Polyhydroxy-containing Compound Or Salt Thereof Having An Ether-oxygen Atom As Reactant Patents (Class 528/300)
-
Patent number: 6562899Abstract: Branched hydroxyl-functional polyester resin having an average hydroxyl functionality of >2, a hydroxyl number of 25 to 300 mg KOH/g, and a number average molecular weight within the range of from 500 to 3,000, which polyester resin comprises polyalkylene oxide groups and, optionally, sulphonate groups, wherein the polyester resin comprises the reaction product of 1) a mixture of carboxylic acids comprising 50 to 80 mole % of an m- and/or p-aromatic and/or cycloaliphatic dicarboxylic acid, 20 to 50 mole % of an aliphatic dicarboxylic acid and/or aliphatic monocarboxylic acid with more than 6 carbon atoms, and, optionally, a tri- or higher-functional acid, and 2) a mixture of alcohols comprising an aliphatic diol with at least 4 carbon atoms and/or a cycloaliphatic diol with at least 4 carbon atoms, a C1-C4 alkoxy polyalkylene oxide glycol and/or C1-C4 alkoxy polyalkylene oxide 1,3-diol having a number average molecular weight of 500 to 3,000, and, optionally, a tri- or higher-functional polyalcohol, wType: GrantFiled: April 20, 2001Date of Patent: May 13, 2003Assignee: Akzo Nobel N.V.Inventors: Roelof Buter, André Steenbergen, Taco Scherer, Petrus Johannes Arnoldus Geurink
-
Patent number: 6552160Abstract: A resin composition is prepared by reacting components comprising dibasic acid, diamine, polyol and monoalcohol, wherein (a) at least 50 equivalent percent of the dibasic acid comprises polymerized fatty acid; (b) at least 50 equivalent percent of the diamine comprises ethylene diamine; (c) 10-60 equivalent percent of the total of the hydroxyl and amine equilvalents provided by diamine, polyol and monoalcohol are provided by monoalcohol; and (d) no more than 50 equivalent percent of the total of the hydroxyl and amine equivalents provided by diamine, polyol and monoalcohol are provided by polyol. This resin composition may be formulated into, for example, personal care products, fragrance releasing products and candles.Type: GrantFiled: May 14, 2001Date of Patent: April 22, 2003Assignee: Arizona Chemical CompanyInventor: Mark S. Pavlin
-
Patent number: 6525164Abstract: Macrocyclic oligoesters and compositions comprising macrocyclic oligoesters are prepared from intermediate molecular weight polyesters. In one embodiment, a diol is contacted with a dicarboxylic acid or a dicarboxylate in the presence of a catalyst to produce a composition comprising a hydroxyalkyl-tenninated polyester oligomer. The hydroxyalkyl-terminated polyester oligomer is heated to produce a composition comprising an intermediate molecular weight polyester which preferably has a molecular weight between about 20,000 Daltons and about 70,000 Daltons. The intermediate molecular weight polyester is heated and a solvent is added prior to or during the heating process to produce a composition comprising a macrocyclic oligoester. An optional step is to separate the macrocyclic oligoester from the composition comprising the macrocyclic oligoester.Type: GrantFiled: August 31, 2001Date of Patent: February 25, 2003Assignee: Cyclics CorporationInventor: Gary R. Faler
-
Patent number: 6509091Abstract: Disclosed is a polyethylene glycol modified copolyester fiber that has exceptional moisture management characteristics and that can be formed into exceptionally comfortable fabrics. The copolyester fiber includes polyethylene terephthalate in an amount sufficient for the copolyester fiber to possess dimensional stability properties substantially similar to those of conventional, unmodified polyethylene terephthalate fibers, polyethylene glycol in an amount sufficient for the copolyester fiber to possess wicking properties that are superior to those of conventional, unmodified polyethylene terephthalate fibers, and chain branching agent in an amount less than about 0.0014 mole-equivalent branches per mole of standardized polymer.Type: GrantFiled: April 6, 2001Date of Patent: January 21, 2003Assignee: Wellman, Inc.Inventors: James Burch Branum, Carl Steven Nichols, Keith James Carnes
-
Patent number: 6497950Abstract: The invention relates to fibers, particularly binder fibers, made from polyesters and the polyesters themselves. The polyesters are the product of a reaction between a glycol component and a dicarboxylic acid component where the glycol component contains at least 50 mole % of a four carbon diol, such as 1,4-butanediol, or a six carbon diol, such as 1,6-hexanediol or a mixture of a four carbon and six carbon diol. Typically, the polyesters of the invention are semicrystalline and/or crystalline and have a specific melting point ranging from about 140 to about 185° C. The polyesters of the invention may be formed into a variety of products, especially binder fibers for nonwoven fabrics, textile/industrial yarns and fabrics, composites and other molded articles.Type: GrantFiled: August 4, 2000Date of Patent: December 24, 2002Assignee: Eastman Chemical CompanyInventors: William A. Haile, Leron R. Dean, Richard L. McConnell, Kishan C. Khemani
