With Solid Polymer Derived From Reactant Containing Plural Unsaturation Patents (Class 525/99)
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Patent number: 7119146Abstract: Compatibilized blends of an isoolefin polymer and an unsaturated diene polymer are prepared by utilizing a compatibilizing agent comprising a block/graft copolymer containing poly- or copoly-isoolefin segments and C4 to C6 alkyl-substituted styrene polymer segments, such as poly(t-butylstyrene) segments.Type: GrantFiled: August 19, 2002Date of Patent: October 10, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Mun Fu Tse, Hsien Chang Wang, Ramanan Krishnamoorti, Andy H. Tsou
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Patent number: 7090924Abstract: This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as the prepregs, laminates and composites made from the thermosetting resin composition.Type: GrantFiled: December 4, 2002Date of Patent: August 15, 2006Assignee: Isola USA Corp.Inventors: Jyoti Sharma, Martin Choate, Steve Peters, Kevin Rafferty
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Patent number: 7081499Abstract: An electrical insulating material for use in electrical insulators, for example, for insulated electric wires such as internal wiring of electronic equipment, automobiles or the like, electrical insulating covers produced from the electrical insulating material and a method of electrical insulation using the material are provided. More particularly, it relates to an electrical insulating material which is excellent in mechanical properties and durability, an electrical insulating cover produced from the material and a method of electrical insulation using the material.Type: GrantFiled: April 4, 2002Date of Patent: July 25, 2006Assignee: Toyo Boseki Kabushiki KaishaInventors: Naomi Matsumoto, Hitoshi Ueno, Yasuhiro Nishihara, Hirota Nagano
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Patent number: 7081498Abstract: The present invention is directed to pressure-sensitive adhesive compositions and pressure-sensitive adhesive constructions fabricated using the pressure-sensitive adhesive compositions. The pressure-sensitive adhesive compositions comprise about 10 to about 40% of a styrene-isoprene block copolymer, about 5 to about 30% of a styrene-butadiene block copolymer, about 30 to about 65% of an aromatically modified tackifying resin, about 8 to about 30% of a plasticizing oil and optionally about 0.2 to about 2% of an antioxidant, wherein the percentages are based on the total weight of the composition.Type: GrantFiled: April 8, 2004Date of Patent: July 25, 2006Assignee: Morgan Adhesives CompanyInventors: Scott Allen Moeller, Gary A. McMaster, Timothy Smith
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Patent number: 7056971Abstract: A thermoplastic elastomer (“TPE”) which is oxygen-permeable is provided with excellent barrier properties against oxygen by melt-blending with a liquid polyisobutene oil plasticizer in an amount insufficient to render the plasticized elastomer tacky. If made tacky, enough detackifier is used to allow the product to be formed into a removable seal. The TPE may be a conventional thermoplastic vulcanizate or a block copolymer of a vinylaromatic compound, typically styrene, and a conjugated diene, typically butadiene or isoprene, or mixtures thereof; the block may be a diblock, triblock or higher block, but the preferred polyblock copolymer is a triblock with styrene end-blocks and a butadiene/isoprene mid-block. Preferably the diene mid-block is hydrogenated to provide a poly(lower)monoolefin mid-block. When the TPE is a TPV, some or all of the mineral oil used to make the TPV processable may also be substituted with the polyisobutene plasticizer.Type: GrantFiled: February 12, 2002Date of Patent: June 6, 2006Assignee: GLS CorporationInventor: Rajesh Kumar Varma
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Patent number: 7015284Abstract: The present invention relates to a soft thermoplastic elastomer composition that is free of thermoplastic resin that can be utilized in manufacturing shoe sole inserts, seals, gaskets, wheels, and that can be overmolded on a hard substrate, such as a metal or a thermoplastic resin, for grips or handles on various household items.Type: GrantFiled: February 25, 2004Date of Patent: March 21, 2006Assignees: The Goodyear Tire & Rubber Company, GLS CorporationInventors: Manoj Ajbani, Christopher Kiehl, Lawson Gibson Wideman, Rajesh Varma
