Mixture Contains Solid Polymer Derived From Reactant Containing A Fused- Or Bridged-ring System Or From Cycloaliphatic Reactant Patents (Class 525/75)
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Publication number: 20150147550Abstract: Disclosed herein is a non-birefringent resin material that is very small in both orientation birefringence and photoelastic birefringence, has high transparency, and is capable of providing a molded article having few foreign matter defects and a film made of such a material. The non-birefringent resin material contains a resin (A) and a polymer (B) and has an orientation birefringence of ?1.7×10?4 to 1.7×10?4 and a photoelastic constant of ?4×10?12 to 4×10?12 Pa?1.Type: ApplicationFiled: June 26, 2013Publication date: May 28, 2015Inventors: Fuminobu Kitayama, Nobuyoshi Maizuru, Keisuke Hatano
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Patent number: 8684866Abstract: Golf balls golf balls containing a core having at least two layers made from a polyalkenamer rubber composition are provided. At least one layer is made from a relatively low modulus polyalkenamer rubber composition and at least one layer is made from a relatively high modulus polyalkenamer rubber composition. The rubber composition may further include other rubbers such as, for example, polybutadiene, polyisoprene, ethylene propylene rubber, ethylene propylene diene rubber, and styrene-butadiene rubber. The rubber composition helps improve resiliency of the core. In one version, a dual-core having an inner core and surrounding outer core layer is provided. In another version, the golf ball contains a three-piece core having an intermediate core layer made of polybutadiene rubber.Type: GrantFiled: August 30, 2010Date of Patent: April 1, 2014Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Brian Comeau, Mark L. Binette, David A. Bulpett, Douglas S. Goguen, Robert Blink
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Patent number: 8680203Abstract: The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process. The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g.Type: GrantFiled: May 7, 2010Date of Patent: March 25, 2014Assignee: BASF SEInventors: Samira Nozari, Rainer Dyllick-Brenzinger, Arno Lange, Stefan Spange
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Patent number: 8344043Abstract: The present invention provides a thermoplastic resin composition that can have improved scratch resistance comprising: (A) about 10 to about 20% by weight of a rubber modified aromatic vinyl graft copolymer resin; (B) about 30 to about 50% by weight of polymethylmethacrylate (PMMA) resin; and (C) about 40 to about 60% by weight of an aromatic vinyl copolymer resin including about 5 to about 50% by weight of a (meth)acrylate alkyl ester. The thermoplastic resin composition of the present invention can have a good balance of various properties such as scratch resistance, impact strength, colorability, gloss, and injection molding properties.Type: GrantFiled: December 17, 2010Date of Patent: January 1, 2013Assignee: Cheil Industries Inc.Inventors: Sung Hun Jin, Chang Min Hong, Dong Hui Chu, Tae Woog Jang, In Chol Kim, Yu Ho Kim, Don Keun Lee
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Patent number: 8236878Abstract: A process for preparing a functionalized polymer composition and a functionalized polymer composition. The process comprises the steps of providing a hydrocarbon resin, a polyolefin and a graft monomer, and dispersing the hydrocarbon resin in the polyolefin, followed by adding the graft monomer under shear to prepare the functionalized polymer composition. The polyolefin can comprise a polyethylene polymer or a C3 to C40 polymer having a molecular weight (Mw) of at least 20000.Type: GrantFiled: September 4, 2008Date of Patent: August 7, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kenneth Lewtas, Jean-Roch Schauder, Stijn Van Lierde, Jurgen Schroeyers
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Publication number: 20120071605Abstract: This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C.Type: ApplicationFiled: February 1, 2008Publication date: March 22, 2012Inventors: Lisa Saunders Baugh, Bryan R. Chapman, Enock Berluche
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Patent number: 8076393Abstract: An ink composition includes (A) at least one polymerizable compound selected from the group consisting of a monofunctional radically polymerizable monomer having an aliphatic cyclic structure, an N-vinyllactam, and an aromatic monofunctional radically polymerizable monomer, (B) a radical polymerization initiator, (C) a pigment, and (D) a graft copolymer having a repeating unit represented by the formula below in a graft chain: wherein R denotes a hydrogen atom or a methyl group, X denotes a single bond, —O—, —CO—, —COO—, —CONR1—, —OCO—, or a phenylene group, R1 denotes a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, L denotes a single bond or a divalent linking group, Z denotes —NR2R3, R2 and R3 independently denote a hydrogen atom, an alkyl group, an aryl group, or an aralkyl group, and R2 and R3 may be bonded to each other to form a ring.Type: GrantFiled: August 26, 2008Date of Patent: December 13, 2011Assignee: FUJIFILM CorporationInventors: Kaoru Tojo, Norihide Shimohara
