Solid Polymer Derived From Reactant Containing Nitrogen Atom Other Than From (meth)acrylonitrile Patents (Class 525/217)
  • Patent number: 6187865
    Abstract: These articles relate to rubber compositions and laminates thereof. The laminates bring together materials not easily bonded to each other. The compositions comprise rubber and a resin component containing ethylene-vinyl acetate copolymer (EVA). The laminates are useful for providing a protective covering such as shelf or drawer liners.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: February 13, 2001
    Assignee: Ludlow Composites Corporation
    Inventor: Edouard A Brodeur, Jr.
  • Patent number: 6156842
    Abstract: The present invention pertains to structures and fabricated articles having shape/reshape behavior (and processes for their preparation) comprising;(A) from about 1 to 100 wt % (based on the combined weights of Components A and B) of at least one substantially random interpolymer having an I.sub.2 of 0.1 to about 1,000 g/10 min and an M.sub.w /M.sub.n of from about 1.5 to about 20, which comprises;(1) from about 38 to about 65 mol % of polymer units derived from;(a) at least one vinyl or vinylidene aromatic monomer, or(b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or(c) a combination of at least one aromatic vinyl or vinylidene monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, and(2) from about 35 to about 62 mol % of polymer units derived from ethylene and/or at least one C.sub.3-20 .alpha.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: December 5, 2000
    Assignee: The Dow Chemical Company
    Inventors: Stephen M. Hoenig, Robert R. Turley, Yunwa W. Cheung, Martin J. Guest, Charles F. Diehl, Kenneth B. Stewart, John Sneddon
  • Patent number: 6150432
    Abstract: Disclosed is a polymer blend composition and shaped article, and a process of blending and making shaped articles of polymer blends in which the biocompatibility of various polymers is improved by blending with them a polymer including a zwitterionic group. The zwitterionic group is usually an ammonium phosphate ester, preferably a choline, zwitterionic group and the polymer containing it may be produced by the free radical polymerization of ethylenically unsaturated monomers including a monomer bearing the zwitterionic group. Blending of the two polymers may be achieved by dry blending particulate polymers or by mixing the polymers in liquid dispersion or solution followed by removal of the liquid medium. The fibrinogen absorption and/or platelet activation of polymers may be reduced to a value of less than 80% or even less than 60% of the base polymer by introducing amounts of more than 10% or more than 30% of the zwitterionic group containing polymer.
    Type: Grant
    Filed: January 26, 1998
    Date of Patent: November 21, 2000
    Assignee: Biocompatibles Limited
    Inventors: Stephen Alister Jones, Peter William Stratford, Steven Rimmer
  • Patent number: 6133368
    Abstract: A dispersant system useful in the formation of dispersions of water soluble polymers is disclosed. The dispersant system comprises two polymers, the first being a copolymer of diallyldimethyl ammonium chloride with a C.sub.6 to C.sub.20 quaternary ammonium salt of a monomer selected the from the group consisting of dialkylaminoalkylacrylates, dialkylaminoalkylmethacrylates, dialkylaminoalkylacrylamides, and dialkylaminoalky (meth) acrylamides as well as certain alkyl esters of acrylic acid. The second polymer is a water soluble cationic polymer composed of at least 20 mole percent of a cationic monomer represented by the formula: ##STR1## where R.sub.4 is either hydrogen or CH.sub.3 ; R.sub.5 and R.sub.6 are each an alkyl group having 1 to 2 carbon atoms; R.sub.7 is a hydrogen atom or an alkyl group having 1 to 2 carbon atoms; A.sub.2 is either an oxygen atom or NH; B.sub.2 is either an alkylene group having 2 to 4 carbon atoms or a hydroxypropylene group and X.sub.2.sup.- is an anionic counterion.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: October 17, 2000
    Assignee: Nalco Chemical Company
    Inventors: John R. Hurlock, Manian Ramesh
  • Patent number: 6114452
    Abstract: Perfluoroelastomer compositions are provided which have excellent high temperature properties. The perfluoroelastomer component of the compositions are copolymers having a plurality of carbonyl-containing functional groups and copolymerized monomer units comprising a perfluoroolefin, a perfluoro(vinyl) ether and a nitrile-containing cure site monomer. The curative component is other than an organotin compound and includes peroxides, ammonium salts, aromatic amino compounds, bisamidrazones, and bisamidoximes.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: September 5, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Walter Werner Schmiegel
  • Patent number: 6103387
