to a preferred embodiment, the coating layer is deposited by coextrusion on the substrate layer, especially for obtaining tubes or pipes used in petrol lines.

Abstract: A method is provided for making a reinforced polymer electrolyte membrane, such as may be used in electrolytic cells such as fuel cells, by mixing a sulfonate- or sulfonyl halide-functional polymer with a bisamidine compound and subsequently trimerizing the amidine groups of the bisamidine compound to form triazine linkages. The sulfonyl halide or sulfonate groups may then be converted to sulfonic acid groups, yielding a polymer electrolyte reinforced with a polytriazine.

Abstract: A blend of nanocomposites is disclosed, with a polyolefin nanocomposite preferably serving as a continuous phase and a polyamide nanocomposite preferably serving as a discontinuous phase. The exfoliated nanoclay in both nanocomposites contributes stiffness, toughness and flame retardancy to the blend. Other optional ingredients include conventional essentially halogen-free flame retardants, intumescent essentially halogen-free flame retardants, and other typical polymer compounding additives. The compound can be processed as a thermoplastic into any practical article needing stiff, tough, and flame retardancy properties.

Abstract: This invention relates to a blend of biodegradable polymers comprising: (A) about 5% to about 95% by weight of at least one flexible biodegradable polymer (A) having a glass transition less than about 0° C., (B) about 5% to about 95% by weight of at least one rigid biodegradable polymer (B) having a glass transition greater than about 10° C., and (C) about 0.25 to about 10 weight % of at least one compatibilizer (C), said percentages being based on the total weight of the polymer blend; where the polymer blend has a higher zero shear melt viscosity than polymers (A) and (B) separately.

Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.

Abstract: The invention provides a method of obtaining a compatible resin blend from at least two incompatible resins which are not conventionally blended with each other. The blend of an incompatible resins is dissolved at a molecular level by being melted and sheared under a high shearing rate by rotating a screw without adding a compatibilizer or the like.

Abstract: The present invention provides a resin composition comprising an amine-neutralized ethylene acid copolymer. These resin compositions copolymers may be characterized by enhanced adhesiveness and reduced crystallinity. Also provided are shaped articles, multilayer films or sheets, and laminate articles comprising the resin composition.

Abstract: The thermoplastic resin composition of the invention comprises (A) 50 to 97% by weight of a polyolefin, (B) 2 to 45% by weight of a polyamide resin comprising a diamine component and a dicarboxylic acid component and (C) 1 to 45% by weight of a modified polyolefin and/or styrene copolymer. The polyamide resin is specified by that at least 70 mol % of the diamine component is a constitutional unit derived from m-xylylenediamine and at least 70 mol % of the dicarboxylic acid component is a constitutional unit derived from a C4-C20 straight-chain ?,?-aliphatic dicarboxylic acid and isophthalic acid in a molar ratio of 3:7 to 10:0. With such a chemical component, the thermoplastic resin composition exhibits excellent fuel barrier properties, heat resistance and moldability.

Abstract: The present invention relates to aqueous compositions comprising component (A) which comprises at least one water-soluble component comprising at least one functional group that undergoes a crosslinking reaction, preferably upon drying and/or heating; component (B) which comprises at least one film-forming material, preferably a latex material; and component (C) which comprises at least one component that provides at least one of moisture and/or water barrier properties and/or vapor barrier properties greater than that provided by the combination of components (A) and (B) alone.

Abstract: The invention provides polymer blends containing polyhydroxyamide and one or more flammable polymers. The polymer blends are flame retardant and have improved durability and heat stability compared to the flammable polymer portion of the blends. Articles containing the polymer blends are also provided.

Abstract: A composition is disclosed which comprises a polyamide, a modifier, and optionally an ABS copolymer, a compatibilizer, or both wherein the modifier includes ethylene copolymer, crosslinked ethylene copolymer, ionomer derived from the ethylene copolymer, crosslinked ionomer derived from the ethylene copolymer, poly(meth)acrylate, or combinations of two or more thereof. The ethylene copolymer can comprise repeat units derived from ethylene, at least one alkyl acrylate or (meth)acrylic acid, and optionally an acid cure site.