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Publication number: 20110152402Abstract: The present invention provides a thermoplastic resin composition that can have improved scratch resistance comprising: (A) about 10 to about 20% by weight of a rubber modified aromatic vinyl graft copolymer resin; (B) about 30 to about 50% by weight of polymethylmethacrylate (PMMA) resin; and (C) about 40 to about 60% by weight of an aromatic vinyl copolymer resin including about 5 to about 50% by weight of a (meth)acrylate alkyl ester. The thermoplastic resin composition of the present invention can have a good balance of various properties such as scratch resistance, impact strength, colorability, gloss, and injection molding properties.Type: ApplicationFiled: December 17, 2010Publication date: June 23, 2011Applicant: CHEIL INDUSTRIES INC.Inventors: Sung Hun Jin, Chang Min Hong, Dong Hui Chu, Tae Woog Jang, In Chol Kim, Yu Ho Kim, Don Keun Lee
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Patent number: 7834081Abstract: The present invention relates to the use of poly acrylic and/or methacrylic macroinitiators in the free radical addition reaction of vinyl aromatic monomers to improve the properties of the resulting copolymer and/or composite. More particularly, the present invention relates to the production of poly acrylic and/or poly methacrylic macroinitiators having nitroxyl end groups. Using such macroinitiators in the free radical addition reaction of vinyl aromatics such as polystyrene compatibilizes the acrylic monomer in the vinyl aromatic matrix thereby improving the properties of the resulting polymer.Type: GrantFiled: August 1, 2006Date of Patent: November 16, 2010Assignee: Arkema Inc.Inventors: Peter A. Callais, Scott C. Schmidt, Barbara L. Stainbrook, Nicolas Passade-Boupat, Pierre Gerard, Stephanie Magnet
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Patent number: 7700689Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.Type: GrantFiled: May 31, 2006Date of Patent: April 20, 2010Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Publication number: 20090221750Abstract: A thermoplastic resin comprising a block copolymer or a graft copolymer possessing (A) a crystalline hydrogenated norbornene ring-opening polymer unit and (B) a non-crystalline polymer unit having a glass transition temperature of 40 to 300° C.; A method for producing thermoplastic resin comprising hydrogenating a block copolymer or a graft copolymer possessing a norbornene ring-opening polymer unit (C) and a polymer unit (D) which is converted into the above-mentioned non-crystalline polymer unit (B) after hydrogenation, in the presence of a hydrogenation catalyst; and a molding material comprising the thermoplastic resin are provided. The thermoplastic resin of the present invention excels in transparency, heat resistance, and mechanical strength.Type: ApplicationFiled: March 20, 2006Publication date: September 3, 2009Applicant: ZEON CORPORATIONInventors: Yasuo Tsunogae, Shigetaka Hayano, Atsushi Ishiguro
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Patent number: 7396882Abstract: Styrene-free unsaturated polyester resin compositions are provided which have low volatile organic compounds and hazardous air pollutants emissions when these resin compositions are used in open molding applications. A process for the manufacture of these resin compositions is provided.Type: GrantFiled: May 19, 2003Date of Patent: July 8, 2008Assignee: AOC, LLCInventors: John C. Hewitt, John E. McAlvin, Paul Taylor Hutson, Amber E. Craig, Marjorie Krantz, Derek K. Rivers
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Patent number: 7193013Abstract: The present invention provides a polyolefin-based resin composition, comprising (A) a polyolefin I produced from at least one monomer selected from the group consisting of ?-olefins, cyclic olefins and styrenes; (B) a polyolefin II produced from said at least one monomer, which differs in composition or properties from said polyolefin I; and (C) a graft copolymer produced by bonding said polyolefins I and II to each other through a polyene, wherein (a) a ratio [(1/R1)/(1/R1)0] of a relaxation velocity (1/R1) of a long-term relaxation component measured by a solid 1H-NMR method about the composition to a relaxation velocity (1/R1)0 of a long-term relaxation component measured by a solid 1H-NMR method about a resin mixture of only the components (A) and (B) is 1.01 or higher; and (b) an intrinsic viscosity [?] of the composition is in the range of 0.1 to 10 deciliter/g as measured in decalin at 135° C.Type: GrantFiled: February 6, 2002Date of Patent: March 20, 2007Assignee: Idemitsu Kosan Co. Ltd.Inventors: Shuji Machida, Kazuo Sato
