Chalcogen Bonded Directly To Triazine Ring Carbon Patents (Class 544/219)
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Patent number: 5721364Abstract: A method is provided for making ammelide ethers, such as a 2-amino-4,6-dialkoxy-1,3,5-triazine. A 2-amino-4,6-dihalo-1,3,5-triazine (ADXT) is synthesized in the presence of an aromatic organic solvent, and reaction is effected directly between the (ADXT) synthesis mixture and an alkali metal C.sub.(1-4) alkoxide and C.sub.(1-4) alkanol, including contact through a static mixer. These ammelide ethers are useful as intermediates for making N-phenylsulfonyl-N-triazinylureas, which have herbicidal and growth regulating properties.Type: GrantFiled: December 13, 1996Date of Patent: February 24, 1998Assignee: Novartis CorporationInventors: Dean Kent Hoglen, Heinz Peter Schwemlein, Herng-Tay Wu
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Patent number: 5703017Abstract: 3-(Het)arylcarboxylic acid derivatives of the formula I ##STR1## where R is formyl, CO.sub.2 H or a radical hydrolyzable to COOH and the other substituents have the following meanings:R.sup.2 and R.sup.3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.14, where R.sup.14 is hydrogen or, together with R.sup.3, forms an alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen;R.sup.4 is phenyl or naphthyl, each of which is unsubstituted or substituted or an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;R.sup.5 is hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, alkoxyalkyl, alkylthioalkyl or phenyl;R.sup.6 is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or C.sub.3 -C.sub.Type: GrantFiled: October 19, 1995Date of Patent: December 30, 1997Assignee: BASF AktiengesellschaftInventors: Ernst Baumann, Joachim Rheinheimer, Uwe Josef Vogelbacher, Matthias Bratz, Hans Theobald, Matthias Gerber, Karl-Otto Westphalen, Helmut Walter, Wilhelm Rademacher
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Patent number: 5696261Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilisers, heat stabilisers and oxidation stabilisers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.Type: GrantFiled: November 8, 1995Date of Patent: December 9, 1997Assignee: Ciba Specialty Chemicals CorporationInventors: Valerio Borzatta, Graziano Vignali, Fabrizio Guizzardi
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Patent number: 5674668Abstract: A color photographic recording material having at least one silver halide emulsion layer, which material contains in at least one of its layers a combination of at least one UV absorber of the formula I and at least one low molecular weight or polymeric oil formula containing acid groups, for example of the formula T--?R.sup.21 --(Q.sup.1).sub.p !.sub.q --X.sup.21 --OH (II), exhibits improved absorption for UV light. ##STR1## In the formula I: R.sup.1 and R.sup.3 mean H, halogen, hydroxy, mercapto, alkyl, aryl, alkoxy, aryloxy, acyloxy, alkylthio, arylthio, --NR.sup.5 --R.sup.6, alkoxycarbonyl, carbamoyl or sulphamoyl;R.sup.2 means H, hydroxy, halogen or alkyl;R.sup.4 means alkyl, alkoxy, alkylthio, aryloxy, arylthio or a residue of the formula ##STR2## R.sup.5 means H, alkyl or aryl; R.sup.6 means H, alkyl, aryl, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl or sulphonyl;m, n and o mean 1, 2, 3 or 4,wherein two or more residues R.sup.1, R.sup.2 and R.sup.3 are identical or different;in the formula II:X.sup.Type: GrantFiled: August 26, 1996Date of Patent: October 7, 1997Assignee: Agfa-GevaertInventors: Jorg Hagemann, Gunter Helling, Beate Weber
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Patent number: 5674894Abstract: The current invention discloses novel amidine derivatives with nitric oxide donating property that can inhibit platelet aggregation and promote vasodilation in a single compound.Type: GrantFiled: May 15, 1995Date of Patent: October 7, 1997Assignee: G.D. Searle & Co.Inventors: Mark G. Currie, Foe S. Tjoeng, Mark E. Zupec
