At Least One Of These Polymers Is Derived From Two Or More Reactants Patents (Class 525/237)
  • Patent number: 6262178
    Abstract: This invention is based upon the discovery that cyclized polyisoprene polymers can be incorporated into tire tread compounds to improve traction, treadwear, and resistance to tear. It is further based upon the discovery that cyclized polyisoprene polymers can be blended with halobutyl rubber and/or natural rubber and can be utilized in tire innerliner formulations. The present invention more specifically discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of a sulfur cured rubber composition which is comprised of about 5 phr to about 50 phr of cyclized polyisoprene and about 50 phr to about 95 phr of at least one other rubbery polymer.
    Type: Grant
    Filed: December 28, 1999
    Date of Patent: July 17, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Joseph Frank Geiser, Judy Chu, David John Zanzig, Richard George Bauer
  • Publication number: 20010007000
    Abstract: A process for preparing blends of syndiotactic 1,2-polybutadiene and rubbery elastomers comprising the steps of (1) providing a mixture of high cis-1,4-polybutadiene rubber cement and 1,3-butadiene monomer, and (2) combining (a) an iron-containing compound, (b) a hydrogen phosphite, and (c) an organoaluminum compound to form a catalyst composition outside the presence of the mixture of rubber cement and monomer, and (3) adding the catalyst composition to the mixture and thereby polymerizing the 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within the rubber cement.
    Type: Application
    Filed: January 23, 2001
    Publication date: July 5, 2001
    Inventor: Steven Luo
  • Patent number: 6242534
    Abstract: A rubber mixture containing at least one rubber component, at least one filler, and conventional additives that it contain at least one first gel as a filler, which is essentially comprised of a rubber, has a particle size of 3×10−9 to 1×10−6 m, and has a swelling index in toluene of 1 to 15, and at least the surface of this gel has acid or base groups, where these groups have not been produced by means of reaction with dithiophosphoric acid, and comprises: a) at least one second gel as an additional filler, which is essentially comprised of a rubber, has a particle size of 3×10−9 to 1×10−6 m, and has a swelling index in toluene of 1 to 15, which is in a position to undergo a neutralization reaction with the acid or base groups of the first gel and/or b) contains at least one substance as an additional additive, which is capable of undergoing a neutralization reaction with the acid or base groups of at least one gel.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: June 5, 2001
    Assignee: Continental Aktiengesellschaft
    Inventors: Werner Obrecht, Thomas Scholl, Peter Wendling, Michael Well, Victor Monroy
  • Patent number: 6218469
    Abstract: Disclosed is an unsaturated elastomer composition comprising (A) an unsaturated olefin copolymer of at least one &agr;-olefin of 2 to 20 carbon atoms, a conjugated diene monomer represented by the following formula (I), and optionally, an aromatic vinyl compound, and (B) at least one rubber selected from a diene rubber and an ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber, a weight ratio of said component (A) to said component (B) ((A)/(B)) being in the range of 1/99 to 99/1; wherein R1 and R2 are each independently a hydrogen atom, an alkyl group of 1 to 8 carbon atoms or an aryl group, and at least one of R1 and R2 is a hydrogen atom. From the composition, a vulcanized product excellent in vibration damping properties, vibration insulation properties and strength properties as well as in heat resistance, weathering resistant, ozone resistance and dynamic fatigue resistance can be obtained.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: April 17, 2001
    Assignee: Mitsui Chemicals INC
    Inventors: Kenichi Morizono, Keiji Okada, Masayoshi Yamaguchi
  • Patent number: 6218473
    Abstract: The present invention relates to a sulfur cured rubber composition particularly suited for use in tire treads. The sulfur cured rubber composition is composed of, based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of a chlorosulfonated polyethylene; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-1,4-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: April 17, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Paul Harry Sandstrom
  • Patent number: 6207723
    Abstract: The present invention provides a rubber composition containing a reclaimed rubber and a method for producing the same. A rubber molded article having excellent rubber properties can be obtained and the recycling of a used rubber product can be promoted by the present invention. A rubber composition of the present invention is a blend comprising a claimed rubber obtained by applying a heat and a shear stress to a vulcanized rubber, a non-vulcanized virgin rubber or/and a thermoplastic resin, wherein the reclaimed rubber contains 40% by weight or more of a residual toluene-insoluble gel component and the network chain density of the rubber in the gel component is 1/20 to 1/4 based on the network chain density of the rubber of the vulcanized rubber.
