With Reactant Containing At Least Two -c-c(=x)-x Groups Patents (Class 528/84)
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Patent number: 7989061Abstract: A polylactic acid monofilament includes a linear polylactic acid with a relative viscosity ?rel of in the range of 2.7 to 4.5, prepared from lactic acid monomers wherein at least 95 mol % of the lactic acid is an L-isomer, and wherein the resin contains 0 to 30 ppm of Sn and 0 to 0.5% by weight of residual monomer.Type: GrantFiled: September 14, 2009Date of Patent: August 2, 2011Assignee: Toray Industries, Inc.Inventors: Hiroji Yoshida, Toichi Ogura
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Patent number: 7956098Abstract: The present invention relates to a binder-containing coating composition, which may be cured by free radical polymerization, wherein the binder resins contain A) the reaction product of i) one or more polyisocyanates with ii) a hydroxyl component containing ii-a) one or more hydroxyl compounds containing two ethylenically unsaturated groups, B) the reaction product of i) one or more polyisocyanates with ii) a hydroxyl component containing ii-a) one or more hydroxy functional lactone ester (meth)acrylates having a number average molecular weight of about 200 to 2,000, and C) the reaction product of i) one or more polyisocyanates with ii) a hydroxyl component containing ii-a) one or more hydroxy functional (meth)acrylates.Type: GrantFiled: April 12, 2005Date of Patent: June 7, 2011Assignee: Bayer MaterialScience LLCInventors: Richard R. Roesler, Charles A. Gambino, Catherine M. Britsch
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Publication number: 20110123476Abstract: The disclosure relates to biocompatible components useful for forming compositions for use as medical/surgical synthetic adhesives and sealants. Biocompatible components of the present disclosure may include a multifunctional amine or multifunctional polyol core, with isocyanate and/or polyalkylene oxide arms, which may optionally be capped with electrophilic or nucleophilic groups. These biocompatible components may, in embodiments, be combined with optional cross linkers to form adhesive and/or sealant compositions.Type: ApplicationFiled: January 25, 2011Publication date: May 26, 2011Inventors: Mbiya Kapiamba, Ahmad Robert Hadba
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Publication number: 20110083884Abstract: An object of the present invention is to provide (a) a polyimide precursor solution which is curable at low temperatures (not more than 200° C.) and which has excellent long-term storage stability, (b) a photosensitive resin composition, a photosensitive resin film, a thermosetting resin composition, and a polyimide insulating film, each of which is obtainable from the polyimide precursor solution and each of which is preferably usable as an insulating material for electric and electronic purposes, and (c) a printed wiring board provided with the insulating film. The above object is achievable by use of a polyimide precursor composition solution containing at least a partially imidized polyimide precursor having a urethane bond.Type: ApplicationFiled: July 15, 2009Publication date: April 14, 2011Applicant: KANEKA CORPORATIONInventors: Koji Okada, Yoshihide Sekito
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Patent number: 7897678Abstract: Fluorochemical urethane compounds and coating compositions derived therefrom are described. The compounds and compositions may be used in treating substrates, in particular substrates having a hard surface such as plastics, ceramics or glass, to render them water, oil, stain, and soil repellent.Type: GrantFiled: July 26, 2007Date of Patent: March 1, 2011Assignee: 3M Innovative Properties CompanyInventor: Zai-Ming Qiu
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Publication number: 20110039999Abstract: The present invention relates to a process for the continuous production of a biodegradable polyester based on aliphatic or aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, where a mixture composed of the aliphatic dihydroxy compounds, of the aliphatic and aromatic dicarboxylic acids, and, if appropriate, of further comonomers (component C) is mixed, without addition of a catalyst, to give a paste, or, as an alternative, the liquid esters of the dicarboxylic acids are fed into the system, as also are the dihydroxy compound and, if appropriate, further comonomers, without addition of any catalyst, and i) in a first stage, this mixture, together with the entire amount or with a portion of the catalyst, is continuously esterified or, respectively, transesterified; ii) in a second stage, the transesterification or, respectively, esterification product obtained in i) is continuously precondensed if appropriate with the remaining amount of catalyst to an intrinsic viscosity of fromType: ApplicationFiled: April 7, 2009Publication date: February 17, 2011Applicant: BASF SEInventors: Uwe Witt, Motonori Yamamoto