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Patent number: 5661106Abstract: 3-(Het)aryloxy(thio)carboxylic acid derivatives of the formula I ##STR1## where R.sup.1 is hydrogen, COOH or a radical which can be hydrolyzed to give COOH;R.sup.2 and R.sup.3 are each halogen, alkyl, haloalkyl, alkoxy, haloalkoxy or alkylthio;X is nitrogen or CR.sup.14, where R.sup.14 is hydrogen or, together with R.sup.3, forms a 3-membered or 4-membered alkylene or alkenylene chain, in each of which a methylene group is replaced by oxygen;R.sup.4 is alkyl, cycloalkyl, cycloalkenyl, alkenyl or alkynyl, each of which is unsubstituted or substituted;an unsubstituted or substituted five-membered or six-membered heteroaromatic structure containing one to three nitrogen atoms or one sulfur or oxygen atom;unsubstituted or substituted phenyl or naphthyl;R.sup.4 and R.sup.5, together with the neighboring carbon atom, form a 3-membered to 8-membered ring which may contain an oxygen or sulfur atom and which is unsubstituted or substituted;R.sup.Type: GrantFiled: October 19, 1995Date of Patent: August 26, 1997Assignee: BASF AktiengesellschaftInventors: Ernst Baumann, Joachim Rheinheimer, Uwe Josef Vogelbacher, Matthias Bratz, Norbert Meyer, Matthias Gerber, Karl-Otto Westphalen, Helmut Walter, Wilhelm Rademacher
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Patent number: 5652364Abstract: Novel process for the preparation of 2,2,6,6-tetramethyl-4-piperidyloxy-1,3,5-triazines, based on the reaction of cyanuric chloride with C.sub.1 -C.sub.4 alkanols or with sodium or potassium C.sub.1 -C.sub.4 alkoxides and subsequent reaction with 2,2,6,6-tetramethyl-4-piperidinols in the presence of a transesterification catalyst.The various reactions can be carried out in the same reactor, without isolation of the intermediates.Type: GrantFiled: August 10, 1995Date of Patent: July 29, 1997Assignee: Ciba-Geigy CorporationInventors: Graziano Vignali, Fabrizio Guizzardi, Graziano Zagnoni, Roberto Scrima
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Patent number: 5641783Abstract: Disclosed are compounds having a straight or branched aliphatic hydrocarbon structure of formula I: ##STR1## In formula I, n is an integer from one to four and m is an integer from four to twenty. Independently, R.sub.1 and R.sub.2 are hydrogen, a straight or branched chain alkyl, alkenyl or alkynyl of up to twenty carbon atoms in length or --(CH.sub.2).sub.w R.sub.5. If R.sub.1 or R.sub.2 is --(CH.sub.2).sub.w R.sub.5, w may be an integer from one to twenty and R.sub.5 may be an hydroxyl, halo, C.sub.1-8 alkoxyl group or a substituted or unsubstituted carbocycle or heterocycle. Alternatively, R.sub.1 and R.sub.2 may jointly form a substituted or unsubstituted, saturated or unsaturated heterocycle having from four to eight carbon atoms, N being a hetero atom of the resulting heterocycle. R.sub.3 may be either hydrogen or C.sub.1-3. In the compounds, a total sum of carbon atoms comprising R.sub.1 or R.sub.2, (CH.sub.2).sub.n and (CH.sub.2).sub.m does not exceed forty. R.sub.Type: GrantFiled: September 8, 1994Date of Patent: June 24, 1997Assignee: Cell Therapeutics, Inc.Inventors: J. Peter Klein, Gail E. Underiner, Anil M. Kumar
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Patent number: 5633378Abstract: Polyalkylpiperidine compounds of the formula I ##STR1## in which Y is the group ##STR2## are very effective stabilizers for organic materials.Type: GrantFiled: June 29, 1995Date of Patent: May 27, 1997Assignee: Hoechst AktiengesellschaftInventors: Karl Gaa, Matthias Z ah, Josef Wiedemann
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Patent number: 5612338Abstract: Compounds of the formula ##STR1## wherein R.sub.1 is hydrogen or methyl,R.sub.2 is hydrogen, halogen, OCH.sub.3, SCH.sub.3 or CN,R.sub.3, R.sub.4, R.sub.5 are each independently of one another hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkoxycarbonyl, C.sub.1 -C.sub.5 alkanoyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, CN, NO.sub.2, or wherein two of those substituents are adjacent to each other and together are a methylenedioxy or difluoromethylenedioxy radical,K, L, M are each independently of one another CH or N (=nitrogen atom), but at least one of these three substituents is N, andY is oxygen or sulfur,are effective microbicides for controlling fungal diseases. They can be used for plant protection by themselves or as formulated compositions.Type: GrantFiled: July 28, 1995Date of Patent: March 18, 1997Assignee: Ciba-Geigy CorporationInventor: Stephan Trah
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Patent number: 5610121Abstract: The invention relates to new heterocyclically disubstituted sulphonylamino(thio)carbonyl compounds of the formula (I) ##STR1## in which Q represents oxygen or sulphur,R.sup.1 and R.sup.2 are identical or different and independently of one another represent a radical from the series comprising heterocyclyl, heterocyclylamino and heterocyclylimino, in each case optionally substituted and bonded via N, with the exception of optionally substituted pyrazolylamino in the meaning of R.sup.1,and salts of the compounds of the formula (I), furthermore to processes for their preparation, and to their use as herbicides.Type: GrantFiled: November 15, 1994Date of Patent: March 11, 1997Assignee: Bayer AktiengesellschaftInventors: Hans-Jochem Riebel, Ernst R. F. Gesing, Klaus-Helmut M uller, Peter M uller, Kurt Findeisen, Hans-Joachim Santel, Klaus L urssen, Robert R. Schmidt
