With Solid Polymer Derived From Reactant Containing Plural Unsaturation Patents (Class 525/99)
  • Patent number: 6541568
    Abstract: Thermoplastic polymer blends and formed articles made thereof which exhibit superior physical properties such as a combination of excellent scratch resistance, rigidity and impact toughness. The thermoplastic polyolefin blend includes from about 40 percent to about 80 percent of a base component of propylene-containing polymer; from about 5 percent to about 30 percent of a toughening component; and from about 3 percent to about 40 percent of a thermoplastic elastomer, preferably of a high styrene containing block or random copolymer. A preferred thermoplastic polyolefin blend includes between about 50 percent to about 70 percent of the base component; between about 10 percent to about 20 percent of the toughening component; and between about 5 percent to about 20 percent of the styrene block copolymer. Advantageously, the thermoplastic elastomer has greater than 50 percent by weight styrene monomer.
    Type: Grant
    Filed: June 1, 2000
    Date of Patent: April 1, 2003
    Assignee: Solvay Engineered Polymers
    Inventors: Ruidong Ding, Satchit Srinivasan, Edmund K. Lau
  • Patent number: 6541569
    Abstract: A polymer alloy and method of making same comprising a block copolymer thermoplastic elastomer comprising a microscopic porosity rapidly plasticized by environmental contaminants and a binder of a polymer or copolymer, the binder binding block copolymer particles while preserving the microscopic porosity and providing a macroscopic porosity to allow fluid penetration. The block copolymer preferably comprises styrene-butadiene-styrene (SBS) triblock copolymer, styrene-butadiene (SB) diblock copolymer, or styrene-isoprene-styrene (SIS) triblock copolymer, or a combination thereof, and the binder preferably comprises styrene-ethylene-butadiene (SEB) terpolymer, ethylene-propylene-diene monomer (EPDM) terpolymer, ethylene-propylene (EPR) copolymer, or styrene-butene butadiene (SBB) terpolymer, or a combination thereof. Most preferably the block copolymer comprises styrene-butadiene-styrene (SBS) triblock copolymer and the binder comprises ethylene-propylene-diene monomer (EPDM) terpolymer.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: April 1, 2003
    Assignee: Abtech Industries, Inc.
    Inventors: James F. Morris, Stephen C. Stelpstra
  • Publication number: 20030055166
    Abstract: The present invention relates to a thermoplastic resin composition comprising
    Type: Application
    Filed: August 2, 2002
    Publication date: March 20, 2003
    Inventor: Hiroki Mizuno
  • Patent number: 6534593
    Abstract: The present invention provides a composition which comprises a radial poly(aromatic vinyl)/polyisoprene block copolymer as a major component and which can be used as a more excellent pressure-sensitive ingredient. This composition is obtained by reacting a diblock polymer with a coupling agent having a functionality of 4 or higher in the presence of a coupling accelerator, and it contains (a) 1 to 34% by weight of a diblock polymer, (b) 34 to 99% by weight of a four-branch polymer, and (c) 0 to 50% by weight of a two-branch polymer and/or a three-branch polymer. The poly(aromatic vinyl)/polyisoprene block copolymer contained in the composition has a weight-average molecular weight (Mw) of 260,000 to 500,000, and the poly(aromatic vinyl)/polyisoprene block copolymer has a poly(aromatic vinyl) block content of 5 to 24% by weight.
    Type: Grant
    Filed: February 1, 2001
    Date of Patent: March 18, 2003
    Assignee: Zeon Corporation
    Inventors: Shigeru Komatsuzaki, Tetsuaki Matsubara, Jun Ishihara
  • Patent number: 6521705
    Abstract: A thermoplastic elastomer composition for powder molding comprising 100 parts by weight of a polyolefin-based resin(A) and 10 to 1000 parts by weight of a specific hydrogenated vinyl aromatic compound-conjugated diene-based block copolymer(B), a powder of the thermoplastic elastomer composition, a method for powder molding the same, a molded article obtained by the method for powder molding, and a multi-layer molded article containing the molded article as one layer.
    Type: Grant
    Filed: June 1, 2000
    Date of Patent: February 18, 2003
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyuki Sugimoto, Yoshihiro Nakatsuji
  • Patent number: 6515072
    Abstract: A transparent rubber-modified styrenic resin composition contains a rubber-particle-dispersed phase (A) and a copolymer matrix (B). The phase (A) contains a rubbery copolymer which is a block copolymer formed from 10 to 50 wt % of styrenic monomers and 90 to 50 wt % of dienic monomers, wherein the rubbery copolymer block contains polystyrene block in an amount of 5 to 35 wt % based on total weight of the rubbery copolymer. The copolymer matrix (B) is composed of 12 to 70 parts by weight of styrenic unit, 20 to 80 parts by weight of (meth)acrylate unit, 1 to 20 parts by weight of vinyl cyanide unit, and 0 to 40 parts by weight of other copolymerizable monomer units, based on 100 parts by weight of total monomer unit. The content of the copolymer matrix (B) having a molecular weight of 3,000˜50,000 is in an amount of 15 to 50 wt %, based on the total weight of the copolymer matrix (B).
