Mixed With -n=c=x Reactant Or Polymer Derived Therefrom (x Is Chalcogen) Patents (Class 525/424)
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Patent number: 5504157Abstract: A homogeneous polymer blend is disclosed containing components A and B. Accordingly A is about 1 to 30% by weight of a rigid, rod-shaped polymer having a persistence length of at least 10 nm and a ratio of molecular length to molecular diameter of at least 30, and B) is about 70 to 99% by weight of a flexible polymer which contains at least one member selected from the group consisting of non-ionic polar groups, ionic groups and groups convertible into ions. The flexible polymer is any one of polyolefins, polyacrylates, polyamides and polyurethanes. Component A) contains at least one chemically fixed member selected from the group consisting of non-ionic polar group, ionic group and a group convertible into ionic group, in an amount sufficient to render said A) and B) compatible one with the other.Type: GrantFiled: January 10, 1995Date of Patent: April 2, 1996Assignee: Bayer AktiengesellschaftInventors: Claus D. Eisenbach, Karl Fischer, Jorg Hoffmann
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Patent number: 5498783Abstract: A thermosetting powder coating composition resistant to overspray incompatibility defects that comprises solid particulates of a uniform mixture of (a) a polyester resin having an average of two or more carboxyl groups, (b) a first crosslinker that is reactive toward the carboxyl groups of the polyester resin, (c) from 1% to 20% of a reactive acrylic copolymer having a weight average molecular weight of from 10,000 to 40,000, and (d) a second crosslinker that is reactive toward the reactive functionality of the acrylic copolymer is described.Type: GrantFiled: August 22, 1994Date of Patent: March 12, 1996Assignee: BASF CorporationInventors: Richard J. Foukes, Cynthia A. Stants
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Patent number: 5486357Abstract: Internal polymeric surfaces of medical devices are provided that have enhanced biocompatibility properties. The internal polymeric surface presents an anti-thrombogenic, fibrinolytic or thrombolytic interface with body fluids such as blood flowing through medical device tubing during implantation for medical procedures. The biocompatibility enhancing agent is secured to the polymeric substrate by a spacer molecule which is covalently bound to the internal polymeric surface which had been subjected to radiofrequency plasma treatment with a low pressure plasma medium of water vapor, oxygen or combination of water vapor and oxygen gas.Type: GrantFiled: October 27, 1993Date of Patent: January 23, 1996Assignee: Cordis CorporationInventor: Pallassana V. Narayanan
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Patent number: 5478887Abstract: A polymer blend comprising an aliphatic polyamide matrix and a dispersed phase of a polycarbonate and a compatibilizing agent having pendant succinic anhydride groups or epoxide groups, made under such blending conditions that the polymer stock melt temperature is 290.degree.-350.degree. C., has a combination of excellent toughness and stiffness properties.Type: GrantFiled: July 26, 1993Date of Patent: December 26, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Gia Huynh-Ba
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Patent number: 5478865Abstract: A method of recycling discarded PU foam articles comprises a first step of grinding the discarded PU foam articles into fine particles, which are then mixed with a predetermined amount of a powdered plastic to form a mixture. The mixture is heated to become a molten mixture, which is cooled to take form. The molten mixture may be adhered to the surface of a cloth or leather material when the cooling and the forming processes of the molten mixture are under way. The final product can be burned at a high temperature to produce a high-carbon residue, which is added to the mixture to make a product having a deodorant and an antistatic effects.Type: GrantFiled: April 21, 1995Date of Patent: December 26, 1995Inventor: Ching-Bing Chang
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Patent number: 5457146Abstract: A blend of polyurethane and chlorinated polyethylene which has a desirable balance of impact, ignition and heat resistance properties.Type: GrantFiled: October 20, 1993Date of Patent: October 10, 1995Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Thomas D. Burns
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Patent number: 5455309Abstract: Methods of producing thermoplastic poly(amide-urethane) block copolymers having excellent flexibility at low temperatures are provided. The methods comprise reacting substantially linear polyamides, the polyamides being based on dimerized fatty acids and terminated by carboxyl and/or amino groups and aliphatic or cycloaliphatic polyethers and/or reaction products thereof with 2,3-epoxypropanol. The reaction products contain substantially no free isocyanate groups or epoxide groups. The invention also relates to the use of these products as adhesives and corrosion inhibitors for metallic and/or wooden materials.Type: GrantFiled: August 3, 1990Date of Patent: October 3, 1995Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Italo Albini, Werner Gruber, Norbert Wiemers, Juergen Wichelhaus, Roberto Leoni, Angela Rossini
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Patent number: 5408012Abstract: This invention relates to polymers having enhanced durable hydrophilicity and rewetting properties. The polymer has bonded thereto a hydrophilic copolymer. The copolymer comprises the reaction product of a primary hydroxylate having rewetting properties and a silane. The aliphatic polyamide or polyester polymer has an affinity for the hydrophilic copolymer and has substantially no polymerization with the hydrophilic copolymer. The present invention also provides a process of treating polymers to impart hydrophilicity and rewetting properties.Type: GrantFiled: May 27, 1993Date of Patent: April 18, 1995Assignee: Comfort Technologies, Inc.Inventor: Lloyd F. Barringer, Jr.
