Mixture Contains Solid Polymer Derived From Reactant Containing A Fused- Or Bridged-ring System Or From Cycloaliphatic Reactant Patents (Class 525/75)
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Patent number: 4849472Abstract: Thermoplastic, high-tenacity, high-flexibility polymeric blends suitable for obtaining molded and thermoformed shaped articles comprising a styrene polymer or copolymer reinforced with ethylene-propylene-diene (EPDM) rubber and an amount higher than 15% by weight of polyethylene.Type: GrantFiled: May 12, 1987Date of Patent: July 18, 1989Assignee: Montedipe S.p.A.Inventors: Gianfranco Biglione, Gian C. Fasulo
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Patent number: 4839422Abstract: An adhesive composition which contains a thermoplastic elastomer which includes ethylene propylene rubber, ethylene propylene diene monomer, polyisobutylene butyl rubber, ethylene vinyl acetate graft copolymers thereof with C.sub.3 to C.sub.10 unsaturated mono- and polycarboxylic acids, a tackifying resin and a di- or polyamine cross-linking agent having 2-10 carbon atoms, which is useful as a hot melt or pressure sensitive adhesive having enhanced higher temperature properties.Type: GrantFiled: December 23, 1987Date of Patent: June 13, 1989Assignee: Exxon Chemical Patents Inc.Inventors: Kenneth O. McElrath, Martha L. Robertson, Wai Y. Chow
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Patent number: 4833195Abstract: A thermoplastic pelletizable polymer composition comprising an oligomer or degraded polyolefin and an olefinic elastomer. Optionally, the composition can also include a polyolefin thermoplastic polymer. The composition, when converted to a film or fabric meets the criteria or drapability, low hardness on the Shore A scale, high melt flow and reprocessability.Type: GrantFiled: July 20, 1987Date of Patent: May 23, 1989Assignee: BP Performance Polymers, Inc.Inventors: Ashok M. Adur, Joseph M. Hogue, Jr.
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Patent number: 4822856Abstract: A process for preparing a polymeric blend stock comprising fluidizing a first particulated polymer, contacting the particulated polymer with droplets of a latex of a second polymer or polymer mixture, retaining the resulting product in a fluid state under conditions sufficient to dry the latex, and recovering the resulting dried polymeric blend stock.Type: GrantFiled: February 18, 1987Date of Patent: April 18, 1989Assignee: The Dow Chemical CompanyInventors: Eugene R. Moore, Wen H. Tong
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Patent number: 4801647Abstract: A thermoplastic elastomeric composition comprising a dynamically crosslinked grafted polyolefin copolymer elastomer and a thermoplastic crystalline polyolefin is disclosed. The crosslinked elastomer is dispersed in the thermoplastic crystalline polyolefin which is present as the continuous phase. The grafted elastomer is ethylene/propylene/diene terpolymer or ethylene/propylene copolymer grafted with fumaric acid, maleic acid, maleic anhydride or derivatives thereof capable of reacting with diamine crosslinking agents.Type: GrantFiled: March 10, 1988Date of Patent: January 31, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: James R. Wolfe, Jr.