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: February 4, 2003
    Assignee: Chi Mei Corporation
    Inventor: Ray-Hsi Hsu
  • Patent number: 6495635
    Abstract: Synthetic roofing products such as simulated slate and clay tile shingles, and other products, such as flower pots, floor coverings, plastic pallets and the like are compression molded from a mixture of ultra low density polyethylene binder and a filler which may comprise recycled rubber products such as E.D.P.M (ethylene propylene diene monomer) and S.B.R. (styrene butadiene rubber). Colorants may be added to the mixture prior to final molding. Many of the products, especially synthetic shingles, are less expensive, easier to handle, and more durable than the slate or clay tile shingle product simulated.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: December 17, 2002
    Inventor: Gerald E. Edson
  • Publication number: 20020173380
    Abstract: The present invention provides a multi-piece solid golf ball having very good shot feel, excellent durability and excellent flight performance. The present invention relates to a multi-piece solid golf ball comprising a core, an inner cover and outer cover, wherein the inner cover has a Shore D hardness of 30 to 62, and is formed from an inner cover composition comprising (a) 50 to 95 parts by weight of ethylene-(meth)acrylic acid copolymer ionomer resin, and (b) 5 to 50 parts by weight of thermoplastic elastomer formed from a polymer alloy of an olefin with a block copolymer having styrene block, based on 100 parts by weight of a base resin; the outer cover is formed from a composition comprising ionomer resin as a main component, and has a Shore D hardness of 58 to 68; and the hardness of the outer cover is higher than that of the inner cover.
    Type: Application
    Filed: December 12, 2001
    Publication date: November 21, 2002
    Inventors: Keiji Ohama, Seiichiro Endo
  • Patent number: 6472464
    Abstract: A styrene-butadiene copolymer having excellent low hysteresis loss characteristic, wet skid resistance, fracture characteristics, and abrasion resistance and a rubber composition comprising the copolymer are disclosed. The styrene-butadiene copolymer has a total styrene content in the range of 33 to 42% by weight of the styrene-butadiene copolymer; a content of styrene sequences having 4 to 20 styrene units in the range of 40 to 65% by weight of the total styrene content, as obtained by measurements by NMR and GPC; a content of styrene sequences having more than 20 styrene units in the range of 5% by weight or less of the total styrene content, as obtained by measurement by GPC; a content of vinyl unit in the range of 30% by mol or less of a butadiene part of the styrene-butadiene copolymer; a sum of the total styrene value and ½ of the content of vinyl units in the range of 46 to 52%; and an inner or end structure having, for example tin-carbon bond.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: October 29, 2002
    Assignee: Bridgestone Corporation
    Inventors: Koichi Morita, Hajime Kondo, Yoichi Ozawa
  • Patent number: 6469081
    Abstract: Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight, and optionally (C) from 0.5 to 10.0 parts by weight, relative to 100 parts by weight of the component (a) of (A), of a polyphenylene ether (having an intrinsic viscosity in chloroform at 25° C. of 0.4 dl/g or higher) and/or (D) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of a styrene-olefin copolymer having a styrene content of from 5 to 35% by weight and/or (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of at least one selected from paraffinic oils, paraffinic waxes, mineral oils and siloxanic oils.
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: October 22, 2002
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Shinji Chino, Akihiko Okada, Nobuyuki Satoh
  • Patent number: 6462131
    Abstract: Compatibilized blends of an isobutylene polymer and an unsaturated diene polymer are prepared by utilizing a compatibilizing agent comprising a block/graft copolymer containing polyisobutylene segments and C4 to C6 alkyl-substituted styrene polymer segments, such as poly(t-butylstyrene) segments.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: October 8, 2002
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Mun Fu Tse, Hsien Chang Wang, Ramanan Krishnamoorti, Andy H. Tsou
  • Patent number: 6455627
    Abstract: The present invention is a hot melt pressure sensitive positioning adhesive for use with an absorbent article. The adhesive comprises: (a) from 6 to less than 15 percent by weight, of the total of (a), (b) and (c) of a blend of (i) from 40 to 95% by weight of a hydrogenated styrene-(butadiene and/or isoprene)-styrene block copolymer; and (ii) from 5 to 60% by weight of a blend of a hydrogenated styrene-isoprene-styrene-isoprene block copolymer; and (iii) from 0 to 40% by weight of an amorphous ethylene/propylene copolymer having a number average molecular weight of 9,000 to 30,000; and (b) from 50 to 80 percent by weight, of the total of (a), (b) and (c), of a tackifying resin which has an aromaticity such that the MMAP cloud point is at least 45° C.; and (c) from 5 to 35 percent by weight, of the total of (a), (b) and (c), of a plasticizer.
