Phenolic Reactant Contains A Fused-or Bridged-ring Other Than As A 1,2 Epoxy Group Fused To Carbocyclic Or Aromatic Ring Patents (Class 528/97)
  • Patent number: 11820875
    Abstract: Provided herein is a polymer composition comprising a polyhydroxyamino ether (e.g., a crosslinked polyhydroxyamino ether) and printed circuit boards comprising the same.
    Type: Grant
    Filed: May 12, 2022
    Date of Patent: November 21, 2023
    Assignee: Thintronics, Inc.
    Inventors: Tarun Amla, Stefan J. Pastine
  • Patent number: 11434581
    Abstract: A method and system for substantially reducing iron and organic impurities in carbon nanotube materials.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: September 6, 2022
    Assignee: Nanocomp Technologies, Inc.
    Inventors: Mark W. Schauer, Erick C. Towle, Rachel Stephenson
  • Patent number: 11359062
    Abstract: Provided herein is a polymer composition comprising a polyhydroxyamino ether (e.g., a crosslinked polyhydroxyamino ether) and printed circuit boards comprising the same.
    Type: Grant
    Filed: January 20, 2021
    Date of Patent: June 14, 2022
    Assignee: Thintronics, Inc.
    Inventors: Tarun Amla, Stefan J. Pastine
  • Patent number: 9605110
    Abstract: The epoxy resin curing agent of the present invention comprises a compound represented by the following formula (1): wherein R represents a methyl group, an ethyl group, or a hydroxyl group, and n is an integer of 1 to 3.
    Type: Grant
    Filed: October 21, 2013
    Date of Patent: March 28, 2017
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Shuichi Ueno, Dai Oguro
  • Patent number: 9169356
    Abstract: Provided is a cyanate ester polymer having excellent flame retardance, low dielectric constant, low dielectric loss tangent and high heat resistance. Specifically provided is a cyanate ester polymer obtained by polymerizing a cyanate ester compound represented by the following general formula (1). (1) In the formula, X represents OCN or OH, and 10-100% by mol of X is composed of OCN.
    Type: Grant
    Filed: September 26, 2006
    Date of Patent: October 27, 2015
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Yuuichi Sugano, Masayuki Katagiri, Daisuke Ohno, Tomoaki Kubota, Yoshikazu Shima
  • Patent number: 8853302
    Abstract: The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.
    Type: Grant
    Filed: May 14, 2010
    Date of Patent: October 7, 2014
    Assignee: Huntsman Advanced Materials Americas LLC
    Inventors: Roger Tietze, Yen-Loan Nguyen, Mark Bryant
  • Patent number: 8791211
    Abstract: High refractive polymers, optical elements, and optical elements employing the same are provided. The polymer includes a repeat unit represented by Formula (I): wherein: R1 is independently an H, C1-8 alkyl group, C1-8 alkoxy group, or halides; R2 is independently an C1-8 alkyl group, C1-8 alkoxy group, or C1-8 alkanol group; n is 0, or 1; Y is R3 and R4 are each independently an H, C1-8 alkyl group, C1-8 alkoxy group, cycloalkyl group, aryl group, heteroaryl group, or heterocycloalkyl group, and two adjacent R3 groups are optionally combined with the carbon atoms which they are attached thereto, to form a cycloalkyl group, aryl group, heteroaryl group, or heterocycloalkyl group; and Z is independently a residual group of polycaprolactone diol, or a residual group of polyethylene glycol.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: July 29, 2014
    Assignee: Industrial Technology Research Institute
    Inventors: Ming-Jyh Chang, Zhi-Long Chen
  • Patent number: 8652757
    Abstract: A method for forming a resist underlayer film of a multilayer resist film having at least three layers used in a lithography, includes a step of coating a composition for resist underlayer film containing a novolak resin represented by the following general formula (1) obtained by treating a compound having a bisnaphthol group on a substrate; and a step of curing the coated composition for the resist underlayer film by a heat treatment at a temperature above 300° C. and 600° C. or lower for 10 to 600 seconds. A method for forming a resist underlayer film, and a patterning process using the method to form a resist underlayer film in a multilayer resist film having at least three layers used in a lithography, gives a resist underlayer film having a lowered reflectance, a high etching resistance, and a high heat and solvent resistances, especially without wiggling during substrate etching.