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Patent number: 4801646Abstract: Low gloss impact and weather resistant thermoplastic resins comprising a hard matrix polymer and a grafted alkylacrylate rubber having a core of a substantially uncrosslinked alkylacrylate polymer and a graftable overpolymer layer of a high crosslink density alkylacrylate polymer.Type: GrantFiled: January 16, 1987Date of Patent: January 31, 1989Assignee: The Dow Chemical CompanyInventor: David E. Henton
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Patent number: 4792583Abstract: Blends are disclosed of monoolefin rubber with high-diene hydrocarbon rubber in which the monoolefin rubber is in the form of discrete vulcanized particles dispersed in a matrix of unvulcanized high-diene hydrocarbon rubber. The blends can be easily processed, and in a subsequent step, the high-diene hydrocarbon portion cured to give rubber articles having the ozone resistance of the monoolefin rubber and the good physical properties of the high-diene hydrocarbon rubber.Type: GrantFiled: June 29, 1987Date of Patent: December 20, 1988Assignee: Monsanto CompanyInventor: Aubert Y. Coran
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Patent number: 4785052Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.Type: GrantFiled: November 14, 1986Date of Patent: November 15, 1988Assignee: Arco Chemical CompanyInventor: Barry D. Dean
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Patent number: 4783505Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.Type: GrantFiled: November 14, 1986Date of Patent: November 8, 1988Assignee: ARCO Chemical CompanyInventor: Barry D. Dean
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Patent number: 4767817Abstract: Shaped articles which have excellent solvent resistance and resistance to fatty acids are formed from a thermoplastic polyblend of poly(vinyl chloride) (PVC), chlorinated polyethylene (CPE), polyolefin (PO), and a graft copolymer of a polyolefin (PO-G). The thermoplastic polyblend contains a PO and PO-G (PO/PO-G) as a first continuous single phase, PVC and CPE as the second and third dispersed phases, and the relative amounts of the components are chosen so that there is, at most, an equal amount by weight of PO and PO-G each of which may be present in an amount as high as 40 parts by weight when the PVC is present in an amount in the range from 40 to 70 parts, so as to provide a mechanically compatible polyblend without miscibility or chemical compatibility. Further, a glass fiber reinforced (GFR) polyblend of PVC/CPE/PO/PO-G having a HDT of at least 95.degree. C. and sufficient thermoformability to form the desired article has excellent notched impact strength.Type: GrantFiled: March 9, 1987Date of Patent: August 30, 1988Assignee: The B. F. Goodrich CompanyInventor: Biing-Lin Lee
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Patent number: 4764558Abstract: A thermodynamically miscible polymer composition containing a copolymer having recurring units of an alkyl vinyl ether and recurring units of an N-aryl substituted maleimide and an acrylonitrile copolymer is disclosed.Type: GrantFiled: March 20, 1987Date of Patent: August 16, 1988Assignee: Arco Chemical CompanyInventor: Bi Le-Khac
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Patent number: 4762886Abstract: A weather resistant thermoplastic resin composition which comprises (A) a graft polymer comprising (A-1) chosen from a copolymer of ethylene and propylene, a terpolymer of ethylene, propylene and a non-conjugated diene, a copolymer of ethylene and vinyl acetate, an alkyl acrylate or methacrylate polymer and a chlorinated polyethylene and (A-2) at least two kinds of monomers chosen from aromatic vinyl compounds, vinyl cyanide compounds and unsaturated carboxylic acid alkyl esters grafted thereon and (B) a terpolymer comprising styrene aromatic compounds, vinyl cyanide compounds and unsaturated carboxylic acid alkyl esters. The weight proportion of the graft polymer (A) and the terpolymer (B) is preferably from 10:90 to 90:10. In particular the amounts of styrene the vinyl cyanide compounds and the unsaturated carboxylic acid alkyl esters in the terpolymer (B) are 3 to 65% by weight, 2 to 35% by weight and 3 to 95% by weight, respectively.Type: GrantFiled: May 5, 1987Date of Patent: August 9, 1988Assignee: Sumitomo Naugatick Co., Ltd.Inventors: Mikio Hirai, Yoshiaki Nishikubo, Tomio Yoshida, Tsuneo Ochi
