Mixture Contains Solid Block Or Block-type Copolymer Derived From Ethylenically Unsaturated Hydrocarbon Reactants Only At Least One Of Which Contains At Least Four Carbon Atoms Patents (Class 525/95)
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Patent number: 6558773Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.Type: GrantFiled: August 22, 2001Date of Patent: May 6, 2003Inventor: Gerald Edson
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Publication number: 20030065048Abstract: Radiation curable adhesive comprising an epoxidized block copolymer, a saturated block copolymer and/or a rosin derived alcohol, and a photoinitiator.Type: ApplicationFiled: June 26, 2001Publication date: April 3, 2003Inventor: Charles W. Paul
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Patent number: 6541569Abstract: A polymer alloy and method of making same comprising a block copolymer thermoplastic elastomer comprising a microscopic porosity rapidly plasticized by environmental contaminants and a binder of a polymer or copolymer, the binder binding block copolymer particles while preserving the microscopic porosity and providing a macroscopic porosity to allow fluid penetration. The block copolymer preferably comprises styrene-butadiene-styrene (SBS) triblock copolymer, styrene-butadiene (SB) diblock copolymer, or styrene-isoprene-styrene (SIS) triblock copolymer, or a combination thereof, and the binder preferably comprises styrene-ethylene-butadiene (SEB) terpolymer, ethylene-propylene-diene monomer (EPDM) terpolymer, ethylene-propylene (EPR) copolymer, or styrene-butene butadiene (SBB) terpolymer, or a combination thereof. Most preferably the block copolymer comprises styrene-butadiene-styrene (SBS) triblock copolymer and the binder comprises ethylene-propylene-diene monomer (EPDM) terpolymer.Type: GrantFiled: April 7, 1998Date of Patent: April 1, 2003Assignee: Abtech Industries, Inc.Inventors: James F. Morris, Stephen C. Stelpstra
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Patent number: 6515072Abstract: A transparent rubber-modified styrenic resin composition contains a rubber-particle-dispersed phase (A) and a copolymer matrix (B). The phase (A) contains a rubbery copolymer which is a block copolymer formed from 10 to 50 wt % of styrenic monomers and 90 to 50 wt % of dienic monomers, wherein the rubbery copolymer block contains polystyrene block in an amount of 5 to 35 wt % based on total weight of the rubbery copolymer. The copolymer matrix (B) is composed of 12 to 70 parts by weight of styrenic unit, 20 to 80 parts by weight of (meth)acrylate unit, 1 to 20 parts by weight of vinyl cyanide unit, and 0 to 40 parts by weight of other copolymerizable monomer units, based on 100 parts by weight of total monomer unit. The content of the copolymer matrix (B) having a molecular weight of 3,000˜50,000 is in an amount of 15 to 50 wt %, based on the total weight of the copolymer matrix (B).Type: GrantFiled: December 7, 2000Date of Patent: February 4, 2003Assignee: Chi Mei CorporationInventor: Ray-Hsi Hsu
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Patent number: 6503621Abstract: Pressure sensitive adhesive compositions and articles, wherein the adhesive includes at least one acrylate pressure sensitive adhesive component and at least one thermoplastic elastomer-based pressure sensitive adhesive component. The acrylate component includes at least one polymerized monofunctional (meth)acrylic acid ester monomer having a Tg of no greater than about 0° C. when homopolymerized, and 0 to about 10 wt % of at least one copolymerized monofunctional ethylenically unsaturated monomer having a Tg of at least about 10° C. when homopolymerized. The thermoplastic elastomer-based pressure sensitive adhesive component includes a radial block copolymer.Type: GrantFiled: February 8, 2000Date of Patent: January 7, 2003Assignee: 3M Innovative Properties CompanyInventors: Jingjing Ma, Jeff J. Cernohous, Paul Sedgwick
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Publication number: 20030004266Abstract: The present invention relates to a pressure-sensitive adhesive composition for a surface-protective film, the composition comprising 40% by weight or more of a hydrogenated random copolymer consisting of 1 to 50% by weight of styrene and 99 to 50% by weight of a diene type hydrocarbon and 60% by weight or less of a tackifier resin and/or a softener, and when the pressure-sensitive adhesive composition of the present invention is applied to the surface-protective film, the composition is caused to exhibit excellent adhesion to adherends, not to leave stains of the adherends nor to leave traces thereon when the films are removed from the adherends and can also impart excellent removability to surface-protective films.Type: ApplicationFiled: July 10, 2002Publication date: January 2, 2003Applicant: Nichiban Company, Limited from Yasuaki KITAZAKI, Kinnosuke HINO and Syuji ICHIMURAInventors: Yasuaki Kitazaki, Kinnosuke Hino, Syuji Ichimura
