The Hetero Ring And Benzene Ring, To Which An Azo Group Is Bonded Directly, Bonded Directly To The Same Nitrogen Patents (Class 534/638)
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Patent number: 4757137Abstract: Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes acyl,R.sub.2 denotes hydrogen, fluorine, chlorine or trifluoromethyl,R.sub.3 denotes hydrogen, optionally substituted C.sub.1 -C.sub.4 -alkyl, cyclohexyl or optionally substituted phenyl andR.sub.4 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl groupare suitable for dyeing natural and synthetic fibre materials, for example for dyeing wool or polyamide fibres, in level read to violet shades with very good fastnesses to light, wet processing and perspiration, the color yield being good.Type: GrantFiled: September 22, 1983Date of Patent: July 12, 1988Assignee: Bayer AktiengesellschaftInventors: Gerhard Wolfrum, Erich Klauke, Hans-Gunter Otten
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Patent number: 4754023Abstract: A reactive dye of the formula ##STR1## in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO.sub.3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxazine dyes and nitroaryl dyes,R is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted with --COOH or --SO.sub.3 H, cyanoethyl, or hydroxyethyl,X is fluorine, chlorine, bromine, --SO.sub.3 H, phenylsulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,p is 1 or 2 andA is a radical of the formula ##STR2## in which: Y is chlorine, bromine, fluorine, --OH, --OSO.sub.3 H, --O-acyl, --CN, --COOH, --COO--C.sub.1 -C.sub.4 -alkyl, --CONH.sub.2 or --SO.sub.2 --Z,the group designated "alk" is a straight or branched polymethylene radical having 2 to 6 carbon atoms,V is ##STR3## hydrogen or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.2 -alkoxy, carboxyl, sulfo, halogen or hydroxy,Z is .beta.Type: GrantFiled: January 23, 1986Date of Patent: June 28, 1988Assignee: Ciba-Geigy CorporationInventors: Athanassios Tzikas, Herbert Seiler, Peter Scheibli
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Patent number: 4754020Abstract: A new method of diazotization consists in using as the diazotizing agent in an aqueous, aqueous organic or organic medium the system comprising salt of nitrous acid+acid insoluble in the reaction medium, in particular organic or inorganic cation exchangers having acid groups. The diazonium salt solutions thus prepared are immediately reacted with coupling components to give azo dyestuffs, the insoluble acid and/or its salt being separated off before or after the coupling.Type: GrantFiled: March 7, 1986Date of Patent: June 28, 1988Assignee: Bayer AktiengesellschaftInventors: Joachim Wolff, Karlheinz Wolf, Reinhold M. Klipper, Peter M. Lange
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Patent number: 4748236Abstract: Reactive azo dyestuffs of the formula ##STR1## wherein D . . . radical of the benzene or naphthalene series, having a sulpho group in the o-position to the azo bridge,K . . . radical of a coupling component of the benzene, naphthalene, pyridone, pyrazolone or hydroxynaphthalene series, or an aryl-azo-aryl radical,R . . . hydrogen or C.sub.1 -C.sub.4 -alkyl,Y . . . OR.sub.1 or SR.sub.1, R.sub.1 representing an optionally substituted alkyl, aryl or heteroaryl radical, or NR.sub.2 R.sub.3, R.sub.2 representing hydrogen or an optionally substituted alkyl radical and R.sub.3 representing hydrogen or an optionally substituted alkyl or aryl radical, or R.sub.2 and R.sub.3 forming a ring, optionally with inclusion of a hetero-atom, andX . . . halogen, such as chlorine or fluorine and their use for dyeing and printing materials containing hydroxyl groups or containing amide groups.Type: GrantFiled: November 9, 1984Date of Patent: May 31, 1988Assignee: Bayer AktiengesellschaftInventors: Horst Jager, Richard Schwaebel
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Patent number: 4746732Abstract: Reactive dyes of the formula ##STR1## in which D is the radical of a dye of the polyazo or metal complex azo series, R.sub.1 is hydrogen or an unsubstituted or substituted C.sub.1-4 -alkyl radical, and X is the vinyl, .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-chloroethyl or .beta.-acetoxyethyl group, are suitable in particular for dyeing and printing cellulose-containing fibre materials by the cold pad-batch method and produce, in high dyeing yields, dyeings and prints having good fastness properties.Type: GrantFiled: July 30, 1984Date of Patent: May 24, 1988Assignee: Ciba-Geigy CorporationInventor: Athanassios Tzikas
