Solid Polymer Derived From Imide Reactant Patents (Class 525/422)
-
Patent number: 6528615Abstract: The present invention relates to copolymers containing polyamide blocks and polyether blocks based on ethoxylated primary amines, these copolymers having a melting point of between 80° C. and 135° C. and an MFI (melt flow index) of between 5 and 80 g/10 min (2.16 kg-150° C.). The invention also relates to adhesives of the HMA (or hot melt adhesive) type consisting of the above copolymers containing polyamide blocks and polyether blocks.Type: GrantFiled: March 26, 2001Date of Patent: March 4, 2003Assignee: AtofinaInventors: Hermann Hilgers, Reinhard Linemann
-
Patent number: 6518392Abstract: A novel dielectric composition is provided that is useful in the manufacture of integrated circuit devices and integrated circuit packaging devices. The dielectric composition is prepared by imidizing and curing an oligomeric precursor compound comprised of a central polybenzoxazole, polybenzothiazole, polyamic acid or polyamic acid ester segment end-capped at each terminus with an aryl-substituted acetylene moiety such as an ortho-bis(arylethynyl)aryl group, e.g., 3,4-bis(phenylethynyl)phenyl. Integrated circuit devices, integrated circuit packaging devices, and methods of synthesis and manufacture are provided as well.Type: GrantFiled: March 8, 2001Date of Patent: February 11, 2003Assignee: International Business Machines CorporationInventors: Kenneth R. Carter, James L. Hedrick, Victor Yee-Way Lee, Dale C. McHerron, Robert D. Miller
-
Patent number: 6509422Abstract: In 100 parts by weight of a composition, from 2 to 89 parts by weight of a fluorinated polymer having a fluorine content of at least 65 wt %, from 97 to 10 parts by weight of a non-fluorinated polymer and from 1 to 35 parts by weight of a dispersing agent having a carboxylic acid group or its derivative, or a sulfonic acid group or its derivative, are blended.Type: GrantFiled: September 20, 1999Date of Patent: January 21, 2003Assignee: Asahi Glass Company Ltd.Inventors: Masako Nagashima, Takeshi Eriguchi, Yuriko Kaida, Hiroki Kamiya, Masao Umino, Masataka Yokota
-
Publication number: 20020198358Abstract: The present invention provides a polymer in which coumarin, a photo-reactive molecule, is grafted onto a polyimide for preparing liquid crystal alignment layer which has a superior alignment property and an excellent thermal stability in photo-alignment, a process for preparing the said grafted polymer, a process for preparing liquid crystal alignment layer by employing the said grafted polymer, and a liquid crystal alignment layer prepared by the process. The polymer of the invention is prepared by mixing a coumarin compound with a polyimide, dissolving the mixture in an organic solvent, adding a catalyst, and stirring under an environment of N2 gas. The polymer of the invention is superior in terms of the thermal stability, which makes possible its universal application for the development of a novel liquid crystal display(LCD).Type: ApplicationFiled: March 8, 2002Publication date: December 26, 2002Inventors: Jung-Ki Park, Shi-joon Sung, Jong-Woo Lee
-
Publication number: 20020193553Abstract: A nonwoven web and method of preparing a novel nonwoven web of synthetic fiber are disclosed. An aqueous solution amide crosslinked synthetic precursor polymer is extruded under defined conditions through a plurality of die orifices to form a plurality of threadlines. The threadlines are attenuated with a defined primary gaseous source to form fiber under conditions of controlled macro scale turbulence and under conditions sufficient to permit the viscosity of each threadline, as it leaves a die orifice and for a distance of no more than about 8 cm, to increase incrementally with increasing distance from the die, while substantially maintaining uniformity of viscosity in the radial direction, at a rate sufficient to provide fiber having the desired attenuation and mean fiber diameter without significant fiber breakage. The attenuated threadlines are dried with a defined secondary gaseous source. The resulting fibers are deposited randomly on a moving foraminous surface to form a substantially uniform web.Type: ApplicationFiled: March 1, 2002Publication date: December 19, 2002Inventors: Jian Qin, Yong Li, Wendy Lynn Van Dyke, Anthony John Wisneski, Palani Raj Ramaswami Wallajapet, Hannong Rhim
-
Patent number: 6468664Abstract: The present invention relates to a poly(imide-siloxane) compound useful as passivation layer for packaging tapeless LOC, which is produced by reacting in a polar solvent a diaminosiloxane compound of the formula(1) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 are independently an aromatic group, aliphatic group or halogenated hydrocarbon, hydroxy, or ether group, and m and n are integers such that m+n is an integer of 0˜1000; and a diamine compound of the formula(2) H2N—R—NH2 (2) wherein R is at least one selected from the below groups: with an aromatic tetracarboxylic dianhydride of the formula (3) wherein A is at least one selected from the below groups: wherein the number of moles of the compound (3) is the same as the total number of moles of compounds (1) and (2).Type: GrantFiled: October 18, 2000Date of Patent: October 22, 2002Assignee: Samsung Electronics Co., Ltd.Inventors: Chan Eon Park, Jin Ho Kang, Sang Min Song, Young Tak Ahn, Jae Geun Park, Myung Sup Jung
