Hetero Ring Patents (Class 544/198)
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Patent number: 5804622Abstract: A stabilizer combination, principally for PVC, is described, comprising A at least one zinc carboxylate B at least one compound of the formula ##STR1## in which R.sub.1 to R.sub.6 are as defined in claim 1.Type: GrantFiled: March 17, 1997Date of Patent: September 8, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Horst Zinke, Wolfgang Wehner, Karl Josef Kuhn, Valerio Borzatta, Gerhard Rytz
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Patent number: 5792864Abstract: The present invention relates generally to carboxylated amino-1,3,5-triazines and the preparation thereof via carboxylation of amino-1,3,5-triazines with carbon dioxide and a base. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, and particularly carbamate and isocyanate functional 1,3,5-triazines. The present invention also relates to the preparation of such carbamate and isocyanate functional 1,3,5-triazines.Type: GrantFiled: May 18, 1995Date of Patent: August 11, 1998Assignee: Cytec Technology Corp.Inventors: Lawrence Allen Flood, Ram Baboo Gupta
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Patent number: 5792865Abstract: The present invention relates generally to carboxylated amino-1,3,5-triazines and the preparation thereof via carboxylation of amino-1,3,5-triazines with carbon dioxide and a base. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, and particularly carbamate and isocyanate functional 1,3,5-triazines. The present invention also relates to the preparation of such carbamate and isocyanate functional 1,3,5-triazines.Type: GrantFiled: May 18, 1995Date of Patent: August 11, 1998Assignee: Cytec Technology Corp.Inventors: Lawrence Allen Flood, Ram Baboo Gupta
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Patent number: 5786475Abstract: The invention relates to compounds of formula ##STR1## wherein the variables have the meanings given in the claims. The compounds are suitable for use as UV absorbers for the photochemical stabilization of undyed, dyed or printed textile fiber materials and for enhancing the sun protection factor thereof.Type: GrantFiled: September 11, 1995Date of Patent: July 28, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Francesco Fuso, Gerhard Reinert
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Patent number: 5777113Abstract: The invention relates to novel compounds of formula I ##STR1## wherein the general symbols are as defined in claim 1, as stabilizers for organic materials against oxidative, thermal or light-induced degradation.Type: GrantFiled: October 10, 1995Date of Patent: July 7, 1998Assignee: Ciba Specialty Chemicals CorporationInventor: Rita Pitteloud
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Patent number: 5770544Abstract: A condensed heterocyclic derivative of the formula ##STR1## (wherein R is a hydroxyl group, R.sup.3 or R.sup.4 is an alkoxy group, W is an oxygen atom, Yn is a hydrogen atom, Z is a methine group, and A is a 5- or 6-membered heterocyclic ring which may be substituted, and a herbicide, are presented. When used for paddy field treatment, upland soil treatment and foliage treatment, the condensed heterocyclic derivative of the present invention exhibits excellent herbicidal activities against gramineous and non-gramineous weeds without adversely affecting crop plants.Type: GrantFiled: October 9, 1996Date of Patent: June 23, 1998Assignees: Kumiai Chemical Industry Co., Ltd., Ihara Chemical Industry Co., Ltd.Inventors: Sumio Yokota, Masafumi Matsuzawa, Nobuyuki Ohba, Toshihiro Nagata, Shigehiko Tachikawa, Takeshige Miyazawa, Katsutada Yanagisawa
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Patent number: 5747423Abstract: The novel 6-thienyl pyridines and 4-thienyl pyrimidines of formula I: ##STR1## (A, R.sub.1 to R.sub.5 and Z are defined in the specification) show selective herbicidal activity.The new compounds can be prepared according to known methods and can be used as herbicides in agriculture and related fields.Type: GrantFiled: July 15, 1996Date of Patent: May 5, 1998Assignee: American Cyanamid CompanyInventors: Stefan Scheiblich, Thomas Maier, Helmut Siegfried Baltruschat, Joseph Luke Pont
