Two Or More Phenolic Reactants Patents (Class 528/193)
  • Patent number: 7740941
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: June 22, 2010
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7737244
    Abstract: The present invention relates to a process for preparing polyarylate, and more specifically, to a process for preparing polyarylate by interfacial polymerization of a bivalent phenol compound and an aromatic dicarboxylic acid or a halide thereof, which comprises mixing a cationic catalyst for the phase transition and a nonionic surfactant in a predetermined ratio, to further increase the yield of polyarylate, as compared with the case of using each of the nonionic surfactant and the cationic catalyst for the phase transition alone.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: June 15, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Dae-Woo Nam, Dong-Ryul Kim, Hyo-Sun Lee, Boong-Goon Jeong, Sang-Uk Ryu, Hee-Jung Kim, Ju-Eun Cha
  • Patent number: 7704605
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: April 27, 2010
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 7674878
    Abstract: Disclosed is a method of producing a non-adhering granulate above the glass-transition temperature comprising a polyester material, in which the polyester material is introduced into a cooling water flow as a melt and is separated from the cooling water after passing through a cooling stretch. The dwell time of the polyester material in the cooling stretch is 0.2-5 sec, and the cooling water has a pressure of at least 2 bar along the cooling stretch. For the thus obtained granulate, post-crystallization is not required, at least not in every case. It has been shown that the granulate does not adhere, even without post-crystallization and mechanical movement if no additional external input of energy takes place. Even during heating under pressure, no adhesion could be observed.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: March 9, 2010
    Assignee: Uhde Inventa-Fischer AG
    Inventors: Kurt Hanimann, Werner Stibal
  • Patent number: 7671164
    Abstract: A method of making a polycarbonate is described. The method comprises melt reacting an ester-substituted diaryl carbonate and a multifunctional compound of the formula: in the presence of catalyst to form an oligomer comprising less than 2,000 ppm of an ester-linked terminal group, and melt polymerizing the oligomer to form a polycarbonate. Use of specific reaction conditions produces a polycarbonate having an Mw of greater than or equal to 25,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising units derived from the multifunctional compound, including homopolycarbonates, aliphatic copolycarbonates further comprising units derived from an aromatic dihydroxy compound, and aliphatic polycarbonate-polyesters, are also disclosed, as are a thermoplastic composition and an article including the disclosed polycarbonates.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: March 2, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Hans-Peter Brack, Maarten Antoon Jan Campman, Jorge Garcia Agudo, Jan Henk Kamps, Hans Looij, Fernando Olmedo Fernandez, Dennis James Patrick Maria Willemse
  • Publication number: 20090212451
    Abstract: The invention relates to a method of preparing wholly aromatic polyester including: mixing monomers, introducing the mixed monomers into a reactor having a rectangular or trapezoidal plate type stirring impeller, and polymerizing the introduced monomers through esterification with a power per unit volume of 10˜60 kW/m3, a length (L) to diameter (D) ratio of the stirring impeller is 1˜3:1, and a distance between the bottom of the reactor and a lower portion of the stirring impeller is 1/100˜ 1/15 times of the diameter (D); b) pulverizing the obtained polymer; and c) solid state polymerizing the pulverized polymer.
    Type: Application
    Filed: November 1, 2006
    Publication date: August 27, 2009
    Applicant: SAMSUNG FINE CHEMICALS CO., LTD.