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Patent number: 5403750Abstract: Affinity matrices useful for the chromatography and immobilization of biological materials and the method of preparing and using the same are disclosed. The affinity supports are based on hydrated polyurethane polymers which have been activated to provide a means for covalently attaching a variety of bioaffinity agents. The hydrated polymer matrices are characterized by their biocompatibility and resistance to nonspecific protein adsorption. Preferably, the prepolymers used to prepare the hydrated polymers are isocyanate-capped oxyethylene-based diols or polyols, at least 75% of said diols and polyols having a molecular weight of 7000 to about 30,000.Type: GrantFiled: April 8, 1991Date of Patent: April 4, 1995Assignee: W. R. Grace & Co.-Conn.Inventors: James A. Braatz, Aaron H. Heifetz
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Patent number: 5389705Abstract: Novel polymers which are suitable as binders are obtainable by reacting(A) a base resin which has an average molecular weight M.sub.w of from 200 to 5,000 and contains on average from 1 to 3 epoxy or isocyanato groups as the reactive groups per moleculewith(B) a mixture of(B1) 5 to 50% by weight of polyisobutylene which is terminated with primary amino groups and has an average molecular weight M.sub.w of from 500 to 5,000 and(B2) 5-95% by weight of an amidoamine which carries primary amino groups and is obtainable by condensation of diprimary diamines of 2 to 20 carbon atoms with aliphatic C.sub.2 -C.sub.44 -dicarboxylic acids,the amounts being such that from 1 to 5 equivalents of primary amino groups of (B) are present per equivalent of reactive groups of (A).Type: GrantFiled: August 6, 1993Date of Patent: February 14, 1995Assignee: BASF Lacke + Farben AktiengesellschaftInventors: Klaus Huemke, Helmut Fobbe, Konrad Knoll
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Patent number: 5384365Abstract: A release agent comprising a resin containing siloxane segments is described. The resin has been modified with a silane coupling agent containing at least one free isocyanate group and contains one or more hydrolyzable silyl groups in side chains of its molecule.Type: GrantFiled: December 29, 1993Date of Patent: January 24, 1995Assignees: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Ukima Colour & Chemicals Mfg. Co., Ltd.Inventors: Kazuyuki Hanada, Iwao Misaizu, Masashi Saito, Katsutoshi Torii, Katsumi Kuriyama
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Patent number: 5367017Abstract: The present invention is directed to a aqueous polyurea dispersion for the preparation of an aqueous polyurea dispersion byI) dispersing in water at an NCO:NH equivalent ratio of 0.5:1.0 to 2.0:1.0a) a polyisocyanate which has an average functionality of 1.5 to 4.0 and an isocyanate content of at least 12% by weight andb) a polyamine component containingi) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups and a molecular weight of at least 1000 andii) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups, a molecular weight of less than 400 and at least one anionic or potential anionic group andII) allowing the polyisocyanate and polyamine component to react to form an aqueous polyurea dispersion.The present invention is also directed to the aqueous polyurea dispersion prepared by this aqueous polyurea dispersion.Type: GrantFiled: May 1, 1992Date of Patent: November 22, 1994Assignee: Miles Inc.Inventors: James W. Rosthauser, Robin E. Tirpak
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Patent number: 5364913Abstract: A thermosetting composition is prepared by reacting a highly crosslinked nylon-1 which contains structural units corresponding to ##STR1## where R is an organic radical with a isocyanate-reactive compound. In carrying out the reaction the molar ratio of carbonyl groups to NCO-reactive groups is about 0.5:1 to 20:1. Desirable properties characterize the reaction product thus prepared.Type: GrantFiled: July 28, 1993Date of Patent: November 15, 1994Assignee: Miles Inc.Inventors: Aaron D. Meltzer, Douglas A. Wicks, Harald Pielartzik
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Patent number: 5360888Abstract: Polyamides stabilized to hydrolysis at high temperatures, particularly in an acidic medium, containing 0.1 to 5% by weight based on polyamide of a polymeric aromatic carbodiimide.Type: GrantFiled: April 19, 1993Date of Patent: November 1, 1994Assignee: Rhein Chemie Rheinau GmbHInventor: Volker Ullrich
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Patent number: 5354798Abstract: An engineering polyacetal resin composition comprising 0.05-20 parts by weight of a dispersant (B) and 5-40 parts by weight of a filler (C), and 100 parts by weight of a resin ingredient (A) which comprises 90-50% by weight of a polyacetal resin (a) and 10-50% by weight of a polyamide resin (b) having a melting point of up to 230.degree. C., a maximum particle diameter of 0.03-10 .mu.m and a maximum aspect ratio of up to 2, and is dispersed in a matrix of said polyacetal resin (a).Type: GrantFiled: August 16, 1991Date of Patent: October 11, 1994Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hiroshi Tsukahara, Masahiko Niino
