Mixed With Additional Polycarboxylic Acid And A Polyamine; Amino Carboxylic Acid Or Derivative; Polyamine Salt Of A Polycarboxylic Acid; Lactam; Or Polymer Derived Therefrom Patents (Class 525/432)
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Patent number: 8455587Abstract: The invention provides a crystalline polyamide-type resin composition comprises (a) a crystalline polyamide resin composition comprising (i) 50 to 90% by weight of crystalline polyamide resin (A) having a relative viscosity in 96% sulfuric acid of not less than 3.5 and (ii) 50 to 10% by weight of a crystalline polyamide resin (B) having a melting point lower than the melting point of polyamide resin (A) by 20° C. or more and a relative viscosity dissolved in 96% sulfuric acid of not more than 3.6, and (b) 1 to 10 part(s) by weight of a modified polyolefin resin (C) having a reactive functional group being able to react with the terminal group and/or main-chain amide group of the polyamide resin. The invention also provides a door checker for automobiles prepared from the crystalline polyamide-type resin composition.Type: GrantFiled: December 19, 2007Date of Patent: June 4, 2013Assignee: Toyo Boseki Kabushiki KaishaInventors: Shyuji Kubota, Satoshi Sakai
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Publication number: 20130123438Abstract: Disclosed is a liquid crystal alignment agent that includes a polymer including a polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof, wherein in Chemical Formulas 1 and 2, X1, X2, Y1 and Y2 are the same as defined in the detailed description.Type: ApplicationFiled: August 10, 2012Publication date: May 16, 2013Applicant: CHEIL INDUSTRIES INC.Inventors: Tae-Hyoung KWAK, Bum-Jin LEE, Jun-Seok KIM, Won-Seok DONG, Kyung-Soo MOON, Hyo-Ju SEO, Yo-Choul PARK, Yong-Tak YANG, Jung-Ah CHOI
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Publication number: 20130122103Abstract: The purpose of the present invention is to provide an electrostatically bonded vesicle which bears disulfide bonds or thiol groups. The present invention relates to a vesicle having a membrane which is formed from both a first polymer of (a) or (b) and a second polymer of (c) or (d) (with the proviso that a combination of (b) and (d) is excepted) and in which the cationic segment and anionic segment of the polymers are partially crosslinked. First polymer: (a) a block copolymer (I) having both an electrically non-charged hydrophilic segment and a cationic segment, (b) an amino acid polymer (I) having a cationic segment. Second polymer: (c) a block copolymer (II) having both an electrically non-charged hydrophilic segment and an anionic segment, (d) an amino acid polymer (II) having an anionic segment.Type: ApplicationFiled: July 27, 2011Publication date: May 16, 2013Applicants: TEIJIN LIMITED, THE UNIVERSITY OF TOKYOInventors: Akihiro Kishimura, Kazunori Kataoka, Stephanie Lee, Yasutaka Anraku, Aya Koide, Mitsuru Sakai, QiuMing Yu
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Publication number: 20130109743Abstract: An excellent nucleic acid delivery composition is provided which has reduced cytotoxicity and improved nucleic acid introduction efficiency and gene expression efficiency. The composition comprises: a block copolymer having an uncharged hydrophilic polymer segment and a cationic polymer segment; a cationic polymer; and a nucleic acid, wherein the mol percentage (B/H ratio) of the cationic groups of the block copolymer to the total cationic groups of the block copolymer and the cationic polymer is between 25% and 90%.Type: ApplicationFiled: July 11, 2011Publication date: May 2, 2013Applicant: The University of TokyoInventors: Kazunori Kataoka, Takehiko Ishii, Kensuke Osada, Qixian Chen, Keiji Itaka, Satoshi Uchida
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Patent number: 8410216Abstract: The invention relates to a composition based on an impact-resistant thermoplastic polyamide resin, comprising, as a blend—from 60 to 98 wt % of polyamide resin (A) and—from 2 to 40 wt % of a blend of at least one graft copolymer with polyamide blocks (B) composed of a polyolefin backbone and at least one polyamide graft in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a functional group capable of reacting with an amine-terminated polyamide, the residues of the unsaturated monomer (X) being attached to the backbone by grafting or copolymerization via its double bond, and of a non-reactive ethylenic polymer (C) that is miscible with (B) and has a density of below 0.960 g/cm3.Type: GrantFiled: October 11, 2007Date of Patent: April 2, 2013Assignee: Arkema FranceInventors: Marius Hert, Alain Bouilloux, Thibaut Montanari, Thomas Fine
