Ethylenically Unsaturated Reactant Patents (Class 528/192)
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Patent number: 8986846Abstract: A thermosetting oligomer or thermosetting polymer is provided. The thermosetting oligomer or thermosetting polymer contains repeating units, each of which has at least one thermosetting functional group in the side chain and is represented by Formula 1: where repeating units include X1, A1, and Y1 subunits, sidechain units include linking unit L and thermosetting functional group Z, and n is an integer from 1 to 4. The thermosetting oligomer or thermosetting polymer has a low coefficient of thermal expansion and high or no glass transition temperature, stiffness, processability, heat resistance and mechanical properties. The thermosetting oligomer or thermosetting polymer is highly soluble, wettable and dimensionally stable and is suitable for use in films, prepregs and printed circuit boards. Further provided are a thermosetting resin composition including the thermosetting oligomer or thermosetting polymer and a printed circuit board using the composition.Type: GrantFiled: June 23, 2009Date of Patent: March 24, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Jae Jun Lee, Mahn Jong Kim, Kwang Hee Kim
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Patent number: 8877420Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to plasticize the pressure plastic material; applying a shear force to the compressive fluid and the plasticized pressure plastic material, between which an interface exists, in the presence of a surfactant to granulate the pressure plastic material in the compressive fluid, so as to produce particles.Type: GrantFiled: March 9, 2011Date of Patent: November 4, 2014Assignee: Ricoh Company, Ltd.Inventors: Chiaki Tanaka, Ryota Inoue, Taichi Nemoto, Yoshitaka Yamauchi
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Patent number: 8859711Abstract: A method of preparing a wholly aromatic liquid crystalline polyester amide resin and a method of preparing a wholly aromatic liquid crystalline polyester amide resin compound. The method of preparing a wholly aromatic liquid crystalline polyester amide resin is performed using a monomer having both a hydroxyl group and an acetylamino group or using a monomer having a hydroxyl group and a monomer having an acetylamino group. In addition, the method of preparing a wholly aromatic liquid crystalline polyester amide resin compound is performed using a wholly aromatic liquid crystalline polyester amide resin that is prepared using the method.Type: GrantFiled: October 21, 2011Date of Patent: October 14, 2014Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim
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Publication number: 20140262021Abstract: Allyl-cyanoacrylate-containing compositions with an anhydride aromatic component, which when cured confers improved moisture resistance, are provided.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: Henkel Ireland LimitedInventors: Ciara Goff, Marisa Phelan, John Guthrie, Cormac Duffy, Sabine Horn, Christina Despotopoulou
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Publication number: 20140256896Abstract: The present invention relates to a polymerizable composition useful as a liquid crystal device, a display, an optical member, a coloring agent, a security marking, and a laser light emitting member and a thin film obtained from the polymerizable composition. The present invention provides a polymerizable liquid crystal composition having excellent solubility into a solvent, exhibiting good adhesion to a base material, and being capable of realizing a thin film having low haze and no variations and, in addition, provides a thin film having excellent appearance by using the polymerizable liquid crystal composition. The polymerizable liquid crystal composition according to the present invention is used and, thereby, a composition and a thin film having low haze and no variations and, at the same time, having excellent adhesion to a base material can be obtained at a low cost.Type: ApplicationFiled: November 21, 2012Publication date: September 11, 2014Inventors: Hidetoshi Nakata, Yasuhiro Kuwana, Hiroshi Hasebe, Kunihiko Kotani, Isa Nishiyama
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Patent number: 8822628Abstract: A crosslinkable liquid crystalline polymer that is formed by polymerizing a precursor monomer in the presence of an aromatic crosslinking agent is provided.Type: GrantFiled: September 17, 2013Date of Patent: September 2, 2014Assignee: Ticona LLCInventors: Kamlesh P. Nair, Young Shin Kim
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Patent number: 8722813Abstract: A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.Type: GrantFiled: August 18, 2011Date of Patent: May 13, 2014Assignee: Kao CorporationInventors: Hiroki Sawada, Masahiro Mori
