With Solid Polymer Derived From Reactant Containing Plural Unsaturation Patents (Class 525/99)
  • Patent number: 7119146
    Abstract: Compatibilized blends of an isoolefin polymer and an unsaturated diene polymer are prepared by utilizing a compatibilizing agent comprising a block/graft copolymer containing poly- or copoly-isoolefin segments and C4 to C6 alkyl-substituted styrene polymer segments, such as poly(t-butylstyrene) segments.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: October 10, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun Fu Tse, Hsien Chang Wang, Ramanan Krishnamoorti, Andy H. Tsou
  • Patent number: 7090924
    Abstract: This invention concerns a thermosetting resin system that is useful in the manufacture of high performance prepreg, laminate and composite materials as well as the prepregs, laminates and composites made from the thermosetting resin composition.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: August 15, 2006
    Assignee: Isola USA Corp.
    Inventors: Jyoti Sharma, Martin Choate, Steve Peters, Kevin Rafferty
  • Patent number: 7081499
    Abstract: An electrical insulating material for use in electrical insulators, for example, for insulated electric wires such as internal wiring of electronic equipment, automobiles or the like, electrical insulating covers produced from the electrical insulating material and a method of electrical insulation using the material are provided. More particularly, it relates to an electrical insulating material which is excellent in mechanical properties and durability, an electrical insulating cover produced from the material and a method of electrical insulation using the material.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: July 25, 2006
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Naomi Matsumoto, Hitoshi Ueno, Yasuhiro Nishihara, Hirota Nagano
  • Patent number: 7081498
    Abstract: The present invention is directed to pressure-sensitive adhesive compositions and pressure-sensitive adhesive constructions fabricated using the pressure-sensitive adhesive compositions. The pressure-sensitive adhesive compositions comprise about 10 to about 40% of a styrene-isoprene block copolymer, about 5 to about 30% of a styrene-butadiene block copolymer, about 30 to about 65% of an aromatically modified tackifying resin, about 8 to about 30% of a plasticizing oil and optionally about 0.2 to about 2% of an antioxidant, wherein the percentages are based on the total weight of the composition.
    Type: Grant
    Filed: April 8, 2004
    Date of Patent: July 25, 2006
    Assignee: Morgan Adhesives Company
    Inventors: Scott Allen Moeller, Gary A. McMaster, Timothy Smith
  • Patent number: 7056971
    Abstract: A thermoplastic elastomer (“TPE”) which is oxygen-permeable is provided with excellent barrier properties against oxygen by melt-blending with a liquid polyisobutene oil plasticizer in an amount insufficient to render the plasticized elastomer tacky. If made tacky, enough detackifier is used to allow the product to be formed into a removable seal. The TPE may be a conventional thermoplastic vulcanizate or a block copolymer of a vinylaromatic compound, typically styrene, and a conjugated diene, typically butadiene or isoprene, or mixtures thereof; the block may be a diblock, triblock or higher block, but the preferred polyblock copolymer is a triblock with styrene end-blocks and a butadiene/isoprene mid-block. Preferably the diene mid-block is hydrogenated to provide a poly(lower)monoolefin mid-block. When the TPE is a TPV, some or all of the mineral oil used to make the TPV processable may also be substituted with the polyisobutene plasticizer.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: June 6, 2006
    Assignee: GLS Corporation
    Inventor: Rajesh Kumar Varma
  • Patent number: 7015284
    Abstract: The present invention relates to a soft thermoplastic elastomer composition that is free of thermoplastic resin that can be utilized in manufacturing shoe sole inserts, seals, gaskets, wheels, and that can be overmolded on a hard substrate, such as a metal or a thermoplastic resin, for grips or handles on various household items.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: March 21, 2006
    Assignees: The Goodyear Tire & Rubber Company, GLS Corporation
    Inventors: Manoj Ajbani, Christopher Kiehl, Lawson Gibson Wideman, Rajesh Varma
  • Patent number: 6939906
    Abstract: Disclosed is a block copolymer composition comprising a block copolymer (I) comprising at least two polymer blocks (each polymer block (S) comprising vinyl aromatic hydrocarbon monomer units) and at least one polymer block (B) comprising isoprene monomer units and 1,3-butadiene monomer units, and a polystyrene resin (II), wherein, in the block copolymer (I), the amount of the vinyl aromatic hydrocarbon monomer units, the total amount of the isoprene monomer units and the 1,3-butadiene monomer units, and the isoprene monomer unit/1,3-butadiene monomer unit weight ratio are within specific range, wherein the block copolymer (I) has a vinyl aromatic hydrocarbon block ratio (BL) within a specific range, and wherein the block copolymer (I) and the polystyrene resin (II) satisfy a relationship represented by the following formula (1): 15+0.25BL?Wa?35+0.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: September 6, 2005
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Susumu Hoshi, Yukio Yamaura, Junko Kakegawa
  • Patent number: 6933344
    Abstract: Thermoplastic elastomeric compositions and processes for preparing the compositions comprising a blend of polypropylene, styrene-ethylene butylene-styrene copolymer, ethylene-propylene-diene monomer elastomer, linear low density polyethylene, peroxide crosslinking agent and a crosslinking coagent. The peroxide crosslinking agent and crosslinking coagent provide a crosslinking system. The compositions improve melt strength and increase resistance to flow and tear. The composition may further comprise mineral oil, antioxidant, colorant, a processing aid and stabilizer and mixtures thereof. The processes for preparing thermoplastic elastomeric compositions are particularly useful in microcellular injection molding to form articles with improved surface characteristics.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: August 23, 2005
    Assignee: Delphi Technologies, Inc.