Abstract: A method is provided for making a reinforced polymer electrolyte membrane, such as may be used in electrolytic cells such as fuel cells, by mixing a sulfonate- or sulfonyl halide-functional polymer with a bisamidine compound and subsequently trimerizing the amidine groups of the bisamidine compound to form triazine linkages. The sulfonyl halide or sulfonate groups may then be converted to sulfonic acid groups, yielding a polymer electrolyte reinforced with a polytriazine.

Abstract: The invention relates to a blend of one or more biopolymers with one or more acrylic copolymers, for the purpose of improving the properties of the biopolymer(s). The biopolymer composition comprises 30-99.9 weight percent of biopolymer(s) and 0.1 to 15 weight percent of one or more acrylic copolymers.

Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group chosen from functional groups (1) to (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.

Abstract: Microporous articles formed by thermally induced phase separation from a diluent in combination with a thermoplastic polymer and a fluorochemical additive providing novel fluid repellent articles. Such articles are useful in clothing, barrier membranes, optical films in electronic devices (such as light reflective and dispersive films), and protective garments.

Abstract: A sealable multi-layer opaque film. In particular, a sealable multi-layer opaque film that is moisture permeable and water resistant. The sealable multi-layer opaque film is an oriented multilayer film with a core layer comprising an orientation-enhancing polymer, a polypropylene homopolymer and a beta crystal nucleator of polypropylene and at least one sealable skin layer.

Abstract: Amino acid functionalized polymers useful for graft copolymerization prepared by reacting a mixture containing, for chain transfer, a thio-substituted amino acid and an ethylenically unsaturated monomer.

Abstract: A method of making amide polymers with improved back-bone rigidity, stability and/or planarity through the promotion of intra-molecular interactions is disclosed. Amide polymers, in accordance with the embodiments of the invention, are formed using aromatic dicarboxylic acids and heterocyclic diamine precursors or reactive amino-acid heterocyclic precursors. The heterocyclic precursors used in the present invention have heterocyclic structures that include hetero-atoms in a position that is beta relative to one or more reactive amine groups. Preferably, the hetero-atoms are nitrogen atoms. In accordance with further embodiments, precursors include functional groups that promote inter-molecular interactions, intra-molecular interactions and/or enhance solubility of the amide polymers formed.

Abstract: Hyperbranched dendron (HD) polymers are synthesized using low molecular weight polyethyleneimine (BPEI-L) as a core and used for gene delivery. The obtained polymers display low toxicity and efficient gene delivery at low nitrogen-to-phosphate (N/P) ratios. Using successive attachment of ethyleneimine moieties to a PEI core, the polymer has a lower relative ratio of linear-to-branched structures than in the core PEI. The more extensive branching enables the polymer to condense plasmid DNA into nanostructure complexes with a size of less than or equal to about 100 nm. The complexes are stable and efficient in transfecting cells in the presence of serum. Bioluminescent imaging of in vivo gene expression using a luciferase reporter gene performed in live mice showed gene expression in the liver and in submandibular lymph nodes.

Abstract: The invention relates to a polyamide-based thermoplastic composition comprising, by weight: 50 to 98 parts of a polyamide (A1) nondiamine; 0.2 to 40 parts, preferably 0.2 to 9 parts, of a polyamide (A2) diamine, said polyamide (A2) being different from the polyamide (A1) and the ratio by mass (A2)/(A1) being less than 1; 1 to 60 parts, preferably 1 to 30 parts, of a reactive impact modifier (B) or of a blend of modifiers comprising at least one reactive impact modifier (B) or of a blend (B?) comprising at least one impact modifier and at least one reactive modifier. It also relates to an impact modifier composition and to the process for the preparation of a thermoplastic composition according to the invention using such an impact modifier composition.

Abstract: The present invention relates to polymer mixtures comprising hydrogel forming polymers capable of absorbing aqueous fluids, having different pH values and each being preparable by polymerization of olefinically unsaturated carboxylic acids or derivatives thereof, their preparation, use and hygiene articles containing same. More particularly, the invention relates to 2-component polymer mixtures comprising polymers having a pH range from acidic to neutral.