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Patent number: 6939906Abstract: Disclosed is a block copolymer composition comprising a block copolymer (I) comprising at least two polymer blocks (each polymer block (S) comprising vinyl aromatic hydrocarbon monomer units) and at least one polymer block (B) comprising isoprene monomer units and 1,3-butadiene monomer units, and a polystyrene resin (II), wherein, in the block copolymer (I), the amount of the vinyl aromatic hydrocarbon monomer units, the total amount of the isoprene monomer units and the 1,3-butadiene monomer units, and the isoprene monomer unit/1,3-butadiene monomer unit weight ratio are within specific range, wherein the block copolymer (I) has a vinyl aromatic hydrocarbon block ratio (BL) within a specific range, and wherein the block copolymer (I) and the polystyrene resin (II) satisfy a relationship represented by the following formula (1): 15+0.25BL?Wa?35+0.Type: GrantFiled: August 31, 2001Date of Patent: September 6, 2005Assignee: Asahi Kasei Kabushiki KaishaInventors: Susumu Hoshi, Yukio Yamaura, Junko Kakegawa
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Patent number: 6933344Abstract: Thermoplastic elastomeric compositions and processes for preparing the compositions comprising a blend of polypropylene, styrene-ethylene butylene-styrene copolymer, ethylene-propylene-diene monomer elastomer, linear low density polyethylene, peroxide crosslinking agent and a crosslinking coagent. The peroxide crosslinking agent and crosslinking coagent provide a crosslinking system. The compositions improve melt strength and increase resistance to flow and tear. The composition may further comprise mineral oil, antioxidant, colorant, a processing aid and stabilizer and mixtures thereof. The processes for preparing thermoplastic elastomeric compositions are particularly useful in microcellular injection molding to form articles with improved surface characteristics.Type: GrantFiled: September 16, 2002Date of Patent: August 23, 2005Assignee: Delphi Technologies, Inc.Inventors: Suresh Deepchand Shah, Michael William Jary, Ismat Ali Abu-Isa
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Patent number: 6930146Abstract: A polymer composition and a thermoplastic elastomer composition containing 1,2-polybutadiene having a 1,2-bond content in the butadiene unit of 70% by weight or more, a melting point in the range of 50 to 140° C., a total halogen content of 30 ppm or less, a viscosity ? in the range of 400 to 1200 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 120° C., a viscosity ? in the range of 300 to 1000 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 150° C., and a viscosity ? in the range of 200 to 800 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 180° C. exhibit excellent moldability, visual appearance and scratch resistance.Type: GrantFiled: July 27, 2000Date of Patent: August 16, 2005Assignee: JSR CorporationInventors: Koji Okada, Masato Suzuki, Junji Kojina
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Patent number: 6927255Abstract: A rubber composition comprising (i) an incompatible polymer blend of at least two diene rubbers selected from rubbers containing a conjugated diene and, optionally, an aromatic vinyl monomer and forming two polymer phases (A) and (B), and (ii) 0.1 to 20 parts by weight, based upon 100 parts by weight of the total polymer component including the block copolymer, of a block copolymer having at least two mutually incompatible blocks (a) and (b), wherein the block (a) is compatible with the polymer phase (A) and incompatible with the polymer phase (B) and the block (b) is compatible with the polymer phase (B) and incompatible with the polymer phase (A), and composed of a conjugated diene and, optionally, an aromatic vinyl monomer, and wherein the molecular weights of the polymers forming the polymer phases (A) and (B) satisfy the specified equations (I) and (II) mentioned in the specification.Type: GrantFiled: February 18, 2000Date of Patent: August 9, 2005Assignees: The Yokohama Rubber Co., Ltd., Nippon Zeon Co., Ltd.Inventors: Tetsuji Kawazura, Masayuki Kawazoe, Masao Nakamura
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Patent number: 6914091Abstract: Flexible hydrogenated block copolymers can be successfully used in a variety of applications including films, profiles, sheets, coatings, injection molded articles, blow or rotational molded articles and pultruded articles.Type: GrantFiled: November 25, 2002Date of Patent: July 5, 2005Assignee: The Dow Chemical CompanyInventors: Robert J. Donald, Stephen F. Hahn, James E. Pate, III
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Patent number: 6861472Abstract: A thermoplastic composition includes specified amounts of a poly(arylene ether), a homopolymer of an alkenyl aromatic monomer, a polyolefin, a hydrogenated block copolymer, and an unhydrogenated block copolymer, but the composition is substantially free of any rubber-modified poly(alkenyl aromatic) resin. The composition provides high stiffness and high impact strength and is suitable for molding a variety of articles, including automotive underhood components.Type: GrantFiled: November 1, 2001Date of Patent: March 1, 2005Assignee: General Electric CompanyInventors: Adeyinka Adedeji, Thomas J. Hartle, John C. Haylock