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Patent number: 5336753Abstract: The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) has an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 100.Type: GrantFiled: January 8, 1993Date of Patent: August 9, 1994Assignee: BASF Lacke + Farben AGInventors: Werner A. Jung, Udo Vorbeck, Arno Schmitz, Wilhelm Heise, Lutz-Werner Gross
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Patent number: 5324795Abstract: The present invention relates to a polymer blend composition for melt molding which is a composition obtained by adding a thickener to a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer, characterized in that the melt viscosity of the composition determined at a molding temperature at a shear rate of 1000 sec.sup.-1 is the same or higher than the melt viscosity of said non-liquid crystal polymer determined under the same conditions.According to the present invention, a polymer blend for melt molding having improved properties, whereby problems observed in prior arts upon molding a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer (for example, insufficient alignment of the liquid crystal polymer and difficulties in extrusion, because of excessively low melt viscosity) can be solved, is obtained.Type: GrantFiled: May 12, 1993Date of Patent: June 28, 1994Assignee: Unitika Ltd.Inventor: Jun-ichi Suenaga
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Patent number: 5321097Abstract: A heat-resistant resin composition comprising a melt-kneaded product of:(A) at least one member selected from the group consisting of a polyamideimide resin precursor composed mainly of a recurring unit of the formula (1)-a, ##STR1## wherein R is a divalent aromatic group or aliphatic group, R.sup.1 is a hydrogen atom, an alkyl group or a phenyl group, and Ar is a trivalent aromatic group composed of at least one six-membered ring, and a polyamideimide resin composed mainly of a recurring unit of the formula (1)-b, ##STR2## wherein R, R.sup.1 and Ar are as defined in the above formula (1)-a, (B) a polyphenylene sulfide resin, and(C) an organic isocyanate compound having at least two isocyanate groups in the molecule, the amount of said organic isocyanate compound being 0.5 to 5 parts by weight based on 100 parts by weight of the total amount of the compounds (A) and (B).Type: GrantFiled: April 30, 1993Date of Patent: June 14, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takao Kawaki, Akikazu Amagai, Masahiko Ishikawa, Toshiaki Yamada, Yasuhiro Hirai, Hajime Ban
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Patent number: 5319039Abstract: The tensile strength of a thermoplastic, transparent, aromatic polyester is markedly improved by incorporating into the polyester a thermoplastic, rigid polyurethane. The resultant transparent blend is particularly useful in making eyeglasses, toothbrushes, and screw-driver handles.Type: GrantFiled: April 30, 1992Date of Patent: June 7, 1994Assignee: The Dow Chemical CompanyInventors: Paul J. Moses, Augustin T. Chen
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Patent number: 5288797Abstract: A one-part moisture curable polyurethane adhesive composition comprises a blend of polyurethane prepolymers and one or more additives which unexpectedly improve the sag resistance and mechanical properties of the formulation. The final adhesive composition retains good stability in the absence of moisture for an extended period between manufacture and application of the adhesive, and has a relatively rapid and consistent cure rate in the presence of atmospheric moisture. The final cured composition exhibits good mechanical properties and generally is unaffected by ambient application and cure conditions.Type: GrantFiled: March 19, 1993Date of Patent: February 22, 1994Assignee: Tremco Ltd.Inventors: Hamdy Khalil, Witek Majewski, George Nickel, George Wypych, Jeffrey D. van Heumen
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Patent number: 5284734Abstract: Radiation-reactive mixtures suitable for producing insulating layers and printed circuits are composed of certain precursors for preparing polyimides polyisoindoloquinazolinediones, polyoxazinediones, polyquinazolinediones or polyquinazolones and aryl-containing carbonyl compounds which when excited by UV radiation are capable of hydrogen abstraction, these mixtures undergoing solubility differentiation on irradiation with actinic light.Type: GrantFiled: September 26, 1989Date of Patent: February 8, 1994Assignee: BASF AktiengesellschaftInventors: Rainer Blum, Gerd Rehmer, Hans Schupp