-
Patent number: 6492090Abstract: A polymer comprising units of formulas (1) and (2) and having a Mw of 1,000-500,000 is provided. R1 is H, CH3 or CH2CO2R3, R2 is H, CH3 or CO2R3, R3 is alkyl, R4 is H, alkyl, alkoxyalkyl or acyl, R5 is alkyl or aryl, Y is a divalent hydrocarbon group which may contain a hetero atom and which forms a ring with the carbon atom, Z is a trivalent hydrocarbon group, k is 0 or 1, and W is —O— or —(NR)— wherein R is H or alkyl. A resist composition comprising the polymer as a base resin is sensitive to high-energy radiation, has excellent sensitivity, resolution, and etching resistance, and lends itself to micropatterning with electron beams or deep-UV rays.Type: GrantFiled: April 26, 2001Date of Patent: December 10, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tsunehiro Nishi, Seiichiro Tachibana, Mutsuo Nakashima, Takeshi Kinsho, Takeru Watanabe, Koji Hasegawa, Jun Hatakeyama
-
Patent number: 6489406Abstract: The invention relates unsaturated polyester resins for the manufacture of subzero flexible, weather-resistant products. The liquid unsaturated polyester resin comprises a linear unsaturated polyester obtained by reacting 5-30 mol % of one or more ethylenically unsaturated dicarboxylic acids (A), 20-45 mol % of one or more other aliphatic or aromatic acids (B) and 40-60 mol % of two or more polyhydric alcohols and 30-60 wt % of one or more reactive monomers. The linear unsaturated polyesters have a cone and plate viscosity (I.C.I.) of 2 ps/125° C.-20 ps/125° C. and a molecular weight Mw of 20,000-100,000. The invention also relates to a process for the manufacture of such unsaturated polyester resins and to the use of them in applications wherein good adhesion to supporting material and flexibility at ambient and especially at low temperatures are needed.Type: GrantFiled: March 29, 2001Date of Patent: December 3, 2002Assignee: Ashland Inc.Inventors: Paul Mahbub, Karri Airola, Eija Valtonen
-
Patent number: 6485819Abstract: A copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; and (c) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: GrantFiled: December 19, 2000Date of Patent: November 26, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
-
Patent number: 6482513Abstract: A monofilament comprising a branched poly(ethylene terephthalate) having an inherent viscosity of at least 0.50 dL/g. Also provided is a process for forming a monofilament that comprises forming a branched poly(ethylene terephthalate) having an inherent viscosity of at least 0.50 dL/g and shaping the branched poly(ethylene terephthalate) to form the monofilament.Type: GrantFiled: August 10, 2001Date of Patent: November 19, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
-
Patent number: 6454982Abstract: Disclosed is a method of copolymerizing polyethylene glycol (PEG) into polyethylene terephthalate (PET) to achieve a polyethylene glycol-modified polyester composition that can be spun into filaments. The method includes the steps of copolymerizing polyethylene glycol into polyethylene terephthalate in the melt phase to form a copolyester composition, then polymerizing the copolyester composition in the solid phase until the copolyester is capable of achieving a melt viscosity that facilitates the spinning of filaments, and thereafter spinning filaments from the copolyester. A copolyester composition comprised of polyethylene glycol and polyethylene terephthalate is also disclosed. Fabrics made from fibers formed from the copolyester composition possess wetting, wicking, drying, flame-retardancy, static-dissipation, and soft hand properties that are superior to those of fabrics formed from conventional polyethylene terephthalate fibers of the same yarn and fabric construction.Type: GrantFiled: November 19, 1999Date of Patent: September 24, 2002Assignee: Wellman, Inc.Inventor: James Burch Branum
-
Patent number: 6447859Abstract: The polyester resin of the present invention is produced by polymerizing a monomer mixture comprising a glycol component containing 5 to 60 mol % of a spiroglycol represented by Formula I: and 30 to 95 mol % of ethylene glycol, and a dicarboxylic acid component containing 80 to 100 mol % of terephthalic acid and/or an ester thereof. The polyester resin has (1): an intrinsic viscosity of 0.4 to 1.5 dL/g, (2) a melt viscosity of 700 to 5,000 Pa·s, (3) a molecular weight distribution of 2.5 to 12.0; and (4) a glass transition temperature of 90° C. or higher and a cooling crystallization exotherm peak of 5 J/g or lower. The polyester resin of the present invention is excellent in heat resistance, transparency, mechanical properties, moldability and fabrication qualities and useful for producing shaped articles such as films, sheets, hollow containers and foamed products.Type: GrantFiled: June 13, 2001Date of Patent: September 10, 2002Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Dai Oguro, Koji Yamamoto, Takeo Hayashi, Takeshi Hirokane, Masahiro Kurokawa