    Type: Grant
    Filed: June 22, 2000
    Date of Patent: September 24, 2002
    Assignee: Kraton Polymers US LLC
    Inventors: Noël Raymond Maurice De Keyzer, Carolyn Ann Stoner
  • Publication number: 20020132922
    Abstract: This invention relates generally to linear tetrablock copolymer compositions and their use in road marking applications. These tetrablock copolymers contain polystyrene, polyisoprene and polybutadiene components. Road marking compounds prepared from these copolymers further contain a hydrocarbon resin.
    Type: Application
    Filed: March 18, 2002
    Publication date: September 19, 2002
    Inventors: Roger Robert Delme, Jacques Bernard Lechat, Chantal Mathilde Martin
  • Patent number: 6448335
    Abstract: Mixtures of C2-C10 olefin polymers functionalized with carboxylic acids which are neutralized from 1 to 100% with metallic ions The mixtures comprise (by weight): (1) 100 parts of a heterophasic polyolefin composition comprising crystalline polypropylene and an elastomeric fraction of an ethylene/propylene or superior ethylene/&agr;-olefin copolymer where the ethylene content is less than 40%; and (II) 0-250 parts of an elastomeric polymer selected from: a) ethylene/C3-C10 &agr;-olefin copolymers containing at least 20% of a C3-C10 &agr;-olefin; b) ethylene/methyl acrylate copolymers containing from 15 to 30% of recurrent units of methyl acrylate, and having a MFR ranging from 1 to 10 g/10 min; and c) polyisobutylenes; d) atactic propylene homopolymers and amorphous ethylene/C3-C10 &agr;-olefins copolymers produced with metallocenic catalysts; and e) styrene block copolymers containing butadiene and isoprene as comonomer.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: September 10, 2002
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Vittorio Braga, Roberto Bonari
  • Patent number: 6441090
    Abstract: The present invention is a rubber modified monovinylidene aromatic polymer having a bimodal particle size distribution comprising: a) rubber particles of a star or branched low viscosity rubber having a volume average particle size of from 0.1 to 2&mgr;, and a cellular or core shell morphology or mixture thereof, and b) rubber particles of a star or branched low viscosity rubber, linear diene rubber or block copolymer rubber having a volume average particle size of from 0.
    Type: Grant
    Filed: October 28, 1999
    Date of Patent: August 27, 2002
    Assignee: The Dow Chemical Company
    Inventors: Mehmet Demirors, David Schrader, Steven M. Black
  • Patent number: 6433069
    Abstract: This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: August 13, 2002
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Susan T. Oeltjen, Jeffrey S. Lindquist, Yoshihiro Kodama, Daisuke Asai
  • Patent number: 6429260
    Abstract: The present invention relates to a composition comprising: A) a polyolefin thermoplastic, B) a hydrogenated block copolymer of a vinyl aromatic and conjugated diene monomer having a level of aromatic hydrogenation of at least 70 percent, and C) at least one linear or substantially linear ethylene/&agr;-olefin polymer.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: August 6, 2002
    Assignee: The Dow Chemical Company
    Inventors: F. Michael Plaver, Charles A. Berglund, Sarada Namhata
  • Publication number: 20020061967
    Abstract: The present invention discloses a polyol resin composition containing a polyether polyol blend, a polyester polyol, and a hydrocarbon blowing agent. The polyether polyol blend has at least a diamine initiated polyol, a propylene oxide polyol, and a polyethylene terephthalate initiated polyol having a functionality of from 2.3 to 3.0. The polyester polyol is preferably a phthalic anhydride initiated polyester polyol. The blowing agent is a C4-C6 hydrocarbon.