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Patent number: 6855767Abstract: A thermoplastic composition includes a poly(arylene ether), a poly(alkenyl aromatic) resin, a polyolefin, a hydrogenated block copolymer of alkenyl aromatic compound and a conjugated diene having an alkenyl aromatic content of about 40 to about 90 weight percent, and an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene. The composition exhibits excellent stiffness-impact strength balance, low property variability, and long melt hang time.Type: GrantFiled: November 1, 2001Date of Patent: February 15, 2005Assignee: General ElectricInventors: Adeyinka Adedeji, David R. Lamb, Vincent L. Lanning, Thomas J. Hartle, John C. Haylock
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Patent number: 6849690Abstract: The present invention relates to a method of preparing rubber-modified styrene copolymer resin with excellent transparency and impact resistance, specifically to a method of preparing transparent resin of rubber-modified styrene copolymer comprising graft-copolymerizing styrene monomer and (meth)acrylate monomer in the presence of block or random styrene-butadiene copolymer which has 30-50% of styrene skeleton content and 20-40 cp of 5% toluene solution viscosity at 25 iÉ. According to the method of the present invention, the transparent resin containing the rubber particles of a double structure comprising onion and core-shell structure can provide transparent resin of rubber-modified styrene copolymer resin with excellent transparency and impact resistance as well as good gloss.Type: GrantFiled: December 12, 2001Date of Patent: February 1, 2005Assignee: LG Chem, Ltd.Inventors: Chang-Hun Han, Oh-Jin Kwon, Dae-Woo Lee
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Patent number: 6846877Abstract: An olefinic thermoplastic vulcanizate is blended with a rubber-modified monovinylidene aromatic monomer, utilizing a flexible block copolymer as compatabilizing agent. The resulting composition demonstrates improved miscibility and bonding characteristics and increased hardness not previously achievable using unmodified thermoplastic vulcanizates.Type: GrantFiled: December 26, 2002Date of Patent: January 25, 2005Assignee: Advanced Elastomer Systems, L.P.Inventors: Sunny Jacob, Kathleen Perevosnik, Joseph E. Pfeiffer
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Patent number: 6844383Abstract: Disclosed is a block copolymer comprising at least two S polymer blocks comprising vinyl aromatic hydrocarbon monomer units, and one B polymer block or two or more B polymer blocks which contains or collectively contain isoprene monomer units and 1,3-butadiene monomer units, wherein the amount of the vinyl aromatic hydrocarbon monomer units and the total amount of the isoprene monomer units and the 1,3-butadiene monomer units are, respectively, from 60 to 95% by weight and from 40 to 5% by weight, each based on the weight of the copolymer, wherein the isoprene monomer unit/1,3-butadiene monomer unit weight ratio is from 45/55 to 97/3, and wherein the vinyl aromatic hydrocarbon monomer unit moiety of the copolymer has a short segment ratio of from 0 to 30% by weight, which is defined as the weight percentage, based on the total weight of vinyl aromatic hydrocarbon monomer units in the copolymer, of the vinyl aromatic hydrocarbon monomer units in at least one short segment consisting of 1 to 3 vinyl aromatic hyType: GrantFiled: May 25, 2001Date of Patent: January 18, 2005Assignee: Asahi Kasei Kabushiki KaishaInventors: Susumu Hoshi, Yukio Yamaura, Junko Kakegawa, Tsutomu Sugimoto
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Patent number: 6828379Abstract: The invention relates to curable resin compositions based on an unsaturated prepolymer, a vinyl ether monomer that can be cross-linked with it and one or more other monomers for use as structural resins. The resin composition is cured with the aid of a radical-forming system that is unstable in the temperature range of −20° C. to +110° C., and contains an unsaturated prepolymer having an acid number of less than 10 mg of KOH per g and a vinyl ether monomer according to formula (I) or (II): A—CH═CH—O—R (I) or (A—CH═CH—O)n—R′ (II) with A, R, R′ and n having the described meanings. The invention also relates to a process for the preparation of such resin compositions and uses thereof.Type: GrantFiled: December 19, 2001Date of Patent: December 7, 2004Assignee: DSM IP Assets B.V.Inventors: Jan H. Udding, Agnes E. Wolters
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Publication number: 20040242775Abstract: The invention provides an elastomer composition which comprises 33.5 to 95% by weight of an aromatic vinyl-isoprene block copolymer (a) having two or more poly(aromatic vinyl) blocks, 0 to 47.5% by weight of an aromatic vinyl-isoprene diblock copolymer (b), and 5 to 33% by weight of polyisoprene (c) having a weight average molecular weight of 20,000 to 100,000, and which has a content of aromatic vinyl monomer unit of 14 to 50% by weight based on the total amount of the components (a), (b) and (c). The invention further provides a pressure-sensitive adhesive composition comprising the elastomer composition and a tackifier resin.Type: ApplicationFiled: February 26, 2004Publication date: December 2, 2004Inventors: Takeshi Tahara, Takeshi Kawanabe
