Nitrogen-containing Polycarboxylic Acid Or Nitrogen-containing Polycarboxylic Acid Derivative Patents (Class 528/292)
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Patent number: 5817739Abstract: A charge transporting polymer represented by formula (I-1) or (I-2) and an electrophotographic photoreceptor containing the same: ##STR1## wherein Y and Z each represents a divalent hydrocarbon group; A represents a group represented by formula: ##STR2## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group or a halogen atom; X represents a substituted or unsubstituted divalent aromatic group; n represents an integer of 1 to 5; and k represents 0 or 1; B and B' each represents --O--(Y--O).sub.m --H or --O--(Y--O).sub.m --CO--Z--CO--OR' (wherein R' represents a hydrogen atom, an alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group; Y and Z are as defined above; and m represents an integer of 1 to 5); m represents an integer of 1 to 5; and p represents an integer of 5 to 5000.Type: GrantFiled: October 16, 1996Date of Patent: October 6, 1998Assignee: Fuji Xerox Co., Ltd.Inventors: Katsumi Nukada, Masahiro Iwasaki, Akira Imai
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Patent number: 5811495Abstract: Elastomeric block copolymers comprising polyether chains as soft segment in combination with aromatic polyamide chains as hard segment are disclosed, the soft and hard segments being introduced under a sequence control so as to develop excellent physical and mechanical properties. Processes for producing the elastomeric block copolymers are also disclosed.Type: GrantFiled: August 12, 1996Date of Patent: September 22, 1998Assignee: Tosoh CorporationInventors: Isamu Kirikihira, Hiroshi Yamakawa, Yuji Kubo
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Patent number: 5811507Abstract: The present invention relates to a new polyesterimide of the type containing ester repeat functional groups E=--CO--O--, imide repeat functional groups I: ##STR1## and at least one chromophore, characterized in that it contains a quantity of recurrent amide functional groups capable of ring closure to imides which is smaller than or equal to 5 mol % relative to the sum of the imide functional groups and of the amide functional groups capable of ring closure to imides, which are present, and in that the polymerization functional groups consist essentially of E functional groups.This polyesterimide is preferably free from amide functional groups capable of ring closure to imides.One of the processes for obtaining this polyesterimide constitutes another subject-matter of the invention.Such a polymer is advantageously capable of behaving like a material that is transparent and/or active in nonlinear optics.Type: GrantFiled: November 14, 1996Date of Patent: September 22, 1998Assignee: Flamel TechnologiesInventors: You-Ping Chan, Gilles Tapolsky, Remi Meyrueix, Jean-Pierre Lecomte, Michael Dickens
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Patent number: 5811032Abstract: A water-soluble polymer prepared by melting and reacting a mixture of an oxycarboxylic acid having a melting point of 170.degree. C. or less and maleamic acid, or a mixture of a plurality of oxycarboxylic acids including at least one oxycarboxylic acid having a melting point of 170.degree. C. or less and maleamic acid, at a temperature of 170.degree. C. or less at the start of the reaction to obtain a polymer; and then hydrolyzing the polymer.Type: GrantFiled: September 19, 1996Date of Patent: September 22, 1998Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Ryozo Kawai, Hiroshi Kurata, Yukari Shimizu, Shoichiro Kajiwara
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Patent number: 5807967Abstract: The present invention is a cyanate resin monomer having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n is an even integer from 6 to 10, inclusive.Another aspect of the invention is an essentially pure cyanate resin mono having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers.Type: GrantFiled: March 21, 1996Date of Patent: September 15, 1998Assignee: The United States of America as represented by the Secretary of the NavyInventors: Arthur W. Snow, Leonard J. Buckley
