Nitrogen, Other Than As Nitro, Nitroso Or Azo, Attached Indirectly To Azo By Nonionic Bonding Patents (Class 534/824)
  • Patent number: 8979987
    Abstract: Provided, amongst other things, are dyes of formula II: wherein R1, R2, R3 and R4 are independently H or alkyl, so long as one or more is alkyl, and salts of the compound of formula II. Methods of making, inks, surgical markers and methods of marking tissue and the like are further provided.
    Type: Grant
    Filed: April 5, 2013
    Date of Patent: March 17, 2015
    Assignee: Viscot Medical, LLC
    Inventors: Eric Stroud, Gary J. Pieringer
  • Patent number: 7078497
    Abstract: The dyes of formula (1) according to claim 1 and the copper complexes of dyes of formula (2) according to claim 9 or the mixtures of mono-copper complex with the bis-copper complex are excellently suitable for dyeing paper with good light-fastness properties.
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: July 18, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Adolf Käser, Holger Lautenbach
  • Publication number: 20030082547
    Abstract: Bis-diazo,triaryl and aryldiazo-N-arylphenazonium quencher moieties, substituted with electron-withdrawing and electron-donating substituents which induce polarity in the delocalized aryl/diazo ring systems, are useful as labels when attached to biomolecules such as polynucleotides, nucleosides, nucleotides, and polypeptides. The quencher moieties are non-fluorescent and accept energy from fluorescent reporter labels by any energy-transfer mechanism, such as FRET.
    Type: Application
    Filed: August 27, 2001
    Publication date: May 1, 2003
    Inventors: Gregory J. Ewing, Khairuzzaman Bashar Mullah, Ronald J. Graham
  • Patent number: 6143062
    Abstract: Are disclosed disazo compounds represented by the general formula (1): ##STR1## wherein A represents a phenylene or naphthylene group which may be optionally substituted; each of R.sup.1 and R.sup.2 represent independently a hydrogen atom, an alkyl group or a phenyl group which may be optionally substituted; and m is 1 or 2. The compounds are highly water-soluble and are stable to long term storage. Ink compositions comprising the compounds of the invention can produce a printed image with full depth of shade and are excellent in resistance to water.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: November 7, 2000
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Takashi Miyazawa, Toru Tabei, Isao Yamaguchi, Yasuo Shirasaki, Junko Yoshioka
  • Patent number: 5882391
    Abstract: A bisazo dye of Formula (1) and salts thereof: ##STR1## in which R is H or ##STR2## R.sub.1 and R.sub.2 each independently is H, optionally substituted C.sub.1-4 -alkyl or optionally substituted aryl;R.sub.3 and R.sub.5 together with the carbon atoms to which they are attached form a 5- or 6-membered carbocyclic ring which is optionally substituted by SO.sub.3 H;R.sub.4 is H;R.sub.6 is COOH;n is 1, 2 or 3; andp is 1, 2, 3 or 4.The dyes are useful for ink jet printing.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: March 16, 1999
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Prahalad Manibhai Mistry, Roy Bradbury, Paul Wight
  • Patent number: 5494507
    Abstract: A dye having a representative formula as follows and an ink providing waterfast printing having the dye, in which a surfactant is not essential: ##STR1##
    Type: Grant
    Filed: December 19, 1994
    Date of Patent: February 27, 1996
    Assignee: Lexmark International, Inc.
