With Two Or More Reactants One Of Which Is A Carboxylic Acid Or Derivative Thereof Which Is Devoid Of An Amine Group And One Reactant Which Is A Polyamine Which Is Devoid Of A Carboxylic Acid Group Or Carboxylic Acid Derivative Group Patents (Class 528/329.1)
  • Patent number: 9963548
    Abstract: Solvent resistant, transparent films prepared from solutions of aromatic polyamides and multi-functional carboxylic acids in polar aprotic solvents are described herein. Solvent resistance is achieved by heating the films for a short time above 300° C. near the polyamide Tg. The films have CTEs less than 40 ppm/° C. and are optically clear displaying transmittance above 75% between 400 and 750 nm. The films are useful as substrates for flexible electronic devices.
    Type: Grant
    Filed: April 23, 2013
    Date of Patent: May 8, 2018
    Assignee: Akron Polymer Systems, Inc.
    Inventors: Limin Sun, Dong Zhang, Frank W. Harris, Jiaokai Jing
  • Patent number: 9012424
    Abstract: The present invention relates to a polymer according to Formulas (1) or (2): The present invention further relates to nanogels and nanoparticles made of a polymer according to general Formulas (1) and (2). The nanogels may comprise a biologically active component such as siRNA, miRNA, DNA, an (oligo)peptide or a proteins.
    Type: Grant
    Filed: May 25, 2012
    Date of Patent: April 21, 2015
    Assignee: 20MED Therapeutics B.V.
    Inventors: Johannes Franciscus Joseph Engbersen, Arkadi Vladimirovich Zinchenko
  • Patent number: 9012026
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Grant
    Filed: April 1, 2014
    Date of Patent: April 21, 2015
    Assignee: Arkema France
    Inventors: Thierry Briffaud, Philippe Blondel
  • Publication number: 20150099080
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine)·(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Application
    Filed: December 10, 2014
    Publication date: April 9, 2015
    Applicant: ARKEMA FRANCE
    Inventors: Thierry BRIFFAUD, Philippe BLONDEL
  • Patent number: 8986846
    Abstract: A thermosetting oligomer or thermosetting polymer is provided. The thermosetting oligomer or thermosetting polymer contains repeating units, each of which has at least one thermosetting functional group in the side chain and is represented by Formula 1: where repeating units include X1, A1, and Y1 subunits, sidechain units include linking unit L and thermosetting functional group Z, and n is an integer from 1 to 4. The thermosetting oligomer or thermosetting polymer has a low coefficient of thermal expansion and high or no glass transition temperature, stiffness, processability, heat resistance and mechanical properties. The thermosetting oligomer or thermosetting polymer is highly soluble, wettable and dimensionally stable and is suitable for use in films, prepregs and printed circuit boards. Further provided are a thermosetting resin composition including the thermosetting oligomer or thermosetting polymer and a printed circuit board using the composition.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: March 24, 2015
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jae Jun Lee, Mahn Jong Kim, Kwang Hee Kim
  • Patent number: 8971766
    Abstract: The present invention provides an electrophotographic member capable of more definitely suppressing occurrence of a C set image. The electrophotographic member has a surface layer including a modified polysiloxane having a structure represented by the following formula (1). In the formula (1), G represents a bivalent group having an ethylene oxide chain represented by (—O—C2H4—) and L represents polysiloxane having at least a SiO4/2(Q) unit or a SiO3/2(T) unit.
    Type: Grant
    Filed: June 4, 2013
    Date of Patent: March 3, 2015
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tomohito Taniguchi, Hiroshi Mayuzumi, Yusuke Yagisawa
  • Patent number: 8907046
    Abstract: Copolymers containing at least one perfluoropolyether segment and multiple aminooxalylamino groups are described. Methods of making the copolymers are also described. The copolymers can be prepared by reacting an oxalylamino-containing compound and an amine compound having at least two primary amino groups, at least two secondary amino groups, or at least one primary amino group plus at least one secondary amino group.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: December 9, 2014
    Assignee: 3M Innovative Properties Company
    Inventors: Suresh S. Iyer, Miguel A. Guerra, Richard G. Hansen, David S. Hays, Ramesh C. Kumar, George G. I. Moore, Yu Yang
  • Publication number: 20140212613
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Application
    Filed: April 1, 2014
    Publication date: July 31, 2014
    Applicant: ARKEMA FRANCE
    Inventors: Thierry BRIFFAUD, Philiippe BLONDEL
  • Patent number: 8779085
    Abstract: The present invention discloses a method of producing a modified polyimide comprising a polycarbonate, which modified polyimide has excellent electric properties and adhesion as well as excellent heat resistance, flexibility, bending property, low warping, chemical resistance and storage stability; and the modified polyimide. Also disclosed are a composition comprising the modified polyimide and used thereof.