    Type: Application
    Filed: November 28, 2001
    Publication date: May 23, 2002
    Applicant: BASF Corporation
    Inventors: Walter R. White, Robert E. Riley, Jimmy L. Patterson, James A. Mullins
  • Patent number: 6390163
    Abstract: The subject invention is based upon the unexpected discovery that tires having outstanding dry and wet traction characteristics, including wet skid resistance, can be made by incorporating certain blends of styrene-butadiene rubber (SBR) and isoprene-butadiene rubber (IBR) into the treads thereof without greatly sacrificing rolling resistance and tread wear characteristics.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: May 21, 2002
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: James Edward Duddey
  • Patent number: 6380305
    Abstract: A polymeric composition is provided which exhibits a combination of high gloss and high environmental stress crack resistance, comprising: (a) high impact polystyrene having a gloss at 60 degrees of greater than 85% and an impact resistance of greater than 0.7 ft-lb/inch, (b) high density polyethylene which has a density greater than or equal to about 0.94 g/cm3, and which has a stress exponent less than or equal to about 1.70; and (c) a compatibilizing polymer for components (a) and (b), selected from the group consisting of diblock styrene butadiene copolymers, triblock styrene butadiene copolymers, diblock styrene isoprene copolymers, triblock styrene isoprene copolymers, and mixtures thereof, wherein the gloss at 60 degrees of the composition is greater than or equal to about 85%, and the environmental stress crack resistance measured in minutes until breakage at 1000 psi is greater than about 60.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: April 30, 2002
    Assignee: BASF Corporation
    Inventor: Hrong-Roang Sheu
  • Patent number: 6380304
    Abstract: Disclosed is a mass polymerized rubber-modified monovinylidene aromatic copolymer composition with an excellent balance of physical and mechanical properties and high intrinsic gloss, and methods for preparing such a composition.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: April 30, 2002
    Assignee: The Dow Chemical Company
    Inventors: Rony S. Vanspeybroeck, Gilbert Bouquet, Dominique Maes, Nicolaas Hermans
  • Patent number: 6372845
    Abstract: A blended composition consisting of a thermoplastic olefin resin (Comp. A) with an acrylonitrile-styrene-alkyl acrylate copolymer (Comp. B) was attempted to create substitution for vinyl chloride compound prepared from vinyl chloride resin proper and a plasticizer, but resulted in inferior interdispersibility. Incorporation of an epoxy resin (Comp. C) has brought definite improvement in the interdispersibility. A resinous composition including the components A, B, and C has the utility of substitution for vinyl chloride compounds as well as its products. (Comp. C) is selected from the group consisting of epoxidized diene block copolymers including, in their molecules, a block prepared by polymerization from a vinyl aromatic monomer and another block prepared by polymerization from a conjugated diene monomer, wherein remnant diene groups after the polymerization have been epoxidized or further partially hydrogenated.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: April 16, 2002
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Yoshihiro Ohtsuka, Tohru Matsuda, Shizuo Maeda, Kouichi Ishiihara, Yoshikazu Hida
  • Publication number: 20020037962
    Abstract: There is disclosed a pneumatic tire having a rubber component comprising a sulfur cured rubber composition composed of, based on 100 parts by weight of rubber (phr):
    Type: Application
    Filed: July 10, 2001
    Publication date: March 28, 2002
    Inventors: Annette Lechtenbohmer, Maurice Peter Catharina Jozef Klinkenberg
  • Patent number: 6355728
    Abstract: A block copolymer (1) containing a polymer block A of a conjugated diene and a random copolymer block B of a conjugated diene and aromatic vinyl compound, (2) having a weight ratio (A:B) of the polymer block A and the copolymer block B of 5:95 to 95:5, (3) having a bound aromatic vinyl compound content in the copolymer block B of 1 to 50% by weight, (4) having a weight average molecular weight (Mw) of 100,000 to 5,000,000, and (5) having at least two transition points measured by differential scanning calorimetry in the range of −150° C. to +150° C., a method of production of the same, and a rubber composition and pneumatic tire containing the same.
    Type: Grant
    Filed: October 12, 2000
    Date of Patent: March 12, 2002
    Assignees: The Yokohama Rubber Co. Ltd., Nippon Zeon Co., Ltd.
    Inventors: Tetsuji Kawazura, Masayuki Kawazoe, Yasushi Kikuchi, Toru Nakamura, Masao Nakamura, Takeshi Karato
  • Patent number: 6350813
    Abstract: The present invention refers to a rubber modified monovinylidene aromatic polymer composition wherein the rubber is in the form of discrete, dispersed rubber particles and comprises: a) from 75 to 25 weight percent based on the total weight of rubber, of a star branched diene rubber, having a cis 1,4 structure content of less than 75 percent; and b) from 25 to 75 weight percent, based on the total weight of rubber, of a linear diene rubber, having a cis 1,4 structure content of less than 50 percent.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: February 26, 2002
    Assignee: The Dow Chemical Company
    Inventors: David Schrader, Steven M. Black
  • Patent number: 6346572
    Abstract: A molding material as based on from 60 to 98% by weight of a hard matrix A comprising polymerized or copolymerized units of at least one vinylaromatic monomer or at least one vinylaromatic monomer and at least one polar comonomer and from 2 to 40% by weight, the percentages in each case being based on the molding material comprising A and B, of a soft phase B formed from a hydrogenated or unhydrogenated block copolymer prepared by anionic polymerization and comprising a vinylaromatic monomer V and a diene D, having at least one random or quasi-random block (V/D) of vinylaromatic monomer and diene and containing from 10 to 80% by weight, based on the soft phase B, of occlusions of matrix material (a) formed during the polymerization of the hard matrix A in the presence of the block rubber, and said molding material is used for the production of films, sheets or moldings.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: February 12, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Loth, Konrad Knoll, Hermann Gausepohl
  • Patent number: 6344519
    Abstract: An oil-sorbent composition of matter has bound combinations of styrene-butadiene-styrene (SBS) and ethylene propylene diene monomer (EPDM). The SBS, or both materials, may be in the form of multitudes of granules. In certain preferred embodiments, the combination is 10-30% by weight and the SBS is about 30% styrene and manufactured without talc. The composition of matter can be formed into a solid, compliant body and utilized in a product for absorbing oil. The body can be formed, in one preferred embodiment, into an extended cylinder having an axial hole.
