Mixture Contains Solid Polymer Derived From Reactant Containing Carboxylic Acid Ester Group Patents (Class 525/80)
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Patent number: 6362274Abstract: The invention relates to grafted copolymers comprising at least three sequences of distinct chemical nature, among which one or more sequence(s) for anchoring on solid particles, one or more sequence(s) of hydrophobic character and one or more sequence(s) of hydrophilic character. The invention also concerns their process of preparation, the compositions containing them, their use as agent for dispersing, stabilizing solid particles and/or emulsifying in an aqueous and/or organic medium, as well as use thereof for preparing pigmentary dispersions in aqueous and/or organic medium.Type: GrantFiled: February 23, 1999Date of Patent: March 26, 2002Assignee: Les Peintures JefcoInventors: Pierre Legrand, Gerard Riess, Jean-Phillipe Lerch, Daniel Lefevre
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Publication number: 20020004557Abstract: The invention is directed to a powder coating composition comprising a first component (A) and a second component (B) that is dry-blended or melt blended with the first component (A). The first component (A) comprises at least one polyepoxy resin and at least one catalyst. The second component (B) comprises at least one carboxylic acid functional acrylic resin. The polyepoxy resins include non-crystalline polyepoxy resins, crystalline polyepoxy resins, and mixtures thereof. The powder coating compositions can be applied to heat sensitive substrates and cured at lower temperature or for shorter time to provide finishes having controllable gloss and/or high hardness.Type: ApplicationFiled: May 8, 2001Publication date: January 10, 2002Inventors: Stephen C. Hart, Jeffrey G. Schmierer, Brian W. Carlson
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Publication number: 20020004565Abstract: The invention relates to a process for preparing graft rubbers built up from at least one graft core and from at least one graft shell, comprisingType: ApplicationFiled: April 5, 2001Publication date: January 10, 2002Inventors: Peter Barghoorn, Volker Schadler, Heiko Maas, Norbert Niebner
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Publication number: 20010049416Abstract: The present invention discloses polymeric compositions containing a vinylaromatic lubricating copolymer which can be melt processed to provide plastic films or layers having excellent optical, printing, weathering, and tensile impact resistance characteristics. The present invention also discloses a processes for preparing plastic films of the compositions of the present invention. The present invention also discloses composite articles having the plastic films of the present invention and an underlying substrate.Type: ApplicationFiled: April 27, 2001Publication date: December 6, 2001Inventor: Olivier Jacques Choulet
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Patent number: 6309739Abstract: A methacrylate, resin composition having an excellent processability and capable of providing films having excellent impact resistance, transparency, weatherability, solvent resistance and plasticizer migration resistance, which comprises (A) 5 to 50% by weight of a crosslinked acrylate elastomer having a two layer structure of a crosslinked polymer component (a-1) having a glass transition temperature of −30 to 10° C. and a crosslinked polymer component (a-2) having a glass transition temperature of less than −30° C. wherein the component (a-1) is located on the inner side or the outer side and the component (a-2) is located on the outer side or the inner side, and (B) 95 to 50% by weight of an alkyl methacrylate polymer prepared by polymerizing an acrylic monomer containing 80 to 100% by weight of an alkyl methacrylate and 20 to 0% by weight of an alkyl acrylate in the presence of a chain transfer agent and in the presence or absence of the elastomer (A).Type: GrantFiled: August 17, 1998Date of Patent: October 30, 2001Assignee: Kaneka CorporationInventors: Keishi Koizumi, Shigemi Matsumoto, Takao Okimi, Juuichi Nishimura
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Patent number: 6310148Abstract: A styrene resin composition excellent in luster, rigidity and surface impact strength is provided. A mixed solution of (b1) a homopolymer of a diene monomer or (b2) a copolymer of a styrene monomer and a diene monomer, the copolymer having 15% or less on a weight basis of the styrene structure units, (b3) a copolymer of a styrene monomer and a diene monomer, the copolymer having 20 to 50% on a weight basis of the styrene structure units, (a1) a styrene monomer, and (a2) a (meth)acrylic acid alkyl ester is continuously bulk polymerized in a continuous bulk polymerization line having incorporated therein a tubular reactor with a plurality of mixing elements that have no mobile part fixed inside thereof.Type: GrantFiled: March 28, 2000Date of Patent: October 30, 2001Assignee: Dainippon Ink and Chemicals, Ltd.Inventors: Tsuyoshi Morita, Mamoru Fujihira, Jiro Matsuo