    Abstract: A thermosetting composition comprises (A) a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a dispersing component of at least one inorganic oxide sol selected from the group consisting of aluminium oxide sol, silica sol, zirconium oxide sol and antimony oxide sol, and optionally (D) a thermal latent acid catalyst which is activated during curing the composition by heating. A method of coating and a coated article comprise applying the composition. The obtained paint film has excellent weathering resistance, stain resistance, stain-removing property, chemical resistance, moisture resistance and excellent appearance.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: August 15, 2000
    Assignee: NOF Corporation
    Inventors: Toshio Yamamoto, Masahiro Sano, Hiroki Mizutani, Keiji Komoto, Masahiro Ishidoya
  • Patent number: 6100338
    Abstract: The present invention is directed to particulate carriers useful as drug carries in a drug delivery system (DDS) and to pharmaceutical compositions making use of such carriers. The invention is characterized by the use, as the particulate carrier, of: graft copolymer (A) whose graft chain is poly N-alkylacrylamide chain, poly N-alkylmethacrylamide chain, etc.; and composition containing a combination of the graft copolymer (A) and at least one graft copolymer selected from the group consisting of graft copolymers (B-1) having polyacrylic acid or polymethacrylic acid as the graft chain and graft copolymers (B-2) having a polyvinyl amine compound as the graft chain.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: August 8, 2000
    Assignee: Daiichi Pharmaceutical Co., Ltd.
    Inventors: Mitsuru Akashi, Akio Kishida, Shinji Sakuma, Hiroshi Kikuchi
  • Patent number: 6099621
    Abstract: The present invention is directed toward a composition comprising a polyamine or its polymer blend and at least one salt of an aminoacid, the salt of the aminoacid being present in an amount ranging from about 10 to 80 wt % based on the total weight of the composition. Another embodiment of the present invention comprises a membrane suitable for use in separating CO.sub.2 from gas streams containing CO.sub.2, especially H.sub.2 rich gas streams containing CO.sub.2 and CO. The membrane of this invention with polyamine shows higher CO.sub.2 selectivity and permeability than the prior membrane without polyamine.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: August 8, 2000
    Assignee: Exxon Research and Engineering Company
    Inventor: W. S. Winston Ho
  • Patent number: 6087448
    Abstract: Poly(vinylguanidine)-based superabsorbent gels are disclosed. The superabsorbent gels either comprise a mixture of a poly(vinylguanidine) polymer and an acidic water-absorbing polymer, like polyacrylic acid, or comprise a salt of a poly(vinylguanidine) polymer.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: July 11, 2000
    Assignee: AMCOL International Corporation
    Inventors: Michael A. Mitchell, Thomas W. Beihoffer
  • Patent number: 6060563
    Abstract: Graft copolymers having cationic units pendant to the backbone chain are disclosed. These polymers are prepared by reacting a polymer containing halogenated paramethylstyrene units in the chain, e.g., a brominated copolymer of isobutylene and para-methylstyrene, with an anionically polymerized polymer made using an organolithium initiator compound having the formula R.sub.1 R.sub.2 Z R.sub.3 --Li where R.sub.1 and R.sub.2 are alkyl radicals, R.sub.3 is a direct link or an organic radical and Z is nitrogen or phosphorous. Reaction of the anionically polymerized polymer having an R.sub.1 R.sub.2 Z R.sub.3 --end group with the halogenated polymer leads to graft polymers coupled by a quaternary ammonium or phosphonium groups.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: May 9, 2000
    Assignee: Exxon Research and Engineering Co
    Inventors: Dennis G. Peiffer, Hsien-Chang Wang, Pamela Jean Wright, Joseph A. Sissano, Lewis J. Fetters, Louise M. Wheeler, Rebecca L. Rucker
  • Patent number: 6040025
    Abstract: The present invention is directed to a multilayer material having in order a layer of fluorinated polymer, a layer of binder for fluorinated polymer having a polymer A with moieties (1)-(4), and a layer of polymer which is incompatible with the fluorinated polymer. The multilayer material is useful for making a pipe which has a superior barrier properties to petroleum products and the additives thereof. The present invention also relates to a pipe having a multilayer structure having two layers of polyamide and a layer of binder comprising a polymer A with glutarimide moieties (1)-(4) in between. The pipe has superior barrier properties to petroleum products and the additives.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: March 21, 2000
    Assignee: Elf Atochem S.A.