    Type: Grant
    Filed: January 25, 1999
    Date of Patent: March 27, 2001
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha, Toyoda Gosei Co., Ltd.
    Inventors: Mitsumasa Matsushita, Makoto Mouri, Hirotaka Okamoto, Norio Sato, Yasuyuki Suzuki, Masao Owaki, Noriyuki Suzuki, Katsumi Nakashima, Hidenobu Honda, Toru Yoshida, Katsumasa Takeuchi
  • Patent number: 6197888
    Abstract: Blends of syndiotactic 1,2-polybutadiene and rubbery elastomers are prepared by a process that comprises polymerizing 1,3-butadiene monomer into syndiotactic 1,2-polybutadiene within a rubber cement of at least one rubbery elastomer by using an iron-based catalyst composition that is formed by combining an iron-containing compound, a hydrogen phosphite, and an organoaluminum compound.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: March 6, 2001
    Assignee: Bridgestone Corporation
    Inventor: Steven Luo
  • Patent number: 6184294
    Abstract: A fabricated article other than a film comprising a thermoplastic blend prepared from polymeric materials consisting of; (A) from 1 to 99 weight percent of at least one interpolymer made from monomer components comprising (1) from 0.5 to 65 mole percent of (a) at least one aromatic vinylidene monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one aromatic vinylidene monomer and at least one hindered aliphatic or cycloaliphatic vinylidene monomer, and (2) from 99.5 to 35 mole percent of at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; and (B) from 99 to 1 weight percent of at least one polymer made from monomer components comprising at least one &agr;-olefin having from 2 to 20 carbon atoms. These articles possess improved properties when compared to the properties of articles derived from the individual polymers comprising the blend.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: February 6, 2001
    Assignee: The Dow Chemical Company
    Inventors: Chung P. Park, Johan Thoen, Rene Broos, Martin J. Guest, Yunwa W. Cheung, Bharat I Chaudhary, John J. Gathers, Lawrence S. Hood
  • Patent number: 6172160
    Abstract: The invention provides a diene polymer composition composed of a branched diene polymer component (A) having at least three branched diene polymer chains through a polyfunctional coupling agent and a linear diene polymer component (B) having a quaternary ammonium group, and having a weight average molecular weight (Mw) within a range of from 100,000 to 2,000,000, a preparation process of the diene polymer composition, and a rubber composition comprising a rubber component containing the diene polymer composition, and a reinforcing agent.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: January 9, 2001
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Masao Nakamura, Yukio Takagishi
  • Patent number: 6150467
    Abstract: Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5. Such elastomeric polymers are combined with metallocene catalyzed ethylene, alpha-olefin copolymers to improve physical properties.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: November 21, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Periagaram Srinivasan Ravishankar, Charles Douglas Burrage
  • Patent number: 6133376
    Abstract: The rubber for high-performance tire tread of the invention basically includes: (a) about 10%.about.50% weight percentage low molecular weight coupled copolymer of aromatic vinyl compound and conjugated diene or conjugated diene monopolymer, having a molecular weight of 5.times.10.sup.4 .about.35.times.10.sup.4, (b) about 10%.about.60% weight percentage middle molecular weight uncoupled copolymer of aromatic vinyl compound and conjugated diene, having a molecular weight of 10.times.10.sup.4 .about.80.times.10.sup.4, and (c) 5.about.60% weight percentage high molecular weight coupled copolymer of aromatic vinyl compound and conjugated diene, having a molecular weight of 45.times.10.sup.4 .about.200.times.10.sup.4.
    Type: Grant
    Filed: December 15, 1997
    Date of Patent: October 17, 2000
    Assignee: Taiwan Synthetic Rubber Co.