    Type: Grant
    Filed: January 9, 1998
    Date of Patent: February 5, 2002
    Assignee: Abtech Industries, Inc.
    Inventors: Glenn R. Rink, James F. Morris, Stephen C. Stelpstra
  • Patent number: 6333382
    Abstract: Polymeric composition containing: a) 100 parts by weight of a random copolymer of propylene and ethylene containing less than 6 weight % of ethylene, b) 0.1 to 4 parts by weight of an elastomeric block copolymer having at least one polymeric block containing predominantly polymerized monovinyl aromatic compound and at least one polymeric block containing predominantly polymerized conjugated diene, and c) 12 to 20 parts by weight of an elastic metallocene polyolefin. Use of said composition for the manufacture of shaped objects and objects so obtained.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: December 25, 2001
    Assignee: Solvay Polyolefins Europe-Belgium
    Inventors: Swanzy Scott, Kelley Sherwood
  • Patent number: 6291585
    Abstract: This invention provides transparent resin compositions of polycarbonate, polyester, methacrylic, styrene, polyvinyl chloride, polyolefin, and polyamide resin, having the advantageous effects of efficiently absorbing near infrared radiation (780-1800 nm) and efficiently transmitting visible light (380-780 nm). The invention provides transparent resin compositions with excellent near infrared absorption characteristics comprising 100 parts by weight of a transparent thermoplastic resin, about 0.01 to about 2 parts by weight of a specific thiuram compound and/or a specific metal dithiocarbamate compound, and about 0.01 to about 2 parts by weight of a specific copper compound. It also provides transparent resin compositions with excellent near infrared absorption characteristics comprising 100 parts by weight of a transparent thermoplastic resin, about 0.01 to about 2 parts by weight of a specific copper dithiocarbamate compound, and about 0 to about 2 parts by weight of a specific copper compound.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: September 18, 2001
    Assignee: Sumitomo Dow Limited
    Inventors: Yukio Tomari, Naoyoshi Kawamoto
  • Patent number: 6277488
    Abstract: A pressure sensitive adhesive composition comprising (a) a block copolymer composition comprising (i) a first component having a configuration of A-B, and (ii) a second component having a configuration of A-B-(B-A)n where n ranges from 1 to 20, wherein A is an alkenyl aromatic or arene hydrocarbon polymer and B is polybutadiene, and wherein the first component is present in an amount ranging from about 40 weight % to about 95 weight % based on a total weight of the block copolymer composition; (b) a polyphenylene oxide resin; and (c) a tackifier resin compatible with B.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: August 21, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: James J. Kobe, David J. Yarusso
  • Patent number: 6274676
    Abstract: A tire having improved tear strength including at least one component comprising a vulcanized elastomer; and up to about 35 parts by weight of polyolefin copolymer per one hundred parts by weight rubber.
    Type: Grant
    Filed: January 8, 1999
    Date of Patent: August 14, 2001
    Assignee: Bridgestone Corporation
    Inventors: Chen-Chy Lin, Hamada Tatsuro
  • Patent number: 6271317
    Abstract: Tire rubbers which are prepared by anionic polymerization are frequently coupled with a suitable coupling agent, such as a tin halide, to improve desired properties. It has been unexpectedly found that greatly improved properties for tire rubbers, such as lower hysteresis, can be attained by asymmetrically coupling the rubber.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: August 7, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel Farhan Halasa, Shingo Futamura, Wen-Liang Hsu, Barry Allen Matrana
  • Patent number: 6262175
    Abstract: A thermoplastic elastomer composition containing in percentages by weight based on the total weight of the composition, about 5% to about 90% vulcanized rubber crumb; about 5% to about 60% polyolefin; about 2% to about 30% uncured rubber or styrene-based thermoplastic elastomer; and about 2% to about 30% vinyl polymer selected from vinyl homopolymers, copolymers and mixtures. The composition in total contains less than 15% styrene block copolymer.
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: July 17, 2001
    Assignee: NRI Technology Inc.