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Patent number: 4746733Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H;R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H; orR.sup.1 & R.sup.2 together with the nitrogen atom form a morpholine ring;a & b are different and from 1 to 8;m is from 1 to 10;n is from 0 to 9;Y is a triphendioxazinylene (TPD) group;M is H, ammonium, or a metal;X is NR.sup.1 R.sup.2, alkoxy, NR.sup.3 R.sup.4 in which R.sup.3 and R.sup.4 are each independently selected from H, alkyl, aryl and heteroaryl, or the residue of a mono- or dis-azo chromophore comprising benzene, naphthalene or mono- or bi-cyclic heteroaryl diazo and coupling components, linked to the triazine nucleus through a primary or secondary amine linking group;andZ is an alkylene, arylene or aralkylene group,suitable for the preparation of a printing ink, especially for ink jet printing.Type: GrantFiled: August 12, 1985Date of Patent: May 24, 1988Assignee: Imperial Chemical Industries PLCInventors: Anthony G. W. Baxter, Stephen B. Bostock, David Greenwood
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Patent number: 4740597Abstract: The reaction of cyanuric fluoride with amines to form monocondensation products is possible in high yields by subjecting the educts to rapid thorough mixing and then bringing the reaction to completion under plug flow conditions.Type: GrantFiled: August 21, 1985Date of Patent: April 26, 1988Assignee: Ciba-Geigy CorporationInventors: Karlheinz Franke, Edmond Ruhlmann
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Patent number: 4740592Abstract: Water soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.Type: GrantFiled: September 30, 1986Date of Patent: April 26, 1988Assignee: Hoechst AktiengesellschaftInventors: Hartmut Springer, Michael Kunze, Marcos Segal, Werner H. Russ
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Patent number: 4731441Abstract: Water-soluble monoazo and disazo compounds having fiber-reactive dye properties which are suitable for dyeing carbamoyl- and hydroxyl-containing materials, in particular cellulose fiber materials, and containing as diazo components an optionally substituted phenyl radical or naphthyl radical or a phenylazophenyl, phenylazonaphthyl, naphthylazophenyl or naphthylazonaphthyl radical, one of these radicals containing bonded in the diazo component a vinylsulfonyl, .beta.-thiosulfatoethylsulfonyl, .beta.-phosphatoethylsulfonyl, .beta.-chloroethylsulfonyl or .beta.-sulfatoethylsulfonyl group, and as coupling component that of a naphthol, aminonaphthaline or aminobenzene having a fiber-reactive grouping of the general formula ##STR1## in which the two R.sup.1 s, identical to or different from each other, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents the vinyl group, a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.Type: GrantFiled: March 19, 1986Date of Patent: March 15, 1988Assignee: Hoechst AktiengesellschaftInventors: Marcos Segal, Michael Kunze
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Patent number: 4730038Abstract: Water-soluble disazo compounds having fiber-reactive dyestuff properties of the general formula (1) ##STR1## in which D.sub.1 and D.sub.2 are identical or different and each represents a phenyl radical or a naphthyl radical, both of which are substituted by a group of the formula moiety Y or formula moiety Z defined below and can additionally be substituted by one or two substituents from the group comprising sulfo, chlorine, bromine, lower alkyl and lower alkoxy, Z is a group of the formula (2a), (2b), (2c), (2d), (2e) or (2f) ##STR2## in which R denotes an alkyl group having 1 to 4 C atoms and X denotes a chlorine atom, the acetoxy group, the thiosulfate group, the phosphate group or the sulfato group; Y is a radical of the formula (3) ##STR3## in which R.sup.1 and R.sup.Type: GrantFiled: December 16, 1985Date of Patent: March 8, 1988Assignee: Hoechst AktiengesellschaftInventors: Fritz Meininger, Ernst Hoyer, Rudolf Fass