    Inventors: Henry Chi-Chen Hsieh, Sean Chwan-Sheng Huang, Fu Lin, Peter J. D. Lee
  • Patent number: 6133364
    Abstract: A rubber composition, which contains a rubber mixture that can be vulcanized with a vulcanizing agent, which includes at least one rubber component, at least one filler, gel particles comprising a rubber, having a particle size between about 3.times.10.sup.-9 and about 1.times.10.sup.-6 m and a swelling index in toluene of about 1 to about 15 and whose surface has electrophilic centers, and a substance which acts as a coupling agent between the gel particles and which has the structure A--R--A, wherein A is a nucleophilic group, and R is a saturated or unsaturated hydrocarbon group. The rubber composition has improved hysteresis behavior in the vulcanized state so that when this rubber composition is used in tires, the rolling resistance is reduced and the wet slippage behavior is improved in relation to the conventional rubber compositions. A method of formulating the rubber composition as well as a composition useful for tire treads and vehicle tires containing the composition are disclosed.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: October 17, 2000
    Assignee: Continental Aktiengesellschaft
    Inventors: Werner Obrecht, Thomas Scholl, Peter Wendling, Michael Well, Victor Monroy
  • Patent number: 6127482
    Abstract: A composition comprising:(a) polyethylene;(b) a cure booster selected from the group consisting of 3,9-divinyl-2,4,8,10-tetra-oxaspiro[5.5]undecane (DVS); a copolymer of ethylene and DVS; and an ethylene homopolymer or copolymer having DVS grafted thereto; and(c) an organic peroxide.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: October 3, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Michael John Keogh
  • Patent number: 6119743
    Abstract: A tire tread comprises a copolymer of butadiene with isoprene and/or styrene having a room temperature elasticity of between 5 and 35% at 22.degree. C., polybutadiene rubber and an aromatic oil selected from the group consisting of an aromatic oil, naphthenic oil, paraffinic oil, and a mixture thereof.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: September 19, 2000
    Assignee: Huels Aktiengesellschaft
    Inventor: Walter Hellermann
  • Patent number: 6120880
    Abstract: The present invention provides performance enhancing shoe components. The invented shoe component includes an upper layer of 1,4-polybutadiene and, optionally, a rubber such as natural rubber, synthetic isoprene rubber or polyisoprene. The first layer is attached to a resilient layer which extends substantially the length of the shoe. Optionally, a third layer or a coating may be attached to the resilient layer. The invented shoe components may be formed as shoe inserts, insoles, midsoles or shoe soles.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: September 19, 2000
    Inventor: William R. Crow
  • Patent number: 6084022
    Abstract: This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: July 4, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, Adel Farhan Halasa, Wen-Liang Hsu, David John Zanzig, John Joseph Andre Verthe
  • Patent number: 6072004
    Abstract: The present invention provides a thermofusible elastomer composition comprising:(a) 100 phr of a selectively hydrogenated block copolymer component comprising an A'B' block copolymer and a multiblock copolymer having at least two end blocks A and at least one mid block B wherein the A' and A blocks are monoalkenyl arene polymer blocks and the B' and B blocks are substantially completely hydrogenated conjugated diene polymer blocks, the number average molecular weight of the A' and A blocks are between about 3,000 and about 7,000 and the monoalkenyl arene content of the multiblock copolymer is between about 7% and about 22% by weight;(b) 20 to 50 phr of at least one high melt flow polyolefin;(c) 0 to 19 phr of a plasticizing oil selected from naphthenic oils and paraffinic oils; and(d) 0 to 40 phr of at least one poly(conjugated diene) block compatible resin wherein the elastomer composition has a particle size of 1400 .mu.m or less.This composition is used in low shear processes.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: June 6, 2000
    Assignee: Shell Oil Company
    Inventors: Peter Migchels, Margaret Ann Burns Clawson
  • Patent number: 6063870
    Abstract: The rigid vinyl chloride resin composition comprises 100 parts by weight of a vinyl chloride resin having an average degree of polymerization of 350 to 600, 5 to 30 parts by weight of an impact-resistant improver, and 5 to 20 parts by weight of an acrylonitrile-styrene copolymer having a weight ratio acrylonitrile and styrene of 1/99 to 9/91. This composition has good impact strength and fluidity.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: May 16, 2000
    Assignee: Shin-Etsu Chemical, Co., Ltd.
