Mixture Contains Solid Polymer Derived From Reactant Containing Carboxylic Acid Ester Group Patents (Class 525/80)
  • Patent number: 7589150
    Abstract: Disclosed are polypropylene homopolymers, copolymers and mono and polyfunctional polypropylene derivatives as well as methods of preparing them. These polymers are prepared in the eresence of a metallocene catalyst and are isotactic. Applications using these polymers include but are not limited to, electrophotography toners, melt facture reduction agents, and compatibilizers.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: September 15, 2009
    Assignee: Baker Hughes Incorporated
    Inventors: Paul Hanna, Satyarayana Nistala, Leon L. Otte, Kent Fudge, Thomas J. Clark, David D. Truong, John Woods
  • Patent number: 7579406
    Abstract: The present invention relates to a transparent thermoplastic resin composition which characteristically contains A) 20-80 weight % of graft copolymer composed of a) conjugated diene rubber latex; b) intermediate layer prepared by copolymerization of acrylic acid alkylester derivative and aromatic vinyl derivative with the above a); and c) graft layer prepared by copolymerization of methacrylic acid alkylester derivative or acrylic acid alkylester derivative, a romatic vinyl derivative and vinyl cyan derivative with the above b) and B) 20-80 weight % of MSAN copolymer prepared by copolymerization of methacrylic acid alkylester derivative or acrylic acid alkylester derivative, aromatic vinyl derivative and vinyl cyan derivative.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: August 25, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Jeong-su Choi, Mi-young Lee, Hyong-min Bahn, Keun-hoon Yoo, Won-seok Lee
  • Patent number: 7569628
    Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrene-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: August 4, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
  • Patent number: 7569638
    Abstract: To provide a thermoplastic elastomer composition which is excellent in light resistance and flexibility and has high tear strength. [MEANS FOR SOLVING PROBLEMS] A thermoplastic elastomer composition comprising 100 parts by mass of acrylic multi-layer polymer particles (A) which each comprise at least two layers, i.e., at least one inner rubber layer (I) and at least one outermost thermoplastic resin layer (II), 5 to 300 parts by mass of an ethylene/vinyl ester copolymer (B), and 0.5 to 150 parts by mass of a graft copolymer (C) composed of an ethylene/vinyl ester copolymer backbone and a graft bonded to the backbone which consists of units derived from a monomer having a polarity higher than that of the backbone.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: August 4, 2009
    Assignee: Kuraray Co., Ltd.
    Inventors: Hiroshi Ozawa, Yuichi Katoh, Motohiro Fukuda
  • Patent number: 7557158
    Abstract: Thermoplastic polymer compositions are disclosed that can be processed into capstocks having a reduced gloss appearance, high impact strength and superior weatherability. The capstocks described herein are especially useful for extrusion into articles. They are also useful for application to various poor weathering structural plastic articles for preparing multi-layered composites having improved weatherability. Methods for manufacturing structural plastic capstocks and composites and articles produced therefrom having reduced gloss appearance are also described.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: July 7, 2009
    Assignee: Rohm and Haas Company
    Inventor: Paul VanRheenen
  • Patent number: 7547744
    Abstract: The present invention relates to a thermoplastic resin composition. In more particular, a thermoplastic resin of graft ABS polymer and heat-resistant copolymer contains acryl-based resin, peroxide-based additive, or cross-linking additive, so that the thermoplastic resin composition of the present invention is effective in processing of a colored heat resistant ABS resin by having excellent cold stress whitening reduction and strength property, without lowering other properties as well as giving excellence in hot-tool weldability, pigmentation and paint spread property which are more important in post process, and maintaining the mechanical property as well as giving excellent heat-resistance and low gloss property.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: June 16, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Jae-Hyug Cha, Seung-Hun Chae, Seong-Lyong Kim, Jun-Tae Lee, Byung-Tae Yang
  • Patent number: 7534832
    Abstract: The present invention relates to an acrylic impact modifier having a multilayered structure, which offers both superior impact resistance and coloring characteristics to engineering plastics, such as polycarbonate (PC) and a polycarbonate/polybutylene terephthalate alloy resin, or to a polyvinyl chloride resin. The present invention provides an acrylic impact modifier having a multilayered structure comprising: a) a seed prepared by emulsion copolymerization of a vinylic monomer and a hydrophilic monomer; b) a rubbery core surrounding the seed and comprising a C2 to C8 alkyl acrylate polymer, and c) a shell surrounding the rubbery core and comprising a C1, to C4 alkyl methacrylate polymer, a method for preparing the same, and a thermoplastic resin comprising the same.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: May 19, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Jeongheon Ahn, Seon-Hee Han, Kwang-Jin Lee