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Patent number: 5744127Abstract: Compounds of formula (I) ##STR1## wherein the groups are as defined in the description, are useful as sunscreens in cosmetics and in the stabilization of synthetic polymers.Type: GrantFiled: September 20, 1996Date of Patent: April 28, 1998Assignee: 3V Inc.Inventors: Raspanti Giuseppe, Zanchi Giorgio
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Patent number: 5736628Abstract: The present invention is directed to novel benzenesulfonylurea derivatives having herbicidal activity.Type: GrantFiled: June 7, 1995Date of Patent: April 7, 1998Assignee: Korea Research Institute of Chemical TechnologyInventors: Dae-Whang Kim, Young Kwan Ko, Jin-Seog Kim, Dong Whan Ku
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Patent number: 5700295Abstract: The invention relates to compounds of formula ##STR1## wherein the variables have the meanings given in the claims. The compounds are suitable for use as UV absorbers for the photochemical stabilisation of undyed, dyed or printed textile fiber materials and for enhancing the sun protection factor thereof.Type: GrantFiled: October 11, 1995Date of Patent: December 23, 1997Assignee: Ciba Specialty Chemicals CorporationInventors: Francesco Fuso, Gerhard Reinert
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Patent number: 5698555Abstract: Hetaryloxy-.beta.-carbolines of formula I ##STR1## in which R.sup.A means a triazine or benzocondensed hetaryl radical with 1-2 nitrogen atoms optionally substituted with halogen, C.sub.1-6 alkyl, C.sub.1-6 alkoxy, C.sub.1-6 alkylthio, trifluoromethyl or SO.sub.2 --R.sup.1 or a 5- or 6-membered hetaryl radical with 1-2 nitrogen atoms substituted with halogen, C.sub.1-6 alkyl, C.sub.1-6 alkoxy, C.sub.1-6 alkylthio, trifluoromethyl or SO.sub.2 --R.sup.1are useful pharmaceutical agents.Type: GrantFiled: July 11, 1994Date of Patent: December 16, 1997Assignee: Schering AktiengesellschaftInventors: Martin Kruger, Andreas Huth, Dieter Seidelmann, Herbert Schneider, Lechoslaw Turski, David Norman Stephens
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Patent number: 5696262Abstract: The invention relates to novel water-soluble triazines of formula ##STR1## wherein the variables are as defined in the claims, to a process for their preparation and to the use thereof for the photochemical and thermal stabilisation of dyed or undyed polyamide fiber materials.Type: GrantFiled: August 22, 1995Date of Patent: December 9, 1997Assignee: Ciba Specialty Chemicals CorporationInventors: Francesco Fuso, Gerhard Reinert
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Patent number: 5696261Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilisers, heat stabilisers and oxidation stabilisers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.Type: GrantFiled: November 8, 1995Date of Patent: December 9, 1997Assignee: Ciba Specialty Chemicals CorporationInventors: Valerio Borzatta, Graziano Vignali, Fabrizio Guizzardi
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Patent number: 5693797Abstract: A process for the preparation of brominated phthalimides that involves mixing tetrabromophthalic anhydride, an organic acid, and an organic dispersing agent in water at approximately 110.degree. C. under 1 bar pressure is disclosed. An amine is added and the reaction mixture is stirred for six hours under approximately 5 bar pressure and heated at least to 120.degree. C. The reactant mass is washed in water and then methanol. The process decreases production time, increases whiteness and purity, and decreases yellowness and particle size of the resulting product.Type: GrantFiled: February 14, 1997Date of Patent: December 2, 1997Assignee: Unitex Chemical CorporationInventor: James F. Day
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Patent number: 5693310Abstract: Compounds of general Formula I ##STR1## wherein R.sup.3 is a saturated, unsaturated, straight- or branched-chain or cyclic aliphatic hydrocarbon residue of up to 16 carbon atoms or, if R.sup.4 is a hydrogen atom, a cycloalkyl group or an aryl or aralkyl group optionally substituted by one or several C.sub.1 -C.sub.6 -dialkylamino groups or by one or several C.sub.1 -C.sub.6 -alkoxy groups,R.sup.4 is a hydrogen atom, a saturated, unsaturated, straight- or branched-chain or cyclic hydrocarbon residue of up to 16 carbon atoms, orR.sup.3 and R.sup.4 jointly mean a saturated or unsaturated 5- or 6-membered ring optionally substituted or containing an O, S, N atom or oxo substituent, and Y is COOX or CONR.sub.3 R.sub.4,are valuable complexing agents, complexes or complex salts, e.g., for use as NMR or X-ray diagnostic image-enhancement agents or radioactive diagnostic agents.Type: GrantFiled: November 19, 1990Date of Patent: December 2, 1997Assignee: Schering AktiengesellschaftInventors: Heinz Gries, Bernd Raduechel, Hans-Joachim Weinmann, Wolfgang Muetzel, Ulrich Speck