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Patent number: 6900273Abstract: Low-hygroscopicity low-birefringence resin compositions. One of the compositions is a resin composition (a) comprising the following polymers (A), and (B) and/or (C). Another is a resin composition (b) comprising the following polymers (A), (B) and (H). Still another is a polymer comprising the following polymers (I) and (J), diphenylsilicone (D), and a phenolic antioxidant (E). (A) A polymer comprising one or more kinds of indene and indene derivatives represented by the following general formula (I). (B) A polymer comprising polystyrene or a polystyrene derivative. (C) A polymer comprising a monomer copolymerizable with styrene or a styrene derivative. (H) A graft polymer having a structure wherein a polymer comprising at least one kind of indene and an indene derivative represented by the general formula (I) bonds to a side chain of a polymer comprising a monomer copolymerizable with styrene or a styrene derivative.Type: GrantFiled: June 27, 2000Date of Patent: May 31, 2005Assignee: Hitachi Chemical Co., Ltd.Inventors: Yukihiko Yamashita, Shuichi Iwata, Tetsuo Yamanaka, Akihiro Yoshida, Keiko Ushikubo
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Patent number: 6806320Abstract: Described are melt-processable block copolymers and compositions, embodiments of which may be useful in applications such as pressure sensitive adhesive (PSA) or heat-activatable adhesive, comprising polymeric end block and polymeric B block, wherein end block comprises copolymer and the B block comprises homopolymer or copolymer.Type: GrantFiled: November 15, 2002Date of Patent: October 19, 2004Assignee: 3M Innovative Properties CompanyInventors: Albert I. Everaerts, JingJing Ma, Ashish K. Khandpur, Francois C. D'Haese, Jianhui Xia, Lang N. Nguyen
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Patent number: 6753378Abstract: The present invention is intended to provide a branched polyolefin having various excellent properties, a process for preparing the branched polyolefin and a thermoplastic resin composition containing the branched polyolefin. This branched polyolefin comprises an olefin chain (A) and olefin chain(s) (B) which have recurring units obtained from at least one olefin as main constituent units. In the branched polyolefin, the olefin chain (B) is linked to a position other than both ends of the olefin chain (A), and at least one olefin chain (B) per one olefin chain (A) is present. The process for preparing a branched polyolefin comprises allowing a functional group-containing polyolefin (C) having one or more carboxyl groups and/or acid anhydride groups at positions other than both ends to react with a terminal modified polyolefin (D) having a group capable of reacting with a carboxyl group or an acid anhydride group at only the position of chain end.Type: GrantFiled: May 10, 2002Date of Patent: June 22, 2004Assignee: Mitsui Chemicals, Inc.Inventors: Shinichi Kojoh, Tomoaki Matsugi, Norio Kashiwa
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Patent number: 6730736Abstract: An alicyclic structure-containing resin composition comprising an alicyclic structure-containing resin (A) having a polar group in a proportion of 3 to 50 mol % based on the whole repeating unit in the resin, and a soft polymer (B), a varnish containing the resin composition, a sheet formed of the resin composition, and an insulating film formed of the resin composition.Type: GrantFiled: October 2, 2000Date of Patent: May 4, 2004Assignee: Nippon Zeon Co., Ltd.Inventors: Shojiro Kaita, Takashi Iga, Yasuhiro Wakizaka, Yasuo Tsunogae
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Patent number: 6653401Abstract: Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.Type: GrantFiled: March 2, 2001Date of Patent: November 25, 2003Assignee: Asahi Kasei Kabushiki KaishaInventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
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Patent number: 6596810Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core/shell particles.Type: GrantFiled: November 10, 1997Date of Patent: July 22, 2003Assignees: Mitsu Petrochemical Ind., Ltd., Ticona GmbHInventors: Wilfried Hatke, Frank Osan, Otto Herrmann-Schönherr, Vincent Joseph Sullivan, Thomas Weller