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Patent number: 6495635Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.Type: GrantFiled: May 26, 2000Date of Patent: December 17, 2002Inventor: Gerald E. Edson
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Patent number: 6489042Abstract: An electronic circuit device comprising at least one substrate having a photoimageable covercoat, comprising at least 95 weight percent of at least one epoxy-modified aromatic vinyl-conjugated diene block copolymer and a catalyst comprising an onium salt selected from a triarylsulfonium salt and a diaryliodonium salt, wherein the covercoat is formed by solvent coating or extrusion and then heat laminated onto at least a portion of the substrate.Type: GrantFiled: October 18, 2001Date of Patent: December 3, 2002Assignee: 3M Innovative Properties CompanyInventors: Ronald L. Imken, Robert S. Clough
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Publication number: 20020173380Abstract: The present invention provides a multi-piece solid golf ball having very good shot feel, excellent durability and excellent flight performance. The present invention relates to a multi-piece solid golf ball comprising a core, an inner cover and outer cover, wherein the inner cover has a Shore D hardness of 30 to 62, and is formed from an inner cover composition comprising (a) 50 to 95 parts by weight of ethylene-(meth)acrylic acid copolymer ionomer resin, and (b) 5 to 50 parts by weight of thermoplastic elastomer formed from a polymer alloy of an olefin with a block copolymer having styrene block, based on 100 parts by weight of a base resin; the outer cover is formed from a composition comprising ionomer resin as a main component, and has a Shore D hardness of 58 to 68; and the hardness of the outer cover is higher than that of the inner cover.Type: ApplicationFiled: December 12, 2001Publication date: November 21, 2002Inventors: Keiji Ohama, Seiichiro Endo
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Patent number: 6479584Abstract: The invention provides a resin composition comprising a crosslinking silyl-terminated stellar-structure vinyl polymer or a stellar-structure vinyl block copolymer or chain-extended vinyl block copolymer. The invention provides a method of producing a stellar-structure vinyl block copolymer or chain-extended vinyl block copolymer which comprises forming a block copolymer using living radical polymerization and adding a compound having two or more polymerizable carbon-carbon double bonds at the end point of polymerization of the block copolymer.Type: GrantFiled: August 9, 2001Date of Patent: November 12, 2002Assignee: Kaneka CorporationInventors: Yoshiki Nakagawa, Katsuhiko Kimura, Masayuki Fujita, Kenichi Kitano
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Patent number: 6476131Abstract: A self-reinforced polymeric composition of matter comprising a plurality of hard domains dispersed throughout an elastomeric matrix, wherein the plurality of hard domains are formed by thermodynamic phase separation and crosslinking of at least one thermosettable domain block of a polymeric precursor and are substantially bonded to the elastomeric matrix.Type: GrantFiled: May 16, 2001Date of Patent: November 5, 2002Assignee: The University of AkronInventors: Gary Hamed, Roderic Quirk, Frank Kelley
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Patent number: 6476129Abstract: The present invention relates to a novel thermoplastic elastomer composition with superior oil resistance along with elastomeric flexibility, creep resistance at high temperature, superior mechanical strength and moldability. The composition comprises (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two A polymer blocks comprised mainly of a vinyl aromatic compound and at least one B polymer block comprised mainly of a conjugated diene compound; and (b) 30-300 parts by weight of a partially crosslinked thermoplastic elastomer obtained by polymerizing an acrylate monomer absorbed in a polyolefin. The novel composition can be applied as a material for various molded parts.Type: GrantFiled: May 27, 1998Date of Patent: November 5, 2002Assignees: Asahi Kasei Kogyo Kabushiki Kaisha, Optatech CorporationInventor: Tetsuo Masubuchi