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Patent number: 5283297Abstract: An artificial hair made of a fibers comprising a poly-.alpha.-amino acid derivative insoluble to water and alcohols and represented by one of the following general formulae (1)-(4): ##STR1## providing that R in each of the above formula (1)-(4) is R.sup.a, R.sup.b and R.sup.c represented, respectively, by the following general formula (5), (6) or (7): ##STR2## or made or polyamino acid urethane fiber comprising a copolymer of an amino acid N-carboxy anhydride and a polyurethane, in which the copolymer is subjected to an amidation reaction with an organic diamine and an organic amine having amino groups and mercapto groups or disulfide groups and to shaping into a fibrous form.The artificial hair has a dyeability, shape retainability, natural and soft and flexible feeling, excellent tough and brushing property, as well as has natural color and gloss and toughness like that natural protein fiber.Type: GrantFiled: February 7, 1992Date of Patent: February 1, 1994Assignee: Aderans Co., Ltd.Inventors: Yasuyoshi Miyachi, Nobuo Ito, Masako Koyama
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Patent number: 5281677Abstract: A thermoplastic polyurethane chain extended with an alkylenediol is blended with a thermoplastic polyurethane chain extended with an oxyalkylene qlycol oligomer. The blend is extruded into a catheter tubing having sufficient initial stiffness for satisfactory insertion in a patient and a high degree of softening for safe positioning and long term catheterization procedures without the risk of vessel wall perforation.Type: GrantFiled: September 3, 1992Date of Patent: January 25, 1994Assignee: Becton, Dickinson and CompanyInventors: Theo O. Onwunaka, Fidelis C. Onwumere, James M. Lambert
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Patent number: 5278257Abstract: Compositions containing A) a copolymer based on at least one 1,3-diene and at least one polar, ethylenically unsaturated comonomer and B) a phenol-terminated polyurethane, polyurea or polyurea-urethane of the formula I ##STR1## in which m is 1 or 2, n is 2 to 6, R.sup.1 is the n-valent radical of an elastomeric prepolymer which is soluble or dispersible in epoxide resins, X and Y independently of one another are --O-- or --NR.sup.3 --, it being necessary for one of these groups to be --NR.sup.3 --, R.sup.2 is an m+1-valent radical of a polyphenol or aminophenol after the removal of the phenolic hydroxy group(s) or the amino group or both the amino group and the phenolic hydroxyl group, respectively, and R.sup.3 is hydrogen, C.sub.1 -C.sub.6 alkyl or phenyl, are described.Compounds containing the components A) and B) as well as an epoxide resin C) are also described.The cured products are distinguished by a high peel strength and high resistance to crack propagation.Type: GrantFiled: January 21, 1992Date of Patent: January 11, 1994Assignee: Ciba-Geigy CorporationInventors: Rolf Mulhaupt, Jeremy H. Powell, Christopher S. Adderley, Werner Rufenacht
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Patent number: 5254668Abstract: Amidamines of the following formula are described: ##STR1## where R is independently hydrogen or lower alkyl of 1 to 4 carbon atoms;R' is an alkyl group if k is 1, or an alkylene group if k is greater than 1; where R' has 2 to 18 carbon atoms;R" is independently lower alkylene of 2 to 4 carbon atoms;R'" is independently straight or branched lower alkylene of 2 to 6 carbon atoms;x is independently 1 to 200;y is independently 1 to 300;z is independently 1 to 200;p is independently 2 to 11; andk is from 1 to 8; where the x and z groups may be distributed in blocks or randomly.These compositions are made by reacting a cyclic lactam with an etheramine. Incorporation of increasing quantities of the polyetherpolyamine did not decrease the crystalline melting point (T.sub.m) of the resulting copolymer. The polyamidopolyfunctional amines (poly(amide-ether-amide) triblock copolymers) have a relatively low modulus and retain higher use temperatures than current polyetheramide segment block copolymers.Type: GrantFiled: June 29, 1992Date of Patent: October 19, 1993Assignee: Texaco Chemical CompanyInventors: Richard J. G. Dominguez, Richard J. Clark, II, Richele T. Howelton, George P. Speranza
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Patent number: 5254641Abstract: Films of thermoplastic polyurethanes (TPU) with a Shore hardness of 75 A to 92 A having 5 to 20% by weight of polyether amide block copolymers and/or polyether ester block copolymers, and their use for adhering to other substrates, particularly for back-foaming with polyurethane foam. The invention also relates to the use of an addition of 5 to 20% by weight of polyether amide block copolymers and/or polyether ester block copolymers to thermoplastic polyurethanes with Shore hardnesses of 75 A to 92 A, based on the weight of the thermoplastic polyurethanes, for decreasing the adhesion and/or interlocking of thermoplastic polyurethanes produced by single layer blown extrusion technique.Type: GrantFiled: August 5, 1992Date of Patent: October 19, 1993Assignee: Elf Atochem Deutschland, GmbHInventors: Patrick Alex, Andre Piard, Eduard de Jong