    Inventors: Suresh Deepchand Shah, Michael William Jary, Ismat Ali Abu-Isa
  • Patent number: 6930146
    Abstract: A polymer composition and a thermoplastic elastomer composition containing 1,2-polybutadiene having a 1,2-bond content in the butadiene unit of 70% by weight or more, a melting point in the range of 50 to 140° C., a total halogen content of 30 ppm or less, a viscosity ? in the range of 400 to 1200 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 120° C., a viscosity ? in the range of 300 to 1000 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 150° C., and a viscosity ? in the range of 200 to 800 poise when measured with a slit die rheometer at a shear rate of 5113 sec?1 at 180° C. exhibit excellent moldability, visual appearance and scratch resistance.
    Type: Grant
    Filed: July 27, 2000
    Date of Patent: August 16, 2005
    Assignee: JSR Corporation
    Inventors: Koji Okada, Masato Suzuki, Junji Kojina
  • Patent number: 6927255
    Abstract: A rubber composition comprising (i) an incompatible polymer blend of at least two diene rubbers selected from rubbers containing a conjugated diene and, optionally, an aromatic vinyl monomer and forming two polymer phases (A) and (B), and (ii) 0.1 to 20 parts by weight, based upon 100 parts by weight of the total polymer component including the block copolymer, of a block copolymer having at least two mutually incompatible blocks (a) and (b), wherein the block (a) is compatible with the polymer phase (A) and incompatible with the polymer phase (B) and the block (b) is compatible with the polymer phase (B) and incompatible with the polymer phase (A), and composed of a conjugated diene and, optionally, an aromatic vinyl monomer, and wherein the molecular weights of the polymers forming the polymer phases (A) and (B) satisfy the specified equations (I) and (II) mentioned in the specification.
    Type: Grant
    Filed: February 18, 2000
    Date of Patent: August 9, 2005
    Assignees: The Yokohama Rubber Co., Ltd., Nippon Zeon Co., Ltd.
    Inventors: Tetsuji Kawazura, Masayuki Kawazoe, Masao Nakamura
  • Patent number: 6914091
    Abstract: Flexible hydrogenated block copolymers can be successfully used in a variety of applications including films, profiles, sheets, coatings, injection molded articles, blow or rotational molded articles and pultruded articles.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: July 5, 2005
    Assignee: The Dow Chemical Company
    Inventors: Robert J. Donald, Stephen F. Hahn, James E. Pate, III
  • Patent number: 6861472
    Abstract: A thermoplastic composition includes specified amounts of a poly(arylene ether), a homopolymer of an alkenyl aromatic monomer, a polyolefin, a hydrogenated block copolymer, and an unhydrogenated block copolymer, but the composition is substantially free of any rubber-modified poly(alkenyl aromatic) resin. The composition provides high stiffness and high impact strength and is suitable for molding a variety of articles, including automotive underhood components.