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Publication number: 20020160137Abstract: A thermoplastic elastomer (“TPE”) which is oxygen-permeable is provided with excellent barrier properties against oxygen by melt-blending with a liquid polybutene oil plasticizer in an amount insufficient to render the plasticized elastomer tacky. If made tacky, enough detackifier is used to allow the product to be formed into a removable seal. The TPE may be a conventional thermoplastic vulcanizate or a block copolymer of a vinylaromatic compound, typically styrene, and a conjugated diene, typically butadiene or isoprene, or mixtures thereof; the block may be a diblock, triblock or higher block, but the preferred polyblock copolymer is a triblock with styrene end-blocks and a butadiene/isoprene mid-block. Preferably the diene mid-block is hydrogenated to provide a poly(lower)monoolefin mid-block. When the TPE is a TPV, some or all of the mineral oil used to make the TPV processable may also be substituted with the polybutene plasticizer.Type: ApplicationFiled: February 12, 2002Publication date: October 31, 2002Inventor: Rajesh Kumar Varma
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Patent number: 6461696Abstract: The present invention provides a multiple layer thermoplastic structure of a (1) skin layer selected from the group consisting of polypropylene, ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc, and ethylene homopolymers having a density of from about 0.930 g/cc to about 0.960 g/cc blended with an ethylene and a-olefin copolymers having a density less than about 0.930 g/cc, the skin layer having a thickness of greater than about 3.0 mils; (2) a radio frequency susceptible layer adhered to the skin layer, the radio frequency susceptible layer having a dielectric loss greater than 0.05 at 1-60 MHz and at temperatures of ambient to 250° C.Type: GrantFiled: February 7, 2000Date of Patent: October 8, 2002Assignee: Baxter International Inc.Inventors: Michael T. K. Ling, Lecon Woo, Robert Wojnarowski, Ketan Shah, Gregg Nebgen, Yuan-pang Samuel Ding, Varsha Kalyankar, Keith M. K. Anderson, Lillian G. Zakarija, Colleen S. Cramer, Michael Scharf, Larry A. Rosenbaum
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Patent number: 6462131Abstract: Compatibilized blends of an isobutylene polymer and an unsaturated diene polymer are prepared by utilizing a compatibilizing agent comprising a block/graft copolymer containing polyisobutylene segments and C4 to C6 alkyl-substituted styrene polymer segments, such as poly(t-butylstyrene) segments.Type: GrantFiled: October 16, 2000Date of Patent: October 8, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mun Fu Tse, Hsien Chang Wang, Ramanan Krishnamoorti, Andy H. Tsou
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Patent number: 6448335Abstract: Mixtures of C2-C10 olefin polymers functionalized with carboxylic acids which are neutralized from 1 to 100% with metallic ions The mixtures comprise (by weight): (1) 100 parts of a heterophasic polyolefin composition comprising crystalline polypropylene and an elastomeric fraction of an ethylene/propylene or superior ethylene/&agr;-olefin copolymer where the ethylene content is less than 40%; and (II) 0-250 parts of an elastomeric polymer selected from: a) ethylene/C3-C10 &agr;-olefin copolymers containing at least 20% of a C3-C10 &agr;-olefin; b) ethylene/methyl acrylate copolymers containing from 15 to 30% of recurrent units of methyl acrylate, and having a MFR ranging from 1 to 10 g/10 min; and c) polyisobutylenes; d) atactic propylene homopolymers and amorphous ethylene/C3-C10 &agr;-olefins copolymers produced with metallocenic catalysts; and e) styrene block copolymers containing butadiene and isoprene as comonomer.Type: GrantFiled: March 22, 2000Date of Patent: September 10, 2002Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vittorio Braga, Roberto Bonari
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Patent number: 6447858Abstract: The present invention provides a multilayered pipe for hot water circulation having excellent oxygen barrier properties and anti-crack properties, in particular, excellent anti-crack properties at low temperatures by using a thermoplastic resin composition comprising 50 to 99% by weight of an ethylene-vinyl alcohol copolymer (A) and 1 to 50% by weight of multilayered polymer particles (B).Type: GrantFiled: June 8, 2001Date of Patent: September 10, 2002Assignee: Kuraray Co., Ltd.Inventors: Hiroyuki Shimo, Takashi Yamashita
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Patent number: 6436494Abstract: A polypropylene resin composition capable of bringing about a non-stretched film superior in the transparency, in the impact resistance, in the low temperature heat-sealability and in the strength of heat-sealing, which composition comprises (A) a polypropylene resin, (B) a specific ethylene/&agr;-olefin random copolymer and (C) a specific propylene/ethylene/1 -butene random copolymer.Type: GrantFiled: December 7, 2000Date of Patent: August 20, 2002Assignee: Mitsui Chemicals IncInventors: Yasuo Tanaka, Norihiko Nakagawa, Naoto Yasaka
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Patent number: 6433069Abstract: This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.Type: GrantFiled: June 14, 2000Date of Patent: August 13, 2002Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Susan T. Oeltjen, Jeffrey S. Lindquist, Yoshihiro Kodama, Daisuke Asai