-
Patent number: 6451955Abstract: A method of making a solution of a polyimide from a diamine monomer and a dianhydride monomer is disclosed. A solution or slurry of one of the monomers in a solvent that boils at a temperature between about 80° C. and about 160° C. is prepared. The solution or slurry is heated to a temperature between about 80° C. and about 160° C. and the other monomer is slowly added to the solution or slurry. Polyamic acid that is formed quickly imidizes to form the polyimide.Type: GrantFiled: September 28, 2000Date of Patent: September 17, 2002Assignee: Sumitomo Bakelite Company LimitedInventors: Michael C. Hausladen, Jin-O Choi
-
Patent number: 6441072Abstract: The invention relates to a polyamide composition for the production of electrical and electronic components that are suitable for the conditions of the surface mounting technology. In particular, the composition exhibits a high resistance to blistering during the reflow soldering process. The composition according to the invention comprises (a) a polyamide having a melting point higher than 280° C., (b) a polymer having a melting point lower than 230° C., (c) a halogen-containing compound, (d) optionally a synergist for the flame-retardant properties (e) reinforcing material (f) optionally other additives. A particularly good resistance to blistering is achieved if (f) contains at least a compound with acid imide groups.Type: GrantFiled: September 1, 2000Date of Patent: August 27, 2002Assignee: DSM N.V.Inventors: Hubertus G. J. Havenith, Wilhelmus J. M. Sour, Johannes Tijssen, Robert M. Leeuwendal
-
Patent number: 6410677Abstract: The present invention provides an insulating material showing excellent thermal propeties and electrical properties in semiconductor applications.Type: GrantFiled: September 27, 2000Date of Patent: June 25, 2002Assignee: Sumitomo Bakelite Company LimitedInventors: Takashi Enoki, Nobuhiro Higashida, Mitsuru Murata
-
Patent number: 6403757Abstract: A reaction between epoxy-terminated polyamide and an acid anhydride compound can yield a modified polyamide resin, into resin skeleton of which carboxy groups to react with epoxy resin are introduced. An adhesive agent having excellent heat-resistance can be provided by the use of a composition of this modified polyamide resin and epoxy resin. Furthermore, an adhesive tape for a semiconductor device having excellent properties can be produced by laminating the adhesive agent and the protective layer on one surface of an organic insulated film.Type: GrantFiled: January 7, 2000Date of Patent: June 11, 2002Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaisahInventors: Katsunori Yabuta, Kiyokazu Akahori, Yasushi Nishikawa
-
Publication number: 20020068037Abstract: Cascade polymers, containing complex-forming ligands, optionally at least five ions of an element of atomic numbers 21-29, 39, 42, 44 or 57-83, as well as, if desired, cations of inorganic and/or organic bases, amino acids or amino acid amides, are valuable complexing compounds and complexes for diagnostics and therapy.Type: ApplicationFiled: October 11, 2001Publication date: June 6, 2002Applicant: Schering AGInventors: Johannes Platzek, Heribert Schmitt-Willich, Heinz Gries, Gabriele Schuhmann-Giampieri, Hubert Vogler, Hanns-Joachim Weinmann, Hans Bauer
-
Patent number: 6359102Abstract: Improvements are disclosed for biphasic polymerization processes in which an aqueous solution of a first monomer that is hydrolytically unstable below a pH of about six or above a pH of about eight is admixed with a water-immiscible organic solvent and there is added to the admixture a catalyst selected from tertiary amine, quaternary amine and phosphonium catalysts, an acid-forming co-monomer for the first monomer, an acid scavenger, after which the resulting polymer is recovered, wherein the improvement includes providing the aqueous solution at a pH between about si and about eight, and adding to the admixture the acid-forming co-monomer and the acid scavenger at relative rates effective to maintain the pH of the admixture between about six and about eight. The catalyst may be added in a molar ratio to the first monomer effective to provide a predetermined weight-average or number-average molecular weight for the resulting polymer.Type: GrantFiled: June 29, 1998Date of Patent: March 19, 2002Assignee: Integra LifeSciences I, Ltd.Inventors: John E. Kemnitzer, George L. Brode, Joachim B. Kohn
-