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Publication number: 20130078402Abstract: [Problems] Provided is a polyamide resin material having high elastic modulus, good gas barrier properties, low water absorption and excellent flexibility. [Means for solving the problems] This is a polyamide resin composition comprising a polyamide resin (A) composed of a diamine structural unit and a dicarboxylic acid structural unit wherein 70 mol % or more of the diamine structural unit is derived from xylylenediamine and 50 mol % or more of the dicarboxylic acid structural unit is derived from sebacic acid, and 1 to 40 parts by mass of at least one copolyamide (B) selected from the following group consisting of (B-1)-(B-3) per 100 parts by mass of the polyamide resin (A); (B-1): a copolyamide 6/66/12; (B-2): a copolyamide 6/66/11; (B-3): a polyether-polyamide copolymer composed of a polyamide 12 unit or a polyamide 11 unit and a polyether unit.Type: ApplicationFiled: July 4, 2011Publication date: March 28, 2013Applicant: Mitsubishi Gas Chemical Company, Inc.Inventors: Jun Mitadera, Masashi Kurokawa, Takahiro Takano
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Patent number: 8404777Abstract: Composite materials that contain thermoplastic-toughened cyanate ester resins as the resin matrix. The composite materials exhibit low levels of heat release when burned. The matrix resins are composed of from 50 to 80 weight percent of a cyanate ester resin component. The matrix resin composition also includes from 10 to 40 weight percent of a thermoplastic blend that is composed of polyetherimide and polyamideimide. The epoxy resin composition further includes from 1 to 10 weight percent of a curative agent. The composite materials may be used for primary structures in aircraft and other load-bearing structures.Type: GrantFiled: September 12, 2012Date of Patent: March 26, 2013Assignee: Hexcel CorporationInventors: Yen-Seine Wang, Yi-Jui Wu
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Patent number: 8399557Abstract: Transparent blend or alloy comprising, by weight, the total being 100%: (A) 1 to 99% of at least one copolymer constituent: which is amorphous or has a crystallinity ranging up to semicrystallinity; and which comprises: (A1) amide units, among which is at least one cycloaliphatic unit; (A2) flexible ether units; (B) 99 to 1% of at least one polymer constituent selected from: (Ba) semicrystalline copolyamides comprising amide units (Ba1) and comprising ether units (Ba2), (Bb) semicrystalline polyamides or copolyamides without ether units, (Bc) transparent polyamides or copolyamides without ether units, which are amorphous or weakly crystalline, and alloys based on such polyamides or copolyamides; and (C) 0 to 50% by weight of at least one polyamide, copolyamide, copolyamide comprising ether units or alloy based on such polyamides or copolyamides other than those used in (A) and (B) above.Type: GrantFiled: June 11, 2007Date of Patent: March 19, 2013Assignee: Arkema FranceInventors: Thibaut Montanari, Philippe Blondel
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Patent number: 8399573Abstract: Thermoplastic compositions having miscible and compatible immiscible polymer blends are disclosed. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.Type: GrantFiled: November 22, 2006Date of Patent: March 19, 2013Assignee: SABIC Innovative Plastics IP B.V.Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
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Patent number: 8389646Abstract: The present invention refers to medical devices comprising a modified Co-Polymer or to the modified Co-Polymer itself having high flexibility and high stress resistance, especially tensile strength or tear resistance, in addition to the good physical characteristics of a Block-Co-Polymers of a polyamide and a polycarbonate, either polycarbonate diol or polycarbonate diamine.Type: GrantFiled: May 9, 2008Date of Patent: March 5, 2013Assignee: Abbott Laboratories Vascular Enterprises LimitedInventor: Günter Lorenz
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Publication number: 20130052375Abstract: An intermediate transfer member that includes a mixture of a thermoplastic polyimide, a polybenzimidazole, and an optional conductive filler.Type: ApplicationFiled: August 22, 2011Publication date: February 28, 2013Applicant: XEROX CORPORATIONInventor: Jin WU