-
Patent number: 6444018Abstract: A phase change ink carrier composition comprising at least one anhydride/amino alcohol based adduct which is a reaction product of at least one anhydride and at least one amino alcohol, wherein the reaction product is an ester material or an amide material, but not an ester-amide material.Type: GrantFiled: February 12, 1999Date of Patent: September 3, 2002Assignee: Xerox CorporationInventors: Clifford R. King, Jeffery H. Banning, Donald R. Titterington
-
Patent number: 6444782Abstract: The invention relates to a process for making a high molecular weight pre-gel for a cross-linked branched polyester comprising: a) reacting polyester precursor repeat units via condensation polymerization in a continuous or semi-continuous, or batch reactor stage to form a low molecular weight pre-gel; and b) further reacting the low molecular weight pre-gel via condensation polymerization in a continuous thin-film reactive vacuum processing stage to form a high molecular weight pre-gel.Type: GrantFiled: April 26, 2000Date of Patent: September 3, 2002Assignee: Eastman Chemical CompanyInventor: Michael D. Hamlin
-
Publication number: 20020115817Abstract: A copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof, (b) one or more aliphatic dicarboxylic acids or an ester thereof, and (c) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: ApplicationFiled: December 19, 2000Publication date: August 22, 2002Inventor: Richard A. Hayes
-
Patent number: 6429278Abstract: In a process for producing a polyester containing 1,4-cyclohexanedimethanol (CHDM) as one of its glycol components, an aqueous or a methanolic slurry comprising CHDM and a dicarboxylic acid is prepared. The slurry is maintained at a temperature below the melting point of CHDM. The slurry is then fed into a reactor. The slurry is esterified at sufficient temperatures and pressures, and optionally in the presence of a suitable catalyst, to effect esterification. A prepolymer is formed. The prepolymer is then polycondensed at sufficient temperatures and pressures in the presence of a suitable catalyst to effect polycondensation to form a polyester.Type: GrantFiled: January 22, 2001Date of Patent: August 6, 2002Assignee: Eastman Chemical CompanyInventors: Earl Edmondson Howell, Jr., Donna Rice Quillen, Aaron Nathaniel Edens
-
Patent number: 6423418Abstract: A substrate having an adherent and stain resistant layer having durability and flexibility, said layer comprising the reaction product of a reactive polyester having free carboxylic acid and/or hydroxyl groups, a hydroxyl terminated polymer including repeat units from an oxetane having pendant —CH2—O—(CH2)n—Rf groups (said Rf groups generally being a fluorinated alkyl group) and an amino resin curative. The substrate may be printed or embossed or both. The coated substrate has both stain resistant properties and dry erase properties with dry erase markers. The coated substrate can be used as prepared or applied to other substrates.Type: GrantFiled: February 4, 1999Date of Patent: July 23, 2002Assignee: Omnova Solutions Inc.Inventors: Marten S. Callicott, David L. Hyde, Charles M. Kausch, Anthony Verrocchi, Joe A. Wright, Raymond J. Weinert, Robert E. Medsker, Daniel D. Woodland, Daniel C. Gottschalk
-
Patent number: 6423789Abstract: A process for producing a polyester that comprises 65 to 90 wt. % poly(alkylene ether) glycol. The process comprises the step of copolymerizing a preformed polyester polymer having an inherent viscosity of at least 0.4 dL/g and a poly(alkylene ether) glycol, to obtain said polyester comprising said 65 to 90 wt. % poly(alkylene ether glycol).Type: GrantFiled: August 10, 2001Date of Patent: July 23, 2002Assignee: E. I. duPont de Nemours & CompanyInventor: Richard Allen Hayes
-
Patent number: 6420040Abstract: A coating composition for application to primed metal substrates as a topcoat is disclosed. The coating composition is especially useful on metal closures for vacuum-packed food products. The coating composition is free of a halide-containing vinyl polymer and comprises: (a) an acrylate co-polymer having pendant hydroxy groups, (b) a hydroxy-terminated polyester, (c) a crosslinker, and (d) a nonaqueous carrier.Type: GrantFiled: April 30, 1999Date of Patent: July 16, 2002Assignee: The Valspar CorporationInventors: Lawrence P. Seibel, Girish G. Parekh
-
