Abstract: Environmentally friendly resin particles are provided which include a monomer having a color, which is able to impart color to the resulting resin. The resulting resin may be used to form various articles, including toner. A toner of the present disclosure may thus include the bio-based polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Methods for providing these resins are also provided.

Abstract: The invention relates to a biaxially oriented film, predominantly formed from a polyester whose diol component includes at least 35 mol-% of 1,4-cyclohexanedimethanol (CHDM) and additionally contains at least one further diol different from CHDM. The dicarboxylic acid component of the polyester includes at least 80 mol-% of one or more benzenedicarboxylic acid(s) and/or one or more naphthalene dicarboxylic acid(s). The dicarboxylic acid component of the polyester includes a main dicarboxylic acid component forming an at least 55 mol-% portion of the dicarboxylic acid component, chosen from 2,6-naphthalene dicarboxylic acid or terephthalic acid. The dicarboxylic acid component further includes a secondary dicarboxylic acid component, present in an amount of at least 5 mol-% of the dicarboxylic acid component, with the secondary dicarboxylic acid component differing from the main dicarboxylic acid component. The invention further relates to a method for producing the film and its use.

Abstract: Presently described are multilayer optical films, oriented polyester films, negatively birefringent copolyester polymers, fluorene monomers, and polyester polymers prepared from such fluorene monomers. In one embodiment, the multilayer optical film comprises at least one first birefringent optical layer; and at least one second optical layer having a lower birefringence than the first optical layer; wherein at least one of the optical layers comprises a negatively birefringent polyester polymer comprising a backbone and repeat units comprising at least one pendent aromatic group that is conformationally locked relative to the backbone.

Abstract: A polymer having a number average molecular weight (Mn) of about 10 000 g/mol comprising a monomeric rigid moiety R and a monomeric flexible moiety F, wherein R comprises a main-chain polycyclic core and F has a main chain comprising a number of atoms sufficient for the transition temperature of the polymer to be lower than the degradation temperature of the polymer is provided. A method of manufacturing of same is also provided. Biomedical devices, scaffolds and supports for tissue engineering, delivery devices, textiles, moulds, vehicle parts, tubes, active disassembly devices, microactuators, toys and inflatable membranes comprising same are also described.

Abstract: A dehydroabietic acid polymer includes a repeating unit containing a dehydroabietic acid skeleton, and a composite material including the same.

Abstract: The present invention relates to compositions having improved rheological properties which are based on polycarbonate having rearrangement structures and cyclic and linear oligomers and also moldings and extrudates composed of these polycarbonate compositions.

Abstract: The present invention relates to hydrophilically terminated amphiphilic polycondensates with a content of from 1 wt. % of copolymerized diol based on hydrogenated and doubly dehydrated aldo- and ketohexoses and use thereof in combination with polyester and polyester-containing surfaces.

Abstract: A back sheet for a solar cell, consisting of a polyester comprising at least one repeating unit of trimethylene naphthalate and trimethylene terephthalate in an amount of 85% by weight or more, has improved hydrolysis-resistance and is useful in the field requiring weatherability.

Abstract: This invention provides a coating composition for use on a food-contact surface of a container (e.g., a food or beverage can) that includes a polymer having one or more segments of Formula I: —O—Ar—Rn—C(O)—O—R1—O—C(O)—Rn—Ar—O— wherein each Ar is independently a divalent aryl group (i.e., an arylene group) or heteroarylene group; R1 is a divalent organic group; each R is independently a divalent organic group; and n is 0 or 1. Containers comprising the polymer and methods of making such containers are also provided.

Abstract: The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.

Abstract: Methods of making unsaturated polyester compositions are provided and include reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers and reinforcements.

Abstract: A process for crystallizing a polyester polymer by introducing a molten polyester polymer, such as a polyethylene terephthalate polymer, into a liquid medium at a liquid medium temperature greater than the Tg of the polyester polymer, such as at a temperature ranging from 100° C. to 190° C., and allowing the molten polyester polymer to reside in the liquid medium for a time sufficient to crystallize the polymer under a pressure equal to or greater than the vapor pressure of the liquid medium. A process flow, underwater cutting process, crystallization in a pipe, and a separator are also described.

Abstract: This invention relates to composite materials for restorative dentistry. More particularly, it relates to new components for dental composites, which impart an attractive combination of good mechanical properties and low shrinkage.