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Patent number: 8383244Abstract: Disclosed is a polyamide molding compound having heat aging resistance for use as automobile or electrical components and composed of: (A) 27-84.99 wt % of a polyamide mixture consisting of (A1) at least one semiaromatic, semicrystalline polyamide having a melting point of 255° C. to 330° C., (A2) at least one caprolactam-containing polyamide that is different from (A1) and that has a caprolactam content of at least 50 wt %, where the total caprolactam content is 22-30 wt %, with respect to the polyamide mixture, (B) 15-65 wt % of at least one filler and reinforcing agent, (C) 0.01-3.0 wt % of at least one thermal stabilizer, and (D) 0-5.0 wt % of at least one additive, where the components (A)-(D) add up to 100 wt %.Type: GrantFiled: May 25, 2012Date of Patent: February 26, 2013Assignee: EMS-Patent AGInventors: Andreas Bayer, Nikolai Lamberts, Botho Hoffmann, Manfred Hewel
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Patent number: 8357455Abstract: The invention relates to the use of a molding composition which comprises at least 50% by weight of a copolyamide, which is composed of the following monomer combination: a) from 65 to 99 mol % of a substantially equimolar mixture composed of an unbranched aliphatic diamine having from 6 to 18 carbon atoms and of an unbranched aliphatic dicarboxylic acid having from 6 to 18 carbon atoms, ?where the mixture composed of diamine and dicarboxylic acid comprises an average of from 8 to 12 carbon atoms, b) from 1 to 35 mol % of a substantially equimolar mixture composed of a cycloaliphatic diamine having from 8 to 20 carbon atoms and of a dicarboxylic acid having from 6 to 18 carbon atoms, for production of a printable or printed item, such as a ski topcoat.Type: GrantFiled: November 9, 2005Date of Patent: January 22, 2013Assignee: Evonik Degussa GmbHInventors: Franz-Erich Baumann, Roland Wursche, Harald Häger, Sonja Bollmann, Kirsten Alting
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Patent number: 8349971Abstract: The present invention provides a process for preparing a solvent-soluble polyimide copolymer synthesized from a 6,6-imide segment having an imide oligomer with PMDA at both ends produced by adding 4 molar equivalents of pyromellitic dianhydride (PMDA) and 2 molar equivalents of diaminotoluene (DAT) to an imide oligomer produced by heating 1 molar equivalent of biphenyltetracarboxylic dianhydride (BPDA) and 2 molar equivalents of diaminodiphenyl ether (DADE) at 160-200° C. in the presence of a catalyst in an organic polar solvent.Type: GrantFiled: June 18, 2007Date of Patent: January 8, 2013Assignees: Solpit Industries, Ltd., Sojitz CorporationInventor: Hiroshi Itatani
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Publication number: 20120315483Abstract: The invention relates to a polymer powder for use in a layer-by-layer method in which areas of each powder layer are selectively fused by introducing electromagnetic energy. Said polymer powder contains: at least one AB-type polyamide produced by polymerizing lactams comprising 10 to 12 carbon atoms in the monomer unit or polycondensing the corresponding ?-amino carboxylic acids comprising 10 to 12 carbon atoms in the monomer unit and at least one AABB-type polyamide produced by polycondensing diamines and dicarboxylic acids, each of which comprises 10 to 14 carbon atoms in the monomer units, the AB-type polyamide containing up to 20 mole % of the AABB comonomer units and the AABB-type polyamide containing up to 20 mole % of the AB monomer units.Type: ApplicationFiled: April 6, 2011Publication date: December 13, 2012Applicant: Evonik Degussa GmbHInventors: Franz-Erich Baumann, Wolfgang Diekmann, Beatrice Kueting, Heike Stemmer, Maik Grebe, Kristiane Warnke, Sylvia Monsheimer, Harald Haeger
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Patent number: 8323791Abstract: A polyamide filament is disclosed. The filament includes a polyamide resin. The resin is obtained from mixing crystalline polyamide (A) with another polyamide (B). Crystalline polyamide (A) is obtained by a polycondensation reaction of metaxylenediamine and adipic acid. Crystalline polyamide (A) comprises from 5 to 50 wt. % of the resin. Polyamide (B) comprises from 50 to 95 wt. % of the resin. The filament is heated to 160 to 200° C. under a constant length condition at an initial load of 20 mg/d. After heating, a thermal contraction stress of the filament is not reduced in a cool-down region not greater than 80° C.Type: GrantFiled: November 10, 2005Date of Patent: December 4, 2012Assignee: Nippon Filcon Co., Ltd.Inventor: Shinya Murakami
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Publication number: 20120296037Abstract: A polyamide block copolymer that includes a first segment including a repeating unit represented by Chemical Formula 1, a repeating unit represented by Chemical Formula 2, or a combination thereof; and a second segment including a repeating unit represented by Chemical Formula 3. The variables R1 to R15, and n1 to n8 are defined herein.Type: ApplicationFiled: February 1, 2012Publication date: November 22, 2012Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventors: Chung Kun CHO, Kalinina FEDOSYA, Kovalev MIKHAIL, Sang Mock LEE