Patent number: 6355737Abstract: The process for producing polymer blends by reacting at least one aminonitrile with water in the presence of thermoplastic polymers and optionally further polyamide-forming monomers comprises the following steps: (1) reacting at least one aminonitrile with water at a temperature from 90 to 400° C. and a pressure from 0.1 to 35×106 Pa to obtain a reaction mixture, (2) further reacting the reaction mixture at a temperature from 150 to 400° C.Type: GrantFiled: August 16, 2000Date of Patent: March 12, 2002Assignee: BASF AktiengesellschaftInventors: Ralf Mohrschladt, Martin Weber, Volker Hildebrandt
-
Patent number: 6348563Abstract: The present invention provides a p-hydroxybenzoic ester represented by the formula (1) wherein R1 represents a C6-C10 straight-chain or branched-chain alkyl group, A1 represents a C2-C4 alkylene group and n in an integer of 1 to 8, a plasticizer for at least one polyamide resin selected from nylon 11 and nylon 12 which comprises the ester, a polyamide resin composition comprising the ester and at least one polyamide resin selected from nylon 11 and nylon 12, and a polyamide resin molded article comprising the ester and having excellent high-temperature volatilization resistance and low-temperature impact resistance.Type: GrantFiled: August 27, 1999Date of Patent: February 19, 2002Assignee: New Japan Chemical Co., Ltd.Inventors: Hideo Fukuda, Yoshifumi Fujitani, Ryuichi Kohzu
-
Patent number: 6346569Abstract: A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced.Type: GrantFiled: February 28, 2000Date of Patent: February 12, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Yoshihiro Irizato, Makoto Sukegawa, Toshio Katoh, Hiroaki Tamatani, Akinori Nagatomo, Masaru Wada
-
Publication number: 20020007042Abstract: A thermoplastic or thermosetting adhesive for bonding an electronic component to a substrate in which the adhesive is cured in situ from a curable composition comprises one or more poly- or mono-functional maleimide compounds, or one or more poly- or mono-functional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, a curing initiator and optionally, one or more fillers.Type: ApplicationFiled: February 1, 2001Publication date: January 17, 2002Inventors: Donald E. Herr, Rose Ann Schultz
-
Patent number: 6335417Abstract: A novel modified polyimide resin having a polybutadiene sheleton and obtainable by reacting the following three (3) kinds of compounds, i.e., a bifunctional hydroxyl-terminal polybutadiene having a number average molecular weight of 800 to 5,000, a tetrabasic acid dianhydride, and a diisocyanate compound, imparts reduced shrinkage upon setting to a thermosetting resin composition comprising the same and also imparts heat resistance and pliability and the like to a hardened mass or article of such thermosetting resin composition. Therefore, such thermosetting resin composition is an excellent resin composition capable of fully satisfying the requirements with regard to the characteristics of an overcoat agent for a wiring circuit which should be pliable, such as a flexible wiring circuit substrate, a film carrier and the like.Type: GrantFiled: August 17, 2000Date of Patent: January 1, 2002Assignee: Ajinomoto Co., Inc.Inventors: Hiroshi Orikabe, Tadahiko Yokota
-
Patent number: 6307008Abstract: A polymide useful as an adhesive for semiconductor assemblies having excellent thermal resistance and adhesive strength at high temperatures.Type: GrantFiled: February 25, 2000Date of Patent: October 23, 2001Assignee: Saehan Industries CorporationInventors: Kyung Rok Lee, Soon Sik Kim, Kyeong Ho Chang, Jeong Min Kweon
-
Patent number: 6307002Abstract: A polyimide represented by the following general formula (1); wherein l, m, and n represent not the order of each repeating unit, but the numbers of each repeating unit existing in the molecule, E1 is a photosensitive group, E2 is a group comprising an alkyl group having 2 to 20 carbon atoms, —A(—E1)—, —A(—E2)—, and B each are a divalent organic group, X and Y each are a tetravalent organic group, X, Y, A, B, E1 and E2 may be identical or different among the repeating units, 1 is an integer of 1 or more, m and n each are an integer of 0 or more. The polyimide and polyimide compositions comprising it has thermoreactivity as well as photoreactivity and photosensitivity.Type: GrantFiled: November 9, 1999Date of Patent: October 23, 2001Assignee: Kaneka CorporationInventors: Kohji Okada, Hitoshi Nojiri
-
Publication number: 20010031853Abstract: The present invention provides PMR-type polyimides that exhibit lower melt viscosities than PMR-type polyimides of the prior art. These PMR-type polyimides are created by incorporating flexible linkages, such as kinked structures and twisted or non-coplanar moietes into the backbone structure of the PMR. Specifically, the present invention provides for the production of PMR-type polyimides having 2,2′-disubstituted biaryls in the polymer backbone.Type: ApplicationFiled: March 2, 2001Publication date: October 18, 2001Inventors: Ronald K. Eby, Michael Meador, Christopher A. Gariepy
-
