Two Azo Groups Attached Indirectly To Each Other By Nonionic Bonding Patents (Class 534/756)
  • Patent number: 8927070
    Abstract: A light absorption anisotropic film, having at least one dichroic dye, in which the light absorption anisotropic film shows a diffraction peak derived from a periodic structure in a direction in a plane of the light absorption anisotropic film in X-ray diffraction measurement and the diffraction peak has a half width of 1.0 ? or less.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: January 6, 2015
    Assignee: FUJIFILM Corporation
    Inventors: Nobutaka Iwahashi, Masashi Ogiyama, Shinichi Morishima
  • Publication number: 20130333123
    Abstract: Described are dyes of formula (I) where R1 is hydrogen, alkyl, alkoxy, trifluoromethyl or halogen, M is hydrogen, an alkali metal cation or an optionally substituted ammonium cation, R2 and R3 are each independently hydrogen, alkyl or alkoxy, R4 is alkyl or alkoxy, R5 and R6 are each independently moieties of the formula —(CmH2m)—O—CnH2n+1, m is an integer from 3 to 6, and n is an integer from 0 to 8. These dyes are useful for dyeing and printing materials having polar groups.
    Type: Application
    Filed: December 17, 2011
    Publication date: December 19, 2013
    Applicant: DyStar Colours Distribution GmbH
    Inventors: Aloysius Engel, Michael Joerss, Clemens Grund, Bernd Hostasch, Gunter Görlitz
  • Publication number: 20120202927
    Abstract: A method of preparing a pigment includes the steps of: a) providing a mixture including: a pigment selected from the group of pigments including at least 50 wt % of C.I. Pigment Violet 23, C.I. Pigment Red 146, C.I. Pigment Red 176, C.I. Pigment Red 177, C.I. Pigment Violet 19 and C.I. Pigment Orange 13 based on the total weight of the pigment; alkyl nitrile; and at least one acid selected from the group consisting of sulfuric acid and chlorosulfuric acid, with the acid present in the mixture in amount of more than 2 wt % based on the total weight of the pigment; b) heating the mixture for more than 2 hours to a temperature of at least 70° C.; and c) filtering the mixture and washing the filtrand with a washing liquid containing water until the filtrate has a pH between 4 and 7. Pigments obtainable by the method and non aqueous pigment dispersions are also disclosed.
    Type: Application
    Filed: October 15, 2010
    Publication date: August 9, 2012
    Applicant: AGFA-GEVAERT N.V.
    Inventor: Geert Deroover
  • Publication number: 20120171435
    Abstract: A dye of Formula (1) and salts thereof: A-N?N-(M-N?N)x-E??Formula (1) wherein: A is optionally substituted aryl carrying at least one substituent selected from the group consisting of —SO3H, —CO2H, and —PO3H2; M is optionally substituted arylene; E is optionally substituted heteroaryl; and x is 1 or 2. Also compositions, dye mixtures, printing processes, printed material and ink-jet cartridges.
    Type: Application
    Filed: August 11, 2010
    Publication date: July 5, 2012
    Applicant: Fujifilm Imaging Colorants Limited
    Inventors: Clive Edwin Foster, Zyta Victoria Morgan
  • Patent number: 8143382
    Abstract: The invention provides a specific pyrazole disazo dye which is a yellow dye having excellent solubility in nonpolar solvents, in particular, hydrocarbon solvents, and having a high extinction coefficient. The dye preferably is preferably a pyrazole disazo dye represented by the following general formula (I): (wherein R1 represents a C2-C10 alkyl group; R2 represents a C3-C10 alkyl group; the six-membered ring A represents a phenyl group which may have a substituent; and the six-membered ring B represents a phenylene group which may have a substituent).
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: March 27, 2012
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasushi Shiga, Mio Ishida
  • Publication number: 20110177315
    Abstract: A light absorption anisotropic film, having at least one dichroic dye, in which the light absorption anisotropic film shows a diffraction peak derived from a periodic structure in a direction in a plane of the light absorption anisotropic film in X-ray diffraction measurement and the diffraction peak has a half width of 1.0 ? or less.