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Publication number: 20120289652Abstract: Supramolecular polymers having repeat units connected by hydrogen bonds, where the repeat units are monomers, macromers, oligomers or polymers where at least one on the monomers contains at least one 2,5-diketopiperazine group are described. Composition prepared from these supramolecular polymers and articles produced from these compositions are also described.Type: ApplicationFiled: July 30, 2010Publication date: November 15, 2012Applicant: RHODIA OPERATIONSInventors: Thierry Badel, Stéphane Jeol, Franck Touraud
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Patent number: 8304499Abstract: Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.Type: GrantFiled: April 29, 2011Date of Patent: November 6, 2012Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
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Patent number: 8293160Abstract: At an optional stage in the production step of a biaxially stretched film using a polyamide resin including, as a first component, nylon 6, and as a second component, a polyamide including xylylenediamine and an aliphatic dicarboxylic acid having 4 to 12 carbon atoms, the film is brought into contact with water set at 40° C. or higher and lower than 70° C. for 1 to 10 minutes and further with water set at 70° C. or higher for 1 to 10 minutes. In the film thus obtained, the content of low molecular weight compounds is 0% by mass to 0.2% by mass.Type: GrantFiled: April 15, 2009Date of Patent: October 23, 2012Assignee: Unitika Ltd.Inventors: Kiwamu Yuki, Makoto Nakai, Atsuko Noda
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Patent number: 8293364Abstract: A highly shrinkable fiber composed of nylon-MXD6 polymer and nylon-6 polymer, characterized in that a weight ratio therebetween is in the range of 35:65 to 70:30, and that each thereof exhibits a breaking strength of 4.00 cN/dtex or greater. Preferably, the weight ratio between nylon-MXD6 polymer and nylon-6 polymer of the highly shrinkable fiber is in the range of 45.55 to 55:45. The highly shrinkable fiber exhibits a high shrinkage ratio in boiling water, so that when the highly shrinkable fiber is used in a woven fabric, there can be realized a high density.Type: GrantFiled: April 18, 2007Date of Patent: October 23, 2012Assignee: KB Seiren, Ltd.Inventors: Hayato Iwamoto, Yoshitomo Hara, Hideo Ueda, Masaharu Saito
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Patent number: 8283408Abstract: Composite materials that contain thermoplastic-toughened cyanate ester resins as the resin matrix. The composite materials exhibit low levels of heat release when burned. The matrix resins are composed of from 50 to 80 weight percent of a cyanate ester resin component. The matrix resin composition also includes from 10 to 40 weight percent of a thermoplastic blend that is composed of polyetherimide and polyamideimide. The epoxy resin composition further includes from 1 to 10 weight percent of a curative agent. The composite materials may be used for primary structures in aircraft and other load-bearing structures.Type: GrantFiled: February 26, 2010Date of Patent: October 9, 2012Assignee: Hexcel CorporationInventors: Yen-Seine Wang, Yi-Jui Wu
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Patent number: 8268934Abstract: Methods of making miscible and compatible immiscible polymer blends are disclosed. The polymer blends have a polyimide as a component. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.Type: GrantFiled: November 22, 2006Date of Patent: September 18, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
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Patent number: 8268937Abstract: The invention pertains to an aramid copolymer composition comprising an aramid copolymer having at least one arylene carboxylic acid moiety and at least one hydroxyarylene moiety, or comprising an aramid copolymer having at least one arylene carboxylic acid moiety or having at least one hydroxyarylene moiety, and a crosslinker agent. The invention further relates to crosslinked copolymers derived thereof and shaped articles comprising said crosslinked copolymers.Type: GrantFiled: September 1, 2007Date of Patent: September 18, 2012Assignee: Teijin Aramid B.V.Inventors: Johannes Bos, Sandra Corien Noordewier