    Inventors: Mahn Jong Kim, Jong Hwa Yun, Youn Eung Lee, Tae Jun Ok, Sun Hwa Jang, Hyun Min Kim
  • Patent number: 7541417
    Abstract: A process comprising the steps of dissolving a dihydric phenol in a solvent to form a solution A, contacting the solution A with an adsorbent material selected from the group consisting of metal oxides, modified metal oxides, activated carbons, and clays, filtering the adsorbent material to form a solution B, adding an anti-solvent to the solution B to form a solution C, and distilling the solution C, wherein the dihydric phenol is represented by Formula (I): wherein R is a hydrogen atom or an aliphatic functionality having 1 to 6 carbon atoms and n is an integer having a value of 1 to 4.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: June 2, 2009
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Sunil Ashtekar, Mahesh Malusare, Gurram Kishan, Pushpa Narayanan, Ramanarayanan GV, Arun Dixit, Pradeep Nadkarni, Jan Plen Lens
  • Patent number: 7528210
    Abstract: A process comprising the steps of dissolving a dihydric phenol in a solvent to form a solution A; contacting the solution A with a zeolite; filtering the zeolite to form a solution B; adding an anti-solvent to the solution B to form a solution C; and distilling the solution C; wherein the dihydric phenol is represented by Formula (I): wherein R is a hydrogen atom or an aliphatic functionality having 1 to 6 carbon atoms and n is an integer having a value 1 to 4.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: May 5, 2009
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Guohua Xiu, Tong Sun, Jan Plen Lens, Sunil Ashtekar, Mahesh Malusare, Gurram Kishan, Pushpa Narayanan
  • Patent number: 7524562
    Abstract: The invention includes embodiments that relate to a method of improving the abrasion resistance of a plastic article. The method comprises: (a) providing a composition comprising at least one e-beam active thermoplastic polymeric material; (b) forming an article from the composition of step (a); and (c) exposing the article formed in step (b) to an electron beam source. The invention also includes embodiments that relate to an article comprising an abrasion resistant surface.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: April 28, 2009
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Ryo Tamaki, Steven Thomas Rice, Hieu Minh Duong, Xian-Zhi Zhou, Gary Charles Davis, Elliott West Shanklin
  • Publication number: 20090105443
    Abstract: A method of making a polycarbonate is described. The method comprises melt reacting an ester-substituted diaryl carbonate and a multifunctional compound of the formula: in the presence of catalyst to form an oligomer comprising less than 2,000 ppm of an ester-linked terminal group, and melt polymerizing the oligomer to form a polycarbonate. Use of specific reaction conditions produces a polycarbonate having an Mw of greater than or equal to 25,000 g/mol as determined by gel-permeation chromatography relative to polystyrene standards. Polycarbonates comprising units derived from the multifunctional compound, including homopolycarbonates, aliphatic copolycarbonates further comprising units derived from an aromatic dihydroxy compound, and aliphatic polycarbonate-polyesters, are also disclosed, as are a thermoplastic composition and an article including the disclosed polycarbonates.
    Type: Application
    Filed: May 21, 2008
    Publication date: April 23, 2009
    Inventors: Hans-Peter BRACK, Maarten Antoon Jan CAMPMAN, Jorge GARCIA AGUDO, Jan Henk KAMPS, Hans LOOIJ, Fernando OLMEDO FERNANDEZ, Dennis James Patrick Maria WILLEMSE
  • Patent number: 7511114
    Abstract: Colored aromatic polycarbonate resin compositions are prepared by dispersing a colorant (b) selected from phthalocyanine-based compounds, anthraquinone-based compounds and ultramarine blue in a polyalkyleneglycol compound (c) having a number-average molecular weight of 62 to 4000 of formula (2): HO—[—CHR1—CHR2—]m—OH??(2) where R1, R2, R3 and R4 are independently hydrogen atoms or alkyl groups, and m is not less than 1. The dispersion is added to an aromatic polycarbonate resin (a) kept in a molten state which has a viscosity-average molecular weight of not less than 16000 and contains a branched constitutional unit of formula (1): in an amount of 0.3 to 0.95 mol % where X is a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, or a divalent connecting group —O—, —S—, —CO—, —SO— and —SO2—.
    Type: Grant
    Filed: November 28, 2006
    Date of Patent: March 31, 2009
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masaaki Miyamoto, Takao Tayama, Kiyoji Kuma, Eiji Fujimoto
  • Patent number: 7510768
    Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: March 31, 2009
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Publication number: 20090076241
    Abstract: Synthesis methods for creating polymeric compounds comprising dihydroxyphenyl derivatives (DHPD), or DHPp i.e. polymers modified with DHPD, with desired surface active effects are described. The polymer backbone of DHPp has structural or performance features that can be tailored to control physical properties of DHPp, allowing it to be useful for different applications i.e. tissue adhesives or sealants, adhesion promoting coatings, and antifouling coatings.