    Inventors: Bradley L. Beach, James F. Feeman, Ann M. Piekunka, Allen C. Sanders
  • Patent number: 5370730
    Abstract: Dye compositions and aqueous inks derived therefrom, especially suitable for use in ink jet printing in which the dye composition contains (a) one or more dyes which, in the free acid form, are of Formula (1): ##STR1## wherein W is H or COOH;X is H or COOH;Y is H or COOH;U & Z are each independently H, COOH or SO.sub.3 H; andV is H or SO.sub.3 H;and (b) one or both dyes which in the free acid form is of Formula (2): ##STR2## wherein A is NH.sub.2 and B is OH; orA is OH and B is NH.sub.2.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: December 6, 1994
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald W. Kenyon, John E. Presgrave
  • Patent number: 5203912
    Abstract: A dye which, in the free acid form, has the formula ##STR1## wherein W is COOHX is selected from H, COOH, SO.sub.3 H, halo, hydroxy, nitro, cyano, C.sub.1-6 -alkyl, C.sub.1-6 -alkoxy and C.sub.1-6 -acylamino;Y is H, COOH or SO.sub.3 H;Z is H, COOH or SO.sub.3 H;R & R.sup.1 are each independently H or C.sub.1-6 -alkyl substituted by 0, 1 or 2 --COOR.sup.2 groups; andR.sup.2 is H or C.sub.1-6 -alkyl;provided that there are at least two COOH groups and that the number of COOH groups is equal to or greater than the number of SO.sub.3 H groups.The dye is adapted for the preparation of inks for use in ink jet printing in which it displays high water-fastness on paper.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: April 20, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: David Greenwood, Nigel Hughes, Ronald W. Kenyon, Suraj L. Hindagolla
  • Patent number: 5062893
    Abstract: Inks are provided comprising (a) at least two dyes corresponding to the formula ##STR1## wherein W is COOH,X is H, or COOH,Y is H, COOH, or SO.sub.3 H,Z is H, COOH, or SO.sub.3 H, andR is H, CH.sub.2 COOH, or CH.sub.2 CH.sub.2 COOH;with the proviso that there are at least two COOH groups and that the number of COOH groups is equal to or greater than the number of SO.sub.3 H groups, and (b) a solvent which may be water or a mixture of water and a water-soluble organic solvent provide excellent waterfast prints on paper. The inks preferably have a pH from about 7 to about 9.5. Also preferably, a phosphate is added to reduce kogation and a metal chelating agent is added to further reduce nozzle clogging.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: November 5, 1991
    Assignee: Hewlett-Packard Company
    Inventors: Raymond J. Adamic, Palitha Wickramanayake, Suraj L. Hindagolla, Garold E. Radke, David J. Halko
  • Patent number: 4973672
    Abstract: Coloring natural or synthetic fiber material containing hydroxyls or nitrogen is achieved by printing or dyeing the fiber material with a water-soluble disazo dyestuff of the formula ##STR1## wherein R.sup.1 is alkyl, alkoxy or alkoxyethoxy, each having 3-6 carbon atoms, B.sup.1 is the radical of a 1-amino-8-hydroxynaphthalene monosulphonic or disulphonic acid and B.sup.2 is the same as B.sup.1 or another napthyl moiety.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: November 27, 1990
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Klaus Hunger
  • Patent number: 4963189
    Abstract: Inks are provided comprising (a) a dye corresponding to the formula ##STR1## wherein W is COOH,X is H, or COOH,Y is H, COOH, or SO.sub.3 H,Z is H, COOH, or SO.sub.3 H, andR is H, CH.sub.2 COOH, or CH.sub.2 CH.sub.2 COOH;with the proviso that there are at least two COOH groups and that the number of COOH groups is equal to or greater than the number of SO.sub.3 groups, and (b) a solvent which may be water or a mixture of water and a water-soluble organic solvent provide excellent waterfast prints on paper. The inks preferably have a pH from about 7 to about 9.5.
    Type: Grant
    Filed: August 24, 1989
    Date of Patent: October 16, 1990
    Assignee: Hewlett-Packard Company
    Inventor: Suraj L. Hindagolla
  • Patent number: 4752337
    Abstract: Recording liquid for ink jet recording systems containing dyestuffs of the formulae ##STR1## with the substituent definitions given in the description. They form high-contrast images of high fastness to water, light and abrasion.
    Type: Grant
    Filed: June 5, 1987
    Date of Patent: June 21, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventor: Klaus Kunde
  • Patent number: 4562249
    Abstract: There are described novel yellow to red azo compounds of the formula I ##STR1## wherein each D independently of the other is the radical of an aromatic or heterocyclic diazo component, each Z independently of the other is hydrogen or a C.sub.1 -C.sub.4 -alkyl group or an acylamino group, Y is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, X is either the direct bond or C.sub.1 -C.sub.6 -alkylene, ##STR2## and n is a number from 2 to 6, preferably 2; and the substituent Y, in the case of an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, can also be bonded to the o-position relative to the N atom of the phenylene group to form a six-membered ring, or both Y substituents can be linked together to form a C.sub.1 -C.sub.
    Type: Grant
    Filed: March 5, 1985
    Date of Patent: December 31, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Hansrudolf Schwander, Rudolf Hurter