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Patent number: 4762882Abstract: A modified polyolefin resin and a composition containing therein such modified polyolefin, having excellent adhesive property and heat-sealing property at the time of high speed forming operations, the modified polyolefin resin consisting essentially of: a copolymer of ethylene and .alpha.-olefin having 4 or more carbon atoms, the copolymer having a density in a range of from 0.890 to 0.910 g/cm.sup.3, a ratio of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn) of Mw/Mn=2 to 15, and a product of a melt tension (g) and a melt-index (g/10 min.) of a molten resin measured at 160.degree. C. of 4 or below; and unsaturated carboxylic acid or derivatives thereof grafted on the ethylene type copolymer at a ratio of from 0.01 to 3% by weight.Type: GrantFiled: June 26, 1986Date of Patent: August 9, 1988Assignee: Mitsubishi Chemical Industries LimitedInventors: Shigeaki Okano, Katsuhiko Hayashi, Yoshiteru Sakurazawa, Yoshinori Suga
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Patent number: 4761455Abstract: Disclosed are normally solid polymers that are the result of addition copolymerization of the monomers acrylonitrile, methyl methacrylate, .alpha.-methylstyrene and/or styrene, and indene in the presence of a preferred unsaturated rubbery polymer, said polymers containing 10-200 parts by weight rubbery polymer, 10-40 parts by weight acrylonitrile, 5-50 parts by weight methyl methacrylate, 5-45 parts by weight of one or both of styrene and .alpha.-methylstyrene and 4-45 parts by weight indene in the polymer structure, per 100 parts by weight of the total parts of acrylonitrile, methyl methacrylate, styrene, .alpha.-methylstyrene and indene combined in said polymer structure. Also disclosed are vinyl chloride polymers compounded therewith to increase the heat distortion temperature as well as the impact resistance.Type: GrantFiled: June 12, 1987Date of Patent: August 2, 1988Assignee: The Standard Oil CompanyInventors: Muyen M. Wu, George S. Li
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Patent number: 4753988Abstract: Impact modified copolymers of vinyl aromatic, ethylenically unsaturated nitrile and, optionally, methyl methacrylate monomer, wherein the impact modifier comprises (a) large grafted rubber particles of a rubbery alkyl acrylate polymer having a particle size from about 0.5.mu. to 0.8.mu., 0.04 to 0.5 percent by weight of a polymerized crosslinking monomer and from 0.5 to 40 percent grafted rigid phase, and (b) small grafted rubber particles of a rubbery alkyl acrylate polymer having a particle size from about 0.05.mu. to about 0.20.mu., 0.25 to about 2.0 percent of a crosslinking monomer, provided that the weight percentage of crosslinking monomer is at least twice the weight percentage of the crosslinking monomer in the large particle, and from about 15 to about 60 percent by weight grafted rigid phase.Type: GrantFiled: February 18, 1987Date of Patent: June 28, 1988Assignee: The Dow Chemical CompanyInventors: David E. Henton, Edward B. Anthony
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Patent number: 4749746Abstract: A polymer composition which contains a polycarbonate resin, a styrenic/maleimide/cyclic anhydride terpolymer, and an ethylene/propylene/nonconjugated diene terpolymer chemically grafted with either styrene/acrylonitrile copolymer, methylmethacrylate/N-phenylmaleimide copolymer or polymethylmethacrylate is disclosed. The composition exhibits excellent impact strength properties upon molding.Type: GrantFiled: January 15, 1987Date of Patent: June 7, 1988Assignee: ARCO Chemical CompanyInventors: Barry D. Dean, Bi Le-Khac
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Patent number: 4748205Abstract: A thermoplastic resin composition of high heat resistance and high impact resistance is described, comprising: (A) 50 to 90% by weight of a copolymer prepared by copolymerization of 10 to 35% by weight of acrylonitrile, 60 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, and 0 to less than 10% by weight of a vinyl monomer copolymerizable with the foregoing monomers; and (B) 10 to 50% by weight of a graft copolymer prepared by polymerizing 15 to 50 parts by weight of at least one monomer selected from the group consisting of aromatic vinyl compounds, vinyl cyanides, methacrylic acid alkyl esters, and acrylic acid alkyl esters in the presence of 50 to 85 parts by weight of a butadiene- or alkyl acrylate-based rubber, the sum of the graft and rubber components being 100 parts by weight.Type: GrantFiled: June 16, 1987Date of Patent: May 31, 1988Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Takayuki Katto, Yasumasa Komatsu, Zenya Shiiki
