Solid Polymer Derived From Reactant Containing Nitrogen Atom Other Than From (meth)acrylonitrile Patents (Class 525/217)
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Patent number: 6608136Abstract: The present invention relates to polymer compositions containing polyphenylene sulfide, a polymeric grafting agent and an ethylene copolymer. The polymeric grafting agent is a copolymer of at least about 50% by weight ethylene, about 0.5% to about 15% by weight of a first reactive moiety selected from the group consisting of: (i) an unsaturated epoxide of 4-11 carbon atoms, (ii) an unsaturated isocyanate of 2-11 carbon atoms, (iii) an alkoxy or alkyl silane wherein the alkyl group is from 1-12 carbon atoms, and (iv) an oxazoline; and about 0 to about 49% by weight of a second moiety selected from at least one of an alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, where the alkyl and ether groups are of 1-12 carbon atoms.Type: GrantFiled: July 20, 2000Date of Patent: August 19, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: David M. Dean, Richard James Arhart
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Patent number: 6602955Abstract: The present invention is directed to ion-sensitive, water-dispersible polymers. The present invention is also directed to a method of making ion-sensitive, water-dispersible polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising ion-sensitive, water-dispersible binder compositions and their applicability in water-dispersible personal care products.Type: GrantFiled: February 21, 2002Date of Patent: August 5, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Dave A. Soerens, Yihua Chang, William S. Pomplun, Kenneth Y. Wang, Pavneet S. Mumick, Frederick J. Lang, Kelly D. Branham, Franklin M. Chen, Eric D. Johnson, Jeffrey D. Lindsay, Kim G. Schick, Walter T. Schultz, Tong Sun
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Publication number: 20030125468Abstract: A tire with a rubber containing component compound of, based on 100 parts by weight (phr) of rubber,Type: ApplicationFiled: October 3, 2002Publication date: July 3, 2003Inventors: Georges Marcel Victor Thielen, Stephan Franz Westermann, Claude Charles Jacoby, Christian Kaes
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Patent number: 6573334Abstract: A bottle closure made from an olefin polymer composition (A) which includes: 1) 90-100% by weight of a crystalline propylene homopolymer or propylene/C2-C10 alpha-olefin random copolymer, those polymers containing at least 94% by weight of a fraction insoluble in xylene at room temperature; and 2) 0-10% by weight of an ethylene/C3-C10 alpha-olefin elastomeric copolymer, provided that when the amount of polymer (2) is 0% by weight, polymer (1) is one of the above random copolymers. Said composition (A) has a flexural elastic modulus value at 23° C. of at least 1620 MPa, a strength at yield at 23° C. of at least 33 MPa, and an IZOD impact resistance at 0° C. of at least 2.5 kJ/m2.Type: GrantFiled: October 16, 2000Date of Patent: June 3, 2003Assignee: Montell Technology Company BVInventors: Silvio Pitteri, Rainer Schweda, Antonella Angelini
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Publication number: 20030092844Abstract: The present invention relates to a composition comprising isotactic polypropylene homo- or copolymer obtained by metallocene catalysis (A), abbreviated to miPP, and isotactic polypropylene homo- or copolymer obtained by Ziegler-Natta catalysis (B), abbreviated to zniPP, and grafted. It also relates to a coextrusion tie comprising such a composition.Type: ApplicationFiled: October 11, 2002Publication date: May 15, 2003Applicant: AtofinaInventor: Jean-Laurent Pradel
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Patent number: 6555625Abstract: An aqueous crosslinkable coating compositions comprising i) an autoxidisably crosslinkable polymer, ii) a not autoxidisably crosslinkable vinyl polymer bearing acetoacetyl groups and iii) acetoacetyl-reactive groups to crosslink the vinyl polymer.Type: GrantFiled: September 20, 2001Date of Patent: April 29, 2003Assignee: Avecia BVInventors: Gerardus Cornelis Overbeek, Ronald Tennebroek, Yvonne Wilhelmina Smak
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Publication number: 20030077243Abstract: Extremely hydrophobic nitric oxide (NO) releasing polymers are disclosed. The extremely hydrophobic NO-releasing polymers provided are extensively cross-linked polyamine-derivatized divinylbenzene diazeniumdiolates. These polymers can be loaded with extremely high NO levels and designed to release NO in manners than mimic natural biological systems. The NO-releasing extremely hydrophobic polymers provided can maintain a sustained NO release for periods exceeding nine months. Also provided are related medical devices made using these NO-releasing extremely hydrophobic polymers.Type: ApplicationFiled: October 4, 2001Publication date: April 24, 2003Inventors: Anthony L. Fitzhugh, Robert Cafferata, Larry K. Keefer