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Publication number: 20140094562Abstract: Modified polyphenol binder compositions and methods for making and using same are provided. In at least one specific embodiment, the binder composition can include at least one unsaturated monomer and at least one polyphenolic compound. The polyphenolic compound can include a lignin, a tannin, a novolac resin, a modified phenol formaldehyde resin, bis-phenol A, humic acid, or any mixture thereof.Type: ApplicationFiled: September 30, 2013Publication date: April 3, 2014Applicant: Georgia-Pacific Chemicals LLCInventors: Cornel Hagiopol, Derek L. Atkinson
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Publication number: 20140088285Abstract: A crosslinkable liquid crystalline polymer that is formed by polymerizing a precursor monomer in the presence of an aromatic crosslinking agent is provided.Type: ApplicationFiled: September 17, 2013Publication date: March 27, 2014Applicant: Ticona LLCInventors: Kamlesh P. Nair, Young Shin Kim
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Patent number: 8637631Abstract: A polyphenylene ether which has a content of a metal magnetic material of 0.001 ppm or higher and lower than 1.000 ppm.Type: GrantFiled: February 24, 2011Date of Patent: January 28, 2014Assignee: Asahi Kasei Chemicals CorporationInventors: Tomohiro Kondo, Akinobu Nagai, Akira Mitsui
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Patent number: 8598300Abstract: The invention provides an amorphous polyester resin that can sufficiently achieve the reciprocal performance properties of hot offset resistance and cold offset resistance, which is a major issue for a toner for electrostatic image development, while allowing adequate blocking resistance to be obtained, as well as a binder resin for toner for electrostatic image development, and an amorphous polyester resin production method, the amorphous polyester resin being obtained by reaction between a polybasic carboxylic acid compound and a polyhydric alcohol, wherein the polybasic carboxylic acid compound comprises (a) the reaction product between an aromatic polybasic carboxylic acid compound and a C2-4 glycol at 60 mol % or greater based on the total amount of the polybasic carboxylic acid compound, and the amorphous polyester resin has a glass transition point of 55° C. to 75° C. and a weight-average molecular weight of 10,000 to 50,000.Type: GrantFiled: April 23, 2010Date of Patent: December 3, 2013Assignee: Nicca Chemical Co., Ltd.Inventors: Tatsuhiro Hishida, Koji Ogawa, Yasumichi Moriyama, Masaaki Hosoda, Kazuo Tanabe
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Publication number: 20130266779Abstract: Provided is a curable resin composition which can provide a cured article having a low dielectric constant and a low dielectric tangent, and can also provide a cured article having excellent moldability at ordinary press-molding temperatures, excellent heat resistance and excellent adhesion properties. The present invention provides a curable resin composition containing a polyphenylene ether, wherein the average number of phenolic hydroxy groups is 0.3 or more per molecule of the polyphenylene ether, the resin flow amount of the curable resin composition upon curing is 0.3 to 15% inclusive, and a cured article having a dielectric tangent of 0.005 or less at 1 GHz and a glass transition temperature of 170° C. or higher can be produced.Type: ApplicationFiled: December 16, 2011Publication date: October 10, 2013Applicant: ASAHI KASEI E-MATERIALS CORPORATIONInventors: Tetsuji Tokiwa, Takamitsu Utsumi, Masaaki Endo
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Patent number: 8524855Abstract: Environmentally-friendly, biodegradable polyol:carboxylic acid polyester solid-phase products may be produced utilizing microwave heating. In this process, a di- or tricarboxylic acid is reacted with a polyol such as a glycerol or a sugar alcohol, or an ester thereof with the application of heating by microwave energy. Sufficient microwave heating is provided to esterify the polyol with the carboxylic acids, while removing as steam the water by-product which is generated during the reaction. The polyesters so-produced are resistant to high temperatures and solvents, and may by cured and/or molded.Type: GrantFiled: May 16, 2012Date of Patent: September 3, 2013Assignee: The United States of America, as represented by the Secretary of AgricultureInventors: Brent Tisserat, Ronald A. Holser, Rogers E. Harry-O'Kuru
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Patent number: 8440780Abstract: A wholly aromatic liquid crystalline polyester contains 2.0 to 15.0 mole percent of a hydroquinone-derived structural unit relative to a total amount of structural units. The wholly aromatic liquid crystalline polyester has sum of an amount (a) of terminal hydroxyl group and an amount (b) of terminal acetyl group in a range of 50 to 350 equivalents/(g·10?6), and has a ratio [(a)+(b)]/(c) of the sum of the amount (a) of terminal hydroxyl group and the amount (b) of terminal acetyl group to an amount (c) of terminal carboxyl group in a range of 1.05 to 2.00.Type: GrantFiled: September 14, 2012Date of Patent: May 14, 2013Assignee: Toray Industries, Inc.Inventors: Mitsushige Hamaguchi, Kohei Miyamoto, Hideyuki Umetsu