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Patent number: 6300412Abstract: This invention relates to a process for preparing rubber-modified aromatic vinyl resin compositions by polymerizing a raw material solution containing 3 to 20% by weight of rubbery polymer, 50 to 97% by weight of an aromatic vinyl monomer, and 0 to 30% by weight of a solvent until the conversion of said aromatic vinyl monomer falls in the range from 30 to 70%, adding a (meth)acrylate monomer or its mixture with other monomers to the reaction mixture so that the ratio by weight of the aromatic vinyl monomer in the reaction mixture to the (meth)acrylate monomer becomes 85/15 to 50/50, continuing the polymerization, and devolatilizing to remove the unreacted monomers, solvent, and the like. It is possible by this process to prepare easily and economically rubber-modified aromatic vinyl resin compositions of easy processability, good surface properties in respect to appearance and scratch resistance, and good balance between impact resistance and rigidity.Type: GrantFiled: January 7, 2000Date of Patent: October 9, 2001Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Yasuji Shichijo, Masanari Fujita
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Publication number: 20010025082Abstract: A syndiotactic polystyrene copolymer resin composition with high impact strength, which comprises: (A) about 1-99 weight % of a syndiotactic polystyrene copolymer which is polymerized from at least one macromonomer having an active polymerization group at its end and at least one styrene monomer; and (B) about 99-1 weight % of at least one rubber phase resin and/or at least one thermoplastic resin.Type: ApplicationFiled: January 19, 2001Publication date: September 27, 2001Inventor: Joon Yong Park
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Patent number: 6277913Abstract: There is provided a thermoplastic resin composition and interior or exterior parts for vehicle using thereof, which is excellent in flexibility, surface appearance, heat deformation property at heating and has low tackiness at a high temperature. The thermoplastic resin composition comprises 25 to 90 parts by weight of a (meth)acrylic ester copolymer (X), which is prepared by polymerizing 40 to 95% by weight of a (meth)acrylic ester, 0 to 40% by weight of a vinyl cyanide compound, not more than 60% by weight of an aromatic vinyl compound and 0 to 40% by weight of a monomer copolymerizable therewith, and has a glass transition temperature of not more than 20° C. and a gel content of not more than 50% by weight, 5 to 75 parts by weight of a copolymer (Y), which has a glass transition temperature or a melting point not less than 50° C.Type: GrantFiled: May 21, 1999Date of Patent: August 21, 2001Assignee: Kaneka CorporationInventors: Ikuhiro Mishima, Kazuhito Wada
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Patent number: 6268427Abstract: A method for increasing the damping properties of tire rubber comprising the steps of adding a saturated damping additive to a vulcanizable composition of matter, and processing the vulcanizable composition of matter containing the damping additive into tire rubber.Type: GrantFiled: February 18, 1999Date of Patent: July 31, 2001Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Michael W. Hayes
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Patent number: 6255387Abstract: A derivatized blend and a process for producing that blend in which a high ethylene content ethylene-propylene polymer and a lower ethylene content ethylene-propylene polymer are subjected to simultaneous blending and shearing to reduce their molecular weights and molecular weight distribution and then reacted with an organic compound to derivatize the blend. The sheared derivatized blend of polymers can function as a shear stable multifunctional viscosity index improver with improved low temperature properties and, in some cases, dispersancy antioxidant and anti-wear properties.Type: GrantFiled: January 8, 1998Date of Patent: July 3, 2001Assignee: Ethyl Additives CorporationInventors: Errol J. Olivier, Robert T. Patterson, Peter N. Nugara
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Patent number: 6228938Abstract: Thermoplastic materials containing A) 5 to 80 parts by weight of a thermoplastic co- or terpolymer made from the monomers styrene, &agr;-methylstyrene, methyl methacrylate, acrylonitrile with an average molecular weight ({overscore (M)}w) of 70,000 to 119,000, B) 1 to 30 parts by weight of a thermoplastic copolymer made from 60 to 95% by weight of styrene and/or &agr;-methylstyrene and 40 to 5% by weight of acrylonitrile with an average molecular weight ({overscore (M)}w) of 25,000 to 49,500, C) 0.1 to 10 parts by weight of a thermoplastic co- or terpolymer made from the monomers styrene, &agr;-methylstyrene, methyl methacrylate, acrylonitrile with an average molecular weight ({overscore (M)}w) of 1,500 to 6,000 and D) 0.5 to 50 parts by weight of a particulate rafted rubber with a glass transition temperature ≦10° C. and an average particle diameter (d50) of 0.05 to 0.Type: GrantFiled: June 20, 1994Date of Patent: May 8, 2001Assignee: Bayer AGInventors: Herbert Eichenauer, Karl-Heinz Ott, Dieter Wittmann, Alfred Pischtschan