  • Patent number: 7510764
    Abstract: A pressure-sensitive adhesive composition comprising polymers and/or copolymers based at least predominantly on (meth)acrylic acid and/or derivatives thereof, wherein said composition possesses an outgassing level of not more than 50 ?g/g in total, preferably less than 10 ?g/g, when said composition is measured by the tesa method.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: March 31, 2009
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zöllner, Heiko Thiede, Reinhard Storbeck
  • Patent number: 7488775
    Abstract: A thermoplastic resin composition comprising 10 to 98 parts by weight of a graft polymer (1A) containing a rubber-like polymer (1G) having a diene unit content of 50% by weight or less, 2 to 50 parts by weight of a hydroxyl group-containing acrylic copolymer (1B) and 0 to 80 parts by weight of other thermoplastic resin (1F), wherein the rubber-like polymer (1G) is at least one selected from the group consisting of a diene-based rubber, a polyorganosiloxane-based rubber and an olefin-based rubber; and, a graft copolymer (2A) obtained by grafting a vinyl-based polymer to a (meth)acrylate-based rubber-like polymer (2G) expansion-treated with an acid group-containing copolymer latex (2K) wherein the (meth)acrylate-based rubber-like polymer contains two or more poly-functional monomer units.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: February 10, 2009
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yoshihiro Nakai, Hideyuki Shigemitsu
  • Patent number: 7482063
    Abstract: An in-mold coating molded article is obtained by coating the surface of a resin molded product comprising a hydroxyl group-containing polypropylene resin composition (A) with a paint composition for in-mold coating, wherein the composition (A) comprises a polypropylene resin (i), an additive rubber (ii) and optionally a polymer compound (iii) other than the polypropylene resin (i) and the additive rubber (ii), the total hydroxyl value of the polypropylene resin (i), the additive rubber (ii) and the optional polymer compound (iii) is from 1 to 40, the composition (A) has a rubber component content (total of the amount of the additive rubber (ii) and the amount of components soluble in n-decane at 23° C.
    Type: Grant
    Filed: August 21, 2003
    Date of Patent: January 27, 2009
    Assignees: Prime Polymer Co., Ltd., Dai Nippon Toryo Co., Ltd., Ube Machinery Corporation, Ltd.
    Inventors: Takeshi Minoda, Yuichi Matsuda, Kaoru Yorita, Kenji Yonemochi, Kenji Oota, Etsuo Okahara, Toshio Arai
  • Patent number: 7452602
    Abstract: A vinylidene fluoride-based resin film including polyvinylidene fluoride whose average spherocrystal diameter is less than 0.1 ?m that is a detection limit or lower by observation using a transmission electron microscope is provided, the average spherocrystal diameter being obtained by shaping a vinylidene fluoride-based resin in a molten state by sandwiching the resin between rollers or metal belts so as to let it cool down. Thereby, a vinylidene fluoride-based resin film and a vinylidene fluoride-based resin multilayered film having excellent transparency, weather resistance, chemical resistance, break resistance and formability are provided.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: November 18, 2008
    Assignee: Kaneka Corporation
    Inventors: Kazuhito Wada, Yukihiro Shimamoto
  • Publication number: 20080254290
    Abstract: The invention relates to a glass-strand sizing composition comprising the following constituents, in the following contents by weight expressed as percentages of the solids: 10 to 99% of at least one copolymer chosen from ethylene/vinyl acetate or ethylene/(meth)acrylic acid copolymers; 1 to 40% of at least one coupling agent; and 0 to 90% of polypropylene grafted by at least one unit derived from at least one monomer containing one or more functional groups that can react with the coupling agent. The glass strands obtained are intended for producing glass-strand granules with a high glass content for the production of composite parts having a thermoplastic matrix reinforced by chopped glass strands using the injection-moulding technique.
    Type: Application
    Filed: May 2, 2006
    Publication date: October 16, 2008
    Applicant: SAINT-GOBAIN VETROTEX FRANCE S.A.
    Inventors: Jean-Philippe Gasca, Yohann Barnaud
  • Patent number: 7432320
    Abstract: There is provided a vinyl chloride resin composition, which is excellent in processability and can produce a processed article having excellent physical property or a formed molding having excellent property. A processing aid having specific viscosity of at least 0.5 is combined with a vinyl chloride resin, wherein the aid is obtained by polymerizing 1 to 50 parts by weight of a monomer mixture (B) comprising 0 to 49% by weight of methyl methacrylate, 51 to 100% by weight of at least one monomer selected from the group consisting of a methacrylate ester except methyl methacrylate and an acrylate ester, and 0 to 20% by weight of a vinyl monomer copolymerizable therewith, in the presence of a latex of a (co)polymer having specific viscosity of at least ?sp 0.