    Type: Grant
    Filed: February 11, 2013
    Date of Patent: February 18, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Jun Hatakeyama, Toshihiko Fujii, Tsutomu Ogihara
  • Patent number: 8546510
    Abstract: Provided are a crystalline resin cured product which shows high thermal conductivity, low thermal expansion, high heat resistance, low moisture absorption, and good gas barrier properties and a crystalline resin composite material produced therefrom. Further provided is a method for producing the crystalline resin cured product and the crystalline resin composite material. The crystalline resin cured product is obtained by the reaction of an aromatic diglycidyl compound or a diglycidyl resin with an aromatic dihydroxy compound or with a dihydroxy resin and it shows a heat of melting of 10 J/g or more in differential thermal analysis while the endothermic peak corresponding to the melting appears in the range of 120 to 320° C. The crystalline resin composite material is obtained by combining the crystalline resin cured product with a filler or a base material. The crystalline resin cured product has a unit represented by -A-O—CH2—CH(OH)—CH2—O—B—, wherein A and B are divalent aromatic groups.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: October 1, 2013
    Assignee: Nippon Steel & Sumikin Chemical Co., Ltd.
    Inventors: Masashi Kaji, Koichiro Ogami, Kazuhiko Nakahara, Tomomi Fukunaga
  • Patent number: 8519065
    Abstract: A problem to be solved by the invention is to provide a novel epoxy resin exhibiting excellent performance with respect to heat resistance and low thermal expansibility of a cured product, a curable composition using the same, and a cured product having excellent heat resistance and low thermal expansibility. The curable composition contains an epoxy compound and a curing agent as essential components, a calixarene-type novel epoxy compound being used as the epoxy compound. The novel epoxy compound has a resin structure represented by structural formula 1 below (in the formula, R1s each independently represent a hydrogen atom, an alkyl group, or an alkoxy group, and n is a repeat unit and an integer of 2 to 10).
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: August 27, 2013
    Assignee: DIC Corporation
    Inventor: Yutaka Satou
  • Publication number: 20130143162
    Abstract: A pattern is printed by forming a photoresist layer on a wafer, forming a protective film thereon, exposure, and development. The protective film is formed from a protective film-forming composition comprising a novolak resin of a bisphenol compound and a mixture of an alcohol solvent and an ether or aromatic solvent.
    Type: Application
    Filed: December 6, 2012
    Publication date: June 6, 2013
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: SHIN-ETSU CHEMICAL CO., LTD.
  • Publication number: 20130046067
    Abstract: The present disclosure provides for polycyclopentadiene compounds that useful as an epoxide resin and/or as an adduct for a curable composition.
    Type: Application
    Filed: April 21, 2011
    Publication date: February 21, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Robert E. Hefner, JR., Michael J. Mullins
  • Patent number: 8338559
    Abstract: The present invention relates to a fluorene-based resin polymer having a repeating unit of Formula 1 and a method for preparing the same. The fluorene-based resin polymer has a high molecular weight and low acid value, and has an excellent developing property, adhesive property, and stability.
    Type: Grant
    Filed: January 21, 2008
    Date of Patent: December 25, 2012
    Assignee: LG Chem, Ltd.
    Inventors: Yoon-Hee Heo, Kyung-Soo Choi, Han-Soo Kim, Min-Young Lim, Ji-Heum Yoo
  • Patent number: 8263714
    Abstract: An epoxy resin composition including an epoxy resin and a curing agent as essential components, in which the curing agent comprises a phenol resin which has each structural moiety of a phenolic hydroxyl group-containing aromatic hydrocarbon group (P), an alkoxy group-containing aromatic hydrocarbon group (B) and a divalent aralkyl group (X), and also has, in a molecular structure, a structure in which the phenolic hydroxyl group-containing aromatic hydrocarbon group (P) and the alkoxy group-containing aromatic hydrocarbon group (B) are bonded with the other phenolic hydroxyl group-containing aromatic hydrocarbon group (P) or alkoxy group-containing aromatic hydrocarbon group (B) via the divalent aralkyl group (X).
    Type: Grant
    Filed: June 10, 2011
    Date of Patent: September 11, 2012
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ichiro Ogura, Yoshiyuki Takahashi, Kazuo Arita, Kunihiro Morinaga, Yutaka Satou
  • Publication number: 20120197000
    Abstract: High refractive polymers, optical elements, and optical elements employing the same are provided. The polymer includes a repeat unit represented by Formula (I): wherein: R1 is independently an H, C1-8 alkyl group, C1-8 alkoxy group, or halides; R2 is independently an C1-8 alkyl group, C1-8 alkoxy group, or C1-8 alkanol group; n is 0, or 1; Y is R3 and R4 are each independently an H, C1-8 alkyl group, C1-8 alkoxy group, cycloalkyl group, aryl group, heteroaryl group, or heterocycloalkyl group, and two adjacent R3 groups are optionally combined with the carbon atoms which they are attached thereto, to form a cycloalkyl group, aryl group, heteroaryl group, or heterocycloalkyl group; and Z is independently a residual group of polycaprolactone diol, or a residual group of polyethylene glycol.