    Inventors: James R. Jury, Alfred Wing Yan Chien
  • Patent number: 6239217
    Abstract: A composition of matter comprising: A) from 25 to 90 parts by weight of a syndiotactic, vinylaromatic polymer, B) from 5 to 30 parts by weight of an oil extended, elastomeric polyolefin; C) from 1 to 10 parts by weight of a compatibilizer comprising a styrene containing block copolymer or a hydrogenated derivative thereof; D) from 0 to 25 parts by weight of a domain forming rubbery polymer comprising a styrene/conjugated diene triblock copolymer or a hydrogenated derivative thereof; E) from 0 to 5 parts by weight of a nucleator for the syndiotactic, vinylaromatic thermoplastic resin, F) from 0 to 60 parts by weight of a reinforcing agent, and G) from 0 to 90 parts by weight of a polyarylene ether or polar group modified polyarylene ether.
    Type: Grant
    Filed: September 21, 1999
    Date of Patent: May 29, 2001
    Assignee: The Dow Chemical Company
    Inventors: David H. Bank, John M. Warakomski, Shaofu Wu, Kalyan Sehanobish
  • Patent number: 6235847
    Abstract: Disclosed is a linear block copolymer comprising at least two vinyl aromatic hydrocarbon polymer blocks (S), at least two conjugated diene polymer blocks (B) and at least one vinyl aromatic hydrocarbon/conjugated diene copolymer block (B/S); the linear block copolymer having a specific block configuration wherein both terminal polymer blocks of the linear block copolymer are S blocks, both terminal S blocks have, bonded directly to the respective inner ends thereof, B blocks, and the B blocks, which are bonded directly to the respective inner ends of both terminal polymer blocks (S), have therebetween one or two B/S blocks which is or are bonded directly to the respective inner ends of the polymer blocks (B); the linear block copolymer comprising at least two fractions having different peak molecular weights, and both terminal S blocks in total comprising at least two fractions having different peak molecular weights.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: May 22, 2001
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Susumu Hoshi, Yukio Yamaura
  • Patent number: 6218588
    Abstract: The invention relates to aromatic modified aliphatic hydrocarbon resins giving excellent balance between tack and shear properties even at low coating weights. These resins are characterized in that they have a Ring and Ball (R&B) softening point of 94° C. or lower, a weight average molecular weight (Mw) of not more than 2000 Dalton, a Z-average molecular weight (Mz) of not more than 6000 Dalton and a mixed methylcyclohexane aniline cloud point (MMAP) between 25 and 45° C. The aromatic modified aliphatic hydrocarbon resins of the invention may be prepared by subjecting polymerization feeds containing petroleum feeds which comprise (a) C5 and C6 olefins and/or diolefins including cycloolefins, (b) aromatic monomers and (c) (di-)cyclodiolefins to a Friedel-Crafts polymerization. The invention is also directed to the use of the aromatic modified aliphatic hydrocarbon resins as mono-tackifiers in adhesive formulations as well as to an adhesive tape comprising these resins.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: April 17, 2001
    Assignee: Hercules Incorporated
    Inventors: Nicolaas Adriaan Dommisse, Christiaan Pieter Louis Charles Donker, Michael Hendrikus Theelen, Jacobus van Rijn, Gerard Arie Verrijzer
  • Patent number: 6214935
    Abstract: An improved hot-melt pressure-sensitive adhesive (HMPSA) composition contains an elastomeric component, such as a blend of SIS and SB block copolymers, and a tackifying component comprising one or more intermediate softening point resins (ISPRs) having a ring and ball softening point of from 35 to 60° C. The improved adhesive compositions are characterized by reduced volatility, less bleed and staining tendencies, and improved overall adhesive performance. The invention also provides improved label constructions in which a release liner is coated with an HMPSA composition and laminated to a flexible facestock. Notably, even when low basis weight paper facestocks are used, the construction can be converted at high speeds.