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Patent number: 6552128Abstract: A rubber composition which can achieve superior adhesion force between it and a material to be adhered without a coating of an adhesive. The rubber composition includes the following components (A) to (D): (A) a rubber composed of at least one of an ethylene-propylene-diene terpolymer and an ethylene-propylene copolymer, (B) a peroxide vulcanizing agent, (C) a resorcinol-based compound, and (D) a melamine resin.Type: GrantFiled: October 2, 2001Date of Patent: April 22, 2003Assignee: Tokai Rubber Industries, Ltd.Inventors: Ayumu Ikemoto, Koji Senda
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Patent number: 6545102Abstract: Improved polymer-immobilized photosensitizer are disclosed as well as methods of preparing and using them. The polymer-immobilized photosensitizers comprise a cross-linked polymer backbone, a plurality of cationic ammonium or phosphonium groups covalently bound to the polymer backbone and an immobilized photosensitizer. The average total number of carbon atoms in the ammonium or phosphonium group is at least four and preferably at least 12. The photosensitizer can be either covalently or ionically bound to the polymer. Polymer-supported photosensitizers of the invention are unexpectedly superior in catalyzing the photosensitized oxidation of compounds containing carbon-carbon double bonds.Type: GrantFiled: September 27, 2001Date of Patent: April 8, 2003Assignee: Lumigen, Inc.Inventors: Hashem Akhavan-Tafti, Richard S. Handley, Mark D. Sandison, Randall K. Larkin
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Patent number: 6541571Abstract: A process for compatibilizing at least two mutually incompatible polymers, and a blended resins thereof, wherein said process comprises: (i) adding to at least one of the polymers an effective amount of a compatibilizing dispersant, wherein said dispersant is the polymerization reaction product of a mixture of monomers consisting essentially of: (a) from about 10% to about 40% by weight styrene; and (b) from about 10% to about 55% by weight of at least one alkyl methacrylate monomer having 1 to 8 carbon atoms in the alkyl group; and (c) from about 10% to about 55% by weight of at least one alkyl methacrylate monomer having greater than 8 carbon atoms in the alkyl group; and (d) from about 5% to about 25% by weight of at least one alkyl acrylate monomer having from 1 to 18 carbon atoms in the alkyl group; and (e) from about 7% to about 25% by weight of at least one hydroxy-functional ethylenically unsaturated monomer having a molecular weight of less than 2000; and (f) from about 0.Type: GrantFiled: August 1, 2001Date of Patent: April 1, 2003Assignee: The Sherwin-Williams CompanyInventor: Gautam S. Haldankar
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Patent number: 6538074Abstract: The combination of powder coatings usable in a coating method comprising mixing two or more powder coatings of which each color is different, wherein each of the powder coatings fuses with each other and is heat-cured, to thereby give a coating film having a homogenous hue. A powder coating composition comprising two or more powder coatings of which each color is different, wherein each of the powder coatings fuses with each other and is heat-cured, to thereby give a coating film having a homogenous hue. A coating method comprising the steps of (a) applying to a substrate two or more powder coatings, of which each color is different; (b) heating to fuse with each other each of the two or more powder coatings applied in step (a); and (c) curing the resulting fused product in step (b), to give a coating film having a homogeneous hue.Type: GrantFiled: May 30, 2000Date of Patent: March 25, 2003Assignee: Nippon Paint Co., Ltd.Inventors: Yukiya Sato, Hisakazu Tajima, Katsutoshi Aoki, Takehiko Tohjo, Yasunori Inagaki, Masayuki Maruta, Shingo Tanaka
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Patent number: 6525139Abstract: A golf ball having a core and a cover enclosing the core. The cover has one or more layers. At least one of the cover layers is composed mainly of a rubber-modified thermoplastic resin composition consisting essentially of a base resin in the form of an ionomer resin, a non-ionomer thermoplastic elastomer or a mixture thereof and a crosslinked functional rubbery copolymer.Type: GrantFiled: January 21, 2000Date of Patent: February 25, 2003Assignee: Bridgestone Sport Co., Ltd.Inventors: Rinya Takesue, Yasushi Ichikawa, Shunichi Kashiwagi