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Patent number: 5783657Abstract: A low molecular weight, ester-terminated polyamide may be blended with a liquid hydrocarbon to form a transparent composition having gel consistency. The ester-terminated polyamide is prepared by reacting "x" equivalents of dicarboxylic acid wherein at least 50% of those equivalents are from polymerized fatty acid, "y" equivalents of diamine such as ethylene diamine, and "z" equivalents of monoalcohol having at least 4 carbon atoms. The stoichiometry of the reaction mixture is such that 0.9.ltoreq.{x/(y+z)}.ltoreq.1.1 and 0.1.ltoreq.{z/(y+z)}.ltoreq.0.7. The reactants are heated until they reach reaction equilibrium. The gel contains about 5-50% ester-terminated polyamide, with the remainder preferably being pure hydrocarbon. The gels are useful in formulating personal care products and other articles wherein some degree of gel-like or self-supporting consistency is desired.Type: GrantFiled: October 18, 1996Date of Patent: July 21, 1998Assignee: Union Camp CorporationInventors: Mark S. Pavlin, Richard C. MacQueen
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Patent number: 5780578Abstract: The invention provides a polymer composed of vinyl monomers bearing imidazole, hydroxyl and carboxyl groups arranged in proximity to each other, that exhibits hydrolytic activity similar to serine proteases, and a process for its preparation. The polymer is useful for the hydrolysis of esters and amides to the corresponding alcohols and amines.Type: GrantFiled: March 14, 1996Date of Patent: July 14, 1998Assignee: Council Of Scientific & Industrial ResearchInventors: Raghunath Anant Mashelkar, Mohan Gopalkishna Kulkarni, Rohini Nitin Karmalkar
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Patent number: 5766679Abstract: Chiral nematic polyesters comprise as alcohol component chiral diol structural units and as acid component dicarboxylic acid residues comprising mesogenic groups. The polyesters are particularly suitable for surface coating.Type: GrantFiled: August 15, 1997Date of Patent: June 16, 1998Assignee: BASF AktiengesellschaftInventors: Karl Siemensmeyer, Frank Meyer, Karl-Heinz Etzbach, Hans R. Kricheldorf, Nicolas Probst
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Patent number: 5756645Abstract: The yield of fully substituted, multidimensional aromatic hubs in the condensation of hydroxyl and acid halide functionalities is improved by adding a thallium catalyst, such as thallium ethoxide (Tl-OC.sub.2 H.sub.5), in the solvent.Type: GrantFiled: June 6, 1995Date of Patent: May 26, 1998Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard, Ronald R. Stephenson
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Patent number: 5750635Abstract: This invention relates to a thermally stable polyester, comprising:a polyester resin prepared by adding a dicarboxylic acid to a glycol compound, said dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having a total of from 3 to 16 carbon atoms, alicyclic dicarboxylic acids having 7 to 12 carbon atoms, aromatic dicarboxylic acids containing a total of from 8 to 16 carbon atoms, and combinations thereof, and wherein said glycol is selected from the group consisting of glycols having from 2 to 12 carbon atoms, glycol ethers having from 4 to 12 carbon atoms, and combinations thereof,said polyester resin having been prepared in the presence of a catalyst system consisting essentially of one or more antimony compounds which is not reacted with .alpha.-hydroxy carboxylic acids, .alpha.,.beta.-dicarboxylic acids or derivatives thereof.Type: GrantFiled: December 6, 1996Date of Patent: May 12, 1998Inventors: Andrew Edwin Brink, Wayne Payton Pruett, Clinton Cherry, Kay Hunt Shackelford
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Patent number: 5744570Abstract: Claimed is a copolyether amide having a melting point in the range of 180.degree. to 260.degree. C., incorporating at least 10 wt. % and not more than 30 wt. % of ethylene oxide groups, and composed of 30 to 60 wt. % of polyamide segments and 70 to 40 wt. % of segments derived from a (cyclo)aliphatic or aromatic dicarboxylic acid or a dimeric fatty acid and a polyoxyalkylene diamine derived from a polyoxyalkylene group having a molecular weight of 600 to 6000 and an atomic ratio of carbon to oxygen of 2.0 to 4.3. Also claimed is a non-porous, waterproof film having a water vapour permeability of at least 1000 g/m.sup.2 day determined at 30.degree. C. and 50% RH in accordance with ASTM E96-66 which is based on a the use of these films in rainwear, shoes, tents, chairs, as mattress covers and understating, for medical purpose garments, and for the manufacture of dressings.Type: GrantFiled: August 16, 1996Date of Patent: April 28, 1998Assignee: Akzo Nobel NVInventor: Bert Gebben
