Plural Nitrogens, Other Than As Nitro, Nitroso Or Azo, Attached Indirectly To Azo By Nonionic Bonding Patents (Class 534/825)
  • Patent number: 8979987
    Abstract: Provided, amongst other things, are dyes of formula II: wherein R1, R2, R3 and R4 are independently H or alkyl, so long as one or more is alkyl, and salts of the compound of formula II. Methods of making, inks, surgical markers and methods of marking tissue and the like are further provided.
    Type: Grant
    Filed: April 5, 2013
    Date of Patent: March 17, 2015
    Assignee: Viscot Medical, LLC
    Inventors: Eric Stroud, Gary J. Pieringer
  • Patent number: 8576485
    Abstract: A method of forming a polarizing material is provided including exposing a layer of dichroic material to activating light illumination to provide an ordered structure with a distinguished absorption axis and thus photo-induce polarization, and fixing the induced polarization by polymerization of the dichroic layer. Novel polarizing materials formed thereby are also provided. By selectively exposing regions of the dichroic material to differing activating radiation, different regions with different polarization axes can be created. The polarizing material can also be provided with a coating or coatings to alter the spectral responses, and a stack formed of a plurality if dichroic layers can be provided.
    Type: Grant
    Filed: September 28, 2010
    Date of Patent: November 5, 2013
    Assignee: The Hong Kong University of Science and Technology
    Inventors: Vladimir Markovich Kozenkov, Wing Chiu Yip, Vladimir Grigorievich Chigrinov, Hoi Sing Kwok
  • Publication number: 20120307363
    Abstract: A method of forming a polarizing material is provided including exposing a layer of dichroic material to activating light illumination to provide an ordered structure with a distinguished absorption axis and thus photo-induce polarization, and fixing the induced polarization by polymerization of the dichroic layer. Novel polarizing materials formed thereby are also provided. By selectively exposing regions of the dichroic material to differing activating radiation, different regions with different polarization axes can be created. The polarizing material can also be provided with a coating or coatings to alter the spectral responses, and a stack formed of a plurality if dichroic layers can be provided.
    Type: Application
    Filed: September 28, 2010
    Publication date: December 6, 2012
    Applicant: The Hong Kong University of Science and Technology
    Inventors: Vladimir Markovich Kozenkov, Wing Chiu Yip, Vladimir Grigorievich Chigrinov, Elena Karlovna Prudnikova, Hoi Sing Kwok
  • Patent number: 6049428
    Abstract: The present invention provides dyes of formula I-XXXIV, described in detail below, and dichroic light polarizers based on the dyes. In the dichroic light polarizers of this invention the dye molecules are aggregated into particles oriented in a predetermined direction on a surface of a substrate to enable the dye to polarize light transmitted through the dye. In another embodiment, a dichroic light polarizer includes a molecularly oriented layer of an organic dye on a surface of a substrate. The layer has a non-periodic arrangement of different polarizing elements. Each of the polarizing elements have differing orientations of the polarization vector in the substrate plane and/or differing colors. The dichroic light polarizer may contain one or more additional dye layers and may have a transparent layer intermediate to the dye layer.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: April 11, 2000
    Assignee: Optiva, Inc.
    Inventors: Ir G Khan, Yuri A. Bobrov, Leonid Y. Ignatov, Elena Y. Shishkina, Pavel I Lazarev, Alexey V. Kurbatov
  • Patent number: 5965717
    Abstract: Nonmutagenic, highly twisted derivatives of benzidine of the following formula ##STR1## useful as intermediates for the preparation of various organic pigments were obtained. The benzidine derivatives are significantly rotated about the biphenyl linkage due to bulky substituents at the R.sub.2 and/or R.sub.4 positions. Bisazomethine, disaoacetoacetanilide, disazopyrazolone, disazobenzimidazolone and disazonaphthol pigments prepared from these highly twisted benzidines exhibit hypsochromic spectral shifts relative to pigments prepared from other benzidine compounds with less twist about the biphenyl linkage, for instance, other benzidine compounds in which all four R.sub.2 and R.sub.4 represent H. Greenish-yellow, yellow, orange, red and brown pigments obtained from the twisted benzidines are nonmutagenic in the standard Ames test and Prival modification.
    Type: Grant
    Filed: November 4, 1997
    Date of Patent: October 12, 1999
    Assignee: North Carolina State University
    Inventors: Harold S. Freeman, David Hinks, Jolanta Sokolowska-Gajda
  • Patent number: 5843218
    Abstract: A bisazo dye of Formula (1) and salts thereof: ##STR1## wherein: R.sub.1 and R.sub.2 together with the carbon atoms to which they are attached form a 5- or 6- membered carbocyclic ring which is optionally substituted by SO.sub.3 H;R.sub.3 and R.sub.4 are each independently H or C.sub.1-4 -alkyl;y is 1, 2, 3 or 4; andn is 1, 2 or 3.The dyes are useful for ink jet printing.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: December 1, 1998
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Prahalad Manibhai Mistry, Roy Bradbury, Paul Wight
  • Patent number: 5536818
    Abstract: A dichroic dye represented by the formula (I) or (II): ##STR1## wherein the substituents are as described in the specification. The dichroic dyes (I) and (II) exhibit excellent dichroism and can be prepared from 2,2'-ditrifluoromethylbenzidine having no toxicity, such as mutagenicity.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: July 16, 1996
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masaharu Kaneko, Hisayo Ishio
  • Patent number: 5118737
    Abstract: A water-soluble dye, free from cellulose reactive groups, of the formula: ##STR1## wherein R.sup.1 is --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H,R.sup.2 is H or --(C.sub.a H.sub.2a O).sub.m (C.sub.b H.sub.2b O).sub.n H, orR.sup.1 and R.sup.2 together with the nitrogen atom form a morpholine ringa and b are different and from 1 to 8m is from 1 to 10;n is from 0 to 9;M is H, ammonium, or a monovalent metal;X (i) NR.sup.1 R.sup.2, (ii) NR.sup.3 R.sup.4, in which R.sup.3 and R.sup.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: June 2, 1992
    Assignee: Canon Kabushiki Kaisha
    Inventors: Anthony G. W. Baxter, Stephen B. Bostock, David Greenwood
  • Patent number: 4973672
    Abstract: Coloring natural or synthetic fiber material containing hydroxyls or nitrogen is achieved by printing or dyeing the fiber material with a water-soluble disazo dyestuff of the formula ##STR1## wherein R.sup.1 is alkyl, alkoxy or alkoxyethoxy, each having 3-6 carbon atoms, B.sup.1 is the radical of a 1-amino-8-hydroxynaphthalene monosulphonic or disulphonic acid and B.sup.2 is the same as B.sup.1 or another napthyl moiety.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: November 27, 1990
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Klaus Hunger
  • Patent number: 4562249
    Abstract: There are described novel yellow to red azo compounds of the formula I ##STR1## wherein each D independently of the other is the radical of an aromatic or heterocyclic diazo component, each Z independently of the other is hydrogen or a C.sub.1 -C.sub.4 -alkyl group or an acylamino group, Y is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, X is either the direct bond or C.sub.1 -C.sub.6 -alkylene, ##STR2## and n is a number from 2 to 6, preferably 2; and the substituent Y, in the case of an unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl group, can also be bonded to the o-position relative to the N atom of the phenylene group to form a six-membered ring, or both Y substituents can be linked together to form a C.sub.1 -C.sub.
    Type: Grant
    Filed: March 5, 1985
    Date of Patent: December 31, 1985
    Assignee: Ciba-Geigy Corporation
    Inventors: Hansrudolf Schwander, Rudolf Hurter