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Patent number: 4745156Abstract: A polyvinyl chloride resin composition is disclosed, which contains an .alpha.-methylstyrene/acrylonitrile copolymer in a specified amount. Forming sheet materials made therefrom having high heat distortion resistance as well as a favorable balance of tensile strength and stretching characteristics at elevated temperatures and being suitable for vacuum and pressure forming are also disclosed.Type: GrantFiled: August 11, 1986Date of Patent: May 17, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Masayuki Yoshihara, Nobuo Naka, Masanori Kobayashi
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Patent number: 4742116Abstract: A thermoplastic moulding compound based on a rubber-modified copolymer consisting of styrene and/or .alpha.-methylstyrene and maleic anhydride, wherein the moulding compound is composed of a mixture of:A. 50-95% (wt) of a copolymer consisting of:(i) 50-95% (wt) styrene and/or .alpha.-methylstyrene,(ii) 50-5% (wt) maleic anhydride,(iii) 0-20% (wt) acrylate,(iv) 0-20% (wt) acrylonitrile;B. 5-50% (wt) of an ethylene-propylene modified rubber or ethylene-propylene-diene modified rubber, the rubber being modified by grafting thereto a compound containing hydroxyl, amide or amine groups; andC. 0-30% (wt) of an ethylene-propylene rubber or an ethylene-propylene-diene rubber.Type: GrantFiled: December 13, 1985Date of Patent: May 3, 1988Assignee: Stamicarbon B.V.Inventors: Herman A. J. Schepers, Wilhelmus A. M. Debets
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Patent number: 4740560Abstract: A polyblend of a high graft copolymer, a low graft copolymer and a matrix interpolymer is made by:(A) mixing a latex of the high graft copolymer and a latex of the low graft copolymer to provide a mixture thereof;(B) coagulating and at least partially dewatering the mixture of step (A);(C) melt blending the mixture of step (B) to provide a first polyblend; and(D) melt blending the first polyblend of step (C) with matrix interpolymer to provide a second polyblend.Type: GrantFiled: April 17, 1986Date of Patent: April 26, 1988Assignee: The Dow Chemical CompanyInventors: Eugene R. Moore, Gary D. Parsons, Paul C. Balliet
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Patent number: 4735988Abstract: A propylene polymer composition comprising (A) a modified propylene polymer obtained by treating: (1) 100 parts by weight of a propylene polymer or a mixture of a propylene homopolymer and a ethylene-propylene copolymer rubber, with (2) 0.1 to 50 parts by weight of an organic compound having at least one unsaturated bond in the molecule and a hydroxyl group and (3) 0.01 to 20 parts by weight of an organic peroxide; and (B) a propylene polymer, wherein content of the component (A) in the composition is 5 to 50% by weight. This composition may further contain one or more of (C) an amorphous ethylene-propylene copolymer having a propylene content of 20% to 50% by weight and a Mooney viscosity ML.sub.1+4 at 100.degree. C. of 20 to 100, (D) a high-density ethylene copolymer having a density of 0.935 g/cm.sup.3 or more, (E) a linear low-density ethylene copolymer having a density of not less than 0.900 g/cm.sup.3 but less than 0.935 g/cm.sup.2, a melting point of 106.degree. C. to 130 C., a melt flow rate of 0.Type: GrantFiled: May 28, 1986Date of Patent: April 5, 1988Assignee: Showa Denko Kabushiki KaishaInventors: Tomio Takada, Tsutomu Suda, Mitsunobu Machida, Yozo Nagai, Minoru Takaishi, Noboru Takagi
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Patent number: 4732935Abstract: A thermoplastic resin composition of high heat resistance and high impact resistance in described, comprising: (A) 5 to 85% by weight of a copolymer prepared from 40 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, 7.Type: GrantFiled: August 29, 1986Date of Patent: March 22, 1988Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Takayuki Katto, Yasumasa Komatsu, Zenya Shiiki
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Patent number: 4717741Abstract: A rubber-modified polymeric composition is disclosed. The rubber-modifying component comprises a grafted rubbery polymer, said grafted rubbery polymer being formed by a process, the steps of the process involving the formation of a hydroperoxidized rubbery polymer intermediate.Type: GrantFiled: May 16, 1985Date of Patent: January 5, 1988Assignee: The Dow Chemical CompanyInventors: Jerry L. Hahnfeld, Alan E. Platt, David A. Habermann
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Patent number: 4716197Abstract: The specification discloses a polymer blend comprising from about 20 to 90% of an olefin combination including a high density polyolefin and a linear low density polyolefin, from about 6 to about 60% of a vinyl aromatic polymer and from about 4 to about 20% of a compatibilizer therefore.Type: GrantFiled: April 21, 1986Date of Patent: December 29, 1987Assignee: The Dow Chemical CompanyInventors: Randolph H. Seiss, Edward H. Yonkers