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Patent number: 5602181Abstract: Naphthyl ethers of the general formula I ##STR1## where the index and the substituents have the meanings defined in the specification.Type: GrantFiled: October 12, 1994Date of Patent: February 11, 1997Assignee: BASF AktiengesellschaftInventors: Wassilios Grammenos, Reinhard Kirstgen, Hartmann K onig, Klaus Oberdorf, Hubert Sauter, Gisela Lorenz, Eberhard Ammermann
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Patent number: 5585422Abstract: s-Triazine UV absorbers substituted by a benzotriazolyl or benzophenonyl moiety exhibit unexpectedly improved UV absorption characteristics and outstanding efficacy in protecting organic substances from the deleterious effects of actinic radiation as well as good resistance to loss by volatilization during processing of stabilized compositions at elevated temperatures.Type: GrantFiled: September 20, 1995Date of Patent: December 17, 1996Assignee: Ciba-Geigy CorporationInventors: Robert A. Falk, Tyler A. Stevenson, Gregory R. Coughlin
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Patent number: 5576440Abstract: Compounds of formula (I), where R.sup.1, R.sup.2, n, W, R.sup.3 and A are as defined in claim 1, are suitable for use as herbicides and plant growth regulators. They can be produced by a process similar to known processes. To produce them, new compounds of formula (II) are reacted with a carbamate of formula R*--O--CO--NR.sup.3 A, where R.sup.3 stands for phenyl or alkyl. The compounds of formula (II) can be obtained from the corresponding sulphochlorides.Type: GrantFiled: January 4, 1995Date of Patent: November 19, 1996Assignee: Hoechst AktiengesellschaftInventors: Heinz Kehne, Lothar Willms, Oswald Ort, Klaus Bauer, Hermann Bieringer
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Patent number: 5565597Abstract: A process for the preparation of an acrylic or methacrylic compound of formula (I): ##STR1## wherein R is a hydrogen atom or methyl and n is an integer ranging from 2 to 20 inclusive, comprising reacting a halogeno-n-alkyl acrylate or methacrylate of the formula: ##STR2## in which n is as defined above and X is a halogen atom, with a thiocyanate salt in an organic solvent and in the presence of an effective phase-transferring amount of at least one phase-transfer agent.Type: GrantFiled: March 27, 1995Date of Patent: October 15, 1996Assignee: AtochemInventors: Marie-Christine Berthe, Paul Caubere, Yves Fort
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Patent number: 5563266Abstract: Disubstituted monochlorotriazines such as 2-chloro-4-mesitoxy-6-glycidoxy-1,3,5-triazine are prepared in organic solution by first combining a monoorganoxy dichlorotriazine with an aqueous alkali metal hydroxide solution in a specific concentration and molar ratio, and adding to the mixture thus produced a hydroxyaliphatic or hydroxyaromatic compound, preferably glycidol, in the presence of at least one hydrophilic phase transfer catalyst such as tetra-n-butylammonium bromide. The reaction can be integrated with either or both of a prior step of dichlorotriazine preparation and a subsequent step of capping a hydroxy-terminated polymer, especially a polyphenylene ether.Type: GrantFiled: June 2, 1995Date of Patent: October 8, 1996Assignee: General Electric CompanyInventors: Thomas J. Stanley, Sterling B. Brown, Paul E. Howson
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Patent number: 5563267Abstract: A method for making trialkali metal and triammonium salts of 2,4,6 trimercapto-s-triazine comprising the steps of:(a) forming a reaction mixture of an acetone solution of cyanuric chloride and an aqueous solution of sodium hydrosulfide hydrates;(b) stirring the mixture thereby forming 2,4,6-trimercapto-s-triazine;(c) acidifying the mixture to form a precipitate; and(d) dissolving the precipitate in a basic solution selected from alkali metal hydroxides and ammonium hydroxide thereby forming a trialkali metal or triammonium salt of 2,4,6 trimercapto-s-triazine.Type: GrantFiled: April 12, 1995Date of Patent: October 8, 1996Assignee: Eastman Kodak CompanyInventors: Charles S. Christ, Jr., Jianmin Shi
