Mixed With Additional Polycarboxylic Acid And A Polyamine; Amino Carboxylic Acid Or Derivative; Polyamine Salt Of A Polycarboxylic Acid; Lactam; Or Polymer Derived Therefrom Patents (Class 525/432)
  • Patent number: 8455587
    Abstract: The invention provides a crystalline polyamide-type resin composition comprises (a) a crystalline polyamide resin composition comprising (i) 50 to 90% by weight of crystalline polyamide resin (A) having a relative viscosity in 96% sulfuric acid of not less than 3.5 and (ii) 50 to 10% by weight of a crystalline polyamide resin (B) having a melting point lower than the melting point of polyamide resin (A) by 20° C. or more and a relative viscosity dissolved in 96% sulfuric acid of not more than 3.6, and (b) 1 to 10 part(s) by weight of a modified polyolefin resin (C) having a reactive functional group being able to react with the terminal group and/or main-chain amide group of the polyamide resin. The invention also provides a door checker for automobiles prepared from the crystalline polyamide-type resin composition.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: June 4, 2013
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shyuji Kubota, Satoshi Sakai
  • Publication number: 20130123438
    Abstract: Disclosed is a liquid crystal alignment agent that includes a polymer including a polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof, wherein in Chemical Formulas 1 and 2, X1, X2, Y1 and Y2 are the same as defined in the detailed description.
    Type: Application
    Filed: August 10, 2012
    Publication date: May 16, 2013
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Tae-Hyoung KWAK, Bum-Jin LEE, Jun-Seok KIM, Won-Seok DONG, Kyung-Soo MOON, Hyo-Ju SEO, Yo-Choul PARK, Yong-Tak YANG, Jung-Ah CHOI
  • Publication number: 20130122103
    Abstract: The purpose of the present invention is to provide an electrostatically bonded vesicle which bears disulfide bonds or thiol groups. The present invention relates to a vesicle having a membrane which is formed from both a first polymer of (a) or (b) and a second polymer of (c) or (d) (with the proviso that a combination of (b) and (d) is excepted) and in which the cationic segment and anionic segment of the polymers are partially crosslinked. First polymer: (a) a block copolymer (I) having both an electrically non-charged hydrophilic segment and a cationic segment, (b) an amino acid polymer (I) having a cationic segment. Second polymer: (c) a block copolymer (II) having both an electrically non-charged hydrophilic segment and an anionic segment, (d) an amino acid polymer (II) having an anionic segment.
    Type: Application
    Filed: July 27, 2011
    Publication date: May 16, 2013
    Applicants: TEIJIN LIMITED, THE UNIVERSITY OF TOKYO
    Inventors: Akihiro Kishimura, Kazunori Kataoka, Stephanie Lee, Yasutaka Anraku, Aya Koide, Mitsuru Sakai, QiuMing Yu
  • Publication number: 20130109743
    Abstract: An excellent nucleic acid delivery composition is provided which has reduced cytotoxicity and improved nucleic acid introduction efficiency and gene expression efficiency. The composition comprises: a block copolymer having an uncharged hydrophilic polymer segment and a cationic polymer segment; a cationic polymer; and a nucleic acid, wherein the mol percentage (B/H ratio) of the cationic groups of the block copolymer to the total cationic groups of the block copolymer and the cationic polymer is between 25% and 90%.