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Patent number: 4713420Abstract: Rubber modified styrene-acrylonitrile polymers (ABS) having three different types of rubber particles. One type is small, usually emulsion-produced particle. The second is a large emulsion-produced particle. The third is a large, mass-produced particle. Such compositions exhibit good combinations of toughness and gloss.Type: GrantFiled: May 21, 1982Date of Patent: December 15, 1987Assignee: The Dow Chemical CompanyInventor: David E. Henton
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Patent number: 4704431Abstract: A polymer resin comprising a blend of polypropylene, a copolymer of a vinylaromatic monomer and .alpha.-methylstyrene prepared by anionic polymerization at a temperature above 61.degree. C. and a monovinylidene aromatic polymer grafted .alpha.-olefin copolymer compatibilizing agent.Type: GrantFiled: April 4, 1986Date of Patent: November 3, 1987Assignee: The Dow Chemical CompanyInventors: Van I. W. Stuart, Duane B. Priddy
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Patent number: 4701495Abstract: A thermoplastic resin composition of high heat resistance and high impact resistance is described, comprising: (A) 50 to 90% by weight of a copolymer prepared by copolymerization of 10 to 35% by weight of acrylonitrile, 60 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, and 0 to less than 10% by weight of a vinyl monomer copolymerizable with the foregoing monomers; and (B) 10 to 50% by weight of a graft copolymer prepared by polymerizing 15 to 50 parts by weight of at least one monomer selected from the group consisting of aromatic vinyl compounds, vinyl cyanides, methacrylic acid alkyl esters, and acrylic acid alkyl esters in the presence of 50 to 85 parts by weight of a butadiene- or alkyl acrylate-based rubber, the sum of the graft and rubber components being 100 parts by weight.Type: GrantFiled: February 26, 1986Date of Patent: October 20, 1987Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Takayuki Katto, Yasumasa Komatsu, Zenya Shiiki
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Patent number: 4690976Abstract: A polymer resin comprising a blend of an olefin polymer, such as polyethylene, a monovinylidene aromatic polymer, such as polystyrene, and a grafted, block copolymer compatibilizing agent. The compatibilizing agent comprises an .alpha.-olefin copolymer substrate grafted with amounts of monovinylidene aromatic polymer. Preferably, the .alpha.-olefin copolymer substrate is a terpolymer of ethylene, propylene and a non-conjugated diolefin. This thermoplastic material has very desirable property combinations, combining the desirable properties from the olefinic and monovinylidene aromatic polymers. The blend can be shaped into final products by thermoforming techniques yet possesses many desirable polyolefin properties such as environmental stress crack resistance.Type: GrantFiled: January 21, 1986Date of Patent: September 1, 1987Assignee: The Dow Chemical CompanyInventor: Jerry L. Hahnfeld
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Patent number: 4687810Abstract: A rubber blend is produced by masticating a mixture of monoolefin copolymer rubber and high-diene hydrocarbon rubber while dynamically vulcanizing the monoolefin copolymer rubber. The blend is then further treated to vulcanize the high-diene hydrocarbon rubber portion. The resulting vulcanized blend has improved properties.Type: GrantFiled: January 2, 1986Date of Patent: August 18, 1987Assignee: Monsanto CompanyInventor: Aubert Y. Coran
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Patent number: 4686263Abstract: The production of impact-resistant polystyrene with EPDM simplifies the process and produces improved products if a modified ethylene/propylene rubber consisting of styrene/butadiene- or diene polymers, ethylene, optionally propylene and an unconjugated diene are used as the elastifying component.The modified EPDM rubbers consisting of (a) from 20 to 90% by weight of ethylene units, (b) from 1 to 25% by weight of units of a butadiene/styrene copolymer containing a quantity of from 10 to 90% by weight of styrene, (c) from 0 to 10% by weight of units of an unconjugated diolefin and (d) C.sub.3 -C.sub.18 .alpha.-monolefin units to make up the difference to 100% by weight, are a further subject of this invention.Type: GrantFiled: July 22, 1985Date of Patent: August 11, 1987Assignee: Bayer AktiengesellschaftInventors: Manfred Beck, Wolfgang Nentwig