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Patent number: 5693808Abstract: Di-, tri- and tetrachromophoric perylene-3,4:9,10-tetracarboxylic acid imides of the formula I ##STR1## in which A is, for example, 1,4-phenylene,R is 1-hexylheptyl andm is 2,are readily accessible by reaction of a perylene-3,4:9,10-tetracarboxylic acid monoanhydride monoimide with 1,4-diaminobenzene-bisformamide. The preparation process and also a specific process for the preparation of monochromic perylene-3,4:9, 10-tetracarboxylic acid bisimides are also claimed. These processes are particularly suitable for reaction of highly electron-rich aromatic amines, which cannot be reacted under conventional condensation conditions.Type: GrantFiled: November 6, 1995Date of Patent: December 2, 1997Assignee: Ciba Specialty Chemicals CorporationInventor: Heinz Langhals
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Patent number: 5686390Abstract: An iminosulfonylurea compound or a salt thereof which is useful as a herbicide and growth control agent against weeds.Type: GrantFiled: December 15, 1995Date of Patent: November 11, 1997Assignee: Nissan Chemical Industries Ltd.Inventors: Kenzi Makino, Shigeaki Akiyama, Hideaki Suzuki, Takeshi Nagaoka, Toshio Niki, Koichi Suzuki, Tsutomu Nawamaki, Shigeomi Watanabe, Kimihiro Ishikawa
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Patent number: 5683964Abstract: An N-(substituted amino)imide derivative represented by the formula (I) is a novel compound which can be utilized as an effective ingredient of herbicidal compositions. ##STR1## wherein, R.sup.1 is hydrogen atom, C.sub.1 -C.sub.4 alkyl group, C.sub.7 -C.sub.9 aralkyl group, C.sub.1 -C.sub.4 haloalkyl group, (C.sub.1 -C.sub.4 alkyl)carbonyl group or (C.sub.1 -C.sub.4 alkyl)sulfonyl group;A represents a structure selected from the group consisting of the following formulas (A-1), (A-2), (A-3), (A-4) and (A-5) ##STR2## wherein R.sup.2 and R.sup.3 in the formula (A-1) are independently hydrogen atom or C.sub.1 -C.sub.4 alkyl group, but not R.sup.2 =R.sup.3 =H, R.sup.4 in the formula (A-4) is halogen atom, C.sub.1 -C.sub.4 alkyl group and/or nitro group, m is an integer of 0-4, the substituents of m not less than 2 being same or different;X.sup.1 and X.sup.2 are independently hydrogen atom, halogen atom, C.sub.1 -C.sub.4 alkyl group, C.sub.1 -C.sub.4 alkoxy group, C.sub.1 -C.sub.4 alkylthio group, C.sub.1 -C.sub.Type: GrantFiled: July 20, 1995Date of Patent: November 4, 1997Assignee: Kureha Kagaku Kogyo K.K.Inventors: Yoichi Kanda, Hideo Arabori, Masato Arahira, Tsutomu Sato
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Patent number: 5679794Abstract: Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.Type: GrantFiled: June 6, 1995Date of Patent: October 21, 1997Assignee: Ciba-Geigy CorporationInventors: Joseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali
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Patent number: 5672703Abstract: New classes of 1,3,5-triazine compounds and compositions containing the same are disclosed, which compounds are of the general formula ##STR1## wherein each of Y, Z and optionally X are independently selected from a group of the formula (II), (III) and/or (IV) ##STR2## These compounds and compositions are particularly suitable for use as crosslinking agents in curable compositions such as coatings, particularly in combination with active hydrogen groups-containing materials. The 1,3,5-triazine compounds of the present invention do not release formaldehyde as a volatile by-product during cure, and certain of these compounds may be used in curable compositions which may be cured at relatively low temperature. Processes for preparing such compounds, compositions containing the same, as well as additional uses thereof, are also disclosed.Type: GrantFiled: March 21, 1995Date of Patent: September 30, 1997Assignee: Cytec Technology Corp.Inventors: Subban Ramesh, Laurence Lyman Williams, Ram Baboo Gupta, Lon-Tang Wilson Lin