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Patent number: 5705603Abstract: The invention relates to reaction products of polyetheramines with polymers containing dicarboxylic anhydride groups, which contain 20-80, preferably 40-60, mol % of bivalent structural units A and/or C and, if required, B ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen or methyl,a and b are equal to zero or one and a+b is equal to one,Y is X or NRR.sup.3,X is --OH, --O--C.sub.1-30 -alkyl, NR.sup.3 R.sup.4 or --O.sup..crclbar. N.sup..sym. R.sup.3 R.sup.4,R.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.6 -C.sub.40 -alkyl or R,R is ##STR2## with the proviso that at least 1 mol % of the anhydride groups bonded to the polymer have reacted with a polyetheramine,Z is C.sub.2 -C.sub.4 -alkyl,n is a number from 1 to 1000,R.sup.5 is hydrogen, C.sub.1 -C.sub.30 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.6 -C.sub.30 -aryl andR.sup.6 is hydrogen or C.sub.1 -C.sub.Type: GrantFiled: June 22, 1995Date of Patent: January 6, 1998Assignee: Hoechst AktiengesellschaftInventors: Matthias Krull, Michael Feustel, Erdmann Mielcke
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Patent number: 5688906Abstract: A method for forming a polyamic acid having nonlinear optical (NLO) or pre-NLO side chains, which method includes the steps of:(1) providing a bis-(aromatic dicarboxylic acid anhydride) containing at least one NLO or pre-NLO side chain having the structure represented by:D-R-Awherein D, R and A form a delocalized resonance configuration in which R is a pi-conjugated non-centrosymmetric moiety, A is hydrogen or an electron withdrawing moiety and D is an electron donating moiety covalently linked to the bis-(aromatic dicarboxylic acid anhydride); and(2) reacting the bis-(aromatic dicarboxylic acid anhydride) with an aromatic diamine to form a polyamic acid having NLO or pre-NLO side chains. Methods for preparing polyamic acids having NLO or pre-NLO side chains by reacting aromatic diamines having NLO or pre-NLO side chains with bis-(aromatic dicarboxylic acid anhydrides) are also disclosed. Methods of forming the polyamic acids into polyimides having NLO side chains are also included.Type: GrantFiled: August 7, 1995Date of Patent: November 18, 1997Assignee: Enichem S.p.A.Inventors: Kwan-Yue Alex Jen, Kevin Joel Drost
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Patent number: 5688899Abstract: An improved clarity copolyester of a diethylene glycol modified poly(ethylene terephthalate) has a b* value of less than 15, preferably less than 10. The copolyester composition has an inherent viscosity of about 0.4 to 1.0 dL/g and comprises (A) 100 mol percent dicarboxylic acid residue component, (B) 100 mol percent diol residue component, (C) catalyst residues and (D) color control agent residues. The dicarboxylic acid residue component comprises at least 75 mol percent of terephthalic acid residues. The diol residue component comprises 10 to 50 mol percent diethylene glycol residue and 50 to 90 mol percent ethylene glycol residue. The catalyst residues comprise 20 to 100 ppm manganese, 50 to 300 ppm antimony, 0 to 100 ppm titanium and 40 to 150 ppm phosphorus, based on the weight of the copolyester.Type: GrantFiled: January 21, 1997Date of Patent: November 18, 1997Assignee: Eastman Chemical CompanyInventors: Marc Alan Strand, Bobby Jones Sublett, Jimmy Ray Trotter
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Patent number: 5672676Abstract: New polyesteramides having glass transition temperatures (Tg's) of up to 130.degree. C. and heat deflection temperatures that are in the 100.degree. C. to 110.degree. C. range are disclosed. The new polyesteramides of this invention are made by sequential addition of selected diamines to the diacid/glycol melt. The polyesteramides comprise:--?--A--G--!.sub.x --?--A--NH--R--NH--!.sub.y --wherein A is an organic dicarboxylic acid; G is a glycol selected from linear aliphatic diols and cycloaliphatic diols having 5 to 20 carbon atoms; R is selected from alkyl, cycloalkyl, arylkyl, or aryl; and x and y are whole numbers having an x/y ratio between about 9 to about 0.5 and sum of X and Y is from about 2 to about 500.Type: GrantFiled: August 21, 1995Date of Patent: September 30, 1997Assignee: Eastman Chemical CompanyInventor: Sam Richard Turner