    Type: Application
    Filed: July 11, 2011
    Publication date: May 2, 2013
    Applicant: The University of Tokyo
    Inventors: Kazunori Kataoka, Takehiko Ishii, Kensuke Osada, Qixian Chen, Keiji Itaka, Satoshi Uchida
  • Patent number: 8410216
    Abstract: The invention relates to a composition based on an impact-resistant thermoplastic polyamide resin, comprising, as a blend—from 60 to 98 wt % of polyamide resin (A) and—from 2 to 40 wt % of a blend of at least one graft copolymer with polyamide blocks (B) composed of a polyolefin backbone and at least one polyamide graft in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a functional group capable of reacting with an amine-terminated polyamide, the residues of the unsaturated monomer (X) being attached to the backbone by grafting or copolymerization via its double bond, and of a non-reactive ethylenic polymer (C) that is miscible with (B) and has a density of below 0.960 g/cm3.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: April 2, 2013
    Assignee: Arkema France
    Inventors: Marius Hert, Alain Bouilloux, Thibaut Montanari, Thomas Fine
  • Publication number: 20130078402
    Abstract: [Problems] Provided is a polyamide resin material having high elastic modulus, good gas barrier properties, low water absorption and excellent flexibility. [Means for solving the problems] This is a polyamide resin composition comprising a polyamide resin (A) composed of a diamine structural unit and a dicarboxylic acid structural unit wherein 70 mol % or more of the diamine structural unit is derived from xylylenediamine and 50 mol % or more of the dicarboxylic acid structural unit is derived from sebacic acid, and 1 to 40 parts by mass of at least one copolyamide (B) selected from the following group consisting of (B-1)-(B-3) per 100 parts by mass of the polyamide resin (A); (B-1): a copolyamide 6/66/12; (B-2): a copolyamide 6/66/11; (B-3): a polyether-polyamide copolymer composed of a polyamide 12 unit or a polyamide 11 unit and a polyether unit.
    Type: Application
    Filed: July 4, 2011
    Publication date: March 28, 2013
    Applicant: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Jun Mitadera, Masashi Kurokawa, Takahiro Takano
  • Patent number: 8404777
    Abstract: Composite materials that contain thermoplastic-toughened cyanate ester resins as the resin matrix. The composite materials exhibit low levels of heat release when burned. The matrix resins are composed of from 50 to 80 weight percent of a cyanate ester resin component. The matrix resin composition also includes from 10 to 40 weight percent of a thermoplastic blend that is composed of polyetherimide and polyamideimide. The epoxy resin composition further includes from 1 to 10 weight percent of a curative agent. The composite materials may be used for primary structures in aircraft and other load-bearing structures.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: March 26, 2013
    Assignee: Hexcel Corporation
    Inventors: Yen-Seine Wang, Yi-Jui Wu
  • Patent number: 8399557
    Abstract: Transparent blend or alloy comprising, by weight, the total being 100%: (A) 1 to 99% of at least one copolymer constituent: which is amorphous or has a crystallinity ranging up to semicrystallinity; and which comprises: (A1) amide units, among which is at least one cycloaliphatic unit; (A2) flexible ether units; (B) 99 to 1% of at least one polymer constituent selected from: (Ba) semicrystalline copolyamides comprising amide units (Ba1) and comprising ether units (Ba2), (Bb) semicrystalline polyamides or copolyamides without ether units, (Bc) transparent polyamides or copolyamides without ether units, which are amorphous or weakly crystalline, and alloys based on such polyamides or copolyamides; and (C) 0 to 50% by weight of at least one polyamide, copolyamide, copolyamide comprising ether units or alloy based on such polyamides or copolyamides other than those used in (A) and (B) above.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: March 19, 2013
    Assignee: Arkema France
    Inventors: Thibaut Montanari, Philippe Blondel
  • Patent number: 8399573
    Abstract: Thermoplastic compositions having miscible and compatible immiscible polymer blends are disclosed. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.
    Type: Grant
    Filed: November 22, 2006
    Date of Patent: March 19, 2013
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
  • Patent number: 8389646
    Abstract: The present invention refers to medical devices comprising a modified Co-Polymer or to the modified Co-Polymer itself having high flexibility and high stress resistance, especially tensile strength or tear resistance, in addition to the good physical characteristics of a Block-Co-Polymers of a polyamide and a polycarbonate, either polycarbonate diol or polycarbonate diamine.
    Type: Grant
    Filed: May 9, 2008
    Date of Patent: March 5, 2013
    Assignee: Abbott Laboratories Vascular Enterprises Limited
    Inventor: Günter Lorenz
  • Publication number: 20130052375
    Abstract: An intermediate transfer member that includes a mixture of a thermoplastic polyimide, a polybenzimidazole, and an optional conductive filler.