    Type: Grant
    Filed: November 1, 2001
    Date of Patent: March 1, 2005
    Assignee: General Electric Company
    Inventors: Adeyinka Adedeji, Thomas J. Hartle, John C. Haylock
  • Patent number: 6855767
    Abstract: A thermoplastic composition includes a poly(arylene ether), a poly(alkenyl aromatic) resin, a polyolefin, a hydrogenated block copolymer of alkenyl aromatic compound and a conjugated diene having an alkenyl aromatic content of about 40 to about 90 weight percent, and an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene. The composition exhibits excellent stiffness-impact strength balance, low property variability, and long melt hang time.
    Type: Grant
    Filed: November 1, 2001
    Date of Patent: February 15, 2005
    Assignee: General Electric
    Inventors: Adeyinka Adedeji, David R. Lamb, Vincent L. Lanning, Thomas J. Hartle, John C. Haylock
  • Patent number: 6849690
    Abstract: The present invention relates to a method of preparing rubber-modified styrene copolymer resin with excellent transparency and impact resistance, specifically to a method of preparing transparent resin of rubber-modified styrene copolymer comprising graft-copolymerizing styrene monomer and (meth)acrylate monomer in the presence of block or random styrene-butadiene copolymer which has 30-50% of styrene skeleton content and 20-40 cp of 5% toluene solution viscosity at 25 iÉ. According to the method of the present invention, the transparent resin containing the rubber particles of a double structure comprising onion and core-shell structure can provide transparent resin of rubber-modified styrene copolymer resin with excellent transparency and impact resistance as well as good gloss.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: February 1, 2005
    Assignee: LG Chem, Ltd.
    Inventors: Chang-Hun Han, Oh-Jin Kwon, Dae-Woo Lee
  • Patent number: 6846877
    Abstract: An olefinic thermoplastic vulcanizate is blended with a rubber-modified monovinylidene aromatic monomer, utilizing a flexible block copolymer as compatabilizing agent. The resulting composition demonstrates improved miscibility and bonding characteristics and increased hardness not previously achievable using unmodified thermoplastic vulcanizates.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: January 25, 2005
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Sunny Jacob, Kathleen Perevosnik, Joseph E. Pfeiffer
  • Patent number: 6844383
    Abstract: Disclosed is a block copolymer comprising at least two S polymer blocks comprising vinyl aromatic hydrocarbon monomer units, and one B polymer block or two or more B polymer blocks which contains or collectively contain isoprene monomer units and 1,3-butadiene monomer units, wherein the amount of the vinyl aromatic hydrocarbon monomer units and the total amount of the isoprene monomer units and the 1,3-butadiene monomer units are, respectively, from 60 to 95% by weight and from 40 to 5% by weight, each based on the weight of the copolymer, wherein the isoprene monomer unit/1,3-butadiene monomer unit weight ratio is from 45/55 to 97/3, and wherein the vinyl aromatic hydrocarbon monomer unit moiety of the copolymer has a short segment ratio of from 0 to 30% by weight, which is defined as the weight percentage, based on the total weight of vinyl aromatic hydrocarbon monomer units in the copolymer, of the vinyl aromatic hydrocarbon monomer units in at least one short segment consisting of 1 to 3 vinyl aromatic hy
    Type: Grant
    Filed: May 25, 2001
    Date of Patent: January 18, 2005
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Susumu Hoshi, Yukio Yamaura, Junko Kakegawa, Tsutomu Sugimoto
  • Patent number: 6828379
    Abstract: The invention relates to curable resin compositions based on an unsaturated prepolymer, a vinyl ether monomer that can be cross-linked with it and one or more other monomers for use as structural resins. The resin composition is cured with the aid of a radical-forming system that is unstable in the temperature range of −20° C. to +110° C., and contains an unsaturated prepolymer having an acid number of less than 10 mg of KOH per g and a vinyl ether monomer according to formula (I) or (II): A—CH═CH—O—R  (I) or (A—CH═CH—O)n—R′  (II) with A, R, R′ and n having the described meanings. The invention also relates to a process for the preparation of such resin compositions and uses thereof.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: December 7, 2004
    Assignee: DSM IP Assets B.V.
    Inventors: Jan H. Udding, Agnes E. Wolters
  • Publication number: 20040242775
    Abstract: The invention provides an elastomer composition which comprises 33.5 to 95% by weight of an aromatic vinyl-isoprene block copolymer (a) having two or more poly(aromatic vinyl) blocks, 0 to 47.5% by weight of an aromatic vinyl-isoprene diblock copolymer (b), and 5 to 33% by weight of polyisoprene (c) having a weight average molecular weight of 20,000 to 100,000, and which has a content of aromatic vinyl monomer unit of 14 to 50% by weight based on the total amount of the components (a), (b) and (c). The invention further provides a pressure-sensitive adhesive composition comprising the elastomer composition and a tackifier resin.