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Publication number: 20130004891Abstract: A toner comprising a modified polyester resin containing a structure represented by Formula (1a) or (1b), wherein, in Formula (1a) and (1b), R1 represents a hydrogen atom, a methyl group, or an ethyl group, R2 represents an aliphatic hydrocarbon which may be branched, or an aromatic hydrocarbon, and R3 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a phenyl group.Type: ApplicationFiled: June 21, 2012Publication date: January 3, 2013Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.Inventors: Hiroshi NAGASAWA, Ken OHMURA
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Publication number: 20120322005Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to plasticize the pressure plastic material; applying a shear force to the compressive fluid and the plasticized pressure plastic material, between which an interface exists, in the presence of a surfactant to granulate the pressure plastic material in the compressive fluid, so as to produce particles.Type: ApplicationFiled: March 9, 2011Publication date: December 20, 2012Inventors: Chiaki Tanaka, Ryota Inoue, Taichi Nemoto, Yoshitaka Yamauchi
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Patent number: 8207287Abstract: Disclosed are polymers derived from units of bisphenol compounds, such as tetramethylcyclobutane diol-bisphenol, and processes for making and using them.Type: GrantFiled: June 7, 2011Date of Patent: June 26, 2012Assignee: SABIC Innovative Plastics IP B.V.Inventor: Jean-Francois Morizur
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Publication number: 20120148949Abstract: Disclosed is a polymer having excellent solvent resistance which can be produced by using a polycarbonate diol having a repeating unit represented by the formula (1) and/or (2), having a hydroxyl group at both termini, and having a number average molecular weight of from 300 to 50,000: wherein R1 represents a linear or branched hydrocarbon group having 2 to 50 carbon atoms; and n represents an integer of 2 to 50, wherein R2 represents a linear or branched hydrocarbon group having 10 to 50 carbon atoms.Type: ApplicationFiled: February 17, 2012Publication date: June 14, 2012Inventor: Katsuya SHIMIZU
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Patent number: 8192649Abstract: A method of preparing a capped poly(arylene ether) resin includes reacting a capping agent with a blend of two or more poly(arylene ether) resins having different intrinsic viscosities. Cured compositions prepared from these capped poly(arylene ether) resins exhibit improved balances of stiffness, toughness, and dielectric properties compared to compositions with two or more separately capped and isolated poly(arylene ether) resins.Type: GrantFiled: April 20, 2007Date of Patent: June 5, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Gary William Yeager, Hua Guo, Zhiqing Lin, Shahid Murtuza
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Patent number: 8163847Abstract: A thermoset composition exhibiting reduced water absorption in the cured state includes an olefinically unsaturated monomer and a capped poly(arylene ether) prepared by the reaction of an uncapped poly(arylene ether) with an anhydride capping agent. The capped poly(arylene ether) is isolated and/or purified by methods that reduce the concentrations of polar impurities that contribute to water absorption by the cured composition.Type: GrantFiled: December 10, 2009Date of Patent: April 24, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Kenneth Paul Zarnoch, John Robert Campbell, Amy Rene Freshour, Hua Guo, John Austin Rude, Prameela Susarla, Michael Alan Vallance, Gary William Yeager
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Patent number: 8148047Abstract: A carboxyl resin according to the present invention is obtained by a process including following steps: epoxy groups on a resin (a) having two or more epoxy groups in one molecule is made to react with 0.3-0.85 mol of a monocarboxylic acid (b) per one epoxy-group equivalent weight to obtain a reaction product (c); the epoxy group or groups on the reaction product (c) are made to react with 0.15-0.95 mol of a polybasic acid (d) per one epoxy-group equivalent weight to obtain a reaction product (e); and the epoxy group or groups on the reaction product (e) are further made to react with 1.0-5.0 mol of a monocarboxylic acid (f) per one epoxy-group equivalent weight. The carboxyl resin thus obtained has an acid value within a range from 20 to 200 mgKOH/g and is soluble in an organic solvent.Type: GrantFiled: February 20, 2009Date of Patent: April 3, 2012Assignee: Goo Chemical Company, Ltd.Inventors: Koichi Ikegami, Noboru Kohiyama, Teppei Nishikawa, Michiya Higuchi, Nobuhito Hamada, Hiroko Daido, Chieko Inui, Tatsuya Kubo