    Type: Grant
    Filed: December 10, 2003
    Date of Patent: October 7, 2008
    Assignee: Kaneka Corporation
    Inventors: Noriko Sakashita, Yasuhiro Miki, Akira Takaki
  • Patent number: 7420016
    Abstract: In order, in the case of a moulding composition for the production of sanitary-ware components, comprising a methyl-methacrylate-based syrup and from 50 to 85%, expressed in terms of the moulding composition, of an inorganic filler, to obtain an improvement in the scratch-proofness and the abrasion resistance of the shaped components which are obtained therefrom, it is proposed that the composition furthermore comprise elastomer particles or elastomer particle aggregates having a particle size <100 ?m in an amount in the range of 5% by weight to <20% by weight, expressed in terms of the mass of the syrup.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: September 2, 2008
    Assignee: BLANCO GmbH + Co KG
    Inventors: Andreas Hajek, Thomas Heck, Stefan Harke, Thomas Wilhelm
  • Patent number: 7405265
    Abstract: Disclosed is a method of preparing a catalyst for polymerization of aliphatic polycarbonates and a method of polymerizing an aliphatic polycarbonate. This method includes reacting a zinc precursor and organic dicarboxylic acid in a non-ionic surfactant-included solution.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: July 29, 2008
    Assignees: Posco, Postech Foundation
    Inventors: Seung-Jae Moon, Moon-Hor Ree, Jong-Sung Kim, Kie-Soo Kim
  • Publication number: 20080176994
    Abstract: Ethylene vinyl acetate compositions that have been partially crosslinked using organic peroxides are disclosed, as well as methods for their production. The crosslinked compositions have low melt index values and increased tensile strength, leading to flexibility and heat resistant properties.
    Type: Application
    Filed: January 18, 2007
    Publication date: July 24, 2008
    Inventors: Gerd A. Allermann, Hitesh A. Fruitwala
  • Patent number: 7396877
    Abstract: Disclosed is a resin composition comprising (A) 100 parts by weight of a base resin comprising a rubber-modified styrene-containing graft copolymer and a styrene-containing copolymer; (B) 0.5-8 parts by weight of an acrylic rubber graft copolymer resin having an average particle size of 0.1-0.5 ?m; and (C) 0.5-8 parts by weight of a graft copolymer resin comprising an ethylene ?-olefinic copolymer rubber having an average particle size of 0.1-0.8 ?m. The thermoplastic resin composition of the present invention greatly improves chemical resistance to insulating materials, such as urethane foam, or foaming agent compounds, such as freon (CFC-11, HCFC-141b, HFC-245fa, HFC-245eb, HFC-245ca, HFC-356mffm) and cyclopentane and offers superior impact strength, whiteness and processability. It can be useful for extrusion sheets of refrigerator interiors.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: July 8, 2008
    Assignee: LG Chem, Ltd.
    Inventors: Sung-je Cha, Sung-tae Ahn, Dong-chul Kim, Yun-kyoung Cho
  • Patent number: 7396876
    Abstract: A thermoplastic resin component has improved transparency and impact resistance, the thermoplastic resin composed of 5 to 40 parts by weight of a graft copolymer (A) and 95 to 60 parts by weight a copolymer (B), the graft copolymer (A) being prepared by polymerizing at least one selected from the group consisting of alkyl methacrylate, aromatic vinyl, and vinylcyanide with an agglomerated rubber, the copolymer (B) being prepared by polymerizing at least one monomer selected from the group consisting of an aromatic vinyl monomer, an alkyl methacrylate monomer, and a vinylcyanide monomer. The agglomerated rubber is prepared by agglomerating a styrene-diene rubber latex with an acid-group-containing copolymer latex containing unsaturated acid, aromatic vinyl, and alkyl acrylate as the essential components and having a controlled refractive index.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: July 8, 2008
    Assignee: Kaneka Corporation
    Inventors: Katsumi Yamaguchi, Hitoshi Hayashi, Akio Sato, Mamoru Kadokura
  • Patent number: 7368061
    Abstract: A continuous process for the production of an elastomer-modified thermoplastic is disclosed. The process entails (i) obtaining graft elastomer (D) having residual moisture content of 1 to 50 wt. %, particularly 5 to 50 wt. %, particularly preferably 10 to 40 wt. %, (ii) introducing (D) and thermoplastic resin (B) through an inlet to a reactor operating under conditions calculated to melt (D) and (B) and to remove organic volatile components C) to produce a molten blend, the reactor being equipped with a plurality of kneading bars, that convey a portion of the molten blend towards the reactor inlet.