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Patent number: 6506840Abstract: A process for producing a succinimide resin composition is provided which comprises reacting a maleic anhydride-olefin type copolymer constituted of 40-60 mol % of maleic anhydride units, 60-40 mol % of olefin units, and 0-20 mol % of a copolymerizable monomer units with one or more amine compounds for imide formation in the presence of a second polymer other than the succinimide resin. This process improves the productivity by lowering the torque in the extrusion reaction, giving a succinimide copolymer resin composition having low yellowness and high transparency with high production efficiency.Type: GrantFiled: April 16, 2001Date of Patent: January 14, 2003Assignee: Tosoh CorporationInventors: Takeshi Harunari, Yoshiki Uchida, Toru Doi
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Patent number: 6500899Abstract: A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C.Type: GrantFiled: November 21, 2001Date of Patent: December 31, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Teruhiko Suzuki, Tsutomu Nagamune, Teiji Kohara
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Patent number: 6498215Abstract: A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C.Type: GrantFiled: November 21, 2001Date of Patent: December 24, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Teruhiko Suzuki, Tsutomu Nagamune, Teiji Kohara
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Publication number: 20020187101Abstract: Cascade polymer complexes with at least 16 ions of an element of atomic numbers 20 to 29, 39, 42, 44 or 57-83, useful NMR or x-ray lymphography imaging.Type: ApplicationFiled: May 6, 2002Publication date: December 12, 2002Applicant: Schering AGInventors: Heribert Schmitt-Willich, Johannes Platzek, Bernd Raduchel, Andreas Muhler, Thomas Frenzel
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Patent number: 6482894Abstract: A liquid ebonite mixture for coating includes two reactive components. The first component contains first unsaturated polymers having first functional groups capable of reaction at ambient condition either with or without a catalyst, a vulcanization agent, and a vulcanization activator. The second component contains second unsaturated polymers having second functional groups that will react with the first functional groups at ambient temperature. The first and the second unsaturated polymers must contain sufficient unsaturated backbones to allow vulcanization with the vulcanization agent. In addition, the second unsaturated polymers must be thermodynamically compatible with the first unsaturated polymers so that macroscopic phase separation will not occur and the vulcanization can happen homogeneously through out the coating.Type: GrantFiled: November 28, 2000Date of Patent: November 19, 2002Assignee: 3L & T, Inc.Inventors: Rong Jong Chang, William L. Betts, III, Linas Mazeika
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Patent number: 6479590Abstract: The present invention relates to a resin material for an electrical insulating material, an electrical insulating material and electric wire and cable using the same. A resin material for an electrical insulating material according to present invention is characterized in that the resin component thereof comprises an ethylene &agr;-olefin copolymer (A) which satisfies specific conditions, such as a density of 0.92˜0.96 g/cm3, a melt flow rate (MFR) of 0.01˜200 g/10 minutes, a molecular weight distribution (Mw/Mn) of 1.5˜5.0, and possessing only one peak in terms of the number of peaks observed in an elution temperature-eluted amount curve as measured by the temperature raising elution fractionation (TREF) method, etc.Type: GrantFiled: March 16, 2001Date of Patent: November 12, 2002Assignee: Japan Polyolefins Co., Ltd.Inventors: Masaaki Ikeda, Yoshimi Shimizu
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Patent number: 6479147Abstract: An emulsion or suspension polymer comprising a vinyl chloride polymeric core and an acrylic ester-acrylonitrile polymeric shell is disclosed. The emulsion polymer is preferably prepared using a two-stage process. In the first stage, a vinyl chloride monomer is polymerized or copolymerized to form a first phase of a polymeric hard core having a relatively high chlorine content. In a second stage, the soft acrylic ester—acrylonitrile copolymer is made in situ in a reaction mixture comprising the first phase. The product provides both flame retardancy and low MFFT, and is useful in a variety of coating and binding applications.Type: GrantFiled: September 17, 2001Date of Patent: November 12, 2002Assignee: Noveon IP Holdings Corp.Inventors: Alexander V. Lubnin, Vic Stanislawezyk