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Patent number: 5250619Abstract: This invention relates to a process for the preparation of particulate, high molecular weight polyamides, to the particulate, high molecular weight polyamides prepared by this process, to the use of these polyamides for the production of moulded bodies, especially by extrusion or blow moulding, and to the articles produced from the polyamides according to the invention. The process is characterized in that polyamides are mixed with concentrates of certain compounds containing phosphorus and worked up into granulates and these granulates are converted into high molecular weight products by solid phase after-condensation.Type: GrantFiled: July 16, 1990Date of Patent: October 5, 1993Assignee: Bayer AktiengesellschaftInventors: Hans-Detlef Heinz, Helmut Schulte, Hans-Josef Buysch
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Patent number: 5248731Abstract: Thermoplastic synthetic polymeric compositions of certain polyurethanes, polyamides or chlorinated polyolefins, having processing temperatures in the range of about 150.degree. to 325.degree. F., can be modified by the addition of a millable thermoplastic polyurethane elastomer thereto to lower the processing temperature by 10.degree. to 30.degree. F. or more. This modification enables the thermoplastic composition to be processed on conventional calendering or extrusion equipment with a lesser amount of energy or with better performance. Also, coated fabrics of such thermoplastic compositions and a fiber reinforcement.Type: GrantFiled: March 20, 1989Date of Patent: September 28, 1993Assignee: Reeves Bros. Inc.Inventors: Fred N. Teumac, John R. Damewood, Jill R. Menzel
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Patent number: 5244654Abstract: Internal polymeric surfaces of medical devices are provided that have enhanced biocompatibility properties. The internal polymeric surface presents an anti-thrombogenic, fibrinolytic or thrombolytic interface with body fluids such as blood flowing through medical device tubing during implantation for medical procedures. The biocompatibility enhancing agent is secured to the polymeric substrate by a spacer molecule which is covalently bound to the internal polymeric surface which had been subjected to radiofrequency plasma treatment with a low pressure plasma medium of water vapor, oxygen or combination of water vapor and oxygen gas.Type: GrantFiled: June 25, 1991Date of Patent: September 14, 1993Assignee: Cordis CorporationInventor: Pallassana V. Narayanan
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Patent number: 5238999Abstract: A one component composition suitable for coating a substrate, including at least one crosslinker having a functionality thereon that is reactive with a functionality on at least one film forming polymer. The crosslinker includes at least one member selected from the group consisting of: blocked isocyanurates of isophorone diisocyanate; derivatives of blocked isocyanurates of isophorone diisocyanate; blocked biurets of isophorone diisocyanate; derivatives of blocked biurets of isophorone diisocyanate. The composition preferably includes a blend of this crosslinker with a second crosslinker, wherein the second crosslinker is at least one member selected from the group consisting of: blocked isocyanurates of hexamethylene diisocyanate; derivatives of blocked isocyanurates of hexamethylene diisocyanate; blocked biurets of hexamethylene diisocyanate; and derivatives of blocked biurets of hexamethylene diisocyanate.Type: GrantFiled: July 14, 1992Date of Patent: August 24, 1993Assignee: BASF CorporationInventors: Vincent C. Cook, James R. Eshelman, Edward A. Guerrini
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Patent number: 5231147Abstract: The present invention relates to thermosetting polyurethane structural adhesive composites and compositions and processes for producing the same comprising dispersing an amine-terminated solid polyamide resin into a polyurethane base resin to form a nonactivated adhesive composite, and activating the same by heating to form an adhesive composition. Another aspect of the invention relates to dispersing an amine-terminated solid polyamide resin and a water generating compound into the polyurethane base resin and heat-activating the same to form an adhesive composition. The invention also relates to polyurethane base resins suitable for use in the processes of the invention, which may also be moisture cured to form a reactive adhesive composition.Type: GrantFiled: February 28, 1992Date of Patent: July 27, 1993Assignee: Rheox, Inc.Inventors: Terrence L. Hartman, Charles A. Cody