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Publication number: 20020107323Abstract: Disclosed is a transparent polymeric blend, which is readily recyclable several times without any significant deterioration in clarity or transparency of articles produced therefrom, comprising:Type: ApplicationFiled: August 20, 2001Publication date: August 8, 2002Inventors: Andre J. Uzee, L. Frank Wright
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Patent number: 6423367Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: July 27, 2001Date of Patent: July 23, 2002Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Publication number: 20020077420Abstract: To provide a curable composition excellent in flexibility and heat resistance. A curable composition which comprises (A) a block copolymer having at least one kind of block formed from an aliphatic hydrocarbon compound and (B) an isobutylene polymer having a silicon group bound to a hydrolyzable group or a hydroxyl group. That composition can be used as sealants, adhesives, pressure sensitive adhesives, compositions for gaskets, double layer glazing spacers and so on.Type: ApplicationFiled: December 3, 2001Publication date: June 20, 2002Inventors: Makoto Chiba, Shintaro Komitsu
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Publication number: 20020077419Abstract: There is provided a process for the continuous polymerization of polyamides which is carried out under conditions of pressure, temperature and polymer concentration in water that will ultimately yield multiple phases (including a second liquid polymer phase or a polymer precipitate). However, a single phase operation is achieved under these conditions by appropriate management of residence time and using a well-mixed reaction environment in early stages of the polymerization.Type: ApplicationFiled: September 28, 2001Publication date: June 20, 2002Inventors: Jocelyn Willis-Papi, Turget Mutel
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Publication number: 20020072561Abstract: An olefin-based copolymer composition comprising the following component (a) in combination with any one component selected from the following components (b) to (i):Type: ApplicationFiled: February 10, 1999Publication date: June 13, 2002Inventors: HIROFUMI JOHOJI, HIDETAKE HOZUMI, TADAAKI NISHIYAMA
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Patent number: 6403709Abstract: The present invention is directed to a curable, water-based coating composition utilized in waterborne coating systems. The coating composition is the reaction product of a water-based copolymer prepared by free-radical polymerization, and a cross-linking agent. The copolymer is the reaction product of a first block and a second block. The first block is the reaction product of a first ethylenically unsaturated monomer, acrylic acid, and a second ethylenically unsaturated monomer, methyl methacrylate, as wells as the reaction product of a vinylaromatic hydrocarbon monomer, diphenylethylene. The second block is the reaction product of a plurality of ethylenically unsaturated monomers, styrene, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, and carbonate-modified glycidyl methacrylate including a carbonate functional group.Type: GrantFiled: December 22, 2000Date of Patent: June 11, 2002Assignee: BASF CorporationInventors: Swaminathan Ramesh, Paul Lessek, Wolfgang Bremser
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Patent number: 6403705Abstract: The invention concerns molecular rods, their uses in a method for fixing and/or crystallising macromolecules, the resulting products and uses of said products in the field of materials and structural biology, in particular as biosensors or as biomaterials. Said molecular rods have a structure represented by the general formula (I) and said method essentially consists in incubating, for at least 15 minutes, a biological macromolecule in solution with a molecular rod as defined by the formula, in suitable temperature and pH conditions.Type: GrantFiled: February 6, 2001Date of Patent: June 11, 2002Assignees: Commissariat a L'Energie Atomique, Centre National de la Recherche Scientifique-CNRSInventors: Fabrice Balavoine, Charles Mioskowski, Patrick Schultz
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Patent number: 6399696Abstract: There are disclosed a thermoplastic elastomer composition which comprises (a) a hydrogenated block copolymer obtained by hydrogenating the block copolymer comprising at least one polymer block composed principally of a vinylic aromatic compound and at least one polymer block composed principally of a conjugated diene compound; (b) a non-aromatic base softening agent having a kinematic viscosity at 40° C.Type: GrantFiled: February 17, 2000Date of Patent: June 4, 2002Assignee: Bridgestone CorporationInventors: Shinichi Toyosawa, Youichi Nishimuro, Kunio Machida, Takashi Shimizu, Naruhiko Mashita, Yasunori Fukuda, Jun Arai, Yasushi Imai, Tadashi Utsunomiya