Publication number: 20010029284Abstract: In 100 parts by weight of a composition, from 2 to 89 parts by weight of a fluorinated polymer having a fluorine content of at least 65 wt %, from 97 to 10 parts by weight of a non-fluorinated polymer and from 1 to 35 parts by weight of a dispersing agent having a carboxylic acid group or its derivative, or a sulfonic acid group or its derivative, are blended.Type: ApplicationFiled: May 16, 2001Publication date: October 11, 2001Applicant: ASAHI GLASS COMPANY, LTD.Inventors: Masako Nagashima, Takeshi Eriguchi, Yuriko Kaida, Hiroki Kamiya, Masao Umino, Masataka Yokota
-
Patent number: 6288208Abstract: The present invention relates to a highly branched polyamide oligomer of the general formula (I) as hereinabove defined, to the process for preparing and branched oligomers and to different uses thereof. As well known to the man skilled in the art, the implementations and efficacy of the different polyamide oligomers may vary, depending on their structure and valency (reactive groups composition). Polyamide oligomers may be used, for example, as epoxy hardeners in the preparation of thermosetting compositions, as thermoplastic hot melt adhesives, as adhesion promoters and many other suitable applications. The highly branched oligomers disclosed have been shown to be highly efficient, for example, as epoxy hardeners, inter alia, in the formation of glue, lacquer, enamel or sealant mixtures.Type: GrantFiled: April 20, 1999Date of Patent: September 11, 2001Assignee: Epox, Ltd.Inventor: Leonid Moshinsky
-
Patent number: 6284867Abstract: A substantially non-crosslinked polymer cementitious composition dispersant for the improvement of the fluidity of cementitious compositions comprising hydrophilic side chain substituted polyimide or polyamide backbone units, having at least some proportion of grafted oligomeric or polymeric hydrophilic side chains linking at least one of amides, esters, and thioesters, wherein the polymer cementitious composition is water soluble, and wherein crosslinking is such that in a statistical sampling there is greater than zero to less than 0.1 mole % of backbone units involved in crosslinking.Type: GrantFiled: June 12, 2000Date of Patent: September 4, 2001Assignee: MBT Holding AGInventors: Thomas M. Vickers, Jr., Runhai Lu, Lynn E. Brower, Samy M. Shendy, Rainer Packe-Wirth, Hong Gao
-
Patent number: 6281275Abstract: The invention is in a conductive prepolymer composition which when polymerized and cured is used to coat a substrate material such as steel, stainless steel, iron, brass, copper, aluminum, platinum, titanium, silver, gold, Telfon, plastics, glass, or combinations thereof. It comprises: (a) from 25 to 99 parts by weight of a poly(amide-imide) prepolymer; (b) from 1 to 25 parts by weight of a trifunctional ester selected from the group consisting of trifunctional methacrylate ester, trifunctional acrylate ester, and mixtures thereof; (c) from 0.5 to 15 parts by weight of an organo-reactive silane consisting of an amino group containing alkoxysilane having the formula NH2(CH2)nSi(OC2H5)3, where n is an integer from 1 to 20; and (d) a conductive additive. The invention also provides polymer coated substrates having a tenaciously bound polymer layer which is corrosion resistant, has advantageous properties of conductivity and can be soldered.Type: GrantFiled: May 29, 1998Date of Patent: August 28, 2001Assignee: Alchemetal Corp.Inventors: Mohan L. Sanduja, Carl Horowitz, Paul Thottathil, Lina Zilberman, Edward Greenwood
-
Patent number: 6265530Abstract: A thermoplastic or thermosetting curable adhesive composition for bonding an electronic component to a substrate in which the adhesive is cured in situ comprises one or more poly- or mono-functional maleimide compounds, or one or more poly- or mono-functional vinyl compounds other than maleimide compounds, or a combination of maleimide and vinyl compounds, a curing initiator and optionally, one or more fillers.Type: GrantFiled: June 18, 1999Date of Patent: July 24, 2001Assignee: National Starch and Chemical Investment Holding CorporationInventors: Donald Herr, Rose Ann Schultz, Pingyong Xu, Scott R. McLaughlin
-
Patent number: 6262223Abstract: Addition-cured polyimides that contain the reaction product of an aromatic triamine or trianhydride analogue thereof, a reactive end group such as 5-norbornene-2, 3-dicarboxylic acid, ester derivatives of 5-norbornene-2,3-dicarboxylic acid, anhydride derivatives of 5-norbornene-2,3-dicarboxylic acid, or 4-phenylethynylphthalic anhydride, an aromatic diamine, and a dialkyl ester of an aromatic tetracarboxylic acid. The resultant starlike polyimides exhibit lower melt flow viscosity than its linear counterparts, providing for improved processability of the polyimide. Also disclosed are methods for the synthesis of these polyimides as well as composite structures formed using these polyimides.Type: GrantFiled: February 1, 2000Date of Patent: July 17, 2001Assignee: The United States of America as represented by the Administrator of National Aeronautics and Space AdministrationInventors: Michael A. Meador, Baochau N. Nguyen, Ronald K. Eby
-