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Publication number: 20040236020Abstract: Provided are a block copolymer including a polymer block containing acrylonitrile or methacrylonitrile as a principal constituent, which is excellent in heat resistance, weatherability, oil resistance, flame retardancy, and low-temperature resistance and which can be economically produced; and a thermoplastic resin composition and an elastomer composition each containing the block copolymer. The block copolymer is produced by reversible addition-fragmentation chain transfer polymerization in the presence of a thiocarbonylthio group-containing compound.Type: ApplicationFiled: January 7, 2004Publication date: November 25, 2004Inventors: Ryotaro Tsuji, Tomoki Hiiro
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Publication number: 20040229986Abstract: Various elastomer materials, cushioning devices, materials for making cushioning elements, and manufacturing techniques are disclosed.Type: ApplicationFiled: February 20, 2004Publication date: November 18, 2004Inventor: Tony M. Pearce
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Publication number: 20040225061Abstract: An elastomer composition is prepared that contains a rubber component (A) containing at least one of diene rubber and EPDM rubber; a mixture composition (B) containing hydrogenated styrene thermoplastic elastomer and olefin resin; and a styrene thermoplastic elastomer (C) having double bonds partly left, wherein the styrene thermoplastic elastomer (C) is blended at a ratio of not less than 2 parts by weight and not more than 100 parts by weight with respect to 200 parts by weight of the mixture composition (B), and the rubber component (A) is dispersed by dynamic crosslinking in the mixture composition (B) having the styrene thermoplastic elastomer (C) dispersed therein. A rubber roller is formed by using the elastomer composition. The elastomer composition is excellent in wear resistance, and the rubber roller made of the elastomer composition is excellent in wear resistance at the time of idling rotation.Type: ApplicationFiled: May 6, 2004Publication date: November 11, 2004Inventors: Mutsuki Sugimoto, Hideyuki Okuyama
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Patent number: 6797766Abstract: This invention relates to high bonding hot melt adhesive compositions comprising a high molecular weight polystyrene-ethylene/butylene-polystyrene (SEBS) block copolymer as the basic ingredient and articles constructed therefrom. This polymer is useful in a variety of hot melt adhesive applications for consumer product articles subject to hostile use environments such as toys and other play things.Type: GrantFiled: December 31, 2001Date of Patent: September 28, 2004Assignee: Mattel, Inc.Inventor: Abimael Cordova
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Publication number: 20040167279Abstract: A process for increasing the stress-cracking resistance of polystyrene molding compositions, stress-cracking-resistant, glossy polystyrene molding compositions, composite layered sheets or composite layered films with an outer layer of this type, and also processes for producing moldings for refrigeration equipment.Type: ApplicationFiled: January 20, 2004Publication date: August 26, 2004Inventors: Daniel Wagner, Peter Weinkotz, Herbert Morgenstern, Hans-Jurgen Renner
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Publication number: 20040167281Abstract: A rubber composition comprising (1) a diene rubber, (2) a highly saturated rubber, and (3) a block copolymer that comprises a diene polymer block A and a hydrogenated diene polymer block B and has a primary structure selected from the following structures:Type: ApplicationFiled: December 15, 2003Publication date: August 26, 2004Inventors: Hideo Takamatsu, Mizuho Maeda, Koji Kitayama, Tsutomu Yamada, Hiroshi Kanbara
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Patent number: 6777082Abstract: The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.Type: GrantFiled: December 6, 2001Date of Patent: August 17, 2004Assignee: The Dow Chemical CompanyInventors: Rajen M. Patel, Pak-Wing S. Chum, Stephen F. Hahn, Leonie K. Walsh, Rexford A. Maugans, Selim Bensason, Thoi H. Ho, Calvin P. Esneault
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Patent number: 6764761Abstract: A method, system and apparatus for performing peritoneal dialysis are provided. To this end, in part, a film is provided. The film includes a layer of a polymer blend having from about 90% to about 99% by weight of a first component containing a styrene and hydrocarbon copolymer and from about 10% to about 1% of a high melt strength polypropylene.Type: GrantFiled: May 24, 2002Date of Patent: July 20, 2004Assignee: Baxter International Inc.Inventors: Bruce Ming-Da Eu, Sherwin Shang, Tahua Yang, Michael T. K. Ling, Loren M. Lundtveit