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Patent number: 5670452Abstract: The present invention provides an indazolesulfonylurea derivative represented by the general formula: ##STR1## wherein R.sup.1 is a hydrogen atom or an alkyl group, etc., R.sup.2 and R.sup.3 are the same or different and represent a hydrogen atom, a halogen atom, an alkyl group, the formula --COR.sup.4 (wherein R.sup.4 represents an alkoxy group, etc.), an alkoxy group, a haloalkoxy group or a cyano group, etc., X is an oxygen atom or a sulfur atom, Y is a hydrogen atom or an alkyl group, etc., A and B are the same or different and represent a halogen atom, an alkoxy group or an alkyl group, etc., and Z represents a nitrogen atom or a methine group, as well as a herbicide containing it as an active ingredient and an intermediate for its production.The compound of the present invention exhibits excellent herbicidal effects over a wide range from the preemergence stage to the growing stage of various weeds which are problematic in agricultural fields.Type: GrantFiled: April 9, 1996Date of Patent: September 23, 1997Assignees: Kumiai Chemical Industry Co., Ltd., Ihara Chemical Industry Co., Ltd.Inventors: Chiharu Suzuki, Katsumi Masuda, Masatoshi Tamaru, Masahito Inamori, Nobuo Takefuji, Katsutada Yanagisawa, Yasunori Ogawa
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Patent number: 5668199Abstract: Compounds possessing both a hindered amine moiety, such as a derivative of 2,2,6,6-tetramethylpiperidine, and a hydroxylamine moiety where the N-hydroxy group is not attached to a nitrogen atom in a piperidine ring are valuable stabilizers for protecting polymer compositions against the deleterious effects of actinic light and from the adverse effects of high temperature polymer processing environments.Type: GrantFiled: June 6, 1995Date of Patent: September 16, 1997Assignee: Ciba-Geigy CorporationInventors: Joseph Suhadolnik, Ramanathan Ravichandran, Valerio Borzatta, Graziano Vignali
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Patent number: 5656760Abstract: The present invention provides a compound having the formula: ##STR1## in which M is hydrogen, sodium, potassium, calcium, magnesium, ammonium, mono-, di-, tri- or tetra-C.sub.1 -C.sub.4 alkylammonium, mono-, di- or tri-C.sub.1 -C.sub.4 hydroxyalkylammonium or ammonium that is di- or tri-substituted by a mixture of C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 hydroxyalkyl groups; R.sub.1 is a group having the formula: ##STR2## in which M has its previous significance and n is 1 or 2; and R.sub.2 is O--C.sub.1 -C.sub.12 alkyl or N(R.sub.3)(R.sub.4) in which R.sub.3 and R.sub.4, independently, are hydrogen, C.sub.1 -C.sub.12 alkyl or C.sub.1 -C.sub.4 hydroxyalkyl, or R.sub.3 and R.sub.4, together with the nitrogen atom, are the atoms required to form a pyrrolidine, piperidine or morpholine group.Type: GrantFiled: September 20, 1995Date of Patent: August 12, 1997Assignee: Ciba-Geigy CorporationInventors: Jean-Pierre Bacher, Claude Eckhardt, Dieter Reinehr
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Patent number: 5641885Abstract: The present invention relates to carboxylated amino-1,3,5-triazines represented by the formula: ##STR1## wherein Z and Z.sup.1 are independently selected from the group consisting of hydrogen, a hydrocarbyl, a hydrocarbyloxy and a group represented by the formula --N(Q).sub.2 ; each Q is independently selected from the group consisting of hydrogen, a hydrocarbyl and a group Y, with the proviso that no more than one Q in each --N(Q.sub.2) is Y; and Y is selected from the group consisting of a carboxyl group and a carboxylate salt group. These carboxylated amino-1,3,5-triazines find use, for example, as intermediates in the production of other useful amino-1,3,5-triazine derivatives, particularly carbamate and isocyanate functional 1,3,5-triazines. The so-produced derivatives may find use as, for example, crosslinking agents in curable compositions.Type: GrantFiled: May 18, 1995Date of Patent: June 24, 1997Assignee: Cytec Technology Corp.Inventors: Lawrence Allen Flood, Ram Baboo Gupta