    Type: Grant
    Filed: April 30, 2010
    Date of Patent: July 15, 2014
    Assignee: PI R&D Co., Ltd.
    Inventors: Toshiyuki Goshima, Maw Soe Win, Eika Kyo
  • Publication number: 20140194570
    Abstract: There is provided a production method of a crystalline polyamide resin by thermal polycondensation of a mixture including at least a diamine component, a dicarboxylic acid component and water as a starting material, wherein the diamine component includes (A) pentamethylene diamine at a ratio that is equal to or greater than 10 mol % and less than 80 mol % relative to a gross amount of the diamine component; and the dicarboxylic acid component includes (B) at least one selected from the group consisting of an aromatic dicarboxylic acid, an alicyclic dicarboxylic acid and dialkyl ester derivatives thereof at a ratio that is equal to or greater than 76 mol % and equal to or less than 100 mol % relative to a gross amount of the dicarboxylic acid component, the production method comprising: a first step that heats the above mixture, which has a water content equal to or less than 30% by weight, at a temperature equal to or higher than 200° C. under a pressure of 1.8 to 3.
    Type: Application
    Filed: August 13, 2012
    Publication date: July 10, 2014
    Applicant: TORAY INDUSTRIES, INC.
    Inventors: Koya Kato, Atsushi Masunaga, Eri Hatano, Hideo Matsuoka
  • Patent number: 8772438
    Abstract: A process for making a polyamide polymer, said process comprising heating, in one or more ionic liquid(s), one or more polyamide precursor(s) selected from: (i) one or more free dicarboxylic acid(s) or ester(s) thereof, with one or more diamine(s); or (ii) one or more salt(s) of a dicarboxylic acid with a diamine; or (iii) one or more lactam(s); or (iv) mixtures of any of the foregoing precursors (i) to (iii).
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: July 8, 2014
    Assignee: Invista North America S.är.l.
    Inventors: Keith Whiston, Charles Richard Langrick, Kenneth Richard Seddon, Alberto V. Puga
  • Patent number: 8759475
    Abstract: Polyamides, e.g., polyhexamethylene adipamide, are continuously produced via the following stages: Stage 1: into and through a reactor, polycondensing a liquid stream which contain the polyamide monomer(s) at a pressure P1 greater than atmospheric pressure, the stream of material at the outlet of the reactor including a vapor phase which contains steam and a liquid phase which at least contains the product of polycondensation; Stage 2: feeding the outlet stream of material into a chamber, evacuating at least a portion of the vapor phase therefrom and recovering at least the liquid phase which at least contains the product of polycondensation, the pressure P2 in the chamber being regulated at a set value such that it is greater than atmospheric pressure and the residence time of said liquid phase in the chamber being less than 5 minutes; and Stage 3: pressure reducing at least the liquid phase which at least contains the stream of polycondensation product recovered during Stage 2.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: June 24, 2014
    Assignee: Rhodia Operations
    Inventors: Jean-Francois Thierry, Sébastien Lomel, Vincent Mollet, Matthieu Helft, Cédric Fillon
  • Patent number: 8748004
    Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.
    Type: Grant
    Filed: August 6, 2009
    Date of Patent: June 10, 2014
    Assignee: Arkema France
    Inventors: Thierry Briffaud, Philippe Blondel
  • Patent number: 8603634
    Abstract: This invention relates to poly(ester amide)s (PEAs) comprising inactivated terminal amino and carboxyl groups, methods of synthesizing the inactivated PEAs and uses for them in the treatment of vascular diseases.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: December 10, 2013
    Assignee: Abbott Cardiovascular Systems Inc.