    Inventor: Serge Lorek
  • Patent number: 6037415
    Abstract: A composition for use in the finishing of a polymer surface comprises a dry, stable homogeneous mixture of pigment and a thermoplastic resin compatible with the polymer surface. The homogeneous mixture is soluble in a solvent to form a lacquer, for application to the surface, that has a colour determined by the amount and chromatic characteristics of the pigment in the dry mixture. The composition can be delivered to a customer and conveniently mixed on site to produce a lacquer having the desired colour characteristics.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: March 14, 2000
    Assignee: Stuart Plastics Ltd.
    Inventor: Gordon Pawelchak
  • Patent number: 6030571
    Abstract: A method of molding which comprises preparing a molding material by compounding a filler and a curable composition, the filler being in an amount of 0 to 800 weight parts based on 100 weight parts of the curable composition and optionally aging the molding material at room temperature or by heating, followed by casting the molding material into a mold and curing the molding material under atmospheric pressure or higher, and articles molded by such method.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: February 29, 2000
    Assignee: NOF Corporation
    Inventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
  • Patent number: 6020433
    Abstract: An anionic electrodeposition coating composition containing, as the heat curable resin components, (A) a water-dispersible vinyl copolymer having hydroxyl group, carboxyl group and an ester linkage modified by a lactone group compound and (B) a crosslinking agent.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: February 1, 2000
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Koji Hirano, Hiroshi Inoue, Shinji Miyatake, Masahiro Kondo
  • Patent number: 6013733
    Abstract: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer.
    Type: Grant
    Filed: March 11, 1998
    Date of Patent: January 11, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Debra L. Singer, Kurt G. Olson, Kurt A. Humbert, Karen A. Barkac, Mark E. Wozniak
  • Patent number: 5998566
    Abstract: The improved phenol derivatives having a phenolic structure as part of the molecular backbone are produced by reacting condensed polycyclic aromatic hydrocarbons, either individually or in combination with unsaturated cyclic aliphatic hydrocarbons, with phenols in the presence of Friedel-Crafts catalysts and have softening points of no more than 150.degree. C., number average molecular weights of 250-800 and phenolic hydroxyl equivalents of 140-850 g/eq. These phenol derivatives are useful either as starting materials for the manufacture of heat-resistant thermosetting resins or as modifiers thereof. They can be produced by reacting the indicated components in the presence of Friedel-Crafts catalysts, typically a mixture of hydrogen fluoride and boron trifluoride, at temperature of 0-350.degree. C.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: December 7, 1999
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takashi Kojima, Takafumi Yoshimura
  • Patent number: 5985950
    Abstract: 1,2-Disulfones are particularly suitable as thermally and photochemically activatable latent acid catalysts for binder systems which contain at least one acid-curable component.