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Patent number: 6225404Abstract: A thermoplastic compound comprising at least one linear or branched thermoplastic polymer or copolymer, having at least one reactive or graftable site (F1), which polymer is compounded with at least one hyperbranched dendritic polyester macromolecule being composed of a monomeric or polymeric nucleus and one or more monomeric or polymeric branching or spacing chain extenders. The macromolecule is optionally chain terminated and/or functionalized, whereby terminal chain extender functions, chain termination and/or functionalization provides the macromolecule with at least one reactive or graftable site (F2) being reactive to or graftable onto said reactive or graftable site (F1). In a further aspect, the invention relates to a thermoplastic composition comprising two or more components, whereby at least one is said thermoplastic compound. In yet a further aspect, the invention relates to a thermoplastic article made of one or more thermoplastic compounds, whereby at least one is said thermoplastic compound.Type: GrantFiled: March 4, 1999Date of Patent: May 1, 2001Assignee: Perstorp ABInventors: Kent Sorensen, Bo Pettersson, Louis Boogh, Jan-Anders Edvin Mansson
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Patent number: 6214914Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyether amine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functonalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. A polyether monoamine that contains from about 36 to about 44 ethylene units and from about 1 to about 6 propylene units, and processes and blends using same.Type: GrantFiled: August 3, 1999Date of Patent: April 10, 2001Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
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Patent number: 6211290Abstract: A polyolefin modified to contain a pendant polar chain structure of at least 200 molecular weight and which has at least one ester group and at least one hydroxyl and/or oxirane group is a useful adhesion-promoting modifier for polyolefin resins.Type: GrantFiled: July 7, 1999Date of Patent: April 3, 2001Assignee: GX Associates, IncInventors: Han Xiong Xiao, Mohammad Hailat
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Patent number: 6177517Abstract: Thermoplastic molding masses made of thermoplastic polymers obtained by mixed graft polymerization and having a glass transition temperature above 20 C., and of special rubber-elastic block copolymers, are characterized by a balanced spectrum of properties.Type: GrantFiled: June 18, 1997Date of Patent: January 23, 2001Assignee: BASF AktiengesellschaftInventors: Norbert G{umlaut over (u)}ntherberg, Martin Weber, Konrad Knoll
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Patent number: 6160048Abstract: There is provided a modified ethylene resin produced by subjecting (a) an ethylene resin to modification with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a hydrocarbon-terminated polyalkylene oxide chain, and with (c) an aromatic vinyl compound and/or (d) an ester of an .alpha.,.beta.-unsaturated carboxylic acid with an aliphatic alcohol.There is also provided an ethylene resin composition comprising: (A) 80 to 99.9% by weight of a modified ethylene resin produced by subjecting (a) an ethylene resin to modification at least with (b) an .alpha.,.beta.-unsaturated carboxylic ester having a polyalkylene oxide chain; and (B) 20 to 0.1% by weight of a surfactant.Type: GrantFiled: August 14, 1998Date of Patent: December 12, 2000Assignee: Mitsubishi Chemical CorporationInventors: Tadashi Uyeda, Keiko Matsuhisa, Kenjiro Takayanagi, Mitsutoshi Aritomi
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Patent number: 6153307Abstract: The present invention relates to compatibilizers useful to laminate a layer of a vinyl aromatic polymer such as polystyrene and a polyester such as PET. The compatibilizer comprises a mixture comprising 5-95 weight % of a polyester, 95-5 weight % of an impact modified polymer of a vinyl aromatic monomer such as high impact polystyrene (HIPS) and from 5 to 20 weight % of a hydrogenated block polymer of a vinyl aromatic monomer and a conjugated diolefin sometimes called SEBS.Type: GrantFiled: July 30, 1998Date of Patent: November 28, 2000Assignee: Nova Chemicals Inc.Inventor: Beth Ann Baran