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Patent number: 4725674Abstract: Water-soluble monoazo and disazo compounds which have fiber-reactive dyestuff properties and containing as diazo component an optionally substituted phenyl radical or naphthyl radical or an optionally substituted phenylazophenyl, phenylazonaphthyl, naphthylazophenyl or naphthylazonaphthyl radical, and as coupling component that of a naphthol, aminonaphthaline or aminobenzene and as fiber-reactive group a group of the formula ##STR1## in which both R.sup.1 s, identical to or different from one another, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents a vinyl group or a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl or .beta.-sulfatoethyl group, this fiber-reactive grouping being bonded to the radical of the coupling component.Type: GrantFiled: March 19, 1986Date of Patent: February 16, 1988Assignee: Hoechst AktiengesellschaftInventors: Marcos Segal, Michael Kunze
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Patent number: 4725675Abstract: Water-soluble azo compounds of the formula (1) ##STR1## in which R is hydrogen or alkyl of 1 to 4 carbon atoms, X is alkyl of 1 to 6 carbon atoms substituted by carboxy or sulfo, or is phenyl substituted by 1 or 2 sulfo or carboxy or both, and Z is vinyl, .beta.-thiosulfatoethyl or .beta.-sulfatoethyl and M is hydrogen or the equivalent of a metal, and in which the second sulfo group in the naphthalene is bonded in the m-position or p-position relative to the acylated amino group. The new azo compounds are very valuable dyestuffs having fiber-reactive properties, and give color-fast and deep dyeings and prints on fiber materials made of cellulose or synthetic or natural polyamide fibers.Type: GrantFiled: December 5, 1983Date of Patent: February 16, 1988Assignee: Hoechst AktiengesellschaftInventors: Fritz Meininger, Joachim Otten
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Patent number: 4713082Abstract: A process for dyeing or printing textile fibre materials with reactive dyes, which comprises using reactive dyes which contain at least one radical of the formula--SO.sub.2 --CH.dbd.CH.sub.2 (1a)or--SO.sub.2 --CH.sub.2 CH.sub.2 --X (1b)and at least one radical of the formula ##STR1## in which X is an inorganic or organic radical detachable under alkaline conditions, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, Y is oxygen or sulfur and R.sub.1 is a substituted or unsubstituted aliphatic radical, gives dyeings or prints having good fastness properties.Type: GrantFiled: August 20, 1986Date of Patent: December 15, 1987Assignee: Ciba-Geigy CorporationInventors: Peter Scheibli, Karl Seitz
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Patent number: 4709018Abstract: Reactive dyes of the formula ##STR1## in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, X is a substituent which is detatchable in the form of an anion, A is arylene or C.sub.2-6 -alkylene, Y is a --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --Z radical, Z is an inorganic or organic radical which is detachable under alkaline conditions, B is hydrogen or the radical of a substituted or unsubstituted hydrocarbon, T is a negative substituent, and n is 1 or 2, are suitable for dyeing or printing cellulose-containing and nitrogen-containing materials and produce, in high colouristic yields, dyeings and prints having good fastness properties.Type: GrantFiled: August 30, 1984Date of Patent: November 24, 1987Assignee: Ciba-Geigy CorporationInventor: Karl Seitz
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Patent number: 4707545Abstract: Lithium salts of anionic dyes are prepared by first converting another salt of this anionic dye in aqueous solution or suspension by means of a compound which releases calcium ions into the water-insoluble or sparingly water-soluble calcium salt of the dye, which is separated from the aqueous medium and is then converted to an aqueous suspension by treatment with lithium sulfate or lithium hydrogensulfate or a mixture thereof in an equivalent amount of each or in an excess of up to 10% into its lithium salt.Type: GrantFiled: November 26, 1985Date of Patent: November 17, 1987Assignee: Hoechst AktiengesellschaftInventors: Fritz Meininger, Ludwig Schlafer