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: November 16, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ekkehard Bartmann, Jorg Ohngemach
  • Patent number: 5962554
    Abstract: Polymers composed of at least >80% by weight of monomers of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.3 -alkyl,R.sup.4 is C.sub.1 -C.sub.5 -alkyl andX is 0 or NH,are used as assistants in the drying of aqueous polymer dispersions and, in the case of a weight average relative molecular weight of from 5000 to 35,000, additionally as protective colloid for the preparation of aqueous polymer dispersions by the free radical aqueous emulsion polymerization method.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: October 5, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Joachim Pakusch, Bernhard Schuler, Walter Machtle, Roland Baumstark
  • Patent number: 5962578
    Abstract: Poly(dialkylaminoalkyl (meth)acrylamide)-based superabsorbent gels are disclosed. The superabsorbent gels either comprise a mixture of a poly(dialkylaminoalkyl (meth) acrylamide) polymer and an acidic water-absorbing polymer, like polyacrylic acid, or comprise a salt of a poly(dialkylaminoalkyl (meth)acrylamide) polymer. An improved method of preparing an N-(dialkylaminoalkyl) (meth)acrylamide monomer also is disclosed.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: October 5, 1999
    Assignee: AMCOL International Corporation
    Inventors: Thomas W. Beihoffer, Michael A. Mitchell, Leticia L. Trzupek
  • Patent number: 5948866
    Abstract: A powder paint composition and application method therefor are provided which can form a paint coating which has superior mar resistance and for which the external appearance, such as its smoothness and sharpness, is excellent.This paint powder composition comprises a multi-functional vinyl-type copolymer (A) which has a glass transition temperature of 40.degree. C. and which contains functional groups which are reactable with carboxylic acid; a polycarboxylic acid (B); and a multi-functional vinyl-type copolymer (C) which has a glass transition temperature of 0.degree. C. and which contains functional groups which are reactable with carboxylic acid.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: September 7, 1999
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Hirofumi Takeda, Ikuo Nakaya, Michiya Sugiyama, Akio Shoji
  • Patent number: 5916968
    Abstract: A graft copolymer for use as an adhesive for drug delivery patches or dressings that is resistant to dissolution in the presence of skin penetration enhancers comprises copolymerized acrylic and, optionally, vinyl monomers, to form a backbone polymer, to which are grafted polymeric moieties that do not absorb greater than 3% by weight of a skin-penetration enhancer under thermodynamic equilibrium at 25.degree. C. if independently introduced into an excess of the enhancer. Preferably, the grafted polymers are selected from the classes of polybutylene, polysaccharide, poly(ethyleneoxide/propyleneoxide), and polyamide polymers, and specific grafted polymers will depend on the specific enhancers used in a particular drug delivery system.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: June 29, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Deepak Hariharan, Roman Bradel, Rama Chandran, Pravin Kukkala
  • Patent number: 5908474
    Abstract: The present invention provides a dye-fixing agent, obtainable by reacting in a first reaction step, either a homopolymer of diallylamine or N-methyl-diallylamine or a copolymer of diallylamine and N-methyl-diallylamine, with an epihalohydrin, the reaction optionally taking place in the presence of an aliphatic amine or polyamine, or reacting the homopolymer or copolymer with a product obtainable by a reaction of epihalohydrin with an aliphatic amine or polyamine, optionally followed by partial quaternization of the reaction product of the first reaction step, characterized in that the end product possesses at least 10 mol % of tertiary amino groups of the following formula (I), based on the total number of amino groups ##STR1## wherein X=halogen, with the provisos that when the homopolymer is an N-methyl-diallylamine, the presence of an aliphatic amine or a polyamine is obligatory in the reaction with the epihalohydrin and when the homopolymer is a homopolymer of diallylamine, partial quaternisation of the re
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: June 1, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bernard Danner, Jurg Heller
  • Patent number: 5907011
    Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: May 25, 1999
    Assignee: Clariant GmbH
    Inventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
  • Patent number: 5905118
    Abstract: Disclosed herein are terpolymers of styrene, acrylonitrile and dimethyl styrene phosphonate and blends thereof with poly(styrene acrylonitrile) polymers and polymers and copolymers of methylmethacrylate.