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Patent number: 5225489Abstract: This invention relates to mixtures of short fibers of varying lengths, diameters and aspect ratios composed of an anisotropic polymer, to compositions containing said fibers and one or more thermoplastic or thermoset resins, and to a process for forming said mixtures.Type: GrantFiled: December 11, 1990Date of Patent: July 6, 1993Assignee: Allied-Signal Inc.Inventors: Dusan C. Prevorsek, Kwok W. Lem, Hong B. Chin
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Patent number: 5223588Abstract: A composite material is comprised of an in situ polymerized rigid rod polymer and an in situ polymerized matrix polymer. The composite material is isotropic and has enhanced mechanical properties as well as improved temperature resistance, improved solvent resistance and improved moisture resistance.Type: GrantFiled: October 28, 1991Date of Patent: June 29, 1993Assignee: GenCorp Inc.Inventors: Gerd M. Lenke, Donald R. Wiff
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Patent number: 5219657Abstract: An insulated wire comprising a conductor coated and baked thereon with an insulating lacquer, the insulating lacquer comprising (a) 100 parts by weight of a polyamideimide resin having a molecular weight corresponding to a reduced specific viscosity of from 0.1 to 1.0, and (b) 75 to 400 parts by weight of a stabilized polyisocyanate compound derived from diphenylmethane-diisocyanate.Type: GrantFiled: June 8, 1992Date of Patent: June 15, 1993Assignee: Sumitomo Electric Industries Ltd.Inventors: Isao Ueoka, Teruyuki Yamamoto
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Patent number: 5216087Abstract: Novel sulfonated polyethyleneoxide-substituted polymers having improved blood compatibility are provided. The polymers are produced by substituting a polymeric substrate having active sites of amide or acid amide group, such as polyurethane, polyamide and polyacrylamide, with sulfonated polyethyleneoxide [PEO--(SO.sub.3 H).sub.n ].The polymers according to the present invention are valuable as construction materials of the artificial organs for the circulatory system in contact with blood, such as artificial hearts, artificial blood vessels, artificial kidneys, etc.Type: GrantFiled: May 17, 1991Date of Patent: June 1, 1993Assignee: Korea Institute of Science and TechnologyInventors: Young-Ha Kim, Seo-Young Jeong, Kwang-Duk Ahn, Dong-Keun Han
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Patent number: 5194503Abstract: A non-isocyanate flexibilizer additive is provided which finds utility in coating systems such as alkyds, polyesters, acrylic/polyester, alkyd/acrylic, carboxy/epoxy, polyether/urethane, epoxy/polyester, other epoxy, and urea and melamine formaldehyde systems. The non-isocyanate functional flexibilizer has the formula; B--C(O)--NW--A--NX--C(O)--K wherein A is selected from the group consisting fundamentally of polyesters, polyamides, polyureas, polyurethanes, acrylics; biuret, allophonate and urethane extended polyesters; wherein B and K are selected from the group consisting of --OR and --Z--R'--SiOR".sub.(3-n) R"".sub.n wherein R' is a divalent lower alkyl radical of from 1 to 18 carbon atoms, R is a lower alkyl radical of from 1 to 18 carbon atoms, Z is a member selected from the group consisting of S and NR", W and X are selected from H and lower alkyl radicals of from 1 to 10 carbon atoms, wherein R", R" and R"" are H or a lower alkyl radical of from 1-18 carbon atoms, and wherein n is 0, 1 or 2.Type: GrantFiled: July 7, 1992Date of Patent: March 16, 1993Assignee: BASF CorporationInventors: Gerald L. Bajc, Thomas E. Noseworthy, James M. Cameron
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Patent number: 5187228Abstract: A monoglycidyl stabilized polycarbonate and polyamide blend comprising a polycarbonate, a polyamide, a polymeric compatabilizing agent and a monoglycidyl compatabilizing agent is provided wherein the monoglycidyl stabilizer effectively end caps the polyamide without cross linking polymer chains. The polymeric compatabilizing agent comprises a polyetherimide, a polyurethane, a linear segmented thermoplastic elastomer having an ester segment and a hard segment of semi-crystalline, partially aromatic polyamide based on diphenylmethane diisocyanate, hydroxyl containing phenoxypolymers, polyamide-polyarylate block copolymers, polyamide-polyester block copolymers, or blends thereof. The polycarbonate and polyamide blend may further comprise an impact modifying agent or an alloying agent.Type: GrantFiled: March 22, 1991Date of Patent: February 16, 1993Assignee: Dexter CorporationInventors: Peter J. Perron, Khemchand Nangrani, Ed Bourbonais