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Patent number: 8263732Abstract: [Object] To obtain an alignment film having excellent alignment stability of a liquid crystal and a high voltage holding ratio by application of linearly polarized light to a polyamic acid having a specific structure and then imidization under heat. [Solving Means] A photo-alignment film is obtained by: applying a polyamic acid solution on a substrate, where the polyamic acid contains, in its main chain, at least a group having unsaturated groups having 1 to 3 carbon-carbon double bonds or 1 to 4 triple bonds; vaporizing a solvent from a film formed; applying linearly polarized light to the film after the vaporization of the solvent; and then heating the film to imidize the polyamic acid.Type: GrantFiled: March 12, 2007Date of Patent: September 11, 2012Assignees: JNC Corporation, Chisso Petrochemical CorporationInventor: Norio Tamura
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Patent number: 8252868Abstract: A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.Type: GrantFiled: November 4, 2011Date of Patent: August 28, 2012Assignee: Techno Polymer Co., Ltd.Inventors: Masaaki Mawatari, Tatsuya Toneri
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Patent number: 8252872Abstract: The invention concerns a polymer material consisting of macromolecular chains bound by hydrogen bonds, wherein: the macromolecular chains consist of a polymer skeleton whereon is fixed by at least one covalent bond a modifying agent, the modifying agent comprising, assembled in a common molecule, one or more associative groups capable of being bound by hydrogen bonds and one or more reactive groups capable of forming covalent bonds with the polymer skeleton, at least one of the associative groups of the modifying agent is an imidazolidone heterocycle, the macromolecular chains bear on average, 1 to 10 imidazolidone groups per chain. The average number of imidazolidone groups to be introduced into the macromolecular chains depends both on the average mass of said chains and the final properties desired for the material.Type: GrantFiled: September 9, 2010Date of Patent: August 28, 2012Assignees: Arkema France, Centre National de la Recherche ScientifiqueInventors: Francois-Genes Tournilhac, Ludwik Leibler, Philippe Cordier, Corinne Soulie-Ziakovic, Annett Linemann, Manuel Hidalgo
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Publication number: 20120202953Abstract: A gas separation membrane is provided which has both excellent gas permeability and gas separation characteristics, particularly permeability of carbon dioxide (CO2) and separation characteristics of carbon dioxide and methane (CH4), at such a high level that has not hitherto been achieved. The gas separation membrane was obtained by heat treating a membrane composed of a hyperbranched polyimide-based material in a non-oxidizing atmosphere.Type: ApplicationFiled: February 17, 2012Publication date: August 9, 2012Applicants: NATIONAL UNIVERSITY CORP KYOTO INSTITUTE OF TECH, IBIDEN CO., LTD.Inventors: Tomoyuki Suzuki, Yasuharu Yamada
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Publication number: 20120183711Abstract: The invention relates to a composition comprising at least one first polyamide, conforming to the formula MXD.10 or MXD.10/Z and having a melting temperature Tf1, and at least one second polyamide. Said at least second polyamide has a melting temperature Tf2 such that Tf1?40° C.?Tf2<Tf1+20° C. The invention likewise relates to an article obtained from such a composition, to a method of shaping such an article, and to the use of such a composition and of such an article.Type: ApplicationFiled: July 1, 2010Publication date: July 19, 2012Applicant: ARKEMA FRANCEInventors: Benoit Brule, Barbara Ramfel
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Publication number: 20120172541Abstract: A liquid crystal alignment agent includes a first polymer including polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof. A liquid crystal alignment film manufactured using the liquid crystal alignment agent, and a liquid crystal display including the liquid crystal alignment film are also provided.Type: ApplicationFiled: July 26, 2011Publication date: July 5, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Won-Seok DONG, Bum-Jin LEE, Tae-Hyoung KWAK, Yo-Choul PARK, Hyo-Ju SEO, Hwan-Sung CHEON, Won-Ho CHOI
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Patent number: 8211344Abstract: The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection molding and sheet extrusion/calendering. Advantageously, the microcrystalline polyamide is such that its degree of crystallinity is greater than 10% and less than 30% (1st DSC heating according to ISO 11357 at 40° C.Type: GrantFiled: October 20, 2010Date of Patent: July 3, 2012Assignee: Arkema FranceInventors: Thibaut Montanari, Christelle Recoquille