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Patent number: 5610211Abstract: Compounds of the formula (I) ##STR1## in which n is zero or 1, X denotes a group of formula (II), ##STR2## R.sub.1 and R.sub.5 are e.g. hydrogen, R.sub.2, R.sub.3 and R.sub.4, which may be identical or different, are C.sub.2 -C.sub.12 alkylene, R.sub.6 is e.g. hydrogen or C.sub.1 -C.sub.18 alkyl and R.sub.7 is e.g. hydrogen or C.sub.1 -C.sub.8 alkyl, are useful as stabilizers for organic materials against degradation induced by light, heat or oxidation.Type: GrantFiled: November 2, 1995Date of Patent: March 11, 1997Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Roberto Scrima
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Patent number: 5607988Abstract: A piperidine compound represented by the following general formula (I) and a stabilized polymeric material composition containing said compound.A[(O--X).sub.n NH--Y].sub.m (I)(wherein A represents a residue formed by eliminating m hydroxyl groups from a polyhydric (tri- to hexa-hydric) alcohol; X represents an alkylene group having 2 to 4 carbon atoms; n is an integer of from 1 to 15; m is an integer of from 3 to 6; and Y represents a group: ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl, alkoxy or acyl group having 1 to 18 carbon atoms or an oxygen free radical; and R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 18 carbon atoms.Type: GrantFiled: June 7, 1995Date of Patent: March 4, 1997Assignee: Asahi Denka Kogyo Kabushiki KaishaInventors: Kazuo Maekawa, Yutaka Nakahara, Kouzaburo Shinpo
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Patent number: 5606055Abstract: A novel organic white pigment which can be applied to an organic white pigment composition useful as a paper coating agent or an aqueous or oily ink or paint is provided. This organic white pigment consists of an alkylene-bismelamine derivative, represented by the following general formula (I), ##STR1## wherein R is a hydrogen atom or a lower alkyl group containing 1 to 4 carbon atoms or alicyclic group, R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are respectively same or different hydrogen atoms or lower alkyl groups containing 1 to 4 carbon atoms, R.sub.1, and R.sub.2, or R.sub.3, and R.sub.4 may respectively form heterocyclic groups with nitrogen atoms and X is a lower alkylene group containing 2 to 3 carbon atoms.Type: GrantFiled: October 13, 1993Date of Patent: February 25, 1997Assignee: Hakkol Chemical Co., Ltd.Inventors: Shigekazu Matsumoto, Takao Yanagisawa
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Patent number: 5604178Abstract: This invention is to provide an N-(substituted amino)pyrrole derivative represented by the formula (I): which is used as an effective ingredient of herbicidal compositions: ##STR1## wherein R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is independently hydrogen atom, halogen atom, C.sub.1 -C.sub.4 alkyl group, (C.sub.1 -C.sub.4 alkyl)carbonyl group, (C.sub.3 -C.sub.6 cycloalkyl) carbonyl group, (C.sub.1 -C.sub.4 haloalkyl)carbonyl group, (C.sub.3 -C.sub.5 alkenyl)carbonyl group, benzoyl group which may be substituted with 1-3 halogen atoms and/or C.sub.1 -C.sub.4 alkyl groups, N,N-[(di-C.sub.1 -C.sub.4 alkyl)amino]carbonyl group, (C.sub.1 -C.sub.4 alkoxy)carbonyl group, etc., X.sup.1 and X.sup.2 are independently hydrogen atom, halogen atom, C.sub.1 -C.sub.4 alkyl group, C.sub.1 -C.sub.4 alkoxy group, etc., and Z is nitrogen atom or CH.Type: GrantFiled: October 14, 1994Date of Patent: February 18, 1997Assignee: Kureha Kagaku Kogyo K.K.Inventors: Yoichi Kanda, Hideo Arabori, Masato Arahira, Tsutomu Sato
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Patent number: 5604179Abstract: An iminosulfonylurea derivative of the formula (1) or its salt ##STR1## wherein Q is ##STR2## wherein the variables are herein below defined, and a herbicidal and and growth control method.Type: GrantFiled: June 7, 1995Date of Patent: February 18, 1997Assignee: Nissan Chemical Industries Ltd.Inventors: Kenzi Makino, Shigeaki Akiyama, Hideaki Suzuki, Takeshi Nagaoka, Toshio Niki, Koichi Suzuki, Tsutomu Nawamaki, Shigeomi Watanabe, Kimihiro Ishikawa