    Type: Application
    Filed: September 3, 2009
    Publication date: July 21, 2011
    Applicant: FUJIFILM CORPORATION
    Inventors: Nobutaka Iwahashi, Masashi Ogiyama, Shinichi Morishima
  • Publication number: 20100305247
    Abstract: A process for mass-colouring high molecular weight material, in which process a compound of formula (I) or a tautomer thereof, wherein M1 is H, ½ M2, ? M3 or NR4R5R6R7, preferably H, ½ M2 or NR4R5R6R7, especially H, M2 is an alkaline earth or transition metal in oxidation state II or an oxo-metal in oxidation state IV, M3 is Al (III), a transition metal in oxidation state III or an oxo-metal in oxidation state V, R1 is H or a non-ionic substituent, R2 is H or, independently of R1, a further non-ionic substituent, R3 is H, C1-C6alkyl, phenyl, CO—C1-C6alkyl or CO-phenyl, preferably H or CO—C1-C6alkyl, especially H, and R4, R5, R6 and R7 are each independently of the others H or phenyl, benzyl or C1-C6alkyl, which are unsubstituted or may be substituted by hydroxy or by halogen and in the case of C3-C6alkyl is uninterrupted or interrupted by O, is incorporated into the high molecular weight material before or during shaping.
    Type: Application
    Filed: October 15, 2007
    Publication date: December 2, 2010
    Inventors: Thomas Ruch, Ursula Luterbacher
  • Publication number: 20100292450
    Abstract: The invention provides a specific pyrazole disazo dye which is a yellow dye having excellent solubility in nonpolar solvents, in particular, hydrocarbon solvents, and having a high extinction coefficient. The dye preferably is preferably a pyrazole disazo dye represented by the following general formula (I): (wherein R1 represents a C2-C10 alkyl group; R2 represents a C3-C10 alkyl group; the six-membered ring A represents a phenyl group which may have a substituent; and the six-membered ring B represents a phenylene group which may have a substituent).
    Type: Application
    Filed: November 11, 2008
    Publication date: November 18, 2010
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Yasushi Shiga, Mio Ishida
  • Publication number: 20100162495
    Abstract: The present invention relates to specific pentamethine cyanine azo complex dye compounds and their use as dyes in optical layers for optical data recording, preferably for optical data recording using a laser with a wavelength from 630 to 670 nm. The invention further relates to an optical layer comprising said dyes and to a write only read many (WORM) type optical recording medium capable of recording and reproducing information with radiation of a red laser, which employs said pentamethine cyanine azo complex type dye in the optical layer.
    Type: Application
    Filed: May 7, 2008
    Publication date: July 1, 2010
    Inventors: Cédric Klein, Jean-Christophe Graciet, Martin Alexander Winter
  • Publication number: 20090297795
    Abstract: A compound of Formula (1) and salts thereof: wherein: A and B are each independently selected from the group consisting of —SO3H, —CO2H, —PO3H2, —NHCOR4, alkoxy; R1 and R2 are each independently H or optionally substituted C1-4alkyl; R3 and R4 are each independently optionally substituted C1-4alkyl; m is 1 or 2; and n is 1 to 3. Also compositions, inks, printed material, ink-jet printing processes and ink-jet cartridges.
    Type: Application
    Filed: June 30, 2009
    Publication date: December 3, 2009
    Inventors: Clive Edwin Foster, Gavin Wright, Neil James Thompson, Rachel Anne James
  • Patent number: 7341607
    Abstract: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper.
    Type: Grant
    Filed: May 27, 2003
    Date of Patent: March 11, 2008
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Michael Lennartz, Adolf Käser, Sandra Weiss
  • Patent number: 6964701
    Abstract: A process for coloration of a substrate comprising applying thereto means of an ink jet printer a composition comprising a medium and a compound of Formula (1): wherein: A is optionally substituted aryl; B is optionally substituted arylene; and R1 and R2 are each independently H or optionally substituted alkyl. Also claimed are novel compounds, compositions and ink-jet cartridges for use an ink-jet printer and substrate printed with an ink-jet printer.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: November 15, 2005
    Assignee: Avecia Limited
    Inventors: Clive Edwin Foster, Helen Ava O'Shaughnessy, Peter Gregory
  • Patent number: 6923855
    Abstract: An ink, which contains at least one dye of formula (1): A—N?N—BX1n1B?—N?N—A???Formula (1) wherein A and A? each independently represent an aryl group or a monovalent heterocyclic group; B and B? each independently represent an arylene group or a divalent heterocyclic group; X1 represents a divalent linking group; n1 is 0 or 1; and at least one of A, B, A?, and B? is a heterocyclic group.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: August 2, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toru Harada, Naotaka Wachi
  • Publication number: 20040129172
    Abstract: An ink, which contains at least one dye of formula (1):
    Type: Application
    Filed: August 1, 2003
    Publication date: July 8, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Toru Harada, Naotaka Wachi
  • Publication number: 20030226221
    Abstract: A compound which can be used as a dye and is represented by the following general formulae (I), (II) and (III). In the general formulae, A and B each independently represents a monovalent heterocyclic group bonded to an azo group by a carbon atom of the monovalent heterocyclic group; m and n each independently represents one of 0 and 1; and M represents one of a hydrogen atom and a monovalent positive ion.