    Type: Grant
    Filed: April 16, 2004
    Date of Patent: May 6, 2008
    Assignee: Lanxess Deutschland GmbH
    Inventors: Alfred Eitel, Haakan Jonsson, Ulrich Liesenfelder, Stefan Moss, Ricarda Nothelle, Andreas Frankenau, Stephen Böhmer
  • Patent number: 7351766
    Abstract: The thermoplastic resin composition of the present invention is obtained by graft polymerizing a monomer that composes a polymer that is compatible with or has affinity for polycarbonate resin in the presence of a polymer that is incompatible with polycarbonate resin; wherein, the weight average molecular weight of a soluble component that dissolves in chloroform is 10,000 to 100,000. In the case of using this thermoplastic resin composition in an engineering plastic, fluidity can be improved without impairing the characteristics of the engineering plastic. The engineering plastic composition of the present invention is preferably used in the field of housings and various parts of OA equipment, telecommunications equipment and home appliances such as photocopiers, facsimiles, televisions, radios, tape recorders, video decks, personal computers, printers, telephones, information terminals, refrigerators and microwave ovens, as well as in other fields such as automotive parts.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: April 1, 2008
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Yasuhiko Nabeshima, Atsunori Koshirai
  • Patent number: 7338706
    Abstract: A resin composition for capstock, comprising 100 to 30 parts by weight of an impact resistance modifier having a multilayer structure, and 0 to 70 parts by weight of a methyl methacrylate (co)polymer containing 50 to 100% by weight of methyl methacrylate and 50 to 0% by weight of a monomer which is copolymerizable therewith, wherein the total amount of the impact resistance modifier and the methyl methacrylate (co)polymer is 100 parts by weight, wherein the outer layer of said impact resistance modifier and/or said methyl methacrylate copolymer is copolymerized with 0.5 to 40% by weight of a reactive monomer based on the total amount of the impact resistance modifier and the methyl methacrylate (co)polymer as a polymer component, and wherein the homopolymer of said reactive monomer has an SP value of 9.8 (cal/cm3)/1/2 or more.
    Type: Grant
    Filed: April 23, 2002
    Date of Patent: March 4, 2008
    Assignees: Kaneka Corporation, Kaneka Texas Corporation
    Inventors: Riichi Nishimura, Takahiko Sugaya
  • Patent number: 7304111
    Abstract: A problem of the invention is to provide a propylene copolymer which is excellent in adhesion to crystalline propylene-based polymers and which is excellent in solubility and compatibility with polar resins, a process for producing the same, and a composition containing the subject polypropylene copolymer. The invention is concerned with a polypropylene copolymer, which is characterized by having a polymer principal chain (A) derived from a propylene-based polymer having (1) a prescribed requirement as defined by the 13C-NMR spectral measurement and having (2) a melting point [Tm] by a differential scanning calorimeter of not higher than 100° C., or a crystal melting heat of less than 5 J/g; and a side chain containing a polymer chain (B) which is different from the principal chain, with a weight ratio of (A)/(B) being in the range of from 20/1 to 1/20, a composition containing the subject copolymer, and a process for producing the subject copolymer.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: December 4, 2007
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Kazuyuki Hata
  • Patent number: 7268186
    Abstract: The present invention relates to a sheet for a carrier tape, having at least one layer comprising (I) a block copolymer comprising a vinyl aromatic hydrocarbon and a conjugated diene, (II) a non-rubber-modified vinyl aromatic type hydrocarbon polymer, and (III) a rubber-modified vinyl aromatic type hydrocarbon polymer, wherein the peak molecular weight of the vinyl aromatic hydrocarbon polymer block in the block copolymer (I) is from 30,000 to 80,000, the half-width in the molecular weight distribution curve of the vinyl aromatic hydrocarbon block is from 1.3 to 2.8, the vinyl aromatic hydrocarbon content in the sheet for a carrier tape is from 75 to 95 wt %, and the content of the vinyl aromatic hydrocarbon polymer component is from 65 to 85 wt %.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: September 11, 2007