    Inventors: Yuji Tokushige, Osamu Sodeyama
  • Patent number: 6038729
    Abstract: Replacement wiper blades are disclosed which adhere directly to the surface of a pre-existing wiper blade and which have advantageous physical properties. Wiper blades according to the invention are simple to install and may be adapted for use in any vehicle and on front or rear windshields or headlights.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: March 21, 2000
    Inventor: Jeffrey J. Feigenbaum
  • Patent number: 6031009
    Abstract: Improved thermoplastic compositions comprising a blend of ground vulcanized rubber and olefin polymer which have improved compatibility and mechanical properties are described; they are improved by incorporation of an alpha olefin copolymer.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: February 29, 2000
    Inventor: Edgar Armando Gonzalez
  • Patent number: 6024146
    Abstract: The present invention relates to a pneumatic rubber tire having an integral innerliner of a sulfur cured rubber compound. The rubber compound is characterized by, based on 100 parts of ruber, (A) from about 70 to 98 parts by weight of bromobutyl rubber, (B) from 2 to 30 parts by weight of a trans 1,4-polybutadiene rubber having at least a 65 percent trans 1,4-content; and (C) from 0 to 28 parts by weight of a rubber selected from the group consisting of an acrylonitrile/butadiene copolymer, styrene/butadiene copolymer, natural rubber and mixtures thereof.
    Type: Grant
    Filed: May 2, 1994
    Date of Patent: February 15, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Raymond Benjamin Roennau
  • Patent number: 6025430
    Abstract: This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: February 15, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, Adel Farhan Halasa, Wen-Liang Hsu, David John Zanzig, John Joseph Andre Verthe
  • Patent number: 6022922
    Abstract: The invention relates to a tire with a tread which is reinforced with a quantitative amount of silica, including a silica coupler, where the tread rubbers are of a blend comprised of styrene/isoprene/butadiene terpolymer rubber and cis 1,4-polybutadiene rubber or styrene/isoprene/butadiene terpolymer rubber, cis 1,4-polybutadiene rubber and isoprene/butadiene copolymer rubber. Optionally, the rubber blend can contain a minor amount of cis 1,4-polyisoprene natural rubber.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: February 8, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Jean Bergh, Marc Junio, Jean-Claude Joseph Marie Kihn, Tom Dominique Linster, Jean-Paul Lambotte
  • Patent number: 6020046
    Abstract: Embossed sheets having improved grain retention can be made from a polyolefin composition containing a propylene polymer material and a partially crosslinked thermoplastic olefin elastomer composition. Large parts such as automobile door and instrument panels can be formed from these sheets.
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: February 1, 2000
    Assignee: Montell North America Inc.
    Inventor: Cheryl L. Abhau
  • Patent number: 6017988
    Abstract: This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend.
    Type: Grant
    Filed: August 3, 1999
    Date of Patent: January 25, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, Adel Farhan Halasa, Wen-Liang Hsu, David John Zanzig, John Joseph Andre Verthe
  • Patent number: 5994448
    Abstract: This invention relates to a tire tread compound that can be used in manufacturing tires having outstanding traction characteristics without compromising treadwear and rolling resistance. The tire tread compounds of this invention are made utilizing an isoprene-butadiene rubber having a high glass transition temperature and having SnR.sub.3 end groups, wherein R represents an alkyl group, such as a tertiary-butyl group. These isoprene-butadiene rubbers are made by reacting an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. with a tin compound of the formula SnR.sub.3 X, wherein R represents an alkyl group and wherein X represents a halogen. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) about 60 phr to about 95 phr of an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C.