    Type: Grant
    Filed: April 24, 1998
    Date of Patent: May 18, 1999
    Assignee: Bayer Antwerpen S.A./N.V.
    Inventor: Allen Robert Padwa
  • Patent number: 5891956
    Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California, Office of Technology Transfer
    Inventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
  • Patent number: 5849834
    Abstract: A W/O type emulsified composition comprising an oil phase containing ethyl cellulose and a solvent capable of swelling ethyl cellulose and a water phase containing a water soluble polymer(s) emulsified as a water-in-oil type (W/O type) emulsion. A W/O type emulsified composition comprising an oil phase containing ethyl cellulose and a solvent capable of swelling ethyl cellulose and a water phase containing a polyion complex comprising cationized cellulose and sodium hyaluronate emulsified as a water-in-oil type (W/O type) emulsion.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: December 15, 1998
    Assignee: Shiseido Co., Ltd.
    Inventors: Fumiaki Matsuzaki, Toshio Yanaki, Michihiro Yamaguchi
  • Patent number: 5840806
    Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: November 24, 1998
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
  • Patent number: 5827928
    Abstract: A one-component, thermosetting resin composition curable through a Michael reaction between (a) a component having a plurality of .alpha., .beta.-unsaturated carbonyl groups and (b) a component having a plurality of activated methylene of activated methyne groups is disclosed. The curing reaction is catalyzed with a quaternary ammonium, quaternary phosphonium or tertiary sulfonium salt in the presence of a five-membered cyclic carbonate compound independently added to the composition or covalently attached to either component (a) or component (b).
    Type: Grant
    Filed: April 11, 1996
    Date of Patent: October 27, 1998
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hideo Morimoto, Takashi Irie, Kei Aoki, Haruhiko Sawada
  • Patent number: 5795939
    Abstract: This invention provides an adhesion binder for binding fluorinated polymers, for example PVDF, with incompatible polymers such as polyamides. The binder is a polymer A which has glutarimide, acid, anhydric and acrylate units, and is useful for the production of fuel hoses. When mixed with a fluorinated polymer such as PVDF, copolymer A acts both as a binder and as a barrier.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: August 18, 1998
    Assignee: Elf Atochem S.A.
    Inventor: Serge Lorek
  • Patent number: 5747145
    Abstract: The composition of the present invention is a miscible blend comprising a first addition copolymer and a second addition copolymer, each having a weight-average molecular weight of about 30,000 to 100,000 and a number-average molecular weight of about 5,000 to 50,000, and each comprising repeating units of (1) at least one of an aromatic vinyl monomer of the structure, ##STR1## where Ar is phenylene or naphthylene and R.sup.1 and R.sup.2 are H or lower alkyl; and (2) at least one of (a) an acrylic ester of the structure ##STR2## where R.sup.3 is linear or branched C.sub.1 -C.sub.10 alkyl and R.sub.4 is H or lower alkyl, or (b) a divinyl compound of the structure ##STR3## where R.sup.5 and R.sup.6 are H, Cl, or CH.sub.3. The polymer composition comprises a miscible blend of the above-described first and second addition copolymers.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: May 5, 1998
    Assignee: Eastman Kodak Company
    Inventors: Louis Joseph Sorriero, John J. Fitzgerald
  • Patent number: 5733538
    Abstract: A hemocompatible surface-modifying additive is provided for modifying polyurethane or polyurethane urea substrates. The additive has a polyurethane or polyurethane urea hard block or an alternative block which is miscible with the poly(urethane) or poly(urethane-urea) base polymer, a polysiloxane hydrophobic soft block, an optional hydrophilic spacer and a peptide selected from the group consisting of Arg-Gly-Asp, X-Arg-Gly-Asp, Arg-Gly-Asp-X and X-Arg-Gly-Asp-X', wherein X and X' are amino acids.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 31, 1998
    Assignee: Thoratec Laboratories, Inc.