    Type: Application
    Filed: June 14, 2011
    Publication date: August 2, 2012
    Inventors: Ming-Jyh CHANG, Zhi-Long CHEN
  • Patent number: 8110614
    Abstract: Adamantane derivatives are provided including a phenolic hydroxyl group-containing adamantane derivative, a glycidyloxy group-containing adamantane derivative, and an adamantyl group-containing epoxy modified acrylate, which exhibit excellent transparency, light resistance, and heat resistance properties. Also provided are resin compositions containing the adamantane derivatives. Further provided are corresponding methods for producing the adamantane derivatives, as well as the resin compositions containing the same.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: February 7, 2012
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Katsuki Ito, Yasunari Okada, Hideki Yamane, Akio Kojima
  • Publication number: 20110259628
    Abstract: Provided is a curable resin composition that exhibits good heat resistance and low thermal expansion, and that realizes good solubility in solvents, a cured product thereof, a printed wiring board including the composition, a novel epoxy resin that imparts these properties, and a process for producing the same. A curable resin composition contains, as essential components, an epoxy resin (A) having, in its molecular structure, a glycidyloxy group and a skeleton in which a naphthalene structure and a cyclohexadienone structure are bonded to each other via methylene group(s); and a curing agent (B).
    Type: Application
    Filed: August 7, 2009
    Publication date: October 27, 2011
    Applicant: DIC Corporation
    Inventors: Yutaka Satou, Kazuo Arita, Ichirou Ogura
  • Patent number: 7985822
    Abstract: An epoxy resin composition including an epoxy resin and a curing agent as essential components, in which the curing agent comprises a phenol resin which has each structural moiety of a phenolic hydroxyl group-containing aromatic hydrocarbon group (P), an alkoxy group-containing aromatic hydrocarbon group (B) and a divalent aralkyl group (X), and also has, in a molecular structure, a structure in which the phenolic hydroxyl group-containing aromatic hydrocarbon group (P) and the alkoxy group-containing aromatic hydrocarbon group (B) are bonded with the other phenolic hydroxyl group-containing aromatic hydrocarbon group (P) or alkoxy group-containing aromatic hydrocarbon group (B) via the divalent aralkyl group (X).
    Type: Grant
    Filed: August 31, 2005
    Date of Patent: July 26, 2011
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ichiro Ogura, Yoshiyuki Takahashi, Kazuo Arita, Kunihiro Morinaga, Yutaka Satou
  • Patent number: 7960483
    Abstract: An adamantane derivative of formula (I), a compound of formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X is bonded to a bridge-head adamantane carbon and represents, for example, a group of represented by the general formula (II), Y represents a group of formula (V) or (VI), R1 represents a methyl group or an ethyl group, R2 represents a C1 to C10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16?m) and p and q are each an integer of 1 to 5.
    Type: Grant
    Filed: February 1, 2007
    Date of Patent: June 14, 2011
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hajime Ito, Yasunari Okada, Hideki Yamane, Nobuaki Matsumoto
  • Publication number: 20110001419
    Abstract: To provide an epoxy polymerizable composition which exhibits low curing shrinkage and high workability and which gives a cured article having a high refraction index and high heat resistance. The epoxy polymerizable composition contains (A2) fluorene epoxy compound having the following general formula (1) or (2), (A3) epoxy compound having a softening point of 30° C. or less, and (B1) thiol compound having two or more thiol groups in one molecule.