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Patent number: 5556974Abstract: Monomers of the formulae: ##STR1## and ##STR2## as well as polymers and copolymers thereof wherein n=2-20; R=H, CH.sub.3 or CHOHR' where R'=straight-chain or branched alkyl, optionally substituted by hydroxyl, alkoxy or ester substituents, straight-chain, branched or cyclic alkenyl, aryl, optionally substituted by halogenated, nitro or alkoxy substituents, unsaturated heterocycle, alkylaryl and arylalkyl, R=CH.sub.3 in formula (I) in the case of monomers and homopolymers wherein n=2 and in the case of monomers wherein n=4.Type: GrantFiled: October 20, 1995Date of Patent: September 17, 1996Assignee: AtochemInventors: Marie-Christine Berthe, Paul Caubere, Yves Fort
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Patent number: 5550234Abstract: Polyalkylpiperidine compounds of the formula I ##STR1## in which Y is one of the groups ##STR2## are distinguished by very low volatility at elevated temperature and are very effective stabilizers for organic substances.Type: GrantFiled: June 29, 1995Date of Patent: August 27, 1996Assignee: Hoechst AktiengesellschaftInventors: Karl Gaa, Matthias Z ah
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Patent number: 5550276Abstract: Compounds of the general formula I ##STR1## in which n is 1, 2 or 3 and in which X is oxygen or sulfur, T has the meaning of --S--, --S--S--, --S--S--, --S--S--S--S--, --S--S--S--S--S--, ##STR2## and Y has the meaning of ##STR3## in which Z has the meaning of --H, --COR.sup.13, --COOR.sup.13 or --CONHR.sup.13, and Q has the meaning of oxygen or --NR.sup.0 --, and R.sup.1, R.sup.2, R.sup.0, R.sup.4 and R.sup.13 are as defined in claim 1, with the proviso that the compound of the formula C.sub.2 H.sub.5 --S--CH.sub.2 CH(OH)--P(OC.sub.2 H.sub.5).sub.2 is excepted.The invention also relates to compositions containing the compounds of the formula I and organic materials, for example functional liquids and, in particular, lubricants.Type: GrantFiled: June 7, 1995Date of Patent: August 27, 1996Assignee: Ciba-Geigy CorporationInventors: Hermann O. Wirth, Hans-Helmut Friedrich, Kay S. Groninger
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Patent number: 5545645Abstract: Compounds of the formula: ##STR1## wherein: m is 0 or 1;R.sup.1 is hydrogen, hydroxy, or lower alkyl;R.sup.2 is hydrogen, or lower alkyl;R.sup.3 is ##STR2## or R.sup.2 and R.sup.3 taken together with the nitrogen atom to which they are attached represent a group of the formula: ##STR3## wherein: n is 0 or 1;p is 0, 1, 2 or 3;q is 0 or 1;R.sup.4 is hydrogen, lower alkyl, cycloalkyl, or optionally substituted phenyl;R.sup.5 is optionally substituted phenyl;X is (CH.sub.2).sub.p, or 4-piperidin-1-yl;Y is CH, CH--O--, CH--S--, or nitrogen;Z is CH.sub.2, NH, sulfur, or oxygen; andA is a substituted furanyl group.Type: GrantFiled: March 9, 1995Date of Patent: August 13, 1996Assignee: Syntex Pharmaceuticals, LimitedInventors: Jean-Claude Pascal, Gary McCort, Dominique Blondet, Fran.cedilla.oise Gellibert
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Patent number: 5545835Abstract: There are provided 5,6-disubstituted-3-pyridylmethyl ammonium halide compounds, a method for the preparation thereof and the use thereof for the preparation of 5-(substituted methyl)-2,3-pylidinedicarboxylic acids.Type: GrantFiled: November 4, 1994Date of Patent: August 13, 1996Assignee: American Cyanamid CompanyInventor: Henry L. Strong
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Patent number: 5529976Abstract: Compounds of formula (I), where R.sup.1, R.sup.2, n, W, R.sup.3 and A are as defined in claim 1, are suitable for use as herbicides and plant growth regulators. They can be produced by a process similar to known processes. To produce them, new compounds of formula (II) are reacted with a carbamate of formula R.sup.* --O--CO--NR.sup.3 A, where R.sup.3 stands for phenyl or alkyl. The compounds of formula (II) can be obtained from the corresponding sulphochlorides.Type: GrantFiled: November 9, 1994Date of Patent: June 25, 1996Assignee: Hoechst AktiengesellschaftInventors: Heinz Kehne, Lothar Willms, Oswald Ort, Klaus Bauer, Hermann Bieringer
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Patent number: 5529977Abstract: Disclosed are a pyrimidine or triazine compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents cyano group, a halogen atom, hydroxy group or --O--R.sup.7 where R.sup.7 represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R.sup.2 represents hydrogen atom or a lower alkyl group; R.sup.3 represents hydrogen atom or a lower alkyl group; R.sup.4 represents a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.Type: GrantFiled: October 21, 1994Date of Patent: June 25, 1996Assignee: UBE Industries, Ltd.Inventors: Katsumasa Harada, Takaaki Abe, Yuji Akiyoshi, Akio Matsushita, Mikio Kojima, Ikuo Shiraishi, Kaoru Yamamoto, Takashi Hayama