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Patent number: 6762218Abstract: Thermoplastic molding compositions comprising, as substantive constituents, A) from 5 to 96% by weight of a vinylaromatic polymer with a syndiotactic structure, B) from 2 to 50% by weight of an inorganic filler, C) from 1 to 15% by weight of a thermoplastic elastomer based on copolymers made from vinylaromatic monomers, dienes and, where appropriate, 1,1-diphenylethylene, D) from 1 to 10% by weight of a compatibilizer, and, where appropriate, E) from 1 to 15% by weight of an elastomeric particulate styrene-diene block copolymer whose diene content may have been completely or to some extent hydrogenated, and, where appropriate, F) additives, where the total of the percentages by weight of A) to F) is 100.Type: GrantFiled: October 3, 2002Date of Patent: July 13, 2004Assignee: BASF AktiengesellschaftInventors: Michael Geprägs, Konrad Knoll
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Publication number: 20040127644Abstract: An olefinic thermoplastic vulcanizate is blended with a rubber-modified monovinylidene aromatic monomer, utilizing a flexible block copolymer as compatabilizing agent. The resulting composition demonstrates improved miscibility and bonding characteristics and increased hardness not previously achievable using unmodified thermoplastic vulcanizates.Type: ApplicationFiled: December 26, 2002Publication date: July 1, 2004Inventors: Sunny Jacob, Kathleen Perevosnik, Joseph E. Pfeiffer
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Publication number: 20040127643Abstract: A thermoplastic vulcanizate prepared by dynamically vulcanizing a halogenated butyl rubber within a mixture that includes the halogenated butyl rubber and from about 10 to about 100 parts by weight of a crystalline thermoplastic resin per 100 parts by weight rubber, to thereby form a thermoplastic vulcanizate, where the thermoplastic resin includes a resin other than polyethylene, melt mixing the thermoplastic vulcanizate with about 5 to about 75 parts by weight of polyethylene resin per 100 parts by weight rubber, from about 3 to about 60 parts by weight of a tackifier per 100 parts by weight rubber, and from about 5 to about 250 parts by weight of a block copolymer containing at least the structure S-B/S-S per 100 parts by weight rubber, where the S block of the block copolymer has a glass transition temperature above about 25° C., the B/S block has a glass transition temperature below about 25° C.Type: ApplicationFiled: December 26, 2002Publication date: July 1, 2004Inventors: Kathleen A. Perevosnik, Sunny Jacob, William Gary Stevenson, Curtis Waddle
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Patent number: 6756106Abstract: An oil resistant, elastomeric rubber composite, particularly suited for use as an elastic tape for garments requiring a high degree of oil resistance due to conditions of its use. The rubber composite is made from a unique blend of nitrile rubber, polychloroprene (neoprene), epoxidised natural rubber and natural rubber. The elastomeric composite has excellent compatibility between two rubbers of different polarity when properly compounded and processed. The composite formed as an elastic tape has a low modulus of elasticity, good needle tear strength when sewn inside a garment, and it provides a comfortable fit for long use in addition to having reduced oil swell and oil abosorption characteristics. Elastic tapes made from the elastomeric rubber composite are particularly suitable for swimwear, shower caps, head bands, face masks and other garments with direct skin contact.Type: GrantFiled: October 15, 2002Date of Patent: June 29, 2004Assignee: Garware Elastomerics LimitedInventor: Ramesh Manjanath Telang
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Publication number: 20040116601Abstract: Thermoplastic elastomers, such as styrene-poly(ethylene-propylene)-styrene (SEPS) and styrene-poly(ethylene-butylene)-styrene (SEBS), have a tendency to undergo homolytic cleavage on mixing, particularly when extended mixing times are employed. Such thermoplastic elastomers are protected by addition of a polymer with multiple reactive sites, such as polybutadiene. The polymer reacts with two or more of the cleaved fragments forming a copolymer which regains much of the original character of the thermoplastic elastomer.Type: ApplicationFiled: December 11, 2002Publication date: June 17, 2004Applicant: BFS Diversified Products, LLCInventor: James E. Hall