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Patent number: 5670603Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electon donating group substituted to different phenyl rings of the fluorene moiety.Type: GrantFiled: March 8, 1993Date of Patent: September 23, 1997Assignee: AlliedSignal Inc.Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
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Patent number: 5668243Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %, the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.Type: GrantFiled: October 15, 1996Date of Patent: September 16, 1997Assignee: Eastman Chemical CompanyInventors: Cheuk Chung Yau, Leslie Shane Moody
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Patent number: 5665151Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.Type: GrantFiled: November 18, 1996Date of Patent: September 9, 1997Assignee: Eastman Chemical CompanyInventors: Nelson Zamora Escano, James John Krutak, Sr.
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Patent number: 5652320Abstract: The present invention provides an novel polymer having 1-2,000 equivalents of an N-sulfoamino group/10.sup.6 g of weight of the polymer.The polymer has excellent dispersibility of inorganic fine particles, hygroscopicity, and dye-affinity. The polymer provides a binder resin in which a magnetic or non-magnetic metal or metal oxide can highly be dispersed. The polymer also provides a magnetic recording medium which is excellent in electromagnetic conversion characteristic, surface smoothness, adhesion to non-magnetic substrates, and durability. The polymer provides a magnetic recording medium with improved travelling, travelling durability, signal-to-noise ratio, and drop-out. The polymer also provides a polyester fiber which has a high fiber strength and an excellent hygroscopicity and can be colored with cationic dyes.Type: GrantFiled: October 3, 1995Date of Patent: July 29, 1997Assignee: Sanyo Chemical Industries, Ltd.Inventors: Takashi Takemoto, Toshiro Shimada, Hiroshi Itayama
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Patent number: 5650481Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %,the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.Type: GrantFiled: October 15, 1996Date of Patent: July 22, 1997Assignee: Eastman Chemical CompanyInventors: Cheuk Chung Yau, Leslie Shane Moody
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Patent number: 5644020Abstract: The invention relates to thermoplastically processible aliphatic polyesteramides which are biodegradable (compostable).Type: GrantFiled: May 10, 1996Date of Patent: July 1, 1997Assignee: Bayer AktiengesellschaftInventors: Ralf Timmermann, Ralf Dujardin, Rainhard Koch
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Patent number: 5616658Abstract: A curing agent for a composition useful for the production of matt epoxy resin and hybrid powder coatings, comprising a mixture ofa) salts of phthalic acid, isophthalic acid and terephthalic acid with the following amines ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are identical or different aliphatic, cycloaliphatic, araliphatic or aromatic hydrocarbon radicals having 1-20 carbon atoms and in which one or more CH.sub.2 groups in the carbon chain may be replaced by 0 atoms, by NR.sub.4 groups where R.sub.4 =C.sub.1-6 -alkyl, CH--OH groups, and/or one or more terminal methyl groups may be replaced by dialkyl-substituted amino groups having 1 to 6 carbon atoms, and R.sub.1 and R.sub.2 may form a joint ring in which one CH.sub.2 group may be replaced by an O atom or by an NR.sub.4 group, and R.sub.1 =R.sub.2 =R.sub.3 --CH.sub.2 --CH.sub.2 -- attached via a common nitrogen atom, and n=3-11, and 0.5-2 mol of amine A)-C) per mole of acid, andb) pyromellitic acid and/or trimellitic acid, 0.Type: GrantFiled: January 10, 1995Date of Patent: April 1, 1997Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Elmar Wolf
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Patent number: 5614008Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.Type: GrantFiled: October 23, 1995Date of Patent: March 25, 1997Inventors: Nelson Z. Escano, James J. Krutak, Sr.