    Type: Application
    Filed: February 26, 2004
    Publication date: December 2, 2004
    Inventors: Takeshi Tahara, Takeshi Kawanabe
  • Publication number: 20040236020
    Abstract: Provided are a block copolymer including a polymer block containing acrylonitrile or methacrylonitrile as a principal constituent, which is excellent in heat resistance, weatherability, oil resistance, flame retardancy, and low-temperature resistance and which can be economically produced; and a thermoplastic resin composition and an elastomer composition each containing the block copolymer. The block copolymer is produced by reversible addition-fragmentation chain transfer polymerization in the presence of a thiocarbonylthio group-containing compound.
    Type: Application
    Filed: January 7, 2004
    Publication date: November 25, 2004
    Inventors: Ryotaro Tsuji, Tomoki Hiiro
  • Publication number: 20040229986
    Abstract: Various elastomer materials, cushioning devices, materials for making cushioning elements, and manufacturing techniques are disclosed.
    Type: Application
    Filed: February 20, 2004
    Publication date: November 18, 2004
    Inventor: Tony M. Pearce
  • Publication number: 20040225061
    Abstract: An elastomer composition is prepared that contains a rubber component (A) containing at least one of diene rubber and EPDM rubber; a mixture composition (B) containing hydrogenated styrene thermoplastic elastomer and olefin resin; and a styrene thermoplastic elastomer (C) having double bonds partly left, wherein the styrene thermoplastic elastomer (C) is blended at a ratio of not less than 2 parts by weight and not more than 100 parts by weight with respect to 200 parts by weight of the mixture composition (B), and the rubber component (A) is dispersed by dynamic crosslinking in the mixture composition (B) having the styrene thermoplastic elastomer (C) dispersed therein. A rubber roller is formed by using the elastomer composition. The elastomer composition is excellent in wear resistance, and the rubber roller made of the elastomer composition is excellent in wear resistance at the time of idling rotation.
    Type: Application
    Filed: May 6, 2004
    Publication date: November 11, 2004
    Inventors: Mutsuki Sugimoto, Hideyuki Okuyama
  • Patent number: 6797766
    Abstract: This invention relates to high bonding hot melt adhesive compositions comprising a high molecular weight polystyrene-ethylene/butylene-polystyrene (SEBS) block copolymer as the basic ingredient and articles constructed therefrom. This polymer is useful in a variety of hot melt adhesive applications for consumer product articles subject to hostile use environments such as toys and other play things.
    Type: Grant
    Filed: December 31, 2001
    Date of Patent: September 28, 2004
    Assignee: Mattel, Inc.
    Inventor: Abimael Cordova
  • Publication number: 20040167279
    Abstract: A process for increasing the stress-cracking resistance of polystyrene molding compositions, stress-cracking-resistant, glossy polystyrene molding compositions, composite layered sheets or composite layered films with an outer layer of this type, and also processes for producing moldings for refrigeration equipment.
    Type: Application
    Filed: January 20, 2004
    Publication date: August 26, 2004
    Inventors: Daniel Wagner, Peter Weinkotz, Herbert Morgenstern, Hans-Jurgen Renner
  • Publication number: 20040167281
    Abstract: A rubber composition comprising (1) a diene rubber, (2) a highly saturated rubber, and (3) a block copolymer that comprises a diene polymer block A and a hydrogenated diene polymer block B and has a primary structure selected from the following structures:
    Type: Application
    Filed: December 15, 2003
    Publication date: August 26, 2004
    Inventors: Hideo Takamatsu, Mizuho Maeda, Koji Kitayama, Tsutomu Yamada, Hiroshi Kanbara
  • Patent number: 6777082
    Abstract: The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: August 17, 2004
    Assignee: The Dow Chemical Company
    Inventors: Rajen M. Patel, Pak-Wing S. Chum, Stephen F. Hahn, Leonie K. Walsh, Rexford A. Maugans, Selim Bensason, Thoi H. Ho, Calvin P. Esneault
  • Patent number: 6764761
    Abstract: A method, system and apparatus for performing peritoneal dialysis are provided. To this end, in part, a film is provided. The film includes a layer of a polymer blend having from about 90% to about 99% by weight of a first component containing a styrene and hydrocarbon copolymer and from about 10% to about 1% of a high melt strength polypropylene.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: July 20, 2004
    Assignee: Baxter International Inc.