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Patent number: 5520906Abstract: Triazine compounds of the formula I ##STR1## wherein Y is NH or O,R.sup.1 in each case independently of one another are a radical of the formula II ##STR2## wherein Phe is a phenylene group which is unsubstituted or substituted by 1 to 4 alkyl or alkoxy groups having 1 to 10 C atoms andX is H or --SO.sub.3 H,andR.sup.2 and R.sup.3in each case independently of one another are a radical of the formula Y-R.sup.1,oralkoxy, alkylamino, arylamino or aryloxy having 1 to 10 C atoms. Also, cosmetic formulations, medicaments and pharmaceutical formulations containing the compounds, particularly as filters for solar rays.Type: GrantFiled: August 12, 1994Date of Patent: May 28, 1996Assignee: Merck Patent Gesellschaft Mit Beschrankter HaftungInventors: Ingeborg Stein, Michael Casutt, Ulrich Heywang, Roland Martin, Michael Schwarz
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Patent number: 5512535Abstract: This invention relates to herbicidal pyridinesulfonylureas which are highly active as preemergence and postemergence herbicides.Type: GrantFiled: December 8, 1994Date of Patent: April 30, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Paul Hsiao-Tseng Liang
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Patent number: 5502028Abstract: Herbicidal haloacetic acid derivatives of the formula: ##STR1## and salts thereof, where: A is --N.dbd. or --CH.dbd.;X is halo;R.sup.1 and R.sup.2, which may be the same or different, each represent alkyl, alkoxy, haloalkyl, haloalkoxy, halo, alkylamino or dialkylamino;R.sup.3 is --CN, --COOR.sup.5, --CONR.sup.6 R.sup.7, --CSNH.sub.2, --CHO, --CH.dbd.Z, --CH(OAlkyl).sub.2, --CH.sub.2 OH, --CH.sub.2 OR.sup.9, or a substituted or unsubstituted 5- or 6-membered heterocyclic group linked via a ring carbon atom which is between two ring heteroatoms;R.sup.4 is H, or a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl or aralkyl group;with R.sup.5, R.sup.6, R.sup.7, R.sup.9,and Z as defined in the specification.Type: GrantFiled: December 16, 1994Date of Patent: March 26, 1996Assignee: Schering Agrochemicals LimitedInventors: Christoph Harde, Gerhard Johann, Gabriele Kru/ ger, Richard Rees, Gerhard Tarara, Peter S. Gates
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Patent number: 5502189Abstract: Compounds which comprise at least one group of the formula I or II ##STR1## and at least one polyalkylpiperidine group of the formula III ##STR2## in which R and R.sub.1 to R.sub.6 have the meaning indicated in claim 1, are effective stabilisers for organic materials against damage by light, oxygen and heat.Type: GrantFiled: October 6, 1994Date of Patent: March 26, 1996Assignee: Ciba-Geigy CorporationInventors: Mario Slongo, Jean-Luc Birbaum, Jean Rody, Andreas Valet
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Patent number: 5498714Abstract: This invention relates to a process for producing tris(tribromophenoxy)-s-triazine. This process is characterized by causing an aqueous tribromophenolate solution of not less than 50 weight % concentration containing a reducing agent to react on cyanuric chloride in the presence of a phase transfer catalyst. The process of this invention provides for a high output per unit reactor capacity. The yield and purity of the product are also high.Type: GrantFiled: June 23, 1994Date of Patent: March 12, 1996Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.Inventors: Setsuo Nishibori, Hideto Kondo
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Patent number: 5493022Abstract: Salts of organic optical brighteners or light stabilizers with compounds which contain at least one ammonium, cycloammonium or immonium group and at least one aliphatic group, cycloaliphatic group, or aromatic group bonded to at least one (up to four) carbonyl group, or heteroaromatic group. resp. basic brighteners or light stabilizers with compounds which contain a radical containing at least one carboxylic acid or sulphonic acid radical and one aliphatic, cycloaliphatic, monomeric aromatic or heteroaromatic group, or contain a C.sub.2-14 -dicarboxylic acid or amino-C.sub.2-1 -alkylcarboxylic acid radical, are eminently suitable for the brightening and light stabilizing of synthetic plastic compositions.Type: GrantFiled: September 8, 1994Date of Patent: February 20, 1996Assignee: Sandoz Ltd.Inventors: Bansi L. Kaul, Angelos-Elie Vougioukas
