Abstract: The invention relates to a powder paint composition comprising a polymer that contains endomethylene tetrahydrophthalic acid units and a crosslinker. The polymer is obtained by preparing an unsaturated polymer in a first step, which then reacts with cyclopentadiene at a temperature between 160 ° C and 220 ° C in a second step. The polymer preferably contains more than 10 wt.% endomethylene tetrahydrophthalic acid units and is preferably an unsaturated polymer.

Abstract: Disclosed is a method of copolymerizing polyethylene glycol (PEG) and branching agent into polyethylene terephthalate (PET) to achieve a polyethylene glycol-modified polyester composition that can be spun into filaments. Fabrics made from fibers formed from the copolyester composition possess wicking, drying, stretching, abrasion-resistance, flame-retardancy, static-dissipation, dyeability, and tactility properties that are superior to those of fabrics formed from conventional polyethylene terephthalate fibers of the same yarn and fabric construction. Also disclosed are polyethylene glycol modified copolyester compositions, fibers, yarns, and fabrics.

Abstract: Disclosed is a nonwoven fabric that is formed of polyethylene glycol modified copolyester staple fibers. The copolyester staple fibers include polyethylene terephthalate in amount sufficient for the copolyester staple fibers to possess dimensional stability properties substantially similar to those of conventional, unmodified polyethylene terephthalate fibers, polyethylene glycol in an amount sufficient for the copolyester staple fibers to possess wicking characteristics that are superior to those of conventional, unmodified polyethylene terephthalate fibers, and chain branching agent in an amount less than about 0.0014 mole-equivalent branches per mole of standardized polymer. Also disclosed are methods for making such nonwoven fabrics.

Abstract: Disclosed is a method of copolymerizing polyethylene glycol (PEG) and branching agent into polyethylene terephthalate (PET) to achieve a polyethylene glycol-modified polyester composition that can be spun into filaments. Fabrics made from fibers formed from the copolyester composition possess wicking, drying, stretching, abrasion-resistance, flame-retardancy, static-dissipation, dyeability, and tactility properties that are superior to those of fabrics formed from conventional polyethylene terephthalate fibers of the same yarn and fabric construction. Also disclosed are polyethylene glycol modified copolyester compositions, fibers, yarns, and fabrics.

Abstract: Mixtures of dimeric and trimeric fatty acid C1-4 alkyl esters and processes for their preparation comprising either A) epoxidizing an unsaturated or partially hydrogenated fatty acid glyceride; B) transesterifying the epoxidized glyceride with a C1-4 alkanol to obtain epoxidized fatty acid C1-4 alkyl esters; and C) ring opening and dimerizing the epoxidized fatty acid C1-4 alkyl esters; or A) transesterifying an unsaturated or partially hydrogenated glyceride with a C1-4 alkanol to obtain olefinically unsaturated fatty acid C1-4 alkyl esters; B) epoxidizing the unsaturated fatty acid C1-4 alkyl esters; and C) ring opening and dimerizing the epoxidized fatty acid C1-4 alkyl esters.

Abstract: The present invention provides a copolyester fiber consisting of a copolyester with primarily C2-4 alkylene terephthalate units and a process for producing these copolyester fibers. The copolyester contains more than 4 wt % up to 12 wt % poly(C2-4 alkylene glycol) units and 60 to 260 ppm pentaerythritol units and/or a total of 150 to less than 2500 ppm carboxy methylene phosphonic acid units and/or carboxy ethylene phosphonic acid units polymerized into it.

Abstract: Low molar mass polyester polyols having a weight-average molar mass M, of not more than 2000 g/mol, with hydroxyl numbers of from 80 to 300 mg/g and acid numbers of from 5 to 35 mg/g, comprising the stated mole fractions (in %=mol/100 mol) of structural units derived from: a) from 1 to 45% of aliphatic polycyclic polyhydroxy compounds having at least two hydroxyl groups per molecule, b) from 5 to 50% of branched aliphatic acyclic dihydroxy compounds, c) from 30 to 50% of aliphatic cyclic polycarboxylic acids, d) from 0 to 30% of aliphatic acyclic or monocyclic polyhydroxy compounds having three or more hydroxyl groups per molecule, and e) from 0 to 10% of polyfunctional compounds selected from aliphatic linear and monocyclic dihydroxy compounds, aliphatic linear and branched dicarboxylic acids, aromatic dicarboxylic acids and polycaboxylic acids having three or more carboxyl groups per molecule, and also f) from 0 to 10% of monofunctional units selected from monocarboxylic acids and monoalcohols,

Abstract: The present invention relates to powder coating compositions which can be cured at low temperatures. The powder coating compositions of the invention include a unique combination of a branched oligoester polyol and triazole blocked isocyanate cross-linking agent which when cured results in a coating binder with desirable hardness, flexibility, solvent resistance, corrosion resistance, weatherability and gloss.