    Type: Application
    Filed: September 28, 2008
    Publication date: March 19, 2009
    Inventor: Bruce P. Lee
  • Publication number: 20090042294
    Abstract: A dihydroxyphenyl cross-linked macromolecular network is provided that is useful in artificial tissue and tissue engineering applications, particularly to provide a synthetic macromolecular network for a wide variety of tissue types. In particular, artificial or synthetic cartilage, vocal cord material, vitreous material, soft tissue material and mitral valve material are described. In an embodiment, the network is composed of tyramine-substituted and cross-linked hyaluronan molecules, wherein cross-linking is achieved via peroxidase-mediated dityramine-linkages that can be performed in vivo. The dityramine bonds provide a stable, coherent hyaluronan-based hydrogel with desired physical properties.
    Type: Application
    Filed: September 15, 2008
    Publication date: February 12, 2009
    Applicant: The Cleveland Clinic Foundation
    Inventors: Anthony Calabro, Lee Akst, Daniel Alam, James Chan, Aniq B. Darr, Kiyotaka Fukamachi, Richard A. Gross, David Haynes, Keiji Kamohara, Daniel P. Knott, Hilel Lewis, Alex Melamud, Anthony Miniaci, Marshall Strome
  • Patent number: 7399799
    Abstract: Disclosed is a flame-retardant polyester polymer dyeable with a cationic dye, a method of producing the same, a copolyester fiber using the same, and fiber products using the copolyester fiber. In the method, after a dimethyl isophthalate component containing metal sulfonate of Formula 2 separately reacts with ethylene glycol so that an extent of the ester interchange reaction is 95% or more to synthesize bis(hydroxyethyl terephthalate) containing metal sulfonate of Formula 3, bis(hydroxyethyl terephthalate) is fed so that a content of bis(hydroxyethyl terephthalate) is 0.01-5 mol % based on a diacid component in a polymer in a course of producing polyester, a phosphorus-based flame retardant of Formula 1 is fed so that a content of a phosphorus atom is 500-40000 ppm based on the polymer, and the mixture is copolymerized. The polyester polymer is dyeable with cationic dye while having excellent flame retardancy, and can be melt-spun like other polymers capable of being melt-spun.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: July 15, 2008
    Assignee: Hyosung Corporation
    Inventors: Seung-Cheol Yang, Eung-Soo Kim, Yang-Kuk Son, Ik-Hyeon Kwon
  • Patent number: 7393467
    Abstract: Provided is a liquid-crystalline polyester with good properties obtainable by subjecting a prepolymer consisting of the repeating units represented by formulae (I), (II), (III) and (IV): to heat treatment in a substantially solid state.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: July 1, 2008
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Motoki Asahara, Tetsuhide Sawada, Hiroyuki Kato
  • Patent number: 7351786
    Abstract: Disclosed are a polyhydroxyalkanoate, containing in a polymer molecule thereof a monomer unit represented by the following general formula (1): (wherein R1 represents a substituent to a cyclohexyl group, where R1 is a H atom, a CN group, a NO2 group, a halogen atom, a CH3 group, a C2H5 group, a C3H7 group, a CF3 group, a C2F5 group, or a C3F7 group; and if there are two or more monomer units, R1 may be different from every monomer unit), and a binder resin using the polyhydroxyalkanoate. The binder resin is biodegradable, so that the binder resin is more responsible for the conservation of natural environment or the like. Also, the binder resin facilitates deinking in the deinking process using an alkali, so that the binder resin accelerates recycling of used copying paper. Furthermore, the binder resin satisfies the desired characteristics of a toner for developing an electrostatic charge image.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: April 1, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tsutomu Honma, Tetsuya Yano, Shinya Kozaki
  • Patent number: 7344657
    Abstract: An aromatic liquid-crystalline polyester composition is provided, which comprises at least one compound selected from an aliphatic carboxylate aryl ester and an aromatic carboxylic anhydride; an aromatic liquid-crystalline polyester; and a solvent containing at least 30% by weight of a halogen-substituted phenol compound. Using the composition, an aromatic liquid-crystalline polyester film with a low viscosity in melting state can be obtained.