Abstract: The present invention is directed to curable film-forming compositions comprising a film-forming resin and a crosslinking agent. The film-forming resin contains a polymer having functional aromatic groups derived from functional aromatic acids. The present invention further provides multi-component composite coating compositions comprising a first film-forming composition applied to a substrate to form a primer or base coat, and a second film-forming composition applied on top of the primer or base coat to form a top coat, the top coat comprising the composition described above. Coating compositions prepared from the curable compositions of the present invention demonstrate superior gloss and acid etch resistance properties, making them ideally suited for automotive applications.

Abstract: A compound having a structural unit of Formula: (I). A polymer having a structural unit of Formula: (II). A conjugated polymer having one or more side groups of the following Formula: (III). Additionally, compositions, polymer blends, films, coatings, and electronic devices prepared from such polymers.

Abstract: The present invention relates to multilayer optical films and birefringent copolyester films. The birefringent copolyester optical layer or birefringent copolyester film comprises a major amount of naphthalate units, ethylene units, and a minor amount of branched or cyclic C4 to C10 alkyl units. Also described are certain copolyester polymeric materials further comprising subunits of a phthalate ionomer such as dimethyl sulfosodium isophthtalate ionomer.

Abstract: The present invention provides a resin obtained by reacting a compound represented by the formula (I): wherein R1 represents a hydrogen atom or a C1-C6 alkyl group, R2, R3 and R4 each independently represents a C1-C6 alkyl group and R1, R2, R3, R4 and A1 are bonded to form a ring, A1 represents a C1-C20 saturated hydrocarbon group in which one or more —CH2— can be replaced by —O—, B1 and B2 each independently represent a C1-C6 alkylene group, L1 and L2 each independently represent a halogen atom, —O—CH?CH2, —O—CH?CH(CH3) or —O—SO2—R? in which R? represents a C1-C6 alkyl group or a C6-C20 aryl group, with a polyhydric phenol compound.

Abstract: Asymmetrically substituted compounds of bisanhydrohexitols are described, including the bisanhydrohexitol isosorbide. The compounds are useful as AB monomers. The synthesis of polymers from the monomers is also described.

Abstract: Unsaturated polyester compositions are disclosed that are obtainable by reacting: (i) plant and animal oil triglycerides, an alkyl ester of a saturated or unsaturated fatty acid or mixtures thereof; (ii) a difunctional, or polyfunctional glycol or mixtures thereof; (iii) a difunctional or polyfunctional acid, their anhydrides or alkyl esters and mixtures thereof; (iv) a strained cycloolefin; (v) a component(s) that function as a compound capable of initiating polymerization at high temperature and which is stable at room temperature; and (vi) low profile additives, fillers, and reinforcements. Also disclosed are methods for the preparation of the polyesters and the use of the polyesters in closed and open mold compositions such as sheet molding compound (SMC), bulk molding compounding (BMC), resin transfer molding (RTM), pultrusion, infusion, filament winding, and spray up.

Abstract: A method for producing a film comprising feeding a composition comprising a crystalline thermoplastic resin having a temperature of higher than the crystallization temperature Tc of the resin to between a first nip-pressing surface and a second nip-pressing surface of a nip-pressing unit, and leading the composition to pass through the nip-pressing surfaces while the nip-pressing unit gives a pressure of from 5 to 1000 MPa to the composition, to thereby form the composition into a film continuously.

Abstract: Disclosed herein is a polycarbonate polymer comprising: an isosorbide unit, a polysiloxane unit; and an aliphatic unit different from the isosorbide unit, wherein the isosorbide unit, polysiloxane unit, and aliphatic unit are each carbonate, or a combination of carbonate and ester units and the aliphatic unit is derived from an aliphatic oligomer having a molecular weight of 900 to 4000.

Abstract: Non-sulfonated aliphatic-aromatic polyester compositions having improved thermal properties and biodegradability, and articles such as films, coatings and laminates, produced from the non-sulfonated aliphatic-aromatic polyester compositions, are provided.

Abstract: The disclosed is a copolymer having a formula as: R1 is a combination of naphthalene, phenylene, butyl, and hexyl. R2 is a combination of ethylene, cyclohexlene, 2-methylpropyl, and neopentyl. n is a number of 1500 to 3000. The copolymer has a transparency greater than 80%, a thermal resistance greater than 100, a moisture absorption less than 0.5 wt %, and yellowing under UV/climate resistance greater than 1000 hours, such that the copolymer is adapted to be applied in packaging material for light emitting devices.