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Publication number: 20120136103Abstract: The invention relates to a thermoplastic polymer composition that contains polyamide and comprises an excellent compromise of properties, in particular mechanical properties, and a high fluidity at the molten state. The invention particularly relates to a composition containing at least a high-fluidity linear polyamide and optionally fillers such as glass fibres, and to a method for making such a composition.Type: ApplicationFiled: November 24, 2009Publication date: May 31, 2012Applicant: RHODIA OPERATIONSInventors: Marco Amici, Cesare Guaita
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Publication number: 20120123063Abstract: An object of the present invention is to provide a polyamide imide resin composition having excellent in heat resistance, mechanical strength, and tracking resistance. The polyamide imide resin composition includes a polymer blend of a polyamide imide resin including an alicyclic structure and an aromatic polyamide imide resin.Type: ApplicationFiled: November 8, 2011Publication date: May 17, 2012Applicant: NITTO DENKO CORPORATIONInventors: Shunsuke MASAKI, Kiichiro MATSUSHITA
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Publication number: 20120108127Abstract: Disclosed herein are composite structures, overmolded composites structures and processes for their preparation. The disclosed composite structures have a surface having at least a portion made of a surface resin composition, and comprise a fibrous material being impregnated with a matrix resin composition, wherein the matrix polyamide resin composition and the surface resin composition are selected from polyamide compositions comprising a blend of semi-aromatic polyamides.Type: ApplicationFiled: October 27, 2011Publication date: May 3, 2012Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: Shengmei Yuan, Andri E. Elia, Olaf Nobert Kirchner, Martyn Douglas Wakeman, Bryan Benedict Sauer, Phong Du
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Publication number: 20120101236Abstract: To provide a polyamic acid ester-containing polyimide precursor composition having a good storage stability, from which a polyimide film having a high imidization degree and excellent adhesion to an inorganic substrate can be obtained. A polyimide precursor composition comprising a polyamic acid ester, a thermal imidization accelerator and a solvent, wherein the thermal imidization accelerator is a compound which has a carboxy group and an amino group or an imino group which is deprotected by heat to show basicity, and which will not accelerate the imidization of the polyamic acid ester before the protecting group leaves, and a polyimide precursor composition containing a silane coupling agent.Type: ApplicationFiled: April 1, 2010Publication date: April 26, 2012Applicant: Nissan Chemical Industries, Ltd.Inventors: Naoki Sakumoto, Masato Nagao, Yuho Noguchi
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Publication number: 20120094059Abstract: The present invention relates to a nylon yarn of a finely dispersed melt blended polymer alloy having i) a polyamide component selected from polyhexamethyleneadipamide, polycaprolactam and mixtures thereof, and ii) a nylon 11 component; wherein the polyamide component is the major component by weight of the total melt blended polymer and wherein the polyamide component has a viscosity of about 2.6 IV or more as measured in 96% sulfuric acid. The resulting nylon yarn shows improved bleach resistance. The present invention also relates to processes of producing the yarn and nylon carpets comprising the yarn described above.Type: ApplicationFiled: May 11, 2010Publication date: April 19, 2012Applicant: INVISTA NORTH AMERICA S.a r.l.Inventors: Kevin Leonard Urman, Sundar Mohan Rao, Isaac Keene Ivedrson
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Patent number: 8158268Abstract: A metal-coated polyimide film is excellent in long-term adhesion reliability, exhibits various dimensional stabilities, and is particularly suitable for FPC, COF and TAB applications. The metal-coated polyimide film comprises a non-thermoplastic polyimide film; and a metal layer being directly formed on one surface or both surfaces of the non-thermoplastic polyimide film without using an adhesive, wherein the non-thermoplastic polyimide film contains a non-thermoplastic polyimide resin having a thermoplastic polyimide block component.Type: GrantFiled: February 1, 2008Date of Patent: April 17, 2012Assignee: Kaneka CorporationInventors: Hisayasu Kaneshiro, Takashi Kikuchi, Shogo Fujimoto