Abstract: A composition suitable for use as a starting material for preparing a high molecular weight polyester through melt polymerization and solid state polymerization is disclosed. The composition comprises (a) a dicarboxylic acid or diester; (b) a glycol; (c) 0.1-5 mol %, relative to said component (a), of a multifunctional acid and/or a multifunctional alcohol; and (d) 0.05-5 wt %, based on the weight of the polyester, of a hindered phenolic aromatic phosphate. A process for preparing a high molecular weight polyester utilizing the above composition is also disclosed.

Abstract: Mixtures of low molar mass polyester polyols having a weight-average molar mass Mw of not more than 2000 g/mol, with hydroxyl numbers of from 80 to 300 mg/g and acid numbers of from 5 to 35 mg/g, comprising structural units derived from aliphatic polycyclic polyhydroxy compounds having at least two hydroxyl groups per molecule, branched aliphatic acyclic dihydroxy compounds, aliphatic cyclic polycarboxylic acids, aliphatic acyclic or monocyclic polyhydroxy compounds having three or more hydroxyl groups per molecule, and polyfunctional compounds selected from aliphatic linear and monocyclic dihydroxy compounds, aliphatic linear and branched dicarboxylic acids, aromatic dicarboxylic acids and polycarboxylic acids having three or more carboxyl groups per molecule, and also monofunctional units selected from monocarboxylic acids and monoalcohols, and acrylic copolymers made by radically initiated polymerisation in the presence of cyclic compounds that can react with hydroxy or acid functional comonomers can be us

Abstract: The invention concerns novel polyester polyols and their use as the polyol component in two-component polyurethane paints. The polyester polyols produce films which display exceptional properties after hardening. Owing to the low solvent requirement when reaction paints are prepared, they are particularly environmentally friendly. The permanence of the gloss of the hardened coatings should be stressed in particular.

Abstract: A water-reducible polyester resin for use in producing urethane coatings comprises the reaction product of: a) hexahydrophthalic anhydride, trimellitic anhydride or phthalic anhydride; b) 1,4-cyclohexane dimethanol or trimethylol propane or mixtures thereof; and c) a polyethylene glycol selected from the group consisting of polyethylene glycols, methoxy polyethylene glycols and trifunctional polyethylene glycols having a molecular weight no greater than approximately 1050; the reaction product having a functionality between approximately 2 and 2.6. Another water-reducible polyester resin comprises the same components and a specified nonionic surfactant. Urethane coatings containing such polyester resins and a diisocyanate are also disclosed.

Abstract: This invention relates to materials containing polyreaction products, which contain reaction products of dicarboxylic acids or polycarboxylic acids or derivatives thereof with epoxidation products of carboxylic acid esters and at least one filler, methods for the production thereof, and the use thereof for the production of planar structures based on renewable raw materials.

Abstract: Polycarbonates having M.sub.n ranging from about 5,000 to about 40,000 and a molecular weight distribution ranging from 1.05 to 2.0 are prepared from epoxides and CO.sub.2 using a catalyst which has a Zn center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group and an activity of at least one turnover per hour, preferably at least 100 turnovers per hour. Preferred catalysts have a ##STR1## moiety with group on each nitrogen containing a phenyl moiety.

Abstract: The powder coating for use in a coating method which includes the steps of mixing and applying two or more powder coatings to a substrate, the powder coating comprising a resin not having thermosetting properties at a temperature of 160.degree. C. or less by itself, and being heat-cured at a temperature of 160.degree. C. or less when used in combination with other powder coatings. The powder coating composition comprising two or more powder coatings, wherein each of the powder coatings comprises a resin not having thermosetting properties at a temperature of 160.degree. C. or less by itself, and being heat-cured at a temperature of 160.degree. C. or less to form a coating film when used in combination with other powder coatings.

Abstract: A thermosetting composition which gives a cured product having excellent weatherability, chemical and physical properties, in particular acid resistance and abrasion resistance, at a relatively low temperature, which has superior storage stability, and which can be used as a one component coating material; a coating composition utilizing this thermosetting composition; a method of coating; and a coated article are provided. The thermosetting composition contains a resin having at least one functional group selected from the group consisting of a blocked hydroxyl group, blocked carboxylic acid, and an epoxy group. The thermosetting composition has a blocked hydroxyl group, blocked carboxylic acid, and an epoxy group.