    Type: Application
    Filed: January 24, 2003
    Publication date: December 11, 2003
    Inventors: Hisashi Mikoshiba, Tadashi Omatsu, Makoto Suzuki, Koushin Matsuoka, Masuji Motoki
  • Publication number: 20020170126
    Abstract: A compound which can be used as a dye and is represented by the following general formulae (I), (II) and (III). In the general formulae, A and B each independently represents a monovalent heterocyclic group bonded to an azo group by a carbon atom of the monovalent heterocyclic group; m and n each independently represents one of 0 and 1; and M represents one of a hydrogen atom and a monovalent positive ion.
    Type: Application
    Filed: January 31, 2002
    Publication date: November 21, 2002
    Inventors: Hisashi Mikoshiba, Tadashi Omatsu, Makoto Suzuki, Koushin Matsuoka, Masuji Motoki
  • Patent number: 5964899
    Abstract: Azo dyes containing sulphur dye entities as a constitutional component are dyes of valuable properties, in particular for the dyeing of leather.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: October 12, 1999
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Jordi Berenguer, Manuel Jose Domingo, Jose Rocas
  • Patent number: 5550218
    Abstract: Compounds of the formula ##STR1## wherein A is C.sub.1-6 alkylene, D is a diazo component radical of the triazolyl, pyrazolyl, cyano(C.sub.1-4 alkyl)-imidazolyl, 4-chlorothiazolyl, 4-chlorotheinyl-2, 3-phenyl-1,2,4-thiadiazolyl-5, isothiazolyl-5, benzoisothiazolyl-3 or 1,3,4-thiadiazolyl-5 series or the phenyl series wherein the phenyl group is free of sulfonyl groups and may be substituted, by a maximum of 3 substituents 5-nitrothiazolyl-2, ##STR2## R.sub.1a is phenyl or phenyl substituted by 1 to 4 substituents each of which is independently halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, trifluoromethyl, hydroxy, nitro, formyl, cyano, --SCN, (C.sub.1-4 alkyl)carbonyl, (C.sub.1-4 alkyl)carbonylamino, (C.sub.1-4 alkoxy)carbonyl, (C.sub.1-4 alkyl)carbonyloxy, carbamoyl, (C.sub.1-2 alkoxy)(C.sub.2-3 alkoxy)carbonyl or phenyl, andR.sub.2 -R.sub.4 and R.sub.10 -R.sub.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: August 27, 1996
    Assignee: Sandoz Ltd.
    Inventor: Ruedi Altermatt
  • Patent number: 5545725
    Abstract: Disazo dyes are disclosed which are particularly suitable for dyeing paper.Paper is dyed with these dyes in greenish-yellow or yellow to red shades of good fastness properties.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: August 13, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Adolf K aser, Willy Stingelin
  • Patent number: 5328995
    Abstract: The compounds of the formula ##STR1## where the substituents are as defined in claim 1, are direct dyes for various substrates, in particular cellulosic fibre materials. They are high temperature resistant and therefore are particularly highly suitable for the one-bath, single-stage dyeing of polyester/cotton blend fabrics with a disperse dye for the polyester fibres under the dyeing conditions for polyester fibres.