    Inventor: Judy S. Riffle
  • Patent number: 5717033
    Abstract: A particulate polymer A having a mean particle size of less than 1000 nm consists ofa1: up to 99.8% by weight of at least one vinylaromatic monomer a1,a2: up to 99.8% by weight of at least one alkyl methacrylate a2 where the alkyl radical is of 1 to 8 carbon atoms,a3: up to 50% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer a3,a4: from 0.1 to 10% by weight of at least one polyfunctional, crosslinking monomer a4 anda5: from 0.1 to 15, preferably from 0.5 to 10, % by weight of at least one monomer a5 containing one or more acidic, basic or epoxy groups,the sum of the components a1, a2 and a3 being from 75 to 99.8% by weight, based on A, and the sum of a1, a2, a3, a4 and a5 being 100% by weight, based on A.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: February 10, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Fischer, Norbert Guntherberg, Graham Edmund McKee
  • Patent number: 5712326
    Abstract: The biocompatibility of various polymers is improved by blending with them a polymer including a zwitterionic group. The zwitterionic group is usually an ammonium phosphate ester zwitterionic group and the polymer containing it may be produced by the free radical polymerisation of ethylenically unsaturated monomers including a monomer bearing the zwitterionic group. Blending of the two polymers may be achieved by dry blending particulate polymers or by mixing the polymers in liquid dispersion or solution followed by removal of the liquid medium. The fibrinogen absorption and/or platelet activation of polymers may be reduced to a value of less than 80% or even less than 60% of the base polymer by introducing amounts of more than 10% or mare than 30% of the zwitterionic group containing polymer. Preferred blends are of copolymers of 2-(methacryloyloxyethyl)-2'-(trimethylammonium)ethyl phosphate inner salt with higher alkyl (meth) acrylate, blended with olefin polymers and/or with rubber latices.
    Type: Grant
    Filed: December 5, 1994
    Date of Patent: January 27, 1998
    Assignee: Biocompatibles Limited
    Inventors: Stephen Alister Jones, Peter William Stratford, Stephen Rimmer
  • Patent number: 5707943
    Abstract: Mixtures of esterified carboxy-containing interpolymers and additive concentrates and lubricating oil compositions containing same. Residual acidity of the esterified interpolymers may be neutralized by reaction with an amine.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: January 13, 1998
    Assignee: The Lubrizol Corporation
    Inventor: Michael J. Covitch
  • Patent number: 5663262
    Abstract: The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: September 2, 1997
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Shinsuke Shirakawa, Kazunori Kanda, Mitsuo Yamada, Kei Aoki, Satoshi Urano, Nobuaki Tomita
  • Patent number: 5660937
    Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 26, 1997
    Assignee: Nippon Oil And Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5661219
    Abstract: A curable composition comprising (A) a compound having in the molecule two or more specific blocked carboxyl groups: (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a catalytic component selected from the following: (a) a thermal latent acid catalyst which comprises a compound having a epoxy group, a specific compound having a sulfur atom and a specific Lewis acid; (b) a thermal latent acid catalyst which comprises a specific compound, having at least one of a nitrogen atom, an oxygen atom, a phosphorus atom or a sulfur atom, a specific compound having a halogen atom and a specific Lewis acid having at least one of an aluminum atom, a zinc atom or a tin atom; or a mixture which comprises (c) a metallic chelate compound and a specific organic silicon compound or a condensate thereof.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: August 26, 1997
    Assignee: Nof Corporation
    Inventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
  • Patent number: 5654369
    Abstract: The invention provides a thermoplastic resin composition uniformly and permanently rendered antistatic which comprises (A) 100 parts by weight of a thermoplastic resin, (B) 3-30 parts by weight of a cationic copolymer comprising 80-98 mol % of an ethylene unit and 2-20 mol % of a cationic unit and having a weight-average molecular weight of 1,000-50,000, and (C) 0.