    Type: Grant
    Filed: August 12, 1998
    Date of Patent: November 30, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Paul Harry Sandstrom, Wen-Liang Hsu, Adel Farhan Halasa
  • Patent number: 5969044
    Abstract: Process for airtight and/or moisture-proof packaging of air-sensitive and/or moisture-sensitive materials for the introduction of the packaged materials in a chemical reactor. Described is a process for the airtight and/or moisture-proof packaging of air-sensitive and/or moisture-sensitive materials in a foil and a method for introducing the packaged materials in a reactor, whereby the polymer foil is dissolved in an organic solvent.
    Type: Grant
    Filed: April 8, 1998
    Date of Patent: October 19, 1999
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Serge Fritz, Reinhold Feldmann
  • Patent number: 5965661
    Abstract: The invention pertains to a sulfur cross-linkable unvulcanized rubber mixture for the manufacture of treads, in particular for winter tires. The rubber mixture contains polyisoprene, polybutadiene and styrene-butadiene copolymer as well as further fillers and additives. In order to prepare vehicle pneumatic tires which exhibit excellent traction on ice and snow while at least maintaining their wet-gripping ability, the rubber mixture preferably contains, relative to 100 parts of total rubber, 20-100 parts by weight cis-1,4 polyisoprene; 0-65 parts by weight polybutadiene with a cis content of greater than about 90 mole %; and 0-65 parts by weight solution-polymerized styrene-butadiene copolymer; as well as 65-120 parts by weight silicic acid.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: October 12, 1999
    Assignee: Continental Aktiengesellschaft
    Inventors: Andre du Bois, Joachim Dumke, Anja Schneider, Wolfgang Loreth
  • Patent number: 5959039
    Abstract: A tire having a portion formed of a rubber composition which comprises a high-molecular-weight polymer component which contains bound styrene in an amount not greater than 30% by weight, is a styrene-butadiene copolymer or a conjugated diene polymer such as polybutadiene, and has a weight-average molecular weight of at least 30.times.10.sup.4 ; and a low-molecular-weight polymer component which contains bound styrene in an amount not greater than 30% by weight, is a styrene-butadiene copolymer or a conjugated diene polymer such as polybutadiene, and has a weight-average molecular weight of from 0.2.times.10.sup.4 to 8.times.10.sup.4. The rubber composition contains 30 parts by weight of the low-molecular-weight polymer component relative to 100 parts by weight of the high-molecular-weight polymer component. The ratio between the amount of bound styrene and the vinyl linkage content falls within specific ranges.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: September 28, 1999
    Assignee: Bridgestone Corporation
    Inventors: Hideaki Yokoyama, Toshiyuki Ishikuro, Tadashi Shibata
  • Patent number: 5955531
    Abstract: An improved pneumatic tire having decreased rolling resistance employing at least one tire component selected from the group consisting of subtreads, black sidewall, body ply skims and bead fillers, prepared from a vulcanizable elastomeric composition having reduced hysteresis comprises from about 10 to 100 parts by weight of an elastomer comprising a plurality of polymer molecules, wherein substantially each polymer molecule contains at least one functional group at the site of initiation, and having a hysteresis reduction of at least about 10 percent compared to the same elastomer without a functional group on substantially each polymer molecule; from about 0 to 90 parts by weight of an elastomer having greater hysteresis than the elastomer having reduced hysteresis and selected from the group consisting of natural rubber, synthetic rubber and blends thereof; and, from about 20 to about 100 parts by weight of carbon black, per 100 parts of the elastomer.
    Type: Grant
    Filed: September 13, 1993
    Date of Patent: September 21, 1999
    Assignee: Bridgestone Corporation
    Inventor: Shingo Futamura
  • Patent number: 5952396
    Abstract: An elastomer has a modulus intermediate between that of a conventional rubber and a gel. The elastomer includes (a) between 20 and 45 parts by weight of a semicrystalline elastomer having between 1 and 15% crystallinity and (b) between 80 and 55 parts by weight of a compatible liquid elastomer having a number-average molecular weight of between 1,500 and 8,500. The elastomer's modulus is sufficiently high to enable it to be fabricated into handleable articles, but is sufficiently low so that it provides effective sealing of substrates it covers without the need for introducing a separate sealing material such as a mastic or adhesive.