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Susumu Hoshi, Fumio Sugeno
  • Patent number: 7235597
    Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrenic-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: June 26, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
  • Patent number: 7211642
    Abstract: A polymer comprises at least two types of monomer units selected from: (1) diethynyl benzene units, (2) triethynyl benzene units, and (3) ester units. After curing, the polymer may form a condensed polyaromatic dielectric having a dielectric constant of at most 2.0 at 1 MHz, an elastic modulus of at least 7.7 GPa, and a hardness of at least 2.0 GPa.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: May 1, 2007
    Assignee: The Board of Trustees of the Univeristy of Illinois
    Inventors: James Economy, Yongqing Huang
  • Patent number: 7195816
    Abstract: To provide an acrylic film, composed of a resin composition (C) that includes an acrylic graft copolymer (A) containing an acrylic ester rubber-like polymer and a methacrylic polymer (B) containing 80% by weight or more of methyl methacrylate, wherein (1) the content of the acrylic ester rubber-like polymer in the resin composition (C) is 5% by weight or more and 30% by weight or less, (2) the average particle size of the acrylic ester rubber-like polymer is 500 to 2000 ?, (3) the relationship between the average particle size d (?) of the acrylic ester rubber-like polymer and the amount w (% by weight) of crosslinking agent used in the acrylic ester rubber-like polymer satisfies the following equation: 0.002d?w?0.005d, (4) the graft ratio of the acrylic graft copolymer (A) is 30% or more and 200% or less, and (5) the reduced viscosity of methyl ethyl ketone soluble matter in the resin composition (C) is 0.2 to 0.8 dl/g.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: March 27, 2007
    Assignee: Kaneka Corporation
    Inventors: Norito Doi, Takao Shibata, Yoichi Matsumura, Shigemi Matsumoto
  • Patent number: 7176258
    Abstract: A water-based emulsion for vibration damper is provided for the formation of an excellent vibration damper. In an aspect, the emulsion for vibration damper contains a particle including a core part formed of an acrylic copolymer (A) and a shell part formed of an acrylic copolymer (B) which covers the core part, the glass transition point of the acrylic copolymer (B) being not lower than ?9° C., and the difference between the glass transition point of the acrylic copolymer (B) and the glass transition point of the acrylic copolymer (A) being not less than 20° C.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: February 13, 2007
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Shigeyasu Morihiro, Yukihiro Miyawaki, Dai Nagaishi
  • Patent number: 7157520
    Abstract: A powdery linear polymer having a narrow particle size distribution with little dusting and excellent in anti-blocking property is recovered from a latex of a linear polymer containing a large proportion (35–75 wt. %) of soft polymer (S) component through a two-step coagulation process including a first (moderate coagulation) step causing 70–98 wt. % of the coagulation. The linear polymer in the latex has a multilayer structure comprising a linear polymer (S) having a glass transition temperature below 40° C. and a linear polymer (H) having a higher glass transition temperature disposed in totally at least two layers and containing 35–75 wt. %, as a whole, of the linear polymer (S) with the proviso that the linear polymer (S) cannot be contained in excess of 30 wt. % in an outermost layer of the multilayer structure.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: January 2, 2007
    Assignee: Rohm and Haas Company
    Inventors: Atsuhiro Higuchi, Yasuhiro Suzuki
  • Patent number: 7122604
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 17, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 7119152
    Abstract: The present invention relates to thermoplastic polyesters, which comprise, by weight: (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shell copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-unsaturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 40/60 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 40/60 and 25/75 for proportions of impact modifier between 2 and 18% in 98 to 82% of polyester, respectively. It is particularly useful for PET and PBT.
