At Least One Of These Polymers Is Derived From Two Or More Reactants Patents (Class 525/237)
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Publication number: 20120219814Abstract: Methods of improving polyethylene stretch film that include providing interpolymer resin particles, forming a polyethylene blend composition by blending from about 0.1 to about 10 percent by weight based on the weight of the blend composition of interpolymer resin particles into one or more polyethylene resins; and forming a film from the polyethylene blend composition. The interpolymer resin particles contain a styrenic polymer intercalated within a first polyolefin, where the first polyolefin is present at from about 20% to about 80% by weight based on the weight of the particles, and the styrenic polymer is present at from about 20% to about 80% by weight based on the weight of the particles.Type: ApplicationFiled: February 14, 2012Publication date: August 30, 2012Applicant: NOVA CHEMICALS INC.Inventors: Eric Vignola, Daniel Purpura, Paul Tas, Jamie Marler, Shaun Pirtle
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Publication number: 20120178848Abstract: The invention relates to the use of butyl ionomers or partially halogenated butyl ionomers in reducing a population of and/or preventing accumulation of organisms. The organisms may be bacteria, algae, fungi, mollusca or arthropoda. The invention also relates to coatings for shaped articles comprising the butyl ionomers.Type: ApplicationFiled: February 5, 2010Publication date: July 12, 2012Applicant: LANXESS INC.Inventors: Dana Adkinson, Lorenzo P. Ferrari, J. Scott Parent, Ralph A. Whitney, Rui Resendes
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Patent number: 8207386Abstract: Rubber-like or rubber-like-material-containing articles contain or are made from hydrogenated natural polyisoprenoids or modified products thereof. These rubber-like or rubber-like-material-containing articles include a rubber-like elastic article made from a hydrogenated natural polyisoprenoid or a modified product thereof. A polymer obtained by reacting a natural polyisoprenoid with hydrogen in a solvent in the presence of a hydrogenation catalyst, for example, can be used as the hydrogenated natural polyisoprenoid. The hydrogenated natural polyisoprenoid preferably has a degree of hydrogenation of 50% or more. The hydrogenated natural polyisoprenoid preferably has a weight-average molecular weight of 20×104 or more and a molecular-weight distribution of 2.0 or more. The rubber-like or rubber-like-material-containing articles have excellent heat resistance and weather resistance, and are also excellent in view of resources and environment, because they use plant-derived raw materials.Type: GrantFiled: December 1, 2004Date of Patent: June 26, 2012Assignees: Nitta Corporation, Shinichi InoueInventors: Shinichi Inoue, Tomohiro Nishio, Haruhiko Ito, Kenichi Horiuchi, Toshiaki Kasazaki
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Publication number: 20120157568Abstract: The invention relates to a silica reinforced rubber composition comprised of low Tg polybutadiene, particularly high cis 1,4-polybutadiene or high trans 1,4-polybutadiene with or without functional groups, and high Tg styrene/butadiene elastomers, particularly functionalized styrene/butadiene, elastomers, together with high Tg liquid unsaturated conjugated diene-based polymer, particularly styrene/butadiene polymer, which can also be functionalized, and high glass transition or softening point temperature (Tm or Tg) resins, particularly high Tg styrene/alpha methylstyrene resin. The invention relates to a tire having a tread comprised of such rubber composition.Type: ApplicationFiled: November 9, 2011Publication date: June 21, 2012Inventors: Paul Harry Sandstrom, Hans-Bernd Fuchs, Erik Paul Sandstrom, Michelle L. Sandstrom
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Publication number: 20120122359Abstract: Adhesive (co)polymers of this disclosure comprise: a) an isobutylene copolymer having pendent succinate groups and optionally a tackifier. The pendent succinic acid groups ionically crosslinks the isobutylene copolymer by hydrogen boding with adjacent pendent succinic acid groups.Type: ApplicationFiled: October 27, 2011Publication date: May 17, 2012Inventors: Hae-Seung Lee, Joon Chatterjee, Gregg A. Caldwell, Babu N. Gaddam
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Publication number: 20120041130Abstract: The present invention relates to a crosslinkable rubber composition, the use thereof, the rubber grains formed therefrom, and a method for preparing and injection molding the rubber grains. The crosslinkable rubber composition includes at least a styrene butadiene copolymer, a softener for rubber, a flow modifier and a peroxide vulcanizing agent. The crosslinkable rubber composition is suitable for being made into rubber products. It can be made into rubber grains that will not crosslink below a temperature of 80° C. The rubber grains are formed through internal mixing, open mixing and pelleting extrusion. The rubber composition and the rubber grains of the present invention can be formed directly by injection molding and kept at room temperature over a long period of time.Type: ApplicationFiled: July 30, 2009Publication date: February 16, 2012Applicant: SHANGHAI DRB&TAFU INDUSTRY CO.Inventor: Sunyong Ye