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Patent number: 4683266Abstract: A thickened composition which is cured by free-radical initiated polymerization is composed of a compound containing at least two ethylenically unsaturated double bonds per molecule; an active hydrogen-containing homopolymer or copolymer of a diene having a number average molecular weight of from 500 to 15,000; the active hydrogens being derived from hydroxyl, amino, or mercapto groups; and an organic polyisocyanate present in an amount sufficient to thicken said composition without gelation.Type: GrantFiled: November 7, 1985Date of Patent: July 28, 1987Assignee: Ashland Oil, Inc.Inventors: Anthony C. Palermo, Roger M. Christenson, Glenn L. Mazza
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Patent number: 4663390Abstract: Polymer alloys containing copolymers of methylmethacrylate/N-phenylmaleimide are disclosed. In one embodiment the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride. In another embodiment, the polymer alloy is an alloy of methylmethacrylate/N-phenylmaleimide and styrene/maleic anhydride/N-phenylmaleimide.Type: GrantFiled: April 1, 1985Date of Patent: May 5, 1987Assignee: Atlantic Richfield CompanyInventor: Barry D. Dean
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Patent number: 4661549Abstract: Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is continued until the proportion of polyolefin in the polymer product is about 2 to about 20 weight percent, the resulting product can be formed to a transparent or translucent article.Type: GrantFiled: October 12, 1983Date of Patent: April 28, 1987Assignee: Occidental Chemical CorporationInventor: Leigh E. Walker
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Patent number: 4659790Abstract: A heat-resistant copolymer obtained by copolymerizing (A) 72-82 parts by weight of .alpha.-methylstyrene and (B) 26-18 parts by weight of acrylonitrile, characterized in that the copolymer contains (a) 0-15% by weight of monomer chain --(A)--(A)--(A)--, (b) 50% by weight or more of monomer chain --(A)--(A)--(B)--, and (c) 50% by weight or less of monomer chain--(B)--(A)--(B)--, the total of (a), (b) and (c) being 100% by weight. This copolymer is excellent in heat stability and moldability when molded at high temperatures, and the blending of this copolymer with other thermoplastic resins gives thermoplastic resins with excellent heat resistance.Type: GrantFiled: April 18, 1985Date of Patent: April 21, 1987Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Yasuyuki Shimozato, Syuji Tsuchikawa, Shinichi Kimura, Masahiko Noro
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Patent number: 4659776Abstract: Several important features and characteristics, particularly and pronouncedly environmental stress crack resistance (i.e., "ESCR") as well as other desirable physical properties of blends or intimate admixtures, known as "polyblends" and usually made by melt-blending, of various styrene polymers (i.e., "SP's"), notably homopolystyrene (i.e., "PS"), and thermoplastic elastomers (i.e., "TE's") are significantly and in emphasized measure enhanced by thorough incorporation in (and simultaneous or subsequent heat action-initiating and cross-link-effecting of) the styrene polymer-thermoplastic elastomer polyblend in low level concentration(s) of a thermally-activatable, organic peroxide in combination with any one (or even a mixture) of an optimizing cross-linking supplement provided in effectively reactive amounts of, for illustration, either a styrene (or the like alkenyl aromatic) monomer or a reagent that is reactive towards alkenes (such as certain dithiols, amino-derivatives, etc.Type: GrantFiled: April 15, 1985Date of Patent: April 21, 1987Assignee: The Dow Chemical CompanyInventor: Robert J. Russell
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Patent number: 4647622Abstract: A thermoplastic resin composition well balanced among heat resistance, high-impact properties and moldability is provided, which composition comprises 50 to 90 parts by weight of a random copolymer (A) composed mainly of .alpha.-methylstyrene units and acrylonitrile units, 0.2 to 1.0 part by weight based on 100 parts by weight of the random copolymer (A), of an oligomer (B) composed mainly of .alpha.-methylstyrene units and acrylonitrile units and having a molecular weight of 200 to 500 and 10 to 50 parts by weight of a dienic rubber-aromatic vinyl monomer-vinyl cyanide graft copolymer (C).Type: GrantFiled: May 20, 1985Date of Patent: March 3, 1987Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tatsuhiro Aoyagi, Tetsuya Shinmura