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Patent number: 5489683Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.Type: GrantFiled: March 28, 1994Date of Patent: February 6, 1996Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Graziano Vignali, Fabrizio Guizzardi
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Patent number: 5488108Abstract: A photographic material is described which comprises, on a base, blue-sensitive, green-sensitive and/or red-sensitive silver-halide emulsion layers and if desired a protection layer, a layer containing a UV absorber being arranged between the uppermost silver-halide emulsion layer and the protection layer or on top of the uppermost silver-halide emulsion layer, wherein the UV absorber conforms to the formula ##STR1## in which the radicals R.sub.1 and R.sub.12 are as defined in claim 1.Type: GrantFiled: August 11, 1994Date of Patent: January 30, 1996Assignee: Ciba-Geigy CorporationInventors: David G. Leppard, Kurt Burdeska, Mario Slongo
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Patent number: 5482520Abstract: The present invention provides a chemical composition comprising a t-butyl calix[8]arene encapsulated cyanuric acid derivatized with at least one C.sub.4 -C.sub.50 n-alkyl halide, n-alkaryl halide, aryl halide or polyoxyalkylene halide.Type: GrantFiled: June 17, 1994Date of Patent: January 9, 1996Assignee: Texaco Inc.Inventors: Iftikhar Alam, Rodney L. D. Sung
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Patent number: 5482920Abstract: Pyrimidinyloxy- and triazinyloxy- and pyrimidinylthio- and triazinylthio-butyric acid derivatives of formula I ##STR1## wherein Q is ##STR2## A is hydroxy or a group ##STR3## and the other substituents are as described in patent claim 1, and salts of compounds of formula I, have herbicidal action and are suitable as active ingredients in weed control compositions.Type: GrantFiled: February 15, 1994Date of Patent: January 9, 1996Assignee: Ciba-Geigy CorporationInventor: Christoph Luthy
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Patent number: 5472933Abstract: This invention relates to certain herbicidal pyrrolesulfonylureas, compositions thereof and a method for their use as herbicides or plant growth regulants.Type: GrantFiled: February 24, 1993Date of Patent: December 5, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: William T. Zimmerman, Bruce A. Lockett, John Cuomo
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Patent number: 5468856Abstract: Monomers of the formulae: ##STR1## as well as polymers and copolymers thereof wherein n=2-20; R=H, CH.sub.3 or CHOHR' where R'=straight-chain or branched alkyl, optionally substituted by hydroxyl, alkoxy or ester substituents, straight-chain, branched or cyclic alkenyl, aryl, optionally substituted by halogenated, nitro or alkoxy substituents, unsaturated heterocycle, alkylaryl and arylalkyl, R=CH.sub.3 in formula (I) in the case of monomers and homopolymers wherein n=2 and in the case of monomers wherein n=4.Type: GrantFiled: March 17, 1994Date of Patent: November 21, 1995Assignee: AtochemInventors: Marie-Christine Berthe, Paul Caubere, Yves Fort
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Patent number: 5468857Abstract: Fungicidal compounds of the formula (I): ##STR1## and stereoisomers thereof, wherein K is oxygen or sulphur; Z is optionally substituted aryl or optionally substituted heteroaryl; X is a specified linking group; and A, B and E, which may be the same or different, are H, hydroxy, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 haloalkyl, C.sub.1-4 haloalkoxy, C.sub.1-4 alkylcarbonyl, C.sub.1-4 alkoxycarbonyl, phenoxy, nitro or cyano; except that when Z is unsubstituted phenyl and X and K are oxygen, A, B and E are not all hydrogen.Type: GrantFiled: February 3, 1994Date of Patent: November 21, 1995Assignee: Imperial Chemical Industries PLCInventors: Alan J. Buckley, Michael G. Huchings, Ian Ferguson, Kevin Beautement, John M. Clough, Patrick J. Crowley, Christopher R. A. Godfrey, Paul J. deFraine, Vivienne M. Anthony, Stephen P. Heaney
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Patent number: 5461024Abstract: A novel thiophenesulfonylurea derivative having herbicidal activity, having the formula (I): ##STR1## wherein the substituents are herein described.Type: GrantFiled: December 9, 1993Date of Patent: October 24, 1995Assignee: Korea Research Institute of Chemical TechnologyInventors: Dae-Whang Kim, Dong Ju Jeon, Sang Soon Park, Jae Chun Woo, Tae Jun Kim