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Publication number: 20100249361Abstract: There is disclosed a process for producing a polyester copolymer. The process comprises the step of condensating a hydroxyacid, a diol, a dicarboxylic acid and a functionalizing agent selected to form a prepolymer having a polyester copolymer backbone with arms comprising cross-linkable groups extending therefrom. The process also comprises the step of coupling said prepolymer in the presence of a coupling agent to cross link the arms of plural prepolymer backbones and thereby form said polyester copolymer comprising said plural straight chain polyester copolymers coupled to each other by said cross-linked arms. The polyester copolymer may be biodegradable and may be used as a modifier to increase the strength of polylactic acid.Type: ApplicationFiled: July 29, 2008Publication date: September 30, 2010Inventors: Shaofeng Wang, Bo Jing, Yuqiang Huang, Lianlong Hou, Siok Ling Sherlyn Yap
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Publication number: 20100239803Abstract: The present invention discloses a thermoplastic polyurethane which is comprised of the reaction product of (1) a hydroxyl terminated polyester intermediate, (2) a polyisocyanate, and (3) a glycol chain extender; wherein the hydroxyl terminated polyester intermediate is comprised of repeat units that are derived from 1,3-propylene glycol and a dicarboxylic acid; wherein the hydroxyl terminated polyester intermediate has a number average molecular weight from 500 to 10,000; and wherein the thermoplastic polyurethane includes hard segments that are the reaction product of the polyisocyanate and the glycol chain extender. This thermoplastic polyurethane is unique in that it has a greatly reduced tendency to bloom. This is highly desirable in applications where high clarity is desired because blooming causes articles containing the thermoplastic polyurethane to be hazy or foggy in appearance.Type: ApplicationFiled: February 25, 2010Publication date: September 23, 2010Applicant: Lubrizol Advanced Materials, Inc.Inventors: Julius Farkas, Charles P. Jacobs
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Patent number: 7771806Abstract: Stable aqueous poly(urea/urethane) polymers and dispersions are made that do not require the inclusion of chain extenders, curing agents or crosslinking agents. The disclosed poly(urea/urethane) dispersions can be used to make articles such as films and gloves with reduced chance of chemical and biological allergic reaction to skin, and which exhibit improved puncture and tear resistance when compared to such articles made with other materials.Type: GrantFiled: November 4, 2003Date of Patent: August 10, 2010Assignee: INVISTA North America S.a r.l.Inventors: Young H. Kim, Michael O'Neill, Jiazhong Chen, Portia D. Yarborough
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Patent number: 7759452Abstract: A functional aspartate prepared by A) reacting an aziridine with a Michael-acceptor molecule to form an aziridinyl aspartate, and B) reacting the aziridinyl aspartate with an active hydrogen containing compound to form the functional aspartate. The functional aspartate can be used in adhesive, sealant or coating compositions that also include an isocyanate functional material. The composition can be used in a method of bonding a first substrate to a second substrate that includes applying a coating of the above-identified adhesive composition to at least one surface of the first substrate or the second substrate, and contacting a surface of the first substrate with a surface of the second substrate, where at least on of the contacting surfaces has the coating applied thereto. The composition can also be used to coat substrates.Type: GrantFiled: January 15, 2009Date of Patent: July 20, 2010Assignee: Bayer MaterialScience LLCInventors: Karsten Danielmeier, Douglas A. Wicks, Karen Marie Henderson, Evan Randall Minnich, John J. McLafferty, Stephanie A. Strazisar, Kurt C. Frisch, Jr.
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Patent number: 7741404Abstract: The present invention provides a non-aqueous composition containing a particulate solid, an organic medium and a polyurethane dispersant having an essentially linear backbone and laterally attached solvent-solubilising side chains of a polyester, a polyether, a polyacrylate or a polyolefin including mixtures of such side chains.Type: GrantFiled: May 11, 2004Date of Patent: June 22, 2010Assignee: The Lubrizol CorporationInventors: Stuart Nicholas Richards, Andrew James Shooter
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Publication number: 20100119853Abstract: The invention aims to provide a resin primer which can stick an insulator layer to a conductor foil whereof the surface is not much roughened with sufficient adhesive force, a conductor foil with resin, a laminated sheet and a method of manufacturing same. The resin primer of the invention comprises a resin having film-forming ability and a breaking energy of 0.15 J or more. The conductor foil with resin of the invention comprises a resin layer comprising a conductor foil and the aforesaid resin primer. Further, the laminated sheet of the invention comprises the conductor foil, an insulating layer disposed facing the conductor foil, and a resin layer comprising the aforesaid resin primer disposed between the conductor foil and insulating layer so that it is in contact therewith. This laminated sheet can be manufactured by heating and pressurizing a laminate comprising the aforesaid conductor foil with resin, and a prepreg laminated on this resin layer.Type: ApplicationFiled: January 15, 2010Publication date: May 13, 2010Inventors: Kenji Tanaka, Kazumasa Takeuchi, Nobuyuki Ogawa, Katsuyuki Masuda