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Patent number: 6747095Abstract: An objective of the invention is to provide a rubber composition which has satisfactory processability and dimension stability, and the like, gives a vulcanized rubber exhibiting excellent wearing resistance and tensile strength, and the like, and thus is useful in a belt, a hose and a tire and the like, as well as a crosslinked rubber particle for obtaining such rubber composition. A rubber composition of the invention comprises [1] a crosslinked rubber particle comprising as repeating units (a) 30 to 94.89% by weight of a conjugated diene unit, (b) 5 to 69.89% by weight of an aromatic vinyl unit, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group, (d) one polymerizable unsaturated group and an amino group, a hydroxyl group and an epoxy group and (e) 0.Type: GrantFiled: April 26, 2001Date of Patent: June 8, 2004Assignee: JSR CorporationInventors: Tomohisa Konno, Toshihiro Tadaki, Yoshiyuki Udagawa, Hiroshi Akema
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Patent number: 6743860Abstract: The present invention relates to a thermoplastic resin composition comprising (a) 100 parts by weight of a block copolymer comprising at least two polymeric blocks A composed mainly of a vinyl aromatic compound and at least one polymeric block B composed mainly of a conjugated diene compound, or a hydrogenated block copolymer thereof, (d) 5 to 50 parts by weight of an organic peroxide, and (e) 10 to 80 parts by weight of one or more substances selected from the group consisting of multifunctional vinyl compounds and multifunctional (meth)acrylate compounds. The present invention provides a master batch of an organic peroxide in which the organic peroxide is so uniformly dispersed in a thermoplastic resin that crosslinking and/or decomposition occur uniformly, a method of preparing the same, a thermoplastic resin composition obtained using the master batch and a method of preparing the same.Type: GrantFiled: August 2, 2002Date of Patent: June 1, 2004Assignee: Riken Technos CorporationInventor: Hiroki Mizuno
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Publication number: 20040082719Abstract: A poly(arylene ether)-polyolefin composition is prepared by melt-blending a poly(arylene ether), a poly(alkenyl aromatic) resin, a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene to form a first blend, and melt-blending the first blend and a polyolefin and additional hydrogenated block copolymer to form a second blend. A reinforcing filler and/or an ethylene/alpha-olefin elastomeric copolymer may, optionally, be added during formation of the second blend or in an additional step. Multiple mixing elements, low throughput, and high extruder rotations per minute may be used to achieve high energy mixing of the first and second blends. Compositions prepared by the method exhibit an improved balance of impact strength, stiffness, and heat resistance, as well as reduced variability of physical properties.Type: ApplicationFiled: July 10, 2003Publication date: April 29, 2004Inventors: Adeyinka Adedeji, John C. Haylock, Robert Hossan, William Eugene Pecak, Mark Victor Vendon
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Patent number: 6723791Abstract: An oil-sorbent composition of matter has bound combinations of styrene-butadiene-styrene (SBS) and ethylene propylene diene monomer (EPDM). The SBS, or both materials, may be in the form of multitudes of granules. In certain preferred embodiments, the combination is 10-30% by weight and the SBS is about 30% styrene and manufactured without talc. The composition of matter can be formed into a solid, compliant body and utilized in a product for absorbing oil. The body can be formed, in one preferred embodiment, into an extended cylinder having an axial hole.Type: GrantFiled: December 31, 2001Date of Patent: April 20, 2004Assignee: Abtech Industries, Inc.Inventors: Glenn R. Rink, James F. Morris, Stephen C. Stelpstra, Robert L. Rosania, Jan R. Hegeman, Peter A. Allen
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Publication number: 20040048982Abstract: The present invention relates to a method of preparing rubber-modified styrene copolymer resin with excellent transparency and impact resistance, specifically to a method of preparing transparent resin of rubber-modified styrene copolymer comprising graft-copolymerizing styrene monomer and (meth)acrylate monomer in the presence of block or random styrene-butadiene copolymer which has 30-50% of styrene skeleton content and 20-40 cp of 5% toluene solution viscosity at 25 ié. According to the method of the present invention, the transparent resin containing the rubber particles of a double structure comprising onion and core-shell structure can provide transparent resin of rubber-modified styrene copolymer resin with excellent transparency and impact resistance as well as good gloss.Type: ApplicationFiled: June 12, 2003Publication date: March 11, 2004Inventors: Chang-Hun Han, Oh-Jin Kwon, Dae-Woo Lee