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Publication number: 20020128390Abstract: A thermoplastic elastomer formed by a process comprising the steps of dynamically vulcanizing a rubber within a mixture that includes the rubber, from about 10 to about 80 percent by weight of a thermoplastic resin based upon the total weight of the rubber and the thermoplastic combined, and from about 1 to about 25 percent by weight of a polymeric processing additive based upon the total weight of the rubber and the thermoplastic combined, where the polymeric processing additive is a linear polyolefin resin that has an melt flow rate that is greater than about 1,000 dg/min, a diene-modified polyolefin polymer that has an melt flow rate that is greater than about 1,000 dg/min, from about 0.005 to about 2.00 mole percent polymeric units deriving from dienes, and a viscosity average branching index that is from about 0.4 to about 0.Type: ApplicationFiled: December 29, 2000Publication date: September 12, 2002Inventors: Maria D. Ellul, Paul E. McDaniel, Thomas L. Peltier, Jianya Cheng, Patrick Brant, Armenag H. Dekmezian
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Patent number: 6448339Abstract: An adhesive composition is prepared from a major proportion of (1) a corboxyl group-containing adhesive component having a weight average molecular weight of 800,000 or greater and a smaller amount of (2) an amino group-containing adhesion-improving component having a weight average molecular weight of 100,000 or less which is added to crosslink the component (1).Type: GrantFiled: December 11, 1997Date of Patent: September 10, 2002Assignees: Soken Chemical & Engineering Co., Ltd., Lintec CorporationInventor: Koji Tomita
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Patent number: 6441092Abstract: A wet-skin adhesive includes a pressure-sensitive adhesive component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having at least 4 carbons on average and at least one monoethylenically unsaturated reinforcing monomer; and a film-forming component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having less than 4 carbons on average and at least one hydrophilic acidic monomer, wherein the wet-stick pressure-sensitive adhesive has an initial wet skin adhesion of at least about 0.8 N/dm. Advantageously, the wet-stick adhesive has an initial wet skin adhesion that is at least about 65% of an initial dry skin adhesion.Type: GrantFiled: August 13, 1999Date of Patent: August 27, 2002Assignee: 3M Innovative Properties CompanyInventor: Melinda B. Gieselman
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Patent number: 6433090Abstract: A thermoplastic vulcanizate prepared by a process comprising the steps of dynamically vulcanizing a vulcanizable rubber within a mixture that includes from about 15 to about 90 percent by weight of the rubber and from about 10 to about 85 percent by weight of a long-chain branched thermoplastic resin, where the long-chain branched thermoplastic resin is (i) an &agr;-olefin polymer, (ii) a copolymer of an &agr;-olefin and an &agr;-&ohgr;-olefin diene, or (iii) a mixture thereof, where the long-chain branched thermoplastic resin is characterized by a weight average molecular weight from about 100,000 to about 600,000, a number average molecular weight from about 40,000 to about 200,000, a z-average molecular weight from about 400,000 to about 2,000,000, a <g′>vis from about 0.2 to about 0.95, and a melt flow rate from about 0.3 to about 30 dg/min.Type: GrantFiled: January 26, 2001Date of Patent: August 13, 2002Assignee: Advanced Elastomer Systems, L.P.Inventors: Maria D. Ellul, Abdelhadi Sahnoune
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Patent number: 6433086Abstract: A method for making rotationally molded objects using resin blends. The resin blend comprises resin pellets and an amount of ground resin particles sufficient to yield rotomolded objects having desirable impact strength and other strength characteristics. Preferably, the resin blend comprises of from about 20% to about 30% by weight of ground resin particles. In addition, resin blends can be used to produce colored objects by rotational molding techniques.Type: GrantFiled: October 15, 1999Date of Patent: August 13, 2002Assignee: Chroma CorporationInventor: Robert D. Swain
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Patent number: 6429261Abstract: The present invention is directed to ion-sensitive, water-dispersible polymers. The present invention is also directed to a method of making ion-sensitive, water-dispersible polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising ion-sensitive, water-dispersible binder compositions and their applicability in water-dispersible personal care products.Type: GrantFiled: May 4, 2000Date of Patent: August 6, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Frederick J. Lang, Kelly D. Branham, Yihua Chang, Franklin M. Chen, Eric D. Johnson, Jeffrey D. Lindsay, Pavneet S. Mumick, William S. Pomplun, Kim G. Schick, Walter T. Schultz, Dave A. Soerens, Tong Sun, Kenneth Y. Wang