    Type: Application
    Filed: January 23, 2009
    Publication date: January 6, 2011
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Yasushi Takamatsu, Yugo Yamamoto, Yuichi Ito
  • Patent number: 7834127
    Abstract: Disclosed are amorphous copolyesters having an inherent viscosity (IV) of about 0.5 to 1.1 dL/g measured at a temperature of 25° C. at 0.5 g/dL concentration in a solvent mixture of symmetric tetrachloroethane and phenol having a weight ratio of symmetric tetrachloroethane to phenol of 2:3 comprising (1) a diacid component comprising about 90 to 100 mole percent terephthalic acid residues and 0 to about 10 mole percent isophthalic acid residues; and (2) a diol component comprising about 10 to 70 mole percent 1,4-cyclohexanedimethanol residues and about 90 to 30 mole percent neopentyl glycol residues; wherein the amorphous copolyesters comprises 100 mole percent diacid component and 100 mole percent diol component. The amorphous copolyesters are useful in the manufacture or fabrication of medical devices which have improved resistance to degradation upon exposure to lipids, as a profile produced by profile extrusion and as an injection molded article.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: November 16, 2010
    Assignee: Eastman Chemical Company
    Inventors: Sam Richard Turner, Jonathan Terrill Milburn, Robert William Seymour, Kab Sik Seo
  • Patent number: 7816067
    Abstract: To provide a coating-type underlayer coating forming composition containing a naphthalene resin derivative. A coating-type underlayer coating forming composition for lithography comprising a compound of formula (1): wherein A is an organic group having an aromatic group, R1 is hydroxy group, an alkyl group, an alkoxy group, a halogen group, a thiol group, an amino group or an amide group, m1 is the number of A substituted on the naphthalene ring and is an integer of 1 to 6, m2 is the number of R1 substituted on the naphthalene ring and is an integer of 0 to 5, a sum of m1 and m2 (m1+m2) is an integer of 1 to 6, in cases where the sum is an integer other than 6, the reminder is hydrogen atom, and n is the number of repeating units ranging from 2 to 7000.
    Type: Grant
    Filed: May 24, 2006
    Date of Patent: October 19, 2010
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Tomoyuki Enomoto, Takahiro Kishioka, Takahiro Sakaguchi
  • Publication number: 20100015551
    Abstract: An novel epoxy compound is represented by the general formula (I) and has a benzo- or naphtho-cycloalkane skeleton: X, Y, and Z each independently represent an alkyl group having 1-10 carbon atoms and optionally substituted with a halogen atom, an aryl group having 6-20 carbon atoms and optionally substituted with a halogen atom, an arylalkyl group having 7-20 carbon atoms and optionally substituted with a halogen atom, a heterocyclic group having 2-20 carbon atoms and optionally substituted with a halogen atom, or a halogen atom; k represents a number of 0-4; p represents a number of 0-8; r represents a number of 0-4; n represents 0-10; x represents a number of 0-4; y represents a number of 0-4; a sum of x and y is 2-4; and an optical isomer that exists when n is not 0 may be of any type.
    Type: Application
    Filed: April 28, 2008
    Publication date: January 21, 2010
    Applicant: ADEKA CORPORATION
    Inventors: Taiki Mihara, Kiyoshi Murata, Koichi Kimijima
  • Publication number: 20100016473
    Abstract: Provided are a crystalline resin cured product which shows high thermal conductivity, low thermal expansion, high heat resistance, low moisture absorption, and good gas barrier properties and a crystalline resin composite material produced therefrom. Further provided is a method for producing the crystalline resin cured product and the crystalline resin composite material. The crystalline resin cured product is obtained by the reaction of an aromatic diglycidyl compound or a diglycidyl resin with an aromatic dihydroxy compound or with a dihydroxy resin and it shows a heat of melting of 10 J/g or more in differential thermal analysis while the endothermic peak corresponding to the melting appears in the range of 120 to 320° C. The crystalline resin composite material is obtained by combining the crystalline resin cured product with a filler or a base material. The crystalline resin cured product has a unit represented by -A-O—CH2—CH(OH)—CH2—O—B—, wherein A and B are divalent aromatic groups.
    Type: Application
    Filed: November 8, 2007
    Publication date: January 21, 2010
    Applicant: NIPPON STEEL CHEMICAL CO., LTD
    Inventors: Masashi Kaji, Koichiro Ogami, Kazuhiko Nakahara, Tomomi Fukunaga
  • Patent number: 7632626
    Abstract: There is provided an anti-reflective coating forming composition for lithography comprising a polymer having an ethylenedicarbonyl structure and a solvent; an anti-reflective coating formed from the composition; and a method for forming photoresist pattern by use of the composition. The anti-reflective coating obtained from the composition can be used in lithography process for manufacturing a semiconductor device, has a high preventive effect for reflected light, causes no intermixing with photoresists, and has a higher etching rate than photoresists.