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Patent number: 6136918Abstract: A rubber latex with its particles grown through cohesion by adding 100 weight parts of (B) a rubber latex (solid), 0.1-15 weight parts (solid) of (A) an acid group-containing latex having an average particle size of 50-500 nm prepared by polymerizing a monomer mixture comprising (a), (b), (c) and (d) [wherein (a)+(b)+(c)+(d)=100 weight %]: (a) 5-25 weight % of at least one of unsaturated acids selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid and crotonic acid, (b) 20-95 weight % of at least one of alkyl methacrylates with its alkyl group 1-12 in carbon number, (c) 0-30 weight % of at least one of alkyl acrylates with its alkyl group 1-12 in carbon number, (d) 0-40 weight % of at least one selected from the group consisting of aromatic vinyls, compounds having at least two polymerizable functional groups in a molecule and vinyl cyanides, copolymerizable with the aforementioned (a), (b) and (c) is provided.Type: GrantFiled: April 30, 1998Date of Patent: October 24, 2000Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Ikuhiro Mishima, Norito Doi, Youichi Matsumura, Shigemi Matsumoto, Shinobu Ochikoshi, Kazuhito Wada, Hiroki Yoshino
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Patent number: 6136903Abstract: Repulpable PSA compositions and constructions that exhibit high adhesive performance on a wide range of substrates are provided. In one embodiment, a PSA composition comprises a blend of two emulsion acrylic copolymers. The first type is a repulpable, emulsion acrylic copolymer that passes TAPPI UM 213. Preferably, the copolymer is prepared by sequential polymerization. The second type of copolymer is a non-repulpable, gpp or removable, repositionable, emulsion acrylic copolymer, also preferably prepared by sequential polymerization. The PSA compositions are inherently tacky and can be used in labels and tapes. In addition, they can be added to other PSAs as external tackifiers.Type: GrantFiled: October 9, 1997Date of Patent: October 24, 2000Assignee: Avery Dennison CorporationInventors: Shiaonung Su, Paul Keller, Graham Yeadon
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Patent number: 6133349Abstract: Compositions which have substantial weatherability and impact resistance include a substantially uniform blend of (1) a physical mixture of an uncross-linked acrylonitrile/styrene copolymer and a cross-linked alkyl acrylate/graft (meth)acrylate copolymer; and (2) a filler component, preferably wood, in an amount effective as a filler in the composition. Methods for making such compositions include forming a substantially uniform physical blend of such copolymers and filler component. The compositions preferably are substantially free of cross-linked acrylonitrile/styrene copolymer.Type: GrantFiled: September 29, 1998Date of Patent: October 17, 2000Assignee: Hughes Processing, Inc.Inventor: Roderick E. Hughes
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Patent number: 6096435Abstract: A thermoplastic polymer composition is provided that includes 100 parts by weight of a block copolymer and/or its hydrogenate having polymer blocks of an aromatic vinyl compound and polymer blocks of a conjugated diene compound, and from 5 to 95 parts by weight of a block copolymer having polymer blocks of an aromatic vinyl compound and/or an olefinic compound and polymer blocks having a constitutional unit derived from a (meth) acrylic compound, a laminate containing a layer of the composition, and a hot-melt adhesive that includes the composition. Because it has good melt adhesiveness, the composition of the invention can firmly adhere in melt to various polar or non-polar materials. Using the composition, it is easy to produce laminates having a layer of the composition and a layer of some other material, through melt shaping or any other melt adhesion techniques.Type: GrantFiled: March 6, 1998Date of Patent: August 1, 2000Assignee: Kuraray Co., Ltd.Inventors: Kazuhiko Maekawa, Masanari Uno, Atsushi Itoh, Hiroshi Hayashihara, Kazushige Ishiura, Shigeru Kawahara, Shiroh Kishii
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Patent number: 6072002Abstract: A thermoplastic molding composition which features improved impact and flow properties as well as reduced opacity is disclosed. The composition contains(A) 15 to 50 percent of a grafted rubber which contains (a) a crosslinked rubber substrate which contains, as a core, about 1 to 25% relative to its weight of at least one vinylaromatic polymer, and (b) a grafted phase, and(B) 85 to 50 percent of a copolymeric matrix.The composition, which contains no additional grafted rubber components, is also characterized in that (i) the substrate amounts to 60 to 90 percent, and grafted phase amounts to 40 to 10 percent, relative to the weight of the grafted rubber and that (ii) the grafted rubber has a monomodal size distribution and that (iii) the grafted rubber has a weight average particle size of about 0.2 to 1.0 microns.Type: GrantFiled: October 21, 1997Date of Patent: June 6, 2000Assignee: Bayer CorporationInventors: Moh Ching Oliver Chang, Richard M. Auclair
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Patent number: 6063870Abstract: The rigid vinyl chloride resin composition comprises 100 parts by weight of a vinyl chloride resin having an average degree of polymerization of 350 to 600, 5 to 30 parts by weight of an impact-resistant improver, and 5 to 20 parts by weight of an acrylonitrile-styrene copolymer having a weight ratio acrylonitrile and styrene of 1/99 to 9/91. This composition has good impact strength and fluidity.Type: GrantFiled: August 5, 1998Date of Patent: May 16, 2000Assignee: Shin-Etsu Chemical, Co., Ltd.Inventors: Yuji Tokushige, Osamu Sodeyama