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Patent number: 6397848Abstract: A mouthguard composition is disclosed, containing (a) from 40 to 80% by weight of a styrene block copolymer, (b) from 20 to 60% by weight of an alicyclic saturated hydrocarbon resin and/or an ester gum, and (c) from 0.1 to 10% by weight of an organopolysiloxane in which at least one of organic groups directly bound to the silicon atom in one molecule thereof is a phenyl group, a methylstyryl group, or an alkyl group having from 7 to 30 carbon atoms. The mouthguard composition is high in durability and impact absorption and is free from sticking to gypsum model or hands and fingers at the time of preparation and adjustment works.Type: GrantFiled: August 4, 2000Date of Patent: June 4, 2002Assignee: GC CorporationInventors: Hiroyuki Kagekata, Hiroshi Kamohara
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Patent number: 6383586Abstract: An adhesive composition that is specifically formulated for use in packaging medical products such as catheters between a spun-bonded polyolefin non-woven fabric and an ethylene vinyl acetate copolymer film includes from about 5 to about 65 percent by weight of a low density polyethylene; from about 35 to about 90 percent by weight of an ethylene vinyl acetate copolymers; and from about 5 to about 65 percent by weight of a linear block copolymer having at least one vinyl substituted aromatic hydrocarbon polymer block and at least one polyolefin polymer block made from an aliphatic conjugated diene.Type: GrantFiled: November 20, 2000Date of Patent: May 7, 2002Assignee: Oliver Products CompanyInventor: Robert J. Langeland
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Patent number: 6384179Abstract: A polyacetal resin composition comprising 30-90% by weight of polyacetal copolymer (A) having a melt index of less than 1.0 g/10 min. and 70-10% by weight of polyacetal copolymer (B) having a melt index of 1.0-100 g/10 min., both melting points of (A) and (B) being 155°-162° C., or a difference in melting point between (A) and (B) being not less than 6° C., has distinguished toughness and creep resistance.Type: GrantFiled: December 15, 2000Date of Patent: May 7, 2002Assignee: Asahi Kasei Kabushiki KaishaInventors: Noritaka Tanimura, Tadao Matsushika
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Patent number: 6380305Abstract: A polymeric composition is provided which exhibits a combination of high gloss and high environmental stress crack resistance, comprising: (a) high impact polystyrene having a gloss at 60 degrees of greater than 85% and an impact resistance of greater than 0.7 ft-lb/inch, (b) high density polyethylene which has a density greater than or equal to about 0.94 g/cm3, and which has a stress exponent less than or equal to about 1.70; and (c) a compatibilizing polymer for components (a) and (b), selected from the group consisting of diblock styrene butadiene copolymers, triblock styrene butadiene copolymers, diblock styrene isoprene copolymers, triblock styrene isoprene copolymers, and mixtures thereof, wherein the gloss at 60 degrees of the composition is greater than or equal to about 85%, and the environmental stress crack resistance measured in minutes until breakage at 1000 psi is greater than about 60.Type: GrantFiled: December 19, 1997Date of Patent: April 30, 2002Assignee: BASF CorporationInventor: Hrong-Roang Sheu
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Patent number: 6372845Abstract: A blended composition consisting of a thermoplastic olefin resin (Comp. A) with an acrylonitrile-styrene-alkyl acrylate copolymer (Comp. B) was attempted to create substitution for vinyl chloride compound prepared from vinyl chloride resin proper and a plasticizer, but resulted in inferior interdispersibility. Incorporation of an epoxy resin (Comp. C) has brought definite improvement in the interdispersibility. A resinous composition including the components A, B, and C has the utility of substitution for vinyl chloride compounds as well as its products. (Comp. C) is selected from the group consisting of epoxidized diene block copolymers including, in their molecules, a block prepared by polymerization from a vinyl aromatic monomer and another block prepared by polymerization from a conjugated diene monomer, wherein remnant diene groups after the polymerization have been epoxidized or further partially hydrogenated.Type: GrantFiled: October 29, 1999Date of Patent: April 16, 2002Assignee: Daicel Chemical Industries, Ltd.Inventors: Yoshihiro Ohtsuka, Tohru Matsuda, Shizuo Maeda, Kouichi Ishiihara, Yoshikazu Hida