    Type: Grant
    Filed: June 16, 1997
    Date of Patent: September 14, 1999
    Assignee: Raychem Corporation
    Inventor: Rong Jong Chang
  • Patent number: 5952427
    Abstract: Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5. Such elastomeric polymers are combined with up to 30 parts of metallocene catalyzed ethylene, alpha-olefin copolymers to improve physical properties.
    Type: Grant
    Filed: June 5, 1997
    Date of Patent: September 14, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Periagaram Srinivasan Ravishankar, Charles Douglas Burrage
  • Patent number: 5948867
    Abstract: Embossed sheets having improved grain retention can be made from a polyolefin composition containing a propylene polymer material and a partially crosslinked thermoplastic olefin elastomer composition that includes (1) 20-80 parts by weight of a thermoplastic elastomer containing (a) from 20 to 70% of a propylene homopolymer having an isotactic index greater than 90, or a crystalline propylene copolymer with ethylene and/or a 4-8 C alpha-olefin having a polymerized propylene content greater than 85% and an isotactic index of greater than 85%; (b) from 30 to 75% of an amorphous ethylene-propylene or ethylene-butane-1 copolymer, which is xylene soluble at room temperature and contains from 30 to 70% polymerized ethylene, and (c) from 3 to 30% of a semi-crystalline ethylene-propylene or ethylene-butene-1 copolymer that is xylene insoluble at room temperature and contains greater than 90% polymerized ethylene, and (2) 80-20 parts by weight of an ethylene/propylene/diene terpolymer rubber containing 1 to 10% of a
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: September 7, 1999
    Assignee: Montell Technology Company bv
    Inventor: Cheryl L. Abhau
  • Patent number: 5945481
    Abstract: A case for memory disks having excellent antistatic properties, which comprises a thermoplastic resin composition comprising 100 parts by weight of the following component (A), 3 to 30 parts by weight of the following component (B) and 5 to 40 parts by weight of the following component (C):component (A): a crystalline propylene resin having a melt flow rate (MFR) of 1 to 80 g/10 min;component (B): a thermoplastic elastomer selected from (b.sup.1) olefin copolymer elastomers having a Mooney viscosity (ML.sub.1+4 (100.degree. C.)) of 10 to 85, and (b.sup.2) hydrogenated products of a block copolymer of styrene or a derivative thereof and a conjugated diene, containing 15 to 50% by weight of styrene or a derivative thereof, having a weight-average molecular weight of 50,000 to 220,000; andcomponent (C): an acrylamide copolymer.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: August 31, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Toshikazu Mizutani, Jichio Deguchi
  • Patent number: 5922153
    Abstract: A halobutyl rubber is generally used in the innerliner of pneumatic tires to retard the escape of air used to inflate the tire, thereby maintaining tire pressure. Since halobutyl rubbers, such as bromobutyl rubber, are generally the most expensive elastomers used in tires, it is desirable from a standpoint of cost reduction to reduce the level of halobutyl rubbers used in tires. The present invention relates to a technique for reducing the quantity of halobutyl rubber utilized in the innerliner of tubeless pneumatic vehicle tires. The present invention more specifically relates to a tire innerliner and pneumatic tires containing the same, which are prepared from a composition comprising, based on 100 parts by weight of rubber, a blend of (1) about 50 parts to about 90 parts of a halobutyl rubber and (2) about 10 parts to about 50 parts of a styrene-isoprene-butadiene terpolymer rubber having a first glass transition temperature which is within the range of about -110.degree. C. to about -20.degree. C.