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Patent number: 7705102Abstract: Golf equipment having at least one portion formed from amine-adduct modified polyurea compositions, including epoxy-silicone modified polyurea compositions, epoxy modified polyurea compositions, silicone modified polyurea compositions, and polyurea compositions including polyamine/carbonyl adducts and/or amine-modified adducts having backbones based on polyfunctional acrylates or methacrylates or caprolactone monomers or oligomers.Type: GrantFiled: March 13, 2006Date of Patent: April 27, 2010Assignee: Acushnet CompanyInventors: Shawn Ricci, Shenshen Wu, Manjari Kuntimaddi, Kevin M. Harris, Murali Rajagopalan
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Patent number: 7683128Abstract: The present invention provides an ionomer composition for a golf ball providing a golf ball which is excellent in abrasion-resistance, durability and resilience, and a golf ball using the same. An ionomer composition for a golf ball of the present invention comprises a binary copolymer obtained by copolymerizing an olefin monomer having 2 to 8 carbon atoms with an unsaturated monomer having an acid functional group and/or a ternary copolymer obtained by copolymerizing an olefin monomer having 2 to 8 carbon atoms, an unsaturated monomer having an acid functional group and an unsaturated carboxylic acid ester, wherein a functional group is introduced in both terminals of the copolymers.Type: GrantFiled: January 9, 2007Date of Patent: March 23, 2010Assignee: SRI Sports LimitedInventors: Toshiyuki Tarao, Takashi Sasaki, Satoko Okabe
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Patent number: 7658974Abstract: There is provided a two-pack composition for making urethane-containing structures, said composition comprising (a) a first pack comprising at least one reaction product of at least one polyisocyanate and at least one polyol, wherein said first pack has %NCO of 6% or greater, and (b) a second pack comprising at least one polyol and at least one amine catalyst, wherein the reactive mixture formed by admixing said first pack and said second pack is capable of curing in the absence of water; and wherein said reactive mixture comprises less than 3% solvent by weight based on the weight of said reactive mixture. Also provided are methods of making such urethane-containing structures, and the urethane structures made thereby.Type: GrantFiled: April 25, 2005Date of Patent: February 9, 2010Assignee: Rohm and Haas CompanyInventor: Sebastiano Failla
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Publication number: 20100022717Abstract: A terminal isocyanate group-containing polyamide resin can be produced by reacting a terminal carboxyl group-containing oligomer and a polyisocyanate compound at such a ratio that the amount of an isocyanate group exceeds that of a carboxyl group. An alkoxysilane-modified polyamide resin can be produced by reacting the terminal isocyanate group-containing polyamide resin with an alkoxysilane compound containing a secondary amine.Type: ApplicationFiled: September 7, 2007Publication date: January 28, 2010Inventors: Shirou Honma, Tamotsu Kunihiro, Tsuyoshi Iwa
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Patent number: 7645831Abstract: Reactive hot melt adhesives compositions with long open time and/or high green strength are prepared by the use of urethane diols. These results are achievable at moderate/low application viscosity or low application temperature.Type: GrantFiled: March 26, 2004Date of Patent: January 12, 2010Assignee: Henkel AG & Co. KGaAInventors: Andrew Slark, Neal Williams, Gavin Toovey
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Patent number: 7619052Abstract: A blade for electrophotographic apparatus which has a blade member formed of a polyurethane resin, wherein the polyurethane resin is a resin produced by using a polyurethane raw-material composition containing at least the following components (A) to (E): (A) a polyisocyanate; (B) a polyol having a number average molecular weight of 2,000 or more and 4,000 or less; (C) a chain extender having a molecular weight of 200 or less: (D) a polyol having a number average molecular weight which is smaller than the number average molecular weight of the component-(B) polyol and is larger than the molecular weight of the component-(C) chain extender; and (E) a urethane curing catalyst.Type: GrantFiled: March 24, 2006Date of Patent: November 17, 2009Assignee: Canon Kasei Kabushiki KaishaInventors: Shouji Inoue, Taku Hatanaka, Kenichi Mochizuki, Mayuko Kodama
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Patent number: 7608329Abstract: A polylactic acid resin suitable for use especially in textile products; textile products obtained from the resin as a raw material (a fiber, multifilament, monofilament, staple, false-twist yarn, long-fiber nonwoven fabric, etc.); and processes for producing these textile products. The polylactic acid resin is a resin consisting mainly of a polylactic acid and is characterized in that it is linear, has an L-isomer content of 95 mol % or higher, an Sn content of 30 ppm or lower, a monomer content of 0.50 wt. % or lower, and has a relative viscosity of 2.7 to 3.9 or has a weight-average molecular weight of 120,000 to 220,000 and a number-average molecular weight of 60,000 to 110,000. Each of the textile products comprises the polylactic acid resin as the main material. The textile products each comprises a polylactic acid that is excellent in processability and excellent fiber properties. The free textile products are problems in practical use.Type: GrantFiled: September 26, 2008Date of Patent: October 27, 2009Assignee: Toray Industries, Inc.Inventors: Hiroshi Kaijiyama, Hideo Ueda, Hiroji Yoshida, Toichi Ogura