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Patent number: 8133650Abstract: A polyester resin which includes acid components having aromatic dibasic acid component and trivalent or higher acid component; alcohol components including aliphatic, aromatic or cycloaliphatic diol component, and trihydric or higher alcohol component; polyolefin polyol having 1,800 to 2,500 number average molecular weight and hydroxyl value of 40 to 55 KOHmg/g; and wax having melting point of 80 to 110, wherein the amount of the polyolefin polyol is 0.1 to 2 weight % and the amount of the wax is 0.5 to 15 weight % with respect to the total polyester resin. Also disclosed is a method for preparing polyester resin by (a) carrying out an esterification reaction or an ester exchange reaction with the acid components, the alcohol components, and the polyolefin polyol; and (b) carrying out a polycondensation reaction for reaction product of the esterification or ester exchange reaction in the presence of the wax.Type: GrantFiled: July 10, 2008Date of Patent: March 13, 2012Assignee: SK Chemicals Co., Ltd.Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
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Patent number: 8114940Abstract: The present invention relates to a phenolic hydroxy group-containing rubber-modified polyamide resin which has, in the molecule, a phenolic hydroxy group-containing aromatic polyamide segment having a structure represented by the following formula (A) (wherein, m and n are average values and Ar represents a divalent aromatic group) and a butadiene (co)polymer segment selected from the following formula (B-1) or (B-2), —(CH2—CH?CH—CH2)X—??(B-1) —(CH2—CH?CH—CH2)Y—(CH2—CH(CN))Z—??(B-2) (wherein, each of x, y and z is an average value and 0.01?z/(y+z)?0.13, x represents a positive number of 5 to 200, and also y+z is a positive number of 10 to 200), and a resin composition containing said resin, in particular an epoxy resin composition; a cured product of said epoxy resin composition is excellent in flexibility, heat resistance and electrical properties especially at high temperature and high humidity.Type: GrantFiled: October 26, 2006Date of Patent: February 14, 2012Assignee: Nippon Kayaku Kabushiki KaishaInventors: Kazunori Ishikawa, Makoto Uchida, Shigeru Moteki
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Publication number: 20120021350Abstract: A polyester resin for a toner, obtained by polycondensing a carboxylic acid component and an alcohol component, wherein the carboxylic acid component and/or the alcohol component contains an aromatic compound represented by the formula (Ia): wherein R1a is a hydrogen atom, a hydroxyl group, or a methoxy group; and Xa is a hydrogen atom, an aldehyde group, an allyl group, a vinyl group, a methoxy group, or a hydroxyl group or carboxyl group which may have a linking group. The toner for electrophotography containing a polyester resin for a toner of the present invention is suitably used for a resin binder of a toner used in developing and the like of latent images formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: ApplicationFiled: April 23, 2010Publication date: January 26, 2012Applicant: KAO CORPORATIONInventors: Norihiro Fukuri, Takashi Kubo, Yasunori Inagaki
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Patent number: 8030441Abstract: A loose mixture formed of one or more solid inert materials and a hardenable resin dissolved in an organic solvent, in particular the remainder of the initial mix used for the manufacture of conglomerate stone sheets, is rendered inert by means of dielectric heating at a frequency of less than 300 MHz. A plant for implements a method where a loose mixture is formed of one or more solid inert materials and a hardenable resin dissolved in an organic solvent, in particular the remainder of the initial mix used for the manufacture of conglomerate stone sheets, is rendered inert by means of dielectric heating at a frequency of less than 300 MHz.Type: GrantFiled: July 10, 2007Date of Patent: October 4, 2011Inventor: Dario Toncelli
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Patent number: 7956154Abstract: A polymer containing a polyester polymer unit having the formula -(I-III-II)-, wherein III is derived form a di-carboxylic acid, wherein I is derived from 1,3 cyclohexanedimethanol, wherein II is derived from 1,4 cyclohexanedimethanol and wherein the polymer is a solid at room temperature.Type: GrantFiled: September 26, 2006Date of Patent: June 7, 2011Inventors: John N. Argyropoulos, Marcos Pini Franca, Gary E. Spilman
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Publication number: 20100261867Abstract: A toner for an electrophotographic image forming process or an electrostatic printing process, and a polyester resin for the toner are disclosed. The polyester resin comprises: acid components including aromatic dibasic acid component and trivalent or higher acid component; alcohol components including aliphatic, aromatic or cycloaliphatic diol component, and trihydric or higher alcohol component; poly olefin polyol having number average molecular weight of 1,800 to 2,500 and hydroxyl value of 40 to 55 KOHmg/g; and wax having melting point of 80 to 110° C., wherein the amount of the poly olefin polyol is 0.1 to 2 weight % and the amount of the wax is 0.5 to 15 weight % with respect to the total polyester resin.Type: ApplicationFiled: July 10, 2008Publication date: October 14, 2010Inventors: Young-Man Yoo, Jae-Kyoung Roh, Kye-Yune Lee, Tae-Woong Lee