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Patent number: 4703111Abstract: Water-soluble monoazo and disazo compounds having fiber-reactive dye properties which are suitable for dyeing carboxamido and/or hydroxy-containing materials, in particular cellulose fiber materials, and contain as coupling component that of a naphthol, aminonaphthalene or aminobenzene and as diazo component an optionally chlorine-, alkyl-, alkoxy- and/or sulfo-substituted phenyl radical or an optionally substituted phenylazophenyl or phenylazonaphthyl radical having the fiber-reactive group of the general formula ##STR1## in which the two R.sup.1, identical to or different from each other, denote a hydrogen atom or an optionally substituted alkyl group of 1 to 4 carbon atoms, R is a hydrogen atom or a sulfo group and Y represents the vinyl group or a .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl or .beta.-sulfatoethyl group, as substituent, and a further such fiber-reactive grouping can be bonded to the radical of the coupling component.Type: GrantFiled: April 7, 1986Date of Patent: October 27, 1987Inventors: Marcos Segal, Michael Kunze
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Patent number: 4686286Abstract: A disazo reaction dyestuff for cellulose fibers which is of the formula: ##STR1## wherein D is a residue of a monoazo dye, R.sup.1 is hydrogen or lower alkyl, and X is a group: ##STR2## wherein R.sup.2 and R.sup.3 are each hydrogen, methyl, methoxy or --SO.sub.3 M, Y is an aromatic or aliphatic divalent residue and M is hydrogen or an alkali metal.Type: GrantFiled: May 17, 1985Date of Patent: August 11, 1987Assignee: Mitsubishi Chemical Industries LimitedInventors: Toshio Niwa, Yoshiaki Katoh
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Patent number: 4680384Abstract: Dyes of the formula ##STR1## in which D is the radical of an organic dye, R is hydrogen or a low molecular weight alkyl group, X is an unsubstituted or substituted alklyl or alkenyl radical, one Y is halogen and the other Y is a substituent.Type: GrantFiled: July 19, 1984Date of Patent: July 14, 1987Assignee: Ciba-Geigy CorporationInventors: Karl Seitz, Henri Riat, Karl Hoegerle
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Patent number: 4678851Abstract: Metal complex dyes that produce level, fast dyeings on textile materials are provided according to the formula ##STR1## wherein: D is a benzene, naphthalene or heterocyclic radical of a diazo component;Y is nitrogen or --CH;K is the radical of a coupling component if Y is nitrogen, or an o-hydroxyaldehyde radical if Y is --CH:Ka is a cation;Me is chromium or cobalt;Z.sub.1 is --O-- or --COO-- ortho to N.dbd.YZ.sub.2 is --O-- or --NR vicinal to N.dbd.Y, wherein R is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or phenyl;X is a fiber reactive radical bound directly to or through an amino or amino-containing group to the complex;R.sub.1 is a direct bond or substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkenyl, or aryl radical or heterocyclic radical containing 1 to 3 sulfur, oxygen or nitrogen atoms;R.sub.2 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl or aryl;R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.Type: GrantFiled: March 28, 1985Date of Patent: July 7, 1987Assignee: Ciba-Geigy CorporationInventors: Gerhard Back, Hans U. Schutz, Ulrich Schlesinger
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Patent number: 4678852Abstract: The process and the apparatus according to the invention are used to produce a suspension of cyanuric chloride in water, or to react cyanuric chloride with ammonia or with amines. It is possible to produce cyanuric chloride suspensions in water which have a mean particle size of below 20 .mu.m, and a concentration of higher than 20% by weight of cyanuric chloride.Type: GrantFiled: October 30, 1984Date of Patent: July 7, 1987Assignee: Ciba-Geigy AGInventors: Marianne Punzar, Franz Marti, Robert Mercier, Paul Tobler, Rudolf Buttiker
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Patent number: 4677199Abstract: Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen, fluorine, chlorine or bromine, R.sup.2 is hydrogen, fluorine, chlorine, bromine, or nitro, B is aliphatic or a sulfo-substituted phenylene radical, and X is a dye radical, are useful for dyeing hydroxyl-containing textile material, in particular cotton.Type: GrantFiled: September 19, 1985Date of Patent: June 30, 1987Assignee: BASF AktiengesellschaftInventors: Dietmar Augart, Heinz Eilingsfeld, Heinz Krueger, Hartmut Lardon, Ortwin Schaffer, Guenther Seybold