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Publication number: 20120010356Abstract: The present invention relates to improved compositions of SSBR rubber. The improved compositions exhibit sufficient or improved balance of characteristics such as rolling resistance, HBU, abrasion, grip, and/or tear. The compositions may be made in an efficient, cost-effective manner.Type: ApplicationFiled: February 24, 2010Publication date: January 12, 2012Inventors: Evemarie Hamann, Hagen Thomas Bartossek, Joachim Kiesekamp
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Publication number: 20110236705Abstract: A mixture of a high molecular weight EPDM rubber with a low molecular weight (liquid) EPDM rubber provides a highly useful laser-ablatable flexographic printing plate precursor formulation. This formulation is sensitive to infrared radiation by the incorporation of an IR absorbing compound such as a carbon black. The inclusion of the liquid EPDM rubber avoids the need for plasticizers such as process oils during manufacturing, and provides improved image sensitivity, print quality, and run length. Both flexographic printing plates and printing sleeves can be made using the mixture of EPDM rubbers.Type: ApplicationFiled: March 29, 2010Publication date: September 29, 2011Inventors: Ophira Melamed, Ido Gal, Limor Dahan
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Publication number: 20110190440Abstract: This invention provides a rubber composition being excellent in the workability during production and the heat resistance and high in the storage elastic modulus (G?) and small in the loss tangent (tan ?), which is formed by compounding 1-60 parts by mass of a low-molecular weight conjugated diene-based polymer (B) having a weight average molecular weight as measured through a gel permeation chromatography and converted to polystyrene of 10,000-200,000 and a vinyl bond content in a conjugated diene compound portion of not less than 40% based on 100 parts by mass of a rubber component (A) comprised of at least one selected from the group consisting of natural rubber, polyisoprene rubber, styrene-butadiene copolymer rubber, polybutadiene rubber and isobutylene isoprene rubber, wherein the rubber component (A) comprises natural rubber and/or polyisoprene rubber and a proportion of styrene units in total of the low-molecular weight conjugated diene-based polymer (B) is less than 5% by mass.Type: ApplicationFiled: March 5, 2008Publication date: August 4, 2011Applicant: Bridgestone CorporationInventors: Fuminori Ohta, Koji Masaki
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Patent number: 7989550Abstract: A rubber composition for a tire tread comprising (A) 100 parts by weight of a rubber component containing (a) 50 to 95 parts by weight of a diene-based rubber containing 50 to 100% by weight of an aromatic vinyl-conjugated diene copolymer rubber and (b) 5 to 50 parts by weight of a conjugated diene-based rubber gel having a toluene swelling index Qi of 16 to 70 and (B) 3 to 40 parts by weight, based upon 100 parts by weight of the total rubber component, of a copolymer resin of an aromatic vinyl and dipentene and/or pinene having a softening point of 100 to 150° C. and a high performance tire using the above rubber composition are disclosed.Type: GrantFiled: December 21, 2007Date of Patent: August 2, 2011Assignee: The Yokohama Rubber Co., Ltd.Inventors: Naoya Amino, Akitomo Sato
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Patent number: 7981966Abstract: There is obtained a rubber composition excellent in processability of unvulcanized compounded rubber, excellent in wear resistance and wet skid resistance of vulcanized rubber, low in rolling resistance, and suitable for tire applications, particularly for tire tread applications in which importance is given to low fuel consumption and safety. A rubber composition mainly comprising (I) 0.5 to 35% by weight of a conjugated diene-based (co)polymer rubber having an amino group and an alkoxysilyl group on a polymer chain and having a weight average molecular weight of 1,000 to 90,000, and (II) 99.5 to 65% by weight of a conjugated diene-based (co)polymer rubber having a weight average molecular weight of 100,000 to 2,000,000 (with the proviso that (I)+(II)=100% by weight).Type: GrantFiled: March 2, 2005Date of Patent: July 19, 2011Assignee: JSR CorporationInventors: Naokazu Kobayashi, Kouta Taniguchi, Toshihiro Tadaki
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Publication number: 20110139496Abstract: A resin composition which is low in a roughness of an insulating layer surface and capable of forming thereon a plated conductor layer having a sufficient peel strength in a wet roughing step and which is excellent in dielectric characteristics and a coefficient of thermal expansion, is disclosed. The resin composition contains a cyanate ester resin and a specified epoxy resin.Type: ApplicationFiled: December 14, 2010Publication date: June 16, 2011Applicant: AJINOMOTO CO., INC.Inventor: Shigeo NAKAMURA
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Patent number: 7939594Abstract: The invention provides a composition that contains at least one specific non-crosslinkable organic medium at least one microgel and at least one thickening agent, a process for the preparation thereof and uses of the compositions.Type: GrantFiled: March 13, 2006Date of Patent: May 10, 2011Assignees: Rhein Chemie Rheinau GmbH, LANXESS Deutschland GmbHInventors: Werner Obrecht, Torsten Ziser, Thomas Früh, Patrick Galda, Achim Fessenbecker