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Patent number: 7592398Abstract: A coating composition comprising a first component having a first polyester polyol having a first functionality, and a second polyester polyol having a second functionality, wherein the second functionality is greater than the first functionality, and a second component comprising an isocyanate, wherein the coating has an NCO:OH ratio of 1:1 or greater is disclosed. A coated flexible substrate comprising a flexible substrate, and a coating deposited on at least a portion of the substrate, wherein the coating comprises a first component having a first polyester polyol having a first functionality and a second polyester polyol having a second functionality, wherein the second functionality is greater than the first functionality and a second component comprising an isocyanate is also within the scope of the present invention.Type: GrantFiled: June 17, 2005Date of Patent: September 22, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Karen R. Rye, Brian K. Rearick, Michael L. Sproule, Deborah E. Hayes
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Patent number: 7589149Abstract: Stable aqueous poly(urea/urethane) polymers and dispersions are made that do not require the inclusion of chain extenders, curing agents or crosslinking agents.Type: GrantFiled: November 4, 2003Date of Patent: September 15, 2009Assignee: INVISTA North America S.a r.l.Inventors: Young H. Kim, Michael O'Neil, Jiazhong Chen
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Publication number: 20090191145Abstract: Adhesive systems comprising: (A) an isocyanate group-containing prepolymer prepared by reacting: (A1) an aliphatic isocyante; and (A2) a polyol having a number average molecular weight of ?400 g/mol and 2 to 6 OH groups; and (B) a curing component comprising: (B1) an amino group-containing aspartate ester of the general formula (I); wherein X represents an n-valent organic radical derived from a corresponding n-functional primary amine X(NH2)n, R1 and R2 each independently represent an organic radical having no Zerevitinov active hydrogens and n represents a whole number of at least 2; and (B2) an organic filler having a viscosity of 10 to 6000 mPas at 23° C. measured according to DIN 53019; their use in wound and tissue incision closure, adhesive films comprising the same and dispensing systems therefor.Type: ApplicationFiled: January 23, 2009Publication date: July 30, 2009Applicant: Bayer MaterialScience AGInventors: Heike Heckroth, Burkhardt Kohler, Sebastian Dorr
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Patent number: 7550556Abstract: The present invention is to prevent the rapid viscosity rise generated at the time of dissolving or dispersing in a solvent a polymer obtained by reacting a material polymer having an acidic functional group and a hydroxyl group in the principal chain part with an isocyanate compound, in particular, a photo-curing polymer obtained by reaction with a radical polymerizable group-containing isocyanate compound. A highly stable polymer can be obtained by reacting a material polymer having a principal chain including at least a component unit having an acidic functional group and a component unit having a hydroxyl group with an isocyanate compound, and further reacting the same with an alcohol. Moreover, by producing a material polymer using a non-nitrile azo-based or peroxide-based polymerization initiator and/or introducing an isocyanate compound using a polymerization inhibitor selected from the compounds represented by the above-mentioned formulae (10) and (16), the transparency can be improved.Type: GrantFiled: August 10, 2000Date of Patent: June 23, 2009Assignee: Dai Nippon Printing Co., Ltd.Inventors: Kazuhiko Nakamura, Shunsuke Sega
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Publication number: 20080319132Abstract: In order to avoid structural heterogeneities in the networks, in accordance with the invention under consideration, a novel system of amorphous polymer networks comprising one or several segments with shape memory properties is provided. The networks are preferably composed of biodegradable and biocompatible components and open up the possibility for use in the medical domain. The systemic character of the materials allows the thermal and mechanical properties as well as the decomposition behavior to be adjusted in a specific manner. The invention under consideration particularly makes it possible to produce polyphase amorphous networks.Type: ApplicationFiled: August 16, 2004Publication date: December 25, 2008Applicant: Mnemoscience GmbHInventors: Andreas Lendlein, Armin Alteheld