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Patent number: 5608031Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %,the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.Type: GrantFiled: November 30, 1995Date of Patent: March 4, 1997Assignee: Eastman Chemical CompanyInventors: Cheuk C. Yau, Leslie S. Moody
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Patent number: 5608016Abstract: The invention relates to salts of pyromellitic acid which comprise 1 mol of pyromellitic acid and 0.5 to 2 mol of a guanidine of the following composition: ##STR1## in which R, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different radicals from the group consisting of hydrogen, alkyl, cycloalkyl and aromatic hydrocarbon residues having 1 to 8 carbon atoms, and R.sup.1 and R.sup.2 and R.sup.3 and R.sup.4 may form a joint ring which may contain an oxygen atom as heteroatom. Also claimed are the preparation of the salts and their use for matt epoxide and hybrid powder coatings.Type: GrantFiled: April 3, 1996Date of Patent: March 4, 1997Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Elmar Wolf
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Patent number: 5591809Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprises the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a core monomer and an end-capping monomer, such as a phenolic ester, for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, in a single processing step.Type: GrantFiled: August 18, 1995Date of Patent: January 7, 1997Assignee: Hoechst Celanese CorporationInventors: Richard Vicari, Kathleen N. Juneau, Carl D. Murphy
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Patent number: 5574128Abstract: Polyetheresteramides, characterized in that they comprise both of the following repeating entities: ##STR1## in which X represents the residue of a polyamide-diacid oligomer with an Mn of between 300 and 8000, Y represents the residue of a polyetherdiol with an Mn of between 200 and 5000, and Z represents the residue of a polyetherdiamine with an Mn of between 200 and 5000, wherein the proportion by mass of the entities Z resulting from the condensation of the polyetherdiamine with respect to the total amount of the entities resulting from the polyetherdiol and polyetherdiamine, i.e. Z/(Z+Y), is between 1 and 50%. The polyetheresteramides according to the invention can be used as is and are suitable for the production of mouldings, extrudates, films, sheaths, or composite materials such as multi-layer film. They can also be mixed with other polymers and in particular with polyamides.Type: GrantFiled: August 10, 1994Date of Patent: November 12, 1996Assignee: Elf Atochem S.A.Inventors: Didier Judas, Jean-Marc Sage
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Patent number: 5567795Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprise the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a second monomer (an end-capping monomer) such as a phenolic ester for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, in a single processing step.Type: GrantFiled: August 18, 1995Date of Patent: October 22, 1996Assignee: Hoechst Celanese CorporationInventors: Richard Vicari, Kathleen N. Juneau, Carl D. Murphy
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Patent number: 5523380Abstract: A polymer comprising an .alpha.-glycol structure unit ##STR1## and a carboxylic acid-based structure unit ##STR2## provides superior results with respect to dispersibility, a chelating ability and a viscosity-stabilizing effect and is useful as a detergent builder, pigment- and cement-dispersing agents, a hydrogen peroxide stabilizer and a gas barrier agent. This polymer can further comprise the following lactone structure unit. ##STR3## This polymer can be produced by copolymerizing a conjugated diene monomer and a carboxylic acid-based monomer and oxidizing a copolymer obtained.Type: GrantFiled: July 13, 1994Date of Patent: June 4, 1996Assignee: Nippon Shokubai Co., Ltd.Inventors: Hideyuki Tahara, Hiroshi Itoh, Keiji Kofuji, Masahito Takagi
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Patent number: 5510451Abstract: The invention deals with copolyester amides built up from units derived from terephthalic acid, 1,4-butane-diol and 1,4-butane diamine.Type: GrantFiled: August 11, 1994Date of Patent: April 23, 1996Assignee: General Electric CompanyInventors: Reinoud J. Gaymans, Jeannette L. de Haan