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Patent number: 7928184Abstract: The present invention provides a method of manufacturing a stabilized polyacetal resin, comprising the step of applying a heat treatment to a polyacetal resin having an unstable terminal group in the presence of an unstable terminal group decomposer selected from the following Group I, Group II and Group III, thereby decreasing the unstable terminal group: unstable terminal group decomposer of Group I: (I) a quaternary ammonium salt of an acidic cyclic amide compound, unstable terminal group decomposer of Group II: (II) a quaternary ammonium salt of a polycarboxylic acid intramolecularly having four or more carboxyl groups and/or a quaternary ammonium salt of an aminocarboxylic acid intramolecularly having one or more carboxyl group(s), unstable terminal group decomposer of Group III: (III) a quaternary ammonium salt, wherein a compound providing a counter-anion of a quaternary ammonium salt is at least one selected from the group consisting of the following (i) to (v): (i) a carbonic acid monoesterType: GrantFiled: March 7, 2006Date of Patent: April 19, 2011Assignee: Polyplastics Co., Ltd.Inventors: Hatsuhiko Harashina, Hiroaki Nakao
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Publication number: 20110077317Abstract: Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.Type: ApplicationFiled: December 3, 2010Publication date: March 31, 2011Inventors: Sunny Jacob, Alistair D. Westwood, Tonson Abraham
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Patent number: 7914868Abstract: Improved single ply, water proof roof coverings having an extruded pressure sensitive rubber-based adhesive backing for attachment to a substrate such as the roof of a building or a transport vehicle, the adhesive consisting of polyisobutylene and at least one polymer comprising conjugated diene monomers.Type: GrantFiled: February 10, 2005Date of Patent: March 29, 2011Assignee: Building Materials Investment CorporationInventors: Michael P. Naipawer, III, Anthony Ruffine
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Publication number: 20110034577Abstract: The invention provides a composition comprising at least the following: A) from “greater than zero” to “less than 100” phr (based on sum weight of Components A and B) of an interpolymer comprising, in polymerized form, ethylene, an ?-olefin and a nonconjugated polyene, and wherein the interpolymer comprises less than, or equal to, 5 weight percent of the polyene, based on the total amount of polymerized monomers, and wherein the interpolymer has a molecular weight distribution (Mw/Mn) less than 3; B) from “less than 100” to “greater than zero” phr (based on sum weight of Components A and B) of an interpolymer comprising, in polymerized form, ethylene, an ?-olefin and a nonconjugated polyene, and wherein the interpolymer comprises greater than, or equal to, 5 weight percent of the polyene, based on the total amount of polymerized monomer; and wherein the total polyene content is less than 7 weight percent (based on the total amount of polymerized monomers in the interpolymers of Components A and B).Type: ApplicationFiled: June 18, 2009Publication date: February 10, 2011Applicant: Dow Global Technologies, Inc.Inventors: Shuwen Peng, Wenbin Liang, Stephen Y. Cheng, Peter X. Lin, Shih-Yaw Lai
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Patent number: 7875678Abstract: Compositions, processes, and methods are provided relating to styrenic polymers, including high impact polystyrene (HIPS), also referred to as rubber-modified polystyrene. In one aspect, a process is provided for making high impact polystyrenes, comprising the steps of combining a monovinylarene component, a monovinylarene-conjugated diene block copolymer, and a conjugated diene polymer. In another aspect, the feed components form an emulsion having a continuous phase and a dispersed phase. The continuous phase comprises at least a portion of the monovinylarene component and at least a portion of the conjugated diene polymer. The dispersed phase is suspended within the continuous phase, and comprises globules having at least a portion of the monovinylarene-conjugated diene block copolymer, a remaining portion of the monovinylarene component, and a remaining portion of the conjugated diene polymer.Type: GrantFiled: April 11, 2006Date of Patent: January 25, 2011Assignee: Chevron Phillips Cheimcal Company, LPInventors: Michael J. Hanner, Chen-Youn Sue, Clifford C. Pettey, Carleton Stouffer, Paul M. Hunt, Ken E. Bowen
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Patent number: 7820763Abstract: A rubber composition comprises a rubber component. The rubber component contains (A) 1-70 weight parts of polybutadiene rubber having a Mooney viscosity (ML) of 35-50 and composed of (a) 1-9 weight % of a boiled n-hexane insoluble fraction having a melting point of 180° C. or higher and (b) 99-91 weight % of a boiled n-hexane soluble fraction. The rubber component also contains (B) 99-30 weight parts of diene-based rubber other than (A). A crosslinking coagent (C) is mixed in the rubber component.Type: GrantFiled: January 6, 2006Date of Patent: October 26, 2010Assignee: Ube Industries, Ltd.Inventors: Naomi Okamoto, Kouji Ishiguchi