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Patent number: 7799424Abstract: A resin composition includes an aliphatic polyester resin. The resin has carboxyl groups at the end termini of the molecular chain and at least one compound represented by the general formula (I), the compound being added to the resin to cap a part or all of the carboxyl groups at the end termini of the molecular chain of the resin. A process for producing a fiber includes mixing a pellet comprising an aliphatic polyester resin having carboxyl groups at the end termini of the molecular chain with a compound represented by the general formula (I) so that the content of the compound becomes 0.1 to 8% by weight and then melt-spinning the resulting mixture under the conditions of a spinning temperature of 200 to 250 C.°, a melt residence time of 180 to 1800 sec and a spinning rate of 500 to 10000 m/min.Type: GrantFiled: March 27, 2006Date of Patent: September 21, 2010Assignee: Toray Industries, Inc.Inventors: Katsuhiko Mochiduki, Takaaki Mihara
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Patent number: 7776991Abstract: The disclosure contains a medical article comprising a polymer containing polyesters and, optionally, agents for use with medical articles and methods of fabricating the same are disclosed. The medical article generally comprises an implantable substrate having a coating, and the coating contains a polymer comprising a polymeric product of a reaction comprising a polyol and a polycarboxylic acid.Type: GrantFiled: June 19, 2009Date of Patent: August 17, 2010Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Stephen D. Pacetti, Yiwen Tang
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Patent number: 7737244Abstract: The present invention relates to a process for preparing polyarylate, and more specifically, to a process for preparing polyarylate by interfacial polymerization of a bivalent phenol compound and an aromatic dicarboxylic acid or a halide thereof, which comprises mixing a cationic catalyst for the phase transition and a nonionic surfactant in a predetermined ratio, to further increase the yield of polyarylate, as compared with the case of using each of the nonionic surfactant and the cationic catalyst for the phase transition alone.Type: GrantFiled: February 16, 2007Date of Patent: June 15, 2010Assignee: LG Chem, Ltd.Inventors: Dae-Woo Nam, Dong-Ryul Kim, Hyo-Sun Lee, Boong-Goon Jeong, Sang-Uk Ryu, Hee-Jung Kim, Ju-Eun Cha
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Patent number: 7687594Abstract: A random amorphous copolyester is synthesized by using diacid monomers and diol monomers. The random amorphous copolyester has a structure of the formula (I): wherein R1, R2 is an aromatic or aliphatic monomer, A is 0-0.8, B is 0-0.8, C is 0-1, D is 0-1, E is 0-0.8, F is 0-0.8, C+D<0.2 and A+B+E+F<0.8. The diacid monomer comprises TPA and an aromatic or aliphatic diacid monomer, the diol monomer comprises EG, 1,3 and 1,4-CHDM, and an aromatic or aliphatic diol monomer.Type: GrantFiled: June 24, 2008Date of Patent: March 30, 2010Assignee: Industrial Technology Research InstituteInventors: Chi-Yuan Hung, Cheng-Hsing Fan, Yuhsin Tsai, Fu-Yu Tsai
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Patent number: 7674878Abstract: Disclosed is a method of producing a non-adhering granulate above the glass-transition temperature comprising a polyester material, in which the polyester material is introduced into a cooling water flow as a melt and is separated from the cooling water after passing through a cooling stretch. The dwell time of the polyester material in the cooling stretch is 0.2-5 sec, and the cooling water has a pressure of at least 2 bar along the cooling stretch. For the thus obtained granulate, post-crystallization is not required, at least not in every case. It has been shown that the granulate does not adhere, even without post-crystallization and mechanical movement if no additional external input of energy takes place. Even during heating under pressure, no adhesion could be observed.Type: GrantFiled: March 13, 2007Date of Patent: March 9, 2010Assignee: Uhde Inventa-Fischer AGInventors: Kurt Hanimann, Werner Stibal