    Type: Grant
    Filed: September 23, 2005
    Date of Patent: March 18, 2008
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Shiro Katagiri
  • Patent number: 7341675
    Abstract: Liquid crystalline polymers containing specified ratios of repeat units derived from hydroquinone, 2,6-naphthalenedicarboxylic acid, 4-hydroxybenzoic acid and optionally terephthalic acid have exceptionally high heat distortion temperatures, making especially useful for service at high temperatures. Compositions containing reinforcing agents, especially fibrous or platy reinforcing agents are particularly useful. These polymers and compositions are useful for electrical and electronic connectors, and as films for the electronics industry, and for other uses.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: March 11, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Richard Alan Jackson, Marion G. Waggoner
  • Patent number: 7304121
    Abstract: The present invention provides a liquid-crystalline polyester obtainable by a method comprising the steps of: (1) preparing a prepolymer consisting of the repeating units represented by formulae (I), (II), (III) and (IV): wherein, p, q, r and s represent relative molar proportions (mol %) of the repeating units in the liquid-crystalline polyester resin and satisfy the following formulae: 60?p?80, 10?r?20, 10?q+s?20, 0.05?s/(q+s)?0.3, p+q+r+s=100; and (2) heating the prepolymer in substantially solid state at 250-350° C., provided that the liquid crystalline polyester has a deflection temperature under load of 280-340° C., and a melt viscosity of 10-60 Pa·s.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: December 4, 2007
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Hiroyuki Kato, Motoki Asahara, Tetsuhide Sawada
  • Patent number: 7271235
    Abstract: It is to provide a branched aromatic polycarbonate excellent in hue and excellent in melt properties such as melt strength.
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: September 18, 2007
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masaaki Miyamoto, Takao Tayama
  • Patent number: 7238769
    Abstract: The present invention provides a method for joining liquid-crystalline polyester resin composition parts, characterized in that the melting point of the liquid crystalline polyester resin measured by differential scanning calorimeter is 190-250° C. and that the parts are jointed by means of welding. By using the method of the present invention, jointed articles with sufficient joint strength are provided with accuracy.
    Type: Grant
    Filed: May 10, 2005
    Date of Patent: July 3, 2007
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Masaya Kitayama, Naoshi Saito
  • Patent number: 7198830
    Abstract: A polycarbonate resin composition obtained by blending a polycarbonate resin (A) obtained by forming a carbonate bond from 95 to 5 mol % of a dihydroxy compound having a fluorene structure represented by the general formula (1) and 5 to 95 mol % of a dihydroxy compound having a dimethanol structure represented by the general formula (2) and a carbonic diester and a polycarbonate resin (B) obtained by forming a carbonate bond from bisphenol A and a carbonic acid diester or phosgene in a ratio of (100×(A)/((A)+(B))=1 to 99% by weight and a polarizing sheet used the same.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: April 3, 2007
    Assignees: Mitsubishi Gas Chemical Company Inc., Fuji Kasei Co., Ltd.
    Inventors: Takayasu Fujimori, Noriyuki Kato, Shingo Kanasaki, Ryozo Kawai, Hiromi Kagaya
  • Patent number: 7179401
    Abstract: A thermotropic liquid crystalline polymer, which is obtainable by copolymerizing a trifunctional hydroxynaphthalene carboxylic acid represented by the general formula (I) and/or reactive derivative thereof with other polymerizing monomer(s) wherein one of m and n is 1 and the other is 2, and a composition including the polymer are provided. The molded article obtained from the thermotropic liquid crystalline polymer or the composition has less anisotropy in mechanical strength and improved weld strength.
    Type: Grant
    Filed: June 11, 2002
    Date of Patent: February 20, 2007
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kiichi Kometani, Hiroyuki Kato, Motoki Asahara
  • Patent number: 7175779
    Abstract: A thermotropic main-chain liquid crystalline homo- or copolymer forming a liquid crystalline phase and containing an aromatic monomer with functional groups in ortho- or meta-position. The polymer exhibits both isotropic and anisotropic properties. The present invention also provides a method for the preparation of the present polymers as well as a method of increasing the melt-processibility of polyester-based liquid crystalline polymers comprising the step of incorporating into the polymers 1 to 30 mol-% of, e.g., a ortho-substituted monomer with hydroxyl and/or carboxylic groups.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: February 13, 2007
    Assignee: Optatech Corporation
    Inventors: Hans Kricheldorf, Andreas Gerken
  • Patent number: 7173102
    Abstract: Facially amphiphilic polymers and articles made therefrom having biocidal surfaces are disclosed. The polymers can inhibit the growth of microorganisms in contact with the surface or in areas adjacent to said biocidal surface. There is also disclosed a method to identify and optimize the facial amphiphilicity of polyamide, polyester, polyurea, polyurethane, polycarbonate and polyphenylene polymers. Utility as a contact disinfectant is disclosed.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: February 6, 2007
    Assignee: The Trustees of the University of Pennsylvania
    Inventors: William F. DeGrado, Gregory N. Tew, Michael L. Klein, Dahui Liu, Jing Yuan
  • Patent number: 7166690
    Abstract: The present invention relates to a method for the recycling waste polyester resins and the reclaimed materials therefrom. The method for recycling waste polyester resins according to one embodiment the present invention comprises (a) depolymerizing waste polyester resin; (b) polycondensing the depolymerized product from step (a) with a polyhydric alcohol to provide a polyester polymer having an acid value of 10–150 mgKOH/g; and (c) recovering the polyester polymer in solid or liquid form if the polyester polymer from step (b) has an acid value of more than 20 mgKOH/g or recovering the polyester polymer in solid form if the polyester polymer from step (b) has an acid value of less than 20 mgkOH/g. The reclaimed polyester resin according to the present invention has the excellent compatibility, dispersibility, and adhesive property for various media, and can be used easily neutralized and dissolved in water. Accordingly, the polyester resin can be used as a useful material for industrial products.