Abstract: A biodegradable polyester prepared from lactic acid, and, optionally, other hydroxy acid or acids. The polyester contains 4-100 carboxyl groups and has an average molecular weight of 1,000 to 200,000 g/mol. Also disclosed are methods of making such polyesters.

Abstract: A method for continuously producing a polyester by continuously melt-polymerizing a raw material consisting of a dicarboxylic acid component composed of mainly an aromatic dicarboxylic acid and containing an alicyclic dicarboxylic acid or an aliphatic dicarboxylic acid, or their ester-forming derivatives with a diol component, characterized in that said diol component as a distillate in the polycondensation reaction, including an adhering material, is condensed, said adhering material is separated centrifugally, and then the residual diol component, after distillation, is supplied to an esterification reaction or an ester interchange reaction.

Abstract: Low molar mass polyester polyols having a weight-average molar mass M.sub.

Abstract: The invention relates to mixtures of preferably from 80 to 99.9% by weight, based on the mixture, of a solution S1 comprising one or more polyamidocarboxylic acids and preferably from 0.1 to 20% by weight, based on the mixture, of a solution S2 comprising one or more, preferably primary, diamines and one or more tetracarboxylic acid diesters, processes for producing polyimide coatings using such mixtures, the use of such mixtures for producing polyimide coatings, and also polyamide-coated articles obtainable using such mixtures.

Abstract: A thermoplastic resin composition containing a polyetherimide resin, a siloxane-polyetherimide copolymer and a branched polycarbonate resin exhibits exhibit high heat distortion temperature, improved room temperature impact properties and improved impact strength and ductility at low temperatures.

Abstract: The present invention relates to curable coatings comprising oligomeric condensation products of aromatic tri- or tetracarboxylic acids and dihydroxyalkyl (meth)acrylates.

Abstract: Polyester resins with a low formaldehyde content, to which an antioxidant acting as free-radical scavenger is added, containing less than 150 ppb of formaldehyde and having a formaldehyde generation rate of less than 15 ppb/min at 290.degree. C.

Abstract: Polymers based ona) lactic acid or its C.sub.1 -C.sub.4 alkyl esters or mixtures thereof,b) at least one aliphatic C.sub.4 -C.sub.10 dicarboxylic acid andc) at least one C.sub.3 -C.sub.10 alkanol containing from three to five hydroxyl groups.

Abstract: The present invention relates to a process for producing polyesters displaying exceptionally low acetaldehyde concentrations and good clarity comprising the steps of:polycondensing in the melt phase, a polyester monomer/oligomer mixture under conditions sufficient to form a precursor having in intrinsic viscosity less than 75% of a possible maximum intrinsic viscosity; andsolid stating said precursor under conditions sufficient to increase said intrinsic viscosity at least about 0.05 dl/g.

Abstract: The present invention provides a condensation polymer, selected from the group consisting of polyamides and polyesters, that comprises between about 0.5% and about 4.0%, based on the theoretical moles of monomeric repeat units, of a trifunctional repeat unit. One of the functional groups of the trifunctional repeat unit comprises a moiety that imparts a desired property to the polymer, such as stain resistance or UV stabilization. One particular embodiment of the invention is a nylon 66 polymer that comprises between about 0.5% and 4.0%, based on the theoretical moles of nylon 66 repeat units, of a trifunctional repeat unit having the general formula: ##STR1## wherein R is the functional group that imparts a desired property to the polymer; a, b, and c are separately integers from 0-5. Preferably a+b=5 and c is 3.

Abstract: A method for preparing polyester films, which comprises addition of partially esterified trimellitate at any stage of the polymerization of polyester through direct esterification or ester interchange, the partially esterified trimellitates resulting from salt formation of partial esterified trimellitic acids which are prepared by partial esterification of aromatic tricarboxylic acids selected from trimellitic acid and trimellitic anhydride with alcohols selected from alkyl alcohols and alkylene alcohols. The polyester film prepared the composition has little voids by virtue of good affinity of the particles originating from the partially esterified trimellitates with polyester and thereby not easily broken when forming films. In addition, it is easy to control particle content and size. Further, fine protrusions can be repeatitively formed in the final films, with ease, giving high abrasion resistance and slip property to the film.