    Inventors: Jessica Renee DesNoyer, Stephen Dirk Pacetti, Vidya Nayak, Lothar Kleiner
  • Publication number: 20130295309
    Abstract: A resin composition, preferably an adhesive composition, comprising a polyether polyamide elastomer capable of being strongly bended with a polyimide resin, preferably strongly bended through an easy process to form an interface between the polyimide resin and the composition, and a bonded composite having the resin composition and a polyimide resin which together form an interface to be bonded with each other. A resin composition for forming an interface together with a polyimide resin for bonding, wherein the resin composition comprises a polyether polyamide elastomer (component R) obtained by subjecting a specific aminocarboxylic acid compound A1 and/or lactam compound A2, polyether compound B, and dicarboxylic acid compound C to polymerization, wherein the content of the component R in the resin composition is 80 to 100% by weight.
    Type: Application
    Filed: December 28, 2011
    Publication date: November 7, 2013
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Yuma Irisa, Shuichi Maeda
  • Patent number: 8546517
    Abstract: The present invention generally relates to a poly(bisoxalamide) and a process for preparing and article comprising the poly(bisoxalamide).
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: October 1, 2013
    Inventors: Rene Broos, Niels Jurrian Sijbrandi, Pieter Jelle Dijkstra, Jan Feijen
  • Patent number: 8541539
    Abstract: A method for preparing a water-soluble polyamide, includes copolymerizing reactive monomers including caprolactam; ethylene glycol bis(2-aminoethyl)ether or ethylene glycol bis(3-aminopropyl)ether; and 5-sulfoisophthalic acid monosodium salt, wherein a molar ratio of caprolactam:ethylene glycol bis(2-aminoethyl)ether or ethylene glycol bis(3 -aminopropyl)ether:5-sulfoisophthalic acid monosodium salt is about 0:1:1 to about 5:1:1, advantageously about 1.85:1:1. Copolymerizing takes place at a copolymerization temperature of about 222-250° C. and a copolymerization pressure of about 3 Bar. The method further includes maintaining a temperature of about 222-250° C. for about 2-3 hours under normal pressure after the copolymerization step. The water-soluble polyamide has a solubility in water of about 10-70%.
    Type: Grant
    Filed: December 29, 2008
    Date of Patent: September 24, 2013
    Assignee: Taiwan Textile Research Institute
    Inventors: Yu-Chi Tseng, Chin-Wen Chen, S-P Rwei
  • Patent number: 8357455
    Abstract: The invention relates to the use of a molding composition which comprises at least 50% by weight of a copolyamide, which is composed of the following monomer combination: a) from 65 to 99 mol % of a substantially equimolar mixture composed of an unbranched aliphatic diamine having from 6 to 18 carbon atoms and of an unbranched aliphatic dicarboxylic acid having from 6 to 18 carbon atoms, ?where the mixture composed of diamine and dicarboxylic acid comprises an average of from 8 to 12 carbon atoms, b) from 1 to 35 mol % of a substantially equimolar mixture composed of a cycloaliphatic diamine having from 8 to 20 carbon atoms and of a dicarboxylic acid having from 6 to 18 carbon atoms, for production of a printable or printed item, such as a ski topcoat.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: January 22, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Franz-Erich Baumann, Roland Wursche, Harald Häger, Sonja Bollmann, Kirsten Alting
  • Patent number: 8268937
    Abstract: The invention pertains to an aramid copolymer composition comprising an aramid copolymer having at least one arylene carboxylic acid moiety and at least one hydroxyarylene moiety, or comprising an aramid copolymer having at least one arylene carboxylic acid moiety or having at least one hydroxyarylene moiety, and a crosslinker agent. The invention further relates to crosslinked copolymers derived thereof and shaped articles comprising said crosslinked copolymers.
    Type: Grant
    Filed: September 1, 2007
    Date of Patent: September 18, 2012
    Assignee: Teijin Aramid B.V.
    Inventors: Johannes Bos, Sandra Corien Noordewier
  • Publication number: 20120095161
    Abstract: A molding compound, containing at least 30% by weight of a copolyamide, which is derived from the following monomers: a) 50 to 95 mole percent of the combination of a diamine, selected from the group consisting of 1,9-nonane diamine, 1,10-decane diamine, 1,11-undecane diamine and 1,12-dodecane diamine, and terephthalic acid, and b) 5 to 50 mole percent of the combination of a diamine, selected from the group consisting of 2,2,4-trimethylhexamethylene diamine, 2,4,4-trimethylhexamethylene diamine, and mixtures thereof, and terephthalic acid. The copolyamide is crystalline and has low water absorption.