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Patent number: 6046275Abstract: A composition comprises (A) a syndiotactic styrene-based resin and (C) rubber polymer particles such as graft copolymers, butadiene or isoprene block copolymers optionally hydrogenated and/or modified with maleic anhydride, and other rubbers, and, optionally, (B) a thermoplastic resin such as a polycarbonate, and/or (D) a filler such as glass fibers.Type: GrantFiled: June 5, 1995Date of Patent: April 4, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 6040062Abstract: Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising:(a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and(b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.Type: GrantFiled: June 2, 1997Date of Patent: March 21, 2000Assignee: BASF CorporationInventors: John D. McGee, Donald H. Campbell, John W. Rehfuss
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Patent number: 6034176Abstract: Polymer compositions including an olefinic polymer, a polar polymer and a compatibilizer are disclosed. The compatilizer can be a block or graft copolymer including polymer portions that are compatible with the olefinic polymer and polymer portions that are compatible with the polar polymer.Type: GrantFiled: April 6, 1998Date of Patent: March 7, 2000Assignee: Teknor Apex CompanyInventors: Raman Patel, Dan Mallin, Keith Saunders, Patrick Tiberio, John Andries
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Patent number: 6031048Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.Type: GrantFiled: July 12, 1996Date of Patent: February 29, 2000Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J.G. Dominguez, Richard J. Clark
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Patent number: 6031047Abstract: Poly(vinyl chloride), when impact modified with a core/shell acrylic impact modifier whose shell is predominantly formed from 50-90 parts of polymerized units of methyl methacrylate and 10-50 parts of polymeric units of a C.sub.2 -C.sub.8 alkyl acrylate and whose core is a crosslinked copolymer mainly of polymeric units of butyl acrylate, exhibits improved fusion behavior, allowing conversion to an intimate, fused, processable blend at lower temperatures and faster rates, than when the shell of the impact modifier is substantially formed from methyl methacrylate alone.Type: GrantFiled: December 30, 1997Date of Patent: February 29, 2000Assignee: Rohm and Haas CompanyInventors: Jean Marie Brady, Steven Richard Rapacki
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Patent number: 6020428Abstract: A rubber-modified styrenic resin composition comprising (A) 100 wt. parts of a rubber-modified styrenic resin which contains 10 to 35 wt. % of soft component particles having an average particle size of 0.1 to 0.5 .mu.m, where said soft component particles have a single occlusion structure comprising a core part which consists of a single continuous phase of a styrenic resin and a shell part which comprises a rubber polymer and occludes said core part, and (B) 0.1 to 10 wt. parts of a polymer having a solubility parameter (SP) of 8.45 to 8.70 and having no aromatic vinyl compound unit therein. This composition has excellent plane impact strength and gloss properties as well as moldability and other physical properties, and satisfies properties required for exterior materials, wrapping materials and molded foam articles.Type: GrantFiled: May 24, 1996Date of Patent: February 1, 2000Assignee: Sumitomo Chemical Company, LimitedInventors: Shuji Yoshimi, Hayato Kihara, Takahiro Ishii
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Patent number: 6013202Abstract: A composition of matter useful for strippable shields for electric power cables comprises:a base polymer which is a copolymer of ethylene with a mono-unsaturated ester;conductive carbon black in an amount to give the composition an electrical resistivity below 500 .OMEGA.m; andas adhesion-controlling additive, a copolymer of ethylene with a mono-unsaturated ester containing from 0.5 to 2% by weight of side-chains each of which comprises an inflexible ring structure bonded to a backbone carbon atom of the copolymer with at most five atoms interposed between them.The compositions have the advantage of being less rubbery than current strippable-screen compositions and can be made successfully with copolymers of lower ester content.Type: GrantFiled: July 29, 1998Date of Patent: January 11, 2000Assignee: BICC General UK Cables LimitedInventors: Mark Richard Easter, Fiona Eleanor Keen