Abstract: A polycarbonate is provided that contains repeat units derived from isosorbide and a residue derived from an activated diaryl carbonate. The polycarbonate has 1H-NMR peaks associated with the repeat units derived from isosorbide. The polycarbonate contains no more than a maximum allowable amount of sorbitol-derived color bodies. If these color bodies are present in the polycarbonate it has a 1H-NMR peak associated with the color bodies. The maximum allowable amount of color bodies are present when the integrated area of the 1H-NMR peak associated with the color bodies divided by the integrated areas of the 1H-NMR peaks associated with the repeat units derived from isosorbide is 0.025.

Abstract: Polyethylene naphthalate fibers that are characterized in that the fibers have a crystal volume of from 550 to 1,200 nm3 obtained by wide angle X-ray diffraction of the fiber and a degree of crystallization of from 30 to 60%. It is preferred that the fibers have a maximum peak diffraction angle of wide angle X-ray diffraction of from 25.5 to 27.0° and a melting point of from 285 to 315° C. The production method thereof is characterized in that a particular phosphorus compound is added to the polymer in a molten state, the spinning draft ratio after discharging from the spinneret is from 100 to 5,000, and the molten polymer immediately after discharging from the spinneret is allowed to pass through a heat-retaining spinning chimney at a temperature within ±50° C. of a temperature of the molten polymer, and is drawn.

Abstract: A subject for the invention is to provide a polycarbonate having excellent mechanical strength, heat resistance, a low refractive index, a large Abbe number, reduced birefringence, and excellent transparency. The invention relates to a polycarbonate characterized by being obtained by subjecting one or more dihydroxy compounds including a dihydroxy compound having at least one linking group —CH2—O— in the molecule thereof to melt polycondensation with a carbonic acid diester, and by having a reduced viscosity of from 0.40 dL/g to 1.70 dL/g and a formic acid content lower than 5 ppm by weight.

Abstract: The birefringent film of the present invention contains an aromatic polyester having a repeating unit represented by the following general formula (1). In the general formula (1), A(s), B(s), C(s), and D(s) are each independently represent a group selected from a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Also, a and b each represent an integer of 0 to 4, and c and d each represent an integer of 0 to 3. R1 represents a hydrogen atom, or an alkyl group which has 1 to 10 carbon atoms. R2 represents an alkyl group which has 2 to 10 carbon atoms. R3 to R6 each independently represent a group or atom selected from a hydrogen atom, a halogeno group, an alkyl group which has 1 to 6 carbon atoms, and an aryl group. Furthermore, l and m each represent an integer of 2 or more.

Abstract: In one embodiment, there is provided a process comprising introducing polyester polymer particles containing residual acetaldehyde into a vessel at a temperature within a range of 130° C. to 195° C. to form a bed of particles within the vessel, flowing a gas through at least a portion of the particle bed, and withdrawing finished particles from the vessel having a reduced amount of residual acetaldehyde. In this process, it is not necessary to introduce a hot flow of gas at high flow rates otherwise required to heat up cool particles to a temperature sufficient to strip acetaldehyde. Rather, this process provides a benefit in that, if desired, gas introduced into the vessel at low flow rates and low temperatures can nevertheless effectively strip acetaldehyde in a reasonable time because the hot particles quickly heat a the gas to the particle temperature.

Abstract: The invention is directed to polyester processes where the esterification process at utilizes a vapor removing device, wherein the vapor removing device is substantially horizontally oriented, wherein the esterification effluent forms a two-phase laminar, stratified, non-circular vapor/liquid flow in at least a portion of said vapor removing device.

Abstract: The present invention provides a liquid crystalline polyester comprising (a) a repeating unit derived from aromatic hydroxycarboxylic acid, (b) a repeating unit derived from aromatic dicarboxylic acid and (c) a repeating unit represented by —X—Ar1-O—Ar1-Y—, wherein Ar1 represents 1,4-phenylene which may be substituted by a halogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 20 carbon atoms, and X and Y independently represent O or NH. The polyester in the preset invention has a sufficiently low dielectric constant and/or is a sufficiently high resistance in hydrolysis.

Abstract: Polyester compositions based on 1,3-propanediol and aromatic and aliphatic diacids that can contain a large fraction of biologically derived content are disclosed. Transesterification between polyesters in blends of such compositions is greatly reduced using phosphorous-containing additives. The blends have properties similar to poly(ethylene terephthalate).