    Type: Grant
    Filed: January 23, 1998
    Date of Patent: July 13, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Roger Neil Beers, David Andrew Benko, Bill Bud Gross, Adel Farhan Halasa
  • Patent number: 5916973
    Abstract: The present invention relates to compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from alkoxy radicals having from 1 to 8 carbon atoms, x is O or an integer of from 1 to 10; and Y is Li, K or Na. These compounds may be used as silica couplers in rubber compositions.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: June 29, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Rene Jean Zimmer, Friedrich Visel, Uwe Ernst Frank, Thierry Florent Edme Materne
  • Patent number: 5912303
    Abstract: A terpolymer rubber prepared from ethylene, .alpha.-olefin having 3 to 20 carbon atoms and branched chain polyene of the formula ##STR1## wherein R.sup.1 represents C.sub.1 -C.sub.5 alkyl, and R.sup.2 and R.sup.3 represent hydrogen atom or C.sub.1 -C.sub.5 alkyl, such as, for example, 6,7-dimethyl-4-ethylidene-1,6-octadiene, 6,7-dimethyl-4-ethylidene-1,6-nonadiene, and 9-methyl-4-ethylidene-1,8-decadiene; when added to a rubber (diene rubber, nitrile rubber or random copolymer rubber from ethylene, C.sub.3 -C.sub.20 .alpha.-olefin, and optionally a nonconjugated diene) provides curable rubber compositions having rapid vulcanization rates, for example, as lows as about 7 to 10 seconds. The diene rubber compositions also have excellent resistances to weather,ozone and heat aging while maintaining excellent mechanical strength characteristics. The nitrile rubber compositions also have excellent oil resistance.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: June 15, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hidenari Nakahama, Masaaki Kawasaki, Tetsuo Tojo, Totshiyuki Tsutsui, Toshihiro Sagane
  • Patent number: 5912374
    Abstract: The present invention relates to asymmetrical siloxy compounds of the formulae ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; R.sup.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: June 15, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Giorgio Agostini, Thierry Florent Edme Materne, Marc Junio, Friedrich Visel, Uwe Ernst Frank
  • Patent number: 5902856
    Abstract: A diene rubber (iii) can be obtained by mixing in a solution state:a modified styrene-butadiene rubber (i) having a weight-average molecular weight of 150,000-500,000, obtained by reacting a diene polymer having a bound active metal in the molecule, with a modifier such as N-methyl-.epsilon.-caprolactam or the like, anda branched styrene-butadiene rubber (ii) having a weight-average molecular weight of 800,000 or more.This diene rubber (iii) and a rubber composition comprising the diene rubber (iii) and other diene rubber (iv) have superior processability when unvulcanized and give a vulcanized rubber having improved abrasion resistance, resiliency and low-temperature properties.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: May 11, 1999
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Fumitoshi Suzuki, Masao Nakamura, Manabu Tomisawa
  • Patent number: 5901766
    Abstract: The present invention relates to a pneumatic tire having a tread containing (a) from 50 to 90 phr (parts by weight of rubber per 100 total parts of rubber) of a rubber which, in its uncured state, has a glass transition temperature in the range of from -80.degree. C. to -110.degree. C. and (b) from 15 to 50 phr of a resin.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: May 11, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Edward John Blok, John Joseph Andre Verthe
  • Patent number: 5895798
    Abstract: A liquid rubber composition including a 1,2-polybutadiene resin component dispersed in the form of fine particles in a liquid rubber component in a weight ratio of 1:100 to 50:100 has a high dispersion stability and a low specific gravity and is useful for forming a cured rubber article having a high elastic modulus and a satisfactory mechanical strength and ultimate elongation.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: April 20, 1999
    Assignee: Ube Industries, Ltd.
    Inventors: Naomi Okamoto, Takeshi Shoda
  • Patent number: 5885718
    Abstract: A treating agent comprises a nitrile group-containing highly saturated polymer rubber latex (A) having an iodine value of 120 or less, a rubber latex (B) other than the highly saturated polymer rubber latex, and a water-soluble resorcinol/formaldehyde condensate in amounts of 15 to 80%, 5 to 70% and 2 to 15%, all by weight in terms of solids, respectively. A rubber-reinforcing fiber product is coated with the treating agent. A rubber article such as a toothed belt, a tire and the like is made using this rubber-reinforcing fiber product. The glass fiber product coated with the treating agent may be further coated with a halogen-containing polymer-based adhesive as a secondary treating agent. Thus, the treating agent exhibits a large bonding force between the reinforcing fiber product and a matrix. Even if the rubber article is repeatedly subjected to a flexing stress, the strength thereof cannot be reduced. A peel-off cannot occurs between the reinforcing fiber product and the rubber matrix.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: March 23, 1999
    Assignee: Nippon Glass Fiber Co., Ltd.