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Patent number: 6696520Abstract: An elastomeric thermoplastic polyolefin composition comprising (i) an heterophasic olefin polymer composition comprising a crystalline propylene homopolymer of copolymer fraction and an elastomeric ethylene copolymer fraction and (ii) an elastomeric polymer having a hardness equal to or less than 90 points selected from the group consisting of copolymers of ethylene, ethylene-methyl acrylate copolyers, saturated or unsaturated styrene block copolymers and unsaturated norbornene polymers.Type: GrantFiled: October 14, 1998Date of Patent: February 24, 2004Assignee: Basell Poliolefine Italia S.p.A.Inventors: Giampaolo Pellegatti, Vittorio Braga, Roberto Bonari
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Patent number: 6689841Abstract: The present invention relates to a polypropylene resin composition and more particularly, to the polypropylene resin composition comprising: (A) a propylene polymer comprising a propylene-ethylene copolymer having a certain limit viscosity alone and/or a propylene homopolymer having a certain pentad fraction (% mmmm); (B) an ethylene-&agr;-olefin copolymer rubber comprising ethylene-propylene copolymer rubber and ethylene-&agr;-olefin copolymer; (C) a styrene copolymer rubber; (D) a polypropylene modified with polar group-containing resin or a polyolefin polyol; and (E) an inorganic filler.Type: GrantFiled: November 6, 2001Date of Patent: February 10, 2004Assignees: Hyundai Motor Company, LG Caltex Co., Ltd.Inventors: Soon-Joon Jung, Jae-Rim Choi, Bong-Hyun Park
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Patent number: 6667363Abstract: A material for liquid keeping containers comprising a resin composition which contains a syndiotactic polystyrene resin and a polypropylene resin and includes a compatibilized structure of the syndiotactic polystyrene resin phase and the polypropylene resin phase, the proportion of these phases being 90-10/10-90 (weight ratio).Type: GrantFiled: March 9, 2001Date of Patent: December 23, 2003Assignees: Asahi Kasei Kabushiki Kaisha, Honda Giken Kogyo Kabushiki KaishaInventors: Ken Mizushiro, Shigekatsu Yoshida, Hideo Kinoshita, Toshiro Ijima
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Patent number: 6664334Abstract: A golf ball maintaining favorable shot feeling, exhibiting great spin rate when hit by a short iron or the like, and that easily comes to a halt, and with high spin maintenance is provided. In a golf ball including a core and a cover surrounding the core, the cover includes an ionomer resin (A component), a thermoplastic elastomer with a rubber component or a modified product thereof (B component), and a resin (C component) having solubility with the thermoplastic elastomer with a rubber segment or a modified product thereof. The mixed ratio of the A component/B component is 0.25-4, and the C component/B component is 0.1-0.9.Type: GrantFiled: February 1, 2001Date of Patent: December 16, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Satoshi Iwami, Akira Kato, Keiji Moriyama
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Publication number: 20030225211Abstract: A process for forming an oil-sorbent composition of matter with bound combinations of styrene-butadiene-styrene (SBS) and ethylene propylene diene monomer (EPDM) utilizes a low-temperature extrusion process. The SBS, or both materials, may be in the form of multitudes of granules. In certain preferred embodiments, the combination is 10-30% by weight and the SBS is about 30% styrene and manufactured without talc. The composition of matter can be extruded into a solid, compliant body for use in a product for absorbing oil. The material can be extruded, in one preferred embodiment, into an extended cylinder body having an axial hole.Type: ApplicationFiled: March 24, 2003Publication date: December 4, 2003Inventors: Glenn R. Rink, James F. Morris, Stephen C. Stelpstra
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Patent number: 6653401Abstract: Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.Type: GrantFiled: March 2, 2001Date of Patent: November 25, 2003Assignee: Asahi Kasei Kabushiki KaishaInventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
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Patent number: 6645341Abstract: A two-component epoxy-based adhesive comprising a resin component and a curing agent. The resin component comprises an epoxy resin, a polymer polyol, and fumed silica. The curing agent comprises a polyoxyalkyleneamine, an amine terminated butadiene-acrylonitrile polymer, tris(2,4,6-dimethlaminomethyl)phenol, polyamide resin, silane and fumed silica. The adhesive composition is particular useful for bonding of metals, plastics and composites and for functions such as laminating, honeycomb bonding, automotive assembly and construction assembly.Type: GrantFiled: August 6, 2002Date of Patent: November 11, 2003Assignee: National Starch and Chemical Investment Holding CorporationInventor: Terry Gordon