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Publication number: 20120088848Abstract: Methods and compositions for the generation of polypeptides having varied material properties are disclosed herein. Methods include means for initiating the polymerization of aminoacid-N-carboxyanhydride (NCA) monomer by combining the monomer with an amido-containing metallacycle, for making self assembling amphiphilic block copolypeptides and related protocols for adding oligo(ethyleneglycol) functionalized aminoacid-N-carboxyanhydrides (NCAs) to polyaminoacid chains. Additional methods include means of adding an end group to the carboxy terminus of a polyaminoacid chain by reacting an alloc-protected amino acid amide with a transition metal-donor ligand complex to forming an amido-amidate metallacycle for use in further polymerization reactions. Novel compositions for use in peptide synthesis and design including five and six membered amido-containing metallacycles and block copolypeptides are also disclosed.Type: ApplicationFiled: March 31, 2011Publication date: April 12, 2012Inventors: Timothy J. Deming, Miaoer Yu, Scott A. Curtin, Jungyeon Hwang, Michael D. Wyrsta, Andrew Nowak, Scott W. Seidel
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Publication number: 20120088040Abstract: Disclosed is a liquid crystal display device including: a first substrate and a second substrate, one of which is transparent; a liquid crystal layer disposed between the first substrate and the second substrate; a group of electrodes for applying an electric field to the liquid crystal layer, which is formed on one of the first substrate and the second substrate; a plurality of active elements connected to the group of electrodes; and an alignment film disposed on one of the first substrate and the second substrate, wherein the alignment film contains a polyimide and a precursor of the polyimide, each of which is formed from a diamine and an acid anhydride, and the diamine contains a first diamine having an acidic group and a second diamine having a nitrogen atom-containing functional group other than two amino groups.Type: ApplicationFiled: October 6, 2011Publication date: April 12, 2012Inventors: Masaki Matsumori, Yasuo Imanishi, Yasushi Tomioka, Noboru Kunimatsu
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Patent number: 8153729Abstract: Dendritic macroinitiator compositions are provided comprising a compound of the general formula, Fx-[G-n]-I, where F is the chain end functional group of the dendrimer, x is the number of chain end functional groups, G is the dendrimer, n is the generation number of the dendrimer, and I is the initiating group. Hybrid dendritic-linear copolymers made from these macroinitators can act as highly efficient dispersing agents for a range of nanoparticles in matrix materials.Type: GrantFiled: May 29, 2008Date of Patent: April 10, 2012Assignees: The Regents of the University of California, Mitsubishi Chemical CorporationInventors: Craig J. Hawker, Robert Vestberg, Nobuhiko Ueno
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Patent number: 8138259Abstract: The invention relates to a housing from a polyamide molding compound containing 70 to 99.5% by weight of at least one thermoplastic polyamide and 0.5 to 30% by weight of at least one polyamide oligomer with linear or branched chain structure with a number average molar mass of 800 to 5000 g/mol with basic end groups which are at least partially NH2 end groups, and carboxyl end groups, one of these end groups being present in excess and the concentration of the end group present in excess being at most 300 mmol/kg.Type: GrantFiled: August 28, 2009Date of Patent: March 20, 2012Assignee: Ems-Chemie AGInventors: Paul Schwitter, Georg Stoeppelmann, Alex Stolarz, Helmut Thullen
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Publication number: 20120062228Abstract: This invention relates to the preparation of polyamide block copolymers by sequential monomer addition. More particularly, it relates to catalysts capable of copolymerizing not only cyclic amides, but other monomers such as cyclic esters and epoxides as well, using sequential addition so as to produce useful and novel block copolymers.Type: ApplicationFiled: November 21, 2011Publication date: March 15, 2012Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventors: David T. Williamson, Elizabeth Forrester McCord, Wilson Tam
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Patent number: 8133417Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enables the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.Type: GrantFiled: April 29, 2011Date of Patent: March 13, 2012Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