    Type: Application
    Filed: July 8, 2010
    Publication date: April 19, 2012
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Andreas Pawlik, Martin Roos, Franz-Erich Baumann, Harald Haeger
  • Publication number: 20120088109
    Abstract: A linear polyimide is produced from mellophanic dianhydride, diamine (NH2-A-NH2), and a monofunctional acid anhydride and contains a repeating unit represented by the following general formula (3): wherein A represents a divalent aromatic diamine residue or aliphatic diamine residue, B represents a monofunctional acid anhydride residue, and n represents a degree of polymerization.
    Type: Application
    Filed: May 26, 2009
    Publication date: April 12, 2012
    Applicant: JFE CHEMICAL CORPORATION
    Inventors: Masatoshi Hasegawa, Naoyuki Kitamura
  • Publication number: 20120021234
    Abstract: Provided is a low-cost polyimide, containing cyclohexane diamine as a diamine unit, that has a low thermal expansion coefficient. Said block polyimide contains blocks having the repeating structural unit shown in formula (1A) and blocks having the repeating structural unit shown in formula (1B). This block polyimide is preferably obtained by imidizing a block polyamide acid imide that contains blocks having the repeating structural unit shown in formula (2A) and blocks having the repeating structural unit shown in formula (2B).
    Type: Application
    Filed: March 18, 2010
    Publication date: January 26, 2012
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Kenichi Fukukawa, Tatsuhiro Urakami, Yoshihiro Sakata, Wataru Yamashita, Masaki Okazaki
  • Publication number: 20120015298
    Abstract: Disclosed is a photosensitive resin composition capable of displaying satisfactory patterning performance against an alkaline developer and yielding a cured film of a sufficiently low coefficient of linear thermal expansion. The photosensitive resin composition contains a photopolymerization initiator and a polyimide precursor obtained by the reaction of an ester-containing diamine such as 4-aminophenyl 4?-aminobenzoate, a biphenyl-based diamine such as 4,4?-diamino-2,2?-dimethylbiphenyl, and an unsaturated group-containing diamine such as 4,4?-diamino-2,2?-divinylbiphenyl with an acid anhydride such as pyromellitic dianhydride. The content of the structural unit derived from the unsaturated group-containing diamine in the polyimide precursor is 5-60 mol %.
    Type: Application
    Filed: March 24, 2010
    Publication date: January 19, 2012
    Inventor: Yasuyuki Takao
  • Publication number: 20110288265
    Abstract: The invention relates to a plastic container or conduit for a cooling system, a heating system, an air intake system, an exhaust system, a pressure system or a fuel system, consisting of or comprising a part or a layer made of a thermoplastic polymer composition comprising a semi-crystalline semi-aromatic polyamide having a glass transition temperature (Tg) of at least 115° C.
    Type: Application
    Filed: January 21, 2010
    Publication date: November 24, 2011
    Inventors: Eric W. Vegte Van Der, Johannes Hoekstra
  • Patent number: 8030433
    Abstract: Tailorable polyimide resin systems suitable for processing by resin transfer molding (RTM) and resin infusion (RI) methods. An exemplary resin system includes first and second prepolymer components present in respective amounts to provide the desired processibility. The cured polyimide system exhibits high glass transition temperature and other properties required for gas turbine engine applications. The first and second prepolymer components independently comprise a monomeric mixture or a reaction product of a diamine component, a dianhydride component, and an end group component.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: October 4, 2011
    Assignee: General Electric Company
    Inventors: Stephen Mark Whiteker, Lisa Vinciguerra Shafer, Warren Rosal Ronk
  • Publication number: 20110189419
    Abstract: The invention relates to a polyamide comprising at least two units having the following general formula: 4.Y in which: 4 denotes butanediamine, and Y represents a dicarboxylic acid chosen from a linear or branched aliphatic dicarboxylic acid, a cycloaliphatic diacid and an aromatic diacid, the dicarboxylic acid containing from 7 to 11 carbon atoms, the butanediamine contains carbon of renewable origin, except for the fact that when the polyamide is a copolyamide, it cannot contain 100% by mass of organic carbon derived from renewable raw materials relative to the total mass of polyamide carbon. The invention also relates to a composition comprising this polyamide and the use of this polyamide and of such a composition.