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Patent number: 6630536Abstract: A pressure-sensitive adhesive composition comprises: 100 parts by weight of a rubber component that is solid in an ordinary temperature; 30 to 170 parts by weight of a rubber component that is liquid in an ordinary temperature; and 50 to 400 parts by weight of a tackifier, wherein the amount of the tackifier is 25 to 80 parts by weight based on 100 parts by weight of the total amount of the rubber components.Type: GrantFiled: August 28, 2001Date of Patent: October 7, 2003Assignee: Nitto Denko CorporationInventors: Masayoshi Kuniya, Yasuyuki Sasaki, Tsuyoshi Kasahara
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Patent number: 6598637Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr): (a) 99 to 50 parts by weight of a first rubber containing olefinic unsaturation; and (b) 1 to 50 parts by weight of a second rubber which is different from said first rubber and which is an elastomeric block copolymer of (1) from 15 to 65 percent by weight, based on the total block copolymer, of butadiene, and (2) from 35 to 85 percent by weight, based on the total block copolymer, of styrene, which block copolymer has: (a) at least two blocks A which have polymerized units of styrene, a glass transition temperature Tg above 25° C.Type: GrantFiled: July 10, 2001Date of Patent: July 29, 2003Assignee: The Goodyear Tire & Rubber CompanyInventors: Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
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Patent number: 6586533Abstract: Articles are formed from a thermosetting composition based on polybutadiene or polyisoprene resins which are subjected to a high temperature cure step of greater than 250° C. The thermosetting compositions may include fillers such as particulate ceramic fillers and may also include woven webs for improved dimensional stability and decreased brittleness. The formation process of this invention is particularly well suited for making electrical circuit substrates for microwave and digital circuits, typically in the form of the thermosetting composition being laminated on one or both opposed surfaces to metal conductive foil (e.g., copper).Type: GrantFiled: May 4, 1994Date of Patent: July 1, 2003Assignee: World Properties, Inc.Inventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins, Michael E. St. Lawrence
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Patent number: 6583220Abstract: A pressure-sensitive adhesive material made of an elastic mixture comprising a continuous phase formed from a physically cross-linked solid rubber such as a styrene-olefin-styrene block copolymer, for example a styrene-isoprene-styrene block copolymer, and a compatible liquid rubber, such as a liquid styrene-isoprene, and a discontinuous phase substantially comprised of one or more “swellable polymers”, absorbents that are swellable in water. Additives such as polybutenes, polyisobutylene, mineral oil, stabilizers and other rubbers, may be present. Water soluble polymers may be added to the swellable absorbents to form part of the discontinuous phase. The pressure-sensitive adhesives the advantage over the prior are that they avoid the need to include materials known to irritate skin and mucous membranes. In particular, prior art compositions have needed to include substantial quantities of tackifying resins, which could cause problems particularly in wound dressings.Type: GrantFiled: February 29, 2000Date of Patent: June 24, 2003Assignee: Avery Dennison CorporationInventor: Roger D. A. Lipman
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Patent number: 6576692Abstract: The present invention is directed to an epoxidized block copolymer composition comprising an epoxidized block copolymer (E) obtained by epoxidizing a block copolymer (C) comprising a polymer block (A) composed mainly of a vinyl aromatic hydrocarbon compound and a polymer block (B) composed mainly of a conjugated diene compound or a product (D) of hydrogenation of the block copolymer (C). The epoxidized block copolymer (E) meets at least one of the following requisites: (1) having a molar ratio (R) of contained hydroxyl to epoxy ranging from 0.001 to 0.Type: GrantFiled: May 28, 1999Date of Patent: June 10, 2003Assignee: Daicel Chemical Industries, Ltd.Inventors: Yoshihiro Ohtsuka, Yasuhiro Oshino, Masaki Tanaka
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Patent number: 6558773Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.Type: GrantFiled: August 22, 2001Date of Patent: May 6, 2003Inventor: Gerald Edson
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Publication number: 20030065048Abstract: Radiation curable adhesive comprising an epoxidized block copolymer, a saturated block copolymer and/or a rosin derived alcohol, and a photoinitiator.Type: ApplicationFiled: June 26, 2001Publication date: April 3, 2003Inventor: Charles W. Paul