    Type: Grant
    Filed: January 27, 1993
    Date of Patent: July 12, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf Schaulin, Urs Lauk
  • Patent number: 5288858
    Abstract: The invention relates to azo dyes of the formula ##STR1## in which R, R.sub.1 and R.sub.2, independently of one another, are hydrogen, substituted or unsubstituted C.sub.1 -C.sub.8 alkyl or phenyl, R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl or phenyl and the benzene rings I and II may be further substituted.The azo dyes are suitable for the dyeing or printing of natural or synthetic polyamide fibre materials, in particular in combination with other dyes and in particular from short liquors. The azo dyes are distinguished by generally good properties, in particular good affinity.
    Type: Grant
    Filed: July 14, 1992
    Date of Patent: February 22, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Jurgen Schaetzer
  • Patent number: 5196520
    Abstract: The invention relates to azo dyes of formula ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is C.sub.2 -C.sub.4 alkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or unsubstituted or substituted C.sub.5 -C.sub.7 cycloalkyl or phenyl, and the benzene rings I and II are unsubstituted or substituted.The azo dyes are suitable for dyeing or printing synthetic polyamide materials, especially in conjunction with other dyes and, preferably, from short liquors. The azo dyes have good allround properties, in particular good affinity.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: March 23, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Jurgen Schaetzer, Jean-Marie Adam
  • Patent number: 5037967
    Abstract: Disperse dyes containing a monoazo coupling component of the formula ##STR1## in which X is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, acylamino, halogen or a group of the formula --NH--CO--NHQ in which Q is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl,Y is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxy,R is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or phenyl, or Y and R, together with the nitrogen atom and the two C atoms linking them, form a 5-membered or 6-membered ring,B is a linear or branched C.sub.2 -C.sub.6 alkylene radical,W is halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,Z is halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or nitro andm and n are each 0, 1, 2 or 3.
    Type: Grant
    Filed: November 7, 1989
    Date of Patent: August 6, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Angelo D. Casa, Peter Liechti, Max Dempfle
  • Patent number: 4965345
    Abstract: Solvent dyes of the formula ##STR1## where ##STR2## R.sup.1 and R.sup.2 are each, independently of the other, hydrogen, methyl, ethyl, methoxy or ethoxy,n is 0 or 1 andk, if n is 0, is the radical of a coupling component of the pyrazolone series or, if n is 1, is the radical of a coupling component of the pyrazolone, 2-naphthol, hydroxyquinoline, aniline, naphthylamine, pyridone or 2,6-diaminopyridine series,R.sup.3 and R.sup.4 each independently of the other being C.sub.1 -C.sub.22 -alkyl which may be substituted or interrupted by oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, subject to the proviso that COR has more than 8 carbon atoms, are very highly suitable for coloring organic substrates.
    Type: Grant
    Filed: October 2, 1987
    Date of Patent: October 23, 1990
    Assignee: BASF Aktiengesellschaft
    Inventor: Hermann Loeffler
  • Patent number: 4956255
    Abstract: The present invention relates to a photosensitive member containing a specific azo compound represented by the following general formula [I]; ##STR1## wherein A is a bivalent group of a condensed poly-cyclic ring which may have a substituent, a pyridine which may have a substituent, a diazine which may have a substituent, a quinoline which may have a substituent, or a benzoazine which may have a substituent; Cp is a residual group of a coupler, which is improved in photosensitive porperties, in particular, sensitivity.
    Type: Grant
    Filed: February 22, 1989
    Date of Patent: September 11, 1990
    Assignee: Minolta Camera Kabushiki Kaisha
    Inventor: Hideaki Ueda
  • Patent number: 4910299
    Abstract: Disperse dyes suitable for dyeing textile material composed of polyester dyes of the formula ##STR1## in which D is the radical of a substituted or unsubstituted, homocyclic or heterocyclic diazo component belonging to the series comprising thienyl, thiazolyl, isothiazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl, benzothiazolyl, benzoisothiazolyl, pyrazolyl, imidazolyl or phenyl,X is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, acylamino, halogen or a group of the formula -NH-CO-NHQ in which Q is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl,Y is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkoxy,R is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl or phenyl, or Y and R, together with the nitrogen atom and the two C atoms linking them, form a 5-membered ring or 6-membered ring,B is a l inear or branched C.sub.2 -C.sub.6 -alkylene radical,W is halogen, C.sub.