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Publication number: 20100222445Abstract: The copolymer rubber composition comprises 60 to 75% by weight of a copolymer rubber (1) and 40 to 25% by weight of a copolymer rubber (2), and [iodine value of the copolymer rubber (1)—iodine value of the copolymer rubber (2)] is 5 to 30. The copolymer rubber (1) is an ethylene-?-olefin-nonconjugated polyene copolymer rubber having an ethylene unit of 50 mol % to 70 mol %, an ?-olefin unit of 50 mol % to 30 mol %, and an iodine value of 15 to 45, and the copolymer rubber (2) is an ethylene-?-olefinic copolymer rubber having an ethylene unit of more than 70 mol % and 95 mol % or less, an ?-olefin unit of less than 30 mol % and 5 mol % or more, and an iodine value of 10 to 30.Type: ApplicationFiled: February 24, 2010Publication date: September 2, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Sadayuki Nakano
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Publication number: 20100137519Abstract: This invention relates to a process for preparing a vulcanized rubber blend, said blend comprising (a) natural rubber or poly-isoprene rubber, (b) butadiene based rubber, and (c) rubber with an essentially saturated backbone. The improvement is that rubber c) is pre-heated with at least part of the vulcanization system before mixing with rubbers a) and b) and co-vulcanizing.Type: ApplicationFiled: February 21, 2006Publication date: June 3, 2010Inventors: Jacobus Wilhelmus Maria J.W.M. Noordermeer, Nityananda L. Naskar, Rabindra Nath R.N. Datta
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Publication number: 20100116403Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising a diene based elastomer and from 1 to 30 parts by weight, per 100 parts by weight of elastomer (phr), of a polyketone short fiber having a length ranging from 0.5 to 20 mm having a weight ranging from 0.5 to 5 decitex, and from 1 to 30 phr of an epoxidized polyisoprene having a number-average molecular weight of 5000 to 100000.Type: ApplicationFiled: November 7, 2008Publication date: May 13, 2010Inventors: Ralf Mruk, Frank Schmitz, Serge Julien Auguste Imhoff, Annette Lechtenboehmer, Julia Martine Francoise Claudine Tahon
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Patent number: 7649051Abstract: A flame retardant thermoplastic composition comprising in combination a polycarbonate component; an impact modifier composition, the components of the impact modifier composition comprising a) a bulk polymerized ABS, and b) an impact modifier different from the ABS; an ungrafted rigid copolymer; and a flame retardant. The compositions have an improved balance of physical properties such as impact strength and flow, while at the same time maintaining their good flame performance.Type: GrantFiled: January 24, 2007Date of Patent: January 19, 2010Assignee: SABIC Innovative Plastics IP B.V.Inventors: Shiping Ma, Srinivas Siripurapu, Pei Sun, Karin van de Wetering, Wayne Yao
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Patent number: 7615591Abstract: A rubber composition comprises a diene rubber component, a filler and a softening agent, in which a given amount of a filler is compounded based on 100 parts by mass of a diene rubber component, and a softening agent is included in a given amount per the filler, and not less than 60% by mass of the diene rubber component is a solution-polymerized styrene-butadiene copolymer rubber having a mass average molecular weight of not less than 1,000,000, and the filler is selected from the group consisting of carbon black, silica and an inorganic agent of a formula (I): mM.xSiOy.zH2O (wherein M is at least one metal selected from the group consisting of aluminum, magnesium, titanium and calcium, or an oxide of such a metal or a hydroxide of such a metal, m is a number of 1-5, x is a number of 0-10, y is a number of 2-5 and z is a number of 0-10), wherein each of the filler and the softening agent is charged in at least two fractions.Type: GrantFiled: February 2, 2005Date of Patent: November 10, 2009Assignee: Bridgestone CorporationInventor: Hideki Matsui
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Publication number: 20090272475Abstract: A tire for vehicle wheels, includes at least one structural element obtained by crosslinking a crosslinkable elastomeric composition including at least one vulcanized rubber in a subdivided form surface treated with at least one oxidizing agent; at least one diene elastomeric polymer, and at least one sulfur-based vulcanizing agent. A surface treatment process of vulcanized rubber and crosslinkable elastomeric composition is obtained with the vulcanized rubber in a subdivided form surface treated with at least one oxidizing agent.Type: ApplicationFiled: October 30, 2006Publication date: November 5, 2009Inventors: Emiliano Resmini, Luigia Rossiello, Diego Tirelli, Franco Peruzzotti
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Publication number: 20090215552Abstract: A rubber composition comprises a rubber component. The rubber component contains (A) 1-70 weight parts of polybutadiene rubber having a Mooney viscosity (ML) of 35-50 and composed of (a) 1-9 weight % of a boiled n-hexane insoluble fraction having a melting point of 180° C. or higher and (b) 99-91 weight % of a boiled n-hexane soluble fraction. The rubber component also contains (B) 99-30 weight parts of diene-based rubber other than (A). A crosslinking coagent (C) is mixed in the rubber component.Type: ApplicationFiled: January 6, 2006Publication date: August 27, 2009Applicant: UBE INDUSTRIES, LTD.Inventors: Naomi Okamoto, Kouji Ishiguchi