Abstract: A copolymer containing vinyl-3,4-cyclohexanediol and at least one monomer selected from acrylic acid, methacrylic acid, alkyl acrylate, alkyl methacrylate, styrene, acrylonitrile, butadiene, isoprene, vinyl acetate, maleic anhydride, ethylene, vinyl chloride, vinylidene dichloride, methyl styrene, vinyl toluene, acrylic and methacrylic acid, vinyl acetate, maleic anhydride, fumarate esters, maleate esters, vinylidene difluoride, vinyl fluoride, acrylic or methacrylic esters of the formula (I)H.sub.2 C.dbd.CHCOOR or H.sub.2 C.dbd.CCH.sub.3 COOR (I)where R is a aromatic or aliphatic hydrocarbon group containing 20 or fewer carbons and optionally containing oxygen, sulfur, or phosphorous, and mixtures thereof. A resin composition containing vinyl-3,4-cyclohexanediol, at least one carboxylic acid or ester thereof or anhydride, and optionally a polyol or diol other than vinyl-3,4-cyclohexanediol.

Abstract: Biodegradable polyesters P1 obtainable by reaction of a mixture consisting essentially of(a1) a mixture consisting essentially offrom 35 to 95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,from 5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, andfrom 0 to 5 mol % of a sulfonate compound, the sum of the individual mole percentages being 100 mol %, and(a2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,the molar ratio of (a1) to (a2) being chosen within the range from 0.4:1 to 1.5:1,with the proviso that the polyesters P1 have a molecular weight (M.sub.n) within the range from 5000 to 50,000 g/mol, a viscosity number within the range from 30 to 350 g/ml (measured in 50:50 w/w o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester P1 at 25.degree. C.) and a melting point within the range from 50 to 170.degree. C.

Abstract: A thermoplastic resin composition containing a polyetherimide resin, a siloxane-polyetherimide copolymer and a branched polycarbonate resin exhibits exhibit high heat distortion temperature, improved room temperature impact properties and improved impact strength and ductility at low temperatures.

Abstract: A process for preventing dye redeposition during the washing of a dyed fabric or garment made from natural fibers, which process incorporates as a dye redeposition inhibiting agent, a water-soluble or water-dispersible polyester resin composition comprising a reaction product of 20%-50% by weight of terephthalate polymer or waste terephthalate polymer, 10-40% by weight of at least one glycol and 5-25% by weight of at least one oxyalkylated polyol.

Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.

Abstract: A film-formable high molecular polyetherpolyester comprising structural unit (1) of formula (1) and functional group (2) of formula (2) and having a number-average molecular weight of 40,000 to 10,000,000, wherein the molar ratio of functional group (2) to R in the polyetherpolyester is in the range of 1.0 to 3.0. This polyetherpolyester can be produced by carrying out a chain extension reaction of a low molecular polyalkylene oxide of 1,000 to 30,000 in number-average molecular weight with a polyvalent acid anhydride at 0.003 MPa or higher in a molar ratio of (acid anhydride group)/(hydroxyl group)=0.8 to 1.0.

Abstract: Biodegradable polymers comprising a polyether ester P1 obtained by reactinga first mixture of20-95 mol% of adipic acid or ester-forming derivatives thereof or mixtures thereof,5-80 mol% of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and0-5 mol% of a compound containing sulfonate groups,and a second mixture of15-99.8 mol% of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,85-0.2 mol% of a dihydroxy compound IHO--?(CH.sub.2).sub.n --O!.sub.m --H(n=2, 3 or 4, m=2-250)with0-5 mol%, based on the first mixture, of a compound D having at least three groups capable of ester formation,and a bisoxazoline C1, their preparation and their use in the manufacture of biodegradable molding materials.

Abstract: A urethanized polyester is claimed which is suitable as an additive for aqueous coating systems, which is obtainable by, in a first reaction stage (A), subjecting(a) from 10 to 45 mol-% of one or more diols,(b) from 5 to 50 mol-% of one or more polyols having at least 3 OH groups, and(c) from 35 to 47 mol-% of one or more aromatic, aliphatic or cycloaliphatic polycarboxylic acids and/or reactive derivatives thereof to a polycondensation reaction in a manner known per se until the reaction mixture has an acid number of from 1 to 10, and, in a reaction stage (B), reacting the resulting reaction product in a manner known per se with an organic polyisocyanate. The urethanized polyester is outstandingly suitable as an additive for aqueous coating materials in order to improve the rheological stabilization of coating materials.