    Type: Grant
    Filed: December 2, 1987
    Date of Patent: March 20, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Angelo D. Casa, Peter Liechti, Max Dempfle
  • Patent number: 4833235
    Abstract: Disazo compounds of the formula ##STR1## and salt thereof, D is the radical of a diazo component of the benzene or naphthalene series.K is the radical of a heterocyclic coupling component of the aminopyrazole-, pyridone- or barbituric acid-series, n is 1 to 4,R.sub.1 is hydrogen, C.sub.1-4 alkyl or substituted C.sub.1-4 alkyl,each of R.sub.2 and R.sub.3 is independently hydrogen, halo, C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy, substituted C.sub.1-4 alkoxy, --NHCO--Rhd 5, amino, substituted amino or a quaternary ammonium group, wherein R.sub.5 is C.sub.1-4 alkyl, substituted C.sub.1-4 alkyl, C.sub.1-4 alkoxy or amino,R.sub.4 is hydrogen, C.sub.1-4 alkyl, C.sub.
    Type: Grant
    Filed: October 7, 1987
    Date of Patent: May 23, 1989
    Assignee: Sandoz Ltd.
    Inventor: Reinhard Pedrazzi
  • Patent number: 4772292
    Abstract: A dyestuff mixture for coloring synthetic fibers a yellow color contains as component A a dyestuff of the formula ##STR1## and as component B a different yellow disperse dyestuff species.
    Type: Grant
    Filed: November 30, 1987
    Date of Patent: September 20, 1988
    Assignee: Cassella Aktiengesellschaft
    Inventors: Manfred Hahnke, Ulrich Buhler, Albert Bode
  • Patent number: 4772687
    Abstract: Metal complex dyestuffs which in the form of the free acid correspond to the formula ##STR1## in which the substituents have the meaning given in the description are, depending on the meanings of the substituents, suitable for use as reactive dyestuffs for cotton, wool or polyamide, as direct dyestuffs for cotton or as pigment dyestuffs. Dyeings are obtained which have good fastness properties, in particular good wet-, light- and chlorine fastness.
    Type: Grant
    Filed: May 1, 1986
    Date of Patent: September 20, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hermann Henk
  • Patent number: 4764599
    Abstract: Sulfo-free compounds of the formula ##STR1## where R is hydrogen or C.sub.1 -C.sub.4 -alkyl andK.sup.1 and K.sup.2 independently of one another are a radical of a coupling component, and the rings A and B may furthermore be monosubstituted or polysubstituted by fluorine, chlorine, bromine, nitro, methyl, trifluoromethyl, ethyl, acetyl, benzoyl, a carboxylic ester group, unsubstituted or substituted carbamyl or sulfamyl, an aryl sulfonate group, C.sub.1 -C.sub.4 -alkylsulfonyl, unsubstituted or substituted phenylsulfonyl, cyano or acylamino or a fused ring, are very useful as pigments for coloring printing inks, surface coatings or plastics.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: August 16, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Horst Colberg, Erwin Hahn
  • Patent number: 4739042
    Abstract: Halftone gravure printing inks containing pyridone azo dyestuffs wherein the dyestuffs are obtained by reacting a pyridone dyestuff of the formula ##STR1## with a dicarboxylic or polycarboxylic acid or a pyridone azo dyestuff of the formula ##STR2## with a dihydroxy or polyhydroxy compound.
    Type: Grant
    Filed: August 4, 1986
    Date of Patent: April 19, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Lorenz, Artur Haus
  • Patent number: 4694075
    Abstract: The compounds of the formula ##STR1## where Y is hydrogen, chlorine, bromine or nitro, Z is hydrogen, chlorine, bromine, a sulfonic ester group or unsubstituted or substituted sulfamyl, X is --O-- or ##STR2## R is alkylene which may or may not be interrupted by oxygen or ##STR3## m is 0 or 1, p is 1 or 2, R.sup.1 and R.sup.2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, or aryl, or R.sup.1 and R.sup.2 together with the nitrogen form a heterocyclic structure, R.sup.3 is hydrogen or unsubstituted or substituted alkyl, R.sup.6 and R.sup.7 independently of one another are each hydrogen, unsubstituted or substituted alkyl, alkoxy or acylamino, K is a radical of a coupling component, A.crclbar. is an anion, R.sup.4 is unsubtituted or substituted alkyl and R.sup.5 is hydrogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: January 21, 1986
    Date of Patent: September 15, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Horst Colberg, Erwin Hahn
  • Patent number: 4686285
    Abstract: (i) Metal-free compounds of the formula ##STR1## (ii) tautomers thereof, (iii) 1:1 and 1:2 metal complexes of (i) and (ii),(iv) salts of (i), (ii), and (iii), and(v) mixtures of (i), (ii), (iii), and (iv),wherein the symbols are as defined in the Specification, are useful as dyes for, for example, polymers and copolymers of acrylonitrile, polyesters modified to contain acid groups, polyamides such as wool, leather, cotton, bast fibers such as hemp, flax, sisal jute, coir and straw, regenerated cellulose, glass fibers and paper (those wherein R.sub.o is other than hydrogen) or as intermediates for the synthesis of dyes.