Abstract: An object of the present invention is to provide a polyester film having excellent dimensional stability to temperature and humidity. The present invention is a polyester containing a dicarboxylic acid component and a diol component, wherein (i) the dicarboxylic acid component contains not less than 5 mol % and less than 50 mol % of a recurring unit represented by the following formula (A) and more than 50 mol % and not more than 95 mol of a recurring unit represented by the following formula (B): wherein RA is an alkylene group having 2 to 10 carbon atoms, wherein RB is a phenylene group or naphthalenediyl group; and (ii) the diol component contains 90 to 100 mol % of a recurring unit represented by the following formula (C): —O—RC—O—??(C) wherein RC is an alkylene group having 2 to 10 carbon atoms, and a film comprising the same.

Abstract: A polymerizable liquid crystal compound that has a wide liquid crystal phase temperature range and has a sterol ferulate skeleton, and a liquid crystal composition containing the compound are provided. A polymer that is excellent in various characteristics, and a molded article having optical anisotropy produced with the polymer are obtained with the polymerizable liquid crystal compound. The compound is represented by formula (1): wherein R represents a sterol moiety derived from vegetable organisms; P represents one of polymerizable groups represented by formulae (P1) to (P8); X, Z, X0 and Z0 each represent a bonding group; and A represents a divalent group having a cyclic structure.

Abstract: A process for the alkoxyalkylation of an unsubstituted aromatic substrate or a substituted aromatic substrate, said substitution being via a carbon-carbon bond, said process comprising reacting the aromatic substrate with a dialkoxyalkane in the presence of a catalyst.

Abstract: The invention is directed to polyester processes that utilizes a pipe reactor in the esterification, polycondensation, or both esterification and polycondensation processes. Pipe reactor processes of the present invention have a multitude of advantages over prior art processes including improved heat transfer, volume control, agitation and disengagement functions.

Abstract: The present invention is a method for efficiently incorporating a nitrogen containing methine light absorber into a polyester resin. The method includes forming a reaction mixture comprising combining a diol component, a diacid component selected from the group consisting of dicarboxylic acids, dicarboxylic acid derivatives, and mixtures thereof, an antimony containing compound, a phosphorus containing compound, a metal containing compound, and a nitrogen containing methine light absorber. The reaction mixture is polymerized in a polycondensation reaction system. In another embodiment the light absorber is added while the reaction products of one reactor are being transferred to the next reactor in the polycondensation reaction system. The present invention is also directed articles made from the polyester resin.

Abstract: The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide, an anionic acrylic polymer or a cationic acrylamide copolymer; or (e) a hydroxylamine and/or a nitrone.

Abstract: A compound having a structural unit of Formula: (I). A polymer having a structural unit of Formula: (II). A conjugated polymer having one or more side groups of the following Formula: (III). Additionally, compositions, polymer blends, films, coatings, and electronic devices prepared from such polymers.

Abstract: Sulfonated aliphatic-aromatic polyester compositions having improved thermal properties, and articles such as films, coatings and laminates, produced from the sulfonated aliphatic-aromatic polyester compositions, are provided. Some of the films are biocompostable. Films made from the sulfonated aliphatic-aromatic copolyesters can be used to make shaped articles, such as sheets, thermoformed containers, and coatings for, for example, films and other substrates. The sulfonated aliphatic-aromatic copolyesters are produced from a mixture of aromatic dicarboxylic acids, aliphatic dicarboxylic acids, certain glycols, and components containing alkali metal or alkaline earth metal sulfonate groups, such as a metal 5-sulfoisophthalic acid derivative.

Abstract: A composition of matter comprising a polyester composition derived from: (i) greater than 80 mole percent of a diol derived from a disubstituted xylene glycol of the formula (I): wherein R1 and R2 are independently selected from the group consisting of aliphatic, aromatic, cycloaliphatic, sulfur containing compounds, amines and halogen; and (ii) a diacid is disclosed. Also disclosed are blends of these polyesters with polycarbonate and process to prepare these compositions and articles therefrom.

Abstract: The present invention provides a process of reducing acrolein by product from polytrimethylene terephthalate using selected phosphorus compounds to contact the polytrimethylene terephthalate or reactants in the process of producing polytrimethylene terephthalate. The selected phosphorus compounds are retained in the polytrimethylene terephthalate. The present invention also provides polytrimethylene terephthalate compositions containing amounts of phosphorus compounds.