Patent number: 6407194Abstract: A process for increasing the pill resistance of a polyester polymer wherein the polyester polymer is produced by polymerizing a polymerization mixture comprising (a) a carbonyl compound or an oligomer of the carbonyl compound and (b) a glycol. The process comprises contacting the polymerization mixture with a cross-linker comprising (RO)mSi(X)nZp, wherein: R is hydrogen, a hydrocarbon, or a hydrocarbon oxygen; X is a hydrocarbon or a hydrocarbon oxygen; Z is a hydrophilic group; m is 1 to 3; n is 1 to 3; and p is 1 to 30.Type: GrantFiled: July 17, 2001Date of Patent: June 18, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Jiwen F. Duan
-
Patent number: 6403756Abstract: Disclosed is a novel, high molecular weight aliphatic polyester having excellent mechanical strengths such as breaking strain and containing a copolymer structure with 3-alkoxy-1,2-propane diol and a method of producing the aliphatic polyester in an industrially advantageous manner. The aliphatic polyester is a biodegradable high molecular weight aliphatic polyester having an ester structure derived from 3-alkoxy-1,2-propane diol.Type: GrantFiled: October 19, 2001Date of Patent: June 11, 2002Assignee: National Institute of Advanced Industrial Science and TechnologyInventors: Yoichi Taguchi, Akihiro Oishi, Yoshikazu Ikeda, Ken-ichi Fujita, Takashi Masuda
-
Patent number: 6399716Abstract: An aromatic group containing copolyester resin composition which has good biodegradability and physical properties, wherein; (i) 0.1 wt % to 30 wt % of an aliphatic prepolymers having number average molecular weight of from 300 to 30,000; (ii) one or a plurality of aromatic dicarboxylic acid (or an acid anhydride thereof which containing aromatic group in the molecule; (iii) one or a plurality of aliphatic (including cyclic type) dicarboxylic acid (or an acid anhydride thereof); and (iv) one or a plurality of aliphatic (including cyclic type) glycol, wherein the copolyester resin has number average molecular weight of from 30,000 to 90,000, weight average molecular weight of from 100,000 to 600,000, melting point of from 70° C. to 150° C., and melt index of from 0.1 to 50 g/10min. (190° C., 2,160 g), and the process for preparing and/or producing the same.Type: GrantFiled: December 13, 2000Date of Patent: June 4, 2002Assignee: IRE Chemical Ltd.Inventors: Hyun Soo Chung, Jae Wang Lee, Dong Hoon Kim, Do Youn Kim, Suok Woo Lee
-
Patent number: 6388024Abstract: Carboxyl functional polyester resins obtainable by reaction of: a) at least a compound of the formula wherein a≧1, and wherein R1 and R2 each may represent an alkyl group having from 1 to 4 carbon atoms or wherein R1 and R2 may form together with the group —CH—(CH2)x—CH˜ a cycloalkyl group and preferably 1,4-cyclohexane dicarboxylic acid (A1), mixed with smaller molar amounts of monoglycidyl esters of &agr;,&agr;-branched carboxyl acids containing from 5 to 19 carbon atoms in the acid moiety (A2), and b) at least one compound B comprising one primary- or secondary hydroxyl group and one tertiary aliphatic carboxyl group, and c) optionally one diol compound C, and d) optionally a dihydroxymonocarboxylic acid compound D, and e) optionally a trihydroxyalkane (E1) or tetrahydroxyalkane (E2), the molar ratio of compounds A1:(C+A2):B:D:E1:E2, being, (X+Y+1):Y:2:X:Q:P, wherein X ranges from 0 to 8, Y ranges from 1 to 8, Q ranges from 0 to 3 and wType: GrantFiled: October 25, 2000Date of Patent: May 14, 2002Inventors: Ronald Petrus Clemens Van Gaalen, Petrus Gerardus Kooijmans, Leo Wim Van Noort
-
Patent number: 6384180Abstract: The process for producing polyesters, and in particular, polyethylene terephthalate (PET) which includes the use of antimony catalyst that is acidic phosphorus additive involves the addition of the catalyst prior to or together with the additive. Moreover, the amount of additive is selected so as to provide a resin that is at least substantially free of non-acidic inorganic compounds such as antimony phosphate which can be formed by the reaction of the catalyst with the additive. The process preferably includes an esterification step, a prepolymer step, and a polymerization step with the antimony catalyst being added prior to, during, or after, the esterification step while the phosphorus-containing additive is introduced prior to or during the prepolymer stage. Polyesters having low levels of elemental phosphorus are also disclosed.Type: GrantFiled: August 7, 2000Date of Patent: May 7, 2002Assignee: Eastman Chemical CompanyInventors: Mary Therese Jernigan, Carol Juilliard Greene, Perry Michael Murdaugh, Alan Wayne White, Cheuk Chung Yau
-
Patent number: 6383651Abstract: A polyester polymer including at least one polyoxetane block of repeating units derived from polymerizing at least one oxetane monomer having at least one pendant —CH2—O—(CH2)n— Rf group wherein said Rf group is partially or fully fluorinated is described. A preferred process for forming said polymer by reacting the hydroxyl terminated polymer with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants.Type: GrantFiled: August 27, 1999Date of Patent: May 7, 2002Assignee: Omnova Solutions Inc.Inventors: Raymond J. Weinert, Edward N. Kresge, Robert E. Medsker, Daniel D. Woodland