Abstract: A polyester resin for a toner whereina ratio of insoluble material in THF is comprised at 5 weight % or less,a ratio of soluble polymer having a molecular weight of 1.times.10.sup.6 or greater in THF is comprised at a range of 1 weight % to 10 weight %,a soluble polymer having a molecular weight greater than 1.times.10.sup.5 in THF is comprised in a range of 10 weight % to 20 weight %, and the following relationship is satisfied W1>W2wherein a ratio of a soluble polymer having a molecular weight less than 1.times.10.sup.4 in THF is shown by W1, a ratio of a soluble polymer having a molecular weight greater than 1.times.10.sup.4 and less than 1.times.10.sup.5 in THF is shown by W2.

Abstract: Process for the production of aromatic polyester resins starting from resins with an IV from 0.1 to 0.4 dl/g comprising the steps of blending the resin with a dianhydride of a tetracarboxylic acid, extruding the resin under the form of a strand, cooling the strand or the chips obtainable by cutting the strand, at a temperature between 150.degree. C. and 210.degree. C. and maintaining the same temperature for sufficient time to obtain a crystalline product wherein the DSC curves of the same do not show presence of premelt peaks or only in a negligible amount.

Abstract: The present invention discloses radiation curable pressure-sensitive adhesives comprising the reaction product of a blend of at least two hydroxy polyesters having different Tgs, and at least one prepolymer functionalized with (Meth) acrylates, isocyanates and mixtures thereof. The present invention further discloses a blend of at least two hydroxy polyesters wherein at least one of the hydroxy polyesters has a Tg of less than -35.degree. C., and at least one of the other hydroxy polyesters has a Tg of greater than about -35.degree. C.

Abstract: Coating compositions comprised of a film forming polymer which is the reaction product of (a) a compound containing pendant and/or terminal hydroxyl or epoxy functional groups and (b) citric acid or citric acid anhydride. The coating compositions have enhanced adhesion to galvanized and galvanealed steel substrates without the use of a chrome containing wash primer.

Abstract: A process for producing an aliphatic polyester carbonate which comprises reacting (1) an aliphatic dicarboxylic acid compound containing succinic acid as a main component, (2) an aliphatic dihydroxy compound containing 1,4-butanediol as a main component, and (3) (a) a polyhydric alcohol having 3 or more hydroxyl groups in a molecule, (b) a polybasic carboxylic acid compound having 3 or more carboxyl groups in a molecule, or (c) a polybasic carboxylic acid having one or more hydroxyl groups in a molecule to obtain an aliphatic polyester oligomer and reacting the obtained aliphatic polyester oligomer and a carbonate compound, wherein the aliphatic polyester carbonate has a melt tension of 1.5 g or more at 190.degree. C.

Abstract: This invention relates to a polyester resin comprising (A) from about 5% to about 50% by weight reactive diluent and (B) from about 50% to about 95% by weight of an unsaturated polyester resin prepared from at least one component selected from the group consisting of (i) from about 0.5% up to about 8% by mole of a polyhydric alcohol, having at least three hydroxyl groups, and at least one transesterification catalyst, (ii) from about 2% up to about 12% by mole of a reaction product of a polyol and a fatty carboxylic acid, and (iii) from about 2% up to about 12% by mole of a fatty reactant selected from the group consisting of a fatty primary alcohol, a fatty epoxide, a fatty monocarboxylic acid and mixtures thereof, wherein each member of the group has up to about 100 carbon atoms. In another aspect, the invention relates to mixtures of the above polyester resins with conventional polyester resins. Methods of reducing volatile organic compound emissions are also part of the invention.

Abstract: An epoxy-modified polyamide resin obtained by reacting a diisocyanate(A) with at least one member selected from the group consisting of a dicarboxylic acid and a tricarboxylic acid anhydride (B) in a nitrogen-containing aprotic solvent to form a polyamide resin intermediate and reacting this polyamide resin intermediate with an epoxy resin (C) in the nitrogen-containing aprotic solvent. This epoxy-modified polyamide resin has a high molecular weight and can provide a film with excellent heat resistance and flexibility, and its composition can be used as a coating material, adhesive or such in the form as it is.