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Patent number: 6429264Abstract: A thermoplastic elastomer composition comprising 100 parts by weight of a polyolefin resin, 5 to 250 parts by weight of a rubbery polymer and 0 to 500 parts by weight of an ethylene-&agr;-olefin copolymer rubber, wherein a complex dynamic viscosity &eegr;*(1) at 250° C. is 1.5×105 poise or less and a Newtonian viscosity index n is 0.67 or less, and furthermore, wherein said thermoplastic elastomer composition has a specific tan &dgr; peak, the peak temperature of which is different from that of the polyolefin resin and that of the rubbery polymer, at a temperature within the range from −70 to 30° C. in a temperature dependence curve of tan &dgr; determined by solid dynamic viscoelasticity measurement, powder or pellet thereof, and a molded article thereof.Type: GrantFiled: April 26, 2001Date of Patent: August 6, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroyuki Sugimoto, Yoshihiro Nakatsuji, Susumu Ejiri
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Patent number: 6407197Abstract: Aqueous dispersion of a polymer, which polymer has been obtained by subjecting a starting polymer which contains maleic anhydride monomer units and vinyl aromatic monomer units to an imidization reaction, the starting polymer containing 7-50 mole % maleic anhydride monomer units and the imidization reaction having been carried out in such a way that at most 75% of the maleic anhydride monomer units has been imidized.Type: GrantFiled: September 1, 2000Date of Patent: June 18, 2002Assignee: DSM N.V.Inventors: Hendrik J. Van Den Berg, Mathijs H. G. Maassen, Laurentius W. Steenbakkers
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Patent number: 6403722Abstract: An elastomeric blend prepared by the steps comprising: dynamically vulcanizing a dynamically-vulcanizable elastomer within a mixture that comprises the dynamically-vulcanizable elastomer, a hydrogenated acrylonitrile-butadiene copolymer, and a vulcanizing agent that is specific for the dynamically-vulcanizable elastomer during dynamic vulcanization. Also, a vulcanizate prepared by the steps comprising: dynamically vulcanizing a dynamically-vulcanizable elastomer within a mixture that comprises the dynamically-vulcanizable elastomer, a hydrogenated acrylonitrile-butadiene copolymer, and a vulcanizing agent that is specific to the dynamically-vulcanizable elastomer during dynamic vulcanization, and effecting vulcanization of the hydrogenated acrylonitrile-butadiene copolymer.Type: GrantFiled: October 3, 2000Date of Patent: June 11, 2002Assignee: The University of AkronInventors: Geralda Severe, James L. White
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Patent number: 6395800Abstract: The biocompatibility of various polymers are improved by blending with them a polymer including a zwitterionic group. The zwitterionic group is usually an ammonium phosphate ester zwitterionic group and the polymer containing it may be produced by the free radical polymerisation of ethylenically unsaturated monomers including a monomer bearing the zwitterionic group. Blending of the two polymers may be achieved by dry blending particulate polymers or by mixing the polymers in liquid dispersion or solution followed by removal of the liquid medium. The fibrinogen absorption and/or platelet activation of polymers may be reduced to a value of less than 80% or even less than 60% of the base polymer by introducing amounts of more than 10% or more than 30% of the zwitterionic group containing polymer. Preferred blends are of copolymers of 2-(methacryloyloxyethyl)-2′-(trimethylammonium)ethyl phosphate inner salt with higher alkyl(meth)acrylate, blended with olefin polymers and/or with rubber latices.Type: GrantFiled: April 14, 2000Date of Patent: May 28, 2002Assignee: Biocompatibles LimitedInventors: Stephen Alister Jones, Peter William Stratford, Steven Rimmer
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Patent number: 6388018Abstract: Graft copolymers having cationic units pendant to the backbone chain are disclosed. These polymers are prepared by reacting a polymer containing halogenated para-methylstyrene units in the chain, e.g., a brominated copolymer of isobutylene and para-methylstyrene, with an anionically polymerized polymer made using an organolithium initiator compound having the formula R1 R2 Z R3—Li where R1 and R2 are alkyl radicals, R3 is a direct link or an organic radical and Z is nitrogen or phosphorous. Reaction of the anionically polymerized polymer having an R1 R2 Z R3— end group with the halogenated polymer leads to graft polymers coupled by a quaternary ammonium or phosphonium groups.Type: GrantFiled: March 3, 2000Date of Patent: May 14, 2002Assignee: ExxonMobile Research and Engineering CompanyInventors: Dennis G. Peiffer, Hsien-Chang Wang, Pamela Jean Wright, Joseph A. Sissano, Lewis J. Fetters, Louise M. Wheeler, Rebecca L. Rucker