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Patent number: 5183864Abstract: Disclosed is a process for the preparation of a thermoplastic polymer blend comprising a first preformed thermoplastic polymer such as a polyester, polycarbonate, ABS graft polymer and the like and a second thermoplastic polyamide or polyamideimide. The second polymer is prepared from a diisocyanate and polycarboxylic compund selected from a dicarboxylic acid, tricarboxylic acid or anhydride thereof, or mixtures of these components by reactively processing the monomer components in the presence of the first polymer.Type: GrantFiled: July 27, 1990Date of Patent: February 2, 1993Assignee: The Dow Chemical CompanyInventors: Robert G. Nelb, II, Kemal Onder
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Patent number: 5179191Abstract: A polycondensation and/or addition product containing carboxyl groups and tertiary amino groups, coating agents based on the latter, and the use thereof.The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) and an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 300.Type: GrantFiled: February 27, 1989Date of Patent: January 12, 1993Assignee: BASF Lacke & Farben AktiengesellschaftInventors: Werner A. Jung, Udo Vorbeck, Arno Schmitz, Wilhelm Heise, Lutz-Werner Gross
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Patent number: 5169641Abstract: Polyester/silicon co-crosslinked polymer substrates at least partially degradable by hydrolysis, well adopted as matrices for the controlled release of a wide variety of active agents therefrom, are prepared by controlledly co-crosslinking (a) at least one diorganopolysiloxane having at least two hydroxyl groups per molecule and (b) an oligomeric polylactic and/or polyglycolic polyester .alpha.,.omega.-diol, with an effective co-crosslinking amount of (c) an organic polyisocyanate.Type: GrantFiled: March 6, 1991Date of Patent: December 8, 1992Assignee: Rhone-Poulenc ChimieInventors: Rafael Jorda, Hugues Porte, Ghislaine Torres
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Patent number: 5157055Abstract: A cation exchange polyimide resin having resistance to organic solvents which contains polyamidocarboxylic acid units providing sites of ion exchange and represented by the formula (I): ##STR1## wherein R.sup.1 is a tetravalent organic group, and R.sup.2 is a bivalent organic group, which is capable of trapping cations from organic solvents.Type: GrantFiled: June 4, 1991Date of Patent: October 20, 1992Assignee: Sharp Kabushiki KaishaInventors: Yoshiro Akagi, Koji Ohoka, Shigeru Kaminishi, Hiroshi Taniguchi, Hideo Asahina, Hirotaka Ohno, Mariko Ishino, Atsuhisa Inoue, Yasunari Okamoto, Yoshiharu Nakajima
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Patent number: 5151489Abstract: Block copolymers can be formed from heterocyclic polymers such as PBO and thermoplastic polymers such as polyamide or poly(aromatic ether ketone). The block copolymer compositions are thermoplastic and do not experiSTATEMENT OF GOVERNMENT INTERESTThis invention was made with Government support under contract F33615-86-C-5068 awarded by the Department of the Air Force. The Government has certain rights in this invention.Type: GrantFiled: September 15, 1989Date of Patent: September 29, 1992Assignee: The Dow Chemical CompanyInventors: William J. Harris, Wen-Fang Hwang
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Patent number: 5137972Abstract: A two component composition suitable for coating a substrate comprises at least one crosslinker having a functionality thereon which is reactive with a functionality on at least one film forming polymer present in a separate component of the composition. The crosslinker comprises at least one member selected from the group consisting of: (1) an isocyanurate of isophorone diisocyanate; (2) a derivative of an isocyanurate of isophorone diisocyanate; (3) a biuret of isophorone diisocyanate; and (4) a derivative of a biuret of isophorone diisocyanate. The composition preferably comprises a blend of the this crosslinker with a second crosslinker, wherein the second crosslinker is at least one member selected from the group consisting of: (1) an isocyanurate of hexamethylene diisocyanate; (2) a derivative of an isocyanurate of hexamethylene diisocyanate; (3) a biuret of hexamethylene diisocyanate; and (4) a derivative of a biuret of hexamethylene diisocyanate.Type: GrantFiled: August 29, 1991Date of Patent: August 11, 1992Assignee: BASF CorporationInventor: Vincent C. Cook