    Type: Application
    Filed: July 6, 2009
    Publication date: August 4, 2011
    Applicant: ARKEMA FRANCE
    Inventors: Guillaume Le, Julien Jouanneau, Thierry Briffaud
  • Publication number: 20110171408
    Abstract: The present invention relates to a copolyamide comprising at least two units and corresponding to the following general formula: A/(diamine).(Cw diacid), in which: the diamine is a cycloaliphatic diamine, w represents the number of carbon atoms of the diacid, A is chosen from a unit obtained from an amino acid or from a lactam and a unit corresponding to the formula (Cx diamine).(Cy diacid), with x representing the number of carbon atoms of the diamine and y representing the number of carbon atoms of the diacid, and in which at least one of the monomers chosen from A and the Cw diacid is obtained, in all or part, from renewable starting materials according to Standard ASTM D6866. The invention also relates to a composition comprising this copolyamide and to the use of this copolyamide and of such a composition.
    Type: Application
    Filed: June 22, 2009
    Publication date: July 14, 2011
    Applicant: Arkema France
    Inventors: Benjamin Saillard, Philippe Blondel, Claire Michalowicz
  • Publication number: 20110165359
    Abstract: The invention relates to a polyamide comprising at least two units having the following general formula: X.Y where: X is an alkylaromatic diamine and Y is an aliphatic carboxylic diacid selected from dodecanedioic (C12) acid, tetradecanedioic (C14) acid, hexadecanedioic (C16) acid, characterized in that the carboxylic diacid comprises organic carbon from a renewable source determined according to standard ASTM D6866 The invention also relates to a composition comprising this polyamide and the use of said polyamide and of such a composition.
    Type: Application
    Filed: July 3, 2009
    Publication date: July 7, 2011
    Inventors: Guillaume Le, Julien Jouanneau, Benjamin Saillard
  • Publication number: 20110105683
    Abstract: Disclosed is a polyamide resin which is produced by the polycondensation of (A) pentamethylenediamin, (B) terephthalic acid and/or a derivative thereof, and (C) at least one member selected from adipic acid, sebacic acid, undecanedioic acid, dodecanedioic acid, isophthalic acid, 1,9-diaminononane, 1,10-diaminodecane, 1,12-diaminododecane, caprolactam, undecalactam, laurolactam, aminocaproic acid, 11-aminoundecanoic acid, 12-aminododecanoic acid, and derivatives of these compounds. In the polyamide resin, the ratio of a repeating unit derived from the component (C) is 10 to 50 wt % (inclusive) relative to the total weight of the polymer. A solution of the polyamide resin in 98% sulfuric acid, which contains the polyamide resin at a concentration of 0.01 g/ml, has a relative viscosity of 1.5 to 4.5 at 25° C.
    Type: Application
    Filed: June 29, 2009
    Publication date: May 5, 2011
    Inventors: Koya Kato, Masaru Akita, Hideo Matsuoka
  • Publication number: 20110014833
    Abstract: An object of the present invention is to provide a copolymerized polyether polyamide resin for coating on or for impregnation to a woven or knitted fabric, which resin further enhances slippage resistance and tear strength affecting the developing property of an airbag which is one of the automobile safety parts, as compared with those in the prior art. According to the present invention, a copolymerized polyether polyamide resin for coating on or for impregnation to a woven or knitted fabric is provided, characterized in that, elongation and elastic modulus of the copolymerized polyether polyamide resin are not less than 1000% and not more than 15 MPa, respectively.
    Type: Application
    Filed: October 16, 2008
    Publication date: January 20, 2011
    Applicant: Toyo Boseki Kabushiki Kaisha
    Inventors: Hiroaki Hagiwara, Kenichiro Kano, Gaku Maruyama, Takahiro Hattori, Takashi Tsuruta
  • Patent number: 7750110
    Abstract: The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an ?,?-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.