Patent number: 6252033Abstract: A method for preparing polyamic acid and polyimide, which is suitable for use in adhesives or adhesive tapes for electronic parts. The polymers have such three-dimensional molecular structures that a significant improvement can be brought about in solvent solubility, thermal resistance, mechanical properties, and adhesive properties onto various substrates. The polyamic acid is prepared by reacting at least one tetracarboxylic dianhydride, at least one aromatic diamine, at least one diamine with a siloxane structure, represented by the following general formula I, and at least one polyamino compound represented by the following general formula II or III. The polyamic acid is converted into polyimide through thermal or chemical imidization.Type: GrantFiled: March 20, 2000Date of Patent: June 26, 2001Assignee: Saehan Industries IncorporationInventors: Jeong Min Kweon, Soon Sik Kim, Kyeong Ho Chang, Kyung Rok Lee
-
Patent number: 6225437Abstract: Provided are alkenyl and/or alkyl succinimides formed from at least one alkenyl or alkyl succinic anhydride and at least one aliphatic amine having one or two primary amino groups in the molecule. These succinimides are characterized in that each alkenyl or alkyl group thereof contains in the range of 16 to 30 carbon atoms. Such group is bifurcated on its alpha carbon atom into two branches neither of which contains less than 2 carbon atoms, one such branch being free of any side chain, and the other such branch either being free of any side chain or containing at most one methyl or methylene side chain. In addition the succinimide has a viscosity at 80° C. of less than about 100 centistokes. These succinimides are especially useful as internal and external sizing agents for paper and paper products.Type: GrantFiled: June 24, 1999Date of Patent: May 1, 2001Assignee: Albemarle CorporationInventors: Patrick C. Hu, Valerie N. LeGloahec
-
Patent number: 6184333Abstract: The present invention is directed to polyimide systems which simultaneously offer low toxicity, a high glass transition temperature, excellent thermal oxidative stability, and desirable processing characteristics. These various polyimide systems include mixtures of monomeric reactants, polyimide-precursor reaction products, polyimides, and polyimide-containing articles. In one aspect of the invention, the mixture of monomeric reactants includes at least one dia-nhydride or a derivative thereof, and at least one diamine. The diamine may be 4,4′-[1,4-phenylene-bis(1-methylethylidene)]bisaniline, 4,4′-[1,3-phenylene-bis(1-methylethylidene)]bisaniline, and/or a derivative thereof. The diamine also may include a phenylenediamine, 2,2-bis[4-(4-aminophenoxyl)phenyl]propane, 4,4′(1,4-phenylene-bismethylene)bisaniline, and/or a derivative thereof. In addition, the mixture may include a reactive end-capping agent and/or a non-reactive end-capping agent.Type: GrantFiled: January 15, 1999Date of Patent: February 6, 2001Assignee: Maverick CorporationInventor: Robert A. Gray
-
Patent number: 6166174Abstract: Polyimide copolymers were obtained containing 1,3-bis(3-aminophenoxy)benzene (APB) and other diamines and dianhydrides and terminating with the appropriate amount of a non-reactive endcapper, such as phthalic anhydride. Homopolymers containing only other diamines and dianhydrides which are not processable under conditions described previously can be made processable by incorporating various amounts of APB, depending on the chemical structures of the diamines and dianhydrides used. Polyimides that are more rigid in nature require more APB to impart processability than polyimides that are less rigid in nature. The copolymers that result from using APB to enhance processability have a unique combination of properties including: excellent thin film properties, low pressure processing (200 psi and below), improved toughness, improved solvent resistance, improved adhesive properties, improved composite mechanical properties, long term melt stability (several hours at 390 C.), and lower melt viscosities.Type: GrantFiled: August 5, 1999Date of Patent: December 26, 2000Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventor: Brian J. Jensen
-
Patent number: 6140462Abstract: The present invention is directed to oxidative and reductive methods of fabricating electrically conducting polymers and precursors thereof in particular polyanilines in which the polymer chains are deaggregated. Such deaggregated conducting polymers and precusors thereof exhibit better processability and higher electrical conductivity than do the corresponding aggregated polymers. Substituted and unsubstituted polyanilines in the substantially non oxidized or non reduced form (emeraldine form) are converted to an intermediate deaggregated reduced or oxidized form. The intermediate reduced or oxidized deaggregated form is processed into an article. The articles is subsequently treated with a dopant and an oxidizing or reducing agent to reform the original substantially non oxidized or non reduced form. The methods described herein permit the formation of articles such as shaped articles and films having deaggregated structure and higher electrical conductivity.Type: GrantFiled: July 27, 1998Date of Patent: October 31, 2000Assignee: International Business Machines CorporationInventors: Marie Angelopoulos, Alan Graham MacDiarmid, Weigong Zheng