Abstract: A polymeric material with antistatic properties, characterised by comprising a dispersion of ions within a polymeric matrix containing heteroatoms.

Abstract: A composition comprising by weight: 70 to 96% of at least one polyamide chosen from PA-11, PA-12, aliphatic polyamides resulting from the condensation of an aliphatic diamine having from 6 to 12 carbon atoms and an aliphatic diacid having from 9 to 12 carbon atoms, and 11/12 copolyamides having either more than 90% of nylon-11 units or more than 90% of nylon-12 units; 4 to 10% of a plasticizer; 0 to 25% of an NBR or H-NBR elastomer; and the sum of the amount of plasticizer and the amount of elastomer is between 4 and 30%; can be manufactured by melt-blending the various constituents using standard techniques for thermoplastics. The composition is particularly useful for pipes used in the operation of offshore oil and gas fields. They exhibit very good ageing resistance. They are also useful for simpler pipes in motor vehicles, these compositions withstanding the ageing caused by the temperature under the bonnet of motor vehicles and the nature of the fluids transported.

Abstract: A thermoplastic resin composition material 1 includes a resin portion (a) 2 made of a thermoplastic resin (A); elastomer portions (b) 3 made of a thermoplastic elastomer (B) having substantially no compatibility with the thermoplastic resin (A) and having a glass transition temperature of lower than or equal to ?40° C.; and polymer portions (c) 4 made of a high polymer (C) having substantially no compatibility with the thermoplastic resin (A) and the thermoplastic elastomer (B), having a glass transition temperature or crystallization temperature of lower than or equal to ?50° C., and having a viscosity at 40° C. of 0.1 to 200000 cP. The material has a structure in which the elastomer portions (b) 3 are dispersed in the resin portion (a) 2, and the polymer portions (c) 4 are dispersed in the elastomer portions (b) 3. Accordingly, low-temperature impact resistance can significantly be improved without deterioration in the other inherent excellent physical properties of the thermoplastic resin.

Abstract: Single coat coating systems (22), as well as articles coated with such non-stick coating systems, are provided. The single coat system includes a fluoropolymer copolymer (14a), such as fluoropolymer terpolymer including tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride monomers, with fluoropolymer copolymers are referred to collectively as THV. The single coat system exhibits excellent substrates adhesion and release properties, is resistant to separation failure at the interface between the binder (12) and fluoropolymer components (14a), and exhibits adhesion to smooth substrates (16). The single coat system may also include a high level of fillers to provide increased damage resistance without compromising the above benefits.

Abstract: Balloons for use on medical devices such as catheter balloons are formed from polymer blend products which include a liquid crystal polymer (LCP), a crystallizable thermoplastic polymer, especially thermoplastic polyesters such as PET, and a compatabilizer. The compatabilizer may be an ethylene-maleic anhydride copolymer, an ethylene-methyl acrylate copolymer, an ethylene-methyl acrylate copolymer, an ethylene-methyl acrylate-maleic anhydride terpolymer, an ethylene-methyl-methacrylic acid terpolymer, an acrylic rubber, an ethylene-ethyl acrylate-glycidyl methacrylate terpolymer or a mixture of two or more such polymers.

Abstract: The invention provides chain extenders made from epoxy-functional (meth)acrylic monomers and styrenic and/or (meth)acrylic monomers. The invention further provides polymeric compositions made from the chain extenders and plastic articles made from the compositions. Finally, the invention provides methods of using the chain extenders to improve the properties of virgin, recycled, and reprocessed condensation polymers.

Abstract: Oriented films are prepared. A thermoplastic vulcanizate, prepared by mixing at least 20 wt % of a thermoset rubber by weight of the total composition into a thermoplastic polymer are disclosed. After the mixture is prepared the thermoset rubber is entrained as discrete particles within the continuous thermoplastic polymer phase. The resulting composite is subjected to a stress either by pulling, blow molding, or any other film-forming process as is known in the art. This stress causes the continuous phase polymer molecules to become aligned or oriented in the direction in which the stress was applied, thus creating the oriented thermoplastic vulcanizate of the invention. This material has improved gas permeability and improved flexibility properties.