    Inventors: Bruce Ming-Da Eu, Sherwin Shang, Tahua Yang, Michael T. K. Ling, Loren M. Lundtveit
  • Patent number: 6762218
    Abstract: Thermoplastic molding compositions comprising, as substantive constituents, A) from 5 to 96% by weight of a vinylaromatic polymer with a syndiotactic structure, B) from 2 to 50% by weight of an inorganic filler, C) from 1 to 15% by weight of a thermoplastic elastomer based on copolymers made from vinylaromatic monomers, dienes and, where appropriate, 1,1-diphenylethylene, D) from 1 to 10% by weight of a compatibilizer, and, where appropriate, E) from 1 to 15% by weight of an elastomeric particulate styrene-diene block copolymer whose diene content may have been completely or to some extent hydrogenated, and, where appropriate, F) additives, where the total of the percentages by weight of A) to F) is 100.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: July 13, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Geprägs, Konrad Knoll
  • Publication number: 20040127644
    Abstract: An olefinic thermoplastic vulcanizate is blended with a rubber-modified monovinylidene aromatic monomer, utilizing a flexible block copolymer as compatabilizing agent. The resulting composition demonstrates improved miscibility and bonding characteristics and increased hardness not previously achievable using unmodified thermoplastic vulcanizates.
    Type: Application
    Filed: December 26, 2002
    Publication date: July 1, 2004
    Inventors: Sunny Jacob, Kathleen Perevosnik, Joseph E. Pfeiffer
  • Publication number: 20040127643
    Abstract: A thermoplastic vulcanizate prepared by dynamically vulcanizing a halogenated butyl rubber within a mixture that includes the halogenated butyl rubber and from about 10 to about 100 parts by weight of a crystalline thermoplastic resin per 100 parts by weight rubber, to thereby form a thermoplastic vulcanizate, where the thermoplastic resin includes a resin other than polyethylene, melt mixing the thermoplastic vulcanizate with about 5 to about 75 parts by weight of polyethylene resin per 100 parts by weight rubber, from about 3 to about 60 parts by weight of a tackifier per 100 parts by weight rubber, and from about 5 to about 250 parts by weight of a block copolymer containing at least the structure S-B/S-S per 100 parts by weight rubber, where the S block of the block copolymer has a glass transition temperature above about 25° C., the B/S block has a glass transition temperature below about 25° C.
    Type: Application
    Filed: December 26, 2002
    Publication date: July 1, 2004
    Inventors: Kathleen A. Perevosnik, Sunny Jacob, William Gary Stevenson, Curtis Waddle
  • Patent number: 6756106
    Abstract: An oil resistant, elastomeric rubber composite, particularly suited for use as an elastic tape for garments requiring a high degree of oil resistance due to conditions of its use. The rubber composite is made from a unique blend of nitrile rubber, polychloroprene (neoprene), epoxidised natural rubber and natural rubber. The elastomeric composite has excellent compatibility between two rubbers of different polarity when properly compounded and processed. The composite formed as an elastic tape has a low modulus of elasticity, good needle tear strength when sewn inside a garment, and it provides a comfortable fit for long use in addition to having reduced oil swell and oil abosorption characteristics. Elastic tapes made from the elastomeric rubber composite are particularly suitable for swimwear, shower caps, head bands, face masks and other garments with direct skin contact.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: June 29, 2004
    Assignee: Garware Elastomerics Limited
    Inventor: Ramesh Manjanath Telang
  • Publication number: 20040116601
    Abstract: Thermoplastic elastomers, such as styrene-poly(ethylene-propylene)-styrene (SEPS) and styrene-poly(ethylene-butylene)-styrene (SEBS), have a tendency to undergo homolytic cleavage on mixing, particularly when extended mixing times are employed. Such thermoplastic elastomers are protected by addition of a polymer with multiple reactive sites, such as polybutadiene. The polymer reacts with two or more of the cleaved fragments forming a copolymer which regains much of the original character of the thermoplastic elastomer.