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Patent number: 5132108Abstract: Polymeric surfaces of medical devices or components of medical devices are provided that have enhanced biocompatibility properties. The polymeric surface presents an anti-thrombogenic, fibrinolytic or thrombolytic interface with body fluids such as blood during implantation or medical procedures. The biocompatibility enhancing agent is secured to the polymeric substrate by a spacer molecule which is covalently bound to the polymeric substrate which had been subjected to radiofrequency plasma treatment with a water vapor medium.Type: GrantFiled: November 8, 1990Date of Patent: July 21, 1992Assignee: Cordis CorporationInventors: Pallassana V. Narayanan, Kimberly D. Stanley
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Patent number: 5130382Abstract: Hydroxy terminated polyamides are prepared having the formula: ##STR1## wherein R represents a defined hydrocarbon group,R' and R" represents defined oxypropylene groups, and R'" represents a defined oxyethylene group,the hydroxy terminated polyamide having been prepared by first preparing an intermediate dicarboxylic acid terminated polyoxypropylene polyamide by reacting an excess of a dicarboxylic acid component with a diamine mixture composed of a higher molecular weight polyoxypropylene diamine and a lower molecular weight polyoxypropylene diamine, and by reacting the intermediate polyamide with a molar excess of an oxyethylene amino alcohol.Type: GrantFiled: March 30, 1990Date of Patent: July 14, 1992Assignee: Texaco Chemical CompanyInventors: George P. Speranza, Wei-Yang Su
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Patent number: 5128408Abstract: A gas-permeable material with excellent compatibility with blood comprising polyurethane, polyurethaneurea, or the derivatives thereof is provided. The polyurethane or polyurethaneurea is obtained from a composition that comprises diisocyanate; polysiloxane containing terminal hydroxyl groups; and polyol or polyamine containing at least one tertiary amino gorup. The derivatives of the polyurethane or polyurethaneurea is obtained by the following steps of: converting the tertiary amino groups contained in the polyurethane or the polyurethaneurea to quarternary ammonium groups, and treating the polyurethane or the polyurethaneurea having quarternary ammonium groups with heparin.Type: GrantFiled: October 31, 1990Date of Patent: July 7, 1992Assignee: Toyo Boseki Kabushiki KaishaInventors: Masakazu Tanaka, Satoru Murata, Susumu Kashiwabara, Ken Murayama
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Patent number: 5115045Abstract: An isocyanate-reactive composition comprising the reaction product of:a) an organic compound having the formula:Q--[X--COY].sub.norQ--[X--CO--R--(COY).sub.m ].sub.nwherein Q represents an organic residue, X-represents oxygen or sulphur, Y represents a halogen atom or an aryloxy group, R is a polyvalent hydrocarbon radical, m is a whole number from 1 to 3 and n is a whole number of at least 2, andb) a polyfunctional compound which is capable of reacting with reactant (a) and contains at least one imino or enamino group.Type: GrantFiled: March 19, 1991Date of Patent: May 19, 1992Assignee: Imperial Chemical Industries PLCInventors: Herbert R. Gillis, Malcolm Hannaby
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Patent number: 5089561Abstract: Novel alkylcarbamylmethyl aminotriazines self-cure and also function as crosslinkers for compounds containing active hydrogen groups. When the active hydrogen-containing compounds are hydroxylated polymers, coatings are provided with exceptional resistance to detergent and salt-spray exposure and improved abrasion resistance. The novel aminotriazines also can be combined with fillers as binders which when cured provide shaped articles of manufacture, such as insulation and foundry core molds.Type: GrantFiled: March 11, 1991Date of Patent: February 18, 1992Assignee: American Cyanamid CompanyInventors: Peter S. Forgione, Balwant Singh
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Patent number: 5089568Abstract: Block copolymers can be formed from heterocyclic polymers such as PBO and thermopSTATEMENT OF GOVERNMENT INTERESTThis invention was made with Government support under contracts F49620-86-C-0057 and/or F33615-86-C-5068 awarded by the Department of the Air Force. The Government has certain rights in this invention.Type: GrantFiled: October 11, 1988Date of Patent: February 18, 1992Assignee: The Dow Chemical CompanyInventors: William J. Harris, Wen-Fang Hwang
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Patent number: 5087550Abstract: Radiation-reactive mixtures suitable for producing insulating layers and printed circuits are composed of certain precursors for preparing polyimides, polyisoindoloquinazolinediones, polyoxiazinediones, polyquinazolinediones or polyquinazolones and aryl-containing carbonyl compounds which when excited by UV radiation are capable of hydrogen abstraction, these mixtures undergoing solubility differentiation on irradiation with actinic light.Type: GrantFiled: September 26, 1989Date of Patent: February 11, 1992Assignee: BASF AktiengesellschaftInventors: Rainer Blum, Gerd Rehmer, Hans Schupp