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Publication number: 20090096136Abstract: A stamp is comprised of a thiol-ene polymer, wherein the thiol-ene polymer allows for creation of micro-scale or nano-scale patterns useful in soft or imprint lithography. A patterned thiol-ene polymer is fabricated by casting a thiol-ene mixture onto a patterned mold, curing the thiol-ene mixture to form the patterned thiol-ene polymer, and peeling off the patterned thiol-ene polymer from the silicon mold. A stamp comprised of a thiol-ene polymer may be replicated by exposing the to oxygen plasma to form a hydrophilic mold, exposing the hydrophilic mold to a fluorinating agent under vacuum conditions to form a functionalized surface of the hydrophilic mold, casting a thiol-ene mixture on top of the functionalized surface, photocuring the thiolene mixture to form a replica thiol-ene polymer, and peeling off the replica thiol-ene polymer.Type: ApplicationFiled: October 13, 2008Publication date: April 16, 2009Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Craig J. Hawker, Luis M. Campos, Ines Meinel
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Patent number: 7511081Abstract: The present invention relates to a recycling method of a mixed waste of polyester and polyamide (hereinafter, referred to as “mixed waste”) in which polyesters including polyethylene terephthalate and polyamides are inseparable from one another. In accordance with the recycling method of the present invention, it is possible to prepare a solid block polymer having an acid value of 1 to 150 mgKOH/g, a weight average molecular weight of 3,000 to 50,000 and a softening point of 10 to 150° C., or a liquid polyester-amide block polymer composition having good compatibility, solubility and dispersibility. In addition, the polymer having an acid value of more than 20 mgKOH/g is reacted with a basic compound to form a neutralized salt which is then used to prepare a water-soluble polyester-amide block polymer composition.Type: GrantFiled: March 24, 2005Date of Patent: March 31, 2009Inventors: Do-Gyun Kim, Hyo-Sung Kim
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Publication number: 20090071697Abstract: The present invention relates to a phenolic hydroxy group-containing rubber-modified polyamide resin which has, in the molecule, a phenolic hydroxy group-containing aromatic polyamide segment having a structure represented by the following formula (A) (wherein, m and n are average values and Ar represents a divalent aromatic group) and a butadiene (co)polymer segment selected from the following formula (B-1) or (B-2), —(CH2—CH?CH—CH2)X—??(B-1) —(CH2—CH?CH—CH2)Y—(CH2—CH(CN))Z—??(B-2) (wherein, each of x, y and z is an average value and 0.01?z/(y+z)?0.13, x represents a positive number of 5 to 200, and also y+z is a positive number of 10 to 200), and a resin composition containing said resin, in particular an epoxy resin composition; a cured product of said epoxy resin composition is excellent in flexibility, heat resistance and electrical properties especially at high temperature and high humidity.Type: ApplicationFiled: October 26, 2006Publication date: March 19, 2009Inventors: Kazunori Ishikawa, Makoto Uchida, Shigeru Moteki
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Patent number: 7399799Abstract: Disclosed is a flame-retardant polyester polymer dyeable with a cationic dye, a method of producing the same, a copolyester fiber using the same, and fiber products using the copolyester fiber. In the method, after a dimethyl isophthalate component containing metal sulfonate of Formula 2 separately reacts with ethylene glycol so that an extent of the ester interchange reaction is 95% or more to synthesize bis(hydroxyethyl terephthalate) containing metal sulfonate of Formula 3, bis(hydroxyethyl terephthalate) is fed so that a content of bis(hydroxyethyl terephthalate) is 0.01-5 mol % based on a diacid component in a polymer in a course of producing polyester, a phosphorus-based flame retardant of Formula 1 is fed so that a content of a phosphorus atom is 500-40000 ppm based on the polymer, and the mixture is copolymerized. The polyester polymer is dyeable with cationic dye while having excellent flame retardancy, and can be melt-spun like other polymers capable of being melt-spun.Type: GrantFiled: September 30, 2004Date of Patent: July 15, 2008Assignee: Hyosung CorporationInventors: Seung-Cheol Yang, Eung-Soo Kim, Yang-Kuk Son, Ik-Hyeon Kwon
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Patent number: 7342050Abstract: The invention concerns a method for preparing a lactic acid ester composition based on a lactic acid composition involving a step of transforming the composition into a lactic acid oligomeric composition having a mean degree of polymerisation (DPM) ranging between 2 and 30 approximately; and a step which involves mixing and reacting said oligomeric composition with an alcohol, in the presence of a transesterification catalyst, to esterify all or part of the lactic acid contained in said oligomeric composition. The invention also concerns the use of ethyl lactate as solvent for preparing gelified compositions.Type: GrantFiled: December 26, 2000Date of Patent: March 11, 2008Assignee: Roquette FreresInventors: Patrick Fuertes, Rodolphe Tamion, Guy Fleche, Serge Comini