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Patent number: 6455634Abstract: The present invention relates to a blend of at least one (meth)acrylate polymer and at least one amorphous propylene-derived polymer, and an optional tackifier that provide pressure sensitive adhesive compositions in which improved peel adhesion to at least one of low and relatively high surface energy substrates can be achieved.Type: GrantFiled: December 29, 2000Date of Patent: September 24, 2002Assignee: 3M Innovative Properties CompanyInventors: Ashish K. Khandpur, Eugene G. Joseph, Greggory S. Bennett
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Patent number: 6380308Abstract: The invention relates to a binder composition containing A) 50-90 parts by wt. of OH-functional graft copolymer resins prepared from a) 0.1 to 10 parts by wt. of polybutadiene, b) 5 to 60 parts by wt. of an unsaturated aromatic monomer, c) 10 to 50 parts by wt. of a hydroxyalkyl ester of (meth)acrylic acid, d) 5 to 70 parts by wt. of a cycloaliphatic ester of (meth)acrylic acid, e) 5 to 50 parts by wt. of an aliphatic ester of (meth)acrylic acid, f) 0.1 to 5 parts by wt. of a mono-olifinically unsaturated mono- or dicarboxylic acid and/or maleic or fumaric acid half esters, B) 0.1 to 5 parts by wt. of a polyfunctional crosslinking agent.Type: GrantFiled: November 13, 2000Date of Patent: April 30, 2002Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Michael Sonntag, Holger Mundstock
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Patent number: 6355727Abstract: A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes including maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product.Type: GrantFiled: July 2, 1999Date of Patent: March 12, 2002Assignee: S. C. Johnson Commercial Markets, Inc.Inventors: Kevin M. Andrist, John E. Blasko, Glenn C. Calhoun, Frederick C. Hansen, Dean R. Hellwig, Kurt A. Hessenius, Steven M. Hurley, D. Sunil Jayasuriya, Matthew G. Lee, Stephen J. Maccani, H. Thomas Mills, Jr., Gregory R. Peterson, Paul E. Sandvick, Dennis M. Wilson, John P. Wiruth
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Publication number: 20020022684Abstract: A process for preparing microgel(s) that uses a wide range of activatable prepolymers; in the process, a polymer composition of crosslinked component A and soluble components B and C is formed from mono-olefinic and multi-olefinic monomers in the presence of catalyst and initiator; the process comprises:Type: ApplicationFiled: October 3, 2001Publication date: February 21, 2002Inventors: Charles T. Berge, Michael Fryd, Jeffery W. Johnson, Graeme Moad, Ezio Rizzardo, Christopher Scopazzi, San H. Thang
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Publication number: 20020019475Abstract: A process for preparing microgel(s) that uses a wide range of activatable prepolymers; in the process, a polymer composition of crosslinked component A and soluble components B and C is formed from mono-olefinic and multi-olefinic monomers in the presence of catalyst and initiator; the process comprises:Type: ApplicationFiled: October 3, 2001Publication date: February 14, 2002Inventors: Charles T. Berge, Michael Fryd, Jeffery W. Johnson, Graeme Moad, Ezio Rizzardo, Christopher Scopazzi, San Hoa Thang
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Publication number: 20010053816Abstract: Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.Type: ApplicationFiled: June 7, 2001Publication date: December 20, 2001Inventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
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Patent number: 6255387Abstract: A derivatized blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and then reacted with an organic compound to derivatize the blend. The sheared derivatized blend of polymers can function as a shear stable multifunctional viscosity index improver with improved low temperature properties and, in some cases, dispersancy antioxidant and anti-wear properties.Type: GrantFiled: January 8, 1998Date of Patent: July 3, 2001Assignee: Ethyl Additives CorporationInventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 6177517Abstract: Thermoplastic molding masses made of thermoplastic polymers obtained by mixed graft polymerization and having a glass transition temperature above 20 C., and of special rubber-elastic block copolymers, are characterized by a balanced spectrum of properties.Type: GrantFiled: June 18, 1997Date of Patent: January 23, 2001Assignee: BASF AktiengesellschaftInventors: Norbert G{umlaut over (u)}ntherberg, Martin Weber, Konrad Knoll