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Patent number: 5578667Abstract: The invention relates to novel water-soluble antioxidants of formula ##STR1## wherein the variables are as defined in the claims, to a process for their preparation and to the use thereof for the photochemical and thermal stabilisation of dyed and undyed polyamide fibre materials.Type: GrantFiled: September 15, 1995Date of Patent: November 26, 1996Assignee: Ciba-Geigy CorporationInventors: Francesco Fuso, Gerhard Reinert
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Patent number: 5574037Abstract: This invention concerns novel compounds of the formula I: ##STR1## in which P is a group of formula II or a group of formula III; R.sup.1 is alkyl, cycloalkyl, cycloalkylalkyl, phenyl or phenylalkyl; R.sup.2 is hydrogen, alkyl, amino or alkylamino; R.sup.3 and R.sup.4 are independently hydrogen, alkyl, phenyl or benzyl; R.sup.6 is alkyl, amino or alkylamino; C and D are independently ethylene or trimethylene; Z is a direct bond between C and D, or an oxy, thio, carbonyl, methylene, ethylenedioxymethylene, ethylidene, or isopropylidene link, or Z is a group of the formula .dbd.N.R.sup.5 in which R.sup.5 is alkyl, phenyl or benzyl; R8 is hydrogen, cycloalkylalkyl, alkyl, alkenyl, alkynyl or phenylalkyl; or R8 is a alkylene or alkenylene linked to the nitrogen atom of the group Q.A.Type: GrantFiled: June 7, 1995Date of Patent: November 12, 1996Assignee: Imperial Chemical Industries PLCInventors: Stuart D. Mills, Rodney B. Hargreaves, Bernard J. McLoughlin
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Patent number: 5571915Abstract: This invention provides a process for preparing amide derivatives of acids by the reaction of haloaminotriazines and acid halides.This invention also provides a process for preparing isocyanates and isocyanate adducts from amide derivatives derived from haloaminotriazines and acid halides such as oxalyl chloride, phosgene and phosgene analogs.Melamine derived acid amides are prepared by reaction of trichloro and hexachloromelamines with chloroformates and acid chlorides. The by-product chlorine may be recycled in this process.Amides, carbamates, sulfonamides, phosphoramides, and related amide derivatives may be prepared by the novel processes of the invention.Type: GrantFiled: March 3, 1995Date of Patent: November 5, 1996Assignee: Cytec Technology Corp.Inventor: Ram B. Gupta
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Patent number: 5561179Abstract: Compounds of the formula (I) ##STR1## in which m and n are numbers from 1 to 50; A is --O-- or >N--R.sub.6 where R.sub.6 is e.g. hydrogen or C.sub.1 -C.sub.18 alkyl; R.sub.1 and R.sub.4, which may be identical or different, are C.sub.1 -C.sub.18 alkyl, phenyl, C.sub.1 -C.sub.8 alkoxy, OH, ONa or OK; R.sub.2 is e.g. C.sub.2 -C.sub.12 alkylene; R.sub.3 is e.g. hydrogen or C.sub.1 -C.sub.8 alkyl; R.sub.5 is e.g. a group of the formula ##STR2## in which R.sub.9 is e.g. 2,2,6,6-tetramethyl-4-piperidyl; A' has one of the meanings of A; p is e.g. 1 and R.sub.10 is e.g. C.sub.2 -C.sub.18 alkylene; X.sub.1 has one of the meanings of R.sub.1 or is a group (R.sub.27).sub.3 SiO-- where R.sub.27 is C.sub.1 -C.sub.18 alkyl; X.sub.2 is hydrogen, Na, K, C.sub.1 -C.sub.8 alkyl or a group (R.sub.27).sub.3 Si-- with R.sub.27 as defined above and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.Type: GrantFiled: November 21, 1995Date of Patent: October 1, 1996Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Primo Carrozza
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Patent number: 5536722Abstract: 2,4,6-Triaminotriazine derivatives as potentiators of chemotherapeutic agents in the treatment of cancer.Type: GrantFiled: May 11, 1994Date of Patent: July 16, 1996Assignee: Pfizer Inc.Inventors: Jotham W. Coe, Anton F. J. Fliri, Takushi Kaneko, Eric R. Larson
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Patent number: 5514213Abstract: A novel organic white pigment which can be applied to an organic white pigment composition useful as a paper coating agent or an aqueous or oily ink or paint is provided. This organic white pigment consists of an alkylenebismelamine derivative, represented by the following general formula (I), ##STR1## wherein R is a hydrogen atom or a lower alkyl group containing 1 to 4 carbon atoms or alicyclic group, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are respectively same or different hydrogen atoms or lower alkyl groups containing 1 to 4 carbon atoms, R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4 may respectively form heterocyclic groups with nitrogen atoms and X is a lower alkylene group containing 2 to 3 carbon atoms.Type: GrantFiled: May 17, 1995Date of Patent: May 7, 1996Assignee: Hakkol Chemical Co., Ltd.Inventors: Shigekazu Matsumoto, Takao Yanagisawa