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Patent number: 5506060Abstract: Crosslinkable, polyaromatic, polyether or polyester oligomers can have glass transition temperatures above 900.degree. F. while exhibiting desirable toughness for aerospace applications and ease of processing. A plurality (i.e. three or more) of generally linear aryl arms extend outwardly like spokes from a central aromatic hub through ether or ester linkages. Each spoke usually includes electronegative linkages, and is capped with one or two crosslinking functionalities (i.e. unsaturated hydrocarbon sites) which may be thermally or chemically activated to complete the advanced composite during curing. Among other methods, linear and multidimensional polyether oligomers are synthesized using nitrophthalic anhydride or halophthalic anhydride, dialcohols, or polyols, diamines, and suitable end caps.Type: GrantFiled: June 5, 1995Date of Patent: April 9, 1996Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
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Patent number: 5506024Abstract: Water vapor permeable films of polymeric material of thermoplastic elastomer type based on polyetheresteramide, and preferably on polyether block amides and articles comprising a film of this kind and capable, in particular, of coming into contact with the human body.Type: GrantFiled: June 7, 1995Date of Patent: April 9, 1996Assignee: AtochemInventor: Joseph R. Flesher
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Patent number: 5506334Abstract: The invention relates to new salts of pyromellitic acid, to a process for their preparation and to their use for the production of matt epoxide and hybrid powder coatings.Type: GrantFiled: April 6, 1995Date of Patent: April 9, 1996Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Elmar Wolf
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Patent number: 5498690Abstract: Carboxyl-containing polycondensation products having glass transition temperatures T.sub.G .gtoreq.20.degree. C. obtained from anhydrides of tricarboxylic or tetracarboxylic acids and diols, diamines or amino alcohols are used for cosmetic purposes, in particular as hair treatment compositions.Type: GrantFiled: January 27, 1995Date of Patent: March 12, 1996Assignee: BASF AktiengesellschaftInventors: Son N. Kim, Axel Sanner, Karin Sperling-Vietmeier
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Patent number: 5494922Abstract: The invention concerns allophanic acid derivatives of formula IR.sup.1 --N(R.sup.2)CO--N(R.sup.3)CO--X.sup.1 --Q--X.sup.2 --GIand pharmaceutically acceptable metabolically labile esters or amides thereof, and pharmaceutically acceptable salts thereof, in which R.sup.1, R.sup.2, R.sup.3, X.sup.1, Q X.sup.2 and G have the meanings given in the specification. The invention also concerns processes for the preparation of the allophanic acid derivatives of formula I, pharmaceutical compositions containing them and their use as inhibitors of the binding of fibrinogen to glycoprotein IIb/IIIa.Type: GrantFiled: June 5, 1995Date of Patent: February 27, 1996Assignee: Zeneca LimitedInventors: George R. Brown, Richard E. Shute
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Patent number: 5494994Abstract: The invention relates to new salts of pyromellitic acid, to a process for their preparation and to their use for the production of matt epoxide and hybrid powder coatings.Type: GrantFiled: December 28, 1994Date of Patent: February 27, 1996Assignee: Huels AktiengesellschaftInventors: Rainer Gras, Elmar Wolf
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Patent number: 5489667Abstract: Poly(ether ester amides) consisting of 60% to 80% by weight of a polyamide block obtainable from the following monomers:20 to 40% by weight of caprolactam or aminocaproic acid30 to 50% by weight of 11-aminoundecanoic acid20 to 40% by weight of the adduct of hexamethylenediamine anddecanedicarboxylic acidthe total amount of these polyamide-forming monomers adding up to 100% by weight, and of 20 to 40% by weight of a polyether diol/dicarboxylic acid block obtainable from equimolar amounts of polyethylene glycol with an M.sub.n molecular weight of 400 to 2,000 and one or several saturated aliphatic dicarboxylic acids with 6 to 36 carbon atoms, methods for their synthesis, spunbonded nonwovens from these poly(ether ester amides) and the use of the poly(ether ester amides) for the heat sealing of textiles.Type: GrantFiled: November 29, 1993Date of Patent: February 6, 1996Assignee: Atochem Deutschland GmbHInventors: Helmut Knipf, Karl-Heinz Hapelt, Eduard De Jong