    Inventors: Akira Okamura, Masato Sekiguchi
  • Patent number: 5877249
    Abstract: The invention relates to a tire with a tread which is reinforced with carbon black and precipitated silica where the tread rubbers are of a blend comprised of at least one diene-based elastomer and a styrene/alphamethylstyrene resin, as hereinafter described.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: March 2, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Jean-Paul Lambotte
  • Patent number: 5859133
    Abstract: The subject invention discloses a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of (a) an isoprene-butadiene diblock rubber, said isoprene-butadiene diblock rubber being comprised of a butadiene block and an isoprene-butadiene block, wherein said butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene diblock rubber has essentially one glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., wherein said isoprene-butadiene diblock polymer has a Mooney ML-4 viscosity at 100.degree. C.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: January 12, 1999
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David John Zanzig, Adel Farhan Halasa, Wen-Liang Hsu, Paul Harry Sandstrom, Laurie Elizabeth Austin
  • Patent number: 5849392
    Abstract: The present invention provides a thread wound golf ball having improved flight performances, which comprises a solid center, a thread layer and an outer cover. The solid center is formed from a rubber component with crosslinked structure which contains an oily substance. Impact resilience of the solid center is 90 cm or more.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: December 15, 1998
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akihiko Hamada, Akira Kato, Keiji Moriyama, Kuniyasu Horiuchi, Tadahiro Ebisuno
  • Patent number: 5844044
    Abstract: Trans 1,4-copolymers of butadiene and isoprene are provided as blends with other elastomers, including partial replacement of natural cis 1,4-polyisoprene in elastomer compositions. Pneumatic rubber tires with components composed of such elastomer blends, including tire treads, are also included.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: December 1, 1998
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul Harry Sandstrom, Wen-Liang Hsu
  • Patent number: 5804645
    Abstract: A rubber composition of tire tread, which comprises an emulsion-polymerized styrene-butadiene rubber with a bonded styrene content of not less than 40% by weight which is contained in an amount of 10 to 100% by weight in a rubber component, and a sodium-containing basic inorganic compound and/or a basic sodium salt of organic acid which is blended in an amount of 0.5 to 5.0 parts by weight per 100 parts by weight of the rubber component. Safe driving at a high speed can be realized by using the rubber compositions.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: September 8, 1998
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Toshiro Matsuo
  • Patent number: 5798408
    Abstract: This invention relates to a tire having a tread composed of quantitatively silica reinforced rubber composition, with a minor amount, if any, of carbon black where the tread elastomers are primarily composed of coupled styrene/isoprene/butadiene terpolymer with tin or silicon in combination with selected diene-based elastomers.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: August 25, 1998
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David John Zanzig, Wen-Liang Hsu, Adel Farhan Halasa, Barry Allen Matrana
  • Patent number: 5763533
    Abstract: Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5. Such elastomeric polymers are combined with up to 30 parts of metallocene catalyzed ethylene, alpha-olefin copolymers to improve physical properties.
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: June 9, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Periagaram Srinivasan Ravishankar, Charles Douglas Burrage
  • Patent number: 5749983
    Abstract: A pneumatic tire comprises a tread of cap and base structure, in which a rubber composition comprising a particular amount of a specified rubber-reinforcing thermoplastic resin containing not less than 10% by weight of a conjugated diene rubber component and the balance being a resin component and having a particular glass transition temperature is used in a tread base rubber of the tread and has excellent chipping resistance, cut resistance and durability to heat build-up.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: May 12, 1998
    Assignee: Bridgestone Corporation
    Inventors: Hideaki Yokoyama, Uchu Mukai