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Patent number: 5512676Abstract: The solvent-resistance and thermal stability of polyamideimides of the general formulae: ##STR1## is improved by capping the amideimides with a crosslinking functionality (Y) containing a residue selected from the group of: ##STR2## wherein R.sub.1 =lower alkyl, lower alkoxy, aryl, aryloxy, substituted alkyl, substituted aryl (either including hydroxyl or halo-substituents), halogen, or mixtures thereof;j=0, 1, or 2:G=--CH.sub.2 --, --O--, --S--, --SO.sub.2 --, --SO--, --CO--, --CHR--, or --CR.sub.2 --;R=hydrogen, lower alkyl, or phenyl;=methallyl or allyl;Me=methyl;R.sub.2 =a trivalent organic radical; andR.sub.3 =a divalent organic radical.The amideimde oligomers may be linear or multidimensional, and can be processed into blends, prepregs, or composites. Methods of making these amideimides and intermediates useful in the syntheses are also described.Type: GrantFiled: July 26, 1994Date of Patent: April 30, 1996Assignee: The Boeing CompanyInventors: Clyde H. Sheppard, Hyman R. Lubowitz
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Patent number: 5512535Abstract: This invention relates to herbicidal pyridinesulfonylureas which are highly active as preemergence and postemergence herbicides.Type: GrantFiled: December 8, 1994Date of Patent: April 30, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Paul Hsiao-Tseng Liang
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Patent number: 5510351Abstract: Described are delta 17 and delta 20 olefinic and saturated 17 Beta-substituted 4-aza-5 alpha-androstan-3-ones and related compounds having 5 alpha reductase inhibitors for treatment of benign prostatic hyperplasia and other hyperandrogenic related disorders.Type: GrantFiled: November 14, 1994Date of Patent: April 23, 1996Assignee: Merck & Co., Inc.Inventors: Donald W. Graham, Susan D. Aster, Richard L. Tolman
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Patent number: 5507963Abstract: There are described compounds of formula I ##STR1## wherein A is ##STR2## and R.sub.1 to R.sub.5 are as defined in claim 1. Said compounds are suitable for use as metal deactivators.Type: GrantFiled: May 3, 1995Date of Patent: April 16, 1996Assignee: Ciba-Geigy CorporationInventor: Jean-Pierre Wolf
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Patent number: 5502189Abstract: Compounds which comprise at least one group of the formula I or II ##STR1## and at least one polyalkylpiperidine group of the formula III ##STR2## in which R and R.sub.1 to R.sub.6 have the meaning indicated in claim 1, are effective stabilisers for organic materials against damage by light, oxygen and heat.Type: GrantFiled: October 6, 1994Date of Patent: March 26, 1996Assignee: Ciba-Geigy CorporationInventors: Mario Slongo, Jean-Luc Birbaum, Jean Rody, Andreas Valet
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Patent number: 5496944Abstract: A process for preparing a tris-lactam crosslinking agent, tris-pyrrolidonyl triazine, from N,N',N"-tris(4-chlorobutyryl)melamine by treatment of the chlorobutyryl derivative with a base such as sodium or potassium carbonate to effect intramolecular cyclization to the tris-lactam. A curable composition comprises tris-pyrrolidonyl triazine as the crosslinking agent and a hydroxyfunctional or aminofunctinoal material as a resin. Thick films with no pinholes are prepared from the curable compositions using powder coating techniques.Type: GrantFiled: June 6, 1995Date of Patent: March 5, 1996Assignee: Cytec Technology Corp.Inventors: R. B. Gupta, Robert G. Lees
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Patent number: 5493023Abstract: Melamine cyanurate is prepared by heating melamine powder and cyanuric acid powder at 250.degree. to 500.degree. C. substantially in the absence of any liquid medium. The melamine cyanurate can be obtained in a granular form when the heating is conducted subsequent to granulation of a mixture of both the powders.Type: GrantFiled: December 2, 1993Date of Patent: February 20, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Kazuo Wakimura, Tetsuo Yoshiyama, Hiroshi Kato, Yuri Kawano