    Type: Grant
    Filed: April 13, 2006
    Date of Patent: December 15, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventor: Rikimaru Sakamoto
  • Publication number: 20090200071
    Abstract: To provide a resin composition which is advantageous not only in that the resin composition can be produced at low cost, but also in that it is unlikely to thermally expand, a prepreg, a laminate, and a wiring board. A resin composition for use in production of a laminate, the resin composition comprising an insulating resin having an aromatic ring, wherein the insulating resin having an aromatic ring has a molecular weight between crosslinking sites of 300 to 1,000 on the stage after the production of the laminate, as determined from an elastic shear modulus of the insulating resin measured at a temperature of Tg or higher.
    Type: Application
    Filed: April 26, 2007
    Publication date: August 13, 2009
    Applicant: HITACHI CHEMICAL CO., LTD.
    Inventors: Koji Morita, Shin Takanezawa, Kazunaga Sakai, Yuusuke Kondou
  • Patent number: 7307128
    Abstract: The present invention relates to an epoxy compound, represented by a general formula (I), which is solid at ordinary temperature, has extremely low melt viscosity and has excellent curing property and which can provide a cured product which is excellent in mechanical strength, heat resistance, and moisture resistance. It also relates to a preparation method of the epoxy compound, an epoxy resin composition, and a cured product thereof. The epoxy compound is represented by the following general formula (I): (wherein R1-R10 each represent hydrogen atom or alkyl group having 1-6 carbon atoms, and n represents an integer of 0 or more).
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: December 11, 2007
    Assignee: Japan Epoxy Resins Co., Ltd.
    Inventors: Atsuhito Hayakawa, Akihiro Itou
  • Patent number: 7304120
    Abstract: An epoxy compound, represented by a general formula (I) is obtained by reacting an anthrahydroquinone compound having a following general formula (II) with epihalohydrin. (wherein R1-R10 each represent hydrogen atom or alkyl group having 1-6 carbon atoms, and n represents an integer of 0 or more, and wherein A1, A2 each represent hydrogen atom or alkali metal atom, R1-R10 each represent hydrogen atom or alkyl group having 1-6 carbon atoms.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: December 4, 2007
    Assignee: Japan Epoxy Resins Co., Ltd.
    Inventors: Atsuhito Hayakawa, Akihiro Itou
  • Patent number: 7150902
    Abstract: Articles are coated by applying a coating composition of a high Tg phenoxy-type material having a Tg of at least about 75° C. to at least a portion of a surface of an article, and forming a dried/cured coating of the high Tg phenoxy-type material on the article surface, where the coating has the high Tg phenoxy-type material and a PHAE; or the article surface comprises a coating includes a PHAE; or the coating has the high Tg phenoxy-type material and a PHAE, and the article surface includes a coating layer of a PHAE.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: December 19, 2006
    Assignee: Pepsico, Inc.
    Inventor: Said Farha
  • Patent number: 7108807
    Abstract: Poly-o-hydroxyamides include binaphthyl substituents as repeating units. The poly-o-hydroxyamides can be cyclized to give the polybenzoxazole by heating. Pore formation occurs, so that a dielectric having a very low dielectric constant k of less than 2.5 is obtained.
    Type: Grant
    Filed: April 28, 2003
    Date of Patent: September 19, 2006
    Assignee: Infineon Technologies AG
    Inventors: Recai Sezi, Andreas Walter, Klaus Lowack, Anna Maltenberger, Robert Banfic
  • Patent number: 7087702
    Abstract: In the technical field where a difunctional epoxy resin having increased molecular weight is used to impart flexibility or improving dielectric properties, the present invention has remarkably improved moisture resistance and water resistance when used to produce a cured epoxy resin article. The epoxy resin composition comprises a difunctional epoxy resin (A) having a structure wherein an aromatic hydrocarbon group (a1) having a bonding site in an aromatic nucleus and a hydrocarbon group (a2) having an ether bond or the other hydrocarbon group (a3) are bonded via an acetal bond (a4), and also has a structure wherein a glycidyloxy group is bonded to the aromatic hydrocarbon group (a1); and a curing agent (B) as essential component.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: August 8, 2006
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ichiro Ogura, Nobuya Nakamura, Tomoyuki Imada
  • Patent number: 6794478