    Type: Application
    Filed: August 22, 2011
    Publication date: February 28, 2013
    Applicant: XEROX CORPORATION
    Inventor: Jin WU
  • Patent number: 8383244
    Abstract: Disclosed is a polyamide molding compound having heat aging resistance for use as automobile or electrical components and composed of: (A) 27-84.99 wt % of a polyamide mixture consisting of (A1) at least one semiaromatic, semicrystalline polyamide having a melting point of 255° C. to 330° C., (A2) at least one caprolactam-containing polyamide that is different from (A1) and that has a caprolactam content of at least 50 wt %, where the total caprolactam content is 22-30 wt %, with respect to the polyamide mixture, (B) 15-65 wt % of at least one filler and reinforcing agent, (C) 0.01-3.0 wt % of at least one thermal stabilizer, and (D) 0-5.0 wt % of at least one additive, where the components (A)-(D) add up to 100 wt %.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: February 26, 2013
    Assignee: EMS-Patent AG
    Inventors: Andreas Bayer, Nikolai Lamberts, Botho Hoffmann, Manfred Hewel
  • Patent number: 8357455
    Abstract: The invention relates to the use of a molding composition which comprises at least 50% by weight of a copolyamide, which is composed of the following monomer combination: a) from 65 to 99 mol % of a substantially equimolar mixture composed of an unbranched aliphatic diamine having from 6 to 18 carbon atoms and of an unbranched aliphatic dicarboxylic acid having from 6 to 18 carbon atoms, ?where the mixture composed of diamine and dicarboxylic acid comprises an average of from 8 to 12 carbon atoms, b) from 1 to 35 mol % of a substantially equimolar mixture composed of a cycloaliphatic diamine having from 8 to 20 carbon atoms and of a dicarboxylic acid having from 6 to 18 carbon atoms, for production of a printable or printed item, such as a ski topcoat.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: January 22, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Franz-Erich Baumann, Roland Wursche, Harald Häger, Sonja Bollmann, Kirsten Alting
  • Patent number: 8349971
    Abstract: The present invention provides a process for preparing a solvent-soluble polyimide copolymer synthesized from a 6,6-imide segment having an imide oligomer with PMDA at both ends produced by adding 4 molar equivalents of pyromellitic dianhydride (PMDA) and 2 molar equivalents of diaminotoluene (DAT) to an imide oligomer produced by heating 1 molar equivalent of biphenyltetracarboxylic dianhydride (BPDA) and 2 molar equivalents of diaminodiphenyl ether (DADE) at 160-200° C. in the presence of a catalyst in an organic polar solvent.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: January 8, 2013
    Assignees: Solpit Industries, Ltd., Sojitz Corporation
    Inventor: Hiroshi Itatani
  • Publication number: 20120315483
    Abstract: The invention relates to a polymer powder for use in a layer-by-layer method in which areas of each powder layer are selectively fused by introducing electromagnetic energy. Said polymer powder contains: at least one AB-type polyamide produced by polymerizing lactams comprising 10 to 12 carbon atoms in the monomer unit or polycondensing the corresponding ?-amino carboxylic acids comprising 10 to 12 carbon atoms in the monomer unit and at least one AABB-type polyamide produced by polycondensing diamines and dicarboxylic acids, each of which comprises 10 to 14 carbon atoms in the monomer units, the AB-type polyamide containing up to 20 mole % of the AABB comonomer units and the AABB-type polyamide containing up to 20 mole % of the AB monomer units.
    Type: Application
    Filed: April 6, 2011
    Publication date: December 13, 2012
    Applicant: Evonik Degussa GmbH
    Inventors: Franz-Erich Baumann, Wolfgang Diekmann, Beatrice Kueting, Heike Stemmer, Maik Grebe, Kristiane Warnke, Sylvia Monsheimer, Harald Haeger
  • Patent number: 8323791
    Abstract: A polyamide filament is disclosed. The filament includes a polyamide resin. The resin is obtained from mixing crystalline polyamide (A) with another polyamide (B). Crystalline polyamide (A) is obtained by a polycondensation reaction of metaxylenediamine and adipic acid. Crystalline polyamide (A) comprises from 5 to 50 wt. % of the resin. Polyamide (B) comprises from 50 to 95 wt. % of the resin. The filament is heated to 160 to 200° C. under a constant length condition at an initial load of 20 mg/d. After heating, a thermal contraction stress of the filament is not reduced in a cool-down region not greater than 80° C.