    Type: Grant
    Filed: July 22, 1996
    Date of Patent: August 5, 1997
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Takayuki Tsubaki, Yutaka Nakayama, Hideyuki Sumi, Hiroshi Hotta
  • Patent number: 5654358
    Abstract: Disclosed are a polyphenylene sulfide composition having excellent impact characteristics, melt flow characteristics and flexibility which comprises, as indispensable components, (A) a polyphenylene sulfide, (B) an epoxy group-containing olefinic polymer, and (C) at least one elastomer selected from ethylene/propylene copolymers, ethylene/butene copolymers, ethylene/propylene/diene copolymers, hydrogenated styrene/butadiene/styrene block copolymers, copolymers of ethylene with a monomer selected from acrylic acid, methacrylic acid and alkyl esters and metal salts thereof, and polyamide elastomers; and a shaped article made from the polyphenylene sulfide composition.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 5, 1997
    Assignee: Toray Industries, Inc.
    Inventors: Sho Kadoi, Norio Shimasaki, Kazuhiko Kobayashi, Katuya Ohno
  • Patent number: 5597859
    Abstract: A novel dispersant system is disclosed for use in forming dialkylaminoalkyl (meth)acylamide polymer dispersions.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: January 28, 1997
    Assignee: Nalco Chemical Company
    Inventors: John R. Hurlock, Manian Ramesh
  • Patent number: 5587426
    Abstract: The present invention provides:(1) a self-crosslinking resin (I) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (A) having at least two free isocyanate groups in the molecule and an acrylic resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with some of the free isocyanate groups of the polymer (A), and subsequently reacting a blocking agent with all the remaining free isocyanate groups, and(2) a self-crosslinking resin (II) having a blocked isocyanate group and a hydroxyl group in the molecule and characterized in that the resin is prepared from a vinyl polymer (C) having a free isocyanate group and a blocked isocyanate group in the molecule and the acrylic resin (B) having at least two hydroxyl groups in the molecule by reacting some of the hydroxyl groups of the resin (B) with all the free isocyanate groups of the polymer (C).
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: December 24, 1996
    Assignee: Kansai Paint Company, Limited
    Inventors: Yoshiyuki Yukawa, Motoshi Yabuta, Akimasa Nakahata, Yoh Sugimura
  • Patent number: 5580924
    Abstract: Reduced gloss polycarbonate graft polymer blends are provided by a process which involves compounding styrene-acrylonitrile copolymer in the presence of an electrophilic reagent and preferably an acid to form gels, and then compounding the resultant gels with polycarbonate, a styrene-acrylonitrile copolymer and ABS graft polymer to form reduced gloss PC/ABS/SAN composition. The process limits side reactions during gel formation by preparing the gels first and then compounding the gels with the other resin materials. The blends are useful as molding resins and the gelled acrylonitrile polymer is useful as a gloss reducing additive.
    Type: Grant
    Filed: February 23, 1993
    Date of Patent: December 3, 1996
    Assignee: General Electric Company
    Inventors: Robert H. Wildi, Keith E. Cox, Edward J. Fewkes
  • Patent number: 5578677
    Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: November 26, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5549932
    Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 27, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5548029
    Abstract: Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 20, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C. Chung, Anthony J. Dias, Joseph A. Olkusz
  • Patent number: 5520849
    Abstract: New electrically conductive polymer compositions comprisei) an electrically conductive polymer a) of one or more oxidatively polymerizable aromatic compounds andii) a polymer d) having ammonium, phosphonium or sulfonium groups in the polymer chain(s).The polymer compositions comprising polymers a) and d) are prepared by oxidative polymerization of one or more aromatic compounds in the presence of a polymer b) having ammonium, phosphonium or sulfonium groups in the polymer chain(s) and containing a polydentate anionic complex which has a redox potential sufficient for enabling oxidative polymerization of the aromatic compounds. Said polymer b) which has a non-metallic anionic complex such as S.sub.2 O.sub.8.sup.2- is also novel.