-
Patent number: 6368710Abstract: A sulfonated copolyester of the reaction product of: (a) one or more aromatic dicarboxylic acids or an ester thereof; (b) one or more aliphatic dicarboxylic acids or an ester thereof; (c) one or more sulfonated compound; and (d) isosorbide. The polyesters are useful to form articles of increased biodegradability.Type: GrantFiled: December 19, 2000Date of Patent: April 9, 2002Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard Allen Hayes
-
Patent number: 6365315Abstract: The invention relates to a process for the production of spherical, polyester particles, wherein the particle size can be exactly adjusted in the range of 1 to 200 &mgr;m and a particle size distribution with a span (=d90−d10/d50)≦1.5, as well as the use of the produced particles for toner compositions in electrophotographic and direct printing systems and powder coatings.Type: GrantFiled: October 18, 2000Date of Patent: April 2, 2002Assignee: Ticona GmbHInventors: Stefan Wulf, Alexandra Jacobs, Volker Mörs, Toshio Shiwaku, Benett Clayton Ward
-
Patent number: 6359079Abstract: Polyoxypropylamines, polypropylene oxide polymers endcapped on one or both ends with carbamate groups, di- or tri-carboxylic acids, carboxylic acid halides, or esters or mixtures comprising one of the above with a hydrophilic polyester copolymer having repeating segments of ethylene terephthalate units containing 10-50% by weight of polyoxyethylene terephthalate units useful for imparting a durable hydrophilic coating to polyester, polypropylene, polyethylene, cotton, polyamide or polyaramid fabric or fiber are disclosed.Type: GrantFiled: July 27, 1999Date of Patent: March 19, 2002Assignee: Stepan CompanyInventor: Charles Francis Palmer, Jr.
-
Patent number: 6359070Abstract: A polymer blend including a polyester and another thermoplastic polymer. The polyester includes terephthaloyl moieties and, optionally, other aromatic diacid moieties; and ethylene glycol moieties; optionally diethylene glycol moieties; isosorbide moieties; and, optionally one or more other diol moieties. The polyester has an inherent viscosity of at least about 0.35 dL/g.Type: GrantFiled: May 23, 2000Date of Patent: March 19, 2002Assignee: E. I. du Pont Nemours and CompanyInventors: Garo Khanarian, Larry F. Charbonneau, Helmut B. Witteler
-
Publication number: 20020032301Abstract: Process of gelification of aqueous medium with a copolyester oligomer comprising essentially oxyalkylenated or ocycycloalkylenated or polyoxyalkylenated dicarboxylate units at least 35 mole % of said units being similar units of which the correspondent homolymer is crystalline, at least 7 mole % of said units being bearing units of hydrophobic(s) sulfonated functions, the molecular mass in weight of said copolyesters oligomer being less than 20.000. For example: the terephtalic polyoxyethylenated sulfonated oligomers of high content of polyethyleneterephtalate.Type: ApplicationFiled: September 6, 2001Publication date: March 14, 2002Inventors: Jean-Marc Ricca, Etienne Fleury
-
Patent number: 6355722Abstract: Aqueous solutions or dispersions of binders for preparing aqueous coating materials are produced, including as an aqueous component water of reaction which is obtained during the condensation of alcohols with carboxylic acids.Type: GrantFiled: June 11, 2001Date of Patent: March 12, 2002Assignee: BASF Coatings AGInventors: Ulrich Poth, Lutz-Werner Gross
-
Patent number: 6355738Abstract: A process for preparing a polyester comprising the steps of blending (A) polyethylene terephthalate before solid phase polymerization having an intrinsic viscosity of 0.3 to 0.8 dl/g in an amount of 40 to 99% by weight, with (B) polyethylene naphthalate before solid phase polymerization having an intrinsic viscosity of 0.3 to 0.7 dl/g in an amount of 1 to 60% by weight, and subjecting the blend to solid phase polymerization. The process of the invention can provide a polyester having excellent gas barrier properties, transparency and heat resistance and hardly generating acetaldehyde.Type: GrantFiled: February 26, 1999Date of Patent: March 12, 2002Assignee: Mitsui Chemicals INCInventor: Koji Nakamachi
-
Patent number: 6348561Abstract: An alkali sulfonated polyester-amine resin generated from the reaction of an organic diol, and a mixture of an organic diacid, an alkali sulfonated diacid and an amino-organic diacid.Type: GrantFiled: April 19, 2001Date of Patent: February 19, 2002Assignee: Xerox CorporationInventors: Walter Mychajlowskij, Daniel A. Foucher, Raj D. Patel, Guerino G. Sacripante
-