    Type: Grant
    Filed: October 5, 2005
    Date of Patent: July 6, 2010
    Assignee: Arkema France
    Inventors: Philippe Blondel, Thibaut Montanari, Annett Linemann, Nicolas Amouroux, Henri Decraemer
  • Patent number: 7696401
    Abstract: An absorbent material formed at least in part of a cross-linked polymer. The absorbent material has a centrifuge retention capacity as determined by a Centrifuge Retention Capacity Test of at least about 20 g/g and a gel bed permeability under load as determined by a Gel Bed Permeability Under Load Test of at least about 300×10?9 cm2 or a free swell gel bed permeability as determined by a Free Swell Gel Bed Permeability Test of at least about 2,500×10?9 cm2. The cross-linked polymer may comprise either at least about 75 weight percent anionic polymer or at least about 75 weight percent cationic polymer. In one embodiment, the cross-linked polymer is surface treated with a water soluble non-cross-linked polymer having a potential for becoming charged opposite that of the cross-linked polymer.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: April 13, 2010
    Assignee: Evonik Stockhausen, Inc.
    Inventors: Jian Qin, Xiaomin Zhang, Debra Ann Miller
  • Publication number: 20080281073
    Abstract: It is to provide a high purity oxydiphthalic anhydride with which, in production of a polyimide containing an oxydiphthalic anhydride, one having sufficiently high strength can be produced, and an industrially simple process for producing it. A high purity oxydiphthalic anhydride, which has a content of fine insoluble particles having a projected area diameter of from 5 to 20 ?m, of at most 3,000 particles per 1 g, and has a light transmittance at 400 nm of at least 98.5% in a light path length of 1 cm when dissolved in acetonitrile at a concentration of 4 g/L.
    Type: Application
    Filed: December 7, 2005
    Publication date: November 13, 2008
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Kazuhiro Nagayama, Toshiharu Yokoyama, Jun Takahara, Makoto Nitta, Hiroshi Mikami
  • Publication number: 20080262191
    Abstract: Provided herein are methods for preparing maleimides, polyimides and maleimide-terminated polyimides. Specifically disclosed are methods for preparing maleimides from N-substituted maleamic acids in the presence of an alcohol catalyst and an acid co-catalyst in a solvent. Also disclosed are methods for preparing polyimides by reacting a diamine with a dianhydride in a reaction medium that includes a solvent and a polar protic co-solvent. Further provided are methods for preparing maleimide-terminated polyimides from diamines in an aromatic solvent containing a polar protic co-solvent.
    Type: Application
    Filed: January 28, 2008
    Publication date: October 23, 2008
    Inventor: Farhad G. Mizori
  • Publication number: 20080146769
    Abstract: Tailorable polyimide resin systems suitable for processing by resin transfer molding (RTM) and resin infusion (RI) methods. An exemplary resin system includes first and second prepolymer components present in respective amounts to provide the desired processibility. The cured polyimide system exhibits high glass transition temperature and other properties required for gas turbine engine applications. The first and second prepolymer components independently comprise a monomeric mixture or a reaction product of a diamine component, a dianhydride component, and an end group component.
    Type: Application
    Filed: December 27, 2007
    Publication date: June 19, 2008
    Inventors: Stephen Mark Whiteker, Lisa Vinciguerra Shafer, Warren Rosal Ronk
  • Patent number: 7388048
    Abstract: The present invention relates to a flexible semiaromatic polyamide composition with a low moisture uptake comprising, by weight, the total being 100: 60 to 99.5% (preferably 70 to 93%) of at least one copolyamide of formula X/Y,Ar in which: Y denotes the residues of an aliphatic diamine having from 8 to 20 carbon atoms, Ar denotes the residues of an aromatic dicarboxylic acid, X denotes either the residues of aminoundecanoic acid NH2—(CH2)10—COOH, of lactam-12 or of the corresponding amino acid, or X denotes the unit Y,x, residue from the condensation of the diamine with an aliphatic diacid (x) having between 8 and 20 carbon atoms, or X denotes the unit Y,I, residue from the condensation of the diamine with isophthalic acid, ?0.5 to 40% (preferably 7 to 30%) of at least one product chosen from plasticizers, nanofillers, polyolefins, crosslinked polyolefins and additives.