    Type: Grant
    Filed: February 8, 1985
    Date of Patent: August 11, 1987
    Assignee: Sandoz Ltd.
    Inventor: Reinhard Pedrazzi
  • Patent number: 4668774
    Abstract: Novel dye salts of anionic dyes of the general formula I ##STR1## where F is a radical of an anionic dye, n is 1, 2, 3 or 4, and B.sup.1 and B.sup.2 independently of one another are each unsubstituted or substituted branched alkyl or alkyl-substituted cycloalkyl having a total of 10 to 36 carbon atoms, are very useful for dyeing solvents, printing inks or polymeric film-forming materials.
    Type: Grant
    Filed: April 23, 1985
    Date of Patent: May 26, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Hermann Loeffler, Rainer Dyllick-Brenzinger
  • Patent number: 4667020
    Abstract: Compounds of the formula ##STR1## where X is a 5-membered heterocyclic structure from the oxazole, oxadiazole, thiazole, thiadiazole, imidazole or triazole series, Y is a radical of the formula ##STR2## the rings A, B and C can be further substituted and can be fused to a benzene ring, R.sup.1 and R.sup.2 are each hydrogen or unsubstituted or substituted alkyl, aralkyl or cycloalkyl, or R.sup.1 and R.sup.2 together with the nitrogen are piperidino, pyrrolidino or morpholino, R.sup.3 is hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aralkyl, acyl, alkoxycarbonyl, aryloxycarbonyl or arylsulfonyl, and R.sup.4 is hydrogen, alkyl or cycloalkyl, are particularly useful as dyes in liquid-crystalline media.
    Type: Grant
    Filed: February 20, 1985
    Date of Patent: May 19, 1987
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Christos Vamvakaris
  • Patent number: 4634764
    Abstract: Compounds of the formula ##STR1## wherein each R is independently --N(R.sub.1).sub.2, --N.sup..sym. (R.sub.2).sub.3 A.sup..crclbar. or hydroxy, whereineach R.sub.1 is independently hydrogen, alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl or aryl orboth R.sub.1 's taken together and with the nitrogen atom to which they are attached form a 5- or 6-membered saturated heterocyclic ring,each R.sub.2 is independently alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl or aryl ortwo R.sub.2 's taken together and with the nitrogen atom to which they are attached form a 5- or 6-membered saturated heterocyclic ring orall three R.sub.2 's taken together and with the nitrogen atom to which they are attached form a 5- or 6-membered unsaturated heterocyclic ring, andA.sup..crclbar. is a non-chromophoric anion,each T is independently a bridging radical, andZ is hydrogen or --N.dbd.
    Type: Grant
    Filed: November 10, 1983
    Date of Patent: January 6, 1987
    Assignee: Sandoz Ltd.
    Inventor: Manfred Greve
  • Patent number: 4515716
    Abstract: Diaminopyridine-based azo dyes for cellulose-containing fibers, represented by the following formula: ##STR1## and the other is hydrogen, phenyl, benzyl, allyl, or alkyl which are unsubstituted or substituted by hydroxyl or lower alkoxy(whereinA is methylene, ethylene, propylene, or 1,3-butylene;n is 0 or 1;Y.sup.1 and Y.sup.2, which are the same or different, are hydrogen, alkyl, alkenyl, cyclohexyl, aryl, or aralkyl which are unsubstituted or substituted by cyano, hydroxy, lower alkoxy, or dialkylamino, or Y.sup.1 and Y.sup.2 together form a 5- or 6-membered heterocyclic ring (NY.sup.1 Y.sup.2) containing one nitrogen, the total number of carbon atoms of Y.sup.1 and Y.sup.2 being 18 or less;R.sup.1 is nitro, cyano, methylsulfonyl, phenylsulfonyl, mono-lower alkylaminosulfonyl, di-lower alkylaminosulfonyl, acetyl, or benzoyl;R.sup.2 and R.sup.3, which are the same or different, are hydrogen, trifluoromethyl, halogen, or cyano;R.sup.