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Patent number: 4645796Abstract: Novel and particularly utile for many specific and extraordinarily-demanding applications intimately-blended admixtures of diverse synthetic resinous copolymers and graft-structured and/or the like or equivalent elastomer-based polymerizates are comprised of thoroughly intermixed products of polymerization (i.e., "polyblends") of: (i) copolymer(s) of styrene/.alpha.-methylstyrene and equivalents thereof with (ii) grafted rubber concentrates of an elastomeric substrate or backbone having thereon and thereto graft-interpolymerized styrene components therein and/or like or equivalent grafted rubber concentrate component(s). The polyblends involved exhibit superior and much-improved properties and characteristics of thermal stability, environmental stress crack resistance, hardness and so forth.Type: GrantFiled: March 14, 1986Date of Patent: February 24, 1987Assignee: The Dow Chemical CompanyInventors: Douglas E. Beyer, Edward T. Carrington
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Patent number: 4640788Abstract: Lubricants of improved properties contain ethylene-propylene copolymers bearing graft units derived from, as a functional monomer, the reaction product of (i) an unsaturated aldehyde or ketone and (ii) a primary or secondary amine which contains at least one nitrogen atom in a heterocyclic ring.Type: GrantFiled: April 29, 1985Date of Patent: February 3, 1987Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Christopher S. Liu, William P. Hart, Larry D. Grina
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Patent number: 4639473Abstract: Thermoplastic, high-impact moulding compositions of (A) 5 to 80 parts by weight of a graft product of 70 to 30% by weight of a mixture of an aromatic vinyl compound and acrylonitrile and/or methacrylonitrile on 30 to 70% by weight of a rubber having a glass transition temperature of below -10.degree. as the graft base and (B) 20 to 95 parts by weight of a terpolymer of styrene and/or .alpha.-methylstyrene, p-methylstyrene and acrylonitrile and/or methacrylonitrile, the terpolymer having been produced by mass polymerization.Type: GrantFiled: November 22, 1985Date of Patent: January 27, 1987Assignee: Bayer AktiengesellschaftInventors: Frank Wingler, Otto Koch, Joachim Doering, Karl-Heinz Ott, Lothar Liebig
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Patent number: 4636553Abstract: A thermoplastic resin composition of high heat resistance and high impact resistance is described, comprising: (A) 5 to 85% by weight of a copolymer prepared from 40 to 85% by weight of a monomer mixture of 2-isopropenylnaphthalene (2-IPN) and .alpha.-methylstyrene (.alpha.-MeSt), the proportion of 2-IPN being 5 to 70% by weight based on the total weight of 2-IPN and .alpha.-MeSt, 7.Type: GrantFiled: June 8, 1984Date of Patent: January 13, 1987Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Takayuki Katto, Yasumasa Komatsu, Zenya Shiiki
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Patent number: 4612347Abstract: The invention relates to polymer mixtures with a mat surface, based on graft polymers with acid functions and thermoplastic resins with basic functions.Type: GrantFiled: February 6, 1985Date of Patent: September 16, 1986Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Joachim Doring, Karl-Heinz Ott, Ludwig Bottenbruch
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Patent number: 4610914Abstract: A highly desirable blend has ethylene vinyl alcohol copolymer blended with a thermoplastic polymer composition. Preferred blends are compatible when the blend is formed into a film and oriented. The invention contemplates the blend composition, the blend composition incorporated into a film, an oriented film, a multiple layer oriented film, a method of making the film, and the film formed into a shrink bag.Type: GrantFiled: July 19, 1984Date of Patent: September 9, 1986Assignee: American Can CompanyInventor: David L. Newsome
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Patent number: 4605704Abstract: Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is continued until the proportion of polyolefin in the polymer product is about 2 to abut 20 weight percent, the resulting product can be formed to a transparent or translucent article.Type: GrantFiled: October 12, 1983Date of Patent: August 12, 1986Assignee: Occidental Chemical CorporationInventors: David W. Eastman, Leigh E. Walker
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Patent number: 4602056Abstract: The invention relates to the use of grafted ethylene-vinylacetate copolymers (EVA-copolymers) for the production of hotmelt adhesives.Type: GrantFiled: May 10, 1985Date of Patent: July 22, 1986Assignee: Bayer AktiengesellschaftInventors: Helmut Waniczek, Gerhard Hohmann, Herbert Bartl, Ludwig Mott