    Type: Grant
    Filed: November 10, 2005
    Date of Patent: December 4, 2012
    Assignee: Nippon Filcon Co., Ltd.
    Inventor: Shinya Murakami
  • Publication number: 20120296037
    Abstract: A polyamide block copolymer that includes a first segment including a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, or a combination thereof; and a second segment including a repeating unit represented by Chemical Formula 3. The variables R1 to R15, and n1 to n8 are defined herein.
    Type: Application
    Filed: February 1, 2012
    Publication date: November 22, 2012
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Chung Kun CHO, Kalinina FEDOSYA, Kovalev MIKHAIL, Sang Mock LEE
  • Publication number: 20120289652
    Abstract: Supramolecular polymers having repeat units connected by hydrogen bonds, where the repeat units are monomers, macromers, oligomers or polymers where at least one on the monomers contains at least one 2,5-diketopiperazine group are described. Composition prepared from these supramolecular polymers and articles produced from these compositions are also described.
    Type: Application
    Filed: July 30, 2010
    Publication date: November 15, 2012
    Applicant: RHODIA OPERATIONS
    Inventors: Thierry Badel, Stéphane Jeol, Franck Touraud
  • Patent number: 8304499
    Abstract: Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: November 6, 2012
    Assignee: Eastman Chemical Company
    Inventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
  • Patent number: 8293160
    Abstract: At an optional stage in the production step of a biaxially stretched film using a polyamide resin including, as a first component, nylon 6, and as a second component, a polyamide including xylylenediamine and an aliphatic dicarboxylic acid having 4 to 12 carbon atoms, the film is brought into contact with water set at 40° C. or higher and lower than 70° C. for 1 to 10 minutes and further with water set at 70° C. or higher for 1 to 10 minutes. In the film thus obtained, the content of low molecular weight compounds is 0% by mass to 0.2% by mass.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: October 23, 2012
    Assignee: Unitika Ltd.
    Inventors: Kiwamu Yuki, Makoto Nakai, Atsuko Noda
  • Patent number: 8293364
    Abstract: A highly shrinkable fiber composed of nylon-MXD6 polymer and nylon-6 polymer, characterized in that a weight ratio therebetween is in the range of 35:65 to 70:30, and that each thereof exhibits a breaking strength of 4.00 cN/dtex or greater. Preferably, the weight ratio between nylon-MXD6 polymer and nylon-6 polymer of the highly shrinkable fiber is in the range of 45.55 to 55:45. The highly shrinkable fiber exhibits a high shrinkage ratio in boiling water, so that when the highly shrinkable fiber is used in a woven fabric, there can be realized a high density.
    Type: Grant
    Filed: April 18, 2007
    Date of Patent: October 23, 2012
    Assignee: KB Seiren, Ltd.
    Inventors: Hayato Iwamoto, Yoshitomo Hara, Hideo Ueda, Masaharu Saito
  • Patent number: 8283408
    Abstract: Composite materials that contain thermoplastic-toughened cyanate ester resins as the resin matrix. The composite materials exhibit low levels of heat release when burned. The matrix resins are composed of from 50 to 80 weight percent of a cyanate ester resin component. The matrix resin composition also includes from 10 to 40 weight percent of a thermoplastic blend that is composed of polyetherimide and polyamideimide. The epoxy resin composition further includes from 1 to 10 weight percent of a curative agent. The composite materials may be used for primary structures in aircraft and other load-bearing structures.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: October 9, 2012
    Assignee: Hexcel Corporation
    Inventors: Yen-Seine Wang, Yi-Jui Wu
  • Patent number: 8268934
    Abstract: Methods of making miscible and compatible immiscible polymer blends are disclosed. The polymer blends have a polyimide as a component. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.