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Publication number: 20090178748Abstract: Process for manufacturing tires includes the following steps: forming at least one layer including a crosslinkable elastomeric material on an outer surface of a toroidal support the shape of which substantially matches that of the inner surface of the tire; manufacturing a green tire on the toroidal support bearing the at least one layer, the green tire including at least one structural element including a crosslinkable elastomeric material; wherein one crosslinkable elastomeric material of the at least one layer includes a crosslinkable elastomeric composition including at least one sulfur-curable elastomeric polymer and at least one compound having the following general formula (I): A-(S)p—B wherein: p is an integer of 2 to 10; and A and B, which may be the same or different from each other, represent a group having the following general formula (II):Type: ApplicationFiled: July 1, 2005Publication date: July 16, 2009Inventors: Francesca Baione, Luigi Fino, Maurizio Galimberti, Luca Giannini, Attilio Citterio, Marco Martino
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Patent number: 7552752Abstract: The object of the present invention is to provide a rubber composition for base tread enhancing a low fuel consumption property of a vehicle. A rubber composition for base tread comprises a rubber composition containing 15 to 80% by weight of a butadiene rubber obtained by copolymerizing a compound represented by the formula 1, wherein R1 represents an amino group, an alkoxy group, a silyloxy group, an acetal group, a carboxyl group, a mercapto group or a derivative thereof.Type: GrantFiled: August 28, 2007Date of Patent: June 30, 2009Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazuo Hochi
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Patent number: 7544745Abstract: A flame retardant thermoplastic composition comprising in combination a polycarbonate component; an impact modifier composition, the components of the impact modifier composition comprising a) a bulk polymerized ABS, and b) an impact modifier different from the ABS; and a flame retardant. The compositions have an improved balance of physical properties such as impact strength and flow, while at the same time maintaining their good flame performance.Type: GrantFiled: October 25, 2005Date of Patent: June 9, 2009Assignee: SABIC Innovative Plastics IP B.V.Inventors: Shiping Ma, Srinivas Siripurapu, Pei Sun, Wayne Yao
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Publication number: 20090139710Abstract: Swellable compositions and methods of using and controlling them are disclosed. In certain examples, the swellable composition may comprise an active phase responsive to swell upon exposure to a swelling fluid. In some examples, the active phase of the swellable composition is effective to deswell in response to an applied stimulus in the presence of the swelling fluid. In other examples, the swellable composition may further comprise a passive phase responsive to swell to a lesser degree than the active phase upon exposure to the swelling fluid. Devices and systems using the swellable compositions are also described.Type: ApplicationFiled: November 30, 2007Publication date: June 4, 2009Applicant: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Agathe Robisson, Partha Ganguly, Huilin Tu, Tania Chan, Dominique Guillot, Kevin Forbes
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Publication number: 20090105398Abstract: A rubber composition for a pneumatic tire which improves workability of rubber processing and heat generation characteristics, and further improves driveability on dry pavement while maintaining grip performance is provided. The rubber composition for a pneumatic tire includes a rubber component comprising a copolymer rubber having a glass transition point of ?40° C. or higher obtained by copolymerization of 1,3-butadiene with styrene using an organic lithium compound as an initiator, alone or a blend of 50% by weight or more of the copolymer rubber and 50% by weight or less of other diene rubber, silica and a silane coupling agent, and further includes a polymer gel which is diene polymer particles having a toluene swelling index Qi of less than 16 and a glass transition point of from 20 to 80° C. in an amount of from 1 to 30 parts by weight per 100 parts by weight of the rubber component.Type: ApplicationFiled: October 20, 2008Publication date: April 23, 2009Applicant: Toyo Tire & Rubber Co., Ltd.Inventor: Kazuya Hirabayashi
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Patent number: 7458406Abstract: There is provided a rubber composition for a side wall, wherein an amount ratio of resources other than petroleum are increased so as to be ecological and take measures for the decrease in supply of petroleum in the future, which further has excellent flex crack resistance and strength. A rubber composition for a side wall comprising 20 to 60 parts by weight of silica based on 100 parts by weight of a rubber component comprising 40 to 80% by weight of a natural rubber and 60 to 20% by weight of at least one rubber selected from the group consisting of a butadiene rubber, a styrene-butadiene rubber and an epoxidized natural rubber, and 4 to 16 parts by weight of a silane compound represented by the following formula: Xn—Si—Y4-n (wherein X represents an ethoxy group or a methoxy group, and Y represents a phenyl group or an alkyl group) based on 100 parts by weight of silica.Type: GrantFiled: August 11, 2006Date of Patent: December 2, 2008Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Takao Wada, Mamoru Uchida, Tomoaki Hirayama