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Patent number: 5489666Abstract: A method and compounds for inhibiting the formation of scale is disclosed. The method is particularly effective at inhibiting the formation and deposition of calcium scales in circulating aqueous systems such as cooling water systems. The method comprises introducing into the aqueous system a compound of the general formula: ##STR1## wherein R is hydrogen, alkyl, aryl, substituted alkyl or substituted aryl; R' and R" are each independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl; Z is 0, S, NH, or NR, where R is as described above; n is a positive integer greater than 1; f is a positive integer; and M is hydrogen, a water soluble cation (e.g., NH.sub.4.sup.+, alkali metal) or a C.sub.1 -C.sub.3 alkyl group.Type: GrantFiled: October 7, 1994Date of Patent: February 6, 1996Assignee: Betz Laboratories, Inc.Inventors: William S. Carey, Andrew Solov, Donald T. Freese, Libardo A. Perez
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Patent number: 5463011Abstract: The invention concerns allophanic acid derivatives of formula IR.sup.1 --N(R.sup.2)CO--N(R.sup.3)CO--X.sup.1 --Q--X.sup.2 --GIand pharmaceutically acceptable metabolically labile esters or amides thereof, and pharmaceutically acceptable salts thereof, in which R.sup.1, R.sup.2, R.sup.3, X.sup.1, Q, X.sup.2 and G have the meanings given in the specification. The invention also concerns processes for the preparation of the allophanic acid derivatives of formula I, pharmaceutical compositions containing them and their use as inhibitors of the binding of fibrinogen to glycoprotein IIb/IIIa.Type: GrantFiled: December 29, 1994Date of Patent: October 31, 1995Assignee: Zeneca LimitedInventors: George R. Brown, Richard E. Shute
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Patent number: 5391699Abstract: A polyester copolymer having an aromatic amine incorporated in the main chain, which is excelent in thermal stability as well as dynamic property, and a process for the production of the polyester copolymer, whereby the existing installation of the prior art can be used as it is, thus resulting in lowering of the production cost, are provided. The polyester copolymer comprises an aromatic dicarboxylic acid, diol and at least one compound selected from the group consisting of aromatic compounds having amino group, represented by the following general formula (I),H.sub.2 N--X--COOR (I)wherein X is an aromatic ring-containing group and R is a hydrogen atom or a hydrocarbon group selected from the group consisting of alkyl groups and cycloalkyl groups.Type: GrantFiled: May 3, 1993Date of Patent: February 21, 1995Assignee: Bridgestone CorporationInventors: Tomohisa Nishikawa, Takeshi Kinoshita, Toshihiko Yotsumoto
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Patent number: 5384377Abstract: This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij]isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.Type: GrantFiled: February 16, 1994Date of Patent: January 24, 1995Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, Wayne P. Pruett, Gerry Rhodes, Samuel D. Hilbert, William W. Parham
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Patent number: 5384387Abstract: Novel polyesters prepared from a diol, a dicarboxylic acid or ester forming reactive derivative thereof and an aromatic amino acid, ester or alcohol are disclosed.Type: GrantFiled: May 4, 1993Date of Patent: January 24, 1995Assignee: General Electric CompanyInventors: John A. Tyrell, Gary F. Smith
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Patent number: 5372864Abstract: This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij] isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.Type: GrantFiled: September 3, 1993Date of Patent: December 13, 1994Assignee: Eastman Chemical CompanyInventors: Max A. Weaver, Wayne P. Pruett, Gerry Rhodes, Samuel D. Hilbert, William W. Parham