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Publication number: 20020042476Abstract: A rubber-reinforced styrene transparent resin composition contains a styrene copolymer reinforced with a rubber polymer, wherein the monomer composition of an acetone soluble resin component contained in the resin composition contains 5 to 70% by weight of aromatic vinyl monomer (a1), 30 to 95% by weight of unsaturated carboxylic acid alkyl ester monomer (a2), 0 to 50% by weight of vinyl cyanide monomer (a3), and 0 to 50% by weight of another monomer copolymerizable with these monomers, and the acid value of the acetone soluble resin component is 0.01 to 1 mgKOH/g.Type: ApplicationFiled: July 26, 2001Publication date: April 11, 2002Inventors: Ryota Kido, Hiroshi Shibata, Hajime Takamura, Akihiro Ohmura, Yoshiyuki Yamamoto
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Patent number: 6365660Abstract: A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C.Type: GrantFiled: January 26, 2000Date of Patent: April 2, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Teruhiko Suzuki, Tsutomu Nagamune, Teiji Kohara
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Patent number: 6348554Abstract: The invention concerns a method for preparation of a liquid polymer composition, where ethylenically unsaturated monomers are polymerized by means of initiators that have a transferable atomic group, and one or more catalysts that contain at least one transition metal, in the presence of ligands that can form a coordination compound with the metallic catalysts, the catalyst is oxidized after the polymerization and then the catalyst is separated by filtration, where the composition contains a solvent with a dielectric constant less than or equal to 4.Type: GrantFiled: November 30, 1999Date of Patent: February 19, 2002Assignee: RohMax Additives GmbHInventors: Sebastian Roos, Boris Eisenberg, Michael Mueller
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Patent number: 6340725Abstract: A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of ammonium groups, (2) first cationic addition polymer consisting essentially of quaternary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, and (3) second cationic addition polymer consisting essentially of secondary, tertiary, or both secondary and tertiary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble filler particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of coating.Type: GrantFiled: October 11, 1999Date of Patent: January 22, 2002Assignee: Hewlett-Packard CompanyInventors: Alan E. Wang, Louis J. Nehmsmann, Suk H. Cho, Robert H. Tang, William C. Allison
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Publication number: 20020007014Abstract: A pressure-sensitive adhesive comprising a blend of at least two components, wherein the first component is at least one pressure-sensitive adhesive and the second component is at least one thermoplastic material, wherein the components form a blended composition having more than one domain and, wherein one domain is substantially continuous (generally, the pressure-sensitive adhesive) and the other domain is substantially fibrinous to schistose (generally, the thermoplastic material). The second component can be (a) at least one thermoplastic elastomer, (b) at least one elastomer with a tackifying resin or (c) at least one elastomer.Type: ApplicationFiled: June 13, 2001Publication date: January 17, 2002Applicant: Minnesota Mining and Manufacturing CompanyInventors: Patrick D. Hyde, Dennis L. Krueger, Felix P. Lau, Eumi Pyun, Robert W. Shipman, Pamela S. Tucker, Roy Wong, David J. Yarusso
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Patent number: 6333386Abstract: A relatively small amount of a plasticizer having an SP value of at least 8.8 and a molecular weight of at most 550 is added to blend rubber of NBR-PVC in which NBR has an AN content of from 43 to 50% by weight. The fuel impermeability and the low-temperature flexibility of the resulting rubber composition are improved to be comparable to those of FKM, and the amount of the plasticizer and its reaction product to be released from the rubber composition in fuel is reduced. Adding a controlled amount of carbon black to the rubber composition makes the composition have favorable electroconductivity. The rubber composition is formed into hoses or electroconductive hoses of low fuel permeation.Type: GrantFiled: June 27, 2000Date of Patent: December 25, 2001Assignee: Tokai Rubber Industries, Ltd.Inventors: Takahiro Nishiyama, Shinobu Kanbe, Atsuo Miyajima, Kazuhiro Kato
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Patent number: 6323306Abstract: High molecular weight, water-soluble, cross-linked cationic polymers are prepared by reacting amine-functionalized cationic base polymers, in which the monomer units of the base polymer contain from about 0.05 to about 5.0% amine functionalized monomer units and from about 95 to about 99.95% additional monomer units, including cationic monomer units and optional non-cationic monomer units, with an amount of a cross-linking agent, reactive with the amines of the base polymer, providing between about 0.02 to about 3.0 equivalents of cross-linking agent reactive groups per each mole of amine. The polymers are useful as coagulants and as coatings.Type: GrantFiled: September 8, 1998Date of Patent: November 27, 2001Assignee: Ciba Specialty Chemicals Water Treatments Ltd.Inventors: Zhiqiang Song, George W. Schriver, Dennis M. Mahoney, Louis E. Trapasso