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Publication number: 20080269385Abstract: A non-halogenated rubber compound is provided for use in conveyor belts, particularly those used in underground mining. The non-halogenated rubber compound is fire-resistant in accordance with MSHA standards and produces acceptable levels of toxicity and smoke upon burning. Such non-halogenated rubber compound includes a blend of rubbery polymers in combination with aluminum trihydrate, which is a fire retardant, and optionally a phosphate plasticizer, which can provide the rubber compound with a more desirable workability. The blend of rubbery polymers is composed of natural rubber and butadiene rubber, and optionally styrene-butadiene rubber, such blend being present in a total amount of 100 phr. In one embodiment, the aluminum trihydrate is present in an amount of about 30 phr to about 150 phr. In another embodiment, the phosphate plasticizer is present in an amount of about 10 phr to about 60 phr.Type: ApplicationFiled: April 25, 2007Publication date: October 30, 2008Inventors: Kenneth Michael Alexander, David Joseph Maguire
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Patent number: 7414094Abstract: A rubber composition for an inner liner improving air retention property of a tire, lowering hysteresis loss and further preventing crack growth is provided. A rubber composition for an inner liner comprising 10 to 50 parts by weight of mica having an aspect ratio of at least 50 and an average particle diameter of 40 to 100 ?m, based on 100 parts by weight of a rubber component comprising 30 to 60% by weight of butyl base rubber, 20 to 50% by weight of natural rubber or isoprene rubber and 10 to 40% by weight of butadiene rubber.Type: GrantFiled: April 18, 2006Date of Patent: August 19, 2008Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Tatsuya Miyazaki
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Publication number: 20080182939Abstract: A thermoplastic elastomer composition of the invention, formed by dynamically crosslinking a polymer composition including a rubber and an olefinic resin and having an average particle size of rubber particles within a specific range, shows an excellent balance of mechanical properties such as flexibility and elastic recovery, and a moldability. Also an inclusion of a (meth)acrylate resin and a hydrogenated diene polymer provides a composition particularly excellent in scratch resistance. Also an inclusion of a maleimide compound provides a composition particularly excellent in injection fusibility. Also an inclusion of an undenatured organopolysiloxane of a specific viscosity and a denatured organopolysiloxane provides a composition particularly excellent in initial slidability and durable slidability.Type: ApplicationFiled: September 27, 2007Publication date: July 31, 2008Applicant: JSR CORPORATIONInventors: Akihiko MORIKAWA, Kentarou Kanae, Hideo Nakanishi, Minoru Maeda, Takahiro Okamoto
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Publication number: 20080161479Abstract: A rubber composition for a tire tread comprising (A) 100 parts by weight of a rubber component containing (a) 50 to 95 parts by weight of a diene-based rubber containing 50 to 100% by weight of an aromatic vinyl-conjugated diene copolymer rubber and (b) 5 to 50 parts by weight of a conjugated diene-based rubber gel having a toluene swelling index Qi of 16 to 70 and (B) 3 to 40 parts by weight, based upon 100 parts by weight of the total rubber component, of a copolymer resin of an aromatic vinyl and dipentene and/or pinene having a softening point of 100 to 150° C. and a high performance tire using the above rubber composition are disclosed.Type: ApplicationFiled: December 21, 2007Publication date: July 3, 2008Applicant: The Yokohama Rubber Co., Ltd.Inventors: Naoya Amino, Akitomo Sato
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Patent number: 7393902Abstract: A rubber composition for a base tread which achieves improved steering stability and rolling resistance properties and a tire containing the same wherein the rubber composition includes a rubber component containing (a) 20 to 60% by weight of a polybutadiene rubber containing 2.5 to 20% by weight of a 1,2-syndiotactic polybutadiene crystal, (b) 5 to 80% by weight of a tin-modified polybutadiene rubber polymerized by a lithium initiator, in which the amount of a tin atom is 50 to 3000 ppm, the amount of a vinyl bond is 5 to 50% by weight and molecular weight distribution (Mw/Mn) is at most 2, and (c) 10 to 75% by weight of a rubber other than (a) and (b).Type: GrantFiled: September 14, 2005Date of Patent: July 1, 2008Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Tatsuya Miyazaki
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Patent number: 7375160Abstract: A rubber-reinforced vinyl resin which is obtained by polymerizing a vinyl monomer in the presence of a rubber-like copolymer comprising at least two members selected from (I) an ethylene-?-olefin based rubber having a Mooney viscosity of 15 or higher, (II) an ethylene-octene based rubber having a Mooney viscosity less than 15, and (III) an ethylene-octene based rubber having a Mooney viscosity of 15 or higher; a process for producing the resin; and a composition containing the rubber-reinforced vinyl resin. They are excellent in moldability and gives a molded articles which are excellent in appearance in terms of gloss, flow marks, weld appearance, color unevenness at welded portions, colorability and the like, and excellent in impact resistance, for example, impact resistance at low temperatures as well as in weatherability.Type: GrantFiled: September 29, 2003Date of Patent: May 20, 2008Assignee: Techno Polymer Co., Ltd.Inventors: Shinji Isoda, Hironari Muraki, Tadashi Nagahara, Hiromi Tomono