    Type: Application
    Filed: December 11, 2002
    Publication date: June 17, 2004
    Applicant: BFS Diversified Products, LLC
    Inventor: James E. Hall
  • Patent number: 6747095
    Abstract: An objective of the invention is to provide a rubber composition which has satisfactory processability and dimension stability, and the like, gives a vulcanized rubber exhibiting excellent wearing resistance and tensile strength, and the like, and thus is useful in a belt, a hose and a tire and the like, as well as a crosslinked rubber particle for obtaining such rubber composition. A rubber composition of the invention comprises [1] a crosslinked rubber particle comprising as repeating units (a) 30 to 94.89% by weight of a conjugated diene unit, (b) 5 to 69.89% by weight of an aromatic vinyl unit, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group, (d) one polymerizable unsaturated group and an amino group, a hydroxyl group and an epoxy group and (e) 0.
    Type: Grant
    Filed: April 26, 2001
    Date of Patent: June 8, 2004
    Assignee: JSR Corporation
    Inventors: Tomohisa Konno, Toshihiro Tadaki, Yoshiyuki Udagawa, Hiroshi Akema
  • Patent number: 6743860
    Abstract: The present invention relates to a thermoplastic resin composition comprising (a) 100 parts by weight of a block copolymer comprising at least two polymeric blocks A composed mainly of a vinyl aromatic compound and at least one polymeric block B composed mainly of a conjugated diene compound, or a hydrogenated block copolymer thereof, (d) 5 to 50 parts by weight of an organic peroxide, and (e) 10 to 80 parts by weight of one or more substances selected from the group consisting of multifunctional vinyl compounds and multifunctional (meth)acrylate compounds. The present invention provides a master batch of an organic peroxide in which the organic peroxide is so uniformly dispersed in a thermoplastic resin that crosslinking and/or decomposition occur uniformly, a method of preparing the same, a thermoplastic resin composition obtained using the master batch and a method of preparing the same.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: June 1, 2004
    Assignee: Riken Technos Corporation
    Inventor: Hiroki Mizuno
  • Publication number: 20040082719
    Abstract: A poly(arylene ether)-polyolefin composition is prepared by melt-blending a poly(arylene ether), a poly(alkenyl aromatic) resin, a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene, and an unhydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene to form a first blend, and melt-blending the first blend and a polyolefin and additional hydrogenated block copolymer to form a second blend. A reinforcing filler and/or an ethylene/alpha-olefin elastomeric copolymer may, optionally, be added during formation of the second blend or in an additional step. Multiple mixing elements, low throughput, and high extruder rotations per minute may be used to achieve high energy mixing of the first and second blends. Compositions prepared by the method exhibit an improved balance of impact strength, stiffness, and heat resistance, as well as reduced variability of physical properties.
    Type: Application
    Filed: July 10, 2003
    Publication date: April 29, 2004
    Inventors: Adeyinka Adedeji, John C. Haylock, Robert Hossan, William Eugene Pecak, Mark Victor Vendon
  • Patent number: 6723791
    Abstract: An oil-sorbent composition of matter has bound combinations of styrene-butadiene-styrene (SBS) and ethylene propylene diene monomer (EPDM). The SBS, or both materials, may be in the form of multitudes of granules. In certain preferred embodiments, the combination is 10-30% by weight and the SBS is about 30% styrene and manufactured without talc. The composition of matter can be formed into a solid, compliant body and utilized in a product for absorbing oil. The body can be formed, in one preferred embodiment, into an extended cylinder having an axial hole.
    Type: Grant
    Filed: December 31, 2001
    Date of Patent: April 20, 2004
    Assignee: Abtech Industries, Inc.
    Inventors: Glenn R. Rink, James F. Morris, Stephen C. Stelpstra, Robert L. Rosania, Jan R. Hegeman, Peter A. Allen
  • Publication number: 20040048982
    Abstract: The present invention relates to a method of preparing rubber-modified styrene copolymer resin with excellent transparency and impact resistance, specifically to a method of preparing transparent resin of rubber-modified styrene copolymer comprising graft-copolymerizing styrene monomer and (meth)acrylate monomer in the presence of block or random styrene-butadiene copolymer which has 30-50% of styrene skeleton content and 20-40 cp of 5% toluene solution viscosity at 25 ié. According to the method of the present invention, the transparent resin containing the rubber particles of a double structure comprising onion and core-shell structure can provide transparent resin of rubber-modified styrene copolymer resin with excellent transparency and impact resistance as well as good gloss.