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Patent number: 7431794Abstract: A process for producing a leather-like sheet, wherein a skin-like layer composed of a resin composition (C) is formed on top of a fibrous substrate (E), comprising; heating and melting a moisture-curable polyurethane hot-melt resin composition (C) which contains a hot-melt urethane prepolymer (A) having isocyanate groups at molecular terminal ends and a colorant (B), and applying said heated and melted resin composition (C) to either [1] a releasable substrate (D) and then bonding the coated surface to a fibrous substrate (E), or [2] a fibrous substrate (E) and then bonding the coated surface to a releasable substrate (D); wherein the colorant (B) contains a polyol with a number average molecular weight within a range from 1,000 to 20,000 as a vehicle (B-1), and a pigment (B-2).Type: GrantFiled: February 23, 2005Date of Patent: October 7, 2008Assignees: Dainippon Ink and Chemicals, Inc., Kuraray Co., Ltd.Inventors: Yoshinori Kanagawa, Toshio Niwa, Toshifumi Tamaki, Hisao Yoneda
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Patent number: 7427647Abstract: A coating composition useful for coating automobile and truck bodies comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: wherein X, Y, R1, R2, m and n are described in the specification, and c. 0.05 to 10% by weight, based on the total weight of the coating composition, of a metal alkoxide compound; and containing optional additional polymeric components, oligomeric components and antioxidants, light absorbers and light stabilizers.Type: GrantFiled: January 12, 2006Date of Patent: September 23, 2008Assignee: E.I. du Pont de Nemours & CompanyInventors: Stefan Reinartz, Robert John Barsotti, Patrick Henry Corcoran, Kalindi Dogra, Christian Peter Lenges, Laura Ann Lewin, Klaus Wissing
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Publication number: 20080132667Abstract: A polyimide resin is produced by the reaction of a compound selected from 1,2,4,5-cyclohexanetetracarboxylic acid, dianhydride thereof and reactive derivatives thereof and a compound selected from diamines and diisocyanates each containing at least one phenylene group and at least one isopropylidene group. The polyimide resin is colorless and exhibits a high heat resistance, a high transparency and a low water absorption.Type: ApplicationFiled: December 19, 2005Publication date: June 5, 2008Inventors: Takashi Makinoshima, Shuta Kihara
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Patent number: 7357889Abstract: Thermoplastic polyether polyurethane polymers are disclosed which are mixed with a non-polyether crosslinking agent to achieve long run times in a melt spinning process to make elastic fibers. The crosslinking agent is preferably a polyester polyol reacted with a diisocyanate. A melt spinning process is also disclosed using a polyether polyurethane with a polyester crosslinking agent. Long melt spinning run times can be achieved without experiencing excessive pressure buildup in the spinneret and fiber breakage.Type: GrantFiled: March 30, 2004Date of Patent: April 15, 2008Assignee: Lubrizol Advanced Materials, Inc.Inventors: Ravi R. Vedula, Yinbing Xia
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Patent number: 7329717Abstract: A process for preparing polyisocyanate-modified polycarboxylic acids by conversion of anhydride-group-free polycarboxylic acids with isocyanate-functional compounds. The process includes reacting A) an anhydride-group-free polycarboxylic-acid component with B) an isocyanate-functional component having an (average) isocyanate functionality of at least 1.8, at an equivalent ratio of carboxylic acid groups to isocyanate groups of from 1.2:1 to 120:1. The polyisocyanate-modified polycarboxylic acids are solid below 40° C. and liquid above 130° C., and have an average carboxylic acid functionality of at least 1.8, a content of free carboxylic acid groups of from 4.0 wt. % to 80.0 wt. % and a content of amide groups of from 0.4 wt. % to 32.5 wt. %.Type: GrantFiled: June 21, 2004Date of Patent: February 12, 2008Assignee: Bayer MaterialScience AGInventors: Hans-Josef Laas, Christoph Gürtler, Reinhard Halpaap, Michael Grahl, Peter Thometzek, James Rawlins
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Patent number: 7276288Abstract: A coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: wherein X is an aliphatic or cycloaliphatic group, R1 and R2 are the same or different organic groups that are inert to isocyanate groups, and n is 2 to 4, and c. optionally, a polymeric component having a number average molecular weight of 5,000 to 50,000 having reactive groups that crosslink with an isocyanate, where the reactive groups are hydroxyl, carboxyl, glycidyl, amine and any mixtures thereof; and d.Type: GrantFiled: December 16, 2003Date of Patent: October 2, 2007Assignee: E. I. du Pont de Nemours & Co.Inventors: Patrick Henry Corcoran, Joseph Norbert Weber
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Patent number: 7196154Abstract: One embodiment of the invention is a composition adapted for coating goods comprising a polyisocyanate component and a polyisocyanate reactive component further comprising a polyaspartic ester and cycloaliphatic amine. Another embodiment of the invention is a method for coating goods by mixing a preferred polyisocyanate component with a preferred polyisocyanate reactive component and then applying the coating to the goods which are to be coated. Yet another embodiment of the invention is a method of adhering two surfaces by forming a coating by mixing a preferred polyisocyanate component with a preferred polyisocyanate reactive component, applying the coating mixture to one surface and contacting the second surface to the coated first surface.Type: GrantFiled: October 31, 2001Date of Patent: March 27, 2007Assignee: Light Black Inc.Inventor: Rafael Bonilla