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Patent number: 7259209Abstract: A mixture of at least two thermoplastic particles having reactive grups which when melted and mixed react to form a high molecular weight polymer. The blend of particles when molten is particularly useful in forming double insulating glass or plastic panels.Type: GrantFiled: March 20, 2001Date of Patent: August 21, 2007Assignee: H.B.Fuller Licensing & Financing, Inc.Inventors: Stefan Grimm, Manfred Proebster, Matthias Kohl, Andreas Ferencz
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Patent number: 7253235Abstract: The present invention provides a rubber composition for a tire, in which gripping performance and abrasion resistance are improved in a balanced manner, and a tire using the same. Specifically, the present invention provides a rubber composition for a tire comprising 5 to 200 parts by weight of a low molecular weight aromatic vinyl-conjugated diene copolymer having a specific aromatic vinyl content and weight average molecular weight, based on 100 parts by weight of a rubber component containing aromatic vinyl-conjugated diene copolymer, a rubber composition for a tire comprising 5 to 200 parts by weight of an olefin-conjugated diene-aromatic vinyl copolymer based on 100 parts by weight of a diene rubber component, and a tire using the same.Type: GrantFiled: October 8, 2004Date of Patent: August 7, 2007Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kazuyuki Nishioka, Takahiro Mabuchi, Katsumi Terakawa, Kiyoshige Muraoka
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Patent number: 7211630Abstract: A rubber composition comprising as a rubber component a specified styrene-butadiene copolymer (A) and a styrene-isoprene copolymer of a specified hydrogenation ratio (B) wherein a bound styrene content of the copolymer (B) is larger by a given value than a bound styrene content of the copolymer (A) is good in the wear resistance and fracture property and further excellent in the wet-skid resistance and dry gripping property.Type: GrantFiled: July 28, 2003Date of Patent: May 1, 2007Assignee: Bridgestone CorporationInventors: Koji Masaki, Yoshikatsu Hatakeyama
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Patent number: 7144959Abstract: The present invention has a main object to provide a modifier for hydrocarbon polymer that improves a coatability of a surface of a hydrocarbon polymer molding. To attain the object, the present invention provides a modifier for hydrocarbon polymer which contains, as an active component, a modified cyclic structure-containing conjugated diene polymer wherein an amount of an ?,?-ethylenically unsaturated carboxylic acid compound bonded by addition is from 0.1 to 20% by weight and a cyclization ratio is from 30 to 95%; and provides a hydrocarbon polymer composition comprising the modifier for hydrocarbon polymer and a hydrocarbon polymer; and provides a molding by molding the hydrocarbon polymer composition.Type: GrantFiled: March 25, 2003Date of Patent: December 5, 2006Assignee: Zeon CorporationInventor: Shizuo Kitahara
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Patent number: 7112632Abstract: A process for the preparation of low branch content polybutadiene comprising: (a) a first butadiene polymerisation stage; (b) treatment of the polymer solution obtained upon completion of stage (a) with a coupling agent selected from: (i) polyunsaturated natural oils; (ii) butadiene and/or isoprene oligomers; (iii) butadiene and/or isoprene co-polymers with vinylarene monomers; the unsaturations present in compounds (i)–(iii) being at least partially substituted with groups selected from epoxides, anhydrides and esters; (c) recovery of the low branch content polybutadiene obtained upon completion of stage (b).Type: GrantFiled: October 17, 2005Date of Patent: September 26, 2006Assignee: Polimeri Europa S.p.A.Inventors: Gian Tommaso Viola, Fabio Bacchelli, Silvia Valenti
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Patent number: 7064171Abstract: The present invention reveals a tire having a tread that is comprised of (1) 30 phr to 80 phr of a non-random styrene-butadiene rubber comprised of polymer chains that are derived from styrene and 1,3-butadiene, wherein from about 10 weight percent to about 50 weight percent of the repeat units in the styrene-butadiene rubber are derived from styrene, wherein from about 60 weight percent to about 90 weight percent of the repeat units in the styrene-butadiene rubber are derived from 1,3-butadiene, wherein from about 30 weight percent to about 50 weight percent of the styrene repeat units are in sequences containing 5 to 20 styrene repeat units, wherein the bound styrene content found in the first half of the polymer chains differs from the bound styrene content found in the second half of the polymer chains by at least 5 weight percent, wherein the styrene-butadiene rubber has a 1,2-vinyl content which is within the range of about 8 percent to about 20 percent, wherein the styrene-butadiene rubber has a numberType: GrantFiled: September 22, 2005Date of Patent: June 20, 2006Assignee: The Goodyear Tire & Rubber CompanyInventors: Adel Farhan Halasa, Wen-Liang Hsu, David Michael Smith, Sr., Warren James Busch, John Joseph Andre Verthe, Scott Edwards Johnson