-
Patent number: 6136950Abstract: The invention is directed to a polymer dispersant comprising a substituted polyimide or polyamide backbone, having at least some proportion of oligomeric or polymeric grafted side chains including one of amides, esters, and thioesters, having the general formula: wherein X is at least one of hydrogen, an alkali earth metal ion, an alkaline earth metal ion, ammonium ion, and amine; R is at least one of C.sub.1 to C.sub.6 alkyl(ene) ether and mixtures thereof and C.sub.1 to C.sub.6 alkyl(ene) imine and mixtures thereof; Q is at least one of oxygen, nitrogen, and sulfur; p is a number from 1 to about 300 resulting in at least one of a linear and branched side chain; R.sub.1 is at least one of hydrogen, C.sub.1 to C.sub.Type: GrantFiled: September 23, 1997Date of Patent: October 24, 2000Assignee: MBT Holding AGInventors: Thomas M. Vickers, Jr., Runhai Lu, Lynn E. Brower, Samy M. Shendy, Rainer Packe-Wirth, Hong Gao
-
Patent number: 6132852Abstract: A multilayer wiring substrate using a resin composition comprising polyquinoline compound and bismaleimide compound as essential ingredients between wiring-carrying resin layers as insulating layers forms no void at the time of lamination, has an excellent adhesive property at various interfaces, has a heat stability after lamination and is high in reliability, so that, it is applicable to many fields not only including the multilayer wiring substrates capable of mounting LSI or tip carrier directly but also including multilayer wiring substrate for work station, mounting substrates for small-sized electronic devices such as camera and video for people's use, and high frequency multitip module multilayer substrate.Type: GrantFiled: March 12, 1999Date of Patent: October 17, 2000Assignee: Hitachi, Ltd.Inventors: Masahiro Suzuki, Akio Takahashi, Minoru Tanaka, Haruhiko Matsuyama, Haruo Akahoshi
-
Patent number: 6111031Abstract: A thermoplastic resin composition that contains a polyetherimide resin, a mineral filler and a gloss-enhancing additive selected from linear polysiloxane polymers, polyethylene resins and crystalline thermoplastic resins imparts improved surface gloss to shaped articles molded therefrom.Type: GrantFiled: December 9, 1997Date of Patent: August 29, 2000Assignee: General Electric CompanyInventors: Robert Puyenbroek, Darryl Nazareth
-
Patent number: 6072024Abstract: A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced.Type: GrantFiled: March 17, 1998Date of Patent: June 6, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Yoshihiro Irizato, Makoto Sukegawa, Toshio Katoh, Hiroaki Tamatani, Akinori Nagatomo, Masaru Wada
-
Patent number: 6066696Abstract: An optical alignment composition including a first polymer selected from a cinnamate-series polymer and a coumarin-series polymer, and a second polymer selected from polyimide having a long-chain alkyl group at its side chains and polyimide having an alkyl group at its both ends, an alignment layer formed using the same, and a liquid crystal display having the alignment layer are provided. According to the present invention, the thermal stability of the alignment layer and pretilt angle characteristic of the liquid crystal are improved.Type: GrantFiled: December 9, 1997Date of Patent: May 23, 2000Assignee: Samsung Display Devices Co. Ltd.Inventors: Han-sung Yu, Seong-han Yu
-
Patent number: 6051722Abstract: The present invention provides, as heteroaromatic compounds made functional so as to be used for nonlinear optical materials, compounds represented by the following general formula (1), and also provides polymers obtained from these and nonlinear optical parts comprising such polymers. In the formula, Ar.sup.1 and Ar.sup.2 each represents a divalent aromatic group; R.sup.1, R.sup.2 and R.sup.3 each represents an atom or a group independently selected from a hydrogen atom or an alkyl group and an aromatic group; X.sup.1 represents a monovalent organic group; n represents an integer of 2 to 12; and Z.sup.1 and Z.sup.2 each represents a group independently selected from electron attractive functional groups.Type: GrantFiled: July 6, 1998Date of Patent: April 18, 2000Assignee: Hitachi Chemical Company, Ltd.Inventors: Yutaka Honda, Iwao Fukuchi, Kwan-Yue Alex Jen
-
Patent number: 6037048Abstract: Fibers having increased strength and small diameters can be produced from compositions comprising long chain branched syndiotactic vinyl aromatic polymers. Due to the increased fiber strength, less strand breakage occurs during processing which increases process productivity and yield.Type: GrantFiled: June 29, 1999Date of Patent: March 14, 2000Assignee: The Dow Chemical CompanyInventors: Curtis E. Peterson, Roel H. Vossen, Yi-Bin Huang, Paul J. Moses, Jr.