Publication number: 20020019508Abstract: Disclosed is a polyethylene glycol modified copolyester fiber that has exceptional moisture management characteristics and that can be formed into exceptionally comfortable fabrics. The copolyester fiber includes polyethylene terephthalate in an amount sufficient for the copolyester fiber to possess dimensional stability properties substantially similar to those of conventional, unmodified polyethylene terephthalate fibers, polyethylene glycol in an amount sufficient for the copolyester fiber to possess wicking properties that are superior to those of conventional, unmodified polyethylene terephthalate fibers, and chain branching agent in an amount less than about 0.0014 mole-equivalent branches per mole of standardized polymer.Type: ApplicationFiled: April 6, 2001Publication date: February 14, 2002Inventors: James Burch Branum, Carl Steven Nichols, Keith James Carnes
-
Publication number: 20020016437Abstract: The invention relates to a process for the preparation of a copolyether ester built up of hard polyester segments of repeating units derived from at least one alkylene glycol and at least one aromatic dicarboxylic acid or an ester thereof and soft segments derived from at least one polyalkylene oxide glycol, which comprises polymerization by condensation in the melt of at least one aromatic dicarboxylic acid, at least one alkylene glycol and at least one polyalkylene oxide glycol, in the presence of a catalyst based on a combination of titanium and a bivalent metal in a single compound or several compounds, characterized in that the molecular ratio of Ti : bivalent metal is at most 1.6, preferably at most 1.5.Type: ApplicationFiled: April 23, 2001Publication date: February 7, 2002Inventors: Geert I.V. Bonte, Gerard H. Werumeus Buning, Krijn Dijkstra, Jean M.M Warnier
-
Patent number: 6342300Abstract: The invention relates to biodegradable polycondensates, to the production of said polycondensates, and to their use for releasing specific substances. The polycondensates are derived from at least three components chosen from the following group: a) dianhydrohexites b) bivalent (polyvalent) organic carboxylic acids and c) polyvalent organic carboxylic acids which, in addition to two carboxylic acid functions, have at least one other, optionally capped, i.e., OH and/or COOH function.Type: GrantFiled: September 7, 2000Date of Patent: January 29, 2002Assignee: Celanese Ventures GmbHInventors: Holger Bengs, Alex Schoenfeld, Gitte Boehm, Siegfried Weis, Joachim Clauss
-
Publication number: 20020010285Abstract: A process for preparing a polyester comprising the steps of blending (A) polyethylene terephthalate before solid phase polymerization having an intrinsic viscosity of 0.3 to 0.8 dl/g in an amount of 40 to 99% by weight, with (B) polyethylene naphthalate before solid phase polymerization having an intrinsic viscosity of 0.3 to 0.7 dl/g in an amount of 1 to 60% by weight, and subjecting the blend to solid phase polymerization. The process of the invention can provide a polyester having excellent gas barrier properties, transparency and heat resistance and hardly generating acetaldehyde.Type: ApplicationFiled: February 26, 1999Publication date: January 24, 2002Inventor: KOJI NAKAMACHI
-
Publication number: 20020010309Abstract: The polyester resin of the present invention is produced by polymerizing a monomer mixture comprising a glycol component containing 5 to 60 mol % of a spiroglycol represented by Formula I: 1Type: ApplicationFiled: June 13, 2001Publication date: January 24, 2002Inventors: Dai Oguro, Koji Yamamoto, Takeo Hayashi, Takeshi Hirokane, Masahiro Kurokawa
-
Patent number: 6337137Abstract: The invention relates to a powder paint composition comprising a polymer that contains endomethylene tetrahydrophthalic acid units and a crosslinker. The polymer is obtained by preparing an unsaturated polymer in a first step, which then reacts with cyclopentadiene at a temperature between 160 ° C and 220 ° C in a second step. The polymer preferably contains more than 10 wt.% endomethylene tetrahydrophthalic acid units and is preferably an unsaturated polymer.Type: GrantFiled: October 14, 1999Date of Patent: January 8, 2002Assignee: DSM N.V.Inventors: Fokeltje A. Koldijk, Eimbert G. Belder, Coenraad M. Gehrels, Tosko A. Misev
-
Patent number: 6335422Abstract: The present invention is a method of preparing a high molecular weight copolyester bottle resin that has excellent melt processing characteristics. The method includes the steps of reacting a diacid or diester component and a diol component to form modified polyethylene terephthalate, wherein diol component is present in excess of stoichiometric proportions. Together, the diacid or diester component and the diol component must include at least 7 percent comonomer. The remainder of the diacid component is terephthalic acid or dimethyl terephthalate and the remainder of the diol component is ethylene glycol. The modified polyethylene terephthalate is copolymerized in the melt phase to an intrinsic viscosity of between about 0.25 dl/g and 0.40 dl/g to thereby form a copolyester prepolymer. Thereafter the copolyester prepolymer is polymerized in the solid phase to form a high molecular weight bottle resin that has an intrinsic viscosity of at least about 0.70 dl/g, and a solid phase density of less than 1.Type: GrantFiled: May 8, 2001Date of Patent: January 1, 2002Assignee: Wellman, Inc.Inventor: Robert Joseph Schiavone