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Patent number: 6013726Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration, a polyamide, and a rubber polymer as main components.Type: GrantFiled: June 5, 1995Date of Patent: January 11, 2000Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 5990239Abstract: A thermoplastic composition comprising (a) a polyalkyl acrylate rubber characterized that it contains no grafted phase, and (b) a poly (vinyl aromatic-co-nitrile)-grafted polyalkyl acrylate rubber, and (c) ungrafted poly (vinyl aromatic-co-nitrile) having a number average molecular weight of about 20,000 to 100,000 g/mole is disclosed. The composition which contains about 15 to 35% by weight of polyalkyl acrylate rubber having a weight average particle size of about 0.02 to 1 microns and wherein weight ratio between (a) to the total (a)+(b) is 0.1 to 0.5, is characterized in having improved physical and mechanical properties.Type: GrantFiled: April 16, 1997Date of Patent: November 23, 1999Assignee: Bayer CorporationInventors: Moh Ching Oliver Chang, Richard M. Auclair
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Patent number: 5981657Abstract: The present invention provides a thermally resistant resin composition containing PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized with a basic metal compound containing a metal element of the group 2B, 3B, 4B or 5B of the periodic table; thermally resistant PS and PPO each with an acid group which is also neutralized in the same manner as described above; and a method for miscible preparation of PS and PPO, wherein at least one of PS and PPO has an acid group and the acid group is neutralized similarly.Type: GrantFiled: August 20, 1996Date of Patent: November 9, 1999Assignee: Sony CorporationInventors: Yasuhito Inagaki, Tsutomu Noguchi, Hidemi Tomita
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Patent number: 5965667Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyetheramine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts.Type: GrantFiled: November 3, 1997Date of Patent: October 12, 1999Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
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Patent number: 5965666Abstract: This invention relates to a resin composition having high impact strength at low temperatures, comprising a polyamide, a graft copolymer obtained by graft polymerizing a monomer mixture of an aromatic vinyl monomer and a vinyl cyanide monomer to a conjugated diene rubber, a copolymer comprising an aromatic vinyl monomer, a vinyl cyanide monomer and other vinyl monomer copolymerizable with the aromatic vinyl monomer and the vinyl cyanide monomer, a modified hydrogenated block copolymer comprising a conjugated diene rubber and styrene or its derivatives to which has been grafted an unsaturated carboxylic acid or an unsaturated carboxylic anhydride, a copolymer comprising an aromatic vinyl monomer, a maleimide monomer, an unsaturated carboxylic acid or an unsaturated carboxylic anhydride, and other vinyl monomer copolymerizable with the aromatic vinyl monomer, and a graft copolymer obtained by graft polymerizing a maleic anhydride to an ethylene-propylene rubber.Type: GrantFiled: February 20, 1998Date of Patent: October 12, 1999Assignee: Cheil Industries, Inc.Inventors: Jung-Kee Koo, Hee-Gu Yeo, Jong-Chul Lim
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Patent number: 5962593Abstract: A graft copolymer rubber comprising an unsaturated hydrocarbon rubber backbone having pendently grafted thereto a polymerized metal salt of an unsaturated carboxylic acid is provided. The graft copolymer rubber is prepared by a method which involves dissolving an unsaturated hydrocarbon rubber in a solvent to form a rubber solution, adding a metal salt of an unsaturated carboxylic acid to the solution, adding a free radical initiator to the solution and then heating the resultant reaction mixture at a temperature of from about 40 to about 150.degree. C. for a time period of from about 0.1 to about 100 hours.The resultant graft copolymer rubber is sulfur curable and when compounded with conventional rubber additives and cured forms rubber compounds having high modulus. The graft copolymer rubbers of the invention can be used in various end use applications where high strength properties are important such as tires, industrial rubber goods and the like.Type: GrantFiled: November 1, 1994Date of Patent: October 5, 1999Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Frederick J. Ravagnani, John M. Doshak
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Patent number: 5959015Abstract: A electrical conductivity modified thermoplastic olefin (TPO) polymer blend with improved electrostatic painting efficiency, the blend comprising a substantially uniform mixture of: I. polymeric material being the reaction product of: (a) polypropylene, (b) maleated polypropylene, (c) elastomer, and (d) amine-terminated polyether being a linear or branched polymer of oxypropyleneamine or oxyethyleneamine repeating units having 40-100 such units, and II. alkali metal salt, the alkali metal salt being included in the thermoplastic polymer blend in an amount which provides the blend with a conductivity of at least 10.sup.-12 S/cm at 25.degree. C.Type: GrantFiled: June 23, 1998Date of Patent: September 28, 1999Assignee: Ford Global Technologies, Inc.Inventors: Jeffrey Hampton Helms, Rose Ann Ryntz, Edmund Joseph Blais