Abstract: A melt phase process for making a polyester polymer melt phase product by adding an antimony containing catalyst to the melt phase, polycondensing the melt containing said catalyst in the melt phase until the It.V. of the melt reaches at least 0.75 dL/g. Polyester polymer melt phase pellets containing antimony residues and having an It.V. of at least 0.75 dL/g are obtained without solid state polymerization. The polyester polymer pellets containing antimony residues and having an It.V. of at least 0.70 dL/g obtained without increasing the molecular weight of the melt phase product by solid state polymerization are fed to an extruder, melted to produce a molten polyester polymer, and extruded through a die to form shaped articles. The melt phase products and articles made thereby have low b* color and/or high L* brightness, and the reaction time to make the melt phase products is short.

Abstract: Sulfonated aromatic copolyesters and articles made therefrom, and processes for producing the sulfonated aromatic copolyesters and articles are provided. Articles that can be made from the sulfonated aromatic copolyesters include films, coatings and laminates. Some of the compositions and articles are biocompostable. The films can further be used to form shaped articles such as sheets, food packaging such as sandwich wraps, thermoformed containers, and coatings for, for example, films and other substrates. The sulfonated aromatic copolyesters contain a hydroxyalkanoic acid component.

Abstract: The present invention relates to a biodegradable copolyester of high molecular weight and narrow molecular weight distribution. The copolyester has a Mw of 100,000-600,000 g/mol, and a molecular weight distribution of 1.2-3.

Abstract: Novel polymerizable ester compounds having formulae (1) to (4) undergo no acid-induced decomposition by ?-elimination wherein A1 is a polymerizable functional group having a carbon-carbon double bond, R1 is H or —C—(R5)3, R2 and R3 are alkyl, R4 is H or alkyl, R5 is a monovalent hydrocarbon group, X is alkylene, Y is methylene, ethylene or isopropylidene, Z is alkylene, and n=1 or 2. Resist compositions comprising polymers derived from the ester compounds have excellent sensitivity and resolution and lend themselves to micropatterning lithography.

Abstract: The present invention is a method for efficiently incorporating a nitrogen containing methine light absorber into a polyester resin. The method includes forming a reaction mixture comprising combining a diol component, a diacid component selected from the group consisting of dicarboxylic acids, dicarboxylic acid derivatives, and mixtures thereof, an antimony containing compound, a phosphorus containing compound, a metal containing compound, and a nitrogen containing methine light absorber. The reaction mixture is polymerized in a polycondensation reaction system. In another embodiment the light absorber is added while the reaction products of one reactor are being transferred to the next reactor in the polycondensation reaction system. The present invention is also directed articles made from the polyester resin.

Abstract: Polyester compositions that provide a higher throughput in calendering processes may be prepared from a polyester having crystallization half time of at least 5 minutes, an inherent viscosity of about 0.55 to about 0.75 dL/g, a branching monomer, and a release additive. The polyester compositions show a combination of excellent melt strength with good shear response that permits higher calendering line speeds before melt fracture occurs. Also disclosed are processes for film or sheet by calendering the above compositions and the film or sheet produced therefrom. The polyester compositions, film, or sheet also may include plasticizers and/or flame retardants to increase their flexibility and enable their use in commercial applications requiring flame resistance. The film and sheet have excellent appearance and can be used in a wide range of decorative and packaging applications.

Abstract: Energy savings are realized during the commercial production of polyethylene terephthalate by partially cooling polyethylene terephthalate pellets exiting a solid stating reactor by contact with water, and using the residual heat stored in the pellets to vaporize associated water to form dry pellets.

Abstract: Disclosed is a process for the preparation of high molecular weight polyesters by reacting one or more dicarboxylic acids directly with 1,4-cyclohexanedimethanol and, optionally, one or more diols. The process uses an overall diol to dicarboxylic acid molar ratio of about 0.97 to about 1.2 and an incremental addition of either the diacid or diol components. The process provides a shorter total reaction time and, thus, lessens the thermal degradation of polyester which may result in high color and reduced molecular weight.

Abstract: The present invention relates to a process of preparing dialkylnaphthylenes and polyalkylenenaphthyleneates dialkylnaphthalenes and polyalkylenenaphthalates.