    Type: Grant
    Filed: November 22, 2006
    Date of Patent: September 18, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
  • Patent number: 8268937
    Abstract: The invention pertains to an aramid copolymer composition comprising an aramid copolymer having at least one arylene carboxylic acid moiety and at least one hydroxyarylene moiety, or comprising an aramid copolymer having at least one arylene carboxylic acid moiety or having at least one hydroxyarylene moiety, and a crosslinker agent. The invention further relates to crosslinked copolymers derived thereof and shaped articles comprising said crosslinked copolymers.
    Type: Grant
    Filed: September 1, 2007
    Date of Patent: September 18, 2012
    Assignee: Teijin Aramid B.V.
    Inventors: Johannes Bos, Sandra Corien Noordewier
  • Patent number: 8263732
    Abstract: [Object] To obtain an alignment film having excellent alignment stability of a liquid crystal and a high voltage holding ratio by application of linearly polarized light to a polyamic acid having a specific structure and then imidization under heat. [Solving Means] A photo-alignment film is obtained by: applying a polyamic acid solution on a substrate, where the polyamic acid contains, in its main chain, at least a group having unsaturated groups having 1 to 3 carbon-carbon double bonds or 1 to 4 triple bonds; vaporizing a solvent from a film formed; applying linearly polarized light to the film after the vaporization of the solvent; and then heating the film to imidize the polyamic acid.
    Type: Grant
    Filed: March 12, 2007
    Date of Patent: September 11, 2012
    Assignees: JNC Corporation, Chisso Petrochemical Corporation
    Inventor: Norio Tamura
  • Patent number: 8252868
    Abstract: A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: August 28, 2012
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Patent number: 8252872
    Abstract: The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: August 28, 2012
    Assignees: Arkema France, Centre National de la Recherche Scientifique
    Inventors: Francois-Genes Tournilhac, Ludwik Leibler, Philippe Cordier, Corinne Soulie-Ziakovic, Annett Linemann, Manuel Hidalgo
  • Publication number: 20120202953
    Abstract: A gas separation membrane is provided which has both excellent gas permeability and gas separation characteristics, particularly permeability of carbon dioxide (CO2) and separation characteristics of carbon dioxide and methane (CH4), at such a high level that has not hitherto been achieved. The gas separation membrane was obtained by heat treating a membrane composed of a hyperbranched polyimide-based material in a non-oxidizing atmosphere.
    Type: Application
    Filed: February 17, 2012
    Publication date: August 9, 2012
    Applicants: NATIONAL UNIVERSITY CORP KYOTO INSTITUTE OF TECH, IBIDEN CO., LTD.
    Inventors: Tomoyuki Suzuki, Yasuharu Yamada
  • Publication number: 20120183711
    Abstract: The invention relates to a composition comprising at least one first polyamide, conforming to the formula MXD.10 or MXD.10/Z and having a melting temperature Tf1, and at least one second polyamide. Said at least second polyamide has a melting temperature Tf2 such that Tf1?40° C.?Tf2<Tf1+20° C. The invention likewise relates to an article obtained from such a composition, to a method of shaping such an article, and to the use of such a composition and of such an article.
    Type: Application
    Filed: July 1, 2010
    Publication date: July 19, 2012
    Applicant: ARKEMA FRANCE
    Inventors: Benoit Brule, Barbara Ramfel
  • Publication number: 20120172541
    Abstract: A liquid crystal alignment agent includes a first polymer including polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof. A liquid crystal alignment film manufactured using the liquid crystal alignment agent, and a liquid crystal display including the liquid crystal alignment film are also provided.
    Type: Application
    Filed: July 26, 2011
    Publication date: July 5, 2012
    Applicant: CHEIL INDUSTRIES INC.
    Inventors: Won-Seok DONG, Bum-Jin LEE, Tae-Hyoung KWAK, Yo-Choul PARK, Hyo-Ju SEO, Hwan-Sung CHEON, Won-Ho CHOI
  • Patent number: 8211344
    Abstract: The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection molding and sheet extrusion/calendering. Advantageously, the microcrystalline polyamide is such that its degree of crystallinity is greater than 10% and less than 30% (1st DSC heating according to ISO 11357 at 40° C.