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Patent number: 5457199Abstract: The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which X.sub.1, X.sub.2, X.sub.3 and n are as defined in the text. The compounds of the invention can be used as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.Type: GrantFiled: July 11, 1994Date of Patent: October 10, 1995Assignee: Ciba-Geigy CorporationInventors: Roberto Scrima, Graziano Zagnoni
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Patent number: 5449777Abstract: Compounds of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other hydrogen, C.sub.1 -C.sub.24 alkyl, phenyl-substituted C.sub.1 -C.sub.4 alkyl, unsubstituted or C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, unsubstituted or C.sub.1 -C.sub.4 alkyl-substituted phenyl, with the proviso that both substituents R.sub.1 and R.sub.2 are not simultaneously hydrogen,n is an integer from 3 to 8,R.sub.3 is C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.8 alkyl which is interrupted by --O--, --S-- or --NR.sub.4 --, unsubstituted or C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, phenyl-substituted C.sub.1 -C.sub.4 alkyl, unsubstituted or C.sub.1 -C.sub.12 alkyl-substituted phenyl or a radical --(CH.sub.2).sub.m --COOR.sub.4 or ##STR2## R.sub.4 is C.sub.1 -C.sub.18 alkyl, unsubstituted or C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.8 cycloalkyl, benzyl or phenyl,R.sub.5 is hydrogen, methyl, benzyl or a radical --OR.sub.7,m is 1 or 2,X is O, S, or NR.sub.Type: GrantFiled: July 1, 1994Date of Patent: September 12, 1995Assignee: Ciba-Geigy CorporationInventor: Rita Pitteloud
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Patent number: 5446044Type: GrantFiled: September 27, 1994Date of Patent: August 29, 1995Assignee: Warner-Lambert CompanyInventors: Edgardo Laborde, Mel Schroeder
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Patent number: 5446155Abstract: Disubstituted monochlorotriazines such as 2-chloro-4-mesitoxy-6-glycidoxy-1,3,5-triazine are prepared in organic solution by first combining a monoorganoxy dichlorotriazine with an aqueous alkali metal hydroxide solution in a specific concentration and molar ratio, and adding to the mixture thus produced a hydroxyaliphatic or hydroxyaromatic compound, preferably glycidol, in the presence of at least one hydrophilic phase transfer catalyst such as tetra-n-butylammonium bromide. The reaction can be integrated with either or both of a prior step of dichlorotriazine preparation and a subsequent step of capping a hydroxy-terminated polymer, especially a polyphenylene ether.Type: GrantFiled: August 30, 1994Date of Patent: August 29, 1995Assignee: General Electric CompanyInventors: Thomas J. Stanley, Sterling B. Brown, Paul E. Howson
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Patent number: 5428002Abstract: The invention relates to compounds of formula ##STR1## wherein W, X, Y.sup.1, Y.sup.2, Z, R.sup.1, R.sup.2 and R.sup.14 are as defined in the description, and to the preparation thereof, to weed control compositions and plant-growth-regulating compositions comprising such compounds as active ingredients, and to the use of the active ingredients or compositions for controlling weeds and for regulating plant growth.Type: GrantFiled: May 13, 1994Date of Patent: June 27, 1995Assignee: Ciba-Geigy CorporationInventors: Christoph Luthy, Jean-Pierre Obrecht
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Patent number: 5428037Abstract: Compounds of the formula: ##STR1## wherein A, R.sup.1, R.sup.2, R.sup.3 and m are defined as in the specification or a pharmaceutically acceptable acid addition salt or N-oxide thereof, are calcium and sodium channel antagonists useful for treating mammals having a variety of disease states, such as stroke, epilepsy, hypertension, angina, migraine, arrhythmia, thrombosis, embolism, and also for treatment of spinal injuries.Type: GrantFiled: April 9, 1993Date of Patent: June 27, 1995Assignee: Syntex Pharmaceuticals, Ltd.Inventors: Jean-Claude Pascal, Gary McCort, Dominique Blondet, Francoise Gellibert