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Patent number: 6127482Abstract: A composition comprising:(a) polyethylene;(b) a cure booster selected from the group consisting of 3,9-divinyl-2,4,8,10-tetra-oxaspiro[5.5]undecane (DVS); a copolymer of ethylene and DVS; and an ethylene homopolymer or copolymer having DVS grafted thereto; and(c) an organic peroxide.Type: GrantFiled: March 31, 1999Date of Patent: October 3, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Michael John Keogh
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Patent number: 6114460Abstract: A method for producing a graft copolymer rubber which comprises graft polymerizing an alkenyl aromatic compound to an ethylene-.alpha.-olefin-dicyclopentadiene terpolymer rubber having a Q value of more than 5.0 and Mooney viscosity at 100.degree. C. of 70 or less, in an aqueous suspension in the presence of a free radical initiator and a dispersant, and a polypropylene-based resin composition comprising 5 to 40% by weight of said graft copolymer rubber and 60 to 95% by weight of a polypropylene-based resin(B) selected from the group consisting of a crystalline propylene homopolymer (i) having a Q value of 3.0 to 5.0, isotactic pentad fraction of 0.97 or more and intrinsic viscosity measured in tetralin solution at 135.degree. C. of 0.85 to 1.60 dl/g, a crystalline propylene-ethylene block copolymer (ii) composed of 60 to 95% by weight of apropylene homopolymer portion having a Q value of 3.0 to 5.0, isotactic pentad fraction of 0.97 or more and intrinsic viscosity measured in tetralin solution at 135.degree.Type: GrantFiled: May 15, 1998Date of Patent: September 5, 2000Assignee: Sumitomo Chemical Company, LimitedInventors: Manabu Hirakawa, Shin-ichi Kondo
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Patent number: 6100331Abstract: Disclosed is a graft copolymer (A+B) of a styrene-based monomer (A) and a terminal styrene derivative-modified olefin-based macromer (B) of formula (1), having a high degree of syndiotacticity for the stereospecificity of the chains derived from the styrene-based monomer: ##STR1## R is H or alkyl; X is H, halogen, or a substituent having one or more of C, Sn and Si; n is 1 to 4; m is 0 or a natural number; Z is a chain moiety derived from an olefin-based monomer. The copolymer is prepared by copolymerizing (A) and (B) in the presence of a catalyst comprising (a) a transition metal compound, (b) (i) a specific oxygen-containing compound and/or (ii) a compound capable of reacting with the compound (a) to form an ionic complex, and optionally (c) an alkylating agent.Type: GrantFiled: February 19, 1998Date of Patent: August 8, 2000Assignee: Idemitsu Petrochemical Co., Ltd.Inventor: Hideo Teshima
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Patent number: 6072002Abstract: A thermoplastic molding composition which features improved impact and flow properties as well as reduced opacity is disclosed. The composition contains(A) 15 to 50 percent of a grafted rubber which contains (a) a crosslinked rubber substrate which contains, as a core, about 1 to 25% relative to its weight of at least one vinylaromatic polymer, and (b) a grafted phase, and(B) 85 to 50 percent of a copolymeric matrix.The composition, which contains no additional grafted rubber components, is also characterized in that (i) the substrate amounts to 60 to 90 percent, and grafted phase amounts to 40 to 10 percent, relative to the weight of the grafted rubber and that (ii) the grafted rubber has a monomodal size distribution and that (iii) the grafted rubber has a weight average particle size of about 0.2 to 1.0 microns.Type: GrantFiled: October 21, 1997Date of Patent: June 6, 2000Assignee: Bayer CorporationInventors: Moh Ching Oliver Chang, Richard M. Auclair
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Patent number: 6051650Abstract: A rubber-reinforced thermoplastic resin composition is disclosed. The rubber-reinforced thermoplastic resin composition comprises a thermoplastic resin matrix having dispersed therein particles of a graft polymer, the particles of a graft polymer comprising particles of a rubber polymer having emulsion-graft-polymerized to the surface thereof two or more kinds of vinyl compounds copolymirizable with the rubber polymer, wherein the surface graft coverage of the vinyl compounds graft-polymerized to the surface of the particles of a rubber polymer as determined by equation (m1) is 80% or more and the average thickness of the vinyl compounds graft-polymerized to the surface of the particles of a rubber polymer is from 5 to 25 nm:Surface graft coverage (%)=(s2/s1).times.Type: GrantFiled: March 17, 1998Date of Patent: April 18, 2000Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Shigeru Endo, Makiko Nagao, Toshinori Yamanaka