-
Patent number: 6331606Abstract: A composition and a process for producing the composition are provided. The composition comprises repeat units derived from 1,3-propanediol; an organic acid, preferably a dicarboxylic acid, its salt, its ester, or combinations of two or more thereof; a polyether diol; and a sulfonated comonomer. The polyether diol can be present in the composition in the range of from about 10 to about 80 weight %. The process comprises contacting 1,3-propanediol with the organic acid, the polyether diol, and the sulfonated comonomer. The sulfonated comonomer can have the formula of (R′OC(O))2A(R)zS(O)2OM in which each R′ can be the same or different and is each independently hydrogen, a C1 to C4 alkyl group, or a C1 to C4 hydroxyalkyl group; each R is independently a C1 to C4 alkyl group; A is an alkylene or arylene group; z is a number of from 0 to 2; and M is hydrogen, alkali metal ion, alkaline earth metal ion, quaternary ammonium, or ammonium ion.Type: GrantFiled: December 1, 2000Date of Patent: December 18, 2001Assignee: E. I. du Pont de Nemours and ComapnyInventor: Yanhui Sun
-
Publication number: 20010051315Abstract: A polymer comprising units of formulas (1) and (2) and having a Mw of 1,000-500,000 is provided. R1 is H, CH3 or CH2CO2R3, R2 is H, CH3 or CO2R3, R3 is alkyl, R4 is H, alkyl, alkoxyalkyl or acyl, R5 is alkyl or aryl, Y is a divalent hydrocarbon group which may contain a hetero atom and which forms a ring with the carbon atom, Z is a trivalent hydrocarbon group, k is 0 or 1, and W is —O— or —(NR)— wherein R is H or alkyl. A resist composition comprising the polymer as a base resin is sensitive to high-energy radiation, has excellent sensitivity, resolution, and etching resistance, and lends itself to micropatterning with electron beams or deep-UV rays.Type: ApplicationFiled: April 26, 2001Publication date: December 13, 2001Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Tsunehiro Nishi, Seiichiro Tachibana, Mutsuo Nakashima, Takeshi Kinsho, Takeru Watanabe, Koji Hasegawa, Jun Hatakeyama
-
Publication number: 20010051316Abstract: A polymer comprising units of formulas (1) and (2) and having a Mw of 1,000-500,000 is provided. R1 is H, CH3 or CH2CO2R3, R2 is H, CH3 or CO2R3, R3 is alkyl, R4 is halogen or acyloxy, alkoxycarbonyloxy or alkylsulfonyloxy group which may be substituted with halogen, R5 is H or alkyl, R6 is an acid labile group, Z is a single bond or a divalent hydrocarbon group, k is 0 or 1, and W is —O— or —(NR)— wherein R is H or alkyl. A resist composition comprising the polymer as a base resin is sensitive to high-energy radiation, has excellent sensitivity, resolution, and etching resistance, and lends itself to micropatterning with electron beams or deep-UV rays.Type: ApplicationFiled: April 26, 2001Publication date: December 13, 2001Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Tsunehiro Nishi, Mutsuo Nakashima, Seiichiro Tachibana, Takeshi Kinsho, Koji Hasegawa, Takeru Watanabe, Jun Hatakeyama
-
Patent number: 6322886Abstract: Disclosed is a method of copolymerizing polyethylene glycol (PEG) and branching agent into polyethylene terephthalate (PET) to achieve a polyethylene glycol-modified polyester composition that can be spun into filaments. Fabrics made from fibers formed from the copolyester composition possess wicking, drying, stretching, abrasion-resistance, flame-retardancy, static-dissipation, dyeability, and tactility properties that are superior to those of fabrics formed from conventional polyethylene terephthalate fibers of the same yarn and fabric construction. Also disclosed are polyethylene glycol modified copolyester compositions, fibers, yarns, and fabrics.Type: GrantFiled: May 16, 2001Date of Patent: November 27, 2001Assignee: Wellman, Inc.Inventor: James Burch Branum
-
Patent number: 6316586Abstract: A copolyether composition that can be used to produce a dyeable polyester is provided. The composition can comprise repeat units derived from a first diol such as, for example, 1,3-propanediol and a sulfonated dicarboxylic acid such as, for example, 5-sulfo-isophthalic acid. The dyeable polyester composition can comprise repeat units derived from the copolyether composition, an acid such as, for example, terephthalic acid, and a second diol such as, for example, 1,3-propanediol. Also disclosed is a process that can be used for producing the copolyether composition. The process comprises contacting the first diol with the sulfonated dicarboxylic acid.Type: GrantFiled: August 15, 2000Date of Patent: November 13, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Hari Babu Sunkara, Yali Yang