    Type: Grant
    Filed: September 3, 1982
    Date of Patent: May 7, 1985
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Toshio Niwa, Toshio Hihara
  • Patent number: 4500455
    Abstract: Diaminopyridine dyes for dyeing cellulose-containing fibers, particularly cellulose fibers and polyester-cellulose fibers in from orange to bluish red, with excellent fastness to light. The dyes are represented by the formula (I): ##STR1## X is a hydrogen atom, or a halogen atom; Y is an alkoxy group containing from 1 to 5 carbon atoms, --O--R.sup.10 --O--R.sup.11, or a phenoxy group; andn is 2 or 3, and wherein R.sup.1 is a nitro group, a cyano group, a methylsulfonyl group, a phenylsulfonyl group, a mono- or di-lower alkylaminosulfonyl group, an acetyl group, or a benzoyl group; R.sup.2 and R.sup.3 are each a hydrogen atom, a trifluoromethyl group, a halogen atom, or a cyano group; R.sup.4 is a hydrogen atom, a lower alkyl group, a mono- or di-lower alkylaminosulfonyl group, a mono- or di-lower alkylcarbamoyl group, or an acetylamino group; R.sup.5 and R.sup.6 are each a hydrogen atom, a halogen atom, or a lower alkyl group; R.sup.7 is a lower alkyl group; R.sup.8 is a hydrogen atom or a halogen atom; R.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: February 19, 1985
    Assignee: Mitsubishi Chemical Industries, Limited
    Inventors: Toshio Niwa, Toshio Hihara, Yukiharu Shimizu
  • Patent number: 4491544
    Abstract: A compound having the formula (I): ##STR1## wherein D is a radical of a heterocyclic or aromatic component selected from the group of aniline, anthraquinone, phthalimide or aminobenzene radicals, wherein the radical is unsubstituted or is substituted by fluorine, chlorine, bromine, nitro, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, trifluoromethyl, cyano, C.sub.1 -C.sub.4 -alkylsulfonyl, carboxylic acid ester groups, carbamyl, sulfamyl, 1,3,4- or 1,2,4-oxadiazolyl or acylamino groups; X is CO-- or --SO.sub.2 --; and R is an aliphatic, aromatic or heterocyclic radical selected from the group of C.sub.1 -C.sub.
    Type: Grant
    Filed: August 18, 1982
    Date of Patent: January 1, 1985
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Radtke, Heinrich Kowarsch, Erwin Hahn, Peter Hauser
  • Patent number: 4483795
    Abstract: Compounds of the general formula I ##STR1## where D is the radical of a diazo component,R is hydrogen, hydroxy or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, phenyl or heterocyclic ring,R.sup.1 and R.sup.2 independently of one another are hydrogen or unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, aralkyl or aryl, orR.sup.1 and R.sup.2 together with the nitrogen are a saturated heterocyclic 5-membered to 7-membered ring,X is hydrogen, chlorine, bromine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, allyloxy, .beta.-cyanoethoxy, benzyloxy, phenoxy, .beta.-alkoxycarbonylethoxy, where alkoxy is of 1 to 4 carbon atoms, alkylmercapto of 1 to 4 carbon atoms, phenylmercapto or alkanoylamino of 1 to 4 carbon atoms, andY is chlorine, alkyl of 1 to 4 carbon atoms, allyloxy, alkoxy of 1 to 4 carbon atoms or .beta.-cyanoethoxy, orX and Y together are a fused benzene ring which is unsubstituted or substituted by alkyl alkoxy chlorine or bromine.
    Type: Grant
    Filed: October 13, 1982
    Date of Patent: November 20, 1984
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Eilingsfeld, Guenter Hansen, Guenther Seybold, Georg Zeidler