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Patent number: 6984706Abstract: A diene rubber (A) having a weight average molecular weight (Mw) of 100,000 to 3,000,000, an Mw/number average molecular weight (Mn) ratio of 1.30 to 2.50, and an Mw/peak top molecular weight (Mp) ratio 0.70 to 1.30. A rubber composition comprising the diene rubber (A) and a diene rubber (B) having an Mw of 2,000 to 90,0000 and/or an oil extender for rubber has good processability and can give a rubber vulcanizate having high tensile strength and good abrasion resistance. The diene rubber (A) is produced by conducting a living polymerization of diene monomer in a hydrocarbon solvent; adding a polymerization stopper to a polymerization mixture at a conversion of 5 to 98% to deactivate 10 to 90% by mole of active terminals present as of the initiation of polymerization; and finally adding a polymerization stopper to completely terminate the polymerization reaction.Type: GrantFiled: March 14, 2003Date of Patent: January 10, 2006Assignee: Zeon CorporationInventors: Takeshi Karato, Masaaki Komatu, Kazuhiro Takase
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Patent number: 6956093Abstract: The present invention relates to the preparation of syndiotactic 1,2-polybutadiene polymer using a catalyst containing a carbon disulfide in which the polymerizate thereof is treated with hydrogen peroxide, to preparation of a composite of conjugated diene-based elastomer and syndiotactic 1,2-polybutadiene polymer using a catalyst containing a carbon disulfide which the polymerizate thereof is treated with hydrogen peroxide, a rubber composition containing said syndiotactic 1,2-polybutadiene polymer and/or said composite and a tire having at least one rubber component thereof.Type: GrantFiled: October 29, 2004Date of Patent: October 18, 2005Assignee: The Goodyear Tire & Rubber CompanyInventors: Wen-Liang Hsu, Adel Farhan Halasa
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Patent number: 6955199Abstract: The present invention overcomes several disadvantages in conventional tires by providing a non-marking surface to the tire. The tire can be a pneumatic bias tire having a pair of parallel annular beads, at least one carcass ply wrapped around the beads, a non-marking tread cap, a tread base and sidewalls. A colorant may be added to the composition of the tread cap to create a tire having a colored, non-marking tread cap.Type: GrantFiled: December 21, 2001Date of Patent: October 18, 2005Assignee: FBT Enterprises, Inc.Inventor: Fredrick Taylor
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Patent number: 6939921Abstract: Transparent and colorable elastomeric compositions are provided. The transparent elastomeric compositions can be covulcanized with rubbers such as polybutadiene, polyisoprene, styrene-butadiene rubber, styrene-isoprene-butadiene rubber, isoprene-butadiene rubber, or natural rubber and polybutene processing oil. The colorable rubber compositions have sufficient properties to function as a reinforcing member in a shoe sole or automobile tire. Preferably, both the transparent and colorable elastomeric compositions include at least one copolymer of a C4 to C7 isoolefin and a p-methylstyrene, silica and a high cis-polybutadiene rubber.Type: GrantFiled: October 16, 2001Date of Patent: September 6, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventors: Walter H. Waddell, Robert R. Poulter
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Patent number: 6939918Abstract: The present invention provides a thermoplastic vulcanizate prepared by a process comprising the steps of dynamically vulcanizing rubber within a blend that includes the rubber and a thermoplastic resin, where the rubber comprises an elastomeric copolymer of ethylene, at least one ?-olefin, and optionally one or more diene monomers, where the elastomeric copolymer is characterized by having a crystallinity, as measured by differential scanning calorimetry, of less than 10 J/g, an ethylene content that is less than 90 mole percent based upon the entire copolymer, a weight average molecular weight that is greater than about 20,000 as measured by GPC with polystyrene standards, a molecular weight distribution that is less than 7, and an ethylene compositional distribution that is less than about 4 percent for the closest 90 percent of fractioned samples.Type: GrantFiled: March 23, 2001Date of Patent: September 6, 2005Assignee: Advanced Elastomer Systems L.P.Inventors: Maria D. Ellul, Sudhin Datta, Jianya Cheng, Paul McDaniel, Kang-Bo Wang
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Patent number: 6930146Abstract: A polymer composition and a thermoplastic elastomer composition containing 1,2-polybutadiene having a 1,2-bond content in the butadiene unit of 70% by weight or more, a melting point in the range of 50 to 140° C., a total halogen content of 30 ppm or less, a viscosity ? in the range of 400 to 1200 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 120° C., a viscosity ? in the range of 300 to 1000 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 150° C., and a viscosity ? in the range of 200 to 800 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 180° C. exhibit excellent moldability, visual appearance and scratch resistance.Type: GrantFiled: July 27, 2000Date of Patent: August 16, 2005Assignee: JSR CorporationInventors: Koji Okada, Masato Suzuki, Junji Kojina