    Type: Grant
    Filed: November 24, 2000
    Date of Patent: October 10, 2006
    Assignee: ATOFINA
    Inventors: Christophe Lacroix, Alain Bouilloux
  • Patent number: 7071246
    Abstract: This invention relates to a tread rubber composition for tires with the addition of crosslinked resinous nanoparticles having a high glass transition temperature (Tg) into elastomeric base polymers. The invention demonstrates greatly improved handling performance without deteriorating controllability and stability during high-speed running. The present invention discloses a rubber composition comprising: (1) a rubbery polymer and (2) from 1 to 30 parts per hundred parts of rubber by weight (phr) of pre-crosslinked polymer particles, wherein the pre-crosslinked polymer particles have a particle size which is within the range of 30 nm to 500 nm, wherein the pre-crosslinked polymer is comprised of repeat units that are derived from at least one monomer selected from the group consisting of acrylate monomers, vinyl aromatic monomers, acrylonitrile monomer, and vinyl halide monomers, and wherein the pre-crosslinked polymer has a glass transition temperature which is within the range of 30° C. to 200° C.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: July 4, 2006
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Feng Anne Xie, Lei Zheng, Eric Sean Castner
  • Patent number: 7064163
    Abstract: A method for producing polyolefin-based adhesive resins having improved physical and optical properties and the improved adhesive resins thereby produced, eliminates at least one reheating and melting of polyolefin polymer, comprises polymerizing a monomer composition of at least one olefin, mixing the polymerization product without pelletizing the polyolefin polymer with at least one graft polymer or copolymer in a heated mixing device at a temperature above the melting point of the components, and recovering the resulting polyolefin-based adhesive resin.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: June 20, 2006
    Assignee: MSI Technology LLC
    Inventor: Mitsuzo Shida
  • Patent number: 6989192
    Abstract: A pressure sensitively adhesive polyacrylate according to a composition known per se, characterized by crosslinked and functionalized polymer particles which on the basis of their chemical nature are suitable for assisting a crosslinking reaction of the pressure sensitive adhesive.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: January 24, 2006
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zöllner
  • Patent number: 6982299
    Abstract: A low gloss thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a process for its preparation are disclosed. The composition contains an effective amount of a gloss-reducing agent that is the reaction product of (i) compound having two or more maleic anhydride groups per molecule and (ii) compound having two or more terminal primary amine groups per molecule. The incorporation of the gloss reducing agent in the inventive composition may be by blending the reaction product or, in the alternative, blending the reactants (i) and (ii) in the molten ASA under process conditions designed to bring about the in situ formation of the inventive gloss reducing agent.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: January 3, 2006
    Assignees: Lanxess Corporation, Bayer Aktiengesellschaft
    Inventors: Moh-Ching Oliver Chang, Allen R. Padwa, Chuan-Ju Chen, Daniel Dufour
  • Patent number: 6894115
    Abstract: Adhesive blend compositions having significantly improved adhesion to metals at elevated temperatures are provided. The compositions are blends of one or more polyolefin base resins, an acid or acid derivative modified polyolefin and silane modified polyolefin. A low level of adhesion promotor is optionally included in the blend.
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: May 17, 2005
    Assignee: Equistar Chemicals, LP
    Inventor: Maged G. Botros
  • Patent number: 6887943
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: May 3, 2005
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 6878775
    Abstract: A pressure-sensitive adhesive composition based on (co)polymers of acrylic acid and/or methacrylic acid and/or derivatives thereof which has an at least two-phase domain structure and also an outgassing level of less than 10 ?g/g, based on the weight of the composition, when measured by the tesa method.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: April 12, 2005
    Assignee: tesa AG
    Inventors: Marc Husemann, Stephan Zöllner
  • Patent number: 6872278
    Abstract: An adhesive composition that includes a) an emulsion that includes a multi-stage polymer that includes a first stage polymer having a Tg from ?20° C. to 90° C. and including from about 0.5% by weight to about 3% by weight latent crosslinking monomer based on the first stage monomer weight, and a second stage polymer having a Tg from 40° C. to 140° C., the second stage polymer being different from the first stage polymer, b) formaldehyde-based crosslinking agent, and c) catalyst, the composition being capable of passing the DIN EN 204 Test Method.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: March 29, 2005
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Nicholas C. Lehman, Scott W. Rhein, John T. Anderson
  • Patent number: 6872776
    Abstract: A vinyl chloride resin composition having excellent weatherability and impact resistance which comprises (a) a vinyl chloride resin, (b) a graft copolymer which is obtained by graft-polymerizing (b2) a graft monomer component composed of 40 to 100% by weight of methyl methacrylate and 0 to 60% by weight of at least one monomer selected from the group consisting of an alkyl acrylate, an alkyl methacrylate, an unsaturated nitrile and an aromatic vinyl compound onto (b1) a crosslinked elastomeric polymer composed mainly of an alkyl acrylate, the methyl ethyl ketone-soluble portion of the graft copolymer having an ?sp/c of 1 to 5 measured at 30° C. with respect to its 0.2 g/100 cc acetone solution, and (c) calcium carbonate; and molded articles having a multilayer structure wherein a layer molded from the above composition is used as the surface layer or the inner layer.