    Abstract: A process for preparing an epoxy resin involves the reaction of a polyhydric phenol with an epihalohydrin in a water-soluble solvent in the presence of an alkali reactive catalyst wherein a continuous distillation of the reaction product is conducted to (1) isolate a first recovered fraction containing unreacted epihalohydnn, water-soluble solvent and at most 0.01 part by weight of the by-product glycidol per one part by weight of unreacted epihalohydrin; (2) isolate a second recovered fraction containing unreacted epihalohydrin, the by-product glycidol and at most 0.01 part by weight of water-soluble organic solvent per one part by weight of unreacted epihalohydrin; (3) recover the epihalohydrin from the second recovered fraction by washing with water to remove the water-soluble organic solvent and glycidol; and (4) reuse the first recovered fraction and the recovered epihalohydrin from the second recovered fraction as a raw material of the reaction.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: September 21, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ichiro Ogura, Kazuo Arita
  • Patent number: 6713589
    Abstract: This invention provides a compound suitable as an encapsulating material for electronic devices and having a high Tg, low moisture-absorption, high adhesion and fluidity which is a cyclopentylene compound represented by Formula (I) and its intermediate cyclopentenyl compound represented by Formula (III). In the formula, m is 0 or more, Ar1 and Ar2 are each a phenol residual group, a naphthol residual group or a fluorene derivative residual group, and each contain a hydroxyl group or a glycidyloxyl group.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: March 30, 2004
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Haruaki Sue, Shinsuke Hagiwara, Fumio Furusawa, Seiichi Akagi, Akihiro Kobayashi, Hideki Yokoyama
  • Publication number: 20040054120
    Abstract: Compounds of formula (I) or (II), wherein R1 is C1-C18alkyl; C5-C12cycloalkyl that is unsubstituted or substituted by one or more C1-C6alkyl groups or C1-C22alkoxy groups; C5-C22aryl that is unsubstituted or substituted by one or more C1-C6alkyl groups or C1-C6alkoxy groups; or C7-C30aralkyl that is unsubstituted or substituted by one or more C1-C6alkyl groups or C1-C6alkoxy groups, and the radicals R2 to R13 are each independently of the others hydrogen; —NO2; dialkylamino; alkylthio; alkylsulfonyl; halogen; C1-C18alkyl; C1-C18alkoxy; C1-C18alkoxyalkyl; C5-C12cycloalkyl that is unsubstituted or substituted by one or more C1-C6alkyl groups or C1-C6alkoxy groups; C5-C22aryl that is unsubstituted or substituted by one or more C1-C6alkyl groups or C1-C6alkoxy groups; or C7-C10alkyl that is unsubstituted or substituted by one or more C1-C6alkyl groups or C1-C6alkoxy groups, are suitable as flame-proofing agents for thermoplastic or thermosetting polymers.
    Type: Application
    Filed: July 21, 2003
    Publication date: March 18, 2004
    Inventors: Franck Magendie, Ulrich Weidmann
  • Patent number: 6624213
    Abstract: The invention provides polyepoxide-based adhesives containing cycloaliphatic-containing polyepoxide resin, aromatic polyepoxide resin, and 9,9-bis(3-methyl-4-aminophenyl)fluorene. The adhesives provide improved peel and shear strength.
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: September 23, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Clayton A. George, William J. Schultz, Wendy L. Thompson
  • Patent number: 6593398
    Abstract: An ink composition comprised of (1) a polymer; (2) an acid compound of the formula CH3(CH2)m(CH2CH═CH)p(CH2)nCOOH wherein n, m, and p represent the number of segments; (3) a conductive component; (4) a lightfastness component; and (5) a colorant.
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: July 15, 2003
    Assignee: Xerox Corporation
    Inventors: Marcel P. Breton, Shadi L. Malhotra, Gregory J. Kovacs
  • Patent number: 6569983
    Abstract: A water-soluble branched polyhydroxyetheramine, wherein the branched polyhydroxyetheramine is prepared by reacting an amine having two reactive hydrogen atoms with a diepoxide to form a polyhydroxyetheramine and then reacting the polyhydroxyetheramine with an N-alkylating agent, an aqueous composition comprising the branched polyhydroxyetheramine and use of the branched polyhydroxyetheramine to modify the permeability to water of a subterranean formation are disclosed.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: May 27, 2003
    Assignee: Ondeo Nalco Energy Services, L.P.
    Inventors: Duane Treybig, Kin-Tai Chang, Dennis Williams
  • Patent number: 6458993
    Abstract: The present invention relates to novel aromatic cyanate ester compounds containing at least two rings linked by a group containing an unsaturated group. The present invention further relates to compositions and prepolymers of said novel aromatic cyanate ester compounds. The present invention further relates to a process for preparing said compounds and cured articles resulting from curable mixtures thereof.