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Patent number: 5489591Abstract: s-Triazine (1,3,5-triazine) is chemically modified to obtain s-triazine derivative effective for prevention and treatment of estrogen-dependent diseases.Type: GrantFiled: August 29, 1994Date of Patent: February 6, 1996Assignee: Zenyaku Kogyo Kabushiki KaishaInventors: Hideshi Kobayashi, Toshihiko Komatsu, Seiichi Fukuda, Yoshio Tsuchida, Masanobu Kato, Shinichi Yaguchi, Naohito Ogose, Hajime Ono, Yasuhiro Izumisawa, Masayuki Takahashi, Tsutomu Nakagane
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Patent number: 5489683Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.Type: GrantFiled: March 28, 1994Date of Patent: February 6, 1996Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Graziano Vignali, Fabrizio Guizzardi
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Patent number: 5472933Abstract: This invention relates to certain herbicidal pyrrolesulfonylureas, compositions thereof and a method for their use as herbicides or plant growth regulants.Type: GrantFiled: February 24, 1993Date of Patent: December 5, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: William T. Zimmerman, Bruce A. Lockett, John Cuomo
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Patent number: 5470921Abstract: A synthetic polyamide of formula I and its salts ##STR1## in which each R.sub.1 independently is selected from hydrogen, carboxyl, amino or a group of formula .alpha.-A.sub.1 -R.sub.10 (.alpha.)where A, is a bridging group and R.sub.10 is a sterically hindered amine group;each R.sub.2 independently is hydrogen or a group of formula .alpha.A is a bridging group of the formula ##STR2## is 0 or 1; R.sub.3 is hydrogen, C.sub.1-12 alkyl or is a significance of R.sub.10 ;R.sub.5 is hydrogen or C.sub.1-12 alkylR.sub.4 is a significance of R.sub.10 or a group of formula .alpha.; andp is an integer from 5 to 200;with the proviso that the compound of formula I contains 1-400 sterically hindered amine groups.Type: GrantFiled: May 20, 1994Date of Patent: November 28, 1995Assignee: Sandoz Ltd.Inventors: Bansi L. Kaul, Angelos-Elie Vougioukas, Jurgen Goldmann
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Patent number: 5466803Abstract: Novel piperidine-triazine compounds of the formula (I) useful as light stabilizers, heat stabilizers and antioxidants for organic materials.The meanings of R.sub.1, R.sub.2, R.sub.3, R.sub.4, X.sub.1, X.sub.2, X.sub.3, Y.sub.1, Y.sub.2, M and N are defined in the text.Type: GrantFiled: February 3, 1994Date of Patent: November 14, 1995Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Graziano Vignali
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Patent number: 5461024Abstract: A novel thiophenesulfonylurea derivative having herbicidal activity, having the formula (I): ##STR1## wherein the substituents are herein described.Type: GrantFiled: December 9, 1993Date of Patent: October 24, 1995Assignee: Korea Research Institute of Chemical TechnologyInventors: Dae-Whang Kim, Dong Ju Jeon, Sang Soon Park, Jae Chun Woo, Tae Jun Kim
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Patent number: 5457199Abstract: The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which X.sub.1, X.sub.2, X.sub.3 and n are as defined in the text. The compounds of the invention can be used as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.Type: GrantFiled: July 11, 1994Date of Patent: October 10, 1995Assignee: Ciba-Geigy CorporationInventors: Roberto Scrima, Graziano Zagnoni
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Patent number: RE35053Abstract: Disclosed are .DELTA..sup.9(11) -steroids (VI) and amino substituted steroids (XI) which contain an amino group attached to the terminal carbon atom of the C.sub.17 -side chain, more particularly amino steroids (Ia and Ib), aromatic steroids (II), .DELTA..sup.16 -steroids (IIIa and IIIb), reduced A-ring steroids (IV), .DELTA..sup.17(20) -steroids (Va and Vb) and .DELTA..sup.9(11) -steroids (VI) which are useful as pharmaceutical agents for treating a number of conditions.Type: GrantFiled: October 9, 1992Date of Patent: October 10, 1995Assignee: The Upjohn CompanyInventors: John M. McCall, E. Jon Jacobsen