-
Patent number: 6025439Abstract: Molecular dispersions of rigid-rod polybenzobisazole polymer/copolymer in thermoplastic matrices in a weight ratio of about 1:99 to 50:50 are prepared by dissolving the rigid-rod polymer in an alcoholic or aprotic solvent, dissolving the thermoplastic polymer in an alcoholic or aprotic solvent, combining the two solutions and recovering the resulting molecular composite from the combined solution. These molecular dispersions consist essentially of rigid-rod polybenzobisazole polymer/copolymer having sulfonic acid groups pendant to the polymer/copolymer backbone and thermoplastic polymers selected from the group consisting of polyvinylpyridines, poly(arylene ether ketone)s with a pyridyl functionality, aromatic poly(pyridine ether)s and poly(pyridine ether sulfone) copolymers, and polyimides with a pyridyl functionality.Type: GrantFiled: July 30, 1998Date of Patent: February 15, 2000Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Fred E. Arnold, Narayanan Venkatasubramanian, Thuy D. Dang, Derrick R. Dean
-
Patent number: 6018015Abstract: The invention relates to belts made of thermoplastic polymer (A) and comprising a sufficient amount of a polymer (B) to render them antistatic, the said polymer (B) comprising polyethylene glycol blocks. Use is advantageously made of polymers (A) containing polyamide-6 (PA-6) or polyamide-12 (PA-12) blocks and polytetramethylene glycol blocks and polymers (B) containing PA-6 or PA-12 blocks and polyethylene glycol blocks.Type: GrantFiled: November 2, 1998Date of Patent: January 25, 2000Assignee: Elf Atochem S.A.Inventors: Patrick Alex, Jun Yamamoto
-
Patent number: 6017634Abstract: A thermally curable adhesive composition that includes a fluxing agent that also acts as an adhesive is provided. The composition includes: (a) a fluxing agent represented by the formula RCOOH, wherein R comprises a moiety having two or more carbon-carbon double bonds wherein in one embodiment, at least one is within an acrylate or methacrylate group, and which may further contain at least one aromatic moiety; (b) a carboxylic acid neutralizing agent; (c) optionally, a crosslinkable diluent; (d) optionally, a source of free radical initiators; and (e) optionally, a resin. The composition can be applied directly onto the surface(s) of devices that are to be joined electrically and mechanically. These devices include, printed circuit substrates, connectors, components, cables, and other electrical devices having metallization patterns to be soldered together by means of a solder-bumped pattern on one or both surfaces.Type: GrantFiled: January 23, 1998Date of Patent: January 25, 2000Assignee: Miguel Albert CapoteInventors: M. Albert Capote, Liqui Zhou, Xioqui Zhu
-
Patent number: 6005058Abstract: Polydiacetylenes prepared from 2,4-hexadiyne monomers substituted with at least one side chain component, exhibit an absorption maximum wavelength maximum greater than that exhibited by polydiacetylenes formed from 1,6-di-N-carbazolyl 2,4-hexadiyne. Preferably, the polydiacetylenes exhibit an absorption maximum that is in the range of visible light. Examples of suitable side chain components of the polydiacetylenes include cyanovinyl aromatic substituents and quinoid substituents. The polydiacetylenes exhibit useful third order nonlinear optical behavior for electromagnetic radiation in the visible and near-infrared electromagnetic wavelength range and can be formed by thermally-based synthesis methods.Type: GrantFiled: November 12, 1997Date of Patent: December 21, 1999Assignee: University of Massachusetts LowellInventors: Daniel J. Sandman, James L. Foley
-
Patent number: 5998550Abstract: Molecular dispersions of rigid-rod polybenzobisazole polymer/copolymer in thermosetting matrices in a weight ratio of about 1:99 to 50:50 are prepared by dissolving the rigid-rod polymer in an alcoholic or aprotic solvent, dissolving the thermosetting polymer in an alcoholic or aprotic solvent, combining the two solutions and recovering the resulting molecular composite from the combined solution. These molecular dispersions consist essentially of rigid-rod polybenzobisazole polymer/copolymer having sulfonic acid groups pendant to the polymer/copolymer backbone and thermosetting polymers selected from the group consisting of iminobis(N-propyl-2-phenylethynyl-phthalimide), N-ethyl-(2,6-di-benzocyclobutenoxy)benzylamine, iminobis(N-propylnadic imide) and difunctional benzoxazine monomers of the formula ##STR1## wherein X is a single bond, --CO-- or --C(CH.sub.3).sub.2 -- and Q is --CH.sub.3 or --C.sub.6 H.sub.5.Type: GrantFiled: July 30, 1998Date of Patent: December 7, 1999Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Fred E. Arnold, Narayanan Venkatasubramanian, Thuy D. Dang, Derrick R. Dean
-