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Patent number: 7304121Abstract: The present invention provides a liquid-crystalline polyester obtainable by a method comprising the steps of: (1) preparing a prepolymer consisting of the repeating units represented by formulae (I), (II), (III) and (IV): wherein, p, q, r and s represent relative molar proportions (mol %) of the repeating units in the liquid-crystalline polyester resin and satisfy the following formulae: 60?p?80, 10?r?20, 10?q+s?20, 0.05?s/(q+s)?0.3, p+q+r+s=100; and (2) heating the prepolymer in substantially solid state at 250-350° C., provided that the liquid crystalline polyester has a deflection temperature under load of 280-340° C., and a melt viscosity of 10-60 Pa·s.Type: GrantFiled: July 13, 2005Date of Patent: December 4, 2007Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo KenkyujoInventors: Hiroyuki Kato, Motoki Asahara, Tetsuhide Sawada
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Patent number: 7235192Abstract: A method of preparing a capped poly(arylene ether) resin includes reacting a capping agent with a blend of two or more poly(arylene ether) resins having different intrinsic viscosities. Cured compositions prepared from these capped poly(arylene ether) resins exhibit improved balances of stiffness, toughness, and dielectric properties compared to compositions with two or more separately capped and isolated poly(arylene ether) resins.Type: GrantFiled: July 1, 2003Date of Patent: June 26, 2007Assignee: General Electric CompanyInventors: Gary William Yeager, Hua Guo, Zhiqing Lin, Shahid Murtuza
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Patent number: 7173102Abstract: Facially amphiphilic polymers and articles made therefrom having biocidal surfaces are disclosed. The polymers can inhibit the growth of microorganisms in contact with the surface or in areas adjacent to said biocidal surface. There is also disclosed a method to identify and optimize the facial amphiphilicity of polyamide, polyester, polyurea, polyurethane, polycarbonate and polyphenylene polymers. Utility as a contact disinfectant is disclosed.Type: GrantFiled: March 7, 2002Date of Patent: February 6, 2007Assignee: The Trustees of the University of PennsylvaniaInventors: William F. DeGrado, Gregory N. Tew, Michael L. Klein, Dahui Liu, Jing Yuan
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Patent number: 7166690Abstract: The present invention relates to a method for the recycling waste polyester resins and the reclaimed materials therefrom. The method for recycling waste polyester resins according to one embodiment the present invention comprises (a) depolymerizing waste polyester resin; (b) polycondensing the depolymerized product from step (a) with a polyhydric alcohol to provide a polyester polymer having an acid value of 10–150 mgKOH/g; and (c) recovering the polyester polymer in solid or liquid form if the polyester polymer from step (b) has an acid value of more than 20 mgKOH/g or recovering the polyester polymer in solid form if the polyester polymer from step (b) has an acid value of less than 20 mgkOH/g. The reclaimed polyester resin according to the present invention has the excellent compatibility, dispersibility, and adhesive property for various media, and can be used easily neutralized and dissolved in water. Accordingly, the polyester resin can be used as a useful material for industrial products.Type: GrantFiled: December 14, 2002Date of Patent: January 23, 2007Assignee: Samsung Electronics Co., Ltd.Inventor: Do-Gyun Kim
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Patent number: 7148296Abstract: A thermoset composition exhibiting reduced water absorption in the cured state includes an olefinically unsaturated monomer and a capped poly(arylene ether) prepared by the reaction of an uncapped poly(arylene ether) with an anhydride capping agent. The capped poly(arylene ether) is isolated and/or purified by methods that reduce the concentrations of polar impurities that contribute to water absorption by the cured composition.Type: GrantFiled: October 3, 2003Date of Patent: December 12, 2006Assignee: General Electric CompanyInventors: Kenneth Paul Zarnoch, John Robert Campbell, Amy Rene Freshour, Hua Guo, John Austin Rude, Prameela Susarla, Michael Alan Vallance, Gary William Yeager
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Patent number: 7147800Abstract: A method for making platform molecules comprising: reacting 4-alkoxy benzoyl chloride with R2-hydroquinone under first conditions effective to produce bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene comprising bis terminal alkoxy groups wherein R2 is a bulky organic group; and, subjecting the bis 1,4[4-alkoxy-benzoyloxy]-R2-phenylene to second conditions effective to selectively cleave the bis terminal alkoxy groups to produce a solution comprising complexes comprising diphenolic platform molecules comprising bis terminal hydroxyl groups, the second conditions also being effective to precipitate the complexes out of the solution.Type: GrantFiled: December 24, 2003Date of Patent: December 12, 2006Assignee: Southwest Research InstituteInventors: Stephen T. Wellinghoff, Douglas P. Hanson