    Type: Grant
    Filed: October 20, 2010
    Date of Patent: July 3, 2012
    Assignee: Arkema France
    Inventors: Thibaut Montanari, Christelle Recoquille
  • Publication number: 20120136103
    Abstract: The invention relates to a thermoplastic polymer composition that contains polyamide and comprises an excellent compromise of properties, in particular mechanical properties, and a high fluidity at the molten state. The invention particularly relates to a composition containing at least a high-fluidity linear polyamide and optionally fillers such as glass fibres, and to a method for making such a composition.
    Type: Application
    Filed: November 24, 2009
    Publication date: May 31, 2012
    Applicant: RHODIA OPERATIONS
    Inventors: Marco Amici, Cesare Guaita
  • Publication number: 20120123063
    Abstract: An object of the present invention is to provide a polyamide imide resin composition having excellent in heat resistance, mechanical strength, and tracking resistance. The polyamide imide resin composition includes a polymer blend of a polyamide imide resin including an alicyclic structure and an aromatic polyamide imide resin.
    Type: Application
    Filed: November 8, 2011
    Publication date: May 17, 2012
    Applicant: NITTO DENKO CORPORATION
    Inventors: Shunsuke MASAKI, Kiichiro MATSUSHITA
  • Publication number: 20120108127
    Abstract: Disclosed herein are composite structures, overmolded composites structures and processes for their preparation. The disclosed composite structures have a surface having at least a portion made of a surface resin composition, and comprise a fibrous material being impregnated with a matrix resin composition, wherein the matrix polyamide resin composition and the surface resin composition are selected from polyamide compositions comprising a blend of semi-aromatic polyamides.
    Type: Application
    Filed: October 27, 2011
    Publication date: May 3, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Shengmei Yuan, Andri E. Elia, Olaf Nobert Kirchner, Martyn Douglas Wakeman, Bryan Benedict Sauer, Phong Du
  • Publication number: 20120101236
    Abstract: To provide a polyamic acid ester-containing polyimide precursor composition having a good storage stability, from which a polyimide film having a high imidization degree and excellent adhesion to an inorganic substrate can be obtained. A polyimide precursor composition comprising a polyamic acid ester, a thermal imidization accelerator and a solvent, wherein the thermal imidization accelerator is a compound which has a carboxy group and an amino group or an imino group which is deprotected by heat to show basicity, and which will not accelerate the imidization of the polyamic acid ester before the protecting group leaves, and a polyimide precursor composition containing a silane coupling agent.
    Type: Application
    Filed: April 1, 2010
    Publication date: April 26, 2012
    Applicant: Nissan Chemical Industries, Ltd.
    Inventors: Naoki Sakumoto, Masato Nagao, Yuho Noguchi
  • Publication number: 20120094059
    Abstract: The present invention relates to a nylon yarn of a finely dispersed melt blended polymer alloy having i) a polyamide component selected from polyhexamethyleneadipamide, polycaprolactam and mixtures thereof, and ii) a nylon 11 component; wherein the polyamide component is the major component by weight of the total melt blended polymer and wherein the polyamide component has a viscosity of about 2.6 IV or more as measured in 96% sulfuric acid. The resulting nylon yarn shows improved bleach resistance. The present invention also relates to processes of producing the yarn and nylon carpets comprising the yarn described above.
    Type: Application
    Filed: May 11, 2010
    Publication date: April 19, 2012
    Applicant: INVISTA NORTH AMERICA S.a r.l.
    Inventors: Kevin Leonard Urman, Sundar Mohan Rao, Isaac Keene Ivedrson
  • Patent number: 8158268
    Abstract: A metal-coated polyimide film is excellent in long-term adhesion reliability, exhibits various dimensional stabilities, and is particularly suitable for FPC, COF and TAB applications. The metal-coated polyimide film comprises a non-thermoplastic polyimide film; and a metal layer being directly formed on one surface or both surfaces of the non-thermoplastic polyimide film without using an adhesive, wherein the non-thermoplastic polyimide film contains a non-thermoplastic polyimide resin having a thermoplastic polyimide block component.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: April 17, 2012
    Assignee: Kaneka Corporation
    Inventors: Hisayasu Kaneshiro, Takashi Kikuchi, Shogo Fujimoto
  • Publication number: 20120088848
    Abstract: Methods and compositions for the generation of polypeptides having varied material properties are disclosed herein. Methods include means for initiating the polymerization of aminoacid-N-carboxyanhydride (NCA) monomer by combining the monomer with an amido-containing metallacycle, for making self assembling amphiphilic block copolypeptides and related protocols for adding oligo(ethyleneglycol) functionalized aminoacid-N-carboxyanhydrides (NCAs) to polyaminoacid chains. Additional methods include means of adding an end group to the carboxy terminus of a polyaminoacid chain by reacting an alloc-protected amino acid amide with a transition metal-donor ligand complex to forming an amido-amidate metallacycle for use in further polymerization reactions. Novel compositions for use in peptide synthesis and design including five and six membered amido-containing metallacycles and block copolypeptides are also disclosed.