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Patent number: 5959032Abstract: A compound comprising a blend of polypropylene with the reaction of a functionalized polypropylene and polyether amine in which the polyether amine is grafted into the functionalized polypropylene in a customary mixing apparatus is disclosed. The blend may include an elastomer such as EP rubber and/or a filler such as glass. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. A polyether monoamine that contains from about 36 to about 44 ethylene units and from about 1 to about 6 propylene units, and processes and blends using same.Type: GrantFiled: July 8, 1996Date of Patent: September 28, 1999Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard J. G. Dominguez, Richard J. Clark
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Patent number: 5955541Abstract: A thermoplastic resin composition which has low rigidity such as bending strength, bending modulus and tensile strength, high impact resistance, and further low stress and large energy absorption at the time of impact, high heat deformation resistance and excellent moldability and comprises 5 to 65 by weight of the copolymer (I) having Tg (glass transition temperature) of not more than 20.degree. C., 20 to 80 parts by weight of the maleimide copolymer (II) and 15 to 75 part by weight of the graft copolymer (III) having a graft ratio of 10 to 70% so that the total amount of the copolymers (I), (II) and (III) becomes 100 parts by weight, can be obtained.Type: GrantFiled: December 4, 1997Date of Patent: September 21, 1999Assignee: Kaneka CorporationInventors: Kazuhito Wada, Ikuhiro Mishima, Shigemi Matsumoto
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Patent number: 5955540Abstract: Rubber-modified monovinylidene aromatic copolymers having an enhanced combination of gloss, toughness and melt flow characteristics are provided by a process wherein a rubber latex having a specified particle size is partially agglomerated, emulsion graft polymerized to a specified graft copolymer to rubber (G/R) ratio and a specified graft copolymer molecular weight and further agglomerated during subsequent dewatering and/or melt compounding operations.Type: GrantFiled: March 26, 1998Date of Patent: September 21, 1999Assignee: The Dow Chemical CompanyInventors: Robert P. Dion, David W. Mitchell, Patricia B. Leng
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Patent number: 5948860Abstract: Disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer and (c) a polar group-containing olefin polymer composition obtained by heating (c-1) an olefin polymer containing a carboxyl group or an acid anhydrous group in its molecule and (c-2) an amino compound, each in a specific amount. Also disclosed is a propylene polymer composition comprising (a) a propylene polymer, (b) an olefin type elastomer, (c-1) an olefin polymer containing a carboxyl group or an acid anhydrous group in its molecule and (c-2) an amino compound, each in a specific amount. The propylene polymer compositions of the present invention are excellent in properties of being coated with various coatings.Type: GrantFiled: January 9, 1997Date of Patent: September 7, 1999Assignee: Mitsui Chemicals, Inc.Inventors: Shoji Hiraoka, Masayoshi Yamaguchi, Hajime Inagaki, Mikio Hashimoto
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Patent number: 5942576Abstract: A compound comprising a blend of polypropylene with the reaction product of a functionalized polypropylene and polyether amine in which the polyether amine is grafted onto the functionalized polypropylene in a customary mixing apparatus is disclosed. A process for producing the reaction product of the functionalized polypropylene and the polyether amine by melting with polypropylene in a customary mixing apparatus is also disclosed.Type: GrantFiled: November 3, 1997Date of Patent: August 24, 1999Assignee: Huntsman Petrochemical CorporationInventors: Randall Keith Evans, Richard Joseph Gilbert Dominguez, Richard James Clark
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Patent number: 5919863Abstract: The instant composition is a sealable and peelable polymer composition consisting essentially of a first ethylene copolymer grafted with a vinyl monomer and a second ethylene copolymer selected from ethylene/methylacrylate copolymers, ethylene/ethylacrylate copolymers and ethylene/butylacrylate copolymers.Type: GrantFiled: December 24, 1996Date of Patent: July 6, 1999Assignee: Borealis A/SInventors: Hanneli Seppanen, Markku Sainio, Torvald Vestberg, Lars-.ANG.ke Mattsson
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Patent number: 5910538Abstract: A thermoplastic molding composition containing a blend of polycarbonate, vinyl copolymer, such as SAN, and a graft polymer, such as ABS is disclosed. The invention resides in the finding that the incorporation of a compatibilizing agent which comprises a polymeric resin having a number average molecular weight of at least about 21,000 and which is miscible with the grafted phase of the graft polymer and which contains secondary amine reactive groups in its structure yields stable compositions having improved mechanical properties especially at low temperatures.Type: GrantFiled: April 24, 1998Date of Patent: June 8, 1999Assignee: Bayer CorporationInventors: Allen R. Padwa, Venkatarayaloo Janarthanan