    Type: Grant
    Filed: May 31, 1999
    Date of Patent: March 29, 2005
    Assignee: Kaneka Corporation
    Inventors: Hirokazu Iguchi, Kazunori Saegusa, Satoshi Mizunuma, Akira Takaki
  • Patent number: 6861475
    Abstract: The present invention, a powder composition for making powder coatings comprising one or more than one curable polymer or resin and an agglomerate of a core-shell polymer, wherein the agglomerate of a core-shell polymer has an average particle size of from 5 to 190 microns, preferably from 10 to 127 microns. The powders in accordance with the present invention provide a cured powder coating that is flexible, smooth, and which may be applied in a thickness of only from 0.3 to 8 mils. In a preferred embodiment of making a powder in accordance with the present invention, the agglomerate is cryoground to form a reduced agglomerate prior to adding it into a powder as a post-blend or a powder-forming mixture as a preblend. The preferred core-shell polymer for use in accordance with the present invention comprises an acrylic impact modifier having a poly(methyl methacrylate) shell and a poly(butyl acrylate) core.
    Type: Grant
    Filed: December 18, 2002
    Date of Patent: March 1, 2005
    Assignee: Rohm and Haas Company
    Inventors: Casmir Stanislaus Ilenda, Michael Louis Spera, Gordon Tullos, Andrew T. Daly
  • Patent number: 6852799
    Abstract: Product, method and use of a copolymer AB as a compatibilizing agent between a polar thermoplastic polymer C and a polyolefine D. The method of making AB comprise the steps of: a) melting a copolymer (A) comprising a larger amount of methylmethacrylate units and a smaller amount of functional vinyl or (meth)acrylate units wherein functional moiety is selected in the group consisting of (a hydroxyl, a carboxylic, a glycidyl or an amine functional group); together with maleic anhydride grafted polypropylene (B) allowing condensation reaction to occur between the functions under “A” and the anhydride under “B”; b) the condensation copolymer obtained under a) is further melt together with the two polymers C and D to be homogenized, or melt processed as an interlayer between the two molten polymers.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: February 8, 2005
    Assignee: Universite de Liege
    Inventors: Alexandre Baidak, Christine Brassine, Jean-Marie Liegeois, Trazollah Ouhadi
  • Patent number: 6849687
    Abstract: A thermoplastic molding composition comprising a grafted acrylate rubber (ASA) and a gloss reducing agent and a process for making the same are disclosed. The gloss reducing agent is the reaction product of (i) an epoxidized grafted rubber having two or more epoxy groups in its graft phase and (ii) a compound having two or more terminal primary amine groups per molecule The gloss reducing agent may be either incorporated in ASA as the reaction product of (i) and (ii) or, in the altemative, formed upon the reaction of (i) with (ii) in the course of the thermal processing of the a blend containing ASA, (i) and (ii).
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: February 1, 2005
    Assignee: Bayer Polymers LLC
    Inventors: Moh-Ching Oliver Chang, Allen R. Padwa, Norma I. Santiago
  • Patent number: 6844396
    Abstract: An acrylic resin composition with excellent impact resistance, weatherability, processability and low gloss is provided. The acrylic resin composition comprises, (A) 10 to 40 parts by weight of a high molecular weight acrylic (co)polymer which is a one-step or multi-step polymer containing 72 to 100% by weight of methyl methacrylate and 0 to 28% by weight of a copolymerizable monomer, the (co)polymer having a specific viscosity of at least 0.5 (solvent: toluene, concentration: 0.4%, temperature: 30° C.), wherein a polymer layer obtained in one of the steps contains at least 72% by weight of methyl methacrylate, has a specific viscosity of at least 0.5 and makes up at least 55% by weight of the total weight of the high molecular weight acrylic (co)polymer (A); (B) 0 to 80 parts by weight of an acrylic (co)polymer containing 50 to 100% by weight of methyl methacrylate and 0 to 50% by weight of a copolymerizable monomer, the acrylic (co)polymer having a specific viscosity of less than 0.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: January 18, 2005
    Assignees: Kaneka Corporation, Kaneka Texas Corporation
    Inventors: Takahiko Sugaya, Riichi Nishimura, Kazuhisa Tajima
  • Patent number: 6841622
    Abstract: Acrylic polymer fine particles which comprise primary particles P of 250 nm or more in average particle diameter having a core shell structure and plastisols prepared using the same. In the fine particles, a core polymer C and a shell polymer S are copolymers of the following monomer mixtures Mc and Ms, respectively, and the weight ratio of Mc and Ms is 10/90-90/10: Mc: methyl methacrylate 20-85 mol % (meth)acrylic ester of C2-C8 aliphatic alcohol and/or aromatic alcohol 15-80 mol % other copolymerizable monomers not more than 30 mol %; , when the total amount of these monomers is 100 mol %; Ms: methyl methacrylate 20-79.5 mol % (meth)acrylic ester of C2-C8 aliphatic alcohol and/or aromatic alcohol 5-40 mol % a monomer containing carboxyl group or sulfonic acid group 0.5-10 mol % other copolymerizable monomers not more than 30 mol %.