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Publication number: 20120047634Abstract: Embodiments of the present disclosure include helmet liners, helmets, helmets with deflective structures, helmets with thermochromic features, and methods of making helmet liners, helmets, helmets with deflective structures, and helmets with thermochromic features.Type: ApplicationFiled: May 14, 2010Publication date: March 1, 2012Inventor: Uday Vaidya
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Publication number: 20120052015Abstract: Polymers that can include an end-cap selected from Formula (I) and/or Formula (II) and a recurring unit of the Formulae (III), and/or (IV). The polymers can include various substituents such as drug, targeting agents, stabilizing agents, imaging agent and polydentate ligands. Such polymer can be useful for variety of drug, targeting, stabilizing and/or imaging agent delivery applications.Type: ApplicationFiled: August 18, 2011Publication date: March 1, 2012Applicant: Nitto Denko CorporationInventors: Lei Yu, Hai Wang, Kwok Yin Tsang, Yi Jin, Sang Van
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Patent number: 8124686Abstract: The present invention relates to a process for the preparation of polyamide-12 powder by anionic polymerization of lauryllactam in solution in a solvent of the lactam, the polyamide-12 powder being insoluble in this solvent, the polymerization being carried out: in the presence of a catalyst and of an activator; in the presence of a finely divided organic or inorganic filler, the proportion of this filler being less than or equal to 1.5 g per 1000 g of lauryllactam; and in the presence of an amide of formula R1—NH—CO—R2 in which R1 can be replaced by an R3—CO—NH— or R3—O— radical and in which R1, R2 and R3 denote an aryl, alkyl or cycloalkyl radical, the proportion of this compound being between 0.001 mol and 0.030 mol per 1000 g of lauryllactam.Type: GrantFiled: March 2, 2005Date of Patent: February 28, 2012Assignee: Arkema FranceInventors: Karine Loyen, Holger Senff, Francois-Xavier Pauly
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Patent number: 8114387Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.Type: GrantFiled: May 24, 2007Date of Patent: February 14, 2012Assignee: Arizona Chemical Company, LLCInventor: Mark S. Pavlin
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Publication number: 20120027859Abstract: The invention provides sequential poly(ester amide)s derived from Proline and that are synthesized by a two-step method, involving a final thermal polyesterification reaction. Molecular weights of polymers prepared by this method are from 14,000 Da to about 77,000 Da.1 When invention proline-based PEAs were thermally characterized, their glass transition temperatures were lower than other alpha-amino acid based poly(ester amides) due to lack of internal hydrogen bonding. These Proline-based PEAs assemble as nano-particles in aqueous solutions and form complexes with various cations and biologies, including hydrophobic small molecule drugs and biologies. Therefore the invention Proline-based PEAs are useful for drug delivery applications requiring a polymer with a molecular weight in the range from 14,000 Da to about 77,000 Da and for fabrication of nanoparticles for delivery of hydrophobic drugs.Type: ApplicationFiled: October 13, 2009Publication date: February 2, 2012Inventors: William G. Turnell, Zaza D. Gomurashvili, Jeffrey Neil Anderl
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Publication number: 20120016077Abstract: A polyamide resin obtained by heating and condensation-polymerizing ingredients mainly comprising pentamethylenediamine having a total content of 2,3,4,5-tetrahydropyridine and piperidine of 0.10 wt. % or lower and an aliphatic dicarboxylic acid having 7 or more carbon atoms, a 0.01 g/mL solution of the polyamide resin in 98% sulfuric acid having a relative viscosity at 25° C. of 1.8-4.5. The polyamide resin has excellent heat resistance, extremely low water absorption, and excellent melt residence stability and is hence suitable for use as long molded articles represented by automotive radiator tanks, etc.Type: ApplicationFiled: March 25, 2010Publication date: January 19, 2012Applicant: TORAY INDUSTRIES INC.Inventors: Koya Kato, Atsushi Masunaga, Hideo Matsuoka
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Patent number: 8097684Abstract: Thermoplastic compositions containing a polyamide and/or polyester matrix and a variety of additives have high fluidity and can be shaped into plastic articles with good mechanical properties and an improved surface appearance.Type: GrantFiled: June 22, 2004Date of Patent: January 17, 2012Assignee: Rhodia Engineering Plastics S.R.L.Inventors: Florence Clement, Franck Touraud, Nicolangelo Peduto, Christophe Lapierre, Frédéric Tronc