    Type: Grant
    Filed: June 23, 1994
    Date of Patent: May 28, 1996
    Assignees: The Dow Chemical Company, Deborah C. Dulude
    Inventor: Jurgen Eiffler
  • Patent number: 5512634
    Abstract: Resin compositions having excellent heat resistance, izod impact strength, rigidity and dimensional resistance and the like, applied in the fields of the automobile, electric and electronic, and the like industries. The resin composition comprising: a) a resin in which 30 to 98 mole % of the component (I) are contained in the whole polymer and 70 to 2 mole % of the component (II) are contained in the whole polymer, its weight-average molecular weight converted into that of polystyrene being 1.times.10.sup.3 or more to 5.times.10.sup.6 or less, and b) an olefin resin; then the a)/b) content being 5/95 to 99/1 as a weight ratio, ##STR1## wherein R.sub.1 is an alkyl group having 1 to 18 carbon atom(s) or a cycloalkyl group having 3 to 12 carbon atoms; and ##STR2## wherein R.sub.2 is hydrogen or an alkyl group having 1 to 8 carbon atom(s), and R.sub.3 and R.sub.4 is an alkyl group having 1 to 8 carbon atoms.
    Type: Grant
    Filed: June 21, 1994
    Date of Patent: April 30, 1996
    Assignee: Tosoh Corporation
    Inventor: Toru Doi
  • Patent number: 5502110
    Abstract: A resin composition for an electrophotographic toner is here disclosed which comprises an ethylene series high polymer (Y) and an ethylene series polymer (X) prepared from 100 parts of a bifunctional ethylene series unsaturated monomer and 0.01-10 parts by weight of a substance having three or more peroxide groups in the molecule and/or a substance having one or more unsaturated functional groups and one or more peroxide groups in the molecule, Mw/Mb (Mw is weight-average molecular weight, and Mb is weight-average molecular weight between crosslinking points) of said polymer (X) being from 2 to 99, Mw of said polymer (X) being 50,000 or less. This resin composition is excellent in the balance of various physical properties required for the toner, and particularly, it is excellent in offset resistance and toner strength.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: March 26, 1996
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Katsuru Matsumoto, Nobuhiro Hirayama, Kenji Uchiyama, Shoji Kawasaki, Tamami Fukui, Katsuo Uramoto
  • Patent number: 5498670
    Abstract: Disclosed herein are crosslinked spherical fine particles having good toughness, elastic properties, and chemical properties, and a process for producing the same, said fine particles being obtained by radical polymerization in the suspended state of a component [M] capable of radical polymerization containing a vinyl group-containing compound (V) capable of radical polymerization which is obtained by reaction of (a) a selected polyol, (b) an isocyanate group-containing compound, and (c) an active hydrogen-containing vinyl monomer capable of radical polymerization. Also disclosed herein are the secondary products of the crosslinked spherical fine particles, which include a coating composition and its derivatives (such as filmlike article, sheetlike article, adhesive filmlike article, and adhesive sheetlike article) and a peelable pressure-sensitive adhesive and peelable pressure-sensitive adhesive article.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: March 12, 1996
    Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
    Inventors: Takahiro Aoyama, Mitsuo Nakazaki, Akikazu Banba, Masatoshi Yoshida, Toshiaki Matsunaga, Tsuneo Tsubakimoto
  • Patent number: 5468585
    Abstract: A resin composition for use in an electrophotographic toner which comprises an ethylenic polymer (L) having a M.sub.w of not greater than 20,000 and an acid value of 2 to 100 mg KOH/g, and an ethylenic polymer (H) having a M.sub.w of not less than 150,000, a M.sub.w /M.sub.n ratio of not less than 5.0 and a time constant for triboelectric charging (.tau.) of 1.2 to 25, the ethylenic polymers (L) and (H) being present in a weight ratio ranging from 15:85 to 85:15. This resin composition can improve the triboelectric charging properties of the toner.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: November 21, 1995
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Katsuru Matsumoto, Nobuhiro Hirayama, Shoji Kawasaki, Kenji Uchiyama, Katsuo Uramoto, Tamami Fukui