    Type: Grant
    Filed: January 31, 2001
    Date of Patent: October 1, 2002
    Assignee: Vantico Inc.
    Inventors: Bor-Sheng Lin, Michael James Amone
  • Patent number: 6455116
    Abstract: A composition comprising a poly(hydroxy aminoether) and an effective amount of a propoxylated or ethoxylated phenol, process for preparing the same and articles prepared from the composition.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: September 24, 2002
    Assignee: Dow Global Technologies Inc.
    Inventors: Guang-Ming Xia, John M. Beckerdite, Wendy D. Hoenig
  • Patent number: 6407225
    Abstract: Compositions comprising a polysaccharide and a hydroxy-functional polyester are prepared by mixing the hydroxy-functional polyester and polysaccharide, modified polysaccharide or a naturally-occurring fiber or particulate filler and, optionally, other additives in a intensive mixer at a temperature and for a time sufficient to provide an intimate, well-dispersed mixture of the components.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: June 18, 2002
    Assignee: The Dow Chemical Company
    Inventors: Michael N. Mang, Jerry E. White
  • Patent number: 6399740
    Abstract: Phenol aralkyistion polymers can be prepared by reaction among a phenolic monomer, at least one styrenic monomer and an aryl diolefin. A phenolic monomer can be initially aralkylated in the presence of an acid catalyst with a first portion of at least one styrenic monomer to obtain an aralkylated phenol. The aralkylated phenol thereafter can be reacted with an aryl diolefin to obtain a phenol aralkylation polymer. Optionally, (though preferably) the phenol aralkylation polymer is further aralkylated with a second portion of at least one styrenic monomer. By employing specific catalyst concentrations, reactant concentrations, reaction temperatures, and reaction times, the formation of mono-functional and non-functional by-products is substantially reduced.
    Type: Grant
    Filed: July 6, 1999
    Date of Patent: June 4, 2002
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Edward Lucas, Jr., David A. Hutchings, Rajan Hariharan, Syed A. Elahi, David J. Bir
  • Publication number: 20020065386
    Abstract: This invention provides, as a novel compound suited as an encapsulating material for electronic devices, having a high Tg, being low moisture-absorptive, having a high adhesion and being rich in fluidity, a cyclopentylene compound represented by Formula (I) and its intermediate cyclopentenyl compound represented by Formula (III). In the formula, m is 0 or more, Ar1 and Ar2 are each a phenol residual group, a naphthol residual group or a fluorene derivative residual group, and each contain a hydroxyl group or a glycidyloxyl group.
    Type: Application
    Filed: November 9, 2001
    Publication date: May 30, 2002
    Applicant: Hitachi Chemical Company, Ltd.
    Inventors: Haruaki Sue, Shinsuke Hagiwara, Fumio Furusawa, Seiichi Akagi, Akihiro Kobayashi, Hideki Yokoyama
  • Publication number: 20020013445
    Abstract: An aromatic-aliphatic copolycarbonate and a process for producing the same which comprises polycondensation of an aromatic dihydroxy compound, such as 1,1-bis(4-hydroxyphenyl)cyclohexane, tricyclo(5.2.1.02,6)decanedimethanol, and a carbonic acid diester in a molten state under heating, wherein the carbonic acid diester has a chlorine content of 20 ppm or lower. The copolycarbonate has improved refractive index, balance of dispersion, and photoelastic constant while retaining high impact resistance, high heat resistance, and excellent hue.
    Type: Application
    Filed: June 9, 1999
    Publication date: January 31, 2002
    Inventors: SATOSHI NAGAI, OSAMU KONDO, KYOHEI TAKAKUWA, TAKAYASU FUJIMORI, YOSHINORI ISAHAYA
  • Publication number: 20010053842
    Abstract: The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C5-20 ring structure formed with the 9-carbon on the fluorene ring or a C4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7′-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7′-positions.