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Patent number: 6346572Abstract: A molding material as based on from 60 to 98% by weight of a hard matrix A comprising polymerized or copolymerized units of at least one vinylaromatic monomer or at least one vinylaromatic monomer and at least one polar comonomer and from 2 to 40% by weight, the percentages in each case being based on the molding material comprising A and B, of a soft phase B formed from a hydrogenated or unhydrogenated block copolymer prepared by anionic polymerization and comprising a vinylaromatic monomer V and a diene D, having at least one random or quasi-random block (V/D) of vinylaromatic monomer and diene and containing from 10 to 80% by weight, based on the soft phase B, of occlusions of matrix material (a) formed during the polymerization of the hard matrix A in the presence of the block rubber, and said molding material is used for the production of films, sheets or moldings.Type: GrantFiled: December 23, 1997Date of Patent: February 12, 2002Assignee: BASF AktiengesellschaftInventors: Wolfgang Loth, Konrad Knoll, Hermann Gausepohl
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Publication number: 20020004571Abstract: Synthetic polymers having moieties capable of covalent or hydrogen bonding to cellulose and one or more amphiphilic moieties are disclosed. These polymers are capable of providing two distinct properties to paper products, such as tissues, which properties heretofore have been imparted through the use of at least two different molecules. The backbone of these synthetic polymers is based on modified vinyl polymers, such as polyvinyl alcohol, polyacrylamides and polyacrylic acids.Type: ApplicationFiled: May 14, 2001Publication date: January 10, 2002Inventors: Wen Zyo Schroeder, Daniel Arthur Clarahan, Mike Thomas Goulet, Thomas Gerard Shannon
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Publication number: 20020004558Abstract: The present invention relates to a novel thermoplastic elastomer composition with superior oil resistance along with elastomeric flexibility, creep resistance at high temperature, superior mechanical strength and moldability. The composition comprises (a) 100 parts by weight of a hydrogenated block copolymer obtained by hydrogenating a block copolymer comprising at least two A polymer blocks comprised mainly of a vinyl aromatic compound and at least one B polymer block comprised mainly of a conjugated diene compound; and (b) 30-300 parts by weight of a partially crosslinked thermoplastic elastomer obtained by polymerizing an acrylate monomer absorbed in a polyolefin. The novel composition can be applied as a material for various molded parts.Type: ApplicationFiled: May 27, 1998Publication date: January 10, 2002Inventor: TETSUO MASUBUCHI
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Publication number: 20020001707Abstract: A low stress relaxation elastomeric material comprises a block copolymer having an elasotmeric soft block portion and thermoplastic hard block portions, at least one vinylarene resin and mineral oil. The elasotmeric material may be used in a film comprising an elastomeric layer and at least one substantially less elastomeric skin layer. The skin layer comprises a thermoplastic polymer such as polyolefins. The film exhibits desired elastic and stress relaxation properties at body temperature. The film is useful in forming a macroscopically-expanded, three-dimensional elastomeric web.Type: ApplicationFiled: June 14, 2001Publication date: January 3, 2002Inventors: John Jianbin Zhang, John Joseph Curro, Michele Ann Mansfield
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Patent number: 6333094Abstract: The present invention relates to a multilayer thermoformable composite synthetic veneer film, furniture parts produced therefrom, and a process for producing the same. The base layer comprising polyolefin has a thickness of 100 to 500 &mgr;m and a particular composition and is composed of at least three different polyolefins. The film also includes at least one intermediate layer in the form of at least one primer layer, bonding layer or bonding film or, respectively, bonding layer; an optional printing layer, coloring layer or color-printing layer arranged over part or all of the surface; at least one polyester-containing single- or multiple-layer-structure layer or film; at least one bonding layer, adhesion-promoting layer or reactant layer on the side of the base layer that is to be applied to a substrate; and a surface-covering layer on the top of the film.Type: GrantFiled: September 17, 1999Date of Patent: December 25, 2001Assignee: Alkor GmbH KunststoffeInventors: Manfred Schneider, Egon Ewald