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Patent number: 6974857Abstract: An end-capped quinoxaline-containing hyperbranched ether-ketone polymer having repeating units of the formula: wherein n represents the degree of polymerization for the parent hyperbranched polymer, x represents the degree of endgroup functionalization, x has a value of 0.05 to 1.0, and G is selected from the group consisting of and alkyl having 2 to 16 carbon atoms, and a method for preparing the polymer are provided.Type: GrantFiled: December 8, 2003Date of Patent: December 13, 2005Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Jong-Beom Baek, Loon-Seng Tan
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Patent number: 6962965Abstract: A functionalized poly(arylene ether) having a pendant carbon—carbon double bond is prepared by reacting the hydroxy end group of a poly(arylene ether) with a polyisocyanate compound to produce a urethane-capped poly(arylene ether) having pendant isocyanate functionality, which is then reacted with a polyfunctional compound having a carbon—carbon double bond and a hydroxy, thiol, or amino group. The functionalized poly(arylene ether) is useful as a component of a curable composition in which its carbon—carbon double bond copolymerizes with one or more olefinically unsaturated comonomers.Type: GrantFiled: February 20, 2004Date of Patent: November 8, 2005Assignee: General Electric CompanyInventor: Gary William Yeager
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Patent number: 6897282Abstract: The invention relates to a method of forming a polyphenylene ether resin containing residual aliphatic unsaturation. A polyphenylene ether is reacted with a capping agent in a solvent to form the polyphenylene ether resin containing residual aliphatic unsaturation, which is precipitated from solution by combining the solution with an antisolvent. The precipitated polyphenylene ether resin containing residual aliphatic unsaturation has lower levels of residual impurities than the same compound isolated by devolatilization.Type: GrantFiled: October 3, 2003Date of Patent: May 24, 2005Assignee: General ElectricInventors: Amy Freshour, Hua Guo, Robert L. Howe, Edward N. Peters, Gary William Yeager
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Patent number: 6849707Abstract: A quinoxaline-containing hyperbranched ether-ketone polymer having repeating units of the formula: and a method for preparing the polymer are provided.Type: GrantFiled: October 23, 2003Date of Patent: February 1, 2005Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Jong-Beom Baek, Loon-Seng Tan
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Patent number: 6835804Abstract: A polymer comprising recurring units of formula (2) is prepared by effecting deblocking reaction on a polymer comprising recurring units of formula (1) in the presence of an acid catalyst. In the formulae, R1 and R4 are H or methyl, R2 and R3 are C1-C10 alkyl, or R2 and R3 may form a ring, R5 is H, hydroxyl, alkyl, alkoxy or halogen, R6 and R7 are H, methyl, alkoxycarbonyl, cyano or halogen, R8 is C4-C20 tertiary alkyl, n is an integer of 0 to 4, p is a positive number, q and r each are 0 or a positive number, exclusive of q=r=0, p1 is a positive number, p2 is 0 or a positive number, and p1+p2=p. The polymer thus produced has a narrower molecular weight distribution than polymers produced by the prior art methods. A resist composition comprising the polymer as a base resin has advantages including a dissolution contrast of resist film, high resolution, exposure latitude, process flexibility, good pattern profile after exposure, and minimized line edge roughness.Type: GrantFiled: December 6, 2001Date of Patent: December 28, 2004Assignee: Shin-Etsu Chemical Co., LTD.Inventors: Takanobu Takeda, Osamu Watanabe
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Patent number: 6833460Abstract: The rate of aminolysis of butyrolactones is predictably adjusted by attaching a substituent having a known field effect value (F) to the alpha position before reacting the substituted buytrolactone with an amine. The aminolysis product is a gamma-hydroxy amide. The resulting materials are useful as the cross-linking agents in a variety of coatings and coatings processes.Type: GrantFiled: November 28, 2001Date of Patent: December 21, 2004Assignee: E. I. du Pont de Nemours and CompanyInventor: Albert Gordon Anderson
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Patent number: 6800220Abstract: The present invention discloses an optically active polyester comprising at least constituent units represented by the general formula (I) and the general formula (II): wherein Ar1 and Ar2 each independently represents a bivalent aromatic group or a bivalent heteroaromatic group, and X1 and X2 each independently represents a hydrogen atom or an electron-withdrawing group, wherein A represents a bivalent substituent.Type: GrantFiled: May 14, 2002Date of Patent: October 5, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Masatoshi Yumoto, Mitsuyoshi Ichihashi, Kouya Kawabata