    Type: Grant
    Filed: July 15, 1998
    Date of Patent: April 10, 2001
    Assignee: Avery Dennison Corporation
    Inventors: Yukihiko Sasaki, Jesse C. Ercillo, Catharina Eyken, Le Hoa Hong, Henk de Koning
  • Patent number: 6184285
    Abstract: Novel hot melt construction adhesives for disposable articles, such as diapers, sanitary napkins, medical gowns, surgical drapes, and the like, are described which offer superior properties versus currently available hot melt adhesives. These hot melt construction adhesive compositions comprise a blend of styrene-isoprene block copolymer containing at least about 25 weight percent styrene and styrene-butadiene block copolymer containing at least about 25 weight percent styrene, at least one compatible tackifying resin and at least one plasticizer. The hot melt construction adhesive possesses a viscosity no greater than about 25,000 mPa·s at about 140° C., a shear adhesion failure temperature of at least about 60° C., and a static shear time to failure of no less than about 25 hours at about 23°.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: February 6, 2001
    Assignee: Henkel Corporation
    Inventors: Stephen F. Hatfield, Alejandro Matassa, Robert Goodman
  • Patent number: 6180717
    Abstract: A block copolymer (1) containing a polymer block A of a conjugated diene and a random copolymer block B of a conjugated diene and aromatic vinyl compound, (2) having a weight ratio (A:B) of the polymer block A and the copolymer block B of 5:95 to 95:5, (3) having a bound aromatic vinyl compound content in the copolymer block B of 1 to 50% by weight, (4) having a weight average molecular weight (Mw) of 100,000 to 5,000,000, and (5) having at least two transition points measured by differential scanning calorimetry in the range of −150° C. to +150° C., a method of production of the same, and a rubber composition and pneumatic tire containing the same.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: January 30, 2001
    Assignees: Yokohama Rubber Co., Ltd., Nippon Zeon Co., Ltd.
    Inventors: Tetsuji Kawazura, Masayuki Kawazoe, Yasushi Kikuchi, Toru Nakamura, Masao Nakamura, Takeshi Karato
  • Patent number: 6176510
    Abstract: An elastomer composition which comprises (a) 100 parts by weight of a hydrogenated block copolymer mixture comprising: (a-1) 10 to 60 parts by weight of a block copolymer prepared by hydrogenating a block copolymer that comprises: at least two polymer blocks A each mainly comprising a vinyl aromatic compound; and at least one polymer block B mainly comprising a conjugated diene compound, the hydrogenated block copolymer having a number average molecular weight of from more than 200,000 to not more than 400,000 and a content of the polymer block A of from 15 to 40% by weight of said block copolymer; and (a-2) 40 to 90 parts by weight of a block copolymer prepared by hydrogenating a block copolymer that comprises: at least one polymer block A mainly comprising a vinyl aromatic compound; and at least one polymer block B mainly comprising a conjugated diene compound, the hydrogenating block copolymer having a number average molecular weight of from more than 30,000 to not more than 140,000 and a content of the po
    Type: Grant
    Filed: November 18, 1998
    Date of Patent: January 23, 2001
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Tetsuo Masubuchi, Mitsuhiro Tanaka
  • Patent number: 6172156
    Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 40% by weight of a block copolymer having a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100° C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 40% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.
    Type: Grant
    Filed: June 12, 1997
    Date of Patent: January 9, 2001
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Jeffrey S. Lindquist, Lisa L. Ryan
  • Patent number: 6172154
    Abstract: Novel elastomeric compositions are disclosed, incorporating silicon-treated carbon black and pre-vulcanization modifier selected from non-silane polysulfidic organo-compounds. The silicon-treated carbon black particulate filler differs chemically and in its performance characteristics from simple mixtures of silica and carbon black fillers. The pre-vulcanization modifier is effective to substantially increase bound rubber content in the product of a non-productive thermomechanical working of a base composition incorporating the silicon-treated carbon black particulate filler and SBR or other such unsaturated elastomer. The thermal working takes place at a maximum temperature sufficient to vulcanize the unsaturated elastomer if it were in the presence of a suitable vulcanization system.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: January 9, 2001
    Assignee: Cabot Corporation
    Inventors: Trevor Alan Brown, Meng-Jiao Wang
  • Patent number: 6127488
    Abstract: Rubber mixtures prepared from at least one styrene/butadiene rubber gel and at least one rubber which contains double bonds and optionally further fillers and rubber auxiliary substances are in particular suitable for the preparation of vulcanizates having unusually high damping at temperatures of from -20 to +20.degree. C. as well as unusually low damping at temperatures of from 40 to 80.degree. C. The rubber mixtures may therefore be used, for example, to manufacture vehicle tires which grip in the wet and have low rolling resistance.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: October 3, 2000
    Assignee: Bayer AG
    Inventors: Werner Obrecht, Thomas Scholl, Ulrich Eisele, Winfried Jeske, Peter Wendling, Adolf Schmidt
  • Patent number: 6127444
    Abstract: The present invention relates to a polymeric compound comprising(a) 100 parts by weight of a block copolymer comprising at least two external monovinyl aromatic hydrocarbon blocks and at least one internal hydrogenated conjugated diene block, wherein the total monovinyl aromatic hydrocarbon content is from 20 to 50% by weight and the total apparent molecular weight is from 140,000 g/mol to 400,000 g/mol;(b) 50 to 250 phr of a plasticiser;(c) 10 to 100 phr of a polybutene-1 polymer having a melt index at 2.16 kg/190.degree. C. of from 0.05 to 400;(d) a blowing agent.The present invention further relates to use of the compound for the preparation of foamed compounds; to a foaming process; to a masterbatch blend; to a foamed compound; and to articles containing the foamed compound.