    Type: Application
    Filed: June 12, 2003
    Publication date: March 11, 2004
    Inventors: Chang-Hun Han, Oh-Jin Kwon, Dae-Woo Lee
  • Patent number: 6696520
    Abstract: An elastomeric thermoplastic polyolefin composition comprising (i) an heterophasic olefin polymer composition comprising a crystalline propylene homopolymer of copolymer fraction and an elastomeric ethylene copolymer fraction and (ii) an elastomeric polymer having a hardness equal to or less than 90 points selected from the group consisting of copolymers of ethylene, ethylene-methyl acrylate copolyers, saturated or unsaturated styrene block copolymers and unsaturated norbornene polymers.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: February 24, 2004
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Giampaolo Pellegatti, Vittorio Braga, Roberto Bonari
  • Patent number: 6689841
    Abstract: The present invention relates to a polypropylene resin composition and more particularly, to the polypropylene resin composition comprising: (A) a propylene polymer comprising a propylene-ethylene copolymer having a certain limit viscosity alone and/or a propylene homopolymer having a certain pentad fraction (% mmmm); (B) an ethylene-&agr;-olefin copolymer rubber comprising ethylene-propylene copolymer rubber and ethylene-&agr;-olefin copolymer; (C) a styrene copolymer rubber; (D) a polypropylene modified with polar group-containing resin or a polyolefin polyol; and (E) an inorganic filler.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: February 10, 2004
    Assignees: Hyundai Motor Company, LG Caltex Co., Ltd.
    Inventors: Soon-Joon Jung, Jae-Rim Choi, Bong-Hyun Park
  • Patent number: 6667363
    Abstract: A material for liquid keeping containers comprising a resin composition which contains a syndiotactic polystyrene resin and a polypropylene resin and includes a compatibilized structure of the syndiotactic polystyrene resin phase and the polypropylene resin phase, the proportion of these phases being 90-10/10-90 (weight ratio).
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: December 23, 2003
    Assignees: Asahi Kasei Kabushiki Kaisha, Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Ken Mizushiro, Shigekatsu Yoshida, Hideo Kinoshita, Toshiro Ijima
  • Patent number: 6664334
    Abstract: A golf ball maintaining favorable shot feeling, exhibiting great spin rate when hit by a short iron or the like, and that easily comes to a halt, and with high spin maintenance is provided. In a golf ball including a core and a cover surrounding the core, the cover includes an ionomer resin (A component), a thermoplastic elastomer with a rubber component or a modified product thereof (B component), and a resin (C component) having solubility with the thermoplastic elastomer with a rubber segment or a modified product thereof. The mixed ratio of the A component/B component is 0.25-4, and the C component/B component is 0.1-0.9.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: December 16, 2003
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Satoshi Iwami, Akira Kato, Keiji Moriyama
  • Publication number: 20030225211
    Abstract: A process for forming an oil-sorbent composition of matter with bound combinations of styrene-butadiene-styrene (SBS) and ethylene propylene diene monomer (EPDM) utilizes a low-temperature extrusion process. The SBS, or both materials, may be in the form of multitudes of granules. In certain preferred embodiments, the combination is 10-30% by weight and the SBS is about 30% styrene and manufactured without talc. The composition of matter can be extruded into a solid, compliant body for use in a product for absorbing oil. The material can be extruded, in one preferred embodiment, into an extended cylinder body having an axial hole.