    Type: Application
    Filed: March 31, 2011
    Publication date: April 12, 2012
    Inventors: Timothy J. Deming, Miaoer Yu, Scott A. Curtin, Jungyeon Hwang, Michael D. Wyrsta, Andrew Nowak, Scott W. Seidel
  • Publication number: 20120088040
    Abstract: Disclosed is a liquid crystal display device including: a first substrate and a second substrate, one of which is transparent; a liquid crystal layer disposed between the first substrate and the second substrate; a group of electrodes for applying an electric field to the liquid crystal layer, which is formed on one of the first substrate and the second substrate; a plurality of active elements connected to the group of electrodes; and an alignment film disposed on one of the first substrate and the second substrate, wherein the alignment film contains a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride, and the diamine contains a first diamine having an acidic group and a second diamine having a nitrogen atom-containing functional group other than two amino groups.
    Type: Application
    Filed: October 6, 2011
    Publication date: April 12, 2012
    Inventors: Masaki Matsumori, Yasuo Imanishi, Yasushi Tomioka, Noboru Kunimatsu
  • Patent number: 8153729
    Abstract: Dendritic macroinitiator compositions are provided comprising a compound of the general formula, Fx-[G-n]-I, where F is the chain end functional group of the dendrimer, x is the number of chain end functional groups, G is the dendrimer, n is the generation number of the dendrimer, and I is the initiating group. Hybrid dendritic-linear copolymers made from these macroinitators can act as highly efficient dispersing agents for a range of nanoparticles in matrix materials.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: April 10, 2012
    Assignees: The Regents of the University of California, Mitsubishi Chemical Corporation
    Inventors: Craig J. Hawker, Robert Vestberg, Nobuhiko Ueno
  • Patent number: 8138259
    Abstract: The invention relates to a housing from a polyamide molding compound containing 70 to 99.5% by weight of at least one thermoplastic polyamide and 0.5 to 30% by weight of at least one polyamide oligomer with linear or branched chain structure with a number average molar mass of 800 to 5000 g/mol with basic end groups which are at least partially NH2 end groups, and carboxyl end groups, one of these end groups being present in excess and the concentration of the end group present in excess being at most 300 mmol/kg.
    Type: Grant
    Filed: August 28, 2009
    Date of Patent: March 20, 2012
    Assignee: Ems-Chemie AG
    Inventors: Paul Schwitter, Georg Stoeppelmann, Alex Stolarz, Helmut Thullen
  • Publication number: 20120062228
    Abstract: This invention relates to the preparation of polyamide block copolymers by sequential monomer addition. More particularly, it relates to catalysts capable of copolymerizing not only cyclic amides, but other monomers such as cyclic esters and epoxides as well, using sequential addition so as to produce useful and novel block copolymers.
    Type: Application
    Filed: November 21, 2011
    Publication date: March 15, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: David T. Williamson, Elizabeth Forrester McCord, Wilson Tam
  • Patent number: 8133417
    Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enables the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: March 13, 2012
    Assignee: Eastman Chemical Company
    Inventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
  • Publication number: 20120047634
    Abstract: Embodiments of the present disclosure include helmet liners, helmets, helmets with deflective structures, helmets with thermochromic features, and methods of making helmet liners, helmets, helmets with deflective structures, and helmets with thermochromic features.