    Type: Grant
    Filed: August 2, 2004
    Date of Patent: June 17, 2008
    Assignee: Arkema France
    Inventors: Philippe Blondel, Thierry Briffaud, Annett Linemann, Helene Egret, Pierre Nogues
  • Patent number: 7381788
    Abstract: Provided is a continuous production method of a polyamide with stabilized polymerization degree and good quality, particularly an aromatic-containing polyamide.
    Type: Grant
    Filed: August 27, 2003
    Date of Patent: June 3, 2008
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Yasuhito Tsujii, Gaku Maruyama, Kaoru Ogawa, Yoshinori Takada, Kazuhisa Koishi, Kenta Susuki
  • Patent number: 7288619
    Abstract: A composition comprises a condensation product of an amine-reactive fluorinated polyether and a polyamine. The compositions may be in dispersed in water.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: October 30, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Zai-Ming Qiu, Naiyong Jing
  • Patent number: 7026435
    Abstract: Polymer derivatives based upon polyalkyleneimine backbones having from about 20% to about 60% of their reactive amino functionalities substituted by C14-20 carboxylic acids, are disclosed. Fiber lubricants and/or sizing compositions comprising such polymer derivatives are also disclosed. The disclosed fiber lubricants exhibit excellent affinity for fiberglass fibers and have excellent hydrophobicity, while also providing excellent lubrication. Methods for preparing said derivatives are also disclosed. Also disclosed are methods for treating fibers using the polymer derivatives.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: April 11, 2006
    Assignee: Cognis Corporation
    Inventors: Douglas F. Fry, Frank Norman Tuller
  • Patent number: 6956099
    Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: October 18, 2005
    Assignee: Arizona Chemical Company
    Inventor: Mark S. Pavlin
  • Patent number: 6864348
    Abstract: Polyetherpolyamide elastomer showing a low water absorption, a high stress relaxation, and a high elastic recovery percentage of elongation is obtainable by polymerizing an aminocarboxylic acid compound and/or a lactam compound, a triblock polyetherdiamine compound having the following formula, and a dicarboxylic acid compound: [x is a value of 1 to 20, y is a value of 4 to 50, z is a value of 1 to 20].
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: March 8, 2005
    Assignee: UBE Industries, Ltd.
    Inventors: Hiroshi Okushita, Tadao Muramatsu, Teruaki Fujii
  • Patent number: 6818732
    Abstract: A series of initiators based on transition metal complexes for the polymerization of optically active beta-lactams into poly-beta-peptides and block copolymers have been developed. These initiators are unique in being able to eliminate chain transfer and chain termination side reactions from these polymerizations resulting in narrow molecular weight distributions, molecular weight control, and the ability to prepare copolymers of defined block sequence and composition.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: November 16, 2004
    Assignee: The Regents of the University of California
    Inventors: Timothy J. Deming, Jianjun Cheng
  • Publication number: 20040220378
    Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These elastomer compositions comprise reaction products of polyisocyanates and telechelic polymers having isocyanate-reactive end-groups such as hydroxyl groups and/or amine groups. These elastomer compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.
    Type: Application
    Filed: June 2, 2004
    Publication date: November 4, 2004
    Inventors: Manjari Kuntimaddi, Shenshen Wu
  • Publication number: 20040220377
    Abstract: Golf balls comprising thermoplastic, thermoset, castable, or millable elastomer compositions are presently disclosed. These elastomer compositions comprise reaction products of polyisocyanates and telechelic polymers having isocyanate-reactive end-groups such as hydroxyl groups and/or amine groups. These elastomer compositions can be used in any one or more portions of the golf balls, such as inner center, core, inner core layer, intermediate core layer, outer core layer, intermediate layer, cover, inner cover layer, intermediate cover layer, and/or outer cover layer.