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Patent number: 6008298Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core/shell particles having a diameter of 0.01 to 0.7 micrometer.Type: GrantFiled: January 22, 1998Date of Patent: December 28, 1999Assignees: Hoechst Aktiengesellschaft, Mitsui Petrochemical Ind., Ltd.Inventors: Wilfried Hatke, Frank Osan, Otto Herrmann-Schonherr
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Patent number: 5863986Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core-shell particles and c) one or more block copolymers.Type: GrantFiled: January 23, 1997Date of Patent: January 26, 1999Assignees: Ticona GmbH, Mitsui Petrochemical Industries, LtdInventors: Otto Herrmann-Schonherr, Frank Osan
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Patent number: 5837773Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution. The sheared blend of polymers can function as a shear stable dispersant viscosity index improver with improved lower temperature properties or the hydrocarbon base for multifunctional for viscosity index improvers, motor fuel additives or polymeric dispersants.Type: GrantFiled: March 12, 1997Date of Patent: November 17, 1998Assignee: DSM Copolymer, Inc.Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 5834557Abstract: An ethylene/.alpha.-olefin copolymer composition including (I) a graft-modified ethylene/.alpha.-olefin copolymer composition and (II) a polyolefin. The graft-modified composition is prepared by graft copolymerizing an ethylene/.alpha.-olefin copolymer with a polar monomer. The ethylene/.alpha.-olefin copolymer composition includes first and second ethylene/.alpha.-olefin copolymers. The copolymers are each prepared in the presence of a polymerization catalyst containing (a) an organoaluminum oxy compound and (b) for the first ethylene/.alpha.-olefin copolymer at least two kinds, and for the second ethylene/.alpha.-olefin copolymer one kind, of compounds of Group IV transition metals of the periodic table containing a ligand having a cyclopentadienyl skeleton. The graft-modified ethylene/.alpha.-olefin copolymer composition is blended with a polyolefin, such as by mechanical or solution blending, at a weight ratio (I) to (II) of 1:99 to 99:1.Type: GrantFiled: June 11, 1997Date of Patent: November 10, 1998Assignee: Mitsui Chemicals, Inc.Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo, Seiji Ohta, Hajime Inagaki
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Patent number: 5777036Abstract: Particulate graft copolymers A) are composed ofa.sub.1) from 5 to 70% by weight, based on A), of a grafting base having a glass transition temperature of less than 10.degree. C. and based ona.sub.11) from 50 to 99.94% by weight, based on a.sub.1), of at least one alkyl acrylate where the alkyl radical is of 1 to 30 carbon atoms,a.sub.12) from 0 to 49.9% by weight, based on a.sub.1), of a further monounsaturated monomer copolymerizable with b.sub.11) anda.sub.13) from 0.01 to 5% by weight, based on a.sub.1), of polyfunctional crosslinking monomers,a.sub.2) from 20 to 85% by weight, based on A), of a stage polymerized in the presence of component a.sub.1) and comprisinga.sub.21) from 95 to 100% by weight, based on a.sub.2), of at least one monomer having a refractive index n.sub.D.sup.20 of more than 1.51 anda.sub.22) from 0 to 5% by weight, based on a.sub.2), of a polyfunctional, crosslinking monomer anda.sub.Type: GrantFiled: April 15, 1997Date of Patent: July 7, 1998Assignee: BASF AktiengesellschaftInventors: Wolfgang Fischer, Jurgen Koch, Graham Edmund McKee
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Patent number: 5708080Abstract: A graft-modified ethylene/.alpha.-olefin copolymer composition is prepared by graft copolymerizing an ethylene/.alpha.-olefin copolymer. The ethylene/.alpha.-olefin copolymer composition includes first and second ethylene/.alpha.-olefin copolymers. The copolymers are each prepared in the presence of a polymerization catalyst containing (a) an organoaluminum oxy compound and (b) for the first ethylene/.alpha.-olefin copolymer at least two kinds, and for the second ethylene/.alpha.-olefin copolymer one kind, of compounds of Group IV transition metals of the periodic table containing a ligand having a cyclopentadienyl skeleton. The ethylene/.alpha.-olefin copolymer composition may be blended with a polyolefin by mechanical or solution blending. The copolymer compositions have excellent moldability and heat stability properties and forms films having high transparency and mechanical strength.Type: GrantFiled: May 25, 1995Date of Patent: January 13, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo, Seiji Ohta, Hajime Inagaki