    Type: Application
    Filed: May 14, 2010
    Publication date: March 1, 2012
    Inventor: Uday Vaidya
  • Publication number: 20120052015
    Abstract: Polymers that can include an end-cap selected from Formula (I) and/or Formula (II) and a recurring unit of the Formulae (III), and/or (IV). The polymers can include various substituents such as drug, targeting agents, stabilizing agents, imaging agent and polydentate ligands. Such polymer can be useful for variety of drug, targeting, stabilizing and/or imaging agent delivery applications.
    Type: Application
    Filed: August 18, 2011
    Publication date: March 1, 2012
    Applicant: Nitto Denko Corporation
    Inventors: Lei Yu, Hai Wang, Kwok Yin Tsang, Yi Jin, Sang Van
  • Patent number: 8124686
    Abstract: The present invention relates to a process for the preparation of polyamide-12 powder by anionic polymerization of lauryllactam in solution in a solvent of the lactam, the polyamide-12 powder being insoluble in this solvent, the polymerization being carried out: in the presence of a catalyst and of an activator; in the presence of a finely divided organic or inorganic filler, the proportion of this filler being less than or equal to 1.5 g per 1000 g of lauryllactam; and in the presence of an amide of formula R1—NH—CO—R2 in which R1 can be replaced by an R3—CO—NH— or R3—O— radical and in which R1, R2 and R3 denote an aryl, alkyl or cycloalkyl radical, the proportion of this compound being between 0.001 mol and 0.030 mol per 1000 g of lauryllactam.
    Type: Grant
    Filed: March 2, 2005
    Date of Patent: February 28, 2012
    Assignee: Arkema France
    Inventors: Karine Loyen, Holger Senff, Francois-Xavier Pauly
  • Patent number: 8114387
    Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: February 14, 2012
    Assignee: Arizona Chemical Company, LLC
    Inventor: Mark S. Pavlin
  • Publication number: 20120027859
    Abstract: The invention provides sequential poly(ester amide)s derived from Proline and that are synthesized by a two-step method, involving a final thermal polyesterification reaction. Molecular weights of polymers prepared by this method are from 14,000 Da to about 77,000 Da.1 When invention proline-based PEAs were thermally characterized, their glass transition temperatures were lower than other alpha-amino acid based poly(ester amides) due to lack of internal hydrogen bonding. These Proline-based PEAs assemble as nano-particles in aqueous solutions and form complexes with various cations and biologies, including hydrophobic small molecule drugs and biologies. Therefore the invention Proline-based PEAs are useful for drug delivery applications requiring a polymer with a molecular weight in the range from 14,000 Da to about 77,000 Da and for fabrication of nanoparticles for delivery of hydrophobic drugs.
    Type: Application
    Filed: October 13, 2009
    Publication date: February 2, 2012
    Inventors: William G. Turnell, Zaza D. Gomurashvili, Jeffrey Neil Anderl
  • Publication number: 20120016077
    Abstract: A polyamide resin obtained by heating and condensation-polymerizing ingredients mainly comprising pentamethylenediamine having a total content of 2,3,4,5-tetrahydropyridine and piperidine of 0.10 wt. % or lower and an aliphatic dicarboxylic acid having 7 or more carbon atoms, a 0.01 g/mL solution of the polyamide resin in 98% sulfuric acid having a relative viscosity at 25° C. of 1.8-4.5. The polyamide resin has excellent heat resistance, extremely low water absorption, and excellent melt residence stability and is hence suitable for use as long molded articles represented by automotive radiator tanks, etc.
    Type: Application
    Filed: March 25, 2010
    Publication date: January 19, 2012
    Applicant: TORAY INDUSTRIES INC.
    Inventors: Koya Kato, Atsushi Masunaga, Hideo Matsuoka
  • Patent number: 8097684
    Abstract: Thermoplastic compositions containing a polyamide and/or polyester matrix and a variety of additives have high fluidity and can be shaped into plastic articles with good mechanical properties and an improved surface appearance.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: January 17, 2012
    Assignee: Rhodia Engineering Plastics S.R.L.
    Inventors: Florence Clement, Franck Touraud, Nicolangelo Peduto, Christophe Lapierre, Frédéric Tronc