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Patent number: 7193011Abstract: The present invention relates to a method of preparing water-dispersible poly (urethane-urea) having aliphatic-aromatic isocyanate, more particularly to a method of preparing water-dispersible poly (urethane-urea) having aliphatic-aromatic isocyanate, with improved mechanical/thermal properties, such as heat resistance, chemical resistance and adhesion, good cost competitiveness and environmental friendliness, by reacting polyester polyol, dimethylol propionic acid and an aromatic isocyanate compound to obtain a hydroxyl (OH)-terminated prepolymer, adding an aliphatic isocyanate compound to said OH-terminated prepolymer to obtain an isocyanate (NCO)-terminated prepolymer wherein aromatic-aliphatic isocyanate is hybridized, neutralizing, water-dispersing and chain extending said NCO-terminated prepolymer.Type: GrantFiled: June 24, 2004Date of Patent: March 20, 2007Assignee: Yonsei UniversityInventors: Jung Hyun Kim, In Woo Cheong, Kyoung Min Ahn
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Patent number: 7193030Abstract: An acid anhydride of the formula (4), and a polyimide using the acid anhydride, wherein anhydrides are substituted at sites 3 or sites 4, which acid anhydride is obtained from, as a raw material, a bifunctional phenylene ether oligomer having a number average molecular weight of 500 to 3,000, represented by the formula (1).Type: GrantFiled: June 17, 2004Date of Patent: March 20, 2007Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Daisuke Ohno, Kenji Ishii, Yasumasa Norisue, Masamitchi Mizukami, Atsushi Hirashima
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Patent number: 7148307Abstract: The present invention relates to novel polyesterpolyols with cyclic imide and isocyanurate structure and to their use in coating compositions.Type: GrantFiled: August 11, 2003Date of Patent: December 12, 2006Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Raul Pires, Ulrich Freudenberg, Robert Reyer
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Patent number: 7112647Abstract: An object of the present invention is to provide a fluorinated polymer of adequate molecular weight with excellent transparency in a wavelength range from visible to near infrared, and to also provide a method of producing such a polymer. The present invention provides a fluorinated polymer comprising a structure represented by a formula (1) as a structural unit, as well as a method of producing this polymer using a corresponding tetrafluoroxylylenediamine or a tetrafluoroxylylene glycol as a raw material.Type: GrantFiled: December 25, 2002Date of Patent: September 26, 2006Assignee: Showa Denko K.K.Inventors: Isamu Taguchi, Ryuji Monden, Nobutoshi Sasaki, Hideo Miyata, Kohei Morikawa
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Patent number: 7105624Abstract: A golf ball comprising a core and at least one layer formed about the core is disclosed. The layer may be composed of a material formed from reactants comprising at least one polyisocyanate and at least one polyaspartic ester, such as N,N?-di(ethylmaleate-amino)-dicyclohexylmethane, N,N?-di(ethylmaleate-amino)-dimethyl-dicyclohexylmethane, N,N?-diethylmaleate-2-methyl-pentamethylene diamine, or a blend thereof. The layer may be an intermediate layer, an outer cover layer, or a coating layer.Type: GrantFiled: January 28, 2005Date of Patent: September 12, 2006Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Shenshen Wu
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Patent number: 7049001Abstract: Compounds with carbodiimide units and carboxyl or carboxylate groups (compounds V), derived from a) aliphatic or araliphatic C4 to C20 polyisocyanates (component a) b) hydroxy carboxylic acids or hydroxy carboxylic salts (component b) and c) if desired, further compounds, carrying groups able to react with isocyanate groups in an addition reaction (component c) d) if desired, other isocyanates (component d), the carbodiimide units being derived essentially exclusively from the isocyanate groups of component a).Type: GrantFiled: January 5, 2001Date of Patent: May 23, 2006Assignee: BASF AktiengesellschaftInventors: Karl Häberle, Ulrike Licht, Sabine Kielhorn-Bayer, Christian Lach, Bernd Meyer-Roscher, Robert Shane Porzio, Christelle Staller, Peter Weyland
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Patent number: 6958379Abstract: Golf equipment having improved cut and shear resistance that includes a polyurea composition, preferably saturated and/or water resistant, formed of a polyurea prepolymer and a curing agent, wherein the polyurea prepolymer includes an isocyanate and an amine-terminated compound, and wherein the curing agent includes a hydroxy-terminated curing agent, amine-terminated curing agent, or a mixture thereof.Type: GrantFiled: April 9, 2003Date of Patent: October 25, 2005Assignee: Acushnet CompanyInventors: Shenshen Wu, David A. Bulpett, Murali Rajagopalan