    Type: Grant
    Filed: September 1, 1999
    Date of Patent: October 3, 2000
    Assignee: Shell Oil Company
    Inventor: Ilham Kadri
  • Patent number: 6121366
    Abstract: A thin-walled rubber article with a relatively low modulus, prepared by dip forming, formed from a composition comprising styrene-isoprene-styrene (S-I-S) triblock copolymer, and styrene-butadiene-styrene (S-B-S) triblock copolymer with a S-I-S content in excess of at least 76% by weight. The composition additionally contains antiblocking agent to prevent the articles from sticking together, especially polyethylene wax. The articles are preferably gloves.
    Type: Grant
    Filed: February 26, 1998
    Date of Patent: September 19, 2000
    Assignee: ECI Medical Technologies Inc.
    Inventor: Pam Sharma
  • Patent number: 6117941
    Abstract: Compositions comprising reaction product of higher molecular weight olefinic reactants with carboxylic reactants of the formula R.sup.3 C(O)(R.sup.4).sub.n C(O)OR.sup.5 (IV) or the corresponding acetals, hemiacetals, ketals, and hemiketals thereof are useful as intermediates for further reaction in the preparation of lubricating oil additives.
    Type: Grant
    Filed: April 9, 1998
    Date of Patent: September 12, 2000
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, Richard M. Lange, Richard Yodice, Mark R. Baker, Jeffry G. Dietz
  • Patent number: 6107411
    Abstract: A block copolymer (hereinafter referred to as the block copolymer (I)), consisting essentially of a vinyl aromatic hydrocarbon and a conjugated diene and satisfying the following conditions (1) to (5):(1) the weight ratio of vinyl aromatic hydrocarbon units to conjugated diene units is from 60:40 to 90:10,(2) the number average molecular weight of the block copolymer is from 40,000 to 500,000,(3) the ratio of E'30/E'10, where E'30 is the storage modulus at a temperature of 30.degree. C. and E'10 is the storage modulus at a temperature of 10.degree. C., is from 0.75 to 1,(4) the block proportion of a vinyl aromatic hydrocarbon polymer contained in the block copolymer is from 70 to 100%, provided the block proportion=W1/W0.times.
    Type: Grant
    Filed: January 5, 1998
    Date of Patent: August 22, 2000
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hideki Toya, Masayoshi Nakazato, Hiroshi Suzuki
  • Patent number: 6106939
    Abstract: The invention provides a petroleum-based aliphatic resin having: a) a Ring and Ball (R&B) softening point in the range of about 75 to about 110.degree. C., b) a weight average molecular weight (Mw) of about 1000 to about 2600 Dalton, a z-average molecular weight (Mz) from about 1900 to about 5000 Dalton and an Mw/Mn below about 2.0, c) a level of aromatic protons below about 1.5% with respect to the total protons determined by .sup.1 H-NMR, and d) a mixed methylcyclohexane aniline cloud point (MMAP) of about 90.degree. C. or less. The resins according to the invention are characterized by a high amount of cyclic structures. Further disclosed is a method of independently controlling the R&B softening point and the molecular weight of an aliphatic resin composition during its preparation by polymerization of a petroleum-based feed, the method being characterized in that the amount of cyclic structures in the resins is increased.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: August 22, 2000
    Assignee: Hercules Incorporated
    Inventors: Christiaan Pieter Donker, Berend Lenselink, Michael Hendrikus Theelen
  • Patent number: 6096829
    Abstract: Disclosed is a syndiotactic, polystyrenic resin composition comprising (A) 100 parts by weight of a component composed of (a) from 10 to 98% by weight of a styrene-based polymer having a syndiotactic configuration and (b) from 2 to 90% by weight of a polyolefin, (B) from 0.5 to 50 parts by weight of a styrene-olefin copolymer having a styrene content of from 40 to 85% by weight, (E) from 0 to 200 parts by weight, relative to 100 parts by weight of the component (b) of (A), of at least one selected from paraffinic oils, paraffinic waxes, mineral oils and siloxanic oils. The composition can be formed into articles having good heat resistance, a high modulus of elasticity and good toughness. In addition, the articles are advantageous in that their surface layers are hardly peeled.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: August 1, 2000
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Shinji Chino, Akihiko Okada, Nobuyuki Satoh
  • Patent number: 6063853
    Abstract: Some rubbers exhibit poor wet skid behavior during ABS braking. The wet skid behavior is substantially improved by the blends, according to the invention, of integral rubber and natural rubber. The rolling resistance is not adversely affected.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: May 16, 2000
    Assignee: Huels Aktiengesellschaft
    Inventor: Walter Hellermann