Abstract: A polyester resin composition comprises: an aliphatic polyester having a number-average molecular weight (Mn) in a range of 10,000 to 100,000; and a crystalline nucleating agent, wherein the aliphatic polyester and the crystalline nucleating agent are mixed in such that a half value width of an exothermic peak based on an annealing crystallization of the aliphatic polyester measured by differential scanning calorimetry in an atmosphere of nitrogen at a cooling rate of 3K/minute is not more than 15K. This polyester resin composition has a biodegradability and a high crystallization rate. The polyester resin composition also has excellent mechanical properties and eliminates a precise temperature control during a molding process which saves labor force resulting in desirable moldability and productivity. For the described beneficial properties, the polyester resin composition can be readily processed into a fiber, a molded article, sheet, film and the like.

Abstract: The present invention relates to liquid crystalline copoly(ester-imides) and a process for the preparation thereof. In particular, the invention relates to liquid crystalline copoly(esteri-imides) comprising structural units derived from N-(3'-hydroxyphenyl)-trimellitic acid imide or N-(4'-carboxyphenyl)trimellitic acid imides optionally in combination with aromatic dicarboxylic acids, dioles or hydroxy acids. The invention also concerns the use of these copolymers in polymer blends, in moulded articles, in fibres, filaments and sheets.

Abstract: Hyperbranched polyester of a polyol with 3 to 10 reactive hydroxyl groups, preferably of equivalent reactivity, and an aromatic polycarboxylic anhydride with 2 to 4 carboxyl groups, preferably 3 carboxyl groups, each hydroxyl group of the polyol forming an ester linkage with one anhydride group of the polycarboxylic anhydride, and further glycidyl (meth)acrylate or allyl glycidyl ether forming ester linkages with the remaining carboxyl groups of the anhydride and free hydroxyl groups. Further in the hyperbranched polyester (meth)acrylic anhydride and/or an aliphatic carboxylic anhydride form ester linkages with the free hydroxyl groups. The invention also comprises a process for the production of hyperbranched polyesters and such polyesters obtainable by the process. The hyperbranched polyesters can be used as resins, curable by UV irradiation, for the production of coatings, adhesives, laminates, foils and thin films and fibre-reinforced composites.

Abstract: Disclosed herein is a novel crystalline form of low molecular weight poly(ethylene terephthalate). This crystalline form may be produced from molten or glassy low molecular weight poly(ethylene terephthalate) material by means of rapid heat transfer to or from the material. The poly(ethylene terephthalate) composition is suitable for use as a starting material for solid-state polymerization in order to produce polymers of higher molecular weight. A higher molecular weight polymer product having a unique physical form can be produced by solid-state polymerization of the low molecular weight poly(ethylene terephthalate).

Abstract: A polyester resin for a toner, wherein a maximum molecular weight is in a range of 1.times.10.sup.3 to 8.times.10.sup.3, Mw/Mn is in a range of 20 to 200, a proportion of component having a molecular weight of 1.times.10.sup.5 or less is comprised at a range of 80 weight % or greater, and at least one component selected from the group consisting of polycarboxylic acid having more than 3 carboxyl groups and polyalcohol having more than 3 hydroxyl groups.

Abstract: A biodegradable polyester obtainable by reacting a mixture comprising(a1) from 95 to 99.9% by weight of a polyester P1 obtainable by reacting a mixture essentially comprising(b1) a mixture comprising35-95 mol % of adipic acid or ester-forming derivatives thereof,5-65 mol % of terephthalic acid or ester-forming derivatives thereof, and0-5 mol % of a compound containing sulfonate groups, and(b2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,with the proviso that a compound D with at least three groups capable of ester formation is employed to prepare the polyester P1,(a2) from 0.1 to 5% by weight of a divinyl ether C1 and(a3) from 0 to 5 mol %, based on component (b1) from the preparation of P1, of compound D,and other biodegradable polymers and thermoplastic molding compositions, processes for the preparation thereof, the use thereof for producing biodegradable moldings and adhesives.

Abstract: Cooling process for polyester and/or polyamide resins downstream of solid-state polycondensation plants in which the cooling is carried out by passing the solid material through two types of equipment in series, of which one is a fluid-bed, the other is a solid/wall cooling equipment. The fluid bed equipment is fed with a stream of inert-gas coming from the solid-state polycondensation reactor, previously subjected to by-products purification, drying and cooling.

Abstract: Provided are a polyester resin for use in a toner binder which is excellent in terms of offset resistance and low-temperature fixability, which keeps triboelectric charge stability even in an environment of a high temperature and a high humidity, which has excellent durability, and which is used in a toner that gives vivid image characteristics, a process for producing the same, and a toner using the same. The polyester resin for use in the toner binder is formed by linking at least a part of the crosslinked low-molecular polyesters through a dicarboxylic acid used as a linking agent.