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Patent number: 5602203Abstract: An olefinic resin composition which comprises 100 parts by weight of a thermoplastic olefin elastomer consisting of a polyolefin resin and an olefinic copolymer rubber and 0.5 to 30 parts by weight of a modified polyolefin obtained by reacting an unsaturated carboxylic acid (anhydride)-modified polyolefin with an aminoalcohol represented by the formula H.sub.2 N--R--OH in which R is an alkylene, arylene or aralkylene group having 18 or less carbon atoms. The olefinic resin composition can give a molded article which can be satisfactorily coated with a coating material without a primer and has excellent heat fusibility to various resin and metals.Type: GrantFiled: March 1, 1995Date of Patent: February 11, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Tatsuo Hamanaka, Tadashi Hikasa, Yoshitsugu Takai, Tetsuya Yamada
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Patent number: 5574100Abstract: A polymer composition comprising [A] a polymer selected from a copolymer of .alpha.-olefin having at least 2 carbon atoms and a specific cyclic olefin, a ring-opening polymer of said specific cyclic olefin and a hydroganted, ring-opening polymer thereof and [B] a core-shell elastomer containing 40 to 85 parts of weight of a core component which comprises a styrene-butadiene copolymer and 15 to 60 parts by weight of a shell component which comprises a copolymer of an acrylate or methacrylate having a specific cyclic structure, a monovinyl aromatic monomer, other monovinyl monomer and a plyfunctional monomer. This polymer composition is excellent in transparency and impact resistance.Type: GrantFiled: March 9, 1995Date of Patent: November 12, 1996Assignees: Mitsui Petrochemical Industries, Ltd., Hoechst AktiengesellschaftInventors: Toshihiro Sagane, Masayuki Okabe, Masahiro Kishine
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Patent number: 5548023Abstract: A method of compatibilizing a blend of at least a hydrocarbon polymer with at least one other polymer which is incompatible with the hydrocarbon polymer, said method comprising adding to the polymer blend a compatibilizer which is an isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.Type: GrantFiled: March 13, 1995Date of Patent: August 20, 1996Assignee: Exxon Chemical Patents, Inc.Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C. Chung, Anthony J. Dias, Joseph A. Olkusz
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Patent number: 5521248Abstract: A flowable uncured adhesive elastomeric composition suitable for delivery to assembly sites by pumping through supply lines is provided, which has a tensile strength suitable for formation of a strong bond, comprising: (a) an elastomer having a viscosity higher than flowable; (b) a synthetic resin curable by the same cure system as said non-flowable elastomer in an amount sufficient to lower the viscosity of the mixture to a pumpable level; (c) an unsaturated polymeric adduct of a dicarboxylic acid or dicarboxylic acid derivative in an amount sufficient to provide adhesive properties to the mixture; and (d) a curing agent. Preferably the composition also comprises a crosslink-enhancing coagent in an amount sufficient to lower percent elongation and increase adhesive bond strength of the cured elastomer. The compositions are useful for bonding substrates such as other elastomers, metals, plastics, glass, fibers, paper and fabrics.Type: GrantFiled: March 23, 1995Date of Patent: May 28, 1996Assignee: Ricon Resins, Inc.Inventors: Ronald E. Drake, John M. Labriola
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Patent number: 5480940Abstract: Process for making a polymer and the resultant polymer wherein polymer particles, preferably those having a core and a shell structure, most preferably wherein the core comprises polybutadiene and the shell comprises polymethylmethacrylate, are included in metathesis polymerizable mixtures to provide the resultant polymer with improved resistance to oxidation and greater retention of mechanical properties upon thermal aging, and to toughen the resultant polymer.Type: GrantFiled: March 7, 1995Date of Patent: January 2, 1996Assignee: Metton America, Inc.Inventors: Nitya P. Khasat, Douglas Leach
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Patent number: 5451636Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and to yield a product that can be recovered as a solid using conventional plastic processing equipment. The sheared blend of polymers can function as a shear stable viscosity index improver with improved lower temperature properties.Type: GrantFiled: November 9, 1994Date of Patent: September 19, 1995Assignee: DSM Copolymer, Inc.Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 5439974Abstract: Adhesive blends especially suitable for adhesion to one or more polypropylene substrates consisting essentially of a mixture of a modified impact copolymer and a graft reaction product of a propylene polymer and a carboxylic acid or derivative thereof are disclosed. Composite structures incorporating such blends are also disclosed.Type: GrantFiled: October 14, 1992Date of Patent: August 8, 1995Assignee: Quantum Chemical CorporationInventor: Diana C. Mattson