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Patent number: 5418212Abstract: The present invention provides a novel alkanoic acid amide derivative of the formula, ##STR1## (wherein R.sup.1 is a hydrogen atom, an alkyl group or an alkoxyalkoxy group, R.sup.2 is a group of --SO.sub.2 R or a hydroxyl group, R.sup.5 is an alkyl group, R.sup.3 is an alkyl group, a cycloalkyl group, a cycloalkenyl group or a phenyl group, R.sup.4 is a hydrogen atom or an alkyl group, X and Y may be the same or different and are an alkoxy group, an alkylamino group or a dialkylamino group, and Z is a methine group or a nitrogen atom) and its salt, a process for preparing the same and a herbicidal composition containing the same as an effective ingredient.This compound kills annual and perennial weeds grown in paddy fields and upland fields at a small dose, and is safe to a useful crop plant.Type: GrantFiled: April 27, 1993Date of Patent: May 23, 1995Assignees: Kumiai Chemical Industry Co., Ltd., Ihara Chemical Industry Co., Ltd.Inventors: Takumi Yoshimura, Keiji Toriyabe, Katsumi Masuda, Ryo Hanai
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Patent number: 5409928Abstract: This invention provides a condensed pyrazole derivative of the Formula (1): ##STR1## (where A denotes CH or N, R.sup.0 and R.sup.3 denote same or different, a hydrogen atom or a lower alkyl group, R.sup.1 and R.sup.2 denote same or different, a hydrogen atom, a lower alkyl group, a lower alkoxy group, a lower alkylthio group, a nitro group or a halogen atom, m denotes 1 or 2, and n denotes 1, 2 or 3, provided that, when n is 2, two R.sup.2 may be connected to each other to form a lower alkylenedioxy group), or its pharmaceutically acceptable salt. This derivative or its salt is excellent in the effect of inhibiting the expression of action of androgen, thereby being excellent in therapeutical effect of benign prostatic hypertrophy, prostatic carcinoma, etc., and has a long lasting of efficacy and high oral absorption.Type: GrantFiled: October 20, 1993Date of Patent: April 25, 1995Assignee: Otsuka Pharmaceutical Co., Ltd.Inventors: Hiroshi Kiyokawa, Satoshi Yamada, Keisuke Miyajima, Koji Edamatsu, Kunihiko Tatsumi, Takeshi Yamauchi, Kazumasa Kishi, Kunihiko Kiyono
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Patent number: 5387683Abstract: A process is described for the photochemical and thermal stabilisation of undyed and dyed or printed polyester fibre materials, which comprises treating said materials with a compound of formula ##STR1## wherein R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl,R.sub.2 is C.sub.1 -C.sub.12 alkyl, andn is 0 to 5.Dyeings of superior lightfastness and sublimation fastness on polyester and cellulose acetate are obtained by this process.Type: GrantFiled: December 30, 1993Date of Patent: February 7, 1995Assignee: Ciba-Geigy CorporationInventors: Kurt Burdeska, Gerhard Reinert, Dieter Reinehr
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Patent number: 5387682Abstract: Radiation-sensitive organo-halogen compounds having a photo-labile halomethyl-1,3,5-triazine moiety and at least one polymerizable moiety within one molecule. The compounds of this invention have at least one halomethyl substituent attached to a carbon atom of the triazine moiety and at least one polymerizable monomeric moiety attached to another atom of the triazine moiety. The compounds of this invention can be used to prepare polymers having 1,3,5-triazine substituents attached thereto. The compounds of this invention are good photoinitiators, and compositions containing them can be used in printing, duplicating, copying, and other imaging systems. The compounds of this invention are capable of stimulation by actinic radiation at a wavelength of about 250 to 900 nanometers to generate free radicals.Type: GrantFiled: April 19, 1993Date of Patent: February 7, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: James A. Bonham, Mithcell A. Rossman, Richard J. Grant
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Patent number: 5378843Abstract: There are provided 5,6-disubstituted-3-pyridylmethyl ammonium halide compounds, a method for the preparation thereof and the use thereof for the preparation of 5-(substituted methyl)-2,3-pyridinedicarboxylic acids.Type: GrantFiled: November 22, 1993Date of Patent: January 3, 1995Assignee: American Cyanamid CompanyInventor: Henry L. Strong
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Patent number: 5360804Abstract: Multicomponent agent or kit for preparing the sulpho-conjugated form of pyridino, pyrimidino or triazino N-oxide compounds and method of use.The present invention relates to a multicomponent agent or kit for preparing the sulpho-conjugated form of pyridino, pyrimidino or triazino N-oxide compounds,comprising at least one compound of the pyridino, pyrimidino or triazino N-oxide type, on the one hand,and a sulphating agent, on the other hand.Type: GrantFiled: December 12, 1991Date of Patent: November 1, 1994Assignee: L'OrealInventors: Quintino Gaetani, Andre Rougier, Albert Duranton, Michel Hocquaux