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Patent number: 4667022Abstract: A red reactive dye represented by a free acid of the formula, ##STR1## wherein X is a hydrogen atom, a methyl, methoxy or sulfonic acid group, Y is --CH.dbd.CH.sub.2, --CH.sub.2 CH.sub.2 Y.sub.1 or --CH.sub.2 CH.sub.2 OY.sub.2 (in which Y.sub.1 is a halogen atom, and Y.sub.2 is the residue of polybasic acids), R is a C.sub.1 -C.sub.4 alkyl group, R.sub.1 and R.sub.2 are each a hydrogen atom, a methyl or ethyl group, and the azo group is located on a meta-or para-position of the benzene ring A with respect to the --NR.sub.2 -- group and the sulfonic acid group on the benzene ring A is adjacent to the azo group. This dye is suitable for dyeingcellulose fibers red to afford dyeings superior in fastnesses, acid stability, build-up property, level dyeing property and white dischargeability.Type: GrantFiled: February 13, 1981Date of Patent: May 19, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Toshio Nakamatsu, Yoshikazu Matsuo, Yasuo Tezuka
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Patent number: 4664714Abstract: A pigment composition consisting of 100 parts by weight of a pigment, and from 0.1 to 30 parts by weight of a pigment dispersant of formula ##STR1## in which Q is (a) an anthraquinone dye or pigment radical, (b) an azo dye or pigment radical, (c) a benzimidazolone dye or pigment radical, (d) a phthalocyanine dye or pigment radical, (e) a quinacridone dye or pigment radical, (f) a dioxazine dye or pigment radical, (g) an anthrapyrimidine dye or pigment radical, (h) an anthanthrone dye or pigment radical, (i) an indanthrone dye or pigment radical, (j) a falvanthrone dye or pigment radical, (k) a pyranthrone dye or pigment radical, (l) a perinone dye or pigment radical, (m) a perylene dye or pigment or (n) a thioindigo dye or pigment radical; X is a direct bonds, --CH.sub.2 --; ##STR2## Y.sub.1 is NH or --O--; Z is in which Y.sub.2 is --NH-- or --O--, or --NH--X--Q when n is 1; R.sub.1 and R.sub.Type: GrantFiled: April 10, 1985Date of Patent: May 12, 1987Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Hiromitsu Katsura, Shigeyuki Ehashi, Motohiko Kashioka, Makoto Sakamoto
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Patent number: 4649193Abstract: Water-soluble fibre-reactive dyestuffs containing one or two fibre-reactive groups of the vinylsulfone series and one or two fibre-reactive groups of the fluoro-s-triazinyl-amino series. These dyestuffs can be applied on fibre materials containing hydroxy and/or carbonamide groups by known application and fixation techniques for fibre-reactive dyes to yield deep and fast dyeings on these materials.Type: GrantFiled: August 1, 1983Date of Patent: March 10, 1987Assignee: Hoechst AktiengesellschaftInventors: Fritz Meininger, Joachim W. Otten, deceased, by Ursula Otten, heir, by Anna G. Rudolph nee Otten, heir
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Patent number: 4647286Abstract: Reactive dyes of the formula ##STR1## in which M is twice-coupled 1-amino-8-hydroxynaphthalene-3,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4-sulfonic acid or 2-amino-5-hydroxynaphthalene-7-sulfonic acid, A and B, independently of each other, are each sulfophenylene or sulfonaphthylene which can be further substituted, and X.sub.1 and X.sub.2 are each a 2,4-difluoro-5-chloropyrimid-6-yl radical, subject to the condition that A and B together contain at least 3 sulfo groups, are particularly suitable for dyeing and printing cellulose-containing fibre materials and produce, in high dyeing yield, dyeings and prints having good fastness properties.Type: GrantFiled: August 20, 1985Date of Patent: March 3, 1987Assignee: Ciba-Geigy CorporationInventor: Karl Seitz
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Patent number: 4631065Abstract: The invention relates to reactive dyes of the formula ##STR1## wherein D is the radical of a dye of the monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, each of R.sub.1 and R.sub.2 independently is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.4 alkyl radical, X.sub.1 is an unsubstituted or substituted aminofluoro-s-triazine radical, and X.sub.2 is a heterocyclic reactive radical which is attached direct to the radical D through the --N(R.sub.2) bridge member, excepting an unsubstituted or substituted aminofluoro-s-triazine.These dyes are particularly suitable for dyeing and printing cellulosic fibre material by the cold pad-batch method and give dyeings and prints of good fastness properties and high tinctorial strength.Type: GrantFiled: August 20, 1985Date of Patent: December 23, 1986Assignee: Ciba-Geigy CorporationInventors: Karl Seitz, Peter Scheibli, Herbert Seiler