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Patent number: 5371167Abstract: A coating composition is described comprising two components that are reactable with each other to cure the coating. The two components are:(a) a carboxyl-functional polyurethane component that is the reaction product of:(i) a polyisocyanate compound, and(ii) a compound comprising at least one acid group and at least one isocyanate-reactive group,(b) a component comprising at least two groups that are reactive with the epoxy groups on the polyurethane compound.Type: GrantFiled: October 29, 1992Date of Patent: December 6, 1994Assignee: BASF CorporationInventors: John W. Rehfuss, Walter H. Ohrbom
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Patent number: 5362843Abstract: The present invention provides novel one-step processes for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprise the reaction of a branching monomer such as a substituted phenyl compound having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 are defined herein, with a second monomer (a core monomer) such as a dihydric phenol for a sufficient period of time and at a sufficient temperature to directly produce the highly branched polymer, characterized by having a single core, in a single processing step.Type: GrantFiled: September 22, 1993Date of Patent: November 8, 1994Assignee: Hoechst Celanese CorporationInventors: Richard Vicari, Michael P. Bodman
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Patent number: 5344872Abstract: This invention relates to an aqueous dispersion of a water-dissipatable polyester and a styrenated acrylic copolymer in combination with either an acrylic polymer or a hydantoin-formaldehyde resin.Type: GrantFiled: February 19, 1993Date of Patent: September 6, 1994Assignee: Eastman Chemical CompanyInventors: Theo J. Debord, Nelson Z. Escano, Louis A. Wilkin
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Patent number: 5342912Abstract: A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.Type: GrantFiled: January 2, 1991Date of Patent: August 30, 1994Inventors: Fred Wudl, Alan Heeger
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Patent number: 5336753Abstract: The present invention relates to a polycondensation and/or addition product containing carboxyl groups and amino groups. This can be obtained by reactinga) polycarboxylic acids or anhydrides thereof, if appropriate together with monocarboxylic acids,b) polyols, if appropriate together with monools, and, if appropriatec) further modifying components, and, if appropriate,d) a component which is capable of reacting with the reaction product from a), b) and, if appropriate, c), with the proviso that the final product contains tertiary amino groups which originate from components a) and/or b) and/or d), and the reaction product from a), b), if appropriate c) and if appropriate d) has an acid number from 5 to 200, preferably 10 to 130, and an amine number from 3 to 150, preferably 10 to 100.Type: GrantFiled: January 8, 1993Date of Patent: August 9, 1994Assignee: BASF Lacke + Farben AGInventors: Werner A. Jung, Udo Vorbeck, Arno Schmitz, Wilhelm Heise, Lutz-Werner Gross
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Patent number: 5336714Abstract: Provided are water-dissipatable, sulfo-containing polyesters and polyester-amides having copolymerized therein thermally stable near infrared flourophoric compounds. The polymers are useful in coating or ink compositions, which are in turn useful for marking articles for identification/authentication purposes. Also provided is a method for invisibly marking such articles and a method for detecting and sorting articles by utilizing the near infrared flourophoric ink or coating compositions.Type: GrantFiled: December 30, 1993Date of Patent: August 9, 1994Assignee: Eastman Chemical CompanyInventors: James J. Krutak, Michael R. Cushman, William W. Parham, Clarence A. Coates, Max A. Weaver, Gabor Patonay
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Patent number: 5274025Abstract: This invention relates to a polymer blend comprising water-dissipatable, sulfonate containing, a hydantoin-formaldehyde resin.Type: GrantFiled: February 19, 1993Date of Patent: December 28, 1993Assignee: Eastman Kodak CompanyInventors: Rebecca R. Stockl, Hieu D. Phan, Gary T. Clark