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Patent number: 5891951Abstract: A polystyrene-based resin composition containing a styrene-based resin with mainly syndiotactic configuration and filler as main components. Styrene-based resins of mainly syndiotactic configuration include polystyrene, poly(alkylstyrene), poly(halogenated styrene), poly(alkoxystyrene), styrene copolymers comprised of polymerized units of at least of styrene, alkylstyrene, halogenated styrene and alkoxystyrene, and mixtures thereof.Type: GrantFiled: June 5, 1995Date of Patent: April 6, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventors: Akikazu Nakano, Takashi Sumitomo, Keisuke Funaki, Toshikazu Ijitsu, Michihiro Sawada, Masahiko Kuramoto, Masakazu Suzuki
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Patent number: 5889111Abstract: Particulate elastomeric graft polymers which are suitable for improving the quality of macromolecular base materials B consist ofa) a grafting core comprising an elastomeric polymer P.sub.K, the particles having a mean particle diameter of from 1 to 150 .mu.m, andb) one or more shells, the outer shell S.sub.a consisting of a polymer P.sub.a which is compatible or partly compatible with the base material B.Type: GrantFiled: June 5, 1997Date of Patent: March 30, 1999Assignee: BASF AktiengesellschaftInventors: Graham Edmund McKee, Ekkehard Jahns, Wolfgang Fischer, Norbert Guntherberg, Bernhard Rosenau
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Patent number: 5889101Abstract: An aqueous polymer emulsion obtainable by free radical polymerization of monomers in aqueous emulsion in the presence of a polymeric protective colloid contains, as components,from 5 to 50% by weight of at least one ethylenically unsaturated monomer having at least one acid or acid anhydride group (monomers I),from 0.1 to 80% by weight of at least one (meth)acrylate of an aliphatic alcohol of at least 10 carbon atoms (monomers II),from 0 to 94.9% by weight of main monomers selected from the group consisting of C.sub.1 -C.sub.8 -alkyl (meth)acrylates, vinyl esters of carboxylic acids of up to 20 carbon atoms, vinyl aromatics of up to 20 carbon atoms, ethylenically unsaturated nitriles, vinyl halides and aliphatic hydrocarbons having 2 to 8 carbon atoms and 1 or 2 double bonds (monomers III) andfrom 0 to 60% by weight of further monomers (monomers IV),the stated weights being based on the polymeric protective colloid.Type: GrantFiled: February 6, 1996Date of Patent: March 30, 1999Assignee: BASF AktiengesellschaftInventors: Bernhard Schlarb, Eberhard Schupp, Maria Gyopar Rau, Gunther Schulz, Harm Wiese
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Patent number: 5886094Abstract: There is provided a thermoplastic resin composition which has damping property, mechanical strength, impact resistance and heat stability resistance in well-balance proportion and has excellent workability, and the composition comprising the following components (A) to (E), in which the ratio by weight of (A)/(B) is from 1/99 to 80/20, the content of the component (C) is from 1 to 50 parts by weight based on 100 parts by weight of the total amount of the components (A) and (B), the content of the component (D) is sufficient amount to compatibilize the components (A) and (B), and the content of the component (E) is from 1 to 120 parts by weight based on 100 parts by weight of the total amount of the components (A) and (B):(A): polyphenylene ether,(B): polyamide,(C): conjugated diene-alkenyl aromatic compound copolymer in which not less than 50% of the conjugated diene compound is polymerized by 1,2-bond or 3,4-bond and the tan .delta. peak temperature thereof is not less than -20.degree. C.Type: GrantFiled: April 9, 1997Date of Patent: March 23, 1999Assignee: Sumitomo Chemical Company, Ltd.Inventors: Takashi Sanada, Mitsuyoshi Shimano
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Patent number: 5886105Abstract: In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 is alkyl of 1 to 32 carbon atoms, a compound (b) of the formula (II) ##STR2## where R.sup.3 is hydrogen or methyl, R.sup.4 is hydrogen or alkyl of 1 to 8 carbon atoms, R.sup.5 is hydrogen or methyl and R.sup.6 is hydrogen or alkyl of 1 to 10 carbon atoms, preferably hydrogen, and, if required, a first monomer (c) or a plurality thereof is polymerized with free radicals to give a rubber (B),in a second stage, the resulting rubber (B) is mixed with a second monomer (d) or with a plurality thereof, preferably dissolved or swollen therein, to form a second mixture (C), andin a third stage, the second mixture (C) formed by mixing is polymerized with free radicals to give the rubber-modified molding material (D).Type: GrantFiled: May 12, 1997Date of Patent: March 23, 1999Assignee: BASF AktiengesellschaftInventors: Graham Edmund Mc Kee, Hermann Gausepohl, Bernhard Rosenau, Walter Heckmann