    Type: Grant
    Filed: December 14, 2002
    Date of Patent: January 23, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Do-Gyun Kim
  • Patent number: 7160977
    Abstract: This invention relates to a blend of biodegradable polymers comprising: (A) about 70% to about 80% by weight of at least one flexible biodegradable polymer (A) having a glass transition less than about 0° C., (B) about 30% to about 20% by weight of at least one rigid biodegradable polymer (B) having a glass transition greater than about 10° C.; said percentages being based on the total weight of the polymer blend; wherein said polymer blend has a notched Izod impact strength according to ASTM D256 of at least 7.5 ft-lbs/in.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: January 9, 2007
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Candace Michele Tanner
  • Patent number: 7148311
    Abstract: Liquid crystal polyester derived from phenylene-naphthalene monomers and one or more comonomers display an improved balance of properties, including low melt viscosity, fast cycle time in molding, very low mold shrinkage, high tensile and/or flexural strength, solvent resistance, excellent barrier properties, low water absorption, low thermal expansion coefficient, excellent thermostability, and/or low flammability. The phenylene-naphthalene monomers are The one or more comonomers include 4-hydroxybenzoic acid, 2-hydroxy-6-naphthoic acid, terephthalic acid, isophthalic acid, and derivatives and combinations thereof.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: December 12, 2006
    Assignee: Rensselaer Polytechnic Institute
    Inventors: Brian Benicewicz, Jiping Shao
  • Patent number: 7138480
    Abstract: This invention relates to a process for the preparation of a 3-hydroxycarboxylic acid from a 3-hydroxynitrile. More specifically, 3-hydroxyvaleronitrile is converted to 3-hydroxyvaleric acid in high yield at up to 100% conversion, using as an enzyme catalyst 1) nitrile hydratase activity and amidase activity or 2) nitrilase activity of a microbial cell. 3-Hydroxyvaleric acid is used as a substitute for ?-caprolactone in the preparation of highly branched copolyester.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: November 21, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Michael G. Bramucci, Robert Dicosimo, Robert Fallon, John E. Gavagan, Frank Herkes, Lech Wilczek
  • Patent number: 7132497
    Abstract: An aromatic dihydroxy compound conforming to formula 1 is disclosed. Also disclosed are (co)polycarbonates derived from the compound. The novel (co)polycarbonates are characterized by their reduced water uptake and improved flowability.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: November 7, 2006
    Assignee: Bayer Materialscience Aktiengesellschaft
    Inventors: Helmut-Werner Heuer, Rolf Wehrmann
  • Patent number: 7132499
    Abstract: A polyester resin container with improved weatherability as well as colorlessness and heat resistance, made of a polyester resin composition comprising (A) 100 parts by weight of a polyester resin and (B) 0.01 to 10 parts by weight of a triazine ultraviolet absorber represented by formula (I): wherein R1 represents a straight-chain or branched alkyl group having 1 to 17 carbon atoms, which may have an alicyclic group at the terminal or in the chain thereof; and R2, R2?, R3, and R3? each represent a hydrogen atom or a methyl group.
    Type: Grant
    Filed: May 18, 2005
    Date of Patent: November 7, 2006
    Assignee: Asahi Denka Co., Ltd.