    Type: Application
    Filed: March 24, 2003
    Publication date: December 4, 2003
    Inventors: Glenn R. Rink, James F. Morris, Stephen C. Stelpstra
  • Patent number: 6653401
    Abstract: Disclosed is a thermoplastic elastomer composition which comprises (A) a thermoplastic resin containing a polystyrene resin, (B) a rubber-like polymer obtained by partially or completely crosslinking an ethylene-&agr;-olefin copolymer and (C) a compatibilizing agent, the amount of the component (B) being 40-90 parts by weight and the amount of the component (C) being 0.1-40 parts by weight based on 100 parts by weight of the components (A), (B) and (C) in total. According to the present invention, an elastomer composition excellent in abrasion resistance can be provided.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: November 25, 2003
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Hideo Kinoshita, Ikuji Ohtani, Takeshi Yasui
  • Patent number: 6645341
    Abstract: A two-component epoxy-based adhesive comprising a resin component and a curing agent. The resin component comprises an epoxy resin, a polymer polyol, and fumed silica. The curing agent comprises a polyoxyalkyleneamine, an amine terminated butadiene-acrylonitrile polymer, tris(2,4,6-dimethlaminomethyl)phenol, polyamide resin, silane and fumed silica. The adhesive composition is particular useful for bonding of metals, plastics and composites and for functions such as laminating, honeycomb bonding, automotive assembly and construction assembly.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: November 11, 2003
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Terry Gordon
  • Patent number: 6630536
    Abstract: A pressure-sensitive adhesive composition comprises: 100 parts by weight of a rubber component that is solid in an ordinary temperature; 30 to 170 parts by weight of a rubber component that is liquid in an ordinary temperature; and 50 to 400 parts by weight of a tackifier, wherein the amount of the tackifier is 25 to 80 parts by weight based on 100 parts by weight of the total amount of the rubber components.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: October 7, 2003
    Assignee: Nitto Denko Corporation
    Inventors: Masayoshi Kuniya, Yasuyuki Sasaki, Tsuyoshi Kasahara
  • Patent number: 6598637
    Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr): (a) 99 to 50 parts by weight of a first rubber containing olefinic unsaturation; and (b) 1 to 50 parts by weight of a second rubber which is different from said first rubber and which is an elastomeric block copolymer of (1) from 15 to 65 percent by weight, based on the total block copolymer, of butadiene, and (2) from 35 to 85 percent by weight, based on the total block copolymer, of styrene, which block copolymer has: (a) at least two blocks A which have polymerized units of styrene, a glass transition temperature Tg above 25° C.
    Type: Grant
    Filed: July 10, 2001
    Date of Patent: July 29, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Annette Lechtenböhmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6586533
    Abstract: Articles are formed from a thermosetting composition based on polybutadiene or polyisoprene resins which are subjected to a high temperature cure step of greater than 250° C. The thermosetting compositions may include fillers such as particulate ceramic fillers and may also include woven webs for improved dimensional stability and decreased brittleness. The formation process of this invention is particularly well suited for making electrical circuit substrates for microwave and digital circuits, typically in the form of the thermosetting composition being laminated on one or both opposed surfaces to metal conductive foil (e.g., copper).
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: July 1, 2003
    Assignee: World Properties, Inc.
    Inventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins, Michael E. St. Lawrence
  • Patent number: 6583220
    Abstract: A pressure-sensitive adhesive material made of an elastic mixture comprising a continuous phase formed from a physically cross-linked solid rubber such as a styrene-olefin-styrene block copolymer, for example a styrene-isoprene-styrene block copolymer, and a compatible liquid rubber, such as a liquid styrene-isoprene, and a discontinuous phase substantially comprised of one or more “swellable polymers”, absorbents that are swellable in water. Additives such as polybutenes, polyisobutylene, mineral oil, stabilizers and other rubbers, may be present. Water soluble polymers may be added to the swellable absorbents to form part of the discontinuous phase. The pressure-sensitive adhesives the advantage over the prior are that they avoid the need to include materials known to irritate skin and mucous membranes. In particular, prior art compositions have needed to include substantial quantities of tackifying resins, which could cause problems particularly in wound dressings.
    Type: Grant
    Filed: February 29, 2000
    Date of Patent: June 24, 2003
    Assignee: Avery Dennison Corporation
    Inventor: Roger D. A. Lipman
  • Patent number: 6576692
    Abstract: The present invention is directed to an epoxidized block copolymer composition comprising an epoxidized block copolymer (E) obtained by epoxidizing a block copolymer (C) comprising a polymer block (A) composed mainly of a vinyl aromatic hydrocarbon compound and a polymer block (B) composed mainly of a conjugated diene compound or a product (D) of hydrogenation of the block copolymer (C). The epoxidized block copolymer (E) meets at least one of the following requisites: (1) having a molar ratio (R) of contained hydroxyl to epoxy ranging from 0.001 to 0.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: June 10, 2003
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Yoshihiro Ohtsuka, Yasuhiro Oshino, Masaki Tanaka
  • Patent number: 6558773
    Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: May 6, 2003
    Inventor: Gerald Edson
  • Publication number: 20030065048
    Abstract: Radiation curable adhesive comprising an epoxidized block copolymer, a saturated block copolymer and/or a rosin derived alcohol, and a photoinitiator.
    Type: Application
    Filed: June 26, 2001
    Publication date: April 3, 2003
    Inventor: Charles W. Paul