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Patent number: 5418276Abstract: There are disclosed a graft copolymer formed by grafting a styrenic monomer onto a high polymer having double bonds in the side chain to constitute highly syndiotactic polystyrenic chain as the graft component, the graft copolymer having a content of graft component of 0.005 to 99% by weight and a reduced viscosity of 0.01 to 30 dl/g as measured at a concentration of 0.05 g/dl in 1,2,4-trichlorobenzene at 135.degree. C. or a melt index of 0.001 to 500 g/10 minutes as measured at 300.degree. C. under a load of 2.16 kg; a process for efficiently producing the above graft copolymer using a catalyst comprising specific components; and a resin composition comprising the above graft copolymer, a highly syndiotactic styrenic polymer or other thermoplastic resin and, when necessary, an inorganic or organic filler. The above graft copolymer and resin composition are excellent in resistance to heat and chemicals, electrical properties, moldability, compatibility, impact resistance, etc.Type: GrantFiled: July 26, 1994Date of Patent: May 23, 1995Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shuji Machida, Noriyuki Tani
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Patent number: 5414044Abstract: A polyolefin resin composition comprising (A) a polyolefin resin, (B) a graft-modified .alpha.-olefin copolymer grafted with an unsaturated carboxylic acid and its derivative, and (C) an amino group-containing compound, (D) said polyolefin resin composition containing a crosslinked structure between the amino group-containing compound (C) and the graft-modified .alpha.-olefin copolymer (B), and containing, based on 100 parts by weight of the polyolefin resin (A) and the graft-modified .alpha.-olefin copolymer (B) in total, 1 to 99 parts by weight of each of the polyolefin resin (A) and the graft-modified .alpha.-olefin copolymer (B) and 0.01 to 10 parts by weight of the amino group-containing compound (C). The polyolefin resin composition gives a crosslinked molded article having impact resistance at ordinary temperature and a low temperature.Type: GrantFiled: October 29, 1993Date of Patent: May 9, 1995Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Satoru Moriya, Mamoru Takahashi, Akio Ishimoto, Toshiyuki Hirose
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Patent number: 5391617Abstract: A blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and to yield a product that can be recovered as a solid using conventional plastic processing equipment. The sheared blend of polymers can function as a shear stable viscosity index improver with improved lower temperature properties.Type: GrantFiled: August 2, 1993Date of Patent: February 21, 1995Assignee: DSM Copolymer, Inc.Inventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 5367022Abstract: Highly functional grafted polymeric products of a predominantly propylene polymeric composition containing a thermoplastic ethylene-propylene copolymer and a carboxylic acid or derivative grafting monomer and having a desirably low melt flow rate, adhesive blends containing such grafted polymeric products, and composite structures incorporating the adhesive blends are provided. The grafted polymeric product may be prepared by melt grafting in the presence of a free radical generating catalyst and the substantial absence of solvent under shear and at a temperature selected to minimize or avoid premature decomposition of the catalyst and vaporization losses of the catalyst and monomer.Type: GrantFiled: October 7, 1992Date of Patent: November 22, 1994Assignee: Quantum Chemical CorporationInventors: Webster W. Kiang, Edward M. Kajiwara, Diana C. Mattson
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Patent number: H1862Abstract: The present invention provides high service temperature sealant and adhesive compositions which contain a functionalized selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene to which has been grafted at least 4% by weight of an acid compound or its derivative wherein substantially all of the acid compound or its derivative is grafted to the block copolymer in the conjugated diene blocks. The present invention also contemplates a stable emulsion comprising the above polymer, water and less than 1 part per 100 of the emulsion of a surfactant.Type: GrantFiled: June 21, 1994Date of Patent: September 5, 2000Assignee: Shell Oil CompanyInventors: Glenn Roy Himes, Jeffrey George Southwick, David Michael Austgen, Jr.