    Inventors: Etsuo Tobita, Yoshinori Negishi, Takahiro Horikoshi
  • Patent number: 7105106
    Abstract: Thermotropic liquid crystalline polymers are produced by the reaction of a polyester made from an aromatic dicarboxylic acid and a diol, one or more hydroxycarboxylic acids, a stoichiometric excess of an aromatic diol, and a carboxylic acid anhydride. Also disclosed are novel liquid crystalline polymers that may be produced by this process. These liquid crystalline polymers are useful as molding resins and shaped articles thereof are produced. In particular, the articles include films, sheets, containers and portions thereof comprising these LCPs.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: September 12, 2006
    Assignee: E. I. du Pont de Nemour and Company
    Inventors: Michael Robert Samuels, Marion Glen Waggoner, Julius Uradnisheck
  • Patent number: 7087704
    Abstract: It is an object of the present invention to manufacture high quality thermotropic liquid-crystalline polymer generating no low boiling gas and inducing no discoloration resulted from thermal degradation at high yield. To manufacture a liquid-crystalline polymer having 50 mol % or larger ratio of constitutive unit introduced from 4-hydroxybenzoic acid, the reaction is conducted under the presence of an acylating agent and of a catalyst quantity of aromatic sulfonic acid.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: August 8, 2006
    Assignee: Polyplastics Co., Ltd.
    Inventors: Keiichi Kanaka, Shinya Yamada
  • Patent number: 7084233
    Abstract: A subject for the invention is to provide a branched aromatic polycarbonate which is excellent in hue and in melt characteristics such as melt strength. The invention provides a branched aromatic polycarbonate having a viscosity-average molecular weight of 16,000 or higher obtained by the transesterification method, characterized in that the ratio of the weight-average molecular weight (Mw) to number-average molecular weight (Mn) as measured by gel permeation chromatography and calculated for standard polystyrene (Mw/Mn) is in the range of from 2.8 to 4.5 and that the proportion of the number of moles of all structural units yielded by a rearrangement reaction in the course of melt polymerization reaction to 1 mol of structural units having the framework of an aromatic dihydroxy compound used as a starting material is higher than 0.3 mol % and not higher than 0.95 mol.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: August 1, 2006
    Assignees: Mitsubishi Chemical Corporation, Mitsubishi Engineering-Plastics Corporation
    Inventors: Masaaki Miyamoto, Takao Tayama, Hiroshi Nakano
  • Patent number: 7081509
    Abstract: The present invention relates to a process for preparing highly functional hyperbranched polyesters which comprises reacting a reaction solution comprising solvent and (a) one or more dicarboxylic acids or one or more derivatives thereof with one or more at least trifunctional alcohols (b) or one or more tricarboxylic acids or higher polycarboxylic acids or one or more derivatives thereof with one or more diols (c) or one or more tricarboxylic acids or higher polycarboxylic acids or one or more derivatives thereof with one or more at least trifunctional alcohols (d) or one or more di- or polyhydroxycarboxylic acids (e) or one or more hydroxydi- or hydroxypolycarboxylic acids or mixtures of at least two of the above reaction solutions in the presence of an enzyme at temperatures above 60° C. and pressures above 500 mbar.
    Type: Grant
    Filed: December 18, 2002
    Date of Patent: July 25, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Eva Wagner, Bernd Bruchmann, Dietmar Haering, Peter Keller, Thomas Pouhe
  • Patent number: 7081510
    Abstract: The invention provides a shell material for recording media comprising an alloy between an acrylonitrile-butadiene-styrene resin and recovery polyethylene terephthalate, the content of recovery polyethylene terephthalate in the total amount of the alloy being in the range of 5 to 80% by mass. The invention also provides a shell material for recording media comprising an alloy between an acrylonitrile-butadiene-styrene resin and recovery polyethylene terephthalate and having a window part. The content of recovery polyethylene terephthalate in the total amount of the alloy is in the range of 5 to 80% by mass, and the window part comprises the polyethylene terephthalate resin, a polycarbonate resin or a polyphenylene ether resin as a constituting material.