    Type: Application
    Filed: June 2, 2004
    Publication date: November 4, 2004
    Inventors: Manjari Kuntimaddi, Shenshen Wu
  • Patent number: 6750318
    Abstract: The polyamide resin of the present invention is produced by the polycondensation of a dicarboxylic acid component and a diamine component containing xylylenediamine and bisaminomethylcyclohexane in a total amount of 70 mol % or higher. The polyamide resin contains impurities having a boiling point of from 150 to 300° C. at ordinary pressure and a solubility parameter of from 8 to 16 in a total amount of 0.3% by weight or lower based on the weight of the polyamide resin. The polyamide resin is free from various inconveniences due to inclusion of the impurities, and suitably used in applications for molding materials, bottles, sheets, films and fibers.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: June 15, 2004
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Kazumi Tanaka, Takatoshi Shida, Hideyuki Kurose
  • Publication number: 20040054123
    Abstract: A mixture substantially comprising caprolactam and water is heated for at most 30 minutes to obtain a polyamide prepolymer having an amino end group content of at least 0.1 mmol/g and a cyclic oligomer content of at most 0.6% by weight. An aqueous solution of caprolactam having a water content of from 2 to 20% by weight is heated under pressure at a temperature of from 200 to 330° C. for 1 to 30 minutes to obtain a polyamide prepolymer having an amino group content of at least 0.1 mmol/g and a cyclic oligomer content of at most 0.6% by weight.
    Type: Application
    Filed: June 18, 2003
    Publication date: March 18, 2004
    Inventors: Yasuto Tachibana, Minoru Noda, Toru Nishimura
  • Patent number: 6623764
    Abstract: Copolymers designed for use as particulate carriers containing functionalizable amino acid subunits for coupling with targeting ligands are described. The copolymers are polyesters composed of &agr;-hydroxy acid subunits such as D,L-lactide and pseudo-&agr;-amino acid subunits which may be derived from serine or terpolymers of D,L-lactide and glycolide and pseudo-&agr;-amino acid subunits which may be derived from serine. Stable vaccine preparations useful as delayed release formulations containing antigen or antigens and adjuvants encapsulated within or physically mixed with polymeric mircoparticles are described. The particulate carriers are useful for delivering agents to the immune system of a subject by mucosal or parenteral routes to produce immune responses, including antibody and protective responses.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: September 23, 2003
    Assignee: Aventis Pasteur Limited
    Inventors: Kenneth K. Sokoll, Pele Chong, Michel H. Klein
  • Patent number: 6566486
    Abstract: A process for the production of polyamides is disclosed. In a first reaction step, suitable monomers such as caprolactam or an aliphatic aminocarboxylic acid are reacted with polyfunctional amines, which contain at least one secondary amino group, and/or with salts containing such amines and dicarboxylic acids. The reaction product is in a further process step undergoes solid phase post-condensation.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: May 20, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlev Joachimi, Hans-Jürgen Dietrich, Heinrich Morhenn, Cliff Scherer, Andreas Gittinger, Friedrich-Karl Bruder
  • Patent number: 6509439
    Abstract: A process for producing polyamides from dinitriles and diamines in a continuous reaction using subsequent heating steps. In particular, the process involves contacting a dinitrile, a diamine, water, and optionally a catalyst to form a reaction mixture; heating the reaction mixture to a first elevated temperature of between about 180 to about 240° C., maintaining said temperature for about 0.10 to about 20 hours, and optionally controlling the pressure in this heating step by venting; heating the reaction mixture to a second elevated temperature of between about 250 to about 350° C., adding water to the reaction mixture before or after the second elevated temperature is reached, maintaining the pressure in the second heating step above atmospheric pressure by venting at least some of the water, and maintaining the second elevated temperature for a period of about 0.10 to about 10 hours; and recovering the polyamide.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: January 21, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, David N Marks, Maria Van Eijndhoven, Hari Babu Sunkara
  • Publication number: 20020132964
    Abstract: In the process for producing polyamide of the present invention, a diamine and a dicarboxylic acid are melt-polycondensed in a batch-wise fist polymerizer in the absence of a solvent to produce a middle-stage polyamide. The diamine has a boiling point higher than a melting point of the middle-stage polyamide being produced under inner pressures of the first polymerizer. The middle-stage polyamide is fed into a continuous second polymerizer while controlling the change of relative viscosity within ±0.2, and further polycondensed there to produce the objective polyamide. With such a process, the change of polymerization degree of the middle-stage polyamide during the switching of the polymerization step from a batch-wise manner to a continuous manner is avoided, thereby preventing the variation in quality of the final product.
    Type: Application
    Filed: January 8, 2002
    Publication date: September 19, 2002
    Inventors: Kazumi Tanaka, Takatoshi Shida, Hideyuki Kurose