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Patent number: 4600747Abstract: ABS-moulding compositions consisting of a thermoplastic copolymer and a graft polymer with rubber-like graft base exhibit an improved flame resistance if the total mixture contains a compound corresponding to the formulae ##STR1## polymerized into one or both components, wherein R.sub.1 represents C.sub.2 -C.sub.6 -alkylene,R.sub.2 represents hydrogen or methyl,R.sub.3 represents a direct bond or C.sub.1 -C.sub.4 -alkylene, andR.sub.4 represents hydrogen, methyl or CH.sub.2 --OOC--CH.sub.2 --CO--CH.sub.3.Type: GrantFiled: April 18, 1985Date of Patent: July 15, 1986Assignee: Bayer AktiengesellschaftInventors: Karl Zabrocki, Christian Lindner, Friedmann Muller, Joachim Doring
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Patent number: 4595727Abstract: Thermoplastic blends having high heat distortion temperature and impact strength comprise 10-90 weight percent of a polyglutarimide, and 90-10 weight percent of a rubber-modified vinyl chloride resin prepared by polymerization of vinyl chloride in the presence of 2 to 50 percent of a rubber to form a graft copolymer.Type: GrantFiled: May 2, 1985Date of Patent: June 17, 1986Inventor: Kenneth W. Doak
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Patent number: 4585832Abstract: A weather and impact resistant resin composition which comprises: a graft copolymer (A) composed of a continuous phase comprising from 10 to 90% by weight of residues of an aromatic vinyl monomer, from 10 to 40% by weight of residues of an .alpha.,.beta.-unsaturated nitrile monomer and from 0 to 80% by weight of residues of methyl methacrylate, and particles of an acrylate rubber having a weight average particle size of from 0.1 to 0.45 .mu.m dispersed in the continuous phase, said acrylate rubber comprising from 70 to 98% by weight of residues of an alkyl acrylate having from 2 to 12 carbon atoms, from 1.92 to 27% by weight of residues of a vinyl monomer copolymerizable with the alkyl acrylate and from 0.08 to 3% by weight of residues of a multifunctional vinyl monomer; a graft copolymer (B) composed of a continuous phase comprising from 10 to 90% by weight of residues of an aromatic vinyl monomer, from 10 to 40% by weight of residues of an .alpha.,.beta.Type: GrantFiled: June 14, 1984Date of Patent: April 29, 1986Assignee: Mitsubishi Monsanto Chemical CompanyInventor: Takashi Kokubo
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Patent number: 4567223Abstract: The hot-melt adhesives of the present invention comprise a blend of at least one propylene/C.sub.4 to C.sub.10 higher 1-olefin copolymer having an acid number of at least 5, a tackifying resin, and a high density, low viscosity polyethylene wax having a melt viscosity of about 5 to 50 cp. at 150.degree. C. This hot-melt adhesive has a novel combination of properties including low melt viscosity and fast setting which meet the requirements necessary for use in rapid bonding or closing in low and high temperature applications.Type: GrantFiled: August 31, 1984Date of Patent: January 28, 1986Assignee: Eastman Kodak CompanyInventor: William A. Ames
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Patent number: 4562230Abstract: A modified polyolefin composition useful for producing a shaped article having an excellent bonding property and an enhanced impact resistance comprises a modified olefin polymer material prepared by melting a mixture of an olefin polymer material comprising at least one crystalline ethylene-propylene random copolymer containing from 0.5 to 5% by weight of copolymerized ethylene and having a melt flow index of from 0.2 to 5 with a modifying agent consisting of at least one unsaturated dicarboxylic anhydride and a radical reaction initiator at a temperature of from 170.degree. C. to 270.degree. C. at which the mixture is melted; and a polyolefin rubber having a Mooney viscosity ML.sub.1+4 (100.degree. C.) of 10 to 100 and mixed in an amount of from 5% to 40% based on the sum of the weight of the modified olefin polymer material and the polyolefin rubber with the modified olefin polymer material at a temperature at which the mixture is melted.Type: GrantFiled: November 10, 1983Date of Patent: December 31, 1985Assignee: UBE Industries, Ltd.Inventors: Osamu Fukui, Yoshihiro Inuizawa, Saburo Hinenoya, Yasufumi Takasaki
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Patent number: RE32217Abstract: Mass graft copolymerization carried out in an extrusion passageway having a sealing zone to prevent back flow of grafting material introduced to the extrusion passageway downstream of the sealing zone.Type: GrantFiled: July 25, 1985Date of Patent: July 29, 1986Assignee: The Dow Chemical CompanyInventor: Paul G. Andersen