    Type: Grant
    Filed: April 30, 2002
    Date of Patent: January 11, 2005
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventor: Toshihiro Kasai
  • Publication number: 20040266947
    Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.
    Type: Application
    Filed: August 23, 2004
    Publication date: December 30, 2004
    Inventors: Anne Vera Macedo, Kenneth Lewias, Joha Richard Shutt
  • Publication number: 20040260021
    Abstract: Resins and oligomer materials and/or combinations thereof grafted with an unsaturated acid or anhydride, such as maleic anhydride, are disclosed herein. The grafted materials are useful in adhesive formulations, particularly in hot melt adhesive applications.
    Type: Application
    Filed: August 23, 2004
    Publication date: December 23, 2004
    Inventors: Anne Vera Macedo, Kenneth Lewtas, John Richard Shutt
  • Patent number: 6833409
    Abstract: An impact strength modifier comprises an acrylic rubber graft copolymer (I) obtained by graft-polymerizing a polyalkyl (meth)acrylate composite rubber (A) with a vinyl monomer (B), and a compound (II) which has a sulfonic acid group or a sulfuric acid group and also has two or more benzene ring skeletons, or a salt thereof. The polyalkyl (meth)acrylate composite rubber (A) contains two or more acrylic rubber components each having a different glass transition temperature, and the respective acrylic rubber components have 20% by weight or less of a monomer having two or more unsaturated bonds in a molecule. The compound (II) preferably has two or more benzene ring skeletons, and a particle size distribution of the polyalkyl (meth)acrylate composite rubber (A) is preferably a polydisperse distribution in which two or more peaks exist within a specific range.
    Type: Grant
    Filed: October 21, 2002
    Date of Patent: December 21, 2004
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Keiji Nakamura, Masakazu Ito
  • Patent number: 6815496
    Abstract: It is an object of the present invention to provide a thermoplastic elastomer composition excellent in softness, permanent compression set (both short- and long-term) and resistance to oil, and controlled in bleed-out of the softening agent. It is another object of the present invention to provide a formed article and composite formed article of the above thermoplastic elastomer composition. The present invention provides a thermoplastic elastomer composition containing (a) 100 parts by weight of at least one hydrogenated block copolymer, (b) 30 to 150 parts by weight of a non-aromatic-based softening agent for rubber and (c) 3 to 100 parts by weight of a thermoplastic resin having a melting point of 70 to 140° C., determined by the DSC analysis, and melt viscosity of 400 to 100,000 cps at 140° C., and formed article and composite formed article thereof.
    Type: Grant
    Filed: August 26, 2002
    Date of Patent: November 9, 2004
    Assignee: Riken Technos Corp.
    Inventors: Michihisa Tasaka, Takaaki Suka
  • Patent number: 6812283
    Abstract: A process for the agglomeration of at least one rubber (A), dispersed in an aqueous phase, by the addition of a dispersion of at least one agglomerating polymer (B) in aqueous phase, in which the agglomerating polymer B used is one containing substantially no free acid groups and the agglomeration is carried out in the presence of at least one basic electrolyte.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: November 2, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Wil Duijzings, Sabine Oepen, Norbert Niessner, Michael Breulmann, Hardy Korb
  • Patent number: 6812282
    Abstract: A low gloss thermoplastic composition suitable for making article having low gloss and a process for its preparation are disclosed. The composition contains (I) a resinous component that includes (a) a (co)polyalkyl (meth)acrylate rubber characterized that it contains no grafted phase, (b) a poly(vinyl aromatic-co-nitrile)-grafted (co)polyalkyl (meth)acrylate rubber, and (c) a poly(vinylaromatic-co-nitrile), and (II) a gloss-reducing agent that is the reaction product of (d) a compound having two or more maleic anhydride groups per molecule, and (e) a compound having two or more terminal primary amine groups per molecule, with the proviso that the total of the maleic anhydride groups per molecule and the terminal primary amine functional groups per molecule is greater than 4.
    Type: Grant
    Filed: September 10, 2002
    Date of Patent: November 2, 2004
    Assignee: Bayer Polymers LLC
    Inventors: Moh-Ching Oliver Chang, Yin-Shen Chang