-
Publication number: 20010039160Abstract: Disclosed is a nonwoven fabric that is formed of polyethylene glycol modified copolyester staple fibers. The copolyester staple fibers include polyethylene terephthalate in amount sufficient for the copolyester staple fibers to possess dimensional stability properties substantially similar to those of conventional, unmodified polyethylene terephthalate fibers, polyethylene glycol in an amount sufficient for the copolyester staple fibers to possess wicking characteristics that are superior to those of conventional, unmodified polyethylene terephthalate fibers, and chain branching agent in an amount less than about 0.0014 mole-equivalent branches per mole of standardized polymer. Also disclosed are methods for making such nonwoven fabrics.Type: ApplicationFiled: January 17, 2001Publication date: November 8, 2001Inventors: Keith J. Carnes, James Burch Branum
-
Patent number: 6303745Abstract: A polyester having repeating units represented by formula (1): wherein R1 represents a divalent hydrocarbon residue which in its structure may contain a heteroatom having no active hydrogen. The polyester has a high refractive index and biodegradability, and is useful as a material for fibers and plastics.Type: GrantFiled: October 20, 2000Date of Patent: October 16, 2001Assignees: Cosmo Research Institute, Cosmo Oil Co., Ltd.Inventors: Kiyotaka Shigehara, Yoshihiro Katayama, Seiji Nishikawa, Yasushi Hotta
-
Patent number: 6300463Abstract: Thermoplastic elastomeric polymers which contain polyether blocks having tetramethylene ether repeat units, and polyamide blocks, have improved elastomeric properties such as higher unload power and lower tensile set, when the polyether blocks also contain 2-alkyltetramethylene ether repeat units. The polymers are useful as molding resins and for fibers.Type: GrantFiled: January 4, 2000Date of Patent: October 9, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Garret Daniel Figuly, Marc Bruce Goldfinger
-
Patent number: 6299789Abstract: The invention provides a finish composition for synthetic filament, which does not generate fume and tar at high speed and high temperature, imparts superior lubricity at high temperature, superior antistaticity and yarn winding performance, and has satisfactory biodegradability. The finish composition for synthetic fiber of the invention is characterized by containing one or more of polyether polyester compounds having a molecular weight of 1,000 to 20,000 and represented by the formula: X—(A—B)n—A′—Y. In the formula, each of X and Y is independently hydrogen, or a residue of C1-8 linear or branched saturated alcohol or C1-18 fatty acid; each of A and A′ is a residue of ethylene oxide/propylene oxide block or random copolymer containing ethylene oxide and propylene oxide from 9:1 to 1:9 mol ratio; B is an aliphatic dibasic acid residue represented as OOC(CH2)mCOO; m is an integer from 1 to 4; and n is an integer from 1 to 3.Type: GrantFiled: February 16, 2001Date of Patent: October 9, 2001Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Shinichi Tatemoto, Tetsuo Doi, Yasuhiko Yada
-
Publication number: 20010027244Abstract: Disclosed is a method of copolymerizing polyethylene glycol (PEG) and branching agent into polyethylene terephthalate (PET) to achieve a polyethylene glycol-modified polyester composition that can be spun into filaments. Fabrics made from fibers formed from the copolyester composition possess wicking, drying, stretching, abrasion-resistance, flame-retardancy, static-dissipation, dyeability, and tactility properties that are superior to those of fabrics formed from conventional polyethylene terephthalate fibers of the same yarn and fabric construction. Also disclosed are polyethylene glycol modified copolyester compositions, fibers, yarns, and fabrics.Type: ApplicationFiled: May 16, 2001Publication date: October 4, 2001Inventor: James Burch Branum
-
Patent number: 6291066Abstract: Disclosed is a method of copolymerizing polyethylene glycol (PEG) and branching agent into polyethylene terephthalate (PET) to achieve a polyethylene glycol-modified polyester composition that can be spun into filaments. Fabrics made from fibers formed from the copolyester composition possess wicking, drying, stretching, abrasion-resistance, flame-retardancy, static-dissipation, dyeability, and tactility properties that are superior to those of fabrics formed from conventional polyethylene terephthalate fibers of the same yarn and fabric construction. Also disclosed are polyethylene glycol modified copolyester compositions, fibers, yarns, and fabrics.Type: GrantFiled: January 18, 2000Date of Patent: September 18, 2001Assignee: Wellman, Inc.Inventor: James Burch Branum