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Patent number: 6333374Abstract: Novel fluffy, solid, strong elastic gels exhibiting resistance to elastic deformation, capable of shape-memory recovery, being dimensionally stable and having a density of at least less than about 0.60 g/cm3, a gel rigidity of from about 20 to about 3,000 gram Bloom, and an elongation of at least 200% can be formed with or physically interlocked with selected material substrates to form composites including any sequential additions or permutations of said combinations of gels and substrates.Type: GrantFiled: October 20, 1997Date of Patent: December 25, 2001Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Publication number: 20010039310Abstract: A high-damping elastomer composition comprises a styrene-isoprene-styrene triblock copolymer (component A) and a ethylene-methyl methacrylate random copolymer (component B). In the high-damping elastomer composition of the present invention, the styrene-isoprene-styrene triblock copolymer (component A) and the ethylene-methyl methacrylate random copolymer (component B) form a so-called “islands-in-the-sea” structure which may vary depending on the blending ratio therebetween. The components A and B are partially compatibilized with each other in a homogeneously mixed state in sea-island interfaces.Type: ApplicationFiled: March 14, 2001Publication date: November 8, 2001Inventors: Takeshi Nomura, Kazunobu Hashimoto
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Patent number: 6306972Abstract: A polypropylene-based resin composition comprising: (1) 95 to 50% by weight of a polypropylene-based resin (A) of a mixture of the following (i) and (ii); (i) a crystalline propylene-ethylene block copolymer comprising a propylene homopolymer portion as a first segment and a propylene-ethylene random copolymer as a second segment, said propylene-ethylene block copolymer having a melt flow rate at 230° C. measured according to JIS-K-6758 of not less than 25 g/10 min., and (ii) a crystalline propylene homopolymer having a melt flow rate at 230° C. measured according to JIS-K-6758 of not less than 70 g/10 min.Type: GrantFiled: May 15, 1998Date of Patent: October 23, 2001Assignee: Sumitomo Chemical Company, LimitedInventors: Kenichi Ohkawa, Shin-ichi Kondo, Moriyasu Shimojo
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Patent number: 6303200Abstract: A steam sterilizable monolayer medical tubing comprising a blend of a melt strength enhancing agent of a homopolymer or copolymer of polypropylene having free-end long chain branches of propylene units, a melt flow index of greater than 10 and in an amount of 1-10% by weight and a second component selected from the group of (i) a selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene and (ii) a selectively hydrogenated block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene to which has been grafted, an alpha, beta-olenfically unsaturated monocarboxylic or dicarboxylic acid reagent.Type: GrantFiled: January 27, 1998Date of Patent: October 16, 2001Assignee: Baxter International Inc.Inventors: Lecon Woo, Michael T. K. Ling, Patrick Balteau, Ying-Cheng Lo, Ketan Shah, Hénaut J. Eric, Yuan-pang Samuel Ding, Stanley Westphal, Robert Wojnarowski
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Patent number: 6294270Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: December 23, 1998Date of Patent: September 25, 2001Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Patent number: 6291583Abstract: An aromatic vinyl compound-isoprene block copolymer composition comprising (i) 5-50 wt. % a branched copolymer of the formula: (A-B)nX wherein A is a polymer block of an aromatic vinyl monomer, B is a polymer block of isoprene, and X is a residue of a polyfunctional coupling agent, and (ii) 50-95 wt. % of a diblock copolymer of the formula: A-B wherein A and B are as defined above. This copolymer composition is produced by allowing an aromatic vinyl monomer to contact with an organic lithium initiator to prepare a polymer block A; incorporating isoprene thereto to prepare a diblock copolymer A-B; and then, adding a polyfunctional coupling agent to convert a part of the diblock copolymer A-B to the branched copolymer (A-B)nX. This block copolymer composition is useful for an adhesive or pressure sensitive adhesive composition.Type: GrantFiled: April 30, 1999Date of Patent: September 18, 2001Assignee: Nippon Zeon Co., Ltd.Inventors: Shigeru Komatsuzaki, Hidemi Tsubaki, Tetsuaki Matsubara
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Publication number: 20010021430Abstract: A medical tubing having rigidity, flexibility, transparency and heat resistance and, additionally, acceptable flexural modulus and tensile strength and further having no stickiness between surfaces of the tubing is provided. The medical tubing is composed of a resin composition containing a low-density ethylene/&agr;-olefin copolymer having a density of 0.860-0.900 g/cm3 polymerized with a metallocene catalyst and a styrene/ethylene-butylene/olefin block copolymer.Type: ApplicationFiled: January 8, 2001Publication date: September 13, 2001Inventor: Mamoru Shimada