Patent number: 5994468Abstract: The instant invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(maleimide-co-alkenyl benzene) polymer with a nylon and an alkyl diamine under substantially dry conditions sufficient to form a nylon grafted poly(maleimide-co-alkenyl benzene) polymer product; and, dispersing the nylon grafted poly(maleimide-co-alkenyl benzene) polymer product with an extender oil sufficient to form the gel. The instant invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: May 6, 1998Date of Patent: November 30, 1999Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, James E. Hall, Naruhiko Mashita, Hideo Takeichi
-
Patent number: 5986016Abstract: A thermoplastic resin composition containing a polyetherimide resin; a siloxane-polyetherimide copolymer; one or more resins selected from the group consisting of polycarbonate resins and copolyester-carbonate resins; and one or more component selected from glycidyl ester impact modifiers and siloxane-polycarbonate copolymers exhibits improved ductility and low temperature impact properties.Type: GrantFiled: December 23, 1997Date of Patent: November 16, 1999Assignee: General Electric Co.Inventors: Robert Puyenbroek, James Fishburn
-
Patent number: 5969079Abstract: Thermomechanical and thermo-oxidative stabilities in resin composites across the range of aerospace "engineering thermoplastic" resins are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities of the general formula: ##STR1## wherein Z= ##STR2## .beta.=the residue an organic radical selected from the group consisting of: ##STR3## R.sub.R =a divalent organic radical; X=halogen;Me=methylT=allyl or methallyl.G=--CH.sub.2 --,--S--, --CO--, --SO--, --O--, --CHR.sub.3 --, or --C(R.sub.3).sub.2 --;i=1 or 2;R.sub.3 =hydrogen, lower alkyl, lower alkoxy, aryl, or aryloxy; and.theta.=--C.tbd.N, --O--C.tbd.N, --S--C.tbd.N, or --CR.sub.3 .dbd.C(R.sub.3).sub.Type: GrantFiled: October 21, 1994Date of Patent: October 19, 1999Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
-
Patent number: 5965682Abstract: Fibers having increased strength and small diameters can be produced from compositions comprising long chain branched syndiotactic vinyl aromatic polymers derived from the polymerization of a vinyl aromatic monomer in the presence of from 10 to 1000 ppm, based on the amount of vinyl aromatic monomer, of a multifunctional monomer having more than one olefinic functionality. Due to the increased fiber strength, less strand breakage occurs during processing which increases process productivity and yield.Type: GrantFiled: March 10, 1998Date of Patent: October 12, 1999Assignee: The Dow Chemical CompanyInventors: Curtis E. Peterson, Yi-Bin Huang, Roel H. Vossen, Paul J. Moses, Jr.
-
Patent number: 5955566Abstract: Thermosetting polymers with high temperature capability for composite and adhesive applications are disclosed. Inhibitors for improving pot life, gel time and storage stability are disclosed. These polymers are ideally suited for adhesives and RTM, resin film infusion, and prepreg methods to make polymer matrix, fiber reinforced composite parts.Type: GrantFiled: November 13, 1996Date of Patent: September 21, 1999Assignee: Cytec Technology CorporationInventors: Jean Lee, Jack Douglas Boyd, Albert Kuo
-
Patent number: 5916688Abstract: This invention relates to resin solution compositions for electronic materials consisting of organic solutions of 100 parts by weight of siloxanepolyimidepolyamic acid copolymers composed of imide segments formed by polycondensation of aromatic tetracarboxylic acid dianhydrides and siloxanediamines and amic acid segments formed by polyaddition of aromatic tetracarboxylic acid dianhydrides and aromatic diamines other than siloxanediamines and represented by the following general formula (1) (in which X is the residue of an aromatic tetracarboxylic acid dianhydride, Y is the residue of a siloxanediamine, Z is the residue of an aromatic diamine, l and m are integers independent of each other, and n is an integer of 1 or more) and 1 to 50 parts by weight of epoxy resins. The compositions are storage-stable and curable at relatively low temperature and yield cured products with an excellent balance of heat resistance, high-frequency characteristics, chemical resistance and stress relaxation characteristics.Type: GrantFiled: February 18, 1998Date of Patent: June 29, 1999Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Kiwamu Tokuhisa, Akira Tokumitsu, Isamu Takarabe
-
Patent number: 5830983Abstract: The invention relates to belts made of thermoplastic polymer (A) and comprising a sufficient amount of a polymer (B) to render them antistatic, the said polymer (B) comprising polyethylene glycol blocks. Use is advantageously made of polymers (A) containing polyamide-6 (PA-6) or polyamide-12 (PA-12) blocks and polytetramethylene glycol blocks and polymers (B) containing PA-6 or PA-12 blocks and polyethylene glycol blocks.Type: GrantFiled: December 23, 1996Date of Patent: November 3, 1998Assignee: Elf Atochem S.A.Inventors: Patrick Alex, Jun Yamamoto