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Publication number: 20040259968Abstract: The invention relates to reactive polyurethane compositions that can be produced by reacting polyols with a stoichiometric excess of mixtures consisting of asymmetric polyisocyanates having a molecular weight of less than 600 and an NCO functionality ranging from 0.175 to 2.5 and high-molecular isocyanates. These reactive polyurethane compositions re suited for producing reactive hot-melt-type adhesives, solvent-free or solvent-containing laminating adhesives, assembly foams, casting compounds, soft/hard and integral foams and for producing reactive one-component or two-component adhesives/sealants.Type: ApplicationFiled: June 22, 2004Publication date: December 23, 2004Inventor: Michael Krebs
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Patent number: 6750286Abstract: A polyurethane which has a number average molecular weight Mn of from 3,000 to 50,000 and an acid number of from 10 to 35 and is preparable by reacting (a1) at least one polyesterpolyol having a number average molecular weight Mn of from 1,000 to 4,000, an acid number of from 0 to 15, and an OH number of from 35 to 150, based on acyclic aliphatic and cycloaliphatic dicarboxylic acids, (a2) a mixture of at least one diol and one triol, (a3) at least one compound containing at least two isocyanate-reactive functional groups and at least one functional group capable of forming anions, and (a4) a mixture of at least one, acyclic aliphatic and at least one cycloaliphatic diisocyanate, to give an isocyanato-containing prepolymer that is then chain extended with a polyfunctional amine or amino alcohol and, if desired, is neutralized.Type: GrantFiled: June 26, 2001Date of Patent: June 15, 2004Assignee: BASF Coatings AGInventors: Stephan Schwarte, Michael Hartung
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Publication number: 20040092697Abstract: A gel coat for a surface of a composite article contains a curable urethane acrylate resin preferably based on aliphatic polyester polyols and aliphatic polyisocyanates. The gel coat provides a surface that has high gloss and color retention after prolonged exposure to ultraviolet radiation. The gel coat composition contains resin and acrylic diluents, including optional difunctional and trifunctional diluents. The gel coat is optionally pigmented to produce an article that may be used without further surface treatment.Type: ApplicationFiled: July 21, 2003Publication date: May 13, 2004Inventors: Sheila F. Kia, Devi N. Rai, Hamid G. Kia, Archie W. Garner, Ehtisham A. Ashai, Brian A. Robertson, Thomas J. Melnyk
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Patent number: 6730768Abstract: A method for preparing a polyol useful in the formation of an isocyanate casting resin or coating composition is presented involving the reaction of an essentially C18 fatty acid mixture with a monofunctional alcohol to form a fatty acid ester mixture, forming a epoxidized fatty acid ester mixture from the fatty acid ester mixture, and reacting the epoxidized mixture with an aliphatic alcohol to form a polyol. The polyol can be further reacted with an isocyanate to form a casting resin or coating composition. The fatty acid mixture contains at least 80 percent oleic acid. Polyols prepared by this method provide good color quality and improved color stability during storage when used in the production of isocyanate casting resins and coating compositions.Type: GrantFiled: May 11, 1999Date of Patent: May 4, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Andreas Heidbreder, Roland Gruetzmacher, Ulrich Nagorny, Alfred Westfechtel
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Patent number: 6716892Abstract: The present invention relates to a new urethane oligomer (A) and a resin composition comprising (A) and an unsaturated group containing polycarboxylic acid resin (B) that can be diluted with water and is excellent in providing a cured product and that is suitable for a solder resist and an interlayer dielectric layer because the cured product is excellent in flexibility, soldering-heat resistance or the like and allows a development with an organic solvent or a dilute alkali solution; a photosensitive resin composition suitable for an etching resist or a cover lay; and a photosensitive film obtained thereby.Type: GrantFiled: September 5, 2001Date of Patent: April 6, 2004Assignee: Nippon Kayaku Kabushiki KaishaInventors: Satoshi Mori, Minoru Yokoshima, Noriko Kiyoyanagi, Yuichiro Matsuo, Hiroo Koyanagi
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Patent number: 6709748Abstract: The present invention provides a flexible two component polyurethane and method for producing the polyurethane. The cured polyurethane is flexible, durable and weather resistant. The polyurethane is suitable for use as a protective layer on various substrates. The flexible polyurethane is the reaction product of solvent-free reaction components. The first component includes one or more polyols, optionally, one or more diols, and a catalyst. The second component includes a primary aliphatic isocyante crosslinker.Type: GrantFiled: November 10, 2000Date of Patent: March 23, 2004Assignee: 3M Innovative Properties CompanyInventors: Chia-Tie Ho, Clarence Fullbright, Jr.