    Type: Grant
    Filed: March 9, 2004
    Date of Patent: July 25, 2006
    Assignee: Sony Corporation
    Inventors: Yasuhito Inagaki, Masahiro Sawaguchi, Daisuke Hasegawa, Tadanori Kawamura
  • Patent number: 7063892
    Abstract: An aromatic liquid-crystalline polyester having a small dielectric loss in a wide frequency region is provided. An aromatic liquid-crystalline polyester is provided that can manufacture a film having a small volume expansion by heating. An aromatic liquid-crystalline polyester substantially comprising a repeating structural unit originating in 2-hydroxy-6-naphthoic acid 30 to 80 mol %, a repeating structural unit originating in aromatic diol 35 to 10 mol %, and a repeating structural unit originating in aromatic dicarboxylic acid 35 to 10 mol %.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: June 20, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Tomoya Hosoda, Shinji Ohtomo
  • Patent number: 7057005
    Abstract: The present invention is a process for producing branched polycarbonate providing for optimum utilization of the branching agent. It was surprisingly found that adding at least a portion of the coupling catalyst to the polymerization at a point during the oligomerization in the reaction results in a higher degree of branching and improved rheological properties.
    Type: Grant
    Filed: June 29, 2004
    Date of Patent: June 6, 2006
    Assignee: Dow Global TechnologiessInc.
    Inventors: Susanne Rohde, Bernhard Elbert
  • Patent number: 7045214
    Abstract: A method for recycling an optical disk includes crushing a recovered optical disk without further treatment into chips that are used as a raw material of a resin composition for forming a film. The resin composition can be formed by injection molding to form a resin molded article. A film is formed on the surface of the resin molded article by plating or coating.
    Type: Grant
    Filed: May 25, 2004
    Date of Patent: May 16, 2006
    Assignee: Sony Corporation
    Inventor: Yasuhito Inagaki
  • Patent number: 7041781
    Abstract: Homo- and/or copolymers of one or more ethylenically unsaturated monomers, suitable for the preparation of molded articles that feature improved properties, especially improved fracture properties, heat stability and notched impact strength are disclosed. These homo- and/or copolymers are characterized in that they contain less than 400 particles per m2 of surface area with a diameter greater than 200 ?m.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: May 9, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alfred Eitel, Michael König, Dorothy Rose, Hans-Bernhard Hauertmann, Heinrich Alberts, Dieter Wittmann
  • Patent number: 7014921
    Abstract: An aromatic liquid-crystalline polyester with good moldability into a film is provided. The resulting film has small dielectric loss. The polyester comprises repeating units represented by formulae (I), (II), (III) and (IV), and the molar amounts of repeating units (I)–(IV) are 40–74.8%, 12.5–30%, 12.5–30% and 0.2–15%, respectively, wherein the molecular amounts of repeating units (III) and (IV) satisfy the relation of (III)/[(III)+(IV)]?0.5.
    Type: Grant
    Filed: November 3, 2004
    Date of Patent: March 21, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Tomoya Hosoda
  • Patent number: 7014791
    Abstract: Liquid crystalline polymer having repeat units derived from 4,4?-biphenol, terephthalic acid, 2,6-naphthalenedicarboxylic acid, and 4-hydroxybenzoic acid in a limited compositional range have melting points of 400° C. or more, and are useful for molded articles and for films, particularly for uses where good high temperature resistance is needed.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: March 21, 2006
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Marion G. Waggoner, Michael Robert Samuels
  • Patent number: 7005497
    Abstract: A liquid-crystalline polyester production method with a shortened reaction time and improved productivity per unit time by using an organic basic compound containing one nitrogen atom in a molecule is achieved by a liquid-crystalline polyester production method comprising carrying out acylation reaction and/or ester-exchange in the presence of an organic basic compound containing one nitrogen atom in one molecule and satisfying the following inequality (1): 0<A+0.4×B ??(1) wherein, A and B satisfy A={(Ech+?Ec)/(Eph+?Ep)}?1 and B=(?f/?fp)?1; Ec denotes the heat of formation of the organic basic compound; Ech+ denotes the heat of formation of a compound coordinated by proton; Ep denotes the heat of formation of pyridine; and Eph+ denotes the heat of formation of pyridine coordinated by proton to the nitrogen atom; ?f and ?fp independently denote parameters relevant to the steric angles.