    Type: Application
    Filed: January 5, 2001
    Publication date: December 20, 2001
    Inventors: Edmund P. Woo, William R. Shiang, Michael Inbasekaran, Gordon R. Roof
  • Patent number: 6329492
    Abstract: This invention provides a compound suitable as an encapsulating material for electronic devices and having a high Tg, low moisture-absorptive, high adhesion and rich fluidity, which is a cyclopentylene compound represented by Formula (I) and its intermediate cyclopentenyl compound represented by Formula (III). In the formula, m is 0 or more, Ar1 and Ar2 are each a phenol residual group, a naphthol residual group or a fluorene derivative residual group, and each contain a hydroxyl group or a glycidyloxyl group.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: December 11, 2001
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Haruaki Sue, Shinsuke Hagiwara, Fumio Furusawa, Seiichi Akagi, Akihiro Kobayashi, Hideki Yokoyama
  • Patent number: 6287656
    Abstract: Amorphous copolyesters containing residues derived from 2,2′-[2,2-](sulfonylbis(4,1-phenyleneoxy))bis(ethanol). They exhibit enhanced heat distortion temperatures and glass transition temperatures without a significant increase in viscosity at low shear rates. The amorphous copolyesters also have improved resistance to attack by lipid solutions and are readily molded and extruded to form medial devices such as connectors, tubes, etc. which are useful for transport of lipids and other medical solutions.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: September 11, 2001
    Assignee: Eastman Chemical Corporation
    Inventors: S. Richard Turner, Gary W. Connell, Bobby J. Sublett
  • Patent number: 6197916
    Abstract: A method for preparing bisphenol A is disclosed, with a selectivity for the p,p′-isomer of greater than about 97%. The method involves reacting phenol with p-isopropenylphenol or 2-(4-hydroxyphenyl)-2-propanol in the presence of a catalyst, at a reaction temperature of no greater than about 65° C. The bisphenol A product is preferably purified by a technique which omits the use of adduct crystallization.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: March 6, 2001
    Assignee: General Electric Company
    Inventors: Eric James Pressman, Joseph Richard Wetzel
  • Patent number: 6169158
    Abstract: The present invention is directed to a polyglycidyl compound having on average more than two, preferably more than two and a half, particularly preferably more than three, glycidyl groups per molecule and a Tg value (determined by DSC, heating rate=20° C./min) higher than 20° C.
    Type: Grant
    Filed: April 23, 1999
    Date of Patent: January 2, 2001
    Assignee: Vantico, Inc.
    Inventors: Christoph Rickert, Hugh Stephen Laver
  • Patent number: 6120889
    Abstract: The invention relates to an amorphous copolyester having a maximum melt viscosity at 1 radian/second and at about 260 to about 290.degree. C. of about 12000 poise, a glass transition temperature ranging from about 88.degree. C. to about 120.degree. C., and an inherent viscosity of at least about 0.6 dl/g. The amorphous copolyesters comprise the reaction product of a diol component and a dicarboxylic acid component. The diol component comprises residues of from about 5.0 to about 50 mole % of 2,2'-(sulfonylbis(4,1 -phenyleneoxy))-bis(ethanol) which has the following chemical formula: ##STR1## and from about 50 to about 95 mole % of a mixture of at least two diols selected from the group consisting of ethylene glycol, neopentyl glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, and mixture thereof. The dicarboxylic acid component comprises residues of terephthalic acid, isophthalic acid, 1,4-cyclohexandedicarboxylic acid, 2,6-naphthalene dicarboxylic acid and mixtures thereof.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: September 19, 2000
    Assignee: Eastman Chemical Company
    Inventors: S. Richard Turner, Bobby J. Sublett
  • Patent number: 6090870
    Abstract: The present invention provides an epoxy resin composition, comprising:(A) a phenol epoxy resin represented by the following formula (I) ##STR1## wherein each R.sup.1 is the same or different and is independently selected from the group consisting of hydrogen, C.sub.1 to C.sub.6 hydrocarbyl groups, C.sub.6 to C.sub.10 aromatic groups, and C.sub.1 to C.sub.6 hydrocarbyl-substituted C.sub.6 to C.sub.10 aromatic groups,each R.sup.2 is the same or different and is independently selected from the group consisting of hydrogen, C.sub.1 to C.sub.6 hydrocarbyl groups, C.sub.6 to C.sub.10 aromatic groups, and C.sub.1 to C.sub.6 hydrocarbyl-substituted C.sub.6 to C.sub.10 aromatic groups, ##STR2## wherein R.sup.3 is selected from the group consisting of hydrogen, C.sub.1 to C.sub.6 hydrocarbyl groups, C.sub.6 to C.sub.10 aromatic groups, and C.sub.1 to C.sub.6 hydrocarbyl-substituted C.sub.6 to C.sub.10 aromatic groups, each R.sup.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: July 18, 2000
    Assignee: Industrial Technology Research Institute
    Inventors: Hsiu-Rong Chang, Yeong-Tsyr Hwang, Meng-Song Yin, Kung-Lung Cheng