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Patent number: 6706807Abstract: A thermoplastic moulding composition that contains an aliphatic thermoplastic polyurethane (TPU) resin is disclosed. The TPU is the product of a reaction of A) a diisocyanate reactant that contains predominantly hexamethylene diisocyanate, and B) a polyol reactant that contains polytetramethylene glycol and C) a chain extending reactant that contains primarily 1,6-hexanediol. The TPU that is further characterized in the equivalence ratio of A to B and NCO index exhibits improved properties.Type: GrantFiled: September 10, 2002Date of Patent: March 16, 2004Assignee: Bayer AktiengesellschaftInventors: Wolfgang Kaufhold, Henricus Peerlings, Hans-Georg Hoppe
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Patent number: 6683151Abstract: The invention relates to a compound comprising a reaction product of (A) an isocyanate functional compound of which at least 40 wt. %, relative to the total amount of (A), has a molecular weight of at least about 500, and (B) a nitrogen-containing compound capable of reacting with said isocyanate functional compound (A). The reaction product has a molecular weight of less then about 20,000 and comprises an effective amount of groups that are able to form reversible intermolecular physical interactions such that a resulting compound shows polymeric mechanical properties at a temperature below a transition temperature. The nitrogen-containing compound is, for instance, melamine, urea, acetoguanamine, benzoguanamine, cyanamide, dicyanamide, thiourea, isocytosine, pyrimidone or aminopyridine. The supramolecular compound comprising a suitable amount of the reaction products exhibits a relatively high elongation at break.Type: GrantFiled: February 24, 2000Date of Patent: January 27, 2004Assignee: DSM N.V.Inventors: Jacobus A. Loontjens, Johan E. G. A. Jansen, Bartholomeus J. M. Plum
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Patent number: 6680352Abstract: The present, invention relates to a process for producing a fabric-elastomer composite that, when transfer or film coated, is preferable for use as an artificial leather substrate. The inventive procedure involves (a) producing an elastomer composition of at least four ingredients (an anionically-stabilized waterborne polymer dispersion, an acid-generating chemical, a cloud-point surfactant, and a foam-stabilizing surfactant); (b) incorporating sufficient gas into the liquid mixture to generate a spreadable foam; (c) applying the foam onto a porous textile substrate; (d) heating said foamed fabric until the elastomer coagulates over the fabric substrate; and (e) drying the resultant composite without destroying the coagulated structure. The resultant composite obtains a suppleness that is similar to that of leather and a surface that is suitable for transfer coating to produce artificial leather. The composite may be utilized as upholstery fabric in furniture or in automobiles, apparel, and the like.Type: GrantFiled: November 4, 2002Date of Patent: January 20, 2004Assignee: Milliken & CompanyInventors: Kirkland W. Vogt, Howell B. Eleazer
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Patent number: 6667416Abstract: To provide a method for producing polyester polyol that can provide a simple process to produce extensively improved production efficiencies and also produce the polyester polyol of stable in quality, an apparatus for producing the polyester polyol produced by the method, a polyester polyol produced by the method, and a polyurethane foam obtained by use of the polyester polyol produced by the method, polyethylene terephthalate and raw polyol are allowed to react in a reaction vessel to produce polyester polyol and also ethylene glycol which is a by-product of the reaction is distilled off and the distillate is modified in a modifying vessel so that it can have a predetermined hydroxyl value and then is fed to the reaction vessel again as the raw glycol, to thereby produce the polyester polyol.Type: GrantFiled: July 26, 2001Date of Patent: December 23, 2003Assignee: Mitsui Takeda Chemicals, Inc.Inventors: Kouichi Murayama, Katsumi Inaoka, Takashi Kumaki
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Patent number: 6660825Abstract: The present invention can provide a lactone polyester diol at least containing &egr;-caprolactone and a dibasic acid as constructing component units, and a polyurethane obtained using the diol and an organic diisocyanate can provide a spandex filament which is more excellent in a recovering ability of elasticity, strength, hydrolysis resistance, and heat resistance.Type: GrantFiled: July 15, 2002Date of Patent: December 9, 2003Assignee: Daicel Chemical Industries, LTDInventor: Toshio Endo
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Publication number: 20030166827Abstract: The invention relates to a cladding resin composition curable by heat, ultraviolet radiation, an electron beam or the like. The composition comprises a polyoxyalkylene polyol phosphate ester (hydroxyl value: 10-2,000 mg KOH/g) and a polymerizable or reactive functional group-containing compound. This composition is highly conductive as it is and, without incorporation of the conventional conductive additives, can be used successfully in the field of coatings and protective films where electric conductivity is a requisite.Type: ApplicationFiled: April 1, 2003Publication date: September 4, 2003Applicant: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Tetsuo Shiraiwa, Shigeo Mori