    Type: Grant
    Filed: September 14, 2004
    Date of Patent: February 28, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shinji Ohtomo, Satoshi Okamoto, Akiko Nakazono, Hideyuki Ikehira
  • Patent number: 6984712
    Abstract: The present invention provides a liquid-crystalline polyester resin which comprises monomer units derived from 2-hydroxy-3-naphthoic acid and/or 2-hydroxynaphthalene-3,6-dicarboxylic acid in an amount of 1-5000 mmol % based on the total monomer components of the resin and an alkaline metal compound in an amount of 10-3000 ppm as alkaline metal based on the total monomer components of the resin. The liquid-crystalline polyester resin of the present invention has good colorability, improved heat resistance and good mechanical properties.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: January 10, 2006
    Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo
    Inventors: Ryuzo Ueno, Masaya Kitayama, Kiichi Kometani, Hiroyuki Kato, Kazunori Ueda
  • Patent number: 6974857
    Abstract: An end-capped quinoxaline-containing hyperbranched ether-ketone polymer having repeating units of the formula: wherein n represents the degree of polymerization for the parent hyperbranched polymer, x represents the degree of endgroup functionalization, x has a value of 0.05 to 1.0, and G is selected from the group consisting of and alkyl having 2 to 16 carbon atoms, and a method for preparing the polymer are provided.
    Type: Grant
    Filed: December 8, 2003
    Date of Patent: December 13, 2005
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Jong-Beom Baek, Loon-Seng Tan
  • Patent number: 6933356
    Abstract: Carboxyl group-containing polymer particles giving a neutralized viscous liquid being excellent in gel appearance and transparency. Carboxyl group-containing polymer particles comprising 55 to 94% by volume of water-swelled gel particles having a particle diameter of less than 50 ?m when the carboxyl group-containing polymer particles are dispersed and swelled in water in a concentration of 0.5% by weight, and 6 to 45% by volume of water-swelled gel particles having a particle diameter of at least 50 ?m when carboxyl group-containing polymer gel particles are dispersed and swelled in water in a concentration of 0.5% by weight.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: August 23, 2005
    Assignee: Sumitomo Seika Chemicals Co., Ltd.
    Inventors: Shigeki Hamamoto, Tomoki Kawakita, Masatoyo Yoshinaka
  • Patent number: 6896966
    Abstract: This invention relates to thermoplastic article having one or more decorative materials on the surface thereof which is obtained by applying heat and pressure to a laminate wherein said thermoplastic article comprises (1) one or more decorative materials; and (2) an upper or lower sheet material; wherein the upper or lower sheet material is formed from a polyester/aromatic polycarbonate blend.
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: May 24, 2005
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Robert William Seymour
  • Patent number: 6890988
    Abstract: The present invention provides an aromatic polyester which is obtained by condensation polymerization reaction of terephthalic acid, 2,6-naphthalenedicarboxylic acid and acylated product obtained by acylation of parahydroxybenzoic acid and hydroquinone with fatty acid anhydride, wherein said aromatic polyester satisfy the following conditions (A) to (D), and the acylation and/or the condensation polymerization reaction are conducted in the presence of heterocyclic organic compound containing at least two nitrogen atoms: (A): Number of moles of a monomer unit derived from parahydroxybenzoic acid (UNIT (1)) is 54-62 moles per 100 moles of UNIT (1), a monomer unit derived from hydroquinone (UNIT (2)), a monomer unit derived from terephthalic acid (UNIT (3)) and a monomer unit derived from 2,6-naphthalenedicarboxylic acid (UNIT (4)) in total; (B): Number of moles of UNIT (2) is 19-23 moles per 100 moles of UNIT (1), UNIT (2), UNIT (3) and UNIT (4) in total; (C): The molar ratio of UNIT (3) and UNIT (4), which is
    Type: Grant
    Filed: February 25, 2003
    Date of Patent: May 10, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tomoya Hosoda, Hiroshi Harada, Satoshi Okamoto
  • Patent number: 6867280
    Abstract: A process for producing an aromatic liquid crystal polyester comprising reacting an aromatic diol, an aromatic hydroxycarboxylic acid, or an aromatic diol and aromatic hydroxycarboxylic acid with an aromatic dicarboxylic acid in the presence of a fatty anhydride having carbon atoms of 4 or less and a fatty anhydride having carbon atoms of over 4.
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: March 15, 2005
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoshi Okamoto, Manabu Hirakawa