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Patent number: 4626589Abstract: A compound of the formula, ##STR1## wherein D is an organic dye moiety, R.sub.1 and R.sub.2 are independently hydrogen or a substituted or unsubstituted lower alkyl group, R.sub.3 is hydrogen or a substituted or unsubstituted lower alkyl, phenyl or naphthyl group, X.sub.1 and X.sub.2 are independently hydrogen, halogen or a lower alkyl, cyano, carbamoyl, vinyl, .beta.-hydroxyethyl, .beta.-sulfoethyl, .beta.-sulfatoethyl, carboxyl, carboxylic acid ester or sulfonic acid group, and Z is appended to the above-defined D or R.sub.3 and stands for --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a group capable of being split by the action of an alkali, which is useful for dyeing hydroxyl or amido group-containing fiber materials with excellent build-up properties, thereby giving dyed products having excellent various fastness properties.Type: GrantFiled: February 7, 1985Date of Patent: December 2, 1986Assignee: Sumitomo Chemical Company, LimitedInventors: Takashi Omura, Yutaka Kayane, Mikoto Takahashi, Tetsuya Miyamoto, Akira Takeshita, Naoki Harada, Katsumasa Otake
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Patent number: 4614818Abstract: A process for the preparation of dyes of the formula ##STR1## in which D is a dye radical and R.sub.1 and R.sub.2 independently of one another is hydrogen or C.sub.1-4 -alkyl, which comprises reacting cyanuric fluoride of the formula ##STR2## simultaneously with a dye of the formula ##STR3## and with an ammonium salt of an amine of the formulaH.sub.2 N--R.sub.2 (4)in a neutral to alkaline medium, to give dyes of the formula (1) as single compounds in good yields in one operation. The novel process has the advantage of being able to be carried out as a "one-pot process" in a closed reaction vessel so that the apparatus is simple and immission by cyanuric fluoride is excluded.Type: GrantFiled: January 18, 1983Date of Patent: September 30, 1986Assignee: Ciba Geigy CorporationInventors: Rolf Deitz, Herbert Seiler
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Patent number: 4602084Abstract: Monoazo dyes of the formula ##STR1## in which K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series, and R is a ##STR2## --CO--R.sub.2 or --SO.sub.2 --O--R.sub.2 group in which R.sub.1 is hydrogen or C.sub.1-4 -alkyl and R.sub.2 is a substituted or unsubstituted monosulfo-C.sub.1-12 -alkyl radical, a substituted or unsubstituted monosulfophenyl, disulfophenyl, monosulfonaphthyl or disulfonaphthyl radical, and X and Y, independently of each other, are hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, halogen, C.sub.2-6 -alkanoylamino, C.sub.1-5 -alkylsulfonylamino or a substituted or unsubstituted phenyl or phenoxy radical, produce dyeings on polyamide material which have good light and wet fastness properties.Type: GrantFiled: July 8, 1983Date of Patent: July 22, 1986Assignee: Ciba-Geigy CorporationInventor: Rudolf Hurter
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Patent number: 4563518Abstract: The invention relates to fibre-reactive monoazo dyestuffs of the general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 and n have the meaning given in the text of the application, and also relates to a process for the preparation of these dyestuffs and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as wool and cotton.Type: GrantFiled: October 20, 1980Date of Patent: January 7, 1986Assignee: Bayer AktiengesellschaftInventor: Hermann Henk
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Patent number: 4560747Abstract: A process for producing granulates of water-soluble dyes by means of fluidized bed granulation, wherein there is added a granulating auxiliary having a softening point or softening range between 30.degree. and 150.degree. C. and consisting of(a) at least one compound of the formula IA--(CH.sub.2 CH.sub.2 O).sub.n --H (I)in which A is the group R--O-- or ##STR1## wherein R is an aliphatic or alicyclic hydrocarbon radical having 8 to 22 carbon atoms, R' is an aliphatic hydrocarbon radical having 8 to 22 carbon atoms, and n is 10 to 200, preferably 20 to 150, or(b) a mixture of a compound of the formula II ##STR2## in which m is 50 to 500, and x is 3 to 5, with a compound of the formula IIIR.sub.1 --NH--CO--NH--R.sub.1 (III),in which each R.sub.1 independently of the other is hydrogen or methyl, or(c) a mixture of a compound of the formula I with at least one compound of the formula II or III.Type: GrantFiled: October 20, 1980Date of Patent: December 24, 1985Assignee: Ciba Geigy CorporationInventors: Beat Bruttel, Hansjorg Schneider, Werner H. Dorfel