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Publication number: 20010018490Abstract: There are disclosed a resin composition which is excellent in rubber elasticity, oil maintainability and adhesivity to a metal, and comprises a thermoplastic elastomer composition comprising a (a1) hydrogenated block copolymer which is obtained by hydrogenating a block copolymer consisting essentially of a polymer block composed principally of a vinyl aromatic compound and a polymer block composed principally of a conjugated diene compound, which has a weight average molecular weight of at least 200,000, in which the polymer block composed principally of a vinyl aromatic compound is polystyrene, and in which the content by weight of the polystyrene moiety contained in the hydrogenated block copolymer is 20 to 40% ; a (b1) non-aromatic rubber-softening agent having a kinematic viscosity at 40° C.Type: ApplicationFiled: February 14, 2001Publication date: August 30, 2001Inventors: Naruhiko Mashita, Shinichi Toyosawa, Youichi Nishimuro, Yasushi Imai, Tadashi Utsunomiya, Ichiro Akasaka, Youkou Saito
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Patent number: 6277916Abstract: This invention includes a process for forming a thermoplastic vulcanizate comprising: (a) admixing a C—H insertion curing agent with at least one elastomeric phase polymer to form a first admixture; (b) admixing at least one non-elastomeric polyolefin with the first admixture to form a second admixture; and (c) heating the second admixture to a temperature at least the decomposition temperature of the curing agent to crosslink the elastomeric phase while mixing the admixture to an extent sufficient to result in the formation of a thermoplastic material, hereinafter referred to as a thermoplastic vulcanizate, and optionally including an additional step (d) of shaping the resulting thermoplastic vulcanizate, especially by heating and foaming or molding the TPV.Type: GrantFiled: February 25, 1999Date of Patent: August 21, 2001Assignee: The Dow Chemical CompanyInventors: Robert H. Terbrueggen, Ray E. Drumright, Thoi H. Ho
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Patent number: 6261655Abstract: A multiple layer structure comprising a skin layer composed of a polypropylene copolymer with styrene ethylene-butene styrene block copolymer within a range of 0-20% by weight skin layer, and, a radio frequency (“RF”) susceptible layer adhered to the skin layer. The RF layer has a first component of a propylene based polymer, a second component of a nonpropylene polyolefin, a third component of a radio frequency susceptible polymer, and a fourth component of a polymeric compatibilizing agent wherein the radio frequency susceptible polymer is selected from the group consisting of ethylene acrylic acid copolymers, ethylene methacrylic acid copolymers, polyimides, polyurethanes, polyesters, and polyureas.Type: GrantFiled: June 17, 1999Date of Patent: July 17, 2001Assignee: Baxter International Inc.Inventors: Larry A. Rosenbaum, William Anderson, Lecon Woo, Dean Laurin, Angeles Lillian Buan, Michael T. K. Ling, Yuan Pang Samuel Ding, Denise S. Hayward, Joseph P. Hoppesch, Gregg Nebgen, Stanley Westphal
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Patent number: 6262175Abstract: A thermoplastic elastomer composition containing in percentages by weight based on the total weight of the composition, about 5% to about 90% vulcanized rubber crumb; about 5% to about 60% polyolefin; about 2% to about 30% uncured rubber or styrene-based thermoplastic elastomer; and about 2% to about 30% vinyl polymer selected from vinyl homopolymers, copolymers and mixtures. The composition in total contains less than 15% styrene block copolymer.Type: GrantFiled: May 1, 1998Date of Patent: July 17, 2001Assignee: NRI Technology Inc.Inventors: James R. Jury, Alfred Wing Yan Chien
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Publication number: 20010003769Abstract: A rubber-modified styrene type polymer excellent in transparency and excellent in impact strength and moldability, is presented.Type: ApplicationFiled: December 20, 2000Publication date: June 14, 2001Applicant: DENKI KAGAKU KOGYO KABUSHIKI KAISHAInventors: Takeshi Yamada, Tetsuya Shinmura
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Patent number: 6242532Abstract: A blend composition including from about 1 to about 99 weight percent syndiotactic polypropylene (sPP) and from about 99 to about 1 weight percent styrene-butadiene-styrene block copolymer (SBS) and olefin elastomer, based on the weight of the sPP, SBS and olefin elastomer. A method of making the composition includes contacting the sPP, SBS and olefin elastomer at a temperature above the melting point of the sPP and olefin elastomer, with useful articles formed therefrom.Type: GrantFiled: July 27, 1998Date of Patent: June 5, 2001Assignee: Fina Technology, Inc.Inventors: Alan S. Baumgartner, Robert H. Burr