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Patent number: 6316107Abstract: An emulsion or suspension polymer comprising a vinyl chloride polymeric core and an acrylic ester-acrylonitrile polymeric shell is disclosed. The emulsion polymer is preferably prepared using a two-stage process. In the first stage, a vinyl chloride monomer is polymerized or copolymerized to form a first phase of a polymeric hard core having a relatively high chlorine content. In a second stage, the soft acrylic ester—acrylonitrile copolymer is made in situ in a reaction mixture comprising the first phase. The product provides both flame retardancy and low MFFT, and is useful in a variety of coating and binding applications.Type: GrantFiled: April 7, 1999Date of Patent: November 13, 2001Assignee: PMD Group Inc.Inventors: Alexander V. Lubnin, Vic Stanislawczyk
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Patent number: 6316090Abstract: A thermoplastic elastomer composition comprising 100 parts by weight of a polyolefin resin, 5 to 250 parts by weight of a rubbery polymer and 0 to 500 parts by weight of an ethylene-&agr;-olefin copolymer rubber, wherein a complex dynamic viscosity &eegr;*(1) at 250° C. is 1.5×105 poise or less and a Newtonian viscosity index n is 0.67 or less, and furthermore, wherein said thermoplastic elastomer composition has a specific tan &dgr; peak, the peak temperature of which is different from that of the polyolefin resin and that of the rubbery polymer, at a temperature within the range from −70 to 30° C. in a temperature dependence curve of tan &dgr; determined by solid dynamic viscoelasticity measurement, powder or pellet thereof, and a molded article thereof.Type: GrantFiled: December 19, 1997Date of Patent: November 13, 2001Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroyuki Sugimoto, Yoshihiro Nakatsuji, Susumu Ejiri
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Patent number: 6313224Abstract: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer.Type: GrantFiled: November 9, 1999Date of Patent: November 6, 2001Assignee: PPG Industrial Ohio, Inc.Inventors: Debra L. Singer, Kurt G. Olson, Kurt A. Humbert, Karen A. Barkac, Mark E. Wozniak
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Publication number: 20010034415Abstract: Impact-modified thermoplastic polymer mixtures comprise copolymers (component A) formed from sulfur dioxide (a1), from vinyl aromatic compounds (a2), from unsaturated polar compounds (a31) selected from the group consisting of compounds of the formula (I) 1Type: ApplicationFiled: December 5, 2000Publication date: October 25, 2001Inventors: Joachim Queisser, Peter Barghoorn, Graham Edmund Mc Kee, Rolf Mulhaupt, Rupert Schnell
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Patent number: 6300418Abstract: The invention relates to an adhesive thermoplastic elastomer composition comprising either a blend of a thermoplastic resin and a rubber, or a thermoplastic elastomeric styrene based blockcopolymer. The invention resides in that the composition also comprises an adhesion promotor in the form of a reaction product of a functionalized rubber and a polyamide. The invention also relates to articles comprising a combination of a substrate and such a composition.Type: GrantFiled: November 2, 1999Date of Patent: October 9, 2001Assignee: DSM N.V.Inventors: Ryszard Brzoskowski, Mohammed R Sadeghi
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Patent number: 6294311Abstract: Imageable elements useful as lithographic printing members are disclosed. The elements contain a substrate, an underlayer, and a top layer. The underlayer contains a combination of polymeric materials that provides resistance both to fountain solution and to aggressive washes, such as a UV wash. The underlayer can be used in either thermally imageable or photochemically imageable elements.Type: GrantFiled: December 22, 1999Date of Patent: September 25, 2001Assignee: Kodak Polychrome Graphics LLCInventors: Ken-ichi Shimazu, Jayanti Patel, Jianbing Huang, Nishith Merchant, Mathias Jarek
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Patent number: 6277487Abstract: The present invention provides a fluoropolymer coating composition which is capable of coating thick and forming a coating film being excellent in abrasion resistance, corrosion resistance and non-sticking property, and provides a coated article obtained by coating the above-mentioned composition as a top coat. The fluoropolymer coating composition comprises fine particles of a fluoropolymer, 0.Type: GrantFiled: October 22, 1998Date of Patent: August 21, 2001Assignee: Daikin Industries, Ltd.Inventors: Yoshihiro Soda, Nobuyuki Tomihashi
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Patent number: 6262178Abstract: This invention is based upon the discovery that cyclized polyisoprene polymers can be incorporated into tire tread compounds to improve traction, treadwear, and resistance to tear. It is further based upon the discovery that cyclized polyisoprene polymers can be blended with halobutyl rubber and/or natural rubber and can be utilized in tire innerliner formulations. The present invention more specifically discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of a sulfur cured rubber composition which is comprised of about 5 phr to about 50 phr of cyclized polyisoprene and about 50 phr to about 95 phr of at least one other rubbery polymer.Type: GrantFiled: December 28, 1999Date of Patent: July 17, 2001Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Joseph Frank Geiser, Judy Chu, David John Zanzig, Richard George Bauer
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Publication number: 20010007892Abstract: A rubber composition obtained byType: ApplicationFiled: February 5, 2001Publication date: July 12, 2001Applicant: Sumitomo Rubber Industries, Ltd.Inventors: Yasuhisa Minagawa, Hiroki Sarashi, Minoru Ueda
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Patent number: 6252009Abstract: Acrylic polymers are typically difficult to cure unless they contain specific curing sites, such as carbon-carbon double bonds. This invention offers a technique to rapidly cure acrylic polymers containing nitrile groups that do not possess typical curing sites, such as carbon-carbon double bonds. By utilizing the process of this invention, heat resistant thermoplastic vulcanizates with high-resistance to solvents can easily be prepared. The present invention more specifically discloses a process for curing an acrylic polymer which comprises distributing an aromatic compound having at least two nitrile oxide groups bonded thereto throughout the acrylic polymer, wherein the acrylic polymer contains nitrile groups, and wherein a bulky group is in at least one ortho position to the nitrile oxide group and wherein the bulky group is a moiety which is larger than a hydrogen atom.Type: GrantFiled: February 24, 1999Date of Patent: June 26, 2001Assignee: The Goodyear Tire & Rubber CompanyInventors: François Jean-Marie Breton, Dane Kenton Parker
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Patent number: 6245854Abstract: A hydrophilic coating composition for hydrophilically coating a metallic surface. The coating composition comprises a fluorocarbon-containing hydrophilic polymer comprising units of hydrophilic monomer and fluorocarbon-containing hydrophobic comonomer. The coating composition produces hydrophilic coatings on the metallic surface having a contact angle below about 50°.Type: GrantFiled: December 11, 1998Date of Patent: June 12, 2001Assignee: Visteon Global Technologies, Inc.Inventors: Chimere N. Obioha, Riad A. Farah, Dennis Schuetzle, Yun-xiang Zhang
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Patent number: 6221933Abstract: The present invention provides a fast drying jet ink composition comprising an organic solvent, a colorant, a polyamine, and an acidic resin. The acidic resin preferably has an acid number of from about 10 to about 250. Examples of suitable polyamines include dendrimers and aminoacrylates. The jet ink composition can be used to print on glass surfaces that have a condensation of moisture on them. The printed messages do not easily rub off after exposure to humid conditions. The messages printed on glass can be washed off by a caustic solution.Type: GrantFiled: April 1, 1999Date of Patent: April 24, 2001Assignee: Marconi Data Systems Inc.Inventors: Linfang Zhu, John P. Folkers, Mark A. Chamerlik, Renita J. Freeze
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Patent number: 6207768Abstract: The combination of powder coatings usable in a coating method comprising mixing two or more powder coatings of which each color is different, wherein each of the powder coatings fuses with each other and is heat-cured, to thereby give a coating film having a homogeneous hue. A powder coating composition comprising two or more powder coatings of which each color is different, wherein each of the powder coatings fuses with each other and is heat-cured, to thereby give a coating film having a homogeneous hue. A coating method comprising the steps of (a) applying to a substrate two or more powder coatings, of which each color is different; (b) heating to fuse with each other each of the two or more powder coatings applied in step (a); and (c) curing the resulting fused product in step (b), to give a coating film having a homogeneous hue.Type: GrantFiled: November 25, 1997Date of Patent: March 27, 2001Assignee: Kao CorporationInventors: Yukiya Sato, Hisakazu Tajima, Katsutoshi Aoki, Takehiko Tohjo